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SP Energy Technology Center
Development status for syngasfrom solid forest residues via
entrained flow gasification
Magnus Marklund
SP Energy Technology Center
2
My origin…
SP Energy Technology Center 3
A view on viable aspects for BtL processes
1. Scale of economy:
Very large plants are favorable, conversion principles needs to be up-scalable.
2. Fuel cost:
Processes that are less sensitive to impurities in low grade fuel will be most viable.
3. Future access to renewable carbon resources:
High energy efficiency, high carbon utilization, and accessible hydrogen will be competitive.
4. Product flexibility:
A system that can produce both electricity and liquid fuel will be advantageous.
5. Physical size of large commercial plants:
Ability to operate at high pressure will be favorable.
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General applications in gasification
40-45 % el, 45-50 % värme
25-30 % el, 50-60 % värme
35-40 % el
40-70 % energi
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General principle entrained flow gasification (EFG)
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SP ETC PEBG syngas pilot1 MW @10 bar(Operational)
MEVA Energy/PiteEnergi3 MW CHP
(Operational)
Solid Bio-EFG in Sweden 2016
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MEVA Energy/PiteEnergi development plant3 MW Hortlax, Piteå.
CycloneGasifier
Multistage cleaning• cyclone• gas cooling• RME scrubber• WESP
Cooperation on speciallydesigned gas engines with supplier Cummins Power Generation Ltd., UK.
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Pressurized Entrained flow Biomass Gasifier (PEBG)
• Owner: SP ETC, Piteå
• Contact: Fredrik Weiland
• 1.0 MWth (~200 kg/h), 10 bar, Oxygen blown
• Approx. 800 h of operation
• Daily operation (some long-term tests, 4 days)
• Wood, Peat, Bark, Forest residue, Lignin, Pyrolysis oil
• In-house (Design – Construction – Operation)
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Solid Bio-EFG (BtL) in Europe 2016
Pilot plants
“Commercial”
Bioliq BTL (in operation)
WoodSpirit (planned)
UPM Stracel (planned)
BioTFuel (planned)
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NER 300 Europe: Solid Bio-EFG
UPM Stracell* – Frankrike. FT. Status okänt,
AIOS BTL – Finland. FT. Avbrutet.
WoodSpirit – Nederländerna. Metanol. Status okänd.
Pyrogrot Billerud – Sverige. Pyrolysolja. Avbrutet
GoBiGas 2 – Sverige. SNG. Fas 1 pågår, fas 2?
1st Call
2nd Call
• Fast pyrolysis – Estland. Pyrolysolja. Status okänd
• CHP Biomass pyrolysis – Lettland. Pyrolysolja. Status okänd
• E.ON Bio2G – Sverige. SNG. Status ?
* “A final decision on whether or not the UPM Stracel BtL facility will proceed is reportedly pending, due to ongoing uncertainty over the regulatory environment for advanced biofuels in Europe. “ (http://biofuelstp.eu/btl.html)
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UDHE Prenflo PDQ gasifier pilot planned to be installed at the Dunkirk refinery of Total at a cost in excess of 100 M€ in ???
BIOTFUEL, FRANCE
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From Solid Biomass to clean Syngas
1. MAXimize process availability
2. MINimize the fuel pre-treatment requirements
3. MAXimize CGE with respect to considered application
4. MINimize soot and tar formation in reactor
5. MAXimize particulate separation from product gas
EFG Process Optimisation Criteria
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PEBG: project history
Start
April
2009
PFD
Nov
2009
Component
Design
February
2010
Assembly
May
2010
Control
System
December
2010
1st Heat up
April
2011
Pressurised
O2 gasification
October
2011
Process
R&D
August
2012
January
2014
Pressure
increase
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PEBG: Process Overview
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PEBG: Process Characterization
CO, H2, CH4, C2H4, C2H2
CO, H2
Weiland et al. Influence of process parameters on the performance of an oxygen blown entrained flow biomass gasifier, Fuel, vol. 153, p. 510-519, 2015.
SP Energy Technology Center Weiland et al. Extractive sampling of gas and particulates from the reactor core of an entrained flow biomass gasifier, submitted to Energy and Fuels, 2016.
PEBG: Extractive sampling from the reactor core
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PEBG: Formation of Particulates, Gasification
Wiinikka et al., Combust. Flame 161 (2014) 1923-1934Weiland et al., Aerosol Sci. Technol. 48 (2014) 1145-1155
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PEBG: Slagging ash
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Fas TRL Kännetecken för uppnådd nivå Exempel på den mognadsnivå som ska uppnås
Införande 9Produkt används med framgång
(verifierad produktanvändning)
Produkten har introducerats på marknaden och
tekniken har visat sig fungera i verklig
användning
8 Det komplett system är validerat
Test- och demonstrationsfasen är avslutad till
potentiella kunders belåtenhet. Tekniken har
funnit sin slutliga form, prestanda är bekräftade.
7 Demonstration i driftsmiljö
Tekniken har visat sig fungera i tester med
prototyp- eller demonstrationsfordon i verklig
driftsmiljö. Överlämning till produktutveckling.
6 Demonstration i relevant miljö
Systemet eller ett större delsystem har testats
under verklighetsliknande förhållanden (t ex på
provbana).
5Teknisk validering i relevant
miljö
Komponenter eller delsystem har testats under
verklighetsliknande förhållanden (t ex testrigg
eller testfordon). Teknikens livskraft verifierad.
4Teknisk validering i
laboratoriemiljö
Komponenter eller delsystem har testats.
Konceptets relation till andra system (t ex i ett
komplett fordon) har bestämts.
3Experimentella bevis på
konceptets potential föreligger
Analytiska eller experimentella studier har
genomförts. Karakteristiska drag hos tekniken är
kända.
2 Teknikkoncept formulerade
Möjliga applikationer har identifierats.
Grundläggande principer studeras. Förfinad
förutsägelse av prestanda.
Grund-
forskning1
Grundläggande principer
observerade
Vetenskapliga resultat finns som tyder på en
möjlig praktisk tillämpning. Prestanda kan
uppskattas.
Teknisk
forskning
Pilot- och
demon-
strator-
projekt
PEBG – TRL ”sawdust to raw syngas”
SP Energy Technology Center
Exemple: Survey SIA gasification/pyrolysis
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My summary for BtL from bio-EFG:
In general: High ambitions – low level of action
Big investment grants available via EU but not sufficient!
SEA: ”In long-term, BtL via EFG is of interets for Sweden”
Favorable market conditions and strong consortia needed for
demonstration and commercialisation!
Swedish competence is internationally competivite but lack solid
technology providers.
Further technology push efforts needed in order to be ”ready” when
market and actor timing is right.
SP Energy Technology Center
Tack för uppmärksamheten!
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SP Energy Technology Center
PEBG Publications
Weiland, F., Wiinikka, H., Hedman, H., Wennebro, J., Pettersson, E., Gebart, R. Influence of process parameters on the performance of an oxygen
blown entrained flow biomass gasifier. Fuel 153 (2015) 510-519.
Leijenhorst, E.J., Assink, D., van de Beld, L., Weiland, F., Wiinikka, H., Carlsson, P., Öhrman, O.G.W. Entrained Flow gasification of straw,- and wood-
derived pyrolysis oil in a pressurized oxygen blown gasifier. Biomass and Bioenergy 79 (2015) 166-176.
Carlsson, P., Ma, C., Molinder, R., Weiland, F., Wiinikka, H., Öhman, M., Öhrman, O. Slag formation during Oxygen Blown Entrained-Flow
Gasification of Stem Wood. Energy & Fuels 28 (2014) 6941-6952.
Weiland, F., Nilsson, P., Wiinikka, H., Gudmundsson, A., Gebart, R., Sanati, M. Online characterization of syngas particulates using aerosol mass
spectrometry in entrained-flow biomass gasification. Aerosol Science and Technology 48 (2014) 1145-1155.
Molinder, R., Öhrman, O.G.W. Characterization and cleanup of waste water from pressurized entrained flow biomass gasification. ACS Sustainable
Chemistry & Engineering 2 (2014) 2063-2069.
Andersson, J., Lundgren, J., Marklund, M., Methanol production via pressurized entrained flow biomass gasification – Techno-economic comparison
of integrated vs. stand-alone production. Biomass and Bioenergy 64 (2014) 256-268.
Weiland, F., Nordwaeger, M., Olofsson, I., Wiinikka, H., Nordin, A. Entrained flow gasification of torrefied wood residues. Fuel Processing
Technology 125 (2014) 51-58.
SP Energy Technology Center
PEBG Publications
Öhrman, O.G.W., Molinder, R., Weiland, F., Johansson, A.C. Analysis of trace compounds generated by pressurized oxygen blown entrained flow
biomass gasification. Environmental Progress & Sustainable Energy 33 (2014) 699-705.
Wiinikka, H., Weiland, F., Pettersson, E., Öhrman, O., Carlsson, P., Stjernberg, J. Characterisation of submicron particles produced during oxygen
blown entrained flow gasification of biomass. Combustion and Flame 161 (2014) 1923-1934.
Ma, C., Weiland, F., Hedman, H., Boström, D., Backman, R., Öhman, M., Characterization of Reactor Ash Deposits from Pilot-Scale Pressurized
Entrained-Flow Gasification of Woody Biomass. Energy & Fuels 27 (2013) 6801-6814.
Öhrman, O.G.W., Weiland, F., Pettersson, E., Johansson, A.C., Hedman, H., Pedersen, M. Pressurized Oxygen Blown Entrained Flow Gasification of a
Biorefinery Lignin Residue. Fuel Processing Technology 115 (2013) 130-138.
Weiland, F., Hedman, H., Marklund, M., Wiinikka, H., Öhrman, O., Gebart, R. Pressurized oxygen blown entrained-flow gasification of wood powder.
Energy & Fuels 27 (2013) 932-941.