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Development of Drinking Water Quality Standards in Jordan Dr. Muna Hindiyeh Water & Environmental Engineering Water and Wastewater Microbiology Amman/Jordan Email: [email protected]

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Development of Drinking Water Quality Standards in Jordan

Dr. Muna Hindiyeh Water & Environmental Engineering Water and Wastewater Microbiology

Amman/Jordan Email: [email protected]

WHO Guidelines and National Standards for Drinking Water Quality

• The evolution of directives and regulations

related to public health matters is not controlled

only by toxicological or epidemiological findings.

· Economic interest,

· Socio-cultural characteristics,

· Hygiene practices,

· Public awareness and

. Sensitivity and technological development

The purpose of developing regulations

To establish limits related to specific practices, which will minimize detrimental effects without affecting the benefits.

These limits have no absolute value, nor can they be definitely established. They will vary with scientific development, economic constraints and status as well as with the changing tendencies towards acceptance or rejection of practices affecting the cultural values of a society.

• Background and guidance to governments for making

risk management decisions related to the protection of

public health and to the preservation of the environment;

also

• Provide common background on which national or

regional standards can be derived.

• They have an advisory nature based on the

state-of-the-art in scientific research and

epidemiological findings and are not to be confused with

legal standards.

WHO guidelines produced to provide :

It must be stressed that guidelines are not intended for absolute

and direct application in every country.

National Standards: are guidelines fixed by law in countries

after being adapted to their national priorities and taking into

account their:

· Economic

· Technical,

· Social

· Cultural, and

. Political situation.

At any time they can be changed or modified whenever new

scientific evidence becomes available.

• An epidemiological study conducted in Sudan did not reveal

any harmful effects at concentrations of nitrate as high as

226 mg/l.

• Sudanese children depend highly on breast feeding for a

minimum period of 18 months, and later on cows and goats

milk. This specific cultural custom of the country, added into

consideration that nitrate can only be removed by costly ion

exchange systems, led the Sudanese authorities to choose a

standard value of 50 mg/l (as N), While WHO has proposed

a guideline value of 10 mg/l (as N) for nitrate in drinking

water.

There is no evidence of adverse physiological reactions at

high levels of TDS, but water becomes unpalatable and may

lead to corrosion or incrustation in water distribution

systems. For this reason the WHO guideline value for TDS

was set at a limit of 1000 mg/l.

However, due to difficulties in finding sources with lower

salinity and the difficulties associated with desalination

systems, the Sudanese authorities adopted standard value of

5000 mg/l of TDS, the maximum level above which water

becomes undrinkable.

Jordan has also followed the same criteria for establishing

Drinking Water Quality Standards. Several parameters {such

as nitrate, sulphate, sodium, chloride, mercury, nickel,

barium, boron, zinc, manganese and iron (JS 286/2001)}

have been given numerical values above the guideline values

prescribed by WHO (1998).

JS 286/2008: Ba, B, Ni, Endrin, 2,4-D, DDT, and Xylene

have been given numerical values above the guideline values

prescribed by WHO (2004).

But unfortunately without conducting any scientific research

and/or epidemiological study concerning risk affecting

health.

Jordanian Drinking Water Quality Standard DW Quality

No. Parameter Unit 286/2001 WHO Guidelines 1997

max. allowable limit max. allowable limit in

case of no other better

source is available

1 NO3 mg/l 50 70 50

2 SO4 mg/l 200 500 250

3 Cl mg/l 200 500 250

4 Na mg/l 200 400 200

5 Fe mg/l 0.3 1.0 0.3

6 B mg/l 2.0 2.0 0.3

7 Mn mg/l 0.1 0.2 0.1

8 Zn mg/l 3 5 3

9 Ni mg/l 0.07 - 0.02

10 Ba mg/l 1.5 - 0.7

11 Hg mg/l 0.002 - 0.001

12 Fungus Count/

100 ml

Dropped out Taste & odor

13 Algae Count Dropped out Taste & odor

Evolution of Jordanian drinking water quality standards 286/ 1982, 1988, 1997 and 2001

Parameter 1982 1988 1990* 1997* 2001

Max. allowable limit

Coliform count /100 ml 10 < 2.2 < 2.2 < 1.1 < 1.1

Thermotolerant coliform count/100

ml

Zero Zero Zero Zero Zero

Free-living organisms

Algae

Fungus

-

-

-

Zero

Zero

Zero

Zero

Zero

Zero

Zero

Zero

Zero

1 alive nematode

-

-

Intestinal nematode - Zero Zero Zero Zero

Pathogenic Protozoa - Zero Zero Zero Zero

THBC / 1 ml 99 1000 1000 - -

NO3 mg/l 15-40 45-50 45-70 50-70 50-70

NO2 mg/l - - - 2 2

Ni mg/l 0.05-0.1 0.05-0.1 0.05-0.1 0.02 0.07

Cd mg/l 0.01 0.005 0.005 0.003 0.003

Pb mg/l 0.05 0.05 0.05 0.01 0.01

As mg/l 0.05 0.05 0.05 0.01 0.01

Hg mg/l 0.005 0.001 0.001 0.002 0.002

CN mg/l 0.02 0.1 0.1 0.07 0.07

THM mg/l - - - 0.15 0.15

* If coliform count only detected, then fecal streptococcus and clostridium has to be tested.

- not mentioned or dropped out

On the other hand, many industrialized countries, increasingly

concerned by risks affecting health, have adopted national standards

for drinking water quality which are more restrictive than WHO

guidelines.

Since they can afford advanced treatment systems as well as

sophisticated laboratories for monitoring and surveillance.

In Jordan Standard for Drinking Water Quality (286/2008) also

showed more restrictive limits than WHO guideline only for

aluminium, antimony, manganese, nitrite and copper.

National Standards

Comparisons & Contradictions

• Updating Jordanian Standard (JS 286/2008) for Drinking Water Quality had been done 6 times within 26 years (established during 1982, and updated in 1988, 1990, 1997, 2001, and 2008).

• While Jordanian Standard (JS 200/1987) for natural mineral water established in 1987, had been updated two times only 2001 and 2009. Contradictions in the limit values for several parameters between both standards were shown in the following table, which seem that drinking water quality standard more restrictive than the natural mineral water standard were infants, elderly people and patients depend on it for drinking.

No. Parameter Unit Jordanian

DW Quality

Standard

286/2001

DW Quality

WHO

Guidelines

1997

Jordanian

Natural

Mineral

Waters

Standards

200/1987

Jordanian Natural

Mineral Waters

Standards 200/2001

1 NO3 mg/l 50-70 50 45 45

2 Mn mg/l 0.1-0.2 0.1 2.0 0.1

3 Ni mg/l 0.07 0.02 - 0.02

4 As mg/l 0.01 0.01 0.05 0.01

5 Pb mg/l 0.01 0.01 0.05 0.01

6 Cd mg/l 0.003 0.003 0.01 0.003

7 Ba mg/l 1.5 0.7 1.0 1.0

8 Zn mg/l 3-5 3.0 5.0 -

9 CN mg/l 0.07 0.07 0.01 0.05

10 B mg/l 2 0.3 0.3 5

11 Free living

Nematodes

Count/l 1 alive Should be

Absent

- -

Mineral Water JS 200/2009

WHO Drinking Water Quality

2011

WHO Drinking Water Quality

2004

Jordanian Drinking Water

JS 286/2008

Parameter

˃ 1000 - 600-1000 1000 TDS

- - 500 500 TH

- - - 0.2 MBAS

- - - 0.2 NH4

- - 0.1-0.2 0.1 Al

- - - 1.0 Fe

- - 3.0 4.0 Zn

- - 200 200 Na

- - 250 500 Cl

˃ 600 - 250 500 SO4

5 2.4 0.5 1.0 B

0.5 - 0.4 0.1 Mn

- - 0.07 0.07 Mo

50 50 50 50 NO3

There are no limits assigned for Organic pollutants as DDT, Lindane, Endrin, ..etc, and Disinfectant by products as THM’s in the JS Mineral Water 200/2009 and Desalinated Water 1528/2010.

Jordanian Drinking Water JS 286/2008

Mineral Water JS 200/2009

Bottled Water JS 1214/2009

Parameter (mg/l)

500 - - TH

0.2 - - NH4

500 - - Cl

1.0 5 0.3 B

500 ˃ 600 100 SO4

0.07 - - Mo

50 50 15 NO3

0.01

0.01 0.05 Se

0.001 0.001 0.002 Hg

0.15 - 0.035 THM

Organic Pollutants (µg/l)

Jordanian Drinking Water

JS 286/2008

WHO Drinking Water Quality

2004

Mineral Water JS 200/2009

Bottled Water JS 1214/2009

Parameter

2.0 0.6 - 2.0 Endrin

90 30 - 90 2, 4 D

2.0 1.0 - 2.0 DDT

700 500 - 700 Xylene

10 10 - 10 Benzene

There are no limits assigned for alpha (α) and (β) radiation in the JS Bottled Water 1214/2009 and Desalinated Water 1528/2010.

While Tap and Mineral drinking water standards for

• alpha (α) = 0.5 Bq/l

• (β) radiation= 1 Bq/l

Microbiological standards for Water And Foods

• Practitioners in the water industry are familiar with the bacteriological requirements but not really with those for foods.

• European directives govern the bacteriological quality of most food, and many practioners who were brought up with zero coliform per 100 ml of drinking water would be surprised by the apparent laxity of microbiological standards for foods.

European Standards

• EC Minced Meat Directives: – Minced meat: 150 000 E. coli per 100 gram.

– Meat preparations: 1 500 000 E. coli per 100 gram.

• EC Milk Directive 92/46/EEC: – Soft cheese : 10 000 000 Total coliform per 100 gram.

– Hard cheese: 10 000 000 E. coli per 100 gram.

– Ice cream 10 000 Total coliform per 100 gram.

Drinking Water Quality and Food Standards

Whilst in the subject of food, the coliform and fecal coliform

counts that permissible in the FAO Standards (1992) were very high comparing with absence in drinking water.

Beyond doubt, the presence of such type of bacteria in water or food samples means its subject to faecal pollution; and that, as a result, it may contain bacterial and/or other pathogens which might initiate disease in anyone consume it.

The permissible values for coliform counts in 100 g

of food that allowed for human consumption as

follows:

Dried milk 10 000

Pasteurized liquid, frozen and

dried egg products 100 000

Coated or filled dried

shelf stable biscuits 100

The following food is allowed for human consumption with fecal

coliform counts per 100 g as follows:

Frozen vegetables and fruits 100 000

Dried vegetables 100 000

Cooked, chilled and

frozen fish, crab etc. 50 000

In the Jordanian Standards the coliform counts per 100 g are

permissible for certain type of foods as follows:

Infants milk and food (JS 472/1989, 2003, 2008) 1000

Pasteurized milk (JS 538/1987, 2003) 1000

Cream (JS430/1985, 2001, 2010) 1000

Milk and Cream powder (JS 121, 2008) 1000

Breast Feeding

JS 25 and 24/2009 for Cucumber and Tomato respectively no limits had been specified for coliform counts. No Jordanian Standards for Lettuce.

“New Jordanian Regualtions for Ready-to-eat food”

- JFDA (2011) Ready-to-eat foods are of “acceptable” quality if they contain:

˂ 100 E. coli per gram (i.e. ˂ 104 per 100 gram).

So absence of coliform per 100 ml of drinking water is fine, and

1000 coliform per 100 g of infant food is just acceptable too.

Suddenly, irrigating lettuces or radishes with water containing 1000

fecal coliform per 100 ml doesn’t seem so dreadful.

We actually live in an invisible “sea” of coliform- they are literally

everywhere: finger-tips are a good place to find them.

Conclusion

National drinking water quality standards are expected to meet WHO Guidelines as closely as possible.

However, if local conditions do not allow for the adoption of the recommended numeric values, alternative control measures should be undertaken to avoid the development of adverse health effects.

Thank you

Muna Hindiyeh

[email protected]

www.gju.edu.jo