descriptive inorganic chemistry (rayner-canham, geoff)

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Chemical Education Today JChemEd.chem.wisc.edu Vol. 75 No. 6 June 1998 Journal of Chemical Education 697 Descriptive Inorganic Chemistry Geoff Rayner-Canham. W. H. Freeman: New York, 1996. 492 pp. ISBN: 0-7167-2819-2. $67.95. There are plenty of good inorganic chemistry books on the market, from venerable reference works (e.g., Cotton and Wilkinson’s Advanced Inorganic Chemistry , Greenwood and Earnshaw’s Chemistry of the Elements) to “comprehensive” two-semester textbooks (e.g., Huheey, Keiter, and Keiter’s Inorganic Chemistry: Principles of Structure and Reactivity, Douglas, McDaniel, and Alexander’s Concepts and Models of Inorganic Chemistry). Undergraduate students, especially those new to inorganic chemistry, frequently find these books overwhelming in depth and length (not to mention weight!). Alternatively, some shorter books with less ambitious goals present an oversimplified view of the field or sacrifice concep- tual material on behalf of sections on environmental, industrial, or biological chemistry. Rayner-Canham’s Descriptive Inor- ganic Chemistry, a one-semester book aimed specifically at the introductory (sophomore) level, provides an excellent balance of theory and descriptive material, with a fresh look at tradi- tional and current areas of interest in inorganic chemistry. The first nine chapters (of a total of 21) concisely present the fundamental concepts in inorganic chemistry with unusually clear text, examples, and illustrations. Included are chapters on covalent, metallic, and ionic bonding, thermo- dynamics, acids and bases, and redox reactions. The rest of the book deals separately with each group or block of the periodic table. Interesting historic notes and anecdotes and important biological aspects of the elements discussed are in- cluded in each of these chapters. Most entertaining, a number of current topics in inorganic chemistry, from “bond-stretch isomers” and platinum anticancer drugs to the chemistry of book preservation, are included in a few “boxed” paragraphs throughout the book. Each chapter concludes with a number of exercises, typically between 20 and 30, for which the inclusion of solutions would have been desirable despite the necessary increase in page count. After using the textbook for a semester, I have found very few factual errors in it; for example, the density of air is given as 2.8 g L {1 instead of 1.293 g L {1 (p 375). Even minor typographical errors, almost unavoidable in any first edition, are also scarce: anthoquinone for anthraquinone (p 321), Moisson in lieu of Moissan (p 351), or Hindenberg instead of Hindenburg (p 376). The display of a modern periodic table on one of the inside covers, featured in many (if not most) modern inorganic chemistry textbooks, would have been a plus. Nevertheless, Rayner-Canham’s is, overall, one of the most readable inorganic chemistry textbooks I have ever seen and I enthusiastically recommend it, especially as an introductory book to the field. Daniel Rabinovich Department of Chemistry The University of North Carolina at Charlotte Charlotte, NC 28223 [email protected]

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Page 1: Descriptive Inorganic Chemistry (Rayner-Canham, Geoff)

Chemical Education Today

JChemEd.chem.wisc.edu • Vol. 75 No. 6 June 1998 • Journal of Chemical Education 697

Descriptive Inorganic Chemistry

Geoff Rayner-Canham. W. H. Freeman: New York, 1996.492 pp. ISBN: 0-7167-2819-2. $67.95.

There are plenty of good inorganic chemistry books onthe market, from venerable reference works (e.g., Cotton andWilkinson’s Advanced Inorganic Chemistry, Greenwood andEarnshaw’s Chemistry of the Elements) to “comprehensive”two-semester textbooks (e.g., Huheey, Keiter, and Keiter’sInorganic Chemistry: Principles of Structure and Reactivity,Douglas, McDaniel, and Alexander’s Concepts and Models ofInorganic Chemistry). Undergraduate students, especially thosenew to inorganic chemistry, frequently find these booksoverwhelming in depth and length (not to mention weight!).Alternatively, some shorter books with less ambitious goalspresent an oversimplified view of the field or sacrifice concep-tual material on behalf of sections on environmental, industrial,or biological chemistry. Rayner-Canham’s Descriptive Inor-ganic Chemistry, a one-semester book aimed specifically at theintroductory (sophomore) level, provides an excellent balanceof theory and descriptive material, with a fresh look at tradi-tional and current areas of interest in inorganic chemistry.

The first nine chapters (of a total of 21) conciselypresent the fundamental concepts in inorganic chemistrywith unusually clear text, examples, and illustrations. Includedare chapters on covalent, metallic, and ionic bonding, thermo-dynamics, acids and bases, and redox reactions. The rest ofthe book deals separately with each group or block of the

periodic table. Interesting historic notes and anecdotes andimportant biological aspects of the elements discussed are in-cluded in each of these chapters. Most entertaining, a numberof current topics in inorganic chemistry, from “bond-stretchisomers” and platinum anticancer drugs to the chemistry ofbook preservation, are included in a few “boxed” paragraphsthroughout the book. Each chapter concludes with a numberof exercises, typically between 20 and 30, for which theinclusion of solutions would have been desirable despite thenecessary increase in page count.

After using the textbook for a semester, I have foundvery few factual errors in it; for example, the density of air isgiven as 2.8 g L{1 instead of 1.293 g L{1 (p 375). Even minortypographical errors, almost unavoidable in any first edition,are also scarce: anthoquinone for anthraquinone (p 321),Moisson in lieu of Moissan (p 351), or Hindenberg insteadof Hindenburg (p 376). The display of a modern periodictable on one of the inside covers, featured in many (if notmost) modern inorganic chemistry textbooks, would havebeen a plus. Nevertheless, Rayner-Canham’s is, overall, oneof the most readable inorganic chemistry textbooks I haveever seen and I enthusiastically recommend it, especially asan introductory book to the field.

Daniel RabinovichDepartment of ChemistryThe University of North Carolina at CharlotteCharlotte, NC [email protected]