2013.3.26

1

CHCCHClCH3

C.A.B.D.

-CH=CH2B1:?

765954513.7011600032011

,,()COH2O4

1,3-

1

(1)__________ a b c d

C7H10ab1

_________ C14H10(3)

__________(2)__________

1,3-

CnH2n+2n1CnH2nn3CnH2nn2CnH2n-2n3CnH2n-2n2CnH2n-6n62C3H8C4H10 C3H6C4H8 C4H6C5H8 C6H6C7H8 CnH2n-61 3

2422664CH3CH=CHCH2CH31 3 652 4

2422665CH3CCCH2CH31 2 3 6444 4

2422661 A. B. C. D. CD

24226610928120 180 120 14C-C()C=CCC 1.541.341.201.3910-10m/KJ/mol2 347612838C-C()C=CCC

13-

KMnO4X2H2HXH2O

KMnO4

12-14

KMnO4KMnO4H260TNT182- (1)KMnO4( )(2) (3)

1KMnO4 A B1- C1- DCKMnO4 ABCDAA ABBCC3182- (1)KMnO4( )(2) (3)

1KMnO4 A B1- C1- DC2 ACCl4 B. C. D.KMnO4B1 2

4121PVC23311.6 2 P38-41