![Page 1: ADVANCES IN BROMINE-BASED MERCURY … · advances in bromine-based mercury emission control at different french waste incineration plants bernhard vosteen vosteen consulting gmbh,](https://reader031.vdocuments.site/reader031/viewer/2022021712/5b9a070b09d3f29c338d6151/html5/thumbnails/1.jpg)
ADVANCES IN BROMINE-BASED MERCURY EMISSION CONTROL AT DIFFERENT FRENCH WASTE INCINERATION PLANTS
BERNHARD VOSTEEN VOSTEEN CONSULTING GMBH, COLOGNE, THIERRY GOSSET AND XAVIER CHAUCHERIE SARP INDUSTRIES-VEOLIA S.A., LIMAY (FRANCE)
VGB WORKSHOP MERCURY CONTROL, MELIA HOTEL BERLIN, JUNE 8 – 9, 2017
VOSTEEN Consulting
![Page 2: ADVANCES IN BROMINE-BASED MERCURY … · advances in bromine-based mercury emission control at different french waste incineration plants bernhard vosteen vosteen consulting gmbh,](https://reader031.vdocuments.site/reader031/viewer/2022021712/5b9a070b09d3f29c338d6151/html5/thumbnails/2.jpg)
VOSTEEN Consulting
Special thanks for cooperation with Vosteen Consulting and SARPI-VEOLIA
to
Dr. Alfred Grissinger, Luc Zonnenberg, Bert Horemans
from
![Page 3: ADVANCES IN BROMINE-BASED MERCURY … · advances in bromine-based mercury emission control at different french waste incineration plants bernhard vosteen vosteen consulting gmbh,](https://reader031.vdocuments.site/reader031/viewer/2022021712/5b9a070b09d3f29c338d6151/html5/thumbnails/3.jpg)
VOSTEEN Consulting
AGENDA •! SARPI-VEOLIA‘s Hazardous Waste Incineration (HWI) in Europe
•! Developement of the BEMO-Technology with CURRENTA in 2000 - 2009
•! SARPI-Application of the BEMO-Technology at Sedibex since 2016 (3 lines with wet FGD)
•! SARPI-Applications at diverse HWI plants with dry FGD since 2014
•! Experiences with the precipitation agent PRAVO®
•! Influence of Sulfur •! Outlook
![Page 4: ADVANCES IN BROMINE-BASED MERCURY … · advances in bromine-based mercury emission control at different french waste incineration plants bernhard vosteen vosteen consulting gmbh,](https://reader031.vdocuments.site/reader031/viewer/2022021712/5b9a070b09d3f29c338d6151/html5/thumbnails/4.jpg)
VOSTEEN Consulting
![Page 5: ADVANCES IN BROMINE-BASED MERCURY … · advances in bromine-based mercury emission control at different french waste incineration plants bernhard vosteen vosteen consulting gmbh,](https://reader031.vdocuments.site/reader031/viewer/2022021712/5b9a070b09d3f29c338d6151/html5/thumbnails/5.jpg)
VOSTEEN Consulting
10 SARPI-Hazardous Waste Incineration sites in Europe Testings of the BEMO-Technology already performed at 5 sites (with 10 lines in total)
![Page 6: ADVANCES IN BROMINE-BASED MERCURY … · advances in bromine-based mercury emission control at different french waste incineration plants bernhard vosteen vosteen consulting gmbh,](https://reader031.vdocuments.site/reader031/viewer/2022021712/5b9a070b09d3f29c338d6151/html5/thumbnails/6.jpg)
VOSTEEN Consulting
Preserving the environment by tackling the most difficult pollutants
![Page 7: ADVANCES IN BROMINE-BASED MERCURY … · advances in bromine-based mercury emission control at different french waste incineration plants bernhard vosteen vosteen consulting gmbh,](https://reader031.vdocuments.site/reader031/viewer/2022021712/5b9a070b09d3f29c338d6151/html5/thumbnails/7.jpg)
VOSTEEN Consulting
AGENDA •! SARPI-VEOLIA‘s Hazardous Waste Incineration (HWI) in Europe •! Developement of the BEMO-Technology with CURRENTA in 2000 - 2009
•! SARPI-Application of the BEMO-Technology at Sedibex since 2016 (3 lines with wet FGD)
•! SARPI-Applications at diverse HWI plants with dry FGD since 2014
•! Experiences with the precipitation agent PRAVO®
•! Influence of Sulfur
•! Outlook
![Page 8: ADVANCES IN BROMINE-BASED MERCURY … · advances in bromine-based mercury emission control at different french waste incineration plants bernhard vosteen vosteen consulting gmbh,](https://reader031.vdocuments.site/reader031/viewer/2022021712/5b9a070b09d3f29c338d6151/html5/thumbnails/8.jpg)
VOSTEEN Consulting
![Page 9: ADVANCES IN BROMINE-BASED MERCURY … · advances in bromine-based mercury emission control at different french waste incineration plants bernhard vosteen vosteen consulting gmbh,](https://reader031.vdocuments.site/reader031/viewer/2022021712/5b9a070b09d3f29c338d6151/html5/thumbnails/9.jpg)
VOSTEEN Consulting
Hg-CEM
Hg-CEM
Invention of the BEMO-Technology in 2000 by Prof. Vosteen
Bromides (HBr, NaBraq, CaBr2,aq)
![Page 10: ADVANCES IN BROMINE-BASED MERCURY … · advances in bromine-based mercury emission control at different french waste incineration plants bernhard vosteen vosteen consulting gmbh,](https://reader031.vdocuments.site/reader031/viewer/2022021712/5b9a070b09d3f29c338d6151/html5/thumbnails/10.jpg)
VOSTEEN Consulting
![Page 11: ADVANCES IN BROMINE-BASED MERCURY … · advances in bromine-based mercury emission control at different french waste incineration plants bernhard vosteen vosteen consulting gmbh,](https://reader031.vdocuments.site/reader031/viewer/2022021712/5b9a070b09d3f29c338d6151/html5/thumbnails/11.jpg)
VOSTEEN Consulting
![Page 12: ADVANCES IN BROMINE-BASED MERCURY … · advances in bromine-based mercury emission control at different french waste incineration plants bernhard vosteen vosteen consulting gmbh,](https://reader031.vdocuments.site/reader031/viewer/2022021712/5b9a070b09d3f29c338d6151/html5/thumbnails/12.jpg)
VOSTEEN Consulting
Source: Diploma thesis Andreas Pohontsch (2000)
Injection of 4 small Hg-bombs of 26 g only into the ABC, causing – without bromide-addition – 4 huge Hg(0)-peaks upstream of the tail-end SCR
![Page 13: ADVANCES IN BROMINE-BASED MERCURY … · advances in bromine-based mercury emission control at different french waste incineration plants bernhard vosteen vosteen consulting gmbh,](https://reader031.vdocuments.site/reader031/viewer/2022021712/5b9a070b09d3f29c338d6151/html5/thumbnails/13.jpg)
VOSTEEN Consulting
Table 1: Injection of Hg bombs [g]
Time Hg g[[amount
[g]
Time Hg amount [g] 9:24 5 10:32 180
9:32 10 10:37 200
9:38 15 10:43 220 9:49 20 10:48 240 9:54 40 10:53 260
9:59 60 10:58 280 10:04 80 11:03 300 10:09 100 11:08 310
10:15 120 11:13 320 10:20 140 11:20 340 10:26 160
Experimental time [min] Total Hg amount [g] 116 3400
Source: Diploma thesis Rico Kanefke (2001)
![Page 14: ADVANCES IN BROMINE-BASED MERCURY … · advances in bromine-based mercury emission control at different french waste incineration plants bernhard vosteen vosteen consulting gmbh,](https://reader031.vdocuments.site/reader031/viewer/2022021712/5b9a070b09d3f29c338d6151/html5/thumbnails/14.jpg)
VOSTEEN Consulting
!! Bromine far more effective than chlorine
![Page 15: ADVANCES IN BROMINE-BASED MERCURY … · advances in bromine-based mercury emission control at different french waste incineration plants bernhard vosteen vosteen consulting gmbh,](https://reader031.vdocuments.site/reader031/viewer/2022021712/5b9a070b09d3f29c338d6151/html5/thumbnails/15.jpg)
VOSTEEN Consulting
Mass ratio Br/Hg and achieved Hg removal rate in test spiking the boiler raw gas with 9,600 µg Hgtotal/dscm
Source: Diploma thesis Rico Kanefke (2001)
![Page 16: ADVANCES IN BROMINE-BASED MERCURY … · advances in bromine-based mercury emission control at different french waste incineration plants bernhard vosteen vosteen consulting gmbh,](https://reader031.vdocuments.site/reader031/viewer/2022021712/5b9a070b09d3f29c338d6151/html5/thumbnails/16.jpg)
VOSTEEN Consulting
Final Installation in 2009 (Dr. Rico Kanefke)
![Page 17: ADVANCES IN BROMINE-BASED MERCURY … · advances in bromine-based mercury emission control at different french waste incineration plants bernhard vosteen vosteen consulting gmbh,](https://reader031.vdocuments.site/reader031/viewer/2022021712/5b9a070b09d3f29c338d6151/html5/thumbnails/17.jpg)
VOSTEEN Consulting
Final Installation in 2009 (Dr. Rico Kanefke)
![Page 18: ADVANCES IN BROMINE-BASED MERCURY … · advances in bromine-based mercury emission control at different french waste incineration plants bernhard vosteen vosteen consulting gmbh,](https://reader031.vdocuments.site/reader031/viewer/2022021712/5b9a070b09d3f29c338d6151/html5/thumbnails/18.jpg)
VOSTEEN Consulting
Final Installation in 2009 (Dr. Rico Kanefke)
![Page 19: ADVANCES IN BROMINE-BASED MERCURY … · advances in bromine-based mercury emission control at different french waste incineration plants bernhard vosteen vosteen consulting gmbh,](https://reader031.vdocuments.site/reader031/viewer/2022021712/5b9a070b09d3f29c338d6151/html5/thumbnails/19.jpg)
VOSTEEN Consulting
Numberof injection lances at the ABC varies between 1 and 3
(depending on the mixing situation)
Final Installation in 2009 (Dr. Rico Kanefke)
![Page 20: ADVANCES IN BROMINE-BASED MERCURY … · advances in bromine-based mercury emission control at different french waste incineration plants bernhard vosteen vosteen consulting gmbh,](https://reader031.vdocuments.site/reader031/viewer/2022021712/5b9a070b09d3f29c338d6151/html5/thumbnails/20.jpg)
VOSTEEN Consulting
![Page 21: ADVANCES IN BROMINE-BASED MERCURY … · advances in bromine-based mercury emission control at different french waste incineration plants bernhard vosteen vosteen consulting gmbh,](https://reader031.vdocuments.site/reader031/viewer/2022021712/5b9a070b09d3f29c338d6151/html5/thumbnails/21.jpg)
VOSTEEN Consulting
Explanation of the control principle: Bromide injection only when needed
![Page 22: ADVANCES IN BROMINE-BASED MERCURY … · advances in bromine-based mercury emission control at different french waste incineration plants bernhard vosteen vosteen consulting gmbh,](https://reader031.vdocuments.site/reader031/viewer/2022021712/5b9a070b09d3f29c338d6151/html5/thumbnails/22.jpg)
VOSTEEN Consulting
Yearly means in 1999 - 2001
Yearly means in 2005 - 2016
?
![Page 23: ADVANCES IN BROMINE-BASED MERCURY … · advances in bromine-based mercury emission control at different french waste incineration plants bernhard vosteen vosteen consulting gmbh,](https://reader031.vdocuments.site/reader031/viewer/2022021712/5b9a070b09d3f29c338d6151/html5/thumbnails/23.jpg)
VOSTEEN Consulting
Successful industrial applications of the BEMO-Technology not only within CURRENTA, but at EGLV‘s central WWTP Bottrop
- since 2004, i.e. more than 12 years
![Page 24: ADVANCES IN BROMINE-BASED MERCURY … · advances in bromine-based mercury emission control at different french waste incineration plants bernhard vosteen vosteen consulting gmbh,](https://reader031.vdocuments.site/reader031/viewer/2022021712/5b9a070b09d3f29c338d6151/html5/thumbnails/24.jpg)
VOSTEEN Consulting
First external testings at the WWTP Bottrop already in December 2003 and June 2004
Little effort during testings in 2004 – Great success
![Page 25: ADVANCES IN BROMINE-BASED MERCURY … · advances in bromine-based mercury emission control at different french waste incineration plants bernhard vosteen vosteen consulting gmbh,](https://reader031.vdocuments.site/reader031/viewer/2022021712/5b9a070b09d3f29c338d6151/html5/thumbnails/25.jpg)
VOSTEEN Consulting
AGENDA •! SARPI-VEOLIA‘s Hazardous Waste Incineration (HWI) in Europe
•! Developement of the BEMO-Technology with CURRENTA in 2000 - 2009
•! SARPI-Application of the BEMO-Technology at Sedibex since 2016 (3 lines with wet FGD)
•! SARPI-Applications at diverse HWI plants with dry FGD since 2014
•! Experiences with the precipitation agent PRAVO®
•! Influence of Sulfur
•! Outlook
![Page 26: ADVANCES IN BROMINE-BASED MERCURY … · advances in bromine-based mercury emission control at different french waste incineration plants bernhard vosteen vosteen consulting gmbh,](https://reader031.vdocuments.site/reader031/viewer/2022021712/5b9a070b09d3f29c338d6151/html5/thumbnails/26.jpg)
VOSTEEN Consulting
![Page 27: ADVANCES IN BROMINE-BASED MERCURY … · advances in bromine-based mercury emission control at different french waste incineration plants bernhard vosteen vosteen consulting gmbh,](https://reader031.vdocuments.site/reader031/viewer/2022021712/5b9a070b09d3f29c338d6151/html5/thumbnails/27.jpg)
VOSTEEN Consulting
![Page 28: ADVANCES IN BROMINE-BASED MERCURY … · advances in bromine-based mercury emission control at different french waste incineration plants bernhard vosteen vosteen consulting gmbh,](https://reader031.vdocuments.site/reader031/viewer/2022021712/5b9a070b09d3f29c338d6151/html5/thumbnails/28.jpg)
VOSTEEN Consulting
![Page 29: ADVANCES IN BROMINE-BASED MERCURY … · advances in bromine-based mercury emission control at different french waste incineration plants bernhard vosteen vosteen consulting gmbh,](https://reader031.vdocuments.site/reader031/viewer/2022021712/5b9a070b09d3f29c338d6151/html5/thumbnails/29.jpg)
VOSTEEN Consulting
![Page 30: ADVANCES IN BROMINE-BASED MERCURY … · advances in bromine-based mercury emission control at different french waste incineration plants bernhard vosteen vosteen consulting gmbh,](https://reader031.vdocuments.site/reader031/viewer/2022021712/5b9a070b09d3f29c338d6151/html5/thumbnails/30.jpg)
VOSTEEN Consulting
AGENDA •! SARPI-VEOLIA‘s Hazardous Waste Incineration (HWI) in Europe •! Developement of the BEMO-Technology with CURRENTA in 2000 - 2009
•! SARPI-Application of the BEMO-Technology at Sedibex since 2016 (3 lines with wet FGD)
•! SARPI-Applications at diverse HWI plants with dry FGD since 2014
•! Experiences with the precipitation agent PRAVO®
•! Influence of Sulfur
•! Outlook
![Page 31: ADVANCES IN BROMINE-BASED MERCURY … · advances in bromine-based mercury emission control at different french waste incineration plants bernhard vosteen vosteen consulting gmbh,](https://reader031.vdocuments.site/reader031/viewer/2022021712/5b9a070b09d3f29c338d6151/html5/thumbnails/31.jpg)
VOSTEEN Consulting
![Page 32: ADVANCES IN BROMINE-BASED MERCURY … · advances in bromine-based mercury emission control at different french waste incineration plants bernhard vosteen vosteen consulting gmbh,](https://reader031.vdocuments.site/reader031/viewer/2022021712/5b9a070b09d3f29c338d6151/html5/thumbnails/32.jpg)
VOSTEEN Consulting
![Page 33: ADVANCES IN BROMINE-BASED MERCURY … · advances in bromine-based mercury emission control at different french waste incineration plants bernhard vosteen vosteen consulting gmbh,](https://reader031.vdocuments.site/reader031/viewer/2022021712/5b9a070b09d3f29c338d6151/html5/thumbnails/33.jpg)
VOSTEEN Consulting
3
![Page 34: ADVANCES IN BROMINE-BASED MERCURY … · advances in bromine-based mercury emission control at different french waste incineration plants bernhard vosteen vosteen consulting gmbh,](https://reader031.vdocuments.site/reader031/viewer/2022021712/5b9a070b09d3f29c338d6151/html5/thumbnails/34.jpg)
VOSTEEN Consulting
![Page 35: ADVANCES IN BROMINE-BASED MERCURY … · advances in bromine-based mercury emission control at different french waste incineration plants bernhard vosteen vosteen consulting gmbh,](https://reader031.vdocuments.site/reader031/viewer/2022021712/5b9a070b09d3f29c338d6151/html5/thumbnails/35.jpg)
VOSTEEN Consulting
Continuous monitoring of the mercury species
Hg(0), Hg2+ and Hgtot under harsh conditions
in the raw gas upstream of the bagfilter
![Page 36: ADVANCES IN BROMINE-BASED MERCURY … · advances in bromine-based mercury emission control at different french waste incineration plants bernhard vosteen vosteen consulting gmbh,](https://reader031.vdocuments.site/reader031/viewer/2022021712/5b9a070b09d3f29c338d6151/html5/thumbnails/36.jpg)
VOSTEEN Consulting
40
45
50
55
60
65
70
75
80
85
90
95
100
15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95
Hgt
ot
aba
tem
ent e
ffici
ency
(%)
Hg(2+) (%)
AC GL50 : 130 mg/Nm3 db
AC GL50 : 180 mg/Nm3 db
AC GL50 : 250 mg/Nm3 db
The AC GL50 flowrate is also important !
Filter temperature: 210°C
Mercury oxidation already upstream of dry APC improves sorptive Hg removal at normal (undonated) AC towards 100 %. Lowering the filter temperature slightly is advantageous.
![Page 37: ADVANCES IN BROMINE-BASED MERCURY … · advances in bromine-based mercury emission control at different french waste incineration plants bernhard vosteen vosteen consulting gmbh,](https://reader031.vdocuments.site/reader031/viewer/2022021712/5b9a070b09d3f29c338d6151/html5/thumbnails/37.jpg)
VOSTEEN Consulting
0
250
500
750
1000
1250
1500
1750
2000
2250
08:30 08:40 08:50 09:00 09:10 09:20 09:30 09:40 09:50 10:00 10:10 10:20 10:30
Time (2014)
Hg
conc
. ups
tream
APC
(!g/
Nm
3 db)
0
10
20
30
40
50
60
70
80
90
100
Hg
conc
. dow
nstre
am A
PC (!
g/N
m3 d
b)
Hg(0)Hg(2+)HgTHgT (Stack)
HgCl2 1% Hg w. (1500 !g/Nm3 db th.)
CaBr2 52% w. 2*7,5 l/h(Br/Hg = 200)
CaBr2 52% w. 2*12,5 l/h(Br/Hg = 320)
AC GL50 : 250 mg/Nm3 db ; Lime : 110 kg/h
Almost 100% Hg oxidation achieved with mass ratio Br/Hg > 300 Bromide need e.g. only: 3 IBC à 1000 liter CaBr2 (52 %) per year
![Page 38: ADVANCES IN BROMINE-BASED MERCURY … · advances in bromine-based mercury emission control at different french waste incineration plants bernhard vosteen vosteen consulting gmbh,](https://reader031.vdocuments.site/reader031/viewer/2022021712/5b9a070b09d3f29c338d6151/html5/thumbnails/38.jpg)
VOSTEEN Consulting
AGENDA •! SARPI-VEOLIA‘s Hazardous Waste Incineration (HWI) in Europe
•! Developement of the BEMO-Technology with CURRENTA in 2000 - 2009
•! SARPI-Application of the BEMO-Technology at Sedibex since 2016 (3 lines with wet FGD)
•! SARPI-Applications at diverse HWI plants with dry FGD since 2014
•! Experiences with the precipitation agent PRAVO®
•! Influence of Sulfur
•! Outlook
![Page 39: ADVANCES IN BROMINE-BASED MERCURY … · advances in bromine-based mercury emission control at different french waste incineration plants bernhard vosteen vosteen consulting gmbh,](https://reader031.vdocuments.site/reader031/viewer/2022021712/5b9a070b09d3f29c338d6151/html5/thumbnails/39.jpg)
VOSTEEN Consulting
The precipitation agents of PAN Chemie Dr. Fülöp and Vosteen Consulting are
Precipan, PRAVO®100, PRAVO®200 These are inorganic liquid agents containing polysulfides and thiosulfate. The highest content of active sulfur has PRAVO®200. For mercury precipitation at wet FGD, only low injection rates are needed (e.g. < 0.5 liter /hour PRAVO® at 60.000 Nm3/h flue gas). An important initial step in such applications is the formation of highly reactive polysulfanes as H-S-S-S-S-H (PRAVO addition to the acidic milieu as performed at MSWI in Darmstadt, 3 lines since 2008); but PRAVO does also work effectively, when added to a basic/neutral scrubber stage (as performed in sewage sludge combustion at WWTP Karlsruhe –Neureuth, 2 lines since 2007/8). References for successful industrial long-time applications at wet FGD :
Municipal Solid Waste Incineration (Darmstadt) Hazardous Waste Incineration (Leverkusen, Fos-Sur-Mer, Sedibex) Sewage Sludge Combustion (Bottrop, Karlsruhe-Neureuth) Thermal Treatment of Contaminated Soils (Moerdijk) Bituminous Coal Combustion (Block 2 in München Unterföhring)
![Page 40: ADVANCES IN BROMINE-BASED MERCURY … · advances in bromine-based mercury emission control at different french waste incineration plants bernhard vosteen vosteen consulting gmbh,](https://reader031.vdocuments.site/reader031/viewer/2022021712/5b9a070b09d3f29c338d6151/html5/thumbnails/40.jpg)
VOSTEEN Consulting
Tests in 2007/8
![Page 41: ADVANCES IN BROMINE-BASED MERCURY … · advances in bromine-based mercury emission control at different french waste incineration plants bernhard vosteen vosteen consulting gmbh,](https://reader031.vdocuments.site/reader031/viewer/2022021712/5b9a070b09d3f29c338d6151/html5/thumbnails/41.jpg)
VOSTEEN Consulting
![Page 42: ADVANCES IN BROMINE-BASED MERCURY … · advances in bromine-based mercury emission control at different french waste incineration plants bernhard vosteen vosteen consulting gmbh,](https://reader031.vdocuments.site/reader031/viewer/2022021712/5b9a070b09d3f29c338d6151/html5/thumbnails/42.jpg)
VOSTEEN Consulting
![Page 43: ADVANCES IN BROMINE-BASED MERCURY … · advances in bromine-based mercury emission control at different french waste incineration plants bernhard vosteen vosteen consulting gmbh,](https://reader031.vdocuments.site/reader031/viewer/2022021712/5b9a070b09d3f29c338d6151/html5/thumbnails/43.jpg)
VOSTEEN Consulting
![Page 44: ADVANCES IN BROMINE-BASED MERCURY … · advances in bromine-based mercury emission control at different french waste incineration plants bernhard vosteen vosteen consulting gmbh,](https://reader031.vdocuments.site/reader031/viewer/2022021712/5b9a070b09d3f29c338d6151/html5/thumbnails/44.jpg)
VOSTEEN Consulting
Regelung der PraVo Dosierung in Abh‰ ngigkeit des Hg-Messwertes nach W‰ scher f̧ r eine Rauchgasmenge von ca. 60.000 m³/h
0,00 g/h
200,00 g/h
400,00 g/h
600,00 g/h
800,00 g/h
1000,00 g/h
1200,00 g/h
1400,00 g/h
1600,00 g/h
1800,00 g/h
2000,00 g/h
0 µg/m³ 5 µg/m³ 10 µg/m³ 15 µg/m³ 20 µg/m³ 25 µg/m³ 30 µg/m³ 35 µg/m³ 40 µg/m³ 45 µg/m³ 50 µg/m³ 55 µg/m³
Messwert Hg nach W‰ scher
Men
ge a
n Pr
avo
Dosing curve of PRAVO®100 as measured at MSWI line to suppress mercury reemissions
Hgtot in clean gas behind scrubber
PR
AVO
®10
0 flo
w ra
te
Testings in 2008 (Dipl.-Ing. Ulrich Mielke)
![Page 45: ADVANCES IN BROMINE-BASED MERCURY … · advances in bromine-based mercury emission control at different french waste incineration plants bernhard vosteen vosteen consulting gmbh,](https://reader031.vdocuments.site/reader031/viewer/2022021712/5b9a070b09d3f29c338d6151/html5/thumbnails/45.jpg)
VOSTEEN Consulting
Testing PRAVO®200 at SWM in 2014
![Page 46: ADVANCES IN BROMINE-BASED MERCURY … · advances in bromine-based mercury emission control at different french waste incineration plants bernhard vosteen vosteen consulting gmbh,](https://reader031.vdocuments.site/reader031/viewer/2022021712/5b9a070b09d3f29c338d6151/html5/thumbnails/46.jpg)
VOSTEEN Consulting
![Page 47: ADVANCES IN BROMINE-BASED MERCURY … · advances in bromine-based mercury emission control at different french waste incineration plants bernhard vosteen vosteen consulting gmbh,](https://reader031.vdocuments.site/reader031/viewer/2022021712/5b9a070b09d3f29c338d6151/html5/thumbnails/47.jpg)
VOSTEEN Consulting
AGENDA •! SARPI-VEOLIA‘s Hazardous Waste Incineration (HWI) in Europe
•! Developement of the BEMO-Technology with CURRENTA in 2000 - 2009
•! SARPI-Application of the BEMO-Technology at Sedibex since 2016 (3 lines with wet FGD)
•! SARPI-Applications at diverse HWI plants with dry FGD since 2014
•! Experiences with the precipitation agent PRAVO®
•! Influence of Sulfur
•! Outlook
![Page 48: ADVANCES IN BROMINE-BASED MERCURY … · advances in bromine-based mercury emission control at different french waste incineration plants bernhard vosteen vosteen consulting gmbh,](https://reader031.vdocuments.site/reader031/viewer/2022021712/5b9a070b09d3f29c338d6151/html5/thumbnails/48.jpg)
VOSTEEN Consulting
SARPI regularly performs 30 d sampling-probes on PCDD/F at all its lines (obligatory in France)
Punctual probes on PBCDD/Fwere performed, as well, confirming the findings of Funcke and Vehlow in the late 1990s.
![Page 49: ADVANCES IN BROMINE-BASED MERCURY … · advances in bromine-based mercury emission control at different french waste incineration plants bernhard vosteen vosteen consulting gmbh,](https://reader031.vdocuments.site/reader031/viewer/2022021712/5b9a070b09d3f29c338d6151/html5/thumbnails/49.jpg)
VOSTEEN Consulting
![Page 50: ADVANCES IN BROMINE-BASED MERCURY … · advances in bromine-based mercury emission control at different french waste incineration plants bernhard vosteen vosteen consulting gmbh,](https://reader031.vdocuments.site/reader031/viewer/2022021712/5b9a070b09d3f29c338d6151/html5/thumbnails/50.jpg)
VOSTEEN Consulting
AGENDA •! SARPI-VEOLIA‘s Hazardous Waste Incineration (HWI) in Europe
•! Developement of the BEMO-Technology with CURRENTA in 2000 - 2009
•! SARPI-Application of the BEMO-Technology at Sedibex since 2016 (3 lines with wet FGD)
•! SARPI-Applications at diverse HWI plants with dry FGD since 2014
•! Experiences with the precipitation agent PRAVO®
•! Influence of Sulfur
•! Outlook
![Page 51: ADVANCES IN BROMINE-BASED MERCURY … · advances in bromine-based mercury emission control at different french waste incineration plants bernhard vosteen vosteen consulting gmbh,](https://reader031.vdocuments.site/reader031/viewer/2022021712/5b9a070b09d3f29c338d6151/html5/thumbnails/51.jpg)
VOSTEEN Consulting
VEOLIA activities global
![Page 52: ADVANCES IN BROMINE-BASED MERCURY … · advances in bromine-based mercury emission control at different french waste incineration plants bernhard vosteen vosteen consulting gmbh,](https://reader031.vdocuments.site/reader031/viewer/2022021712/5b9a070b09d3f29c338d6151/html5/thumbnails/52.jpg)
VOSTEEN Consulting
SARPI will perform tests of the BEMO-Technology at Veolia’s MSWI sites starting in October 2017
![Page 53: ADVANCES IN BROMINE-BASED MERCURY … · advances in bromine-based mercury emission control at different french waste incineration plants bernhard vosteen vosteen consulting gmbh,](https://reader031.vdocuments.site/reader031/viewer/2022021712/5b9a070b09d3f29c338d6151/html5/thumbnails/53.jpg)
VOSTEEN Consulting
Prof. Bernhard Vosteen and Ric Ulrich, PE, presenting the VOSTEEN-Technology („BEMO“) at the VEOLIA Hazardous Waste Incineration site in Port Arthur, near Houston, TX (USA) - already in 2006, i.e. more than 10 years ago.