dispersions for architectural coatings...natrosol plus 331 0.40 thickener aqualon natrosol 250 mbr...

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Dispersions for architectural coatings Vinavil 03 V Ravemul PC2 Vinavil 4555 Vinavil 4528 Ravemul T33 Ravemul T37 Vinavil 4425 Vinavil EVA 4612 Crilat D120S Crilat 4724 Crilat 4706 Crilat D117 Crilat 4818 Crilat 4816

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Page 1: Dispersions for architectural coatings...Natrosol Plus 331 0.40 Thickener Aqualon Natrosol 250 MBR 0.20 Thickener Aqualon Soda (sol 10%) 0.10 Neutralizing agent Various Reotan L 0.50

Dispersions for architectural coatings

Vinavil 03 V

Ravemul PC2

Vinavil 4555

Vinavil 4528

Ravemul T33

Ravemul T37

Vinavil 4425

Vinavil EVA 4612

Crilat D120S

Crilat 4724

Crilat 4706

Crilat D117

Crilat 4818

Crilat 4816

Page 2: Dispersions for architectural coatings...Natrosol Plus 331 0.40 Thickener Aqualon Natrosol 250 MBR 0.20 Thickener Aqualon Soda (sol 10%) 0.10 Neutralizing agent Various Reotan L 0.50
Page 3: Dispersions for architectural coatings...Natrosol Plus 331 0.40 Thickener Aqualon Natrosol 250 MBR 0.20 Thickener Aqualon Soda (sol 10%) 0.10 Neutralizing agent Various Reotan L 0.50

Vinavil 03 V page 2

Ravemul PC2 page 4

Vinavil 4555 page 6

Vinavil 4528 page 8

Ravemul T33 page 10

Ravemul T37 page 12

Vinavil 4425 page 14

Vinavil EVA 4612 page 16

Crilat D120S page 18

Crilat 4724 page 20

Crilat 4706 page 22

Crilat D117 page 24

Crilat 4818 page 26

Crilat 4816 page 28

INDEX

1

Page 4: Dispersions for architectural coatings...Natrosol Plus 331 0.40 Thickener Aqualon Natrosol 250 MBR 0.20 Thickener Aqualon Soda (sol 10%) 0.10 Neutralizing agent Various Reotan L 0.50

VINAVIL 03 VVINAVIL 03 V is an anionic/non-ionic water dispersion of vinyl-acetate/vinyl-versatate copolymer with 50% solid content, free from alkylphenol-ethoxylates (APEO-free).

PACKAGING

VINAVIL 03 V is available in bulk quantities, 1000 L IBC and 125 Kg PE drums.

STORAGE

VINAVIL 03 V remains stable for at least 6 months when stored at temperatures between +5°C ÷ +40°C.

VINAVIL 03 V is suitable for formulating interior/exterior wall paints and coatings at various PVC and has excel-lent rheological behaviour for application of both thin and thick coats.VINAVIL 03 V is highly versatile, easy to formulate and is used in a wide range of paints at medium or high PVC. Products containing VINAVIL 03 V have ex-

cellent properties in terms of binding and adhesion capacity, colour strength and weather resistance. Thanks to all these special characteristics, VINAVIL 03 V is one of the leading dispersion products used in the building industry.VINAVIL 03 V is also used as a fixative for the temporary encapsulation of asbestos cement.

APPLICATIONS

The main characteristics of VINAVIL 03 V are:

a) free from alkylphenol-ethoxylates (APEO-free) b) good water resistance c) high binding power with respect to pigments and fillers d) excellent compatibility with additives and fillers e) excellent rheology behaviour f) highly versatile, suitable for use in various formulates

2

Page 5: Dispersions for architectural coatings...Natrosol Plus 331 0.40 Thickener Aqualon Natrosol 250 MBR 0.20 Thickener Aqualon Soda (sol 10%) 0.10 Neutralizing agent Various Reotan L 0.50

VINAVIL 03 V

3

UNIT VALUE METHOD1. SUPPLY SPECIFICATIONSSolid content % 50±1 MVPF 01bis

Brookfield viscosity (1) mPa.s 3.500±500 UNI EN ISO 2555

pH 4.5±0.5 ISO 976

2. TYPICAL VALUESMinimum film-forming temperature °C +5 UNI 8490-14

Particle size distribution μm 0.1÷0.6 MVANS 20

Density at 23°C Kg/dm³ 1.06 MVPF 18

Glass transition temperature °C 28±1 MVANS 01

(1) RVT 20 rpm spindle 3, 23°C

INTERIOR PAINT 75% PVCWET SCRUB RESISTANCE – NORM DIN 53778

N° C

ycle

s

Vinavil 03 V Competitor 1 Competitor 2 Competitor 3

1.200

1.000

800

600

400

200

0

Page 6: Dispersions for architectural coatings...Natrosol Plus 331 0.40 Thickener Aqualon Natrosol 250 MBR 0.20 Thickener Aqualon Soda (sol 10%) 0.10 Neutralizing agent Various Reotan L 0.50

RAVEMUL PC2 RAVEMUL PC2 is an anionic/non-ionic water dispersion of vinyl-acetate/vinyl-versatate copolymer with 50% solid content, free from alkylphenol-ethoxylates (APEO-free).

PACKAGING

RAVEMUL PC2 is available in bulk quantities, 1000 L IBC and 125 Kg PE drums.

STORAGE

RAVEMUL PC2 remains stablefor at least 6 months when stored at temperatures between +5°C ÷ +40°C.

RAVEMUL PC2 is suitable for formulating interior/exterior paints and coatings at various PVC.Particle size distribution has been specially designed to give paints high hiding power.RAVEMUL PC2 is characterised by its optimum combi-nation of various parameters which have high impact

on finished products for the building industry, such as binding capacity, rheological behaviour, low film sen-sitivity to water, compatibility with various types of fillers, pigments and additives and weather resistance.When used in exterior paints, it gives them the properties of low water absorption and good permeability to vapour.

APPLICATIONS

The main characteristics of RAVEMUL PC2 are:

a) free from alkylphenol-ethoxylates (APEO-free)b) good alkali resistancec) good water resistanced) high hiding powere) excellent compatibility with additives and fillersf) excellent rheology behaviourg) highly versatile, suitable for use in various formulates

4

Page 7: Dispersions for architectural coatings...Natrosol Plus 331 0.40 Thickener Aqualon Natrosol 250 MBR 0.20 Thickener Aqualon Soda (sol 10%) 0.10 Neutralizing agent Various Reotan L 0.50

RAVEMUL PC2

UNIT VALUE METHOD1. SUPPLY SPECIFICATIONSSolid content % 50±1 MVPF 01

Brookfield viscosity (1) mPa.s 3.000±500 UNI EN ISO 2555

pH 4.5±0.5 ISO 976

2. TYPICAL VALUESMinimum film-forming temperature °C +3 UNI 8490-14

Particle size distribution μm 0.2÷1.2 MVANS 20

Density at 23°C Kg/dm³ 1.06 MVPF 18

Glass transition temperature °C 28±1 MVANS 01

(1) RVT 20 rpm spindle 3, 23°C

COMPONENTS w. % FUNCTION SUPPLIERSWater 28.00

Tego Foamex 1488 0.10 Defoamer Evonik

Natrosol Plus 331 0.40 Thickener Aqualon

Natrosol 250 MBR 0.20 Thickener Aqualon

Soda (sol 10%) 0.10 Neutralizing agent Various

Reotan L 0.50 Dispersant Lamberti

Sodium hexametaphosphate 0.20 Dispersant Various

Disponil PL 400 0.20 Wetting agent Cognis

Acticide SPX 0.28 Biocide Thor

Texanol 0.70 Coalescent Eastman

Ethylene glycol 0.50 Co-solvent Various

TiO2 type RXL 19.00 Pigment Tioxide

CaCO3 type Omyacarb 10AV 17.00 Filler Omya

Polestar 200P 6.50 Filler Imerys

Talc 9.00 Filler LuzenacRavemul PC2 16.00 Binder VinavilTego Foamex 1488 0.10 Defoamer Evonik

Water 1.00

Total 100.00

INTERIOR MATT PAINT WITH HIGH HIDING POWER

Rif. 01 025E E

5

Page 8: Dispersions for architectural coatings...Natrosol Plus 331 0.40 Thickener Aqualon Natrosol 250 MBR 0.20 Thickener Aqualon Soda (sol 10%) 0.10 Neutralizing agent Various Reotan L 0.50

VINAVIL 4555VINAVIL 4555 is an anionic/non-ionic water dispersion of vinyl-acetate/vinyl-versatate copolymer with 55% solid content, free from solvents (plasticizer and coalescing agents) and from alkylphenol-ethoxylates (APEO-free).

PACKAGING

VINAVIL 4555 is available in bulk quantities, 1000 L IBC and 125 Kg PE drums.

STORAGE

VINAVIL 4555 remains stablefor at least 6 months when stored at temperatures between +5°C ÷ +40°C.

VINAVIL 4555 is suitable for formulating interior/exterior paints and textured coatings, satin and gloss paints with good adhesion and sheen.Thanks to its special characteristics, formulates con-taining VINAVIL 4555 have good rheological properties and excellent dirt pick-up resistance.Thanks to its high resistance to alkalinity and good weather resistance, it may also be used in the prepa-ration of exterior paints and textured coatings. Paints

at high PVC, formulated with VINAVIL 4555, are cha-racterised by high wet scrub resistance. When used in water paints, the binding power of VINAVIL 4555 is best expressed when coalescing agents are added to lower the filming temperature. The amount used de-pends on the effectiveness of the coalescing agent. For diethylenglycol monobutyl ether acetate, for example, the amount required is 2-3% on the VINAVIL 4555 in the formulation.

APPLICATIONS

The main characteristics of VINAVIL 4555 are:

a) free from alkylphenol-ethoxylates (APEO-free) b) good water resistance c) high binding power with pigments and fillers d) excellent compatibility with additives and fillers e) excellent rheology behaviour f) highly versatile, suitable for various applicationsg) high solid content dispersion

6

Page 9: Dispersions for architectural coatings...Natrosol Plus 331 0.40 Thickener Aqualon Natrosol 250 MBR 0.20 Thickener Aqualon Soda (sol 10%) 0.10 Neutralizing agent Various Reotan L 0.50

VINAVIL 4555

UNIT VALUE METHOD1. SUPPLY SPECIFICATIONSSolid content % 55±1 MVPF 01

Brookfield viscosity (1) mPa.s 3.000±1

.000 UNI EN ISO 2555

pH 5.0±0.5 ISO 976

2. TYPICAL VALUESMinimum film-forming temperature °C +13 UNI 8490-14

Particle size distribution μm 0.1÷0.6 MVANS 20

Density at 23°C Kg/dm³ 1.1 MVPF 18

Glass transition temperature °C 28±1 MVANS 01

Resistance to freeze-thaw N° of cycles > 5 UNI 8490-13

(1) RVT 20 rpm spindle 3, 23°C

N° C

ycle

s

Vinavil 4555 Competitor 1 Competitor 2 Competitor 4Competitor 3

INTERIOR PAINT 75% PVCWET SCRUB RESISTANCE – NORM DIN 53778

1.200

1.000

800

600

400

200

0

7

Page 10: Dispersions for architectural coatings...Natrosol Plus 331 0.40 Thickener Aqualon Natrosol 250 MBR 0.20 Thickener Aqualon Soda (sol 10%) 0.10 Neutralizing agent Various Reotan L 0.50

VINAVIL 4528 VINAVIL 4528 is an anionic/non-ionic water dispersion of vinyl-acetate/vinyl-versatate copolymer with 50% solid content, free from alkylphenol-ethoxylates (APEO-free).

PACKAGING

VINAVIL 4528 is available in bulk quantities, 1000 L IBC and 125 Kg PE drums.

STORAGE

VINAVIL 4528 remains stablefor at least 6 months when stored at temperatures between +5°C ÷ +40°C.

VINAVIL 4528 is suitable for formulating interior/exterior paints and textured coatings and is particularly versatile when used in products with low and high PVC and in wall textured coatings.VINAVIL 4528 has a high binding power in paints with

a medium to high PVC and has good alkali and water resistance.Its specific low viscosity makes it particularly simple to dose when used in automatic plant equipment and ma-kes handling easier during paint manufacturing.

APPLICATIONS

The main characteristics of VINAVIL 4528 are:

a) free from alkylphenol-ethoxylates (APEO-free) b) good water resistance c) high binding power with respect to pigments and fillers d) excellent compatibility with additives and fillers e) excellent rheology behaviour f) highly versatile, suitable for various applications

8

Page 11: Dispersions for architectural coatings...Natrosol Plus 331 0.40 Thickener Aqualon Natrosol 250 MBR 0.20 Thickener Aqualon Soda (sol 10%) 0.10 Neutralizing agent Various Reotan L 0.50

VINAVIL 4528

CHARACTERISTICS VALUE METHODBrookfield RVT Viscosity at 20rpm, 23°C (mPa.s) 10

.000 UNI EN ISO 2555

pH 7.5 ISO 976

Density (g/ml) 1.62 MVPF 18

Solid content (%) 64 MVPF 01

VOC content (g/l) 8.5 ISO 11890

Wet scrub resistance (n° cycles) 1.900 DIN 53778

UNIT VALUE METHOD1. SUPPLY SPECIFICATIONSSolid content % 50±1 MVPF 01

Brookfield viscosity (1) mPa.s <500 UNI EN ISO 2555

pH 5.0±0.5 ISO 976

2. TYPICAL VALUESMinimum film-forming temperature °C +5 UNI 8490-14

Particle size distribution μm 0.2÷0.4 MVANS 20

Density at 23°C Kg/dm³ 1.1 MVPF 18

Glass transition temperature °C 28±1 MVANS 01

Resistance to freeze-thaw N° of cycles >5 UNI 8490-13

(1) RVT 20 rpm spindle 1, 23°C

COMPONENTS w. % FUNCTION SUPPLIERSWater 24.00

Comiel L 808E 0.20 Defoamer Comiel

Natrosol PLUS 331 0.50 Thickener Aqualon

Soda (sol 10%) 0.10 Neutralizing agent Various

Sodium hexametaphosphate (sol 10%) 2.50 Dispersant Various

Disponil PL 400 0.20 Wetting agent Cognis

Acticide B 20 0.20 Biocide Thor

Texanol 0.40 Coalescent Eastman

Ethylene glycol 0.50 Co-solvent Various

TiO2 type RXL 10.00 Pigment Huntsman

Polestar 200 P 6.00 Filler Imerys

CaCO3 type Omyacarb 5 AV 40.50 Filler OmyaVinavil 4528 14.00 Binder VinavilWater 0.90

Total 100.00

WASHABLE PAINT 75% PVC

9

Page 12: Dispersions for architectural coatings...Natrosol Plus 331 0.40 Thickener Aqualon Natrosol 250 MBR 0.20 Thickener Aqualon Soda (sol 10%) 0.10 Neutralizing agent Various Reotan L 0.50

RAVEMUL T33 RAVEMUL T33 is a water dispersion of a special vinyl terpolymer with 55% solid content, characterised by its high glass transition temperature and low film-forming temperature. Ravemul T33 is free from alkylphenol-ethoxylates (APEO-free).

PACKAGING

RAVEMUL T33 is available in bulk quantities, 1000 L IBC and 125 Kg PE drums.

STORAGE

RAVEMUL T33 remains stablefor at least 6 months when stored at temperatures between +5°C ÷ +40°C.

RAVEMUL T33 is particularly suitable for use in for-mulates such as wall textured coatings with high gloss and low dirt pick-up, water paints with low water ab-sorption for conventional applications, high gloss and matt wall enamels. RAVEMUL T33 is characterised by a high glass transition temperature which makes it par-ticularly suitable for wall textured coating at low PVC, with characteristic of poor blocking tendency and low

dirt pick-up retention over the years. The films obtained using RAVEMUL T33 show very high alkali resistance, even at high pH. RAVEMUL T33-based products, there-fore, may be applied on substrates with a high level of alkalinity. We recommend, however, that substrates are verified beforehand to make sure they are well conso-lidated. RAVEMUL T33 is compatible with fillers, pig-ments and the most commonly used additives.

APPLICATIONS

The main characteristics of RAVEMUL T33 are:

a) free from alkylphenol-ethoxylates (APEO-free) b) excellent water resistance c) high gloss d) excellent rheology behavioure) low dirt pick-up f) excellent blocking resistance

10

Page 13: Dispersions for architectural coatings...Natrosol Plus 331 0.40 Thickener Aqualon Natrosol 250 MBR 0.20 Thickener Aqualon Soda (sol 10%) 0.10 Neutralizing agent Various Reotan L 0.50

RAVEMUL T33

CHARACTERISTICS VALUE METHODBrookfield RVT Viscosity at 20 rpm, 23°C (mPa.s) 3

.650 UNI EN ISO 2555

ICI Viscosity at 10˙000 s-1 (Poise) 2.97 ASTM D 4287

pH 7.56 ISO 976

Dirt pick-up (ΔL) 4.74 UNI 10792

Hiding power (RC) 0.99 UNI ISO 3905

Gloss at 20° after 24h 53.4 UNI 9389

Gloss at 60° after 24h 80.5 UNI 9389

UNIT VALUE METHOD1. SUPPLY SPECIFICATIONSSolid content % 55±1 MVPF 01

Brookfield viscosity (1) mPa.s 3.000±1

.000 UNI EN ISO 2555

pH 4.5±0.5 ISO 976

2. TYPICAL VALUESMinimum film-forming temperature °C +12 UNI 8490-14

Particle size distribution μm 0.4÷1.2 MVANS 20

Density at 23°C Kg/dm³ 1.1 MVPF 18

Glass transition temperature °C 34±1 MVANS 01

Resistance to freeze-thaw N° of cycles >5 UNI 8490-13

(1) RVT 20 rpm spindle 3, 23°C

COMPONENTS w. % FUNCTION SUPPLIERSWater 12.80

Ethylene glycol 2.00 Co-solvent Various

Sodium hexametaphosphate (sol 10%) 1.00 Dispersant Various

Coadis BR3 0.20 Dispersant Coatex

Acticide SPX 0.15 Biocide Thor

Tego Foamex 1488 0.10 Defoamer Evonik

Butyl diglycol acetate 2.00 Coalescent Various

TiO2 type R-HD2 19.50 Pigment Tioxide

Tego Foamex 1488 0.15 Defoamer Evonik

Ammonia (sol 30%) 0.60 Neutralizing agent Various

Rheotech 2000 (*) 3.50 Thickener CoatexRavemul T33 57.00 Binder VinavilWater 1.00

Total 100.00

(*) dilution 1:1 with water

GLOSS PAINTRif. 04 022E E

11

Page 14: Dispersions for architectural coatings...Natrosol Plus 331 0.40 Thickener Aqualon Natrosol 250 MBR 0.20 Thickener Aqualon Soda (sol 10%) 0.10 Neutralizing agent Various Reotan L 0.50

RAVEMUL T37 RAVEMUL T37 is a water dispersion of vinyl-acetate terpolymer with versatic acid esthers. Ravemul T37 is free from alkylphenol-ethoxylates (APEO-free).

PACKAGING

RAVEMUL T37 is available in bulk quantities, 1000 L IBC and 125 Kg PE drums.

STORAGE

RAVEMUL T37 remains stablefor at least 6 months when stored at temperatures between +5°C ÷ +40°C.

RAVEMUL T37 is particularly suitable for use in lime-ba-sed paints and coatings for intumescent and fire-retardant paints. Thanks to its high alkali resistance, it is also used as an additive for cement-based systems such as repair mor-tars, construction joints, grout protection and thermal insu-lation finishing systems (EIFS).RAVEMUL T37 is particularly recommended where good hydrophobicity is required, being the polymer film highly wa-

ter resistant. Moreover, thanks to the high alkali resistance and excellent compatibility with cement, it is recommended for applications where the following performance characte-ristics need to be improved: adhesion to the substrate, fle-xibility, dimensional stability during the drying phase, resi-stance to wear and reduction of water permeability.RAVEMUL T37 is highly compatible and stable in lime-ba-sed paints.

APPLICATIONS

The main characteristics of RAVEMUL T37 are:

a) free from alkylphenol-ethoxylates (APEO-free) b) excellent alkali resistance c) high chemical resistance d) excellent compatibility with additives and fillers e) excellent rheology behaviour f) low water absorption

12

Page 15: Dispersions for architectural coatings...Natrosol Plus 331 0.40 Thickener Aqualon Natrosol 250 MBR 0.20 Thickener Aqualon Soda (sol 10%) 0.10 Neutralizing agent Various Reotan L 0.50

RAVEMUL T37

UNIT VALUE METHOD1. SUPPLY SPECIFICATIONSSolid content % 50±1 MVPF 01

Brookfield viscosity (1) mPa.s 1.000±500 UNI EN ISO 2555

pH 4.5±0.5 ISO 976

2. TYPICAL VALUESMinimum film-forming temperature °C +3 UNI 8490-14

Particle size distribution μm 0.4÷1.2 MVANS 20

Density at 23°C Kg/dm³ 1.1 MVPF 18

Glass transition temperature °C 34±1 MVANS 01

(1) RVT 20 rpm spindle 2, 23°C

Before exposure After exposure

INTUMESCENT COATINGS BEFORE AND AFTER EXPOSURE

In case of fire when exposed to flame, the coating expands to form a protective foam to the substrate where it is applied.

13

Page 16: Dispersions for architectural coatings...Natrosol Plus 331 0.40 Thickener Aqualon Natrosol 250 MBR 0.20 Thickener Aqualon Soda (sol 10%) 0.10 Neutralizing agent Various Reotan L 0.50

VINAVILL 4425 VINAVIL 4425 is an anionic/non-ionic water dispersion of vinyl-acetate/acrylate copolymer with 55% solid content, free from solvents (plasticizer and coalescing agents) and alkylphenol-ethoxylates (APEO-free).

PACKAGING

VINAVIL 4425 is available in bulk quantities, 1000 L IBC and 125 Kg PE drums.

STORAGE

VINAVIL 4425 remains stablefor at least 6 months when stored at temperatures between +5°C ÷ +40°C.

VINAVIL 4425 is a vinyl/acrylic dispersion developed for formulating interior paints with high scrub resistance and excellent dirt pick-up resistance.

APPLICATIONS

The main characteristics of VINAVIL 4425 are:

a) free from alkylphenol-ethoxylates (APEO-free)b) high scrub resistance, even at high PVC c) excellent dirt pick-up resistanced) excellent mechanical stabilitye) low water absorption of the filmf) high hiding powerg) good compatibility with additives most commonly used for formulating water paints

14

Page 17: Dispersions for architectural coatings...Natrosol Plus 331 0.40 Thickener Aqualon Natrosol 250 MBR 0.20 Thickener Aqualon Soda (sol 10%) 0.10 Neutralizing agent Various Reotan L 0.50

VINAVIL 4425

UNIT VALUE METHOD 1. SUPPLY SPECIFICATIONSSolid content % 55±1 MVPF 01

Brookfield viscosity (1) mPa.s 1.000±500 UNI EN ISO 2555

pH 4.5±0.5 ISO 976

2. TYPICAL VALUESMinimum film-forming temperature °C +7 UNI 8490-14

Particle size distribution μm 0.2÷0.4 MVANS 20

Density at 23°C Kg/dm³ 1.07 MVPF 18

Glass transition temperature °C 28±1 MVANS 01

(1) RVT 20 rpm spindle 1, 23°C

15

N° C

ycle

s

Vinavil 4425 Competitor 1 Vinyl-versatate Styrene-acrylic

INTERIOR PAINT 80% PVCWET SCRUB RESISTANCE – NORM DIN 53778

1.600

1.400

1.200

1.000

800

600

400

200

0

INTERIOR PAINT 80% PVC - DIRT PICK-UP METHOD UNI 10792

VINAVIL 4425 L = 14.8

Vinyl-versatate L = 16.8

Competitor 1 L = 16.3

Page 18: Dispersions for architectural coatings...Natrosol Plus 331 0.40 Thickener Aqualon Natrosol 250 MBR 0.20 Thickener Aqualon Soda (sol 10%) 0.10 Neutralizing agent Various Reotan L 0.50

VINAVIL EVA 4612VINAVIL EVA 4612 is a water dispersion of vinyl-acetate/ethylene copolymer, free from solvents (plasticizer and coalescing agents), alkylphenol-ethoxylates (APEO-free) and is characterised by very low free monomer content.

PACKAGING

VINAVIL EVA 4612 is available in bulk quantities, 1000 L IBC and 125 Kg PE drums.

STORAGE

VINAVIL EVA 4612 remains stable for at least 6 months when stored at temperatures between +5°C ÷ +40°C.

VINAVIL EVA 4612 is odourless and suitable for the pre-paration of interior/exterior paints, including those at high PVC, satin paints and wall textured coatings where a low content of volatile organic compounds (VOC) is required.VINAVIL EVA 4612 allows the formulation of paints in accordance to Ecolabel norms, which are identified by a specific labelling.The VINAVIL EVA 4612 contained in formulates develo-

pes very good rheology to make application easier, high binding, hiding properties and excellent compatibility with pigment pastes. Thanks to the presence of ethylene in the monomer composition, VINAVIL EVA 4612 has a mini-mum film-forming temperature (MFFT) of 0°C. This pro-perty allows painting products to be formulated without the use of coalescing agents and plasticizer, which redu-ces VOC content to levels well below 1 g/l.

APPLICATIONS

The main characteristics of VINAVIL EVA 4612 are:

a) free from alkylphenol-ethoxylates (APEO-free) b) no coalescing agent for film-forming required c) good water resistance d) high binding power with respect to pigments and fillers e) excellent compatibility with additives and fillers f) excellent rheology behaviour g) low content of volatile organic compounds (VOC)

16

Page 19: Dispersions for architectural coatings...Natrosol Plus 331 0.40 Thickener Aqualon Natrosol 250 MBR 0.20 Thickener Aqualon Soda (sol 10%) 0.10 Neutralizing agent Various Reotan L 0.50

VINAVIL EVA 4612

UNIT VALUE METHOD1. SUPPLY SPECIFICATIONSSolid content % 52±1 MVPF 01

Brookfield viscosity (1) mPa.s 3.500±1

.000 UNI EN ISO 2555

pH 4.5±0.5 ISO 976

2. TYPICAL VALUESMinimum film-forming temperature °C 0 UNI 8490-14

Particle size distribution μm 0.2÷0.6 MVANS 20

Density at 23°C Kg/dm³ 1.1 MVPF 18

Glass transition temperature °C 12±1 MVANS 01

(1) RVT 20 rpm spindle 3, 23°C

In spite of the differences of VOC content, all tested samples are conforming to 2004/42/CE.

MEASUREMENT VOC EMISSIONS OF PAINTSWITH GC-MASS METHOD EN 13999-1 PART 2

VOC

(mg/

m3 )

Paint75% PVCAcV/VeoVa

Paint75% PVC

Vinavil EVA 4612

Low-VOCpaint fromEngland

Low-VOC paint from

Italy

10.000

9.000

8.000

7.000

6.000

5.000

4.000

3.000

2.000

1000

0

After 24 hours After 10 days

101

1.234

74

23 12 38

2.021

9.647

17

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CRILAT D120S CRILAT D120S is a water dispersion of styrene/acrylic copolymer used as a binder in the preparation of interior/exterior wall paints and textured coatings such as quartz, silicate, siloxane and coloured renders.

PACKAGING

CRILAT D120S is available in bulk quantities, 1000 L IBC and 125 Kg PE drums.

STORAGE

CRILAT D120S remains stablefor at least 6 months when stored at temperatures between +5°C ÷ +40°C.

CRILAT D120S is a multi-purpose, styrene/acrylic di-spersion used in a multitude of interior/exterior paint formulations, including those at high PVC with excel-lent wet scrub resistance, quartz paints, wall textured coatings and coloured renders.CRILAT D120S is highly compatible with hydraulic and mineral binders which makes it suitable for formula-ting cementitious and silicate-based products.The high water resistance of the CRILAT D120S film offers the best solution when formulates, characteri-

sed by high water resistance (paints, wall textured co-atings, covering products for roofs and terraces) and formulates without pigments, are required.Thanks to the high binding power of CRILAT D120S, paints at high PVC with excellent wet scrub resistance may be prepared.The excellent alkali resistance allows the prepara-tion of paints and wall textured coatings suitable for exterior applications, also on substrates with high alkalinity.

APPLICATIONS

The main characteristics of CRILAT D120S are:

a) free from solvents or coalescing agents and plasticizer b) high water resistance c) good compatibility with hydraulic binders, minerals and polysiloxane d) excellent adhesion e) high binding power with respect to pigments and fillers f) excellent alkali resistance g) highly versatile, suitable for various applications

18

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CRILAT D120S

UNIT VALUE METHOD1. SUPPLY SPECIFICATIONSSolid content % 50±1 MVPF 01

Brookfield viscosity (1) mPa.s 9.000±3

.000 UNI EN ISO 2555

pH 8.0±0.5 ISO 976

2. TYPICAL VALUESMinimum film-forming temperature °C +18 UNI 8490-14

Particle size distribution μm 0.08÷0.15 MVANS 20

Density at 23°C Kg/dm³ 1.06 MVPF 18

Glass transition temperature °C 26±1 MVANS 01

Resistance to freeze-thaw N° of cycles >5 UNI 8490-13

(1) RVT 20 rpm spindle 5, 23°C

Dynamometer Alliance MTS RT/50Break value: 0.9 MPa

Type of break: A (break of substrate)

MEASUREMENT OF ADHESION BY TENSILE TEST OF A TEXTURED COATING BASED ON CRILAT D120S UNI EN ISO 4624

19

CRILAT 4706

CRILAT 4724

CRILAT 4818

CRILAT 4816

CRILAT D117

CRILAT D120S

Broo

kfiel

d RV

T vi

scos

ity a

t 20

rpm

, 23°

C (m

Pa. s

)

SILICA PAINTS: ACCELERATING STORAGE STABILITY AT 50°C

Days

50.000

45.000

40.000

35.000

30.000

25.000

20.000

15.000

10.000

5.000

00 15 30

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CRILAT 4724CRILAT 4724 is a water dispersion of styrene/acrylic copolymer (APEO-free) used as a binder in the preparation of interior/exterior wall paints and coatings such as quartz, silicate and siloxane paints as well as wall textured coatings and paints at high PVC, with excellent scrub resistance.

PACKAGING

CRILAT 4724 is available in bulk quantities, 1000 L IBC and 125 Kg PE drums.

STORAGE

CRILAT 4724 remains stable for at least 6 months when stored at temperatures between +5°C ÷ +40°C.

CRILAT 4724 has been developed for a multitude of applications in formulations for interior/exterior paints, wall textured coatings and, thanks to its excellent com-patibility with hydraulic and mineral binders, it is used in cement and silicate-based systems.Even when used in paints at high PVC, because of its high binding power with respect to pigments and fillers,CRILAT 4724 offers excellent wet scrub resistance.

The high water resistance of the CRILAT 4724 film offers the best solution when formulates characterised by high water repellence such as paints, wall textured coatings and covering products for roofs and terraces are required.The excellent alkali resistance allows the preparation of paints and wall textured coatings suitable for exterior applications, also on substrates with high alkalinity and in combination with polysiloxane resins.

APPLICATIONS

The main characteristics of CRILAT 4724 are:

a) free from alkylphenol-ethoxylates (APEO-free) b) high water resistance c) excellent compatibility with hydraulic binders, minerals and polysiloxane d) high binding power, also in paints at high PVC e) excellent alkali resistance f) highly versatile, suitable for various applications

20

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CRILAT 4724

CHARACTERISTICS METHOD UNIT VALUE CLASSIFICATIONDirt pick-up ( L) UNI 10792 0.24 Very low

Liquid-water transmission rate (W24) UNI EN 1062-3 (Kg/(m.h0.5)) 0.19 Medium

Water-vapour transmission rate (Sd) UNI EN ISO 7783-2 (m) 0.010 High

Künzel Theory W24 x Sd < 0.1 DIN 18550 (Kg/(m.h0.5)) 0.002 Respected

UNIT VALUE METHOD1. SUPPLY SPECIFICATIONSSolid content % 50±1 MVPF 01

Brookfield viscosity (1) mPa.s 9.000±3

.000 UNI EN ISO 2555

pH 8.5±0.5 ISO 976

2. TYPICAL VALUESMinimum film-forming temperature °C +15 UNI 8490-14

Particle size distribution μm 0.08÷0.15 MVANS 20

Density at 23°C Kg/dm³ 1.06 MVPF 18

Glass transition temperature °C 24±1 MVANS 01

(1) RVT 20 rpm spindle 5, 23°C

In accordance with Künzel Theory the wall is considered dry when W24 · Sd < 0,1 Kg/(m.h0.5) where:W24<0.5 Kg/(m.h0.5) and Sd <2m

The siloxane paint based on Crilat 4724 has the ability to make the surface hydrophobic by changing the surface tension reaching the drop effect.

SILOXANE PAINT BASED ON CRILAT 4724

21

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CRILAT 4706CRILAT 4706 is a water dispersion of styrene/acrylic copolymer free from alkylphenol-ethoxylates (APEO-free) and solvents, which forms a transparent, slightly sticky and flexible film, with excellent water resistance.

PACKAGING

CRILAT 4706 is available in bulk quantities, 1000 L IBC and 125 kg PE drums.

STORAGE

CRILAT 4706 remains stable for at least 6 months when stored at temperatures between +5°C ÷ +40°C.

CRILAT 4706 is suitable for formulating interior/exterior paints, where more flexibility is required compared with conventional styrene/acrylics products.CRILAT 4706 is used for preparing quartz paints and wall textured coatings, water-based membranes, silicate and siloxane-based systems and solvent-free formulates. Thanks to its low film-forming temperature, CRILAT 4706

does not require the addition of coalescing agents in the formulation.The good flexibility of the film allows the preparation of wall textured coatings with no problem of cracking when applied in thick layers. Its high resistance to water, alkali and dirt pick-up, allows the formulation of liquid mem-branes for roofs.

APPLICATIONS

The main characteristics of CRILAT 4706 are:

a) free from alkylphenol-ethoxylates (APEO-free)b) free from solvents or coalescing agents and plasticizer c) no coalescing agent for film-forming required d) high water resistance e) compatible with hydraulic and mineral binders (cement, polysiloxane and silicate) f) good flexibility g) low dirt pick-up h) excellent alkali resistance

22

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CRILAT 4706

COMPONENTS w. % FUNCTION SUPPLIERSWater 15.40

Tego Foamex 1488 0.10 Defoamer Evonik

Natrosol 250 MBR 0.30 Thickener Aqualon

Ammonia (sol 28%) 0.10 Neutralizing agent Various

Sodium hexametaphosphate (sol 10%) 1.00 Dispersant Various

Acticide MBS 0.20 Biocide Thor

Disponil PL 400 0.40 Wetting agent Cognis

Reotan L 0.40 Dispersant Lamberti

Propylene glycol 0.40 Co-solvent Various

TiO2 type Tioxide RXL 3.00 Pigment Huntsman

Crilat 4706 60.00 Binder Vinavil

CaCO3 5 μm type Omyacarb 5AV 4.50 Filler Omya

Plastorite 000 14.00 Filler Luzenac

Tego Foamex 1488 0.20 Defoamer Evonik

Total 100.00

CHARACTERISTICS VALUE METHODBrookfield RVT Viscosity at 20 rpm, 23°C (mPa.s) 5

.100 UNI EN ISO 2555

pH 8.34 ISO 976

Dirt pick-up (ΔL) 5.50 low UNI 10792

Strength at break (N/mm2) 1.4 UNI 8490/17

Elongation at break (%) 1.300 UNI 8490/17

UNIT VALUE METHOD1. SUPPLY SPECIFICATIONSSolid content % 50±1 MVPF 01

Brookfield viscosity (1) mPa.s 6.000±2

.000 UNI EN ISO 2555

pH 8.0±0.5 ISO 976

2. TYPICAL VALUESMinimum film-forming temperature °C 0 UNI 8490-14

Particle size distribution μm 0.08÷0.14 MVANS 20

Density at 23°C Kg/dm³ 1.06 MVPF 18

Glass transition temperature °C 6±1 MVANS 01

(1) RVT 20 rpm spindle 5, 23°C

WATER PROOF MEMBRANERif. 07 02E E

23

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CRILAT D117CRILAT D117 is a water dispersion of acrylic copolymer with 46% solid content, free from alkylphenol-ethoxylates (APEO-free).

PACKAGING

CRILAT D117 is available in bulk quantities, 1000 L IBC and 125 Kg PE drums.

STORAGE

CRILAT D117 remains stable for at least 6 months when stored at temperatures between +5°C ÷ +40°C.

CRILAT D117 is suitable for formulating exterior paints, tex-tured coatings and decorative interior paints (veiling, etc.).CRILAT D117 gives paints and wall textured coatings ex-cellent characteristics of weather and strong alkali resi-

stance, good colour fastness and low sensitivity to water.Thanks to these properties, the product allows the prepa-ration of various formulates of high quality and of presti-gious products for exterior use (building industry).

APPLICATIONS

The main characteristics of CRILAT D117 are:

a) free from alkylphenol-ethoxylates (APEO-free) b) high water resistance c) high binding power with respect to pigments and fillers d) excellent alkali resistance e) excellent colour strength

24

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CRILAT D117

UNIT VALUE METHOD1. SUPPLY SPECIFICATIONSSolid content % 46±1 MVPF 01

Brookfield viscosity (1) mPa.s 4.000±1

.500 UNI EN ISO 2555

pH 9.0±0.5 ISO 976

2. TYPICAL VALUESMinimum film-forming temperature °C +9 UNI 8490-14

Particle size distribution μm 0.1÷0.2 MVANS 20

Density at 23°C Kg/dm³ 1.06 MVPF 18

Glass transition temperature °C 18±1 MVANS 01

(1) RVT 20 rpm, 23°C, spindle 3

COMPONENTS w. % FUNCTION SUPPLIERSWater 65.40

Ethylene glycol 0.60 Co-solvent Various

Texanol 1.00 Coalescent Eastman

Tego Foamex 1488 0.20 Defoamer Evonik

Acticide SPX 0.20 Biocide Thor

Tego Phobe 1650 7.00 Siloxane binder Evonik

Crilat D117 22.00 Binder Vinavil

Rheothec 2000 3.20 Thickener Coatex

Tego Foamex 1488 0.10 Defoamer Evonik

AMP 90 0.30 Neutralizing agent Angus

Total 100.00

Add the pigment pasta to get the desired colour.

FINISHING VEILED WITH DECORATIVE EFFECT

Rif. 03 040E

25

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CRILAT 4818CRILAT 4818 is a water dispersion of acrylic copolymer with 47% solid content, free from alkylphenol-ethoxylates (APEO-free).

PACKAGING

CRILAT 4818 is available in bulk quantities, 1000 L IBC and 125 Kg PE drums.

STORAGE

CRILAT 4818 remains stablefor at least 6 months when stored at temperatures between +5°C ÷ +40°C.

CRILAT 4818 is suitable for formulating exterior paints and wall textured coatings with high performance of du-rability and weather resistance. The excellent alkali re-

sistance, the colour fastness, the water resistance and the dirt pick-up of CRILAT 4818 allow the preparation of products where high durability class paints is required.

APPLICATIONS

The main characteristics of CRILAT 4818 are:

a) free from alkylphenol-ethoxylates (APEO-free)b) high water resistancec) high binding power with respect to pigments and fillers, also at high PVCd) excellent alkali resistancee) excellent colour strengthf) high weather resistance

26

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CRILAT 4818

Method Exterior paint Exterior paint Exterior paint UNI EN ISO 11507 based on based on based on St/A (1) St/A (2) Crilat 4818 L 85.46 85.88 87.44

a* 7.76 7.37 6.19

b* 23.70 22.82 21.03

200 hours cycle UV-CON ΔE* 1.66 2.17 1.14

400 hours cycle UV-CON ΔE* 5.71 3.19 2.38

600 hours cycle UV-CON ΔE* 9.43 6.54 3.36

800 hours cycle UV-CON ΔE* 11.86 9.18 4.62

1000 hours cycle UV-CON ΔE* 12.95 10.43 5.48

UNIT VALUE METHOD1. SUPPLY SPECIFICATIONSSolid content % 47±1 MVPF 01

Brookfield viscosity (1) mPa.s <200 UNI EN ISO 2555

pH 8.5±0.5 ISO 976

2. TYPICAL VALUESMinimum film-forming temperature °C +10 UNI 8490-14

Particle size distribution μm 0.1÷0.2 MVANS 20

Density at 23°C Kg/dm³ 1.06 MVPF 18

Glass transition temperature °C 18±1 MVANS 01

(1) RVT 20 rpm spindle 1, 23°C

COLORIMETRIC MEASUREMENTS OF EXTERIOR PAINTS, AFTER TEST OF ARTIFICIAL WEATHERING EXPOSURE WITH THE USE OF UV LAMPS

UV-CON Cycle:

Segment 1 (4h) 2 (8h)

Water spray ON OFF

UV irradiance OFF ON

27

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CRILAT 4816CRILAT 4816 is a water dispersion of acrylic copolymer with 50% solid content, free from solvents (plasticizer and coalescing agents) and from alkylphenol-ethoxylates (APEO-free).

PACKAGING

CRILAT 4816 is available in bulk quantities, 1000 L IBC and 125 Kg PE drums.

STORAGE

CRILAT 4816 remains stablefor at least 6 months when stored at temperatures between +5°C ÷ +40°C.

CRILAT 4816 is suitable for formulating interior/exterior odourless wall paints and coatings with a low impact on the environment. CRILAT 4816 has been developed for formulating inte-rior/exterior paints with a low VOC (volatile organic com-pounds) in compliance with Directive 2004/42/CE.

Its high alkali resistance and excellent colour fastness allow it to be used in exterior paints with characteristics of excellent weather resistance. CRILAT 4816 remains stable in highly alkaline systems, such as lime and potassium silicate.

APPLICATIONS

The main characteristics of CRILAT 4816 are:

a) free from alkylphenol-ethoxylates (APEO-free)b) no coalescing agent for film-forming requiredc) high water resistance d) excellent alkali resistancee) excellent colour strengthf) low dirt pick-upg) good adhesion on old alkyd paintsh) high weather resistance

28

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VINAVIL CRILAT 4816

UNIT VALUE METHOD1. SUPPLY SPECIFICATIONSSolid content % 50±1 MVPF 01

Brookfield viscosity (1) mPa.s <1.000 UNI EN ISO 2555

pH 8.0±0.5 ISO 976

2. TYPICAL VALUESMinimum film-forming temperature °C 0 UNI 8490-14

Particle size distribution μm 0.06÷0.12 MVANS 20

Density at 23°C Kg/dm³ 1.06 MVPF 18

Glass transition temperature °C 8±1 MVANS 01

(1) RVT 20 rpm spindle 1, 23°C

29

LIME PAINT (Rif. 02 007E E)ACCELERATED STORAGE STABILITY AT 50°C

51.000

25.750

36.000

24.00016.000

10.000

CRILAT 4816 COMPETITOR

Broo

kfiel

d RV

T vi

scos

ity a

t 20

rpm

, 23°

C

(mPa

. s)

Days

60.000

50.000

40.000

30.000

20.000

10.000

0

0 15 30

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Notes:

30

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Notes:

31

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Published byVinavil S.p.A.

Graphic design – LayoutPensieri e Colori Cooperativa Sociale

PhotosVinavil S.p.A. / Mapei S.p.A.

PrintingArti Grafiche Beta

Milan, March 2011

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www.vinavil.com

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