document no.: pfgrtl4190716 epa licence no.: p0652-01 visit … · 2017. 2. 7. · epa licence...

Document No.: PFGRTL4190716 EPA Licence No.: P0652-01 Visit No: 4 Licence Holder: Pfizer Ireland Pharmaceuticals Year: 2016 Facility Location: Clondalkin, Co. Dublin Office: Limerick Version No: 1

1 of 33

Report Title Air Emissions Compliance Monitoring Emissions Report

Company address Air Scientific Ltd., Unit 5, Caherdavin Business Centre,

Caherdavin, Park, Ennis Road, Limerick V94 NT63.

Stack Emissions Testing Report Commissioned by Pfizer Ireland Pharmaceuticals

Facility Name The Pfizer Biotech Campus at Grange Castle

Contact Person Gerard Shannon

EPA Licence Number P0652-01

Licence Holder Pfizer Ireland Pharmaceuticals

Stack Reference Number A1-1, A1-2 & A1-3

Dates of the Monitoring Campaign 19-07-2016

Job Reference Number PFGRTL4190716

Report Written By Gregory Dempsey

Report Approved by Mr. Mark McGarry

Stack Testing Team Mr. David Noonan

Report Date 09-08-2016

Report Type Test Report Compliance Monitoring

Version 1

Signature of Approver Operations Manager

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 07-02-2017:02:12:38


2 of 33

Opinions and interpretations expresses herein will be outside the scope of Air Scientific Limited INAB accreditation. This test report shall not be reproduced, without the written approval of Air Scientific Limited.

All sampling and reporting is completed in accordance with Environmental Protection Agency Air Guidance Note 2 requirements.

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 07-02-2017:02:12:38


3 of 33

Executive Summary

Monitoring Objectives

Overall Aim of the monitoring Campaign

The aim of the monitoring campaign was to demonstrate compliance with a set of emission limit values as specified in the site licence.

Special Requirements There were no special requirements.

Target Parameters

Total Particulate Matter (TPM)

Oxides of Nitrogen (NOx) as NO2

Sulphur Dioxide (SO2)

Volumetric Flow Rates (m3.hr-1)

Emission Limit Values

A1-1 mg.m-3

TPM 5

NOx as NO2 75

SO2 35

Volume (m3.hr-1) 13,755

Reference Conditions

Reference Conditions Value

Oxygen Reference % 3

Temperature K 273.15

Total Pressure kPa 101.3

Moisture % Dry


A1-2 mg.m-3

TPM 5

NOx as NO2 75

SO2 35

Volume (m3.hr-1) 13,755






Moisture % Dry

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 07-02-2017:02:12:38


4 of 33


A1-3 mg.m-3

TPM 5

NOx as NO2 75

SO2 35

Volume (m3.hr-1) 13,755






Moisture % Dry

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 07-02-2017:02:12:38


5 of 33

Executive Summary

Overall Results

A1-1 Concentration

Parameter Units Result MU +/- Limit Compliant

Total Particulate Matter (TPM) mg.m-3 <0.96 0.51 5 Yes

Oxides of Nitrogen (NOx) as NO2 mg.m-3 32.6 3.3 75 Yes

Sulphur Dioxide (SO2) mg.m-3 <6.1 9.2 35 Yes

Volumetric Flow Rate (Ref.) m3.hr-1 6,526 0.64m.s-1 13,755 Yes

A1-2 Concentration






A1-3 Concentration






Blank for 19-07-16 Concentration

Parameter Units Result ELV <10% of ELV

Compliant

Total Particulate Matter (TPM) mg.m-3 <0.56 5 No*

*Note: Blank >10% of ELV due to extremely low Emission Limit. No dust was detected on the blank sample.

Accreditation details

Air Scientific Limited INAB Number: 319T

External Analytical Laboratory Accreditation number: UKAS 1549

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 07-02-2017:02:12:38


6 of 33

Executive Summary

Process details

Stack Name A1-1

Process status Normal

Capacity (per/hour) (if applicable) Variable

Continuous or Batch Process Continuous

Feedstock N/a

Abatement System No

Abatement Systems Running Status N/a

Fuel Natural Gas

Plume Appearance No

Other information N/a

Stack Name A1-2




Feedstock N/a

Abatement System No


Fuel Natural Gas

Plume Appearance No


Stack Name A1-3




Feedstock N/a

Abatement System No


Fuel Natural Gas

Plume Appearance No


For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 07-02-2017:02:12:38


7 of 33

Executive Summary

Monitoring, Equipment & Analytical Methods

Parameter Standard Technical Procedure

Accredited Testing

Analytical Technique

Equipment / Media

Equipment ID Used on Site

Total Particulate Matter (TPM)

EN13284 -1:2002

2000 Yes Gravimetric Isokinetic

Equipment

ASLLK12EQ525 ASLLK12EQ527 ASLLK13EQ503 ASLLK13EQ504 ASLLK13EQ506 ASLLK13EQ508 ASLLK14EQ503 ASLLK14EQ510 ASLLK14EQ513 ASLLK16EQ503

Oxides of Nitrogen (NOx) as NO2

EN14792:2006 2002 Yes Chemiluminescence Horiba

Sulphur Dioxide (SO2)

NDIR AG2 2003 Yes Non Dispersive

Infra Red Horiba

Oxygen (%) EN14789 2008 Yes Paramagnetic/

Zirconia Horiba

Stack Gas Temperature

EN 16911:2013 2005 Yes Thermocouple Thermocouple

Stack Gas Velocity

EN 16911:2013 2005 Yes Pitot tubes Meter / Pitot

Volumetric Flow Rate

EN 16911:2013 2005 Yes Manometer / Pitot /

Calculation

Manometer / Pitot /

Calculation

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 07-02-2017:02:12:38


8 of 33

Sampling Deviations

Parameter: A1-1 Deviation

EN13284 -1:2002 One port available.

EN14792:2006 None

NDIR AG2 Uncertainty >10% due to low concentrations in the

gas and low ELV

EN14789 None

EN 16911:2013 One port available. Flow Rates - in accordance

with MID 6911-1


EN13284 -1:2002 One port available. Differential Pressure <5Pa.

Ratio of flow >3:1. Constant flow used.

EN14792:2006 None


gas and low ELV

EN14789 None

EN 16911:2013

One port available. Differential Pressure <5Pa. Ratio of flow >3:1.Flow uncertainty >10%.Flow. Constant Flow used. Rates - in accordance with

MID 6911-1


EN13284 -1:2002 One port available.

EN14792:2006 None


gas and low ELV

EN14789 None

EN 16911:2013 One port available. Flow Uncertainty >10%. Flow

Rates - in accordance with MID 6911-1

Reference Documents

Risk Assessment (RA) SOP 1011

Site Review (SR) SOP 1015

Site Specific Protocol (SSP) SOP 1015

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 07-02-2017:02:12:38


9 of 33

Suitability of Sample Location

General Information A1-1

Permanent/Temporary Permanent

Inside/ Outside Inside

Platform Details

Irish EPA Technical Guidance Note AG1 / BS EN 15259 Platform Requirements

Value Comment

Sufficient Working area to manipulate probe and measuring instruments

Yes -

Platform has 2 handrails (approx. 0.5m & 1.0 m high) Yes -

Platform has vertical base boards (approx. 0.25 m high) Yes -

Platform has chains / self-closing gates at top of ladders Yes -

There are no obstructions present which hamper insertion of sampling equipment

Yes -

Safe Access Available Yes -

Easy Access Available Yes -

Sampling Location / Platform Improvement Recommendations

None

BSEN 15259 Homogeneity Test Requirements

1.

Select Option : 1: There is no requirement to perform a BSEN15259 Homogeneity Test on this stack 2: Test results were obtained from previous Homogeneity test carried out by ASL 3: Test results were obtained from previous Homogeneity test carried out by Alternative contractor 4: Homogeneity Test is required on this stack and the client has been informed of this requirement.

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 07-02-2017:02:12:38


10 of 33





Platform Details


Value Comment


Yes -





Yes -




None


1.


For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 07-02-2017:02:12:38


11 of 33





Platform Details


Value Comment


Yes -





Yes -




None


1.


For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 07-02-2017:02:12:38


12 of 33

Stack Diagram

No cameras allowed on site

c. 10 m

Ports 1

c. 4 metres

Ground Level

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 07-02-2017:02:12:38


13 of 33

Stack Name

Example Note: Platform located on second platform 2 Ports 2 Lines 4 points per line

Port

Port

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 07-02-2017:02:12:38


14 of 33

1. APPENDICES

Appendix I Monitoring Personnel & Equipment

Stack Emissions Monitoring Personnel

Team Leader Name David Noonan

System approval ASL Team Leader Approved

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 07-02-2017:02:12:38


15 of 33

Appendix II Stack Raw Data

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 07-02-2017:02:12:38


16 of 33

Title: Determination of Total Particulates Method: EN 13284-1

Test Date: 19/07/2016 Uncertainty Data Laboratory Used: SAL

Certificate Numbers: 588644-1 Temperature at Pump 24.554 Deg C

Stack Name A1-1 Pressure at Pump 76.499 kPa

Test Time 12:21:03

Air Volume at Pump 0.9494 m3

Moisture Content 11.44 % Humidity at Pumps 0 %

Reference Oxygen 3 % Filter Weight 0.3 mg

Measured Oxygen 3.9 % Front End Weight 0.3 mg

Stack Flow Rate 7759 Nm3/hr Adjusted Stack Flow Rate 6526 Nm3/hr, dry @ % Oxygen

Volume of Air Sampled 0.6579 Nm3

Balance Calibration Weight 500.0 500.0 g

1000.0 1000.0 g

Impinger Weights Initial Final Difference 1 470.2 506.6 36.4 2 461 471 10 3 365 369.3 4.3 4 613.9 631.5 17.6 Volume of Air Sampled 0.6579 Nm3 68.3 Moisture Content (EN 14790) 11.44 %

Leak Check Results Result

% Leak

Before Blank 0 l/min 0.0 After Blank 0 l/min 0.0 Before Sample 1 0 l/min 0.0 After Sample 1 0 l/min 0.0 Average Flow Rate 21.785 l/min 0.0 Standard Maximum 0.4357 l/min 2% Back Pressure 69 kPa

Standard Criteria to be Met Result Standard Requirement

Angle of Flow Pass <15 Degrees Negative Flow in the Stack Pass None Pitot Pressure Difference Pass >5Pa Ratio of Flow Measurement Pass <3:1 Stagnation Test Pass <10Pa Pitot Tube Leak Check Result

Positive Pressure Pass - Negative Pressure Pass - Number of Ports 1 2 Straight length before sample point Pass > 5 Hydraulic Diameters

Straight length after sample point Pass > 5 Hydraulic Diameters

Sample Calculations Blank (Filter and Front Wash Combined) 0.35 mg

Sample 1 (Filter and Front Combined) 0.6 mg Volume of Air Sampled 0.6579 Nm3 Blank Result 0.53 mg/Nm3, dry 0.56 mg/Nm3, dry @ Ref O2

Sample Result 0.91 mg/Nm3, dry 0.96 mg/Nm3, dry @ Ref O2

Uncertainty of Measurement 0.51 mg/Nm3 Emission Limit Value 5 mg/Nm3, dry @ Ref O2

Blank as Percentage of ELV 11.2 % Standard Requirement <10% ELV

Isokinetic Criterion Compliance Isokinetic Variation % 0

Allowable Isokinetic Range % From - 5 to + 15 Isokinetic Acceptable - Yes

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 07-02-2017:02:12:38


17 of 33

DUCT AND GAS SPECIFICATION Name

PFIZER.A1.1

Section

Circular

Diameter

[m] 1.035

Area

[m2] 0.841

Port B [#] 1

Points P [#] 8

Density ρn [kg/m3] 1.317

Carbon dioxide CO2 [%] 8.6

Oxygen O2 [%] 3.7

Water vapor ratio rw [0;1] 0.08

Nozzle nz [mm] 14

Turbolence factor ft [sec] 9

DUCT FLOW RATE Dry actual QVa [m3/h] 10497

Moist actual Q'Va [m3/h] 11412

Moist standard [Tnorm Pnorm] Q'Vn [m3/h] 7759

Dry standard [Tnorm Pnorm] QVn [m3/h] 7138

AVERAGE VALUES Total Points

[#] 1

Velocity v'a [m/sec] 3.768

Stack temperature ta [°C] 124.071

Stack Static Pressure Pastatic [kPa] 100.178

Isokinetic Deviation DI [%] 0

Velocity at nozzle v'N [m/sec] 3.77

Probe temperature tprobe [°C] 25.689

Box temperature tbox [°C] 25.983

Aux1 temperature taux1 [°C] 35.862

Aux2 temperature taux2 [°C] 24.87

Stack Differential Pitot Pressure dPpitot [Pa] 8.318

Ambient Pressure Pamb [kPa] 100.271

SAMPLED VOLUMES Elapsed time et [hh:mm:ss] 00:30:00

Total encoder impulses

[#] 18988

Standard Volume [Tnorm Pnorm] Vgn [m3] 0.6579

Moist Volume at stack conditions V'ga [m3] 0.7912

Volume at dgm conditions Vdgm [m3] 0.9494

Gas meter temperature tgm [°C] 24.554

Gas Meter Pressure Pdgm [kPa] 76.499

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 07-02-2017:02:12:38


18 of 33

start ts Port Point Distance Elapsed

Time rw avg tfumes avg Pa avg

dP pitot avg

[timestamp] [###] [###] [cm] [hh:mm:ss] [0;1] [°C] [kPa] [Pa]

19/07/2016 1 1 3.4 00:01:00 0.08 125.159 100.197 11.053 12:06:21

19/07/2016 1 2 10.9 00:01:00 0.08 123.005 100.193 10.732 12:07:22

19/07/2016 1 3 20.1 00:01:00 0.08 125.651 100.198 11.248 12:08:30

19/07/2016 1 4 33.5 00:01:00 0.08 128.033 100.202 12.769 12:09:31

19/07/2016 1 5 70.1 00:01:00 0.08 128.877 100.195 13.293 12:10:32

19/07/2016 1 6 83.5 00:01:00 0.08 129.542 100.19 12.72 12:11:32

19/07/2016 1 7 92.7 00:01:00 0.08 129.578 100.181 10.742 12:12:35

19/07/2016 1 8 100.2 00:01:00 0.08 128.828 100.185 9.621 12:13:41

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 07-02-2017:02:12:38


19 of 33

Title: Determination of Combustion Flue Gases Method: EN 14792 / EN 14789 / EN 12039 / TGN M21 Test Date: 19/07/2016

Stack Name A1-1

Reference Conditions Measured Oxygen 3.9 %

Reference Oxygen 3 %

Parameter

NO SO2 O2 Emission Limit Values mg.m-3 ref

75 35

Instrument Range ppm

500 1000 25 Span Gas Value ppm

305 630 20.9

Acceptable Gas Range -

Yes Yes Yes Calibration Gas Uncertainty %

0.6 0.8 0.5

Quality Assurance Units Conditioning Unit Temperature C

2 2 2 Average Temperature < C

2 2 2

Allowable Temperature -

4 4 4 Temperature Acceptable -

Yes Yes Yes

Pump flow rate l/min.

0.5 0.5 0.5

Zero Drift Units Zero (Pre) ppm

0 -1 0 Zero (Post) ppm

-0.5 -3 0

Zero drift ppm

-0.5 -2 0 Allowable Zero Drift (Less than) ppm

6.1 12.6 0.418

Adjustable Zero Drift (Less than) ppm

15.25 31.5 1.045 Zero Drift Failure (Greater than) ppm

15.25 31.5 1.045

Zero Drift Acceptable -

Yes Yes Yes

Span Drift Units Span Down (Pre) ppm

304 628 20.9 Span Down (Post) ppm

303 625 20.8

Span Drift ppm

-1 -3 -0.1 Allowable Span Drift (less than) ppm

6.1 12.6 0.418

Adjustable Span Drift (Less than) ppm

15.25 31.5 1.045 Span Drift Failure (Greater than) ppm

15.25 31.5 1.045

Span Drift Acceptable (Y/N) -

Yes Yes Yes

Leak Check Span Gas Conc. ppm

305 630 20.9

Recorded Conc. down Line ppm

304 628 20.9 Leak Detected ppm

-1 -2 0

Leak check acceptable (< 2%) ppm

6.1 12.6 0.418 Pass (Y/N)

Yes Yes Yes

Test Conditions Units Run Ambient Temperature Range C

25.6 25.6 25.6

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 07-02-2017:02:12:38


20 of 33

Raw Data

Date/Time Data source

NOx O2 SO2

ppm vol% ppm

19/07/2016 11:09

14.9 5.3 <6.1 19/07/2016 11:10

15.7 4.1 <6.1 19/07/2016 11:11

15.6 3.6 <6.1 19/07/2016 11:12

15.8 3.1 <6.1 19/07/2016 11:13

15.6 2.9 <6.1 19/07/2016 11:14

15.5 3.1 <6.1 19/07/2016 11:15

15.2 3.4 <6.1 19/07/2016 11:16

15.6 2.7 <6.1 19/07/2016 11:17

15.6 2.6 <6.1 19/07/2016 11:18

16.2 2.6 <6.1 19/07/2016 11:19

16.3 2.7 <6.1 19/07/2016 11:20

15.3 3.5 <6.1 19/07/2016 11:21

14.7 4.2 <6.1 19/07/2016 11:22

14.2 4.8 <6.1 19/07/2016 11:23

14.3 4.8 <6.1 19/07/2016 11:24

14.6 4.8 <6.1 19/07/2016 11:25

14.5 5.0 <6.1 19/07/2016 11:26

14.5 4.9 <6.1 19/07/2016 11:27

14.5 4.5 <6.1 19/07/2016 11:28

14.4 4.5 <6.1 19/07/2016 11:29

14.8 4.0 <6.1 19/07/2016 11:30

14.8 3.9 <6.1 19/07/2016 11:31

14.6 4.4 <6.1 19/07/2016 11:32

14.5 4.1 <6.1 19/07/2016 11:33

14.7 4.3 <6.1 19/07/2016 11:34

14.6 4.3 <6.1 19/07/2016 11:35

14.6 4.2 <6.1 19/07/2016 11:36

15.1 3.8 <6.1 19/07/2016 11:37

15.0 3.9 <6.1 19/07/2016 11:38

15.5 3.9 <6.1

Average

15.0 3.9 <6.1

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 07-02-2017:02:12:38


21 of 33

Referenced Data

NOx SO2

mg/Nm3 Reference O2

19/07/2016 11:09

35.1 <6.1 19/07/2016 11:10

34.3 <6.1

19/07/2016 11:11

33.1 <6.1 19/07/2016 11:12

32.5 <6.1

19/07/2016 11:13

31.9 <6.1 19/07/2016 11:14

32.1 <6.1

19/07/2016 11:15

31.9 <6.1 19/07/2016 11:16

31.5 <6.1

19/07/2016 11:17

31.2 <6.1 19/07/2016 11:18

32.5 <6.1

19/07/2016 11:19

33.0 <6.1 19/07/2016 11:20

32.2 <6.1

19/07/2016 11:21

32.2 <6.1 19/07/2016 11:22

32.5 <6.1

19/07/2016 11:23

32.5 <6.1 19/07/2016 11:24

33.4 <6.1

19/07/2016 11:25

33.5 <6.1 19/07/2016 11:26

33.3 <6.1

19/07/2016 11:27

32.4 <6.1 19/07/2016 11:28

32.2 <6.1

19/07/2016 11:29

32.1 <6.1 19/07/2016 11:30

31.9 <6.1

19/07/2016 11:31

32.5 <6.1 19/07/2016 11:32

31.8 <6.1

19/07/2016 11:33

32.3 <6.1 19/07/2016 11:34

32.3 <6.1

19/07/2016 11:35

32.3 <6.1 19/07/2016 11:36

32.4 <6.1

19/07/2016 11:37

32.4 <6.1 19/07/2016 11:38

33.4 <6.1

Average

32.6 <6.1 Uncertainty of Measurement

3.3 9.2

Uncertainty as % of ELV

4.35 26.33 Standard Requirement

<10% <10%

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 07-02-2017:02:12:38


22 of 33





Test Time 13:21:36



Reference Oxygen 3 % Filter Weight 1 mg





1000.0 1000.0 g

Impinger Weights Initial Final Difference 1 506.6 542.7 36.1 2 471 478.2 7.2 3 369.3 372.5 3.2 4 631.5 644.4 12.9 Volume of Air Sampled 0.5690 Nm3 59.4 Moisture Content (EN 14790) 11.50 %


% Leak

Before Blank 0 l/min 0.0 After Blank 0 l/min 0.0 Before Sample 1 0.2 l/min 1.1 After Sample 1 0.2 l/min 1.1 Average Flow Rate 18.887 l/min 1.1 Standard Maximum 0.37774 l/min 2% Back Pressure 69 kPa


Angle of Flow Pass <15 Degrees Negative Flow in the Stack Pass None Pitot Pressure Difference No >5Pa Ratio of Flow Measurement No <3:1 Stagnation Test Pass <10Pa Pitot Tube Leak Check Result








Isokinetic Criterion Compliance Isokinetic Variation % -8.4


For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 07-02-2017:02:12:38


23 of 33


PFIZER.A1.2 Section

Circular Diameter

[m] 1.035

Area

[m2] 0.841 Port B [#] 1 Points P [#] 8 Density ρn [kg/m

3] 1.313 Carbon dioxide CO2 [%] 7.6 Oxygen O2 [%] 5.5 Water vapor ratio rw [0;1] 0.08 Nozzle nz [mm] 14 Turbolence factor ft [sec] 9


Moist actual Q'Va [m3/h] 10740 Moist standard [Tnorm Pnorm] Q'Vn [m3/h] 7352 Dry standard [Tnorm Pnorm] QVn [m3/h] 6763


[#] 1 Velocity v'a [m/sec] 3.546 Stack temperature ta [°C] 121.203 Stack Static Pressure Pastatic [kPa] 100.13 Isokinetic Deviation DI [%] -8.4 Velocity at nozzle v'N [m/sec] 3.247 Flowrate Deviation DF [%] -0.4 Probe temperature tprobe [°C] 26.866 Box temperature tbox [°C] 26.924 Aux1 temperature taux1 [°C] 36.468 Aux2 temperature taux2 [°C] 25.759 Stack Differential Pitot Pressure dPpitot [Pa] 7.421 Ambient Pressure Pamb [kPa] 100.241



[#] 15750 Standard Volume [Tnorm Pnorm] Vgn [m3] 0.569 Moist Volume at stack conditions V'ga [m3] 0.6873 Volume at dgm conditions Vdgm [m3] 0.7875 Gas meter temperature tgm [°C] 25.987 Gas Meter Pressure Pdgm [kPa] 80.162

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 07-02-2017:02:12:38


24 of 33



dP pitot avg


19/07/2016 1 1 3.4 00:01:00 0.08 122.87 100.165 7.222 13:10:35

19/07/2016 1 2 10.9 00:01:01 0.08 123.657 100.165 5.221 13:11:39

19/07/2016 1 3 20.1 00:01:00 0.08 122.782 100.163 2.644 13:12:41

19/07/2016 1 4 33.5 00:01:00 0.08 121.2 100.147 2.598 13:13:43

19/07/2016 1 5 70.1 00:01:00 0.08 120.115 100.166 3.165 13:14:44

19/07/2016 1 6 83.5 00:01:00 0.08 119.495 100.158 2.067 13:15:45

19/07/2016 1 7 92.7 00:01:00 0.08 118.102 100.156 2.537 13:16:47

19/07/2016 1 8 100.2 00:01:00 0.08 117.578 100.149 2.625 13:17:51

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 07-02-2017:02:12:38


25 of 33


Stack Name A1-2



Parameter


75 35



305 630 20.9



0.6 0.8 0.5



2 2 2



Yes Yes Yes


0.5 0.5 0.5



-0.5 -2 0

Zero drift ppm

-0.5 -1 0 Allowable Zero Drift (Less than) ppm

6.1 12.6 0.418



15.25 31.5 1.045


Yes Yes Yes



304 626 20.9

Span Drift ppm

-1 -2 0 Allowable Span Drift (less than) ppm

6.1 12.6 0.418



15.25 31.5 1.045


Yes Yes Yes


305 630 20.9



0 -2 0


6.1 12.6 0.418 Pass (Y/N)

Yes Yes Yes


25.6 25.6 25.6

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 07-02-2017:02:12:38


26 of 33

Raw Data


NOx O2 SO2

ppm vol% ppm

19/07/2016 12:00

23.5 5.4 <6.1 19/07/2016 12:01

23.7 5.2 <6.1 19/07/2016 12:02

23.6 5.1 <6.1 19/07/2016 12:03

23.6 5.1 <6.1 19/07/2016 12:04

23.9 5.1 <6.1 19/07/2016 12:05

24.9 5.2 <6.1 19/07/2016 12:06

25.4 5.2 <6.1 19/07/2016 12:07

26.4 5.0 <6.1 19/07/2016 12:08

26.6 5.1 <6.1 19/07/2016 12:09

26.6 5.3 <6.1 19/07/2016 12:10

26.7 5.4 <6.1 19/07/2016 12:11

26.9 5.4 <6.1 19/07/2016 12:12

26.0 5.4 <6.1 19/07/2016 12:13

26.1 5.3 <6.1 19/07/2016 12:14

25.9 5.4 <6.1 19/07/2016 12:15

26.0 5.5 <6.1 19/07/2016 12:16

25.7 5.3 <6.1 19/07/2016 12:17

25.9 5.1 <6.1 19/07/2016 12:18

24.3 4.8 <6.1 19/07/2016 12:19

23.3 5.1 <6.1 19/07/2016 12:20

19.7 5.6 <6.1 19/07/2016 12:21

19.7 5.4 <6.1 19/07/2016 12:22

19.7 5.4 <6.1 19/07/2016 12:23

19.8 5.4 <6.1 19/07/2016 12:24

20.1 5.4 <6.1 19/07/2016 12:25

20.2 5.4 <6.1 19/07/2016 12:26

20.3 5.4 <6.1 19/07/2016 12:27

20.1 5.4 <6.1 19/07/2016 12:28

21.1 5.2 <6.1 19/07/2016 12:29

23.4 5.0 <6.1

Average

23.6 5.3 <6.1

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 07-02-2017:02:12:38


27 of 33

Referenced Data

NOx SO2

mg/Nm3 Reference O2

19/07/2016 12:00

55.5 <6.1 19/07/2016 12:01

55.5 <6.1

19/07/2016 12:02

55.1 <6.1 19/07/2016 12:03

55.0 <6.1

19/07/2016 12:04

55.4 <6.1 19/07/2016 12:05

58.1 <6.1

19/07/2016 12:06

59.4 <6.1 19/07/2016 12:07

60.9 <6.1

19/07/2016 12:08

62.1 <6.1 19/07/2016 12:09

62.9 <6.1

19/07/2016 12:10

63.1 <6.1 19/07/2016 12:11

63.8 <6.1

19/07/2016 12:12

61.7 <6.1 19/07/2016 12:13

61.4 <6.1

19/07/2016 12:14

61.4 <6.1 19/07/2016 12:15

61.9 <6.1

19/07/2016 12:16

60.3 <6.1 19/07/2016 12:17

60.2 <6.1

19/07/2016 12:18

55.4 <6.1 19/07/2016 12:19

54.2 <6.1

19/07/2016 12:20

47.2 <6.1 19/07/2016 12:21

46.6 <6.1

19/07/2016 12:22

46.7 <6.1 19/07/2016 12:23

46.8 <6.1

19/07/2016 12:24

47.6 <6.1 19/07/2016 12:25

47.9 <6.1

19/07/2016 12:26

47.9 <6.1 19/07/2016 12:27

47.6 <6.1

19/07/2016 12:28

49.4 <6.1 19/07/2016 12:29

54.0 <6.1

Average


4.8 7.6



<10% <10%

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 07-02-2017:02:12:38


28 of 33





Test Time 14:24:23



Reference Oxygen 3 % Filter Weight 0.05 mg





1000.0 1000.0 g

Impinger Weights Initial Final Difference 1 542.7 589.4 46.7 2 478.2 486.3 8.1 3 372.5 378.3 5.8 4 644.4 656.3 11.9 Volume of Air Sampled 0.6821 Nm3 72.5 Moisture Content (EN 14790) 11.68 %


% Leak

Before Blank 0 l/min 0.0 After Blank 0 l/min 0.0 Before Sample 1 0 l/min 0.0 After Sample 1 0 l/min 0.0 Average Flow Rate 22.602 l/min 0.0 Standard Maximum 0.45204 l/min 2% Back Pressure 69 kPa


Angle of Flow Pass <15 Degrees Negative Flow in the Stack Pass None Pitot Pressure Difference Pass >5Pa Ratio of Flow Measurement Pass <3:1 Stagnation Test Pass <10Pa Pitot Tube Leak Check Result








Isokinetic Criterion Compliance Isokinetic Variation % -0.3


For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 07-02-2017:02:12:38


29 of 33


PFIZER.A1.3 Section

Circular Diameter

[m] 1.035

Area

[m2] 0.841 Port B [#] 1 Points P [#] 8 Density ρn [kg/m

3] 1.317 Carbon dioxide CO2 [%] 8.5 Oxygen O2 [%] 4.2 Water vapor ratio rw [0;1] 0.08 Nozzle nz [mm] 14 Turbolence factor ft [sec] 9


Moist actual Q'Va [m3/h] 11866 Moist standard [Tnorm Pnorm] Q'Vn [m3/h] 8081 Dry standard [Tnorm Pnorm] QVn [m3/h] 7434


[#] 1 Velocity v'a [m/sec] 3.918 Stack temperature ta [°C] 122.928 Stack Static Pressure Pastatic [kPa] 100.045 Isokinetic Deviation DI [%] -0.3 Velocity at nozzle v'N [m/sec] 3.906 Probe temperature tprobe [°C] 27.599 Box temperature tbox [°C] 27.69 Aux1 temperature taux1 [°C] 37.345 Aux2 temperature taux2 [°C] 26.808 Stack Differential Pitot Pressure dPpitot [Pa] 8.997 Ambient Pressure Pamb [kPa] 100.161



[#] 20204 Standard Volume [Tnorm Pnorm] Vgn [m3] 0.6821 Moist Volume at stack conditions V'ga [m3] 0.8266 Volume at dgm conditions Vdgm [m3] 1.0102 Gas meter temperature tgm [°C] 26.666 Gas Meter Pressure Pdgm [kPa] 75.064

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 07-02-2017:02:12:38


30 of 33



dP pitot avg


19/07/2016 1 1 3.4 00:01:00 0.08 125.105 100.091 11.271 14:13:09

19/07/2016 1 2 10.9 00:01:00 0.08 125.467 100.073 11.275 14:14:13

19/07/2016 1 3 20.1 00:01:00 0.08 125.831 100.077 10.489 14:15:14

19/07/2016 1 4 33.5 00:01:00 0.08 125.71 100.085 9.882 14:16:16

19/07/2016 1 5 70.1 00:01:00 0.08 125.375 100.072 8.36 14:17:34

19/07/2016 1 6 83.5 00:01:00 0.08 125.166 100.066 8.586 14:18:36

19/07/2016 1 7 92.7 00:01:00 0.08 124.979 100.068 8.719 14:19:39

19/07/2016 1 8 100.2 00:01:00 0.08 124.642 100.062 7.641 14:20:41

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 07-02-2017:02:12:38


31 of 33


Stack Name A1-3



Parameter


75 35



305 630 20.9



0.6 0.8 0.5



2 2 2



Yes Yes Yes


0.4 0.4 0.4



-1 -4 0

Zero drift ppm

-1 -2 0 Allowable Zero Drift (Less than) ppm

6.1 12.6 0.418



15.25 31.5 1.045


Yes Yes Yes



302 624 20.8

Span Drift ppm

-2 -3 0 Allowable Span Drift (less than) ppm

6.1 12.6 0.418



15.25 31.5 1.045


Yes Yes Yes


305 630 20.9



-1 -3 -0.1


6.1 12.6 0.418 Pass (Y/N)

Yes Yes Yes


25.6 25.6 25.6

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 07-02-2017:02:12:38


32 of 33

Raw Data


NOx O2 SO2

ppm vol% ppm

19/07/2016 12:43

20.3 4.6 <6.1

19/07/2016 12:44

20.6 4.7 <6.1

19/07/2016 12:45

20.9 4.5 <6.1

19/07/2016 12:46

20.7 4.4 <6.1

19/07/2016 12:47

20.7 4.2 <6.1

19/07/2016 12:48

21.3 4.4 <6.1

19/07/2016 12:49

20.7 4.5 <6.1

19/07/2016 12:50

20.4 4.3 <6.1

19/07/2016 12:51

20.6 4.1 <6.1

19/07/2016 12:52

20.4 4.3 <6.1

19/07/2016 12:53

20.7 4.2 <6.1

19/07/2016 12:54

20.3 4.5 <6.1

19/07/2016 12:55

20.3 4.4 <6.1

19/07/2016 12:56

20.5 4.3 <6.1

19/07/2016 12:57

20.2 4.2 <6.1

19/07/2016 12:58

20.3 4.2 <6.1

19/07/2016 12:59

20.6 4.3 <6.1

19/07/2016 13:00

20.1 4.3 <6.1

19/07/2016 13:01

20.2 4.3 <6.1

19/07/2016 13:02

19.9 4.5 <6.1

19/07/2016 13:03

19.8 4.7 <6.1

19/07/2016 13:04

20.2 4.3 <6.1

19/07/2016 13:05

20.3 4.2 <6.1

19/07/2016 13:06

20.0 4.4 <6.1

19/07/2016 13:07

19.3 4.4 <6.1

19/07/2016 13:08

19.9 4.4 <6.1

19/07/2016 13:09

20.4 4.4 <6.1

19/07/2016 13:10

20.2 4.4 <6.1

19/07/2016 13:11

20.4 4.3 <6.1

19/07/2016 13:12

20.1 4.4 <6.1

Average

20.3 4.4 <6.1

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 07-02-2017:02:12:38


33 of 33

Referenced Data

NOx SO2

mg/Nm3 Reference O2

19/07/2016 12:43

45.9 <6.1 19/07/2016 12:44

46.7 <6.1

19/07/2016 12:45

46.8 <6.1 19/07/2016 12:46

45.9 <6.1

19/07/2016 12:47

45.7 <6.1 19/07/2016 12:48

47.5 <6.1

19/07/2016 12:49

46.4 <6.1 19/07/2016 12:50

45.2 <6.1

19/07/2016 12:51

45.0 <6.1 19/07/2016 12:52

45.0 <6.1

19/07/2016 12:53

45.6 <6.1 19/07/2016 12:54

45.3 <6.1

19/07/2016 12:55

45.2 <6.1 19/07/2016 12:56

45.2 <6.1

19/07/2016 12:57

44.5 <6.1 19/07/2016 12:58

44.7 <6.1

19/07/2016 12:59

45.6 <6.1 19/07/2016 13:00

44.5 <6.1

19/07/2016 13:01

44.9 <6.1 19/07/2016 13:02

44.4 <6.1

19/07/2016 13:03

44.9 <6.1 19/07/2016 13:04

44.6 <6.1

19/07/2016 13:05

44.6 <6.1 19/07/2016 13:06

44.6 <6.1

19/07/2016 13:07

43.0 <6.1 19/07/2016 13:08

44.4 <6.1

19/07/2016 13:09

45.5 <6.1 19/07/2016 13:10

44.9 <6.1

19/07/2016 13:11

45.0 <6.1 19/07/2016 13:12

44.8 <6.1

Average


4.7 9.5



<10% <10%

For

insp

ectio

n pur

pose

s only

.

Conse

nt of

copy

right

owne

r req

uired

for a

ny ot

her u

se.

EPA Export 07-02-2017:02:12:38