data on chlorofluorocarbons (cc13f and cclf^ as dating tools

60
DATA ON CHLOROFLUOROCARBONS (CC13F and CCLF^ AS DATING TOOLS AND HYDROLOGIC TRACERS IN SHALLOW GROUND WATER OF THE DELMARVA PENINSULA By L.N. Plummer, S.A. Dunkle, and Eurybiades Busenberg U.S. GEOLOGICAL SURVEY Open-File Report 93-484 Reston, Virginia 1993

Upload: others

Post on 03-Feb-2022

3 views

Category:

Documents


0 download

TRANSCRIPT

DATA ON CHLOROFLUOROCARBONS (CC13F and CCLF^ AS

DATING TOOLS AND HYDROLOGIC TRACERS IN SHALLOW

GROUND WATER OF THE DELMARVA PENINSULA

By L.N. Plummer, S.A. Dunkle, and Eurybiades Busenberg

U.S. GEOLOGICAL SURVEY

Open-File Report 93-484

Reston, Virginia

1993

U.S. DEPARTMENT OF THE INTERIOR

BRUCE BABBITT, Secretary

U.S. GEOLOGICAL SURVEY

Robert M. Hirsch, Acting Director

For additional information write to:

Chief, Branch of Regional ResearchEastern RegionU.S. Geological Survey432 National Center12201 Sunrise Valley DriveReston, Virginia 22092

Copies of this report can be purchased from:

U.S. Geological SurveyBooks and Open-File Reports SectionFederal Center, Bldg. 810P.O. Box 25425Denver, Colorado 80225

CONTENTS

Abstract ...................................................................................... 1Introduction ................................................................................ 1Data on chlorofluorocarbon concentrations ............................................ 2References ................................................................................... 5Appendix A. Summary of well-construction and water-quality data ........... 7

B. Summary of chlorofluorocarbon data ............................... 39

ILLUSTRATIONS

Figure 1. Map showing the location of the study area, local-scale networks,and wells on regional transects ............................................. 3

m

CONVERSION FACTORS, VERTICAL DATUM, AND ABBREVIATED WATER-QUALITY UNITS

Multiply

foot (ft) gallon (gal)

gallon per minute (gal/min) inch (in)

mile (mi) tritium unit (TU) tritium unit (TU)

By0.3048 3.785 0.06309 2.540 1.609 3.24xlO' 15 3.24

To obtain

meter (m) liter (1) liter per second (1/s) centimeter (cm) kilometer (km) curies per milliliter (Ci/ml) picocuries per liter (pCi/L)

Temperature in degree Fahrenheit (°F) can be converted to degree Celsius (°C) as follows:

°C=(°F-32)/1.8

Temperature in degree Celsius (°C) can be converted to degree Fahrenheit (°F) as follows:

°F = 1.8°C + 32

The following terms and abbreviations are also used in this report:

centimeter (cm)milligram per liter (mg/1)picogram per kilogram (pg/kg)tritium unit (TU)parts per trillion volume (pptv)microsiemens per cm (uS/cm)tritium atoms per 10 18 hydrogen atoms (TU)cubic centimeter per second (cm3/s)

Sea level: In this report "sea level" refers to the National Geodetic Vertical Datum of 1929 (NGVD of 1929) a geodetic datum derived from a general adjustment of the first-order level nets of both the United States and Canada, formerly called Sea Level Datum of 1929.

IV

DATA ON CHLOROFLUOROCARBONS (CC13F and CCl^ AS DATINGTOOLS AND HYDROLOGIC TRACERS IN SHALLOW GROUND

WATER OF THE DELMARVA PENINSULA

L.N. Plummer, S.A. Dunkle, and Eurybiades Busenberg

ABSTRACT

Data on concentrations of two chlorofluorocarbons (CFC's; CC13F and CC12F2), tritium, and oxygen-18 and deuterium stable-isotope composition; pH; water temperature; dissolved oxygen (DO); and specific conductance are reported for ground water from 109 shallow wells in sediments of the Delaware-Maryland-Virginia (Delmarva) Peninsula of the mid-Atlantic Coastal Plain. The shallow piezometers were sampled during May 1989 - December 1992, and are part of a network of monitoring wells established by the U.S. Geological Survey's National Water Quality Assessment Program. pH, DO concentration, specific conductance, and temperature were measured at the sampling site. Water samples collected for CFC analysis were flame-sealed into 62 milliliter borosilicate-glass ampules in the field and returned to the laboratory for analysis. The data on the chemical, isotopic, and chlorofluorocarbon composition of Delmarva ground water are tabulated in two appendixes. Recharge ages are assigned to each water sample and tabulated for each well sampled. The data are being used to evaluate the reliability and utility of CFC's as age-dating tools for shallow ground water.

INTRODUCTION

Chlorofluorocarbons are stable synthetic compounds that have been used in age-dating and tracing ground water (Randall and Schultz, 1976; Thompson and Hayes, 1979; Busenberg and Plummer, 1991, p. 542-547; Busenberg and Plummer, 1992; Busenberg and others, 1993; Plummer and others, 1993). The introduction of a sampling procedure for the collection and storage of water samples in borosilicate-glass ampules without contact with air (Busenberg and Plummer, 1991; Busenberg and Plummer, 1992) has facilitated age-dating of ground water using CFC's in a variety of environments. Busenberg and others (1993) evaluate the CFC age-dating method for ground water and unsaturated-zone air in the Snake River Plain Aquifer at the Idaho National Engineering Laboratory, Idaho. Plummer and others (1993) summarize the CFC age-dating method, evaluate the effects of hydrodynamic dispersion, and compare CFC age-dating to dating methods incorporating other environmental tracers. Dunkle and others (1993) apply CFC age-dating to shallow ground water of the Delmarva Peninsula, mid-Atlantic Coastal Plain.

This report presents data on concentrations of two chlorofluorocarbons (CFC's; CC12F, hereafter referred to as CFC-11, and CC12F2 , hereafter referred to as CFC-12) and other chemical, isotopic and hydrologic data for ground water collected from shallow coastal plain sands on the Delaware-Maryland-Virginia (Delmarva) Peninsula of the mid-Atlantic Coastal Plain. The data are discussed and interpreted in a companion report (Dunkle and others,

1993). The data were collected during May 1989 - December 1992, as part of a study being conducted by the U.S. Geological Survey to investigate applications of CFC's as tools for age-dating ground water.

DATA ON CHLOROFLUOROCARBON CONCENTRATIONS

The wells sampled were selected from a monitoring network established by the U.S. Geological Survey as part of its National Water Quality Assessment (NAWQA) Program. With few exceptions (see Dunkle and others, 1993), the wells are 5.08-cm (2-inch inside diameter (i.d.)) polyvinyl chloride (PVC) piezometers with 0.91-m (3-ft-long) screened intervals at the bottom. The location of wells on regional transects and the location of local-scale networks sampled in this study are shown in figure 1. Further details of well construction are given in Dunkle and others (1993).

Appendix A includes the assigned well number, name, local identifier, latitude, and longitude; the date of sampling; the formation sampled; a generalized classification of the hydrogeologic environment (as either recharge zone, discharge zone, confined aquifer, or location in an area of low hydraulic gradient) (see Dunkle and others, 1993, for criteria used to classify hydrogeologic environments); altitude of the land surface; depth to top and bottom of the screened interval; depth to water; time when well purging began; concentrations of tritium (3H, in tritium units, TU's, and reported for the date of sampling); stable isotope compositions of O and H (in per mil relative to Vienna Standard Mean Ocean Water (VSMOW) and compositions normalized on scales such that the O and H isotopic compositions of Standard Light Antartic Precipitation (SLAP) are -55.5 (d 18O) and -428 (dD) per mil, respectively (Coplen, 1988)); purging times corresponding to field measurements of water temperature, pH, dissolved oxygen concentration (DO, in milligrams per liter); and specific conductance (in microsiemens per centimeter (uS/cm) at 25 degrees Celsius).

The duration of well purging was at least that required to remove three well volumes prior to sampling (typically 20 to 40 minutes). Water samples were collected by means of a helical-rotor submersible pump (Keck1) with a 1.3-cm (0.5-inch i.d.) Teflon discharge line at pumping rates of approximately 20 to 80 cm3/s. Typically the wells were purged with the pump positioned 1 to 2 m above the screened interval. Stability in the field-recorded properties pH, temperature, DO, and specific conductance was also used to determine purging times prior to the start of CFC sampling. After purging was completed, the pump was lowered into the screened interval for sampling.

A total of 109 wells were sampled for CFC's (Appendix B). Multiple samples were collected for CFC analysis (typically six samples) during each well sampling. Many of the wells were sampled in the fall of 1991 and in the spring of 1992. Some wells were sampled on four separate occasions. Each water sample was flame-sealed into a borosilicate-glass ampule

1 The use of brand names in this report is for identification purposes only and does not constitute endorsement by the U.S. Geological Survey.

76° 75°

39'

TRANSECT A

TRANSECT]

TRANSECT

38'

nch

Delmarva Peninsula

TRANSECT D

.._.._..JEN NSY LVA NJA._..^ .. c ... ., ,.'-N,, MARYLAND ,. Jj» NEW

A--' \ _ f^SB JERSEY

TRANSECT ETown send

10 0 10 20 MILES

10 0 10 20 KILOMETERS

Figure 1. Map showing the location of the study area, the local-scale networks, and the wells on the transects. Well numbers are from Appendix A and B.

and returned to the U.S. Geological Survey Chlorofluorocarbon Laboratory in Reston, Virginia, for analysis. CFC data for selected surface waters on Delmarva are included in Appendix B (samples 110-116).

Appendix B lists measured concentrations of CFC-11 and CFC-12 in each sealed ampule, in picograms per kilogram of solution (pg/kg), for each sampling time at each well. Busenberg and Plummer (1992) describe the sampling and analytical procedures. Appendix B also includes the calculated atmospheric CFC concentration that would exist in equilibrium with the analyzed concentration in the ground water at the recharge temperature. The recharge temperatures used to calculate the equilibrium partial pressures of CFC's were 9°C for wells 1-97 and 14°C for wells 98-109 (Dunkle and others, 1993). The water temperatures used for surface water samples 110 to 116 are given in Dunkle and others (1993) where additional information on the method of calculation of recharge age also is given. Appendix B also gives the modeled CFC-based recharge dates resolved to the nearest 0.5 years for CFC-11 and CFC-12 for each water sample (ampule) and a summary for CFC-11 and CFC-12 analyses of all samples for the sampling date; the appendix lists the average Julian recharge date, the average water age, and the standard deviation of water age, in years, as reported in Dunkle and others (1993).

The CFC-based ages are referenced to the National Oceanographic and Atmospheric Administration (NOAA) atmospheric air scale for air sampled at Niwot Ridge, Colorado (Elkins and others 1993). The atmospheric concentrations of CFC's used to calculate water ages are given in Busenberg and others (1993) and Dunkle and others (1993). The reader is referred to Hamilton, Shedlock and Phillips (1989), Hamilton and Shedlock (1992), and Shedlock and others (1993) for information on the Delmarva Peninsula study area, and to Dunkle and others (1993) for discussion of the results of the CFC dating of Delmarva ground water.

Dashed lines in Appendix B indicate that the concentrations of CFC-11 or CFC-12 were below the detection limit of 1 pg/kg, or that the CFC-11 or CFC-12 peak on the chromatogram could not be separated from another peak such as that of N2O. The assigned age is determined for the remaining samples according to procedures given in Busenberg and Plummer (1992) and Dunkle and others (1993). The wells sampled in 1989 show extreme variations because of the infancy of the dating technique at the time they were collected. Samples were also contaminated with CFC-11 that was introduced from the Tygon tubing used in the sampling equipment at the time. For these wells, the analyses were not averaged, but the oldest age obtained for any sample was chosen as the assigned age; this oldest age represents a minimum age. Some ages appear to be more uncertain compared to other ages of water samples from a particular well; however, there is no obvious basis to discard these uncertain ages, which, although retained in the data base, were not included in obtaining the averaged assigned ages (Appendix B). Dunkle and others (1993) discuss the criteria used in assigning recharge ages for the Delmarva waters.

REFERENCES

Busenberg, E., and Plummer, L.N., 1991, Chlorofluoromethanes (CC13F and CCLjFj): Use as an Age-Dating Tool and Hydrologic Tracer in Shallow Groundwater Systems, in Mallard, G.E., and Aronson, D.A., eds., U.S. Geological Survey Toxic Substances Hydrology Program Proceedings of the Technical Meeting, Monterey, California, March 11-15, 1991: U.S. Geological Survey Water-Resources Investigations Report 91-4034, 730 P-

Busenberg, E., and Plummer, L.N., 1992, Use of Chlorofluoromethanes (CC13F and CC^F^ as Hydrologic Tracers amd Age-Dating Tools: Example- The Alluvium and Terrace System of Central Oklahoma: Water Resources Research, v. 28, p. 2257-2283.

Busenberg, E., Weeks, E.P., Plummer, L.N., and Bartholomay, R.C., 1993, Age Dating Ground Water by Use of Chlorofiuorocarbons (CC13F and CCl^), and Distribution of Chlorofiuorocarbons in the Unsaturated Zone, Snake River Plain Aquifer, Idaho National Engineering Laboratory, Idaho: U.S. Geological Survey Water-Resources Investigations Report 93-4054, 47 p.

Coplen, T.B., 1988, Normalization of Oxygen and Hydrogen Isotope Data: Chemical Geology (Isotope Geoscience Section), v. 72, p. 293-297.

Dunkle, S.A., Plummer, L.N., Busenberg, E., Phillips, P.J., Denver, J.M., Hamilton, P.A., Michel, R.L., and Coplen, T.B., 1993, Chlorofiuorocarbons (CC1,F and CC^F^ as Dating Tools and Hydrologic Tracers in Shallow Ground Water of the Delmarva Peninsula, Atlantic Coastal Plain, United States: Water Resources Research, v. 29, no. 12, p. 3837-3860.

Elkins, J.W., Thompson, T.M., Swanson, T.H., Butler, J.H., Hall, B.D., Cummings, S.O., Fisher, D.A., and Roffo, A.G., 1993, Decrease in the growth rates of atmospheric Chlorofiuorocarbons 11 and 12: Nature, v. 364, p. 780-783.

Hamilton, P.A., Shedlock, R.J., and Phillips, P.J., 1989, Ground-Water-Quality Assessment of the Delmarva Peninsula, Delaware, Maryland, and Virginia Analysis of Available Water-Quality Data Through 1987: U.S. Geological Survey Open-File Report 89-34, 71 p.

Hamilton, P.A., and Shedlock, R.J., 1992, Are Fertilizers and Pesticides in Ground Water? A Case Study of the Delmarva Peninsula, Delaware, Maryland, and Virginia: U.S. Geological Survey Circular 1080, 16 p.

Plummer, L.N., Michel, R.L., Thurman, E.M., and Glynn, P.O., 1993, Environmental Tracers for Age-Dating Young Ground Water, in Alley, W.M., ed., Regional Ground-Water Quality, New York, Van Nostrand Reinhold, p. 255-294.

Randall, J.H., and Shultz, T.R., 1976, Chlorofiuorocarbons as Hydrologic Tracers, A New Technology: Hydrology and Water Resources in Arizona and the Southwest, v. 6, p. 189-195.

Shedlock, R.J., Hamilton, P.A., Denver, J.M., and Phillips, P.J., 1993, Muitiscale Approach to Regional Ground-Water-Quality Assessment of the Delmarva Peninsula, in Alley, W.M., ed., Regional Ground-Water Quality, New York, Van Nostrand Reinhold, p. 563-587.

Thompson, G.M., and Hayes, J.M., 1979, Trichlorofluoromethane in Groundwater- A Possible Tracer and Indicator of Groundwater Age: Water Resources Research, v. 15, no. 3, p. 546-554.

App

endi

x A

. -S

umm

ary

of w

ell c

onst

ruct

ion

and

wa te

r qua

lity

da ta

[Typ

e: I

, ind

ivid

ual w

ell;

C, w

ell c

lust

er;

Form

atio

n: A

l, A

lluvi

um; A

q, A

quia

; BS

, Bea

vert

on S

and;

Ch,

Che

sape

ake;

JN

, Jon

es K

eck;

KI,

Ken

t Is

land

; Ma,

Man

okin

; N

a, N

assa

wad

ox;

Om

, Om

ar; F

a, F

arso

nbu

rg; F

e, P

enns

auke

n; S

i, Si

nepu

xent

; W

a, W

acha

prea

gue;

Yo,

Yor

ktow

n; h

ydro

geol

ogic

set

ting:

C, c

onfin

ed;

D, d

isch

arge

zon

e; L

G, l

ow h

ydra

ulic

gra

dien

t;

R, r

echa

rge

zone

; el

evat

ions

and

dep

ths

in m

eter

s ab

ove

sea

leve

l dat

um;

TU

, tri

tium

con

cent

ratio

n in

tri

tmm

uni

ts;

Del

ta O

18, o

xyge

n 1

8 in

per

mil;

Del

ta D

, deu

teri

um in

per

mil;

DO

, dis

solv

ed o

xyge

n in

mill

igra

ms p

er li

ter;

C, t

empe

ratu

re i

n de

gree

s C

elsi

us; s

peci

fic c

ondu

ctan

ce i

n m

icro

siem

ens

per

cent

imet

er a

t 25

degr

ees

Cel

sius

]

Form

atio

n Tr

itium

Ti

me

Sam

plin

g or

grou

p;

Alti

tude

T

op

Bot

tom

Dep

th

Pum

p Tr

itium

on

e of

T

emp-

W

ell

Wel

l Lo

cal

date

hy

drog

eolo

gic

of la

nd

of

of

to

start

conc

en-

*d.

Del

ta

Del

ta

mea

s-

erat

ure

no.

nam

e id

entif

ier

Type

La

titud

e Lo

ngitu

de

(moW

yr)

letii

ng

surfa

ce

scre

en

scre

en

wat

er

time

tratio

n de

v.

O-1

8 D

ur

emer

t C

TR

AN

SE

CT

A1

KeC

c28

KE

401

I 39

1028

76

0853

10

/29/

90

AqR

9.

14

14.8

15

.7

1635

2.

74

0.19

-7

.30

-42.

0 17

0317

0817

1317

1817

2317

2817

332

KE

Bd3

9 K

E40

4 I

3916

45

7603

50

10/2

9/90

A

qR

22.8

6 10

.8

11.7

4.6

6 15

02

40.2

0 1.

50

-8.0

5 -4

9.5

1517

1522

1527

1532

1542

1547

1552

1557

3 H

dl5-

07

NC

204

I 39

1938

75

4014

10

/30/

90

PeR

20

.73

5.5

6.4

835

19.4

0 0.

70

-73

5

-42.

5 85

590

090

791

291

792

292

793

293

794

094

294

54

Hdl

4-01

N

C10

5 I

3918

04

7530

51

10/3

0/90

P

eR

4.57

7.

7 8.

6 1.

01

1040

24

.50

0.90

-6

.70

-38

5

1050

1055

1100

1108

1117

1123

1128

13.5

13.5

13.5

13.5

13.5

135

13.5

12.7

12.4

12.5

12.4

12.7

12.6

12.6

12.4

14.9

14.8

15.0

15.0

15.0

15.0

15.2

14.5

14.1

14.1

14.2

14.2

14.2

14.2

14.5

14.8

15.3

14.6

14.3

pH 5.9

6.2

6.2

6.2

6.2

6.2

6.2

4.6

4.6

4.6

4.6

4.6

4.6

4.7

4.7

5.2

5.2

5.2

5.2

5.3

5.3

5.3

5.3

5.2

5.3

5.3

4.4

43 4.3

4.3

4.3

4.3

4.3

Spec

ific

cond

-

DO

uc

tanc

e

4.8 45 4.5

4.5

4.5

4.3

4.4

2.6

1.8

1.6

1.3

1.1

1.0

1.0

1.0

3.6

3.6

3.6

3.6

3.7

3.9

3.8

3.9

3.9

4.0

4.0

4.0

0.9

0.8

0.7

0.7

0.7

0.7

0.7

--

115

112

--

__

66

68

102

104

239

243

App

endi

x A

. -S

umm

ary of w

ell c

onst

ruct

ion

and

wat

er q

uali

ty d

ata

(con

t.)

Form

atio

n

Sam

plin

g or

gro

up;

Wel

l W

ell

Loca

l da

te

bydr

cgeo

logi

c

no.

nam

e id

entif

ier

Typ

e L

atitu

de

Lon

gitu

de

(moj

U/y

r)

Kiti

ng

5 K

EB

g35

KE1

01

I 39

1957

75

4906

10

/29/

90

PeR

5 K

EB

g35

KE

101

I 39

1957

75

4906

04

/02/

91

PeR

6 K

EB

e65

KE

405

I 39

1608

75

5943

10

/29/

90

AqR

LO

CU

ST

GR

OV

E N

ET

WO

RK

7 K

EB

e53

LG

205S

C

l 39

1810

75

5558

04

/02/

91

PeR

8 K

EB

e52

LG

205D

C2

3918

10

7555

58

11/0

5/90

P

eR

Tri

tium

T

ime

Alti

tude

T

op

Bot

tom

Dep

th

Pum

p T

ritiu

m

one

of

of la

nd

of

of

to

tare

con

cen-

«d

. D

elta

D

elta

m

ea»-

turf

ace

scre

en

scre

en

wat

er

time

trat

ion

dev.

O

-18

D

urem

ent

1133

1138

18.9

0 13

.6

14.6

15.2

0 1.

10

-7.3

5 -4

2.0

1205

1209

1212

1216

1220

1225

1233

1240

1250

18.9

0 13

.6

14.6

5.

65

1312

14

.90

0.6

1330

1335

1340

1345

1350

1405

1410

1415

14.9

4 5.

8 6.

7 2.

74

900

14.7

0 0.

60

-6.5

0 -3

7.5

937

942

947

952

1011

1017

1022

1035

1038

22.7

4 6.

1 6.

7 5.

15

1247

16

.00

0.70

-6

.85

-42.

5 12

5112

5613

0013

0313

0513

0913

1813

2622

.77

10.1

11

.0

5.46

16

00

15.3

0 0.

60

-7.5

5 -4

4.5

0 10

Tem

erat

ure

C 14.2

14.4

12.4

12.4

12.3

12.4

12.3

12.3

12.3

12.3

12.4

13.3

13.1

13.0

13.1

13.0

12.8

12.9

13.0

15.2

15.3

15.3

15.3

15.6

15.7

15.7

15.7

15.8

13.3

13.5

13.3

12.9

12.8

12.7

13.1

12.8

14.7

14.7

pH 4.3

4.3

5.1

5.1

5.1

5.1

5.0

5.0

5.0

5.0

5.0

5.3

5.3

5.3

5.3

5.3

5.3

5.3

5.2

5.5

5.5

5.5

55 5.5

5.5

5.5

5.5

5.5

5.3

5.2

5.2

5.2

5.2

5.2

5.2

5.2

4.7

4.7

1

DO

i

0.7

0.7

9.8

9.8

9.8

9.8

9.8

9.8

9.8

9.8

9.7

9.5

9.6

9.7

9.5

9.7

9.5

9.6

9.5

1.7

1.7

1.7

1.5

1.3

1.3

1.3

1.2

1.2

9.0

9.0

9.0

9.0

9.2

9.0

8.4

8.4

9.8

8.8

Spec

ific

cond

­

ucta

nce

242

--

__

__

240

£i^

\J

240

230

230

230

220

220

220

127

136

132

122 83 68 48 29 41 97 94 93 93 92 92 92 92 193

188

App

endi

x A

. -S

umm

ary

of w

ell c

onst

ruct

ion

and

wat

er q

uali

ty d

ata

(con

t)

Form

atio

n Tr

itium

Ti

me

Sam

plin

g or

gro

up;

Alti

tude

T

op

Bot

tom

Dep

th

Pum

p Tr

itium

on

e of

Wel

l W

ell

Loca

l da

te

bydr

ogeo

togj

c of

land

of

of

to

sta

rt co

ncen

- *d

. D

elta

D

elta

m

ea>-

no.

nam

e id

entif

ier

Type

La

titud

e Lo

ngitu

de

(mot

i/yr)

te

tting

su

rface

sc

reen

sc

reen

w

ater

tim

e tra

tion

dev.

O

-18

D

urem

ent

40 45 908

KE

Bc5

2 L

G20

5DC

2 39

1810

75

5558

11

/05/

91

PcR

22

.77

10.1

11

.0

1230

16

.60

0.80

1245

1250

1255

1300

1305

1310

1315

1320

1325

1331

1350

1400

1410

1430

1440

1505

1530

1541

9 K

EB

c61

LG

305

C3

3918

10

7555

58

11/0

5/90

A

qR

22

.73

14.5

15

.4 5

.39

1130

50

.00

1.60

-7

.70

-47.

025 30 35 60 90 12

09

KE

Bc6

1 L

G30

5 C

3 39

1810

75

5558

04

/02/

91

AqR

22

.73

14.5

15

.4

5.22

13

31

60.3

0 2.

50

1332

1338

1342

1345

1348

1351

1400

1411

1415

1420

9 K

EB

c61

LG

305

C3

3918

10

7555

58

11/0

4/91

A

qR

22

.73

14.5

15

.4

1410

63

.40

2.90

1445

Tem

erat

ure

C 14.6

14.5

143

14.5

143

14.5

14.5

14.7

14.8

14.6

14.7

14.8

14.6

14.8

15.0

14.8

14.8

14.8

14.7

145

14.4

14.0

13.9

14.0

14.0

14.1

143

1 O

A

13.4

13.3

13.5

13.5

13.8

13.9

13.7

13.7

13.7

13.7

-\f

\ A

13.4

pH 4.9

4.9

4.9

4.9

4.8

4.9

4.9

4.8

4.9

4.9

4.9

4.9

4.9

4.9

4.9

4.9

4.9

4.9

4.9

4.8

4.8

4.7

4.8

4.9

4.9

4.8

4.9

4.9

4.9

4.9

4.9

4.9

4.9

4.9

4.9

4.9

4.9

I

DO

i

8.8

8.7

92

^ ̂

10.5

10.4

10.6

10.5

10.4 9.9

9.4

11.0

11.0

11.2

11.1

11.2

112

11.0

11.1

11.2

Spec

ific

Con

ucta

nce

188

187

143

212

211

210

210

209

209

208

208

207

207

206

206

206

205

205

204

205

205

105

103

102

105

105

105

114

106

106

106

106

106

105

106

106

105

137

App

endi

x A

. -S

umm

ary

of w

ell c

onst

ruct

ion

and

wat

er q

uali

ty d

ata

(con

t.)

Form

atio

n Tr

itium

Ti

me

Sam

plin

g or

gro

up;

Alti

tude

To

p B

otto

m D

epth

Pu

mp

Triti

um

one

of

Wel

l W

ell

Loca

l da

te

bydr

qgeo

logi

c of

land

of

of

to

ta

rt c

once

n-

«d.

Del

ta

Del

ta

mea

s-

no.

nam

e id

entif

ier

Type

La

titud

e Lo

ngitu

de

(moA

i/yr)

Kiti

ng

surfa

ce

scre

en

scre

en

wat

er

time

tratio

n de

v.

O-1

8 D

ur

emen

t

1450

1456

1502

1511

1521

1525

1533

1546

1643

1655

1702

1726

9 K

EB

e61

LG

305

C3

3918

10

7555

58

11/0

5/91

A

qR

22.7

3 14

.5

15.4

1022

1037

1104

1106

1116

1127

1148

9 K

EB

e61

LG

305

C3

3918

10

7555

58

11M

6/91

A

qR

22.7

3 14

.5

15.4

1525

58

.20

2.20

1540

1550

1600

1610

1637

1701

1715

1725

10 K

EB

e62

LG

314

Cl

3917

42

7555

48

11M

6/90

A

qR

la

SO

6.9

7.8

2.59

92

0 13

.70

0.50

-7

.20

-42.

0 0 5 10 15 45

10 K

E B

e 62

L

G31

4 C

l 39

1742

75

5548

11

M6/

91

Aq

R

18.5

0 6.

9 7.

8

832

13.7

0 0.

60

855

900

908

920

925

935

1000

Tem

erat

ure

C 13.3

13.3

13.1

13.1

12.9

12.7

13.1

13.3

13.1

132

13.2

13.0

! »<

LJ,J

13.5

13.4

13.5

13.5

13.8

13.2

12.9

12.9

12.6

13.3

13.2

13.3

132

14.0

142

142

142

13.8

14.0

14.1

142

14.0

14.2

13.9

13.8

pH 5.0

5.0

5.0

5.0

5.0

5.0

5.0

5.0

5.1

5.0

5.0

5.0

5.0

4.9

4.9

4.9

4.9

4.9

4.9

4.8

4.9

4.8

5.3

5.6

5.6

5.6

5.7

5.7

5.6

5.5

5.5

5.6

5.5

5.5

1

DO

-

- '

8.8

8.8

8.8

8.8

9.0

Spec

ific

Con

ucta

nce

13

713

613

613

613

513

513

513

613

513

513

413

813

913

813

813

913

913

814

01*T

\J

140

140

139

139

140

139

139

266

253

253

252

251

f^/r

o26

826

826

826

826

826

826

7

App

endi

x A

. -S

umm

ary

of w

ell c

onst

ruct

ion

and

wat

er q

uali

ty d

ata

(con

t.)

Form

atio

n

Sam

plin

g or

gro

up;

Wel

l W

ell

Loca

l da

te

bydr

ogeo

logi

c

no.

nam

e id

entif

ier

Type

La

titud

e Lo

ngitu

de

(mot

tyr)

le

tting

11 K

EB

el63

L

G51

4 C

2 39

1742

75

5548

11

/06/

90

Aq

R

11 K

EB

el63

L

G51

4 C

2 39

1742

75

5548

11

/06/

91

Aq

R

12 K

E B

e 16

2 L

G 4

14

C3

3917

42

7555

48

11/0

6/90

A

qR

12 K

E B

e 16

2 L

G 4

14

C3

3917

42

7555

48

11/0

6/91

A

qR

13 K

E B

e 64

L

G31

3S

Cl

3917

21

7555

45

11/0

6/90

A

qR

Triti

um

Tim

e

Alti

tude

T

op

Bot

tom

Dep

th

Pum

p Tr

itium

on

e of

of la

nd

of

of

to

«art

con

cen-

«d

. D

elta

D

elta

m

eu-

njrf

ace

nree

n Er

een

wat

er

time

tratio

n de

v.

O-1

8 D

ur

emen

t

1024

1045

1117

18.5

4 12

.2

13.1

2.

59

1355

16

.50

0.60

-7

.45

-44.

5 0 5 11 15 40 60

18.5

4 12

.2

13.1

1136

16

.70

0.80

1150

1155

1200

1205

1210

1215

1220

1225

1240

1250

1310

1340

1357

1407

18.6

0 19

.5

20.4

2.6

5 11

40

0.90

0.

16

-7.3

0 -4

4.0

0 5 10 15 20 9018

.60

19.5

20

.4

1415

2.

20

0.15

1420

1430

1435

1440

1455

1505

13.7

5 4.

0 4.

9 12

5 16

40

16.5

0 0.

60

-7.3

5 -4

3.5

0 5 10

Tem

erat

ure

C 13.7

13.8

13.7

12.9

13.1

13.1

13.1

13.0

13.1

1*)

GIZ

.o12

.913

.012

.912

.912

.912

.912

.912

.912

.912

.912

.913

.012

.913

213

.113

.113

.113

.113

.01O

GIZ

.o13

.013

.013

.112

.913

.015

.315

.615

.7

pH 5.5

5.6

5.6

5.3

5.3

5.3

5.3

52

52

4.9

4.9

4.9

4.9

4.9

4.9

4.9

4.9

4.9

4.9

4.9

5.0

4.9

4.9

5.7

5.7

5.6

5.6

5.6

5.6

5.5

5.6

5.6

5.6

5.5

5.5

5.0

5.0

5.0

I {

DO

i

9.5

9.6

9.7

9.7

9.7

9.7

8.9

9.1

9.4

9.4

9.5

8.5

8.4

8.4

Spec

ific

cond

­

ucta

nce

267

268

267

154

164

164

164

163

163

1 JC

Qlo

o16

816

716

716

716

716

716

716

716

616

616

616

616

6 61 57 55 54 53 53 57 55 54 55 54 54

App

endi

x A

. -S

umm

ary

of w

ell c

onst

ruct

ion

and

wat

er q

ualit

y da

ta (

cont)

Form

atio

n

Sam

plin

g or

Gro

up;

Wel

l W

ell

Loc

al

Dat

e H

ydro

geol

cgic

No.

N

ame

Iden

tifie

r Ty

pe

Lat

itude

L

ongi

tude

(m

o/U

ay/y

r)

Setti

ng

14 K

E B

e 63

L

G31

3DC

2 39

1721

75

5545

11

/06/

90

Aq

R

15 K

EB

el61

L

G66

7 C

l 39

1720

75

5546

11

/07/

90

Aq

R

15 K

E B

e 16

1 L

G 6

67

Cl

3917

20

7555

46

04/0

2/91

A

q R

15 K

E B

e 16

1 L

G66

7 C

l 39

1720

75

5546

11

/07/

91

AqR

16 K

E B

e 16

0 L

G 5

67

C2

3917

20

7555

46

1V19

/90

AqD

16 K

E B

e 16

0 L

G 5

67

C2

3917

20

7555

46

04/0

2/91

A

q D

Tri

tium

T

ime

Alti

tude

T

op

Bot

tom

Dep

th

Pum

p T

ritiu

m

One

of

T

emp-

of L

and

of

of

to

Star

t C

once

n-

Std.

D

elta

D

elta

M

eat-

er

atur

e

Surf

ace

Scre

en

Scre

en

Wat

er

Tim

e tr

atio

n D

ev.

0-18

D

ur

emei

t C

1513

.74

11.1

12

.0

1.22

15

35

38.5

0 1.

40

-7.8

0 -4

7.0

0 5 10 15 20 5813

.77

4.9

5.8

1.43

16

07

19.2

0 1.

00

-7.3

5 -4

2.5

0 5 10 15 65 1150

1155

1200

1205

1210

13.7

7 4.

9 5.

8

1122

16

.80

0.60

1133

1136

1143

1148

1200

1210

1228

1241

1302

1308

1315

1330

13.7

9 10

.7

11.6

1.

40

1605

20

.00

1.10

-7

.50

-44.

5 16

2316

2916

3416

4016

4916

5513

.79

10.7

11

.6

1.28

10

47

1105

1110

15.7

13.7

13.3

13.3

13.3

13.3

13.5

14.8

14.8

14.8

14.8

15.0

14.2

14.0

14.4

14.5

14.4

13.8

14.9

14.9

15.0

15.0

14.8

15.0

14.9

15.0

14.9

14.9

15.0

15.0

12.8

13.1

13.1

13.1

13.3

13.3

14.1

14.1

pH 5.0

5.5

5.4

5.3

5.3

5.3

__ 5.4

5.0

5.0

5.0

5.0

5.4

5.4

5.3

5.3

5.3

5.3

5.1

5.1

5.1

5.0

5.0

5.0

5.0

5.0

4.9

4.9

4.9

4.9

5.5

5.5

5.5

5.3

5.1

5.0

62 5.6

Spec

ific

Con

d-

DO

uc

tanc

e

8.4

7.7 9.4

9.5

9.5

9.5

9.8

9.2

9.5

9.4

9.4

9.3

9.3

9.3

9.4

9.4

9.5

9.5

--

9.8

9.9

9.9

9.9

9.9

9.9

9.4

9.6

228 87 81 78 77 74 143

138

138

138

136

129

126

123

120

118

117

155

154

154

153

152

152

150

150

149

149

148

148 56 56 56 55 55 55 52 54

App

endi

x A

.- -S

umm

ary of w

ell c

onst

ruct

ion

and

wat

er q

ualit

y da

ta (

cont

)

Form

atio

n Tr

itium

T

ime

Sam

plin

g or

{rou

p;

Atti

tude

T

op

Bot

tom

Dep

th

Pum

p Tr

itium

on

e of

Wel

l W

ell

Loca

l da

te

bydr

ogeo

logk

of

land

of

of

to

«a

rt c

once

n-

td.

Del

ta

Del

ta

mea

t-

no,

nam

e id

otff

ier

Type

La

titud

e Lo

ngitu

de

(moA

tyr)

le

tting

su

rfac

e «r

een

cree

n w

ater

tim

e tr

atio

n de

v.

O-1

8 D

ur

emet

t

11

15

1120

1125

1130

1135

16K

B B

e 16

0 L

G56

7 C

2 39

1720

75

5546

11

/07/

91

AqD

13

.79

10.7

11

.6

940

40.8

0 1.

60

955

1007

1012

1020

1030

1055

1102

1108

1118

17 K

EB

el59

L

G46

7 C

3 39

1720

75

5546

11

/07/

90

AqD

13

.80

20.0

20.9

806

0.04

02

2 -7

.85

-47.

0 81

4-0

.03

021

-7.9

0 -4

7.0

819

825

CO

ToZ

/

830

834

839

852

855

858

900

904

907

910

17 K

EB

el59

L

G46

7 C

3 39

1720

75

5546

11

/07/

90

AqD

13

.80

20.0

20.9

1430

-0.0

9 0.

14

-7.8

5 -4

7.0

0 5 10 15 73n

KF

Rp

1SQ

T

fr 4

67

f*^

^017

20

7SS

S46

fl

4/ft

?/91

A

n D

1

^8

0

9i)

fl 900

1 7f

i <M

fi

Iflf

tS

1010

1015

1020

1025

Tem

erat

ure

C 14.1

14.1

14.0

14.0

142

13.1

13.3

13.3

13.3

13.5

13.3

13.3

133

13.3

13.0

12.9

12.9

13.1

13.1

13.0

13.0

13.0

13.0

13.0

13.1

13.1

132

13.3

132

132

132

13.5

13.4

13.4

13.5

13.5

13.5

pH 5.6

5.5

5.5

5.5

5.5 s? J*£i

5.1

5.1

5.1

52 5.2

5.3

5.3

5.3

6.9

7.1

7.1

7.1

7.1

7.1

7.1

7.1

7.0

7.1

7.1

7.1

__ 7.3

7.5

7.5

7.5

7.5

1

DO

i

9.8

9.5

9.5

9.4

9.4

__

2.9

2.9

2.9

3.1

3.1

32 3.5

3.5

3.5

3.5

3.5

3.6

3.6

3.5

3.6

3.6

3.6

4.1

2?

£**£i

23 2.3

23 2.4

Sfxc

ific

Con

ucta

nce

53 52 52 52 51 59 59 59 59 59 59 59 59 59 --

fOC

1O

J

185

185

185

185

184

184

199

198

198

197

194

210

210

210

200

200

App

endi

x A

. -S

umm

ary

of w

ell c

onst

ruct

ion

and

wat

er q

uali

ty d

ata

(con

t.)

Form

atio

n

Sam

plin

g or

gro

up;

Wel

l W

ell

Loca

l da

te

hydr

ngeo

logi

c

no.

nam

e id

entif

ier

Typ

e L

atitu

de

Lon

gitu

de

(mo/

d/yr

) se

tting

17 K

E B

e 15

9 L

G46

7 C

3 39

1720

75

5546

11

/07/

91

AqD

18 K

E B

e 16

7 L

G63

5 C

l 39

1838

75

5609

11

/07/

90

AqR

19 K

EB

el66

L

G53

5 C

2 39

1838

75

5609

11

/07/

90

AqR

20 K

E B

e 16

5 L

G43

5 C

3 39

1838

75

5609

11

/07/

90

AqR

20 K

E B

e 16

5 L

G43

5 C

3 39

1838

75

5609

04

/02/

91

AqR

Tri

tium

T

ime

Alti

tude

T

op

Bot

tom

D

epth

Pu

mp

Tri

tium

on

e of

ofla

nd

of

of

to

atai

t co

ncen

at

d.

Del

ta

Del

ta

mea

s

surf

ace

scre

en

scre

en

wat

er

time

trat

ion

dev.

O

-18

D

urem

ent

1030

1035

1040

1 ^ s

o ^n

n ^

n o

1 IIA

.

1 "

un13

4513

5814

0614

1614

2214

2814

4214

4714

5515

1015

1520

.09

4.6

5.5

2.01

12

05

13.9

0 0.

80

-6.9

5 -4

0.0

0 5 10 15 4620

.06

7.6

8.5

1.98

11

10

16.7

0 1.

50

-7.7

0 -4

5.0

0 5 10 15 20 5020

.01

13.7

14

.6

1.95

93

5 44

.20

2.20

-8

.15

-50.

5 0 5 10 15 20 25 30 80

20.0

1 13

.7

14.6

1.

34

1450

42

.10

1.60

1450

1455

1500

1513

Tem

erat

ure

C 13.5

13.5

135

13.3

13.3

13.2

13.3

13.3

13.3

13.3

13.3

13.2

13.2

13.1

13.1

15.3

16.0

16.0

16.0

15.9

14.4

14.1

14.0

13.9

14.0

13.9

13.1

12.9

12.9

12.9

12.9

13.0

13.0

13.2

12.9

12.8

12.9

13.0

pH 7.5

7.5

7.5

6.5

6.9

72 7.3

7.3

7.3

7.4

7.4

7.4

7.4

7.4

7.4

5.1

5.1

5.1

5.1

-- 5.3

5.0

5.0

5.0

5.0

5.0

7.6

5.5

53 52 5.1

5.0

5.0

5.7

5.5

5.4

5.3

1

DO

i

2.4

2.4

2.5

--

--

--

--

--

--

-

- 9.2

10.8

10.1

10.1

10.0 8.4

10.0

10.4

10.4

10.4

10.4 8.6

9.0

10.1

10.4

10.6

10.6

10.7

10.8 9.0

10.2

10.4

10.6

Spec

ific

Con

ucta

nce

200

200

200

*\r\g-

2.2JO

224

221

219

218

217

216

215

214

214

213

213

202

187

187

188

187

224

224

227

228

229

232

238

235

232

232

232

231

231

230

900

£*

\J\J

238

242

247

App

endi

x A

. -S

umm

ary of w

ell c

onst

ruct

ion

and

wat

er q

uali

ty d

ata

(con

t.)

Form

atio

n Tr

itium

Ti

me

Sam

plin

g or

gro

up;

Alti

tude

To

p B

otto

m D

epth

Pu

mp

Triti

um

one

of

Tem

p-

Spec

ific

Wel

l W

ell

Loca

l da

te

hydr

cgeo

logi

c of

land

of

of

to

ta

rt c

once

n-

*d.

Del

ta

Del

ta

mea

>-

erat

ure

Con

d-

no._

___n

ame_

____

iden

tifi

er

Type

La

titud

e Lo

ngitu

de

(mof

l/yr

)___

_let

ting

su

rface

gr

een

gree

n w

ater

tim

e tra

tion

dev.

O

-1S

____

D__

__ur

emen

t C

pH

D

O

ucta

nce

1517

13

.1 5

.3

10.6

24

615

21

13.1

5.3

10

.6

248

1526

13

.1 5

.3

10.6

24

715

33

12.8

5.3

10

.6

245

1542

12

.9 5

.3

10.4

24

515

46

12.8

5.3

10

.8

248

21 K

EB

e59

LG

325

Cl

3918

32

7556

08

1V19

/90

Aq

R

21.7

5 12

8.1

3.81

11

32

14.8

0 0.

70

-7.0

5 -4

3.0

1140

10.4

4.6

211

1145

10

.4

5.6

241

1150

10.4

6.

5 25

711

55 10.4

7.

0 26

812

00

10.4

7.6

276

1205

14

.9 5

.2

7.6

281

1221

14

.3 5

.3

8.5

288

1232

14

.4 5

.5

8.2

290

1238

14

2 5.

2 8.

8 29

122

KE

Be

164

LG

425

C2

3918

32

7556

08

1V19

/90

AqR

21

.76

13.7

14

.63.

72

1000

31

.50

120

-7.5

5 -4

5.5

1025

13

.35.

9 9.

1 14

810

30

13.3

5.9

9.

0 14

710

35

13.3

5.9

92

14

610

40

13.4

5.9

92

146

23 K

E B

e 16

9 L

G37

1 I

3917

19

7555

47

04/0

2/91

P

eD

11.8

0 0.

8 1.

7 0.

52

1137

12

20

0.50

-7

.40

-43.

0 11

38

12.6

5.5

9.4

7811

39

12.6

5.3

9.

4 69

1140

13

.0 5

2

92

6911

41

12.8

52

92

7011

42

12.6

52

9

2

7011

43

12.6

52

92

70

1145

12

.4 5

2

9.4

7011

50

12.6

5.1

92

7012

00

12.6

5.1

9.

1 70

1207

11

.8 5

.1

9.4

7012

12

122

5.1

92

7024

KE

Be

170

LG

381

I 39

1720

75

5547

04

/02/

91

PeR

12

.28

12

2.1

0.70

10

02

20.0

0 0.

80

-6.9

5 -4

0.0

1043

13

.36.

1 5.

4 26

010

46

13.3

6.1

5.

2 26

010

49

12.9

6.1

5.

2 26

211

03

12.1

6.0

4.

4 27

811

08

12.4

6.0

4.

6 26

811

18

12.7

6.0

5.

4 25

911

25

11.7

6.0

6.

3 25

211

29

12.1

6.0

6.

6 25

0

App

endi

x A

. -

Sum

mar

y of w

ell c

onst

ruct

ion

and

wat

er q

uali

ty d

ata

(con

t.)

Form

ati

on

Sam

plin

g or

gro

up;

Wel

l W

ell

Loca

l da

te

bydr

ogeo

logi

c

no.

nam

e id

entif

ier

Type

L

atitu

de

Lon

gitu

de

(mo/

d^r)

se

tting

25 K

EB

eSO

L

G20

3 I

3918

51

7556

18

1V19

/90

Pe R

26 K

E B

e 49

L

G20

2 I

3919

23

7556

43

11/2

0/90

P

eR

27 K

E B

e 51

L

G20

4 I

3918

51

7555

44

11/2

0/90

P

eR

28 K

E B

e 60

L

G31

9 I

3918

11

7556

49

11/2

1/90

A

qR

29 K

EB

el58

LG

446

I 39

1814

75

5755

11

/21/

90

Aq

R

Tri

tium

T

ime

Alti

tude

T

op

Bot

tom

Dep

th

Pum

p T

ritiu

m

one

of

Tem

p-

ofla

nd

of

of

to

star

t co

ncen

- *d

. D

elta

D

elta

m

eat-

er

atur

e

surf

ace

scre

en

scre

en

wat

er

time

trat

ion

dev.

O

18

D

urem

ent

C

2139

6.

1 6.

7 3.

63

1403

15

.70

0.80

-7

35

-4

2.0

1415

1420

1425

1430

1439

1454

1506

1511

1517

1528

22.4

5 6.

7 7.

6 4.

12

730

15.6

0 0.

80

-7.2

0 -4

1.0

810

815

820

826

832

839

844

848

21.3

4 73

8.

2 4.

02

1550

18

.50

1.00

-7

.25

-42.

5 16

0516

1016

1516

2016

2516

3016

3516

4023

.81

7.5

8.1

6.19

81

0 16

.60

0.90

-7

.05

-41.

0 85

085

590

090

591

491

992

520

.41

9.4

10.4

7.

18

945

15.1

0 0.

80

-7.7

0 -4

6.0

1005

1010

1015

1020

1025

153

15.1

15.0

14.9

15.1

14.8

15.1

15.2

153

15.0

14.6

14.4

14.4

14.2

14.0

14.2

14.4

14.4

14.0

14.0

13.9

13.9

13.9

13.7

13.8

13.9

13.7

13.6

13.6

13.8

13.7

13.6

133

13.3

13.6

13.6

13.5

13.5

PH 5.1

5.1

5.1

4.8

4.8

4.8

4.8

4.8

4.8

4.8

5.6

5.6

5.6

5.6

5.6

5.6

5.6

5.6

5.0

5.1

5.1

4.9

4.9

* 4.9

4.9

5.3

53 53

5.2

5.2

5.2

4.6

4.8

4.8

4.8

4.8

Spec

ific

Con

d-

DO

uc

tanc

e

8.8

9.0

9.0

9.2

9.2

9.0

9.4

8.8

8.7

9.2

9.1

93 9.2

9.1

9.6

9.4

93 93

113

11.2

10.9

10.8

10.7

10.7

10.6

10.7 8.6

8.7

8.7

8.7

9.3

8.7

8.8

10.2 9.8

9.9

9.7

9.5

383

382

382

384

384

381

472

474

474

473

275

249

248

248

249

248

248

246

178

172

167

164

165

166

166

167

153

147

147

145

145

140

142

167

164

163

163

158

App

endi

x A

. -S

umm

ary of w

ell c

onst

ruct

ion

and

wat

er q

uali

ty d

ata

(con

t.)

Wdl

no.

Wdl

Loca

l

iden

tifie

r Ty

pe

Latit

ude

Long

itude

Sam

plin

g

date

Form

atio

n Tr

itium

or g

roup

; A

ltitu

de

Top

Bot

tom

Dep

th

Pum

p Tr

itium

on

e

bydr

qgeo

logi

c of

land

of

of

to

*a

rt c

once

n

atd.

letti

ng

turf

ace

tcre

en

gree

n w

ater

tim

e tra

tion

dev.

Del

ta

0-1

8

Del

ta

D

Tim

e

of

Tem

p-

Spec

ific

mea

»-

erat

ure

Con

d-

urem

ent

C

pH

DO

uc

tanc

e

VA

N D

YK

E N

ET

WO

RK

30 G

541-

12

VD

E2

I 39

2120

75

4410

11

/08/

90

PeR

24.6

3 4.

6 5.

5

1605

13

.10

0.70

-7

.30

-42.

0

31 G

541-

09

VD

E3

Cl

3921

20

7544

19

04/0

2/91

P

eR

25.6

2 3.

7 4.

6 13

5 16

31

12.9

0 0.

50

-6.5

5 -3

7.5

32 G

541-

22

C2

3921

20

7544

19

04/0

2/91

P

eR

24.3

8 6.

4 7.

3 1.

51

1536

15

.10

0.60

-7

.25

-43.

0

CY

PR

ES

S B

RA

NC

H N

ET

WO

RK

33 G

b42-

06

CY

103

I 39

2118

75

4347

11

/08/

90

Pe R

24.3

8 4.

6 5.

5

845

16.4

0 0.

90

-7.1

5 -4

0.0

34 G

b42-

08

CY

302

Cl

3921

20

7543

44

11/0

8/90

P

eR

22.8

6 1.

8 2.

7

1230

18

.90

0.90

-7

.35

-42.

5

35 G

b42-

05

CY

202

C2

3921

20

7543

44

11/0

8/90

P

eR

22.8

6 4.

6 55 --

1032

18

.20

0.90

-7

.30

-41

5

1030

13

.3 4

.8

9.6

168

1035

13

.3 4

.8

9.7

171

1040

13

.3 4

.8

9.7

171

0 15

.9 5

.4

10.5

25

75

16.1

5.4

92

259

10

16.1

5.4

9.

1 26

015

16

.1 5

.4

9.1

260

20

15.9

5.4

9.

7 26

116

40

12.4

5.8

9.

9 20

016

45

12.4

5.8

9.

8 20

016

50

12.4

5.8

9.

8 20

016

55

12.5

5.8

9.

4 20

317

00

12.4

5.8

92

20

315

50

14.3

5.7

8.

9 11

815

55

14.7

5.6

8.

7 11

516

00

14.8

5.6

9.

6 11

016

05

15.0

5.6

9.

5 11

416

10

152

5.6

9.5

114

1615

14

.9 5

.5

9.3

112

1625

14

.0 5

.5

9.1

112

0 5 10 15 57 0 5 10 15 20 70 0 5 10

14.2

14.3

14.4

14.4

14.3

15.9

16.1

16.1

16.1

16.3

16.0

14.6

14.8

14.7

4.5

4.6

4.6

4.6

4.6

6.0

5.7

5.6

5.5

5.5

5.4

5.5

5.5

5.5

9.4

9.4

9.4

9.5

9.4

72

8.6

8.8

8.8

8.8

9.0

8.4

8.8

8.8

185

181

180

179

180

263

255

253

253

252

250

174

173

173

App

endi

x A

. -S

umm

ary

of w

ell c

onst

ruct

ion

and

wat

er q

uali

ty d

ata

(con

t.)

Form

atio

n

Sam

plin

g or

gro

up;

Wel

l W

ell

Loca

l da

te

bydr

qgeo

logk

no.

nam

e id

entif

ier

Type

L

atitu

de

Lon

gitu

de

(mo/

d/yr

) le

tting

36 G

b42-

07

CY

104

C

l 39

2120

75

4343

11

/08/

90

PeD

37 G

b42-

09A

CY

204

C

2 39

2120

75

4343

04

/02/

91

Pe D

BL

AC

KB

IRD

ST

AT

E F

OR

ES

T N

ET

WO

RK

38 G

b41-

06

VD

32

I 39

2045

75

4435

11

/20/

90

PeR

39 G

b41-

07

VD

33

I 39

2051

75

4439

11

/20/

90

PeR

40 G

b41-

05

VD

31

I 39

2104

75

4435

11

/20/

90

PeR

Tri

tium

T

ime

Alti

tude

T

op

Bot

tom

Dep

th

Pum

p T

ritiu

m

one

of

of la

nd

of

of

to

*art

con

cen-

*d

. D

elta

D

elta

m

eas-

surf

ace

icre

en

icre

en

wat

er

time

trat

ion

dev.

O

18

D

urem

ent

15 6022

.25

0.8

1.7

1400

24

.10

1.20

-7

.00

-41.

0 0 5 10 15 65

21.6

1 2.

4 3.

4Flo

wi

1650

17

.80

0.70

-7

.10

-40.

5 16

5517

0217

0517

1017

1417

1817

2417

29

25.4

9 7.

3 8.

2 2.

76

1014

18

.50

0.70

-3

.95

-28.

0 10

2510

3110

3610

4210

5511

0011

0511

1024

.83

52.

6.7

1.62

13

10

23.7

0 12

0 -5

.75

-34.

5 13

2513

3013

3513

4013

4613

5025

.56

8.2

9.1

3.06

14

10

1920

1.

00

-7.2

5 -4

3.0

1430

1436

1441

1444

Tem

erat

ure

C 14.7

14.8

14.6

14.6

14.6

14.7

13.4

11.8

12.5

12.5

12.4

12.1

12.1

12.0

12.1

13.1

13.1

13.1

13.0

13.0

13.1

13.1

13.1

13.4

13.4

13.4

13.4

13.4

13.3

12.5

12.7

12.9

12.9

pH 5.4

5.4

5.8

5.8

5.8

5.8

5.8

5.6

5.6

5.6

5.6

5.6

5.5

5.5

5.5

5.5

5.5

5.6

5.6

5.7

5.7

5.6

5.7

5.8

5.8

5.8

5.8

5.8

5.8

6.7

6.7

6.7

6.7

Spec

ific

Con

d-

DO

uc

tanc

e

8.8

8.8

5.9

5.8

5.9

5.9

5.4

7.5

8.3

8.3

8.3

8.5

8.6

8.7

8.9

0.1

0.1

0.1

0.1

0.1

0.1

0.1

0.1

02.

02.

02

02.

02

02

4.4

4.9

4.8

5.3

173

175 66 65 65 65 66 104

100

100

100

100

100 99 98 53 53 53 53 54 54 54 54 59 59 59 59 59 60 255

243

241

235

TR

AN

SE

CT

B41

QA

Fd2

W

Y10

2 I

3954

56

7609

0311

/02/

90

ChD

4.

57

11.0

11

.9

2.01

94

0 11

.70

0.50

-7

.30

-42.

595

5 14

2 7.

3 0.

4

1000

13

.9 7

.3

0.4

361

App

endi

x A

. -S

umm

ary

of w

ell c

onst

ruct

ion

and

wat

er q

uali

ty d

ata

(con

t.)

Form

atio

n Tr

itium

Ti

me

Sam

plin

g or

gro

up;

Alti

tude

To

p B

otto

m D

epth

Pu

mp

Triti

um

one

of

Tem

p-

Spec

ific

Wel

l W

ell

Loca

l da

te

bydr

qgeo

logi

c of

land

of

of

to

ia

tt c

once

n-

id.

Del

ta

Del

ta

mea

t-

erat

ure

Con

d-

no._

___nam

e____id

etti

Ser

Ty

pe

Latit

ude

Long

itude

(m

ofl/

yr)_

___l

etti

ng

mrf

ace

acre

en

acre

en

wat

er

time

tratio

n de

v.

O-1

8____D

ur

emet

t C

pH

D

O

ucta

nce

1005

14

.0 7

.3

0.3

1010

14

.1 7

.3

0.4

1015

14

.1 7

.3

0.4

1021

14

.2 7

.4

0.4

1025

14

.2 7

.4

0.4

1030

14

3 7.

3 0.

4

1035

14

.4 7

.4

0.4

361

41 Q

AF

d2

WY

102

I 39

5456

76

0903

04

/03/

91

Ch

D

4.57

11

.0

11.9

1.

16

1006

12

.00

0.50

1015

14

.57.

1 02

399

1020

14

.7 7

.2

0.1

381

1025

14

.8 7

.3

0.1

345

1030

14

.8 7

.3

0.1

330

1035

15

2 7.

3 0.

1 31

010

40

15.1

7.3

0.

1 28

810

45

14.9

7.3

0.

1 30

710

50

14.8

7.3

0.

2 28

742

QA

Ed3

9 Q

A40

2 C

l 38

5555

76

0754

11

/02/

90

PeR

18

.29

7.0

7.9

3.75

74

0 19

.60

1.00

-7

25

-42.

5 75

0 14

.1 5

.0

7.6

802

14.4

4.9

8.

0

807

14.4

4.9

8.

4 16

481

2 14

.4 4

.9

8.4

817

14.4

4.9

8.

3

822

14.4

4.9

82 --

827

14.4

4.9

82

--

832

14.5

4.9

8.

3 16

783

7 14

.4 4

.7

8.3

842

14.4

4.7

8.

1

847

14.5

4.7

8.

2

42 Q

AE

d39

QA

402

Cl

3855

55

7607

54

04/0

3/91

P

eR

18.2

9 7.

0 7.

9 3.

08

729

16.3

0 0.

60

750

12.9

4.7

92

171

755

12.9

4.7

9.

0 17

080

0 13

.0 4

.8

9.0

170

805

132

4.8

9.0

170

815

13.0

4.8

8.

8 17

082

0 12

.8 4

.8

8.5

170

825

132

4.8

9.0

170

830

132

4.9

8.8

170

835

13.3

4.9

9.

0 17

043

QA

Ed

38

QA

302

C2

3855

55

7607

54

04/0

3/91

P

eR

1829

10

.1

11.0

3.14

83

6 21

.80

0.90

-7

.35

-45.

0 90

0 13

26.6

2.

0 35

690

5 13

.3 6

.7

0.9

371

910

13.6

6.7

1.

0 36

4

App

endi

x A

. -S

umm

ary of w

ell c

onst

ruct

ion

and

wat

er q

uali

ty d

ata

(co

nt)

to

Form

atio

n

Sam

plin

g or

gro

up;

Wel

l W

ell

Loca

l da

te

bydr

cgeo

logi

c

no.

nam

e id

entif

ier

Typ

e L

atitu

de

Lon

gitu

de

(moH

/yr)

xt

ting

44 T

A B

e 85

T

A10

1 I

3954

40

7602

44

11/0

1/90

P

eR

45 C

O D

C 14

6 C

A 1

02

I 38

5302

75

5401

11

/01/

90

PeR

45 C

O D

C 14

6 C

A 1

02

I 38

5302

75

5401

04

/03/

91

Pe

R

46 N

d41-

04

SX20

2 I

3846

30

7534

51

04/0

3/91

B

SR

47 O

g43-

02

SX20

6 I

3841

18

7517

31

04/0

3/91

B

SR

Tri

tium

T

ime

Alti

tude

T

op

Bot

tom

Dep

th

Pum

p T

ritiu

m

one

of

of la

nd

of

of

to

stai

t co

ncen

- td

. D

elta

D

elta

m

eas-

surf

acc

scre

en

scre

en

wat

er

time

trat

ion

dev.

O

-18

D

ur

emen

t

917

13.7

2 6.

1 7.

0 3.

05

1525

17

.60

0.90

-7

20

-4

0.0

1545

1550

1555

1602

1607

1612

1617

13.7

2 5.

2 6.

1 2.

59

1405

16

.10

0.80

-7

.00

-41.

0 14

2014

2514

3014

3514

4014

4514

5013

.72

5.2

6.1

1.49

12

35

17.5

0 0.

80

1250

1255

1300

1305

1310

1315

1320

1325

1330

13.7

2 52

6.1

3.06

10

12

10.9

0 0.

60

-6.1

0 -3

4.0

1018

1022

1041

1044

1057

1112

1115

13.4

1 5.

2 6.

1 0.

52

1233

10

.90

050

-7.8

0 -4

65

12

3812

4312

4712

5012

5313

0013

03

Tem

erat

ure

C 13.6

14.9

14.9

14.9

14.9

14.9

14.9

14.8

17.4

17.2

172

17.1

17.0

17.0

17.0

1-»<

CiJ

tJ

135

135

135

13.8

13.6

13.5

13.6

13.6

13.6

14.3

14.7

14.3

15.0

14.7

14.4

13.3

13.4

13.4

13.4

13.4

13.4

13.4

pH 6.6

4.5

45 4.5

4.6

4.6

4.6

4.6

5.4

5.3

5.3

5.3

5.2

5.2

52

CO

~J.<

&

5.2

5.1

5.1

5.1

5.1

5.1

5.0

5.0

5.2

5.2

5.2

5.2

5.1

5.1

5.1

4.9

4.6

4.6

4.6

4.6

4.6

4.6

I

DO

i

3.6

85 85 85 8.6

8.6

8.6

8.6

9.0

95 9.7

9.8

9.8

9.8

10.0

10.4

105

11.0

10.9

105

10.6

10.8

10.8

10.8 9.3

8.0

8.0

8.4

9.0

9.6

9.2

10.0

10.0

11.2

11.2

11.2

112

11.2

Spec

ific

Con

ucta

nce

319

205

205

__

269

264

__

242

242

240

237

235

236

233

231

228

281

286

285

289

287

287

287

135

136

137

138

137

137

137

App

endi

x A

. -S

umm

ary

of w

ell c

onst

ruct

ion

and

wat

er q

uali

ty d

ata

(con

t.)

Form

atio

n

Sam

plin

g or

grou

p;

Wel

l W

ell

Loca

l da

te

bydr

ogeo

logi

c

no.

nam

e id

entif

ier

Type

La

titud

e Lo

ngitu

de

(mo/

U/y

r) le

tting

48 N

b24-

03

SX30

1 I

3848

37

7541

52

11/0

1/90

B

SR

49 P

gl4-

01

SX20

5 I

3839

39

7516

38

1Q/3

0/90

B

SR

50 O

i51-

12

SX30

9 C

l 38

4044

75

0910

11

/01/

90

BS

R

51 O

I51-

11

SX20

9 C

2 38

4044

75

0910

11

/01/

90

BS

R

FA

IRM

OU

NT

NE

TW

OR

K53

Phl

3-03

Cl

3839

07

7512

41

10/3

1/90

B

SR

Triti

um

Tim

e

Alti

tude

To

p B

otto

m D

epth

Pu

mp

Triti

um

one

of

of la

nd

of

of

to

cart

con

cen-

«d

. D

elta

D

elta

m

eai-

surfa

ce

icre

en

icre

en

wat

er

time

(rat

ion

dev.

O

-18

D

urem

ent

11.5

8 3.

4 4.

0 1.

98

1220

12

.90

0.60

-6

.30

-35.

5 12

3812

4312

4812

5312

5813

0313

0812

.50

6.1

7.0

2.59

15

00

13.6

0 0.

80

-7.2

5 -4

1.5

1505

1510

1513

1515

1518

1523

1527

1531

1535

1540

1545

3.05

5.

6 6.

6 1.

40

844

22.8

0 1.

00

-6.7

5 -3

7.5

900

905

915

920

925

930

938

3.05

16

.8

17.7

1.

43

720

26.1

0 1.

00

-6.6

0 -3

8.0

807

810

815

820

825

830

835

840

6.83

6.

1 7.

6 4.

39

1630

15

30

0.80

-5

.85

-31.

5 16

4016

4516

50

Tem

erat

ure

C 17.7

17.6

17.6

17.6

17.6

17.5

17.4

16.2

16.4

16.5

16.5

16.5

16.5

16.3

16.4

163

163

16.3

14.5

14.6

14.6

14.6

14.7

14.7

14.7

13.3

13.2

13.1

13.2

13.2

13.2

13.2

13.2

14.8

14.8

14.8

pH 5.2

5.2

5.2

5.1

5.2

52

5.1

4.3

42

4.3

42

42

42

42

42

42

42

42

5.7

5.7

5.7

5.7

5.7

5.7

5.7

5.4

5.4

5.3

5.4

5.3

5.3

5.4

5.4

5.1

5.1

5.1

Spec

ific

Con

d-

DO

uc

tanc

e

0.8

0.8

0.9

0.9

1.0

1.0

1.0

8.0

8.0

8.5

92

9.1

9.1

8.9

8.9

8.9

9.0

9.0

33 3.1

2.9

2.8

2.9

2.9

2.8

1.5

1.5

1.6

1.5

1.5

1.5

1.4

1.4

8.0

8.0

7.9

58

59

309

300

58

62

110

App

endi

x A

, -S

um

mary

of w

ell c

onst

ruct

ion

and

wat

er q

uali

ty d

ata

(con

t)

K>

K>

Form

atio

n T

ritiu

m

Tim

e

Sam

plin

g or

gro

up;

Alti

tude

T

op

Bot

tom

Dep

th

Pum

p T

ritiu

m

one

of

Tem

p-

Wel

l W

ell

Loca

l da

te

hydr

ogeo

logi

c of

land

of

of

to

st

art

conc

en-

ltd.

Del

ta

Del

ta

mea

s-

erat

ure

no.

nam

e id

entif

ier

Typ

e L

atitu

de

Lon

gitu

de

(mot

ifyr)

se

tting

su

rfac

e sc

reen

sc

reen

w

ater

tim

e tr

atio

n de

v.

O 1

8 D

ur

emen

t C

1655

1700

1705

1710

1715

1720

1725

54 P

hl3

-16

C2

3839

07

7512

41

10/3

1/90

B

SR

6.

85

12.2

13

.7

3.25

91

0 20

.50

1.00

-6

.25

-35.

0 92

092

593

093

594

094

595

095

510

0010

0510

1055

Phl3

-17

C3

3839

07

7512

41

10/3

1/90

B

SR

6.

86

16.8

18

3 2.

59

1016

19

.40

1.00

-6

.50

-37.

0 10

3010

3510

4010

4510

5511

0011

0511

1011

1511

2011

2856

Phl3

-18

C4

3839

07

7512

41

10/3

1/90

B

SR

6.

87

24.4

25.

9 3.

26

800

29.3

0 1.

40

-6.9

0 -3

9.5

820

825

830

835

840

845

850

855

900

14.8

14.8

14.8

14.8

14.8

14.8

14.8

14.2

14.2

14.1

14.2

14.3

14.4

14.4

14.4

14.4

14.6

14.6

14.9

14.8

14.6

14.4

14.1

14.0

14.1

14.1

14.3

14.4

14.1

12.9

13.1

13.1

13.2

13.5

13.6

13.7

13.8

13.7

pH 5.1

5.1

5.1

5.1

5.1

5.1

5.1

5.4

5.4

5.4

5.4

5.4

5.4

5.4

5.4

5.4

5.4

5.3

5.0

5.0

5.0

5.0

5.0

4.9

5.0

4.9

4.9

4.9

5.0

5.7

5.7

5.7

5.7

5.7

5.6

5.6

5.6

5.6

Spec

ific

Con

d-

DO

uc

tanc

e

7.5

7.8

7.8

7.9

7.9

7.9

7.9

8.8

8.9

9.6

9.4

9.5

9.1

9.3

9.6

9.4

9.3

9.3

6.1

6.0

6.9

7.0

7.3

7.3

7.4

7.4

7.5

7.4

7.5

52

5.1

5.4

5.4

5.3

5.3

5.3

5.3

5.4

264

255

290

__

288

_

311

318

164

__

_ 163

App

endi

x A

. - -S

umm

ary

of w

ell c

onst

ruct

ion

and

wat

er q

ualit

y da

ta (

cont

.)

Form

atio

n

Sam

plin

g or

gro

up;

Wel

l W

ell

Loca

l da

te

bydr

ogeo

logi

c

no.

nam

e id

entif

ier

Type

La

titud

e Lo

ngitu

de

(mo/

dtyr

) le

tting

57 P

h 13

-04

Cl

3839

03

7512

30

04/0

4/91

B

SR

58 P

hl3

-23

C2

3839

03

7512

30

04/0

4/91

B

SR

59 P

hl3

-24

C3

3839

03

7512

30

04/0

4/91

B

SR

60 P

h 13

-25

C4

3839

03

7512

30

04/0

4/91

B

SR

61 P

hl3

-26

C4

3839

03

7512

30

04/0

4/91

B

SR

62 P

H23

-10

Cl

3838

54

7512

20

10/3

1/90

B

SR

Triti

um

Tim

e

Alti

tude

To

p B

otto

m D

epth

Pu

mp

Triti

um

one

of

Tem

p-

ofla

nd

of

of

to

cart

con

cen-

Id

. D

elta

D

elta

m

eat-

er

atur

e

surfa

ce

scre

en

scre

en

wat

er

time

tratio

n de

v.

O-1

8 D

ur

emen

t C

905

5.88

6.

1 7.

6 2.

01

1025

14

.70

0.70

-6

.65

-37.

0 10

3510

4010

4510

5010

5511

005.

89

12.2

13

.7

2.04

11

54

18.8

0 0.

80

-6.7

5 -3

8.5

1215

1220

1225

1230

1235

1305

1310

5.89

18

.3

19.8

2.0

1 11

17

22.1

0 1.

00

-6.7

5 -3

9.0

1125

1130

1135

1140

1145

1150

5.89

24

.4

25.9

1.

98

810

27.8

0 1.

10

-6.7

0 -3

9.0

900

905

910

915

5.90

29

.6 3

1.1

2.04

92

3 28

.60

1.00

-6

.80

-38.

0 95

095

510

0010

0510

1010

1510

205.

82

6.1

7.6

3.07

14

44

17.5

0 0.

80

-6.6

5 -3

7.5

1455

1500

1505

1510

1515

1518

1523

13.8

13.7

13.7

13.8

13.9

14.2

13.9

14.4

14.3

14.2

14.2

14.5

14.4

14.2

14.7

14.1

14.2

14.7

14.3

14.3

13.9

14.0

14.0

14.1

14.4

14.1

14.1

14.7

14.1

14.1

14.1

13.7

13.7

13.7

13.7

13.7

13.7

13.7

pH 5.6

5.0

5.0

5.0

5.0

5.0

5.0

4.9

5.0

5.0

5.0

5.0

5.0

5.0

5.6

5.7

5.7

5.7

5.7

5.7

6.8

5.6

5.6

5.6

5.5

5.5

5.5

5.5

5.5

5.5

5.5

5.4

5.4

5.4

5.5

5.5

5.5

5.5

Spec

ific

Con

d-

DO

uc

tanc

e

5.3

10.2

10.0 9.9

9.9

9.7

9.9

9.1

8.9

8.8

8.8

8.3

8.0

8.9

7.5

7.4

7.4

6.7

12

7.3

7.1

12

6.7

7.1

7.7

7.4

7.1

6.5

6.9

6.9

6.9

6.4

6.1

5.9

5.9

5.6

5.6

5.6

319

322

323

324

324

325

351

353

354

354

354

354

354

340

342

341

339

340

339

236

236

236

236

227

225

224

224

224

223

223

328

328

App

endi

x A

. -

Sum

mar

y of w

ell c

onst

ruct

ion

and

wat

er q

uali

ty d

ata

(con

t.)

to

Form

atio

n

Sam

plin

g or

gro

up;

Wel

l W

ell

Loc

al

date

by

drog

eolo

gic

no.

nam

e id

entif

ier

Typ

e L

atitu

de

Lon

gitu

de

(mo/

dtyr

) le

tting

62 P

h23-

10

Cl

3838

54

7512

20

04/0

4/91

B

SR

63 P

h23-

12

C2

3838

54

7512

20

10/3

1/90

B

SR

63 P

h23-

12

C2

3838

54

7512

20

04/0

4/91

B

SR

64 P

h23-

13

C3

3838

54

7512

20

10/3

1/90

B

SR

64 P

h23-

13

C3

3838

54

7512

20

04/0

4/91

B

SR

Tri

tium

T

ime

Alti

tude

T

op

Bot

tom

Dep

th

Pum

p T

ritiu

m

one

of

of la

nd

of

of

to

Har

t co

ncen

- ltd

. D

elta

D

elta

m

eas-

surf

ace

scre

en

scre

en

wat

er

time

trat

ion

dev.

O

18

D

urem

enl

5.82

6.

1 7.

6 2.

02

1045

12

20

0.50

1050

1055

1100

1105

1110

1130

1135

1140

5.79

12

2 13

.7

3.02

15

30

12.8

0 0.

60

-7.0

5 -4

0.0

1540

1545

1550

1555

1600

1605

1610

5.79

12

2 13

.7

2.00

11

45

18.4

0 0.

80

1150

1155

1200

1205

1210

1212

1218

1242

1245

5.85

18

.3

19.8

3.

06

1329

15

50

0.70

-6

.90

-40.

5 13

5013

5814

0514

1014

1514

2014

2514

3014

3514

385.

85

18.3

19

.8 2

.04

945

16.7

0 0.

50

950

955

1000

1005

Tem

erat

ure

C 13.1

132

13.4

13.2

13.5

13.8

14.0

13.8

14.6

14.6

14.6

14.6

14.6

14.5

14.4

14.0

14.1

142

142

14.4

14.3

14.4

14.3

14.4

14.6

13.6

13.6

13.5

13.4

13.4

13.5

13.7

13.6

13.5

13.4

13.5

13.6

13.6

pH 4.9

4.9

4.9

4.8

4.8

4.8

4.8

4.8

5.0

5.0

5.0

5.0

5.0

5.0

5.0

5.1

52 52 52 52 52 52 52 52 5.8

5.7

5.7

5.7

5.7

5.7

5.7

5.7

5.7

5.7

5.5

5.6

5.6

5.5

i 1

DO

i

4.0

4.4

4.4

5.0

5.0

5.0

5.0

5.0

1.1

1.3

1.3

1.4

1.6

1.6

1.6

45 *T«»*

5.4

5.5

5.6

5.7

5.7

5.8

5.9

5.9

5.0

7.6

7.5

7.4

7.3

72

72

7.1

7.1

7.1

10.1

10.1

10.1

Spec

ific

Con

ucta

nce

372

372

371

371

371

370

370

371

_

379

_

374

364

JVT

363

363

362

362

362

362

362

362

261

257

347

346

346

346

App

endi

x A

. - -S

umm

ary of w

ell c

onst

ruct

ion

and

wat

er q

uali

ty d

ata

(co

nt)

N>

Form

atio

n

Sam

plin

g or

gro

up;

Wel

l W

ell

Loca

l da

te

hydr

ogco

logi

c

no.

nam

e id

entif

ier

Type

La

titud

e Lo

ngitu

de

(moi

U/y

r) le

tting

65 P

h23-

14

C4

3838

54

7512

20

1Q/3

1/90

B

SR

65 P

h23-

14

C4

3838

54

7512

20

04/0

4/91

B

SR

70 P

hl3

-30

SX20

1 C

l 38

3939

75

1201

04

/03/

91

BS

R

71 P

hl3

-29

SX10

1 C

2 38

3939

75

1201

10

/30/

90

BS

R

Triti

um

Tim

e

Alti

tude

To

p Bo

ttom

Dep

th

Pum

p Tr

itium

on

e of

T

emp-

ofla

nd

of

of

to

star

t co

ncen

- ad

. D

elta

D

elta

m

eat-

en

ture

surf

ace

icre

en

rree

n w

ater

tim

e tra

tion

dev.

O

-18

D

urem

ent

C

1010

1017

1034

1040

23.8

25

.3

3.03

12

20

22.9

0 0.

90

-6.6

5 -3

75

12

3512

4012

4512

5012

5513

0013

0513

1013

1513

2013

23S

Rfi

21 8

2S

1 4 9

9 81

? 2S

1(1

1

9ft

Sd.7

847

852

857

902

903

909

935

940

3.44

3.

7 4.

6 1.

04

1515

11

.80

050

-6.1

0 -3

3.0

1518

1521

1524

1527

1529

1535

1541

1545

3.44

22

.9 2

3.8

1710

13

.70

0.60

-6

.80

-37

5

1720

1725

1730

1735

1740

1745

13.7

13.6

13.6

13.8

13.7

13.7

13.7

135

135

13.5

135

135

13.5

135

13.6

13.4

13.4

135

135

135

135

135

135

13.6

10.8

10.7

10.8

10.8

11.0

10.8

10.8

10.8

13.3

13.3

133

13.3

13.3

13.3

pH 5.6

5.6

5.5

5.5

5.5

5.6

55 5.5

55 55 55 5.6

5.6

5.6

5.6

5.4

5.4

5.4

55 5.4

5.4

5.4

55 5.4

5.1

5.0

4.9

4.9

4.9

4.9

4.9

4.9

5.3

5.3

53

53 5.3

5.3

Spec

ific

Con

d-

DO

uc

tanc

e

10.1

10.1 9.8

9.8

3.3

3.5

3.6

3.7

3.7

3.8

3.8

3.8

3.8

3.8

3.8

5.2

5.2

5.2

6.0

6.2

6.4

6.4

6.4

6.4

4.0

3.0

2.4

3.4

1.8

1.6

1.6

1.6

4.6

4.6

4.6

45 4.4

4.4

346

345

345

345

_

349

_ _

_

_ _

347

__

412

411

410

410

410

409

409

406

406 79 71 71 72 73 72 72 72

__

108

_ _

__

106

App

endi

x A

. -

Sum

mar

y of w

ell c

onst

ruct

ion

and

wat

er q

uali

ty d

ata

(con

t.)

to 0\

Form

atio

n

Sam

plin

g or

grou

p;

Wel

l W

ell

Loca

l da

ce

hydr

ogeo

logi

c

no.

nam

e id

entif

ier

Type

L

atitu

de

Lon

gitu

de

(mcv

d/yr

) le

tting

71 P

hl3-

29

SX10

1 C

2 38

3939

75

1201

04

/03/

91

BS

R

TR

AN

SE

CT

C72

DO

Ce

89

DO

401

I 38

3123

76

0313

1V

16/9

0 K

ILG

73 D

O C

g 46

D

O40

3S

Cl

3832

18

7552

28

1V13

/90

BS

LG

74 D

O C

g 45

D

O40

3D C

2 38

3218

75

5228

1V

13/9

0 B

SL

G

Tri

tium

T

ime

Alti

tude

T

op

Bot

tom

Dep

th

Pum

p T

ritiu

m

one

of

of la

nd

of

of

to

(ait

con

cen-

ltd

. D

elta

D

elta

m

eas-

urf

ace

scre

en

scre

en

wat

er

time

trat

ion

dev.

O

-18

D

ur

emen

t

1750

1755

3.44

22

.9

23.8

0.

98

1407

23

.60

0.90

1407

1410

1420

1425

1430

1434

1439

1445

1452

1502

1510

3.66

4.

4 5.

3 1.

71

1456

5.

19

0.27

-6

.60

-38.

0 15

1515

2015

2515

3015

3515

4015

455.

49

4.3

5.2

1.17

16

44

23.6

0 1.

10

-6.9

5 -4

1.0

1655

1700

1705

1710

1715

1720

1725

5.49

14

.2

15.1

1.

11

1525

4.

18

0.26

-6

.65

-40.

5 16

0016

0516

1016

1516

2016

2516

3516

40

Tem

erat

ure

C 13.3

13.3

13.6

13.6

13.4

14.0

13.6

13.5

13.4

13.2

13.3

13.3

13.3

18.8

18.8

18.8

18.7

18.8

18.8

18.7

16.7

16.7

16.7

16.7

16.8

16.9

17.0

14.0

14.0

14.1

14.0

13.9

14.0

14.0

14.0

pH 5.2

5.2

5.1

5.1

5.3

5.3

5.3

5.3

5.3

5.3

5.3

5.3

5.3

6.0

6.0

6.0

6.0

6.0

6.0

6.0

4.8

4.8

4.8

4.8

4.8

4.8

4.8

6.1

6.1

6.1

6.1

62

62

62 6.1

i iD

O

i

4.5

4.5

5.5

5.5

5.6

62 62 6.2

62 6.1

6.4

6.4

6.4

0.4

0.4

0.4

0.3

0.3

0.3

0.3

0.4

0.3

0.4

0.3

03 0.3

0.4

5.3

2.2

1.9

1.8

1.7

1.7

1.6

15

Spec

ific

Con

ucta

nce

165

165

163

164

163

164

164

164

163

164

163

438

_ _

442

_

441

_ 94 94 94 _ 94 84 83

84 79

75 W

I Be

52

WO

404D

I

3826

44

7536

12

1V12

/90

BS

C

14.3

3 14

.0

14.9

4.4

0 74

0 11

.90

0.70

-6

.85

-39.

5 80

5 14

.1 4

.9

11.0

App

endi

x A

. -S

umm

ary

of w

ell c

onst

ruct

ion

and

wat

er q

uali

ty d

ata

(con

t.)

Form

atio

n

Sam

plin

g or

gro

up;

Wdl

W

ell

Loca

l da

te

bydr

ogeo

logi

c

no.

nam

e id

entif

ier

Typ

e L

atitu

de

Lon

gitu

de

(mof

l/yr)

««

ting

76W

IBgl8

W

O40

5S C

l 38

2508

75

2712

1V

12/9

0 P

aR

76 W

I B

g 18

W

0405

S C

l 38

2508

75

2712

04

/03/

91

Pa R

77 W

I B

g 17

W

0405

D C

l 38

2508

75

2712

1V

12/9

0 B

S C

77 W

I B

g 17

W

O40

5D C

l 38

2508

75

2712

04

/03/

91

BS

C

Tri

tium

T

ime

Alti

tude

T

op

Bot

tom

Dep

th

Pum

p T

ritiu

m

one

of

of la

nd

of

of

to

Can

con

cen-

«d

. D

elta

D

elta

m

eas-

urf

ace

icre

en

icre

en

wat

er

time

trat

ion

dev.

O

18

D

urem

ent

815

820

825

831

835

840

845

852

900

907

912

915

19.8

1 3.

7 4.

3 2.

33

1124

15

.50

0.80

-6

.40

-34.

5 10

3010

3510

4010

4510

5010

5511

0011

0511

1011

1519

.81

3.7

4.3

0.91

16

24

1640

1650

1655

1700

19.8

1 15

.2

16.2

7.

07

1013

3.

60

0.40

-6

.65

-36.

5 11

5011

5512

0012

0512

1012

1512

1812

2512

2819

.81

15.2

16

.2

5.43

15

15

1540

1550

1555

Tem

erat

ure

C 14.1

14.1

14.1

14.1

14.0

13.8

13.9

13.8

13.9

13.8

13.8

13.8

15.2

16.1

15.4

15.3

15.4

15.9

15.8

15.6

15.7

15.6

11

/I

1Z.O

12.4

12.2

12.2

14.0

13.7

13.8

13.7

13.7

13.9

13.7

13.7

13.8

14.5

14.4

14.4

PH 4.9

4.8

4.9

4.9

4.9

4.9

4.9

4.8

4.9

4.9

4.9

4.8

5.0

5.1

5.1

5.1

5.1

5.0

5.0

5.0

5.0

5.0

<2

J~

£t

52,

52,

52

5.7

5.8

5.9

5.9

6.0

5.9

5.9

5.9

5.9

g- f

\O

.Z 62

62

< {

DO

i

11.0

11.0

10.8

10.6

10.7

10.8

10.8

10.8

11.0

11.0

10.8

10.9 1.1

1.1

12 0.8

0.7

0.8

0.6

0.6

0.6

0.6

0.6

0.6

0.5

0.5

0.3

0.3

0.3

03 0.3

0.4

0.3

0.3

0.3

0.1

2.5 1.6

Spec

ific

Con

ucta

nce

--

149

--

--

154

--

-- 73

-

--

__ 72 --

75 73 72 71 -- 50 -

50 __

__ 48 47 47

App

endi

x A

- -S

umm

ary

of w

ell c

onst

ruct

ion

and

wat

er q

uali

ty d

ata

(con

t.)

oo

Form

atio

n

Sam

plin

g or

gro

up;

Wel

l W

ell

Loca

l da

te

bydr

cgeo

logk

no.

nam

e id

ertif

ier

Type

La

titud

e Lo

ngitu

de

(mot

dfyr

) le

tting

78 W

O B

f 87

WR

402S

C

l 38

2332

75

1418

1V

12/9

0 B

SR

79 W

O B

f 86

WR

402D

C2

3823

32

7514

18

1V12

/90

BS

R

80 W

O C

g 80

W

R40

3S

Cl

3818

44

7509

32

1V13

/90

SiR

80 W

O C

g 80

W

R40

3S C

l 38

1844

75

0932

04

/04/

91

SiR

Triti

um

Tim

e

Alti

tude

T

op

Bot

tom

Dep

th

Pum

p Tr

itium

on

e of

T

emp-

of la

nd

of

of

to

*att

conc

en-

*d.

Del

ta

Del

ta

mea

t-

erat

ure

til-fa

ce

nree

n ic

reen

w

ater

tim

e tra

tion

dev.

O

-18

D

urem

ent

C

1600

1605

1610

1615

1620

10.0

6 4.

6 5.

5 1.

65

1345

12

.40

0.60

-6

.40

-36.

0 13

5514

0014

0514

1014

1514

2014

2514

3014

3514

4014

4514

5010

.06

14.2

15

.1

1.70

14

56

14.8

0 0.

70

-650

-36.

0 15

2015

2515

3015

3515

4015

4515

5015

5515

2 3.

7 4.

3 0.

14

1250

8.

80

0.50

-5

.50

-27.

5 13

0713

1213

1713

2213

2713

3213

3713

421.

52

3.7

4.3

0.02

14

55

14.7

0 0.

60

1500

1510

1515

1520

1525

14.3

14.3

14.3

14.4

14.3

17.3

17.2

112

17.2

17.4

112

112

112

17.4

173

173

17.3

14.0

14.0

13.9

13.9

13.9

13.8

13.7

13.7

112

17.8

17.8

17.8

17.6

17.6

17.6

17.6

14.1

14.3

142

14.3

14.1

pH 6.2

6.2

6.2

62

62

5.6

5.6

5.6

5.5

5.5

5.5

5.5

55 5.5

55 55 55 53 52

52

52

52

52

52

52 6.5

65 6.4

6.4

6.3

6.3

6.3

62

6.6

6.3

62 62 6.1

Spec

ific

Con

d-

DO

uc

tanc

e

1.3

12 0.8

0.6

0.5

7.7

7.7

7.7

7.7

7.7

7.7

7.7

7.7

7.7

7.7

7.7

7.7

9.0

92

8.9

9.0

9.0

9.0

9.0

9.1

0.8

12 1.4

1.4

1.4

1.3

1.1

1.1

1.3

1.3

1.4

1.5

1.5

47 47 47 47 47 --

313

307

--

151

146

79 79

84 84 112

102 97 95 94

App

endi

x A

. - -S

umm

ary

of w

ell c

onst

ruct

ion

and

wat

er q

uali

ty d

ata

(con

t.)

Form

atio

n

Sam

plin

g or

gro

up;

Wel

l W

ell

Loca

l da

te

nydr

ogeo

logi

c

no.

nam

e id

entif

ier

Typ

e L

atitu

de

Lon

gitu

de

(mat

ter)

le

tting

81 W

O C

g 79

W

R40

3DC

2 38

1844

75

0932

1V

13/9

0 B

SD

81 W

O C

g 79

W

R40

3DC

2 38

1844

75

0932

04

/04/

91

BS

D

81 W

O C

g 79

W

R40

3DC

2 38

1844

75

0932

12

/23/

92

BS

D

82 W

O C

g 78

P2

8S

Cl

3817

54

7508

36

11A

3/90

S

iLG

83 W

OC

g77

P28I

C

2 38

1754

75

0836

1V

13/9

0 S

iLG

Tri

tium

T

ime

Alti

tude

T

op

Bot

tom

Dep

th

Pum

p T

ritiu

m

one

of

Tem

p-

otla

nd

of

of

to

*art

coo

cen-

«d

. D

elta

D

elta

m

eai-

er

atur

e

Hjr

ttce

icre

en

icre

en

wat

er

time

trat

ion

dev.

O

-18

D

ur

emea

C

1545

1550

1.52

12

.3

133

0.16

11

50

0.01

0.

14

-6.1

5 -3

4.0

1205

1210

1215

1220

1225

1230

1235

1240

1245

152

173

1^3

Flo

wn

141S

ft

fl?

0 I

fi

1417

1421

1424

1430

1435

1440

1449

1 S?

171

1^3 F

lnw

i 94

O

9S5

1008

1020

1027

1047

1054

1058

1103

1107

1114

3.66

3.

0 4.

0 2.

60

905

10.9

0 0.

60

-6.4

0 -3

7.0

910

915

920

925

930

935

940

945

3.66

9.

1 10

.1

251

742

18.6

0 0.

60

-6.5

5 -3

75

810

815

14.1

14.1

13.7

13.7

13.9

13.8

13.6

13.8

13.8

13.7

13.9

15.5

15.7

15.7

15.5

15.6

15.6

15.5

14.9

15.0

15.0

15.0

14.7

14.7

14.7

14.7

14.7

14.7

17.0

17.0

17.0

17.0

17.1

17.0

16.9

17.0

14.9

14.9

pH 6.0

6.0

6.6

6.5

6.5

6.5

6.5

6.5

6.5

6.5

6.5

6.1

6.1

6.2

6.3

6.4

6.4

6.4

6.3

6.5

6.5

6.5

6.6

6.5

6.5

6.6

6.6

6.5

4.8

4.8

4.8

4.8

4.8

4.7

4.8

4.8

6.7

6.7

Spec

ific

Con

d-

DO

uc

tanc

e

1.5

1.5 0.3

0.4

0.3

0.3

0.3

0.2

0.2

0.2

0.2

1.0

1.0

0.8

0.9

0.8

0.8

0.8

0.4

0.3

0.2

0.2

0.2

0.2

0.2

0.2

0.2

0.2

0.3

03 0.3

03 03 03 03 0.3

03

0.3

90 88 132

129

129

129

130

130

130

130

130

130

130

133

132

130

129

130

130

130

130

130

130

123

126

131

131

206

206

App

endi

x A

. -

Sum

mar

y of w

ell c

onst

ruct

ion

and

wat

er q

uali

ty d

ata

(con

t)

UJ

O

Form

atio

n

Sam

plin

g or

grou

p;

Wel

l W

ell

Loca

l da

te

hydr

cgco

logk

no.

nam

e

idei

tifie

r Ty

pe

Lat

itude

L

ongi

tude

(m

ofl/y

r)

letti

ng

83 W

O C

g 77

P2

8I

C2

3817

54

7508

36

04/0

4/91

Si

LG

84 W

O C

g 76

P2

8D

C3

3817

54

7508

36

04/0

4/91

B

S L

G

WIL

LA

RD

S N

ET

WO

RK

OF

TR

AN

SE

CT

C85

WIC

h56

WS1

06

Cl

3824

52

7520

29

11/1

4/90

P

aR

85W

ICh56

WS1

06

Cl

3824

52

7520

29

04/0

5/91

P

aR

R^w

TO

iSA

w

sirv

; n

ISO

AV>.

T&

mo

wm

m

Pa R

Tri

tium

T

ime

Alti

tude

T

op

Bot

tom

Dep

th

Pum

p T

ritiu

m

one

of

Tem

p-

ofla

nd

of

of

to

cart

con

cen-

st

d.

Del

ta

Del

ta

mea

l-

erat

ure

surf

ace

n-ee

n sc

reen

w

ater

tim

e tr

atio

n de

v.

O-1

8

D

urem

eit

C

820

826

830

835

841

845

850

856

900

3.66

9.

1 10

.1

0.91

17

07

21.2

0 0.

80

1712

1717

1722

1727

1730

1740

1800

1805

3.66

21

.3 2

7.4

1800

0.

11

0.14

-5

.95

-34.

0 18

2018

2518

45

12.5

5 4.

6 5

2

3.11

10

17

10.7

0 0.

50

-6.4

5 -3

5.5

0 5 10 15 End

12.5

5 4.

6 52

2.

53

905

908

910

912

914

916

920

925

932

935

17 «

4/

i *o

nm

-

_

1*54

.

15.0

14.9

15.0

14.8

14.8

14.8

14.9

14.8

14.8

15.3

15.4

15.4

15.4

15.4

15.4

15.3

15.3

14.0

14.4

13.5

15.1

15.1

11.1

12.7

15.6

13.2

12.8

12.9

12.9

132

13.2

13.3

13.2

13.2

147

PH 6.8

6.9

6.9

6.9

6.7

6.8

6.8

6.8

6.9

6.5

6.7

6.8

6.8

6.7

6.8

6.8

6.8

6.8

7.0

7.3

5.3

5.3

5.3

5.3

52 5.1

5.0

5.1

5.2

52 52 5.3

5.3

SR

Spec

ific

Con

d-

DO

uc

tanc

e

0.3

0.3

0.3

0.3

0.3

03 0.3

0.3

0.3

1.3

0.9

0.9

0.8

0.8

0.8

0.8

0.8

0.7

0.7

0.7

0.3

02 0.0

0.0

0.0

2.7

2.7

2.6

2.6

2.5

2.4

2.4

2.5

2.4

1 *

207

__

__

210

205

230

229

228

228

228

227

227

227

219

218

218

159

161

162

163

164

180

164

164

165

167

171

174

175

174

App

endi

x A

. -S

umm

ary

of w

ell c

onst

ruct

ion

and

wat

er q

ualit

y da

ta (

cont

.)

Form

atio

n Tr

itium

Ti

me

Sam

plin

g or

grou

p;

Alti

tude

To

p B

otto

m D

epth

Pu

mp

Triti

um

one

of

Wel

l W

ell

Loca

l da

te

bydr

ogeo

lagi

c of

land

of

of

to

*a

it co

ncen

- *d

. D

elta

D

elta

m

eat-

no,

nam

e Id

entif

ier

Type

La

titud

e Lo

ngitu

de

(moK

/yr)

le

tting

su

rface

cr

een

cree

n w

ater

tim

e tra

tion

dev.

O

-18

D

urem

ent

1332

1340

1347

1350

1356

1405

1412

86W

ICh57

WS2

06

C2

3824

52

7520

29

1V14

/90

BS

R

12.6

6 14

.3

15.2

3.05

80

5 15

.80

0.70

-6

.45

-35.

5 0 10 15 20 25 79 End

86

WIC

h5

7

WS2

06

C2

3824

52

7520

29

04/0

5/91

B

SR

12

.66

14.3

15

.22.

53

747

15.4

0 0.

60

757

802

807

813

827

840

848

853

900

86

WIC

h5

7

WS

206

C2

3824

52

7520

29

12/2

3/92

B

SR

12

.66

143

15.2

1305

1425

1433

1440

1450

1505

1510

1515

1519

1524

1528

1532

1536

87W

IBhll

W

S21

0 I

3826

26

7520

18

1V14

/90

BS

C

10.5

1 9.

4 10

.4

1.11

13

40-0

.15

0.14

-6

30

-35.

0 0 5 10

Tem

erat

ure

C 14.7

14.7

14.6

14.7

14.7

14.7

14.7

12.9

13.0

13.0

13.1

12.9

12.9

13.2

14.2

14.2

14.3

14.3

14.4

14.4

14.6

14.4

14.4

14.0

14.0

14.0

14.0

13.9

13.9

13.9

13.9

13.9

13.9

13.9

13.9

135

135

13.7

pH 5.8

5.8

5.8

5.8

5.8

5.8

5.8

5.5

5.5

5.6

5.6

5.5

5.6

5.6

5.6

5.7

5.7

5.7

5.7

5.6

50 .O 5.8

5.8

5.8

5.9

5.9

5.9

5.9

5.9

5.9

5.9

5.9

6.0

6.1

6.1

I

DO

i

1.3

13 13 13 13 13 1.3

0.5

0.1

0.1

0.1

0.1

0.1

0.1

0.7

0.6

0.6

0.6

0.5

0.5

0.5

0.5

0.4

0?

\l^r

02.

02,

02,

02,

02,

0.1

0.1

0.1

0.1

0.1

0.1

05

0.5

0.1

Spec

ific

Con

ucta

nce

165

164

164

163

163

162

161

150

299

308

313

315

339

342

320

J£A

J

321

321

325

328

329

337

332

337

f\ri

261

261

262

263

273

274

272

272

272

270

271

271

151

146

145

App

endi

x A

. -

Sum

mar

y of w

ell c

onst

ruct

ion

and

wat

er q

ualit

y da

ta (

cont)

Wel

l W

ell

Loca

l

no._

___m

ine_

___id

enti

fier

T

ype

Lat

itude

Lon

gitu

de

Form

atio

n T

ritiu

m

Sam

plin

g or

gro

up;

Alti

tude

T

op

Bot

tom

Dep

th

Pum

p T

ritiu

m

one

date

by

drog

eolo

gk

of la

nd

of

of

to

tart

con

cen-

*d

.

(mo/

d/yr

)___

_let

ting

m

rfac

e gr

een

cree

n w

ater

tim

e tr

atio

n de

v.

Del

ta

0-1

8

Del

ta

D

Tim

e

of

Tem

p-

Spec

ific

mea

s-

erat

ure

Con

d-

urem

ent

C

pH

DO

uc

tanc

e

15

13.6

6.1

0.

1 14

5 E

nd

13.8

0.

1 14

4

N)

oi

moil

11

wo,

6ivi

i

jo^u

^o

fO6u

io

ut/

UJ/

-'i

DO

v_

88W

IBh8

WS1

08

Cl

3826

09

7521

05

04/0

5/91

A

ID

89W

IBH

9 W

S208

C

2 38

2609

75

2105

04

/05/

91

BS

C

90 W

I B

h 4

WS

103

Cl

3825

43

7521

22

04/0

5/91

Pa

R

91 W

I B

h 5

WS

203

C2

3825

43

7521

22

04/0

5/91

B

S C

1210

1215

1220

1222

1225

1230

1234

11.0

6 3.

4 4.

0 1.

83

1108

5.

53

024

-63

0

-35.

5 11

1211

1611

2011

2111

2511

3011

3511

.06

11.6

12

.5

123

1015

-0.

10

0.13

-6

.00

-34.

5 10

2010

2510

3010

3510

4010

4510

5511

0312

23

3.0

3.7

122

1430

13

20

0.60

-5

.95

-32.

5 14

3514

4014

4514

4714

5014

5515

0015

0311 ^

1

ft

-9

-t f\

-t

1 O

£.

-t *

>1O

1*JA

Q

1410

1420

14.4

14.4

14.4

14.4

14.4

14.4

145

145

14.7

14.9

15.1

15.4

155

15.4

152

15.0

15.0

14.9

14.8

14.8

14.8

14.8

16.1

13.9

13.7

13.8

13.8

13.9

13.8

13.9

16.0

165

165

o.u

5.9

5.9

5.9

5.9

5.9

6.0

5.9

6.1

6.1

6.1

6.1

6.1

6.1

6.1

62

62 62 62

62

62 62 62 5.9

5.5

5.4

5.4

5.4

5.4

5.4

5.4

5.9

5.9

6.0

VI.

J

0.5

05 0.5

0.5

0.5

0.5

0.5

0.5

0.5

0.5

0.5

0.5

0.5

0.5

0.5

0.5

0.5

05 0.5

0.5

0.5

0.5

1.4

0.8

0.8

0.8

0.7

0.7

0.7

2.8

2.8

ijz,

148

147

147

146

146

145

144

203

202

205

206

209

213

212

167

165

165

165

165

165

165

165 82 105

116

117

119

122

123

125

fyrj

O / 87 89

App

endi

x A

-S

umm

ary

of w

ell c

onst

ruct

ion

and

wat

er q

uali

ty d

ata

(con

t.)

Form

atio

n T

ritiu

m

Tim

e

Sam

plin

g or

g-ou

p;

Alti

tude

T

op

Bot

tom

Dep

th

Pum

p T

ritiu

m

one

of

Tem

p-

Spec

ific

Wel

l W

ell

Loca

l da

te

nydr

ogeo

logt

c of

land

of

of

to

«a

n co

ncen

- ltd

. D

elta

D

elta

m

eas-

er

atur

e C

ond-

no._

___nam

e____id

enti

fier

T

ype

Lat

itude

L

ongi

tude

(m

oAlf

rr)_

___l

etti

ng

surf

ace

gree

n »c

reen

w

ater

tim

e (r

atio

n de

v.

O-1

8_

__

_D

__

_u

rero

ent

C

pH

DO

uc

tanc

e

92 6

6M41

A

C20

1D

I 37

5744

75

3536

1V

15/9

0 Y

oC

3.05

11

.9

12.8

2.33

15

37

1.50

0.

18

-6.0

5 -3

3.5

1550

14

.16.

1 0.

8 17

515

55

14.3

6.1

0.

5

1600

14

.4 6

.1

0.4

175

1605

14

.4 6

.1

0.4

1610

14

.4 6

2

0.4

1615

14

.3 6

.1

0.3

171

1620

14

.4 6

.1

0.3

1625

14

.3 6

.1

03

9266

M41

A

C20

1D

I 37

5744

75

3536

04

/04/

91

YoC

3.

05

11.9

12

.8

1.36

15

57

222

0.14

1610

14.9

62

0.1

157

1615

14

.9 6

2

0.1

157

1620

14

.9 6

2

0.1

157

1625

14

.9 6

2

0.1

157

1630

14

.9 6

2

0.1

157

1635

14

.8 6

2

0.1

157

1640

14

.9 6

2

02

156

1645

14

.8 6

2

0.1

157

1650

14

.9 6

2

0.1

157

9266

M41

A

C20

1D

I 37

5744

75

3536

12

/22/

92

YoC

3.

05

11.9

12

.8

1215

1247

14

.8 6

5

03

171

1253

14

.8 6

2

03

171

1302

14

.8 6

2

02

17

113

08

14.9

62

02

171

1321

14

.8 6

2

03

173

1329

14

.9 6

2

02

172

1330

14

.8 6

2

0.3

172

1340

14

.8 6

2

03

172

1349

14

.8 6

2

02

172

1355

14

.8 6

2

02

17

214

00

14.8

62

02

172

1450

14

.5 6

2

OS

172

1456

14

.6 6

3 03

17

215

03

14.6

62

02

172

93 6

6M19

SO

W lif

t I

3757

23

7534

44

1V16

/90

KIC

3.

35

7.9

11.0

33

6 73

3 13

50

0.50

-6

.35

-35

5

825

14.6

52

02

9783

0 14

.6 5

2 0.

1 97

835

14.6

52

0.1

9784

0 14

.6 5

.1

0.1

9784

5 14

.6 5

2 02

97

850

14.6

5.1

0.

1 97

855

14.7

52

0.

1 97

App

endi

x A

. -S

umm

ary of w

ell c

onst

ruct

ion

and

wat

er q

uali

ty d

ata

(con

t.)

Form

atio

n

Sam

plin

g or

p-ou

p;

Wel

l W

dl

Loca

l da

te

bydr

cgeo

logi

c

no.

nam

e id

entif

ier

Type

La

titud

e Lo

ngitu

de

(moA

tyr)

le

tting

94 6

6M42

A

C20

3 I

3756

23

7533

03

11/1

6/90

O

mC

95 6

6M44

A

C20

4S

Cl

3755

35

7532

49

11/1

5/90

O

mC

9666

M45

A

C20

4D C

2 37

5535

75

3249

11

/15/

90

Om

C

97 6

6M46

A

C20

5S

I 37

5552

75

3018

11

/15/

90

Om

C

Triti

um

Tim

e

Alti

tude

T

op

Bot

tom

Dep

th

Pum

p Tr

itium

on

e of

of la

nd

of

of

to

tart

con

cen-

«d

. D

elta

D

elta

m

ea»-

rarf

ace

scre

en

Bre

en

wat

er

time

tratio

n de

v.

O-1

8 D

ur

emen

t

900

905

6.71

4.

3 5.

2 1.

62

941

0.14

0.

14

-6.2

5 -3

4.0

1005

1015

1020

1025

1030

1035

1040

1045

8.23

5.

9 6.

9 2.

36

1648

17

20

0.70

-6

.15

-33.

0 16

5517

0017

0517

1017

1517

2017

2517

3017

3583

3 13

.9

14.8

2.2

2 15

39

20.8

0 1.

00

-6.4

5 -3

6.0

1600

1605

1610

1615

1620

1625

1630

1635

1640

1645

9.14

5.

8 6.

7 2.

45

1416

19

.50

0.80

-6

.20

-32.

0 14

3014

3514

4014

4514

5014

5515

00

Tem

erat

ure

C 14.7

14.7

17.0

17.0

16.9

16.7

16.7

16.6

16.6

16.6

16.6

16.6

16.6

16.6

16.6

16.6

16.6

153

153

153

153

153

153

152

152

152

152

15.7

15.7

15.7

15.5

15.6

15.5

15.5

pH 5.2

5.2

6.4

6.4

6.5

6.5

6.5

6.5

6.5

6.5

5.1

5.1

5.1

5.1

5.1

5.1

5.1

5.4

5.7

5.7

5.7

5.7

5.0

5.0

5.0

5.0

5.0

5.0

5.0

Spoc

iOc

Con

d-

DO

uc

tanc

e

02 0.2

0.4

0.0

0.0

0.0

0.0

0.0

0.0

0.0

0.0

0.0

02 0.0

0.0

0.0

0.0

0.0

0.0

0.0

0.0

0.0

2.3

2.4

2.4

2.5

2.5

25 25

97 97 150

150

151 15

123

022

121

721

421

421

321

321

321

331

032

032

533

033

333

834

134

334

534

743

6

440

445

TR

AN

SE

CT

E

98 6

3F25

W

ell 1

I

3711

45

7556

59

1V14

/90

JN&

WaD

3.

77

1.1

2.0

0.32

93

3 21

.00

0.80

-6

.25

-35.

0 94

5 16

.76.

3 3.

1 49

0

App

endi

x A

. -S

um

ma

ry o

f wel

l con

stru

ctio

n an

d w

ater

qua

lity

dat

a (c

ont)

Wel

l W

ell

no.

nam

e

99 6

3F26

100

63F

49

100

63F

49

101

63F

44

Form

atio

n Tr

itium

Ti

me

Sam

plin

g cr

youp

; A

ttitu

de

Top

Bot

tom

Dep

th

Pum

p Tr

itium

on

e of

Loca

l da

te

bydr

cgeo

logi

c of

land

of

ot

to

ta

ct c

once

n-

td.

Del

ta

Del

ta

mea

i-

iden

tifie

r Ty

pe-

Latit

ude

Long

itude

(m

atte

r)

Jetti

ng

lurf

ace

vree

n ar

een

wat

er

time

tratio

n de

v.

O-1

8 D

ur

emen

t

950

955

1000

1005

1010

1015

1020

Wel

l 2

I 37

1143

75

5658

11

/14/

90 J

N&

WaR

4.

68

1.8

2.7

1.12

82

3 10

.90

0.50

-6

.80

-38.

0 85

085

590

090

591

091

592

092

5W

elH

E

Cl

3711

25

7557

02

11/1

4/90

N

aR

8.34

4.

2 5.

1 3.

72

1647

8.

90

0.40

-5

.80

-31.

5 16

5517

0017

0517

1017

2017

2517

3017

3517

40W

ell4

E

Cl

3711

25

7557

02

04/0

5/91

N

aR

8.34

4.

2 5.

1 32

6 13

12

11.7

0 0.

50

1325

1330

»,

1335

1340

1345

1350

1355

1400

Wel

HB

C

2 37

1125

75

5702

11

/14/

90

NaR

8.

33

7.0

7.9

3.72

13

12

12.9

0 0.

60

-6.3

5 -3

5.0

1330

1335

1340

1345

1350

1355

Tem

erat

ure

C 16.8

16.7

16.7

16.7

16.8

16.8

16.9

18.9

18.7

18.8

19.1

19.1

19.4

19.4

19.6

17.8

18.3

175

18.0

17.8

17.8

17.8

17.8

17.8

145

14.4

14.4

14.4

14.6

145

14.4

14.4

17.4

17.4

17.6

17.4

17.6

17.6

pH 6.3

6.3

6.3

6.3

6.3

6.3

6.3

5.3

5.3

5.3

5.3

5.3

5.3

5.3

5.3

5.9

55 6.3

55 55 5.4

5.4

5.4

5.4

C O

J.O 5.8

5.7

5.7

5.7

5.7

5.6

5.6

5.4

5.3

5.4

5.4

5.3

5.4

1

DO

i

3.3

3.5

3.7

3.8

3.8

3.9

3.8

3.9

3.9

3.8

3.8

3.8

3.8

3.7

3.6

8.7

8.7

8.6

8.6

8.6

8.5

8.5

8.5

*7 o /.o

7.9

8.1

8.0

7.8

8.0

82.

8.0

8.6

8.6

8.3

8.1

83

83

Spec

ific

Con

ucta

nce

489

490

490

328

323

313

674

653

657

657

659

661

661

300

J\A

/

300

298

297

2% 2% 294

294

324

322

__

Appe

ndix

. A. -

Sum

mar

y of w

ell c

onst

ruct

ion

and

wat

er q

ualit

y dat

a (c

ont.)

Form

atio

n Tr

itium

Ti

me

Sam

plin

g or

grou

p;

Alti

tude

To

p B

otto

m D

epth

Pu

mp

Triti

um

one

of

Tem

p-

Spec

ific

Wel

l W

ell

Loca

l da

te

bydr

ogeo

logi

c of

land

of

of

to

ca

n co

ncen

- td

. D

elta

D

elta

m

eal-

er

atur

e C

ond-

no._

____

nam

e___

_ide

ntif

ier

Type

La

titud

e Lo

ngitu

de

(moU

/ft)

____

_let

ting

mria

ce

gree

n gr

een

wat

er

time

trat

ion

dev.

O

-18____D

or

emen

t C

pH

D

O

ucta

nce

1400

11

2 5.

3 8.

2 31

914

05

16.6

5.4

8.

3

1016

3F44

W

eH4B

C

2 37

1125

75

5702

04

/05/

91

NaR

8.

33

7.0

7.9

3.90

12

10

13.1

0 05

0 -

1220

16

.05.

5 8.

2 24

012

25

16.0

5.5

8.

2 23

612

30

16.0

5.5

8.

2 26

312

35

16.0

5.5

82

262

1240

16

.0 5

,5

7.5

262

1245

16

.1 5

.5

7.9

261

1250

15

.8 5

.4

8.2

260

1255

15

.8 5

.4

8.2

259

1300

15

.9 5

.4

8.2

258

1026

3F45

W

ell4

C

C3

3711

25

7557

02

11/1

4/90

N

aR

8.21

11

.7

12.6

3.

55

1411

16

.60

0.70

-6

.30

-34.

5 14

25

14.7

6.1

7.9

449

1430

14

.6 6

.4

7.0

452

1435

14

5 6.

4 6.

6 45

214

40

14.8

65

62

453

1445

14

.8 6

5 6.

1 45

4..

1450

14

.8 6

5 5.

8

ON

1455

15

.0 6

5 5.

8

1500

15

.4 6

5 5.

7

1505

15

2 6.

5 5.

7 46

215

10

14.9

65

5.6

1026

3F45

W

ell4

C

C3

3711

25

7557

02

04/0

5/91

N

aR

821

11.7

12

.6

3.72

10

48

17.3

0 0.

60

1105

16

.46.

6 4.

1 32

711

10

16.4

6.6

5.

5 32

311

15

163

6.6

5.8

351

1120

16

.4 6

.6

5.8

348

1125

16

.4 6

.6

5.7

342

1130

16

.6 6

.6

5.7

343

1135

16

.7 <

>.6

5.7

340

1140

16

.4 6

.6

5.8

336

1145

16

.46.

6 5.

8 33

511

50

16.4

6.6

5.

8 33

311

55

16.4

6.6

5.8

336

1200

16

5 6.

6 5.

7 33

010

363F

46

Wel

UD

C

4 37

1125

75

5702

11

/14/

90

NaC

82

5 17

&

18.7

3.

74

1518

2.

95

0.19

-6

20

-3

4.0

1540

15

.97.

7 1.

5 36

515

45

15.7

7.8

1.

1 36

115

50

15.7

7.8

0.

8

1555

15

.9 7

.8

0.7

356

1600

16

.1 I

S

0.6

356

App

endi

x A

. -S

umm

ary of w

ell c

onst

ruct

ion

and

wat

er q

uali

ty d

ata

(con

t.)

OJ

Wel

l W

ell

no.

nam

e

103

63F

46

1046

3F29

105

63F

47

1066

3F30

Form

atio

n T

ritiu

m

Tim

e

Sam

plin

g or

grou

p;

Alti

tude

T

op

Bot

tom

Dep

th

Pum

p T

ritiu

m

one

of

Loc

al

date

by

drog

eolq

gic

of la

nd

of

of

to

cart

con

cen-

«d

. D

elta

D

elta

m

ea»-

idei

tirie

r T

ype

Lat

itude

L

ongi

tude

(m

o/U

tyr)

le

tting

su

rfac

e m

en

«ree

n w

ater

tim

e tr

atio

n de

v.

O-1

8

D

urem

ea

1605

1610

1615

1620

1628

1633

1638

Wel

UD

C

4 37

1125

75

5702

04

/05/

91

NaC

8.

25

17.8

18

.7

3.66

93

2 4.

00

0.40

1005

1010

1015

1020

1025

1030

1035

1040

1045

Wel

lSA

C

l 37

1121

75

5650

11

/14/

90 J

N&

Wa

R

4.02

2.

0 2.

9 12

0 12

11

10.4

0 0.

40

-6.5

0 -3

5.0

1220

1225

1230

1235

1240

1245

Wel

lSB

C

2 37

1121

75

5650

11

/14/

90 J

N&

Wa

R

4.10

7.

6 8.

5 12

0 10

53

19.8

0 0.

70

-62

0

-33.

0 11

1511

2011

2511

3011

4011

4511

5011

5512

0012

05W

ell 6

I

3711

28

7557

21

11/1

5/90

N

aR

8.83

3.

7 4.

6 3.

14

1124

11

.80

0.50

-6

.05

-33.

5 11

3011

3511

4011

4511

5011

55

Tem

erat

ure

C 15.9

16.9

17.3

16.8

15.6

14.8

142

16.3

16.1

16.1

16.2

16.4

16.2

16.4

16.1

16.1

202

20.7

20.7

20.7

21.0

20.8

16.7

16.8

16.8

16.6

17.0

16.5

16.6

16.6

16.8

17.1

17.8

17.9

17.8

17.8

17.8

17.9

pH 7.8

7.8

7.8

7.8

7.3

7.5

7.5

7.9

7.9

7.9

7.9

7.9

7.9

7.9

7.9

7.9

5.8

5.8

5.8

5.8

5.8

5.8

52 52 52

52 5.3

52 52 52 52 5.3

5.5

5.5

5.5

5.5

5.5

5.5

I

DO 0.

50.

50.

40.

511

.311

.111

.1 0.1

0.1

0.1

0.1

0.1

0.1

0.1

0.1

0.1

5.0

4.9

5.0

4.9

4.9

4.9

5.6

5.6

5.6

5.5

5.5

5.5

5.5

5.7

5.7

5.5

8.9

9.0

9.0

8.9

8.9

8.9

Spec

ific

Con

ucta

nce

350

0

onn

J\m 281

263

258

282

301

295

292

277

275

276 27

241

1

412

409

409

584

581

575

576

574

574

App

endi

x A

. -S

umm

ary of w

ell c

onst

ruct

ion

and

wat

er q

ualit

y da

ta (

cont

)

oo

Form

atio

n Tr

itium

Ti

me

Sam

plin

g or

grou

p;

Alti

tude

To

p B

otto

m D

epth

Pu

mp

Triti

um

one

of

Tem

p-

Wel

l W

ell

Loca

l da

te

bydr

ogeo

lqgi

c of

land

of

of

to

*

xt

conc

en-

*d.

Del

ta

Del

ta

mea

j-

enti

re

no.

nam

e id

entif

ier

Type

La

titud

e Lo

ngitu

de

(moy

td/y

r) le

tting

fu

rfac

e cr

een

cree

n w

ater

tim

e tra

tion

dev.

O

-18

D

urem

ent

C

1200

1205

1076

3F31

W

ell7

A

Cl

3711

36

7558

02

1V15

/90

NaR

9.

69

2.7

3.7

2.29

93

5 11

.40

0.50

-6

.30

-34.

5 94

094

595

095

510

0010

0510

863F

48

Wel

l7B

C

2 37

1136

75

5802

1V

15/9

0 N

aR

9.53

8.

5 9.

4 2.

15

823

26.0

0 0.

90

-6.4

0 -3

5 5

85

085

590

090

591

091

592

092

593

010

963F

32

Wel

l 8

I 37

1136

75

5748

1V

15/9

0 N

aR

8.82

2.

9 3.

7 1.

90

1027

13

20

0.50

-6

.30

-34.

0 10

3510

4010

4510

5010

5511

0011

05

17.8

17.1

172

112

172

172

172

15.9

15.9

15.9

15.9

15.7

15.6

15.5

15.5

15.5

185

185

18.4

18.3

18.4

18.4

18.4

pH 5.5

5.5

5.5

5.5

5.4

5.5

5.5

55 5.6

5.6

5.6

5.6

5.6

5.7

5.6

5.6

5.6

5.3

53 53 53 53 53 53

Spec

ific

Con

d-

DO

uc

tanc

e

8.9

8.9

5.6

5.5

5.5

5.4

53 52

22

22

2.1

2.1

2.1

2.0

2.1

2.1

2.1

6.6

6.6

6.8

6.7

6.7

6.8

6.8

574

574

457

458

458

458

458

458

227

227

226

226

227

229

229

230

230

614

604

610

612

612

612

Appendix B. - Summary of chlorofluorocarbon da ta[CFC-11, chlorofluorocarbon-11; CFC-12, chlorofluorocarbon-12; pg/kg, picograms per kilogram of solution; pptv, parts per trillion

(volume); - - -, no data; C, contaminated- - CFC concentration > modern; Modern, CFC concentration = modern]

Well Well

no. name

1KECC28 1KECC28 1KECC28 1KECC28 !KECc28 1KECC282KEBd39 2KEBd39 2KEBd39 2KEBd39 2KEBd393 Hd 15-07 3 Hd 15-07 3 Hd 15-07 3 Hd 15-07 3 Hd 15-07 3 Hd 15-07 3 Hd 15-07 3 Hd 15-074 Hd 14-01 4 Hd 14-01 4 Hd 14-01 4 Hd 14-015KEBg35 5KEBg35 5KEBg35 5KEBg35 5KEBg35 5 KE Bg 35 5KEBg356KEBe65 6KEBe65 6KEBe65 6KEBe65 6KEBe657KEBe53 7KEBe53 7KEBe53 7KEBe538KEBe52 8KEBe52 8KEBe52 8KEBe52 8KEBe52

Local Via

identifer no.

KE401 1 KE401 2 KE401 3 KE401 4 KE401 5 KE401 6KE404 1 KE404 2 KE404 3 KE404 5 KE404 6NC204 1 NC204 2 NC204 3 NC204 4 NC204 5 NC204 6 NC204 7 NC204 8NC 105 1 NC 105 2 NC 105 3 NC 105 4KE101 1 KE101 3 KE101 4 KE101 5 KE101 6KE101 1 KE101 3KE405 2 KE405 3 KE405 4 KE405 5 KE405 6LG205S 1 LG205S 2 LG205S 3 LG205S 4LG205D 1 LG205D 2 LG205D 3 LG205D 4 LG205D 5

Sampling

date Time

mo/d/yr

10/29/90 1713 10/29/90 1716 10/29/90 1720 10/29/90 1724 10/29/90 1728 10/29/90 173310/29/90 1525 10/29/90 1529 10/29/90 1544 10/29/90 1552 10/29/90 155610/30/90 913 10/30/90 917 10/30/90 921 10/30/90 927 10/30/90 932 10/30/90 934 10/30/90

10/30/90 94210/30/90 1101 10/30/90 1113 10/30/90 1123 10/30/90 112810/29/90 1220 10/29/90 1235 10/29/90 1243 10/29/90 1247 10/29/90 125304/02/91 1344 04/02/91 141010/29/90 1015 10/29/90 1019 10/29/90 1024 10/29/90 1030 10/29/90 103504/02/91 1305 04/02/91 1309 04/02/91 1318 04/02/91 132611/05/90 1615 11/05/90 1617 11/05/90 1623 11/05/90 1632 11/05/90 1636

Concentration

in solution,

in pg/kg

CFC-11 CFC-12

41.8 40.1 40.3 16.3 33.6 18.9 46.4 38.9 44.8 18.0 37.1 33.855.4 54.3 39.7 6.4 24.9 24.6 38.4 4.1 38.3 47.4

257.7 175.4 271.1 130.1 257.8 123.3 264.7 153.7 274.2 1332 266.6 153.1 310.2 137.8 260.5 149.633.9 107.2 32.6 84.7 23.8 74.2 31.9 92.7

593.0 265.6 591.8 224.4 617.9 257.0 593.7 244.1 611.2 262.7631.4 267.9 624.3 281.3525.0 234.8 488.4 293.8 564.1 299.9 542.4 345.5 544.8 296.1862.1 307.6 742.4 2612 858.3 303.8 730.4 258.7714.9 243.7 768.3 251.4 742.1 208.4 735.8 244.9 757.1 235.9

Partial pressure,

in pptv, at recharge

temperature

CFC-11 CFC-12

13.6 57.6 13.1 23.3 11.0 272 15.1 55.8 14.6 25.8 12.1 48.418.1 77.9 12.9 9.2 8.1 35.4

12.5 5.9 12.5 68.084.0 251.7 88.4 186.7 84.0 176.9 86.3 220.6 89.4 191.1 86.9 219.7

101.1 197.8 84.9 214.711.0 153.8 10.6 121.5 7.8 106.4

10.4 133.0193.3 381.1 192.9 322.1 201.4 368.8 193.5 350.4 1992 377.0205.8 384.5 203.5 403.7171.1 336.9 159.2 421.6 183.9 430.4 176.8 495.9 177.6 425.0281.0 441.4 242.0 374.8 279.8 436.1 238.1 371.2233.0 349.8 250.4 360.8 241.9 299.1 239.9 351.4 246.8 338.5

Model CFC-based

recharge dates

CFC-11 CFC-12

1961.5 1963.5 1961.0 1957.0 1960.0 1958.0 1962.0 1963.5 1961.5 1957.5 1960.5 1962.51962.5 1966.0 1961.0 1951.0 1958.0 1960.0 1961.0 1949.0 1961.0 1965.01972.5 1976.5 1972.5 1973.0 1972.5 1972.5 1972.5 1975.0 1972.5 1973.5 1972.5 1974.5 1973.5 1973.5 1972.5 1974.51960.0 1971.5 1960.0 1969.5 1958.0 1968.5 1960.0 1970.01982.5 1984.5 1982.5 1981.0 1983.5 1983.5 1982.5 1982.5 1983.0 1984.01984.0 1984.5 1984.0 1985.51980.0 1981.5 1978.5 1986.5 1981.5 1987.0 1980.5 1991.0 1981.0 1986.5

Modern 1987.0 1987.0 1984.0

Modern 1987.0 1987.0 1983.51986.5 1982.5 1988.0 1983.0 1987.0 1979.5 1987.0 1982.5 1987.5 1982.0

No. of samples,

Julian date,

age in years,

standard deviation,

CFC-11 CFC-12

6.00 6.00 1961.08 1960.33

29.74 30.49 0.67 2.87

5.00 5.00 1960.70 1958.20

30.13 32.63 1.47 7.03

8.00 8.00 1972.63 1974.13

1821 16.71 0.33 1.194.00 4.00

1959.50 1969.88 31.33 20.96 0.87 1.08

5.00 5.00 1982.80 1983.10

8.03 7.73 0.40 1.24

1984.00 1985.00 725 6.25 0.00 0.505.00 5.00

1980.30 1986.50 10.53 4.33

1.03 3.024.00 4.00

1989.13 1985.38 2.13 5.88 2.13 1.63

5.00 5.00 198720 1981.90

3.65 8.95 0.51 1.24

39

Appendix B. - Summary of chlorofluorocarbon data (cont.)

Well Well

no. name

8KB Be 52 8KB Be 52 8KB Be 52 8KB Be 52 8KB Be 52 8KB Be 52 8KB Be 52 8KB Be 52 8 KB Be 52 8KB Be 52 8KB Be 52 8 KB Be 52 8KB Be 529 KB Be 61 9 KB Be 61 9KEBe61 9KEBe61 9 KB Be 61 9KEBe61 9KEBe61 9 KB Be 61 9 KB Be 61 9 KB Be 61 9 KB Be 61 9 KB Be 61 9KEBe61 9KEBe61 9KEBe61 9 KB Be 61 9KEBe61 9KEBe61 9 KB Be 61 9KEBe61 9 KB Be 61 9 KB Be 61 9KEBe61 9KEBe61 9 KB Be 61

10 KB Be 62 10 KB Be 62 10 KB Be 62 10 KB Be 62 10 KB Be 62 10 KB Be 62

Local Vial

identifer no.

LG205D 1 LG205D 2 LG205D 3 LG205D 4 LG205D 5 LG205D 6 LG205D 7 LG205D 8LG205D 1 LG205D 2 LG205D 3 LG205D 4 LG205D 5LG301 1 LG301 2 LG301 3 LG301 4 LG301 5LG301 2 LG 301 3 LG301 4 LG301 5LG301 1 LG301 2 LG301 3 LG301 4LG301 1 LG301 2 LG301 3 LG301 4 LG301 5 LG301 6LG301 1 LG301 2 LG301 3 LG301 4 LG301 5 LG301 6LG314 1 LG314 2 LG314 3 LG314 4 LG314 5 LG314 6

Sampling

date Time

mo/d/yr

11/05/91 1315 11/05/91 1320 11/05/91 1334 11/05/91 1439 11/05/91 1442 11/05/91 1534 11/05/91 1539 11/05/91 154303/31/92 1355 03/31/92 1406 03/31/92 1412 03/31/92 1420 03/31/92 142711/05/90 1225 11/05/90 1230 11/05/90 1240 11/05/90 1250 11/05/90 125404/02/91 1351 04/02/91 1411 04/02/91 1415 04/02/91 142011/04/91 1456 11/04/91 1515 11/04/91 1534 11/04/91 165711/05/91 1108 11/05/91 1208 11/05/91 1215 11/05/91 1220 11/05/91 1702 11/05/91 170511/06/91 1600 11/06/91 1609 11/06/91 1634 11/06/91 1734 11/06/91 1738 11/06/91 174511/06/90 1030 11/06/90 1034 11/06/90 1043 11/06/90 1100 11/06/90 1110 11/06/90 1130

Concentration

in solution,

in pg/kg

CFC-11 CFC-12

615.0 250.7 604.9 248.4 643.5 257.9 618.4 254.9 642.5 266.7 647.5 269.4 631.6 258.6 590.9 244.2669.5 270.1 679.7 256.6 670.9 270.6 674.3 265.0 660.2 264.8526.4 108.9 539.9 104.5 533.2 92.2 490.8 105.1 492.4 111.8251.4 83.9 276.5 98.3 239.7 84.3 199.8

284.6 112.9 273.4 108.4 282.9 108.4 242.7 104.8211.7 91.6 209.7 91.3 232.3 106.5 237.2 104.0 228.9 95.3 253.7 105.3203.1 91.0 229.9 103.6 221.6 101.6 225.5 101.9 218.8 101.2 204.7 92.5

1176.6 315.5 1022.8 375.7 1607.4 373.8 924.0 871.3

1182.2 308.9 700.6 302.1

Partial pressure,

in pptv, at recharge

temperature

CFC-11 CFC-12

200.5 359.8 197.2 356.6 209.8 370.1 201.6 365.7 209.4 382.7 211.1 386.6 205.9 371.1 192.6 350.5218.2 387.6 221.6 368.3 218.7 388.3 219.8 380.3 215.2 380.1171.6 156.3 176.0 149.9 173.8 132.3 160.0 150.8 160.5 160.481.9 120.5 90.1 141.1 78.1 121.0

286.792.8 162.0 89.1 155.6 92.2 155.5 79.1 150.369.0 131.4 68.4 131.0 75.7 152.8 773 1493 74.6 136.8 82.7 151.266.2 130.6 74.9 148.7 72.2 145.8 73.5 146.2 71.3 145.3 66.7 132.8

383.5 452.8 333.4 539.1 524.0 536.4 301.2 1250.4 385.4 443.4 228.4 433.5

Model CFC-based

recharge dates

CFC-11 CFC-12

1983.5 1983.0 1983.0 1983.0 19845 1983.5 1983.5 1983.0 1984.5 1984.5 1984.5 1984.5 1984.0 1983.5 1982.5 1982.51985.0 1984.5 1985.5 19835 1985.5 1984.5 1985.5 1984.5 1985.0 1984.51980.0 1971.5 1980.5 1971.0 1980.0 1970.0 1978.5 1971.0 1978.5 1972.01972.0 1969.5 1973.0 1970.5 1971.5 1969.5 1978.01973.0 1972.0 1972.5 1971.5 1973.0 1971.5 1972.0 1971.01971.0 1970.0 1971.0 1970.0 1971.5 1971,5 1971.5 1971.0 1971.5 1970.5 1972.0 1971.01970.5 1970.0 1971.5 1971.0 1971.0 1971.0 1971.5 1971.0 1971.0 1971.0 1970.5 1970.0

C 1988.0 C Modem C Modern C C C 1987.5

1986.0 1987.0

No. of samples.

Julian date,

age in years,

standard deviatioi,

CFC-11 CFC-12

8.00 8.00 1983.75 1983.44

8.10 8.41 0.71 0.68

5.00 5.00 1985.30 1984.30

6.95 7.95 0.24 0.40

5.00 5.00 1979.50 1971.10

11.35 19.75 0.84 0.663.00 4.00

1972.17 1971.88 19.09 19.38 0.62 3.564.00 4.00

1972.63 1971.50 19.22 20.34 0.41 0.35

6.00 6.00 1971.42 1970.67

20.43 21.18 034 0.55

6.00 6.00 1971.00 1970.67

20.85 21.18 0.41 0.47

1.00 5.00 1986.00 1988.84

4.85 2.01 1.67

40

Appendix B. Summary of'chloroBuorocarbon data (cont.)

Well Well

no. name

Local Via

identifer no.

10 KE Be 62 LG314 2 10KEBe62 LG314 3 10KEBe62 LG314 4 10 KE Be 62 LG314 510 KE Be 62 10 KE Be 62 10 KE Be 62 10 KE Be 62 10 KE Be 6211 KE Be 163 11 KE Be 163 11 KE Be 163 11 KE Be 163 11 KE Be 163 11 KE Be 163 11 KE Be 163 11 KE Be 163 11 KE Be 163 11 KE Be 163 11 KE Be 16312 KE Be 162 12 KE Be 162 12 KE Be 162 12 KE Be 162 12 KE Be 162 12 KE Be 162 12 KE Be 162 12 KE Be 16213 KE Be 64 13 KE Be 64 13 KE Be 64 13 KE Be 6414 KE Be 63 14 KE Be 63 14 KE Be 63 14 KE Be 63 14 KE Be 6315 KE Be 161 15 KE Be 161 15 KE Be 161 15 KE Be 161

LG314 1 LG314 2 LG314 3 LG314 4 LG314 5LG514 1 LG514 2 LG514 4 LG514 5LG514 1 LG514 2 LG514 3 LG514 4 LG514 5 LG 514 6 LG514 7LG414 1 LG414 2 LG414 3 LG414 4LG414 1 LG 414 2 LG414 3 LG414 4LG313S 1 LG313S 2 LG313S 4 LG313S 5LG313D 2 LG313D 3 LG313D 4 LG313D 5 LG313D 6LG667 1 LG667 3 LG667 4 LG667 5

Sampling

date Time

mo/d/yr

11/06/91 919 11/06/91 924 11/06/91 1122 11/06/91 112603/31/92 1524 03/31/92 1537 03/31/92 1559 03/31/92 1608 03/31/92 162011/06/90 1433 11/06/90 1438 11/06/90 1448 11/06/90 145211/06/91 1207 11/06/91 1212 11/06/91 1217 11/06/91 1222 11/06/91 1400 11/06/91 1404 11/06/91 140811/06/90 1323 11/06/90 1329 11/06/90 1333 11/06/90 133511/06/91 1438 11/06/91 1442 11/06/91 1500 11/06/91 150511/06/90 1706 11/06/90 1710 11/06/90 1719 11/06/90 172211/06/90 1610 11/06/90 1615 11/06/90 1628 11/06/90 1602 11/06/90 163011/07/90 1632 11/07/90 1641 11/07/90 1657 11/07/90 1701

Concentration

in solution,

in pg/kg

CFC-11 CFC-12

793.7 329.3 772.3 312.3 806.3 318.5 803.1 324.2720.4 292.8 813.4 306.3 740.9 294.8 724.8 288.9 734.5 302.8652.0 227.7 888.6 228.1 666.6 233.3 634.8 216.2568.9 242.6 570.4 238.9 609.0 252.6 616.7 251.5 604.9 252.7 590.0 253.0 561.4 236.4114.5 9.8 122.6 11.2 129.4 9.4 114.0 10.440.1 14.4 55.3 14.0 62.1 18.9 50.1 15.2

728.5 243.9 1005.3 285.6 736.0 244.3 776.7 223.8369.0 111.7 3932 120.0 351.3 115.9 343.5 115.5 329.4 100.1584.3 214.9 601.7 190.5 600.8 215.7 573.7 191.8

Partial pressure,

in pptv, at recharge

temperature

CFC-11 CFC-12

258.7 472.6 251.8 448.2 262.8 457.1 261.8 465.3234.8 420.3 265.1 439.6 241.5 423.1 236.2 414.5 239.4 434.5212.5 326.7 289.7 327.4 217.3 334.8 206.9 310.2185.4 348.2 185.9 342.9 198.5 362.5 201.0 360.9 197.2 362.6 192.3 363.1 183.0 339.337.3 14.1 40.0 16.0 42.2 13.4 37.2 14.913.1 20.7 18.0 20.0 20.2 27.1 16.3 21.8

237.5 350.1 327.7 409.9 239.9 350.6 253.2 321.2120.3 160.3 128.2 172.2 114.5 166.3 105.8 157.6 107.4 143.7190.5 308.4 196.1 273.3 195.8 309.5 187.0 275.2

Model CFC-based

recharge dates

CFC-11 CFC-12

1988.5 1989.0 1988.0 1987.5 1989.0 1988.0 1989.0 1988.51986.5 1986.5 1989.5 1987.0 1987.0 1986.5 1987.0 1986.0 1987.0 1987.01984.5 1981.0

Modern 1981.0 1985.0 1981.5 1984.0 1980.01982.0 1982.5 1982.0 1982.0 1983.0 1983.0 1983.5 1983.0 1983.0 1983.0 1982.5 1983.0 1981.5 1982.01967.0 1953.5 1967.5 1954.5 1967.5 1953.5 1967.0 1954.01961.0 1956.0 1962.5 1956.0 1963.5 1958.0 1962.0 1956.51987.0 1982.5

C 1986.0 1987.0 1982.5 1988.0 1981.01975.0 1971.5 1975.5 1972.5 1974.5 1972.0 1974.0 19715 1974.0 1971.01982.5 1980.0 1983.0 1977.5 1983.0 1980.0 1982.0 1977.5

No. of samples,

Julian date,

age in years,

standard deviation,

CFC-11 CFC-12

4.00 4.00 1988.63 1988.25

322 3.60 0.41 0.56

5.00 5.00 1987.40 1986.60

4.85 5.65 1.07 0.374.00 4.00

1986.09 1980.88 4.76 9.98 2.77 0.54

7.00 7.00 1982.50 1982.64

9.35 921 0.65 0.444.00 4.00

196725 1953.88 23.60 36.98

0.25 0.414.00 4.00

196225 1956.63 29.60 35.22

0.90 0.823.00 4.00

1987.33 1983.00 3.52 7.85 0.47 1.84

5.00 5.00 1974.60 1971.70

16.25 19.15 0.58 0.514.00 4.00

1982.63 1978.75 823 12.10 0.41 125

41

Appendix B. Summary of chlorofluorocarbon data (cont.)

Well Well

no. name

15 KE Be 161 15 KE Be 161 15 KE Be 161 15 KE Be 161 15 KE Be 161 15 KE Be 161 15 KE Be 161 15 KE Be 16116KB Be 160 16KB Be 160 16KB Be 160 16KB Be 160 16KB Be 160 16KB Be 160 16KB Be 160 16KB Be 160 16KB Be 160 16KB Be 160 16KB Be 160 16KB Be 160 16KB Be 160 16KB Be 160 16KB Be 160 16KB Be 160 16KB Be 160 16KB Be 160 16KB Be 16017 KE Be 159 17 KE Be 159 17 KE Be 159 17 KE Be 159 17 KE Be 159 17 KE Be 159 17 KE Be 159 17 KE Be 159 17 KE Be 159 17 KE Be 159 17 KE Be 159 17 KE Be 159 17 KE Be 159 17 KE Be 159 17 KE Be 159 17 KE Be 159 17 KE Be 159

Local V

identifer n

LG667 LG667LG667 LG667 LG667 LG667 LG667 LG667LG567 LG567 LG567 LG567 LG567 LG567LG567 LG567LG567 LG567 LG567 LG567 LG567 LG567LG567 LG567 LG567 LG567 LG567LG467 LG467 LG467 LG467 LG467LG467 LG467LG467 LG467 LG467 LG467 LG467 LG467 LG467 LG467 LG467 LG467

ial Sampling

o. date Time

mo/d/yr

1 04/02/91 1151 3 04/02/91 12031 11/07/91 1141 2 11/07/91 1145 3 11/07/91 1150 4 11/07/91 1302 5 11/07/91 1308 6 11/07/91 13301 11/19/90 1630 2 11/19/90 1634 3 11/19/90 1638 4 11/19/90 1642 5 11/19/90 1650 6 11/19/90 16551 04/02/91 1115 3 04/02/91 11291 11/07/91 1020 2 11/07/91 1029 3 11/07/91 1035 4 11/07/91 1109 5 11/07/91 1114 6 11/07/91 11181 03/31/92 1728 2 03/31/92 1734 3 03/31/92 1741 4 03/31/92 1748 5 03/31/92 17551 11/07/90 1525 2 11/07/90 1529 3 11/07/90 1533 4 11/07/90 1544 5 11/07/90 15491 04/02/91 1014 3 04/02/91 10300 11/07/91 - 0 11/07/91 1 11/07/91 1425 2 11/07/91 1438 3 11/07/91 1443 4 11/07/91 1450 5 11/07/91 1500 6 11/07/91 1506 7 11/07/91 1513 8 11/07/91 1516

Concentration

in solution,

in pg/kg

CFC-11 CFC-12

501.9 224.0 488.3 228.2549.7 228.6 575.5 237.9 559.9 237.7 553.0 223.6 535.2 233.3 514.7 217.8138.0 48.8 139.4 46.4 136.6 37.9 164.4 37.4 141.2 50.8 175.7 38.6133.9 74.1 130.9 71.1141.4 70.2 162.7 80.5 174.8 85.0 166.3 93.7 175.7 79.9 147.5 83.8210.3 80.1 176.6 74.1 203.8 79.9 177.8 72.2 211.6 73.970.0 3.5 69.0 0.0 62.6 68.0 0.0 69.3 9.966.5 18.2 56.7 12.511.0 3.8 17.0 0.0 14.8 11.0 20.8 0.6 31.8 4.1 14.9 5.3 32.4 4.0 8.8 0.0

19.2 0.0 12.0 0.0

Partial pressure,

in pptv, at recharge

temperature

CFC-11 CFC-12

163.6 321.5

159.2 327.6179.2 328.1 187.6 341.4 182.5 341.2 180.3 320.9 174.5 334.8 167.8 312.645.0 70.0 45.5 66.5 44.5 54.5 53.6 53.7 46.0 72.9 57.3 55.443.6 106.4 42.7 102.146.1 100.7 53.0 115.5 57.0 122.0 54.2 134.5 57.3 114.7 48.1 120.368.5 114.9 57.6 106.3 66.4 114.6 58.0 103.7 69.0 106.022.8 5.0 22.5 0.0 20.4 22.2 0.0 22.6 14.221.7 26.1 18.5 18.03.6 5.4 5.5 0.0 4.8 15.7 6:8 0.8

10.4 5.9 4.8 7.6

10.5 5.8 2.9 0.0 6.3 0.0 3.9 0.0

Model CFC -based

recharge dates

CFC-11 CFC-12

1979.0 1981.0

1978.5 1981.01981.0 1981.0 1982.0 1982.0 1981.5 1982.0 1981.0 1981.0 1980.5 1981.5 1979.5 1980.51968.0 1965.0 1968.0 1964.5 1968.0 1963.5 1969.0 1963.0 1968.0 1965.5 1969.5 1963.51968.0 1968.5 1967.5 1968.01968.0 1968.0 1969.0 1969.0 1969.5 1969.5 1969.0 1970.0 1969.5 1969.0 1968.5 1969.51971.0 1969.0 1969.5 1968.5 1970.5 1969.0 1969.5 1968.0 1971.0 1968.51964.0 1948.5 1964.0 1940.0 1963.5 1964.0 1940.0 1964.0 1953.51963.5 1958.0 1963.0 1955.01954.5 1948.5 1956.5 1940.0 1956.0 1954.5 1957.0 1942.5 1960.0 1949.0 1956.0 1950.0 1960.0 1949.0 1954.0 1940.0 1957.0 1940.0 1955.0 1940.0

No. of samples,

Julian date,

age in years,

standard deviation,

CFC-11 CFC-12

1978.75 1981.00 12.50 10.25 0.25 0.00

6.00 6.00 1980.92 198133

10.94 10.52 0.79 0.55

6.00 6.00 1968.42 1964.17

22.47 26.72 0.61 0.90

1967.75 1968.25 23.50 23.00

0.25 0.25

6.00 6.00 1968.92 1969.17

22.94 22.69 0.53 0.62

5.00 5.00 1970.30 1968.60

21.95 23.65 0.68 0.37

5.00 4.00 1963.90 1945.50

26.95 45.35 0.20 5.78

1963.25 1956.50 28.00 34.75

4.25 3.25

10.00 10.00 1956.60 1945.35

35.25 46.50 1.95 5.14

42

Appendix B. - Summary of chlorofluorocarbon data (cont)

Well Well

no. name

18 KE Be 167 18 KE Be 167 18 KE Be 167 18 KE Be 167 18 KE Be 16719 KE Be 166 19 KE Be 166 19 KE Be 166 19 KE Be 166 19 KE Be 16620 KE Be 165 20 KE Be 165 20 KE Be 165 20 KE Be 165 20 KE Be 165 20 KE Be 165 20 KE Be 165 20 KE Be 165 20 KE Be 16521 KE Be 59 21 KE Be 59 21 KE Be 59 21 KE Be 59 21 KE Be 59 21 KE Be 5922 KE Be 164 22 KE Be 164 22 KE Be 164 22 KE Be 164 22 KE Be 164 22 KE Be 16423 KEBe 169 23 KEBe 169 23 KEBe 16924 KEBe 170 24 KEBe 170 24 KEBe 170 24 KE Be 17025 KEBe 50 25 KEBe 50 25 KEBe 50 25 KE Be 50 25 KEBe 50 25 KEBe 50

Local V

identifer n

LG635 LG635 LG635 LG635 LG635LG535 LG535 LG535 LG535 LG535LG435 LG435 LG435 LG435LG435 LG435 LG435 LG435 LG435LG325 LG325 LG325 LG325 LG325 LG325LG425 LG425 LG425 LG425 LG425 LG425LG371 LG371 LG371LG381 LG381 LG381 LG381LG203 LG203 LG203 LG203 LG203 LG203

ial Sampling

o. date Time

mo/d/yr

1 11/07/90 1232 2 11/07/90 1236 3 11/07/90 1241 4 11/07/90 1252 5 11/07/90 12561 11/07/90 1134 2 11/07/90 1143 3 11/07/90 1147 4 11/07/90 1154 5 11/07/90 11581 11/07/90 1020 2 11/07/90 1023 3 11/07/90 1027 4 11/07/90 10331 04/02/91 1513 2 04/02/91 1517 3 04/02/91 1526 4 04/02/91 1542 5 04/02/91 15461 11/19/90 1155 2 11/19/90 1205 3 11/19/90 1218 4 11/19/90 1225 5 11/19/90 1230 6 11/19/90 12351 11/19/90 1037 2 11/19/90 1043 3 11/19/90 1048 4 11/19/90 1055 5 11/19/90 1100 6 11/19/90 11071 04/02/91 1147 2 04/02/91 1150 4 04/02/91 12121 04/02/91 1103 2 04/02/91 1108 3 04/02/91 1125 4 04/02/91 11291 11/19/90 1423 2 11/19/90 1427 3 11/19/90 1439 4 11/19/90 1456 5 11/19/90 1500 6 11/19/90 1504

Concentration

in solution,

inpg/kg

CFC-11 CFC-12

926.3 335.6 977.5 350.9

1321.8 307.3 1000.7 352.3 994.7 325.0702.3 273.5 724.0 288.0 748.8 251.4 727.5 286.9 728.4 257.9339.2 99.9 375.7 117.0 340.4 101.7 362.3 116.2371.9 141.5 181.0

344.0 138.6 508.6 224.8 530.0 224.4733.3 262.0 805.9 286.6 922.7 269.4 855.8 277.7 835.1 274.9 810.7 264.13022 70.1 291.3 832 233.8 44.1 265.5 69.6 246.3 49.7 311.2 58.0392.0 46.4 620.6 1562 569.9 173.2483.3 121.9 103.6

473.6 133.8 417.1 189.1816.9 304.1 907.9 311.1

1051.1 284.7 975.0 361.6 907.2 298.4 9652 339.2

Partial pressure,

in pptv, at recharge

temperature

CFC-11 CFC-12

301.9 481.6 318.6 503.7 430.9 441.1 326.2 505.6 324.2 466.3228.9 392.5 236.0 413.3 244.1 360.8 237.1 411.8 237.4 370.1110.6 143.3 122.5 168.0 110.9 145.9 118.1 166.8121.2 203.1 259.7

112.1 198.9 165.8 322.7 172.8 322.0239.0 375.9 262.7 411.4 300.8 386.6 279.0 398.6 272.2 394.5 264.3 379.0

98.5 100.7 95.0 119.3 76.2 63.3 86.5 99.9 80.3 71.4

101.4 83.3127.8 66.6 202.3 224.2 185.8 248.6157.6 175.0 148.7

154.4 192.1 136.0 271.4266.3 436.4 295.9 446.4 342.6 408.6 317.8 519.0 295.7 428.2 314.6 486.7

Model CFC-based

recharge datei

CFC-11 CFC-12

C 1989.5 C Modern C 1987.0 C Modern C 1988.5

1986.0 1985.0 1987.0 1986.0 19875 1983.0 1987.0 1986.0 1987.0 1983.51974.5 1971.0 1975.0 1972.0 1974.5 1971.0 1975.0 1972.01975.0 1974.0 1977.0 1974.5 1973.5 1979.5 1981.0 1980.0 1981.01987.0 1984.0 1989.0 1986.0

C 1984.5 Modern 1985.5 Modern 1985.0

1989.5 1984.01973.5 1968.0 1973.0 1969.0 1971.5 1964.5 1972.5 1968.0 1972.0 1965.5 1973.5 1966.51975.5 1964.5 1983.5 1975.0 1982.0 1976.01978.5 1972.5 1971.0

1978.0 1973.5 1976.0 1977.51989.5 1987.0

C 1987.5 C 1986.0 C Modern C 1987.0 C 1990.0

No. of samples,

Julian date,

age in years,

standard deviation,

CFC-11 CFC-12

5.00 5.00 C 1989.60

1.25 1.74

5.00 5.00 1986.90 1984.70

3.95 6.15 0.49 1.254.00 4.00

1974.75 1971.50 16.10 19.35 0.25 0.50

4.00 5.00 1977.25 1977.30

14.00 13.95 2.51 3.25

5.00 6.00 1989.46 1984.83

1.43 6.05 1.44 0.75

6.00 6.00 1972.67 1966.92

1822 23.97 0.75 1.57

1980.33 1971.83 10.92 19.42 3.47 5.203.00 4.00

197750 1973.63 13.75 17.63 1.08 2.41

1.00 6.00 1989.50 1988.07

1.39 2.82 1.76

43

Appendix B. Summary of chlorofluorocarbon data (cont.)

Well Well

no. name

Local

identifer

25 KE Be 50 LG20325 KE Be 5025 KE Be 5025 KE Be 5025 KE Be 5025 KE Be 5025 KE Be 5025 KE Be 5025 KE Be 5025 KE Be 5026 KE Be 4926 KE Be 4926 KE Be 4926 KE Be 4926 KE Be 4926 KE Be 4927 KE Be 5127 KE Be 5127 KE Be 5127 KE Be 5127 KE Be 5127 KE Be 5128 KE Be 6028 KE Be 6029 KE Be 15829 KE Be 15829 KE Be 15829 KE Be 15829 KE Be 15829 KE Be 15830Gb 41 -1230Gb 41- 1230Gb 41 -1230Gb 41 -1230Gb 41 -1231Gb 41-0932 Gb 41-2233 Gb 42-0633 Gb 42-0633 Gb 42-0633 Gb 42-0633 Gb 42-0634 Gb 42-0834 Gb 42-0834 Gb 42-0834 Gb 42-0834 Gb 42-08

LG203LG203LG203LG203LG203LG203LG203LG203LG203LG202LG202LG202LG202LG202LG202LG204LG204LG204LG204LG204LG204LG319LG319LG446LG446LG446LG446LG446LG446VDE2VDE2VDE2VDE2VDE2VDE3____

CY103CY103CY103CY103CY103CY302CY302CY302CY302CY302

Vial

no.

1

2345123451234561234561212345612345311234512345

Sampling

date

mo/d/yr

11/14/9111/14/9111/14/9111/14/9111/14/9103/31/9203/31/9203/31/9203/31/9203/31/9211/20/9011/20/9011/20/9011/20/9011/20/9011/20/9011/20/9011/20/9011/20/9011/20/9011/20/9011/20/9011/21/9011/21/9011/21/9011/21/9011/21/9011/21/9011/21/9011/21/9011/08/9011/08/9011/08/9011/08/9011/08/9004/02/9104/02/9111/08/9011/08/9011/08/9011/08/9011/08/9011/08/9011/08/9011/08/9011/08/9011/08/90

Time

1400

1409

14171427143512051212122012291237821824829835841847

161616201624162816321639904927

1019102310291032103710421640165216561705171016591606926932938948955

12551310131513251330

Concentration

in solution,

in pg/kg

CFC-11 CFC-12

821.0 345.1

797.2 334.7823.6 428.8796.0 337.6814.6 330.3880.3 347.9915.9 332.6918.6 348.3902.1 335.0917.0 353.4703.5 273.1766.5 287.5816.9 278.8827.5 304.2756.3 282.0824.1 331.7775.5 234.8749.7 232.9772.1 211.9718.9 215.8748.7 235.4673.5 210.8

1047.7 199.8849.1 233.3770.3 280.4773.5 286.6763.1 229.9718.2 236.3746.7 289.9744.3 257.9920.5 351.2885.4 353.7

1315.4 326.6910.9 328.3927.0 339.5706.7 342.5679.0 279.6916.9 330.9927.8 341.9

1258.9 312.2928.4 330.4908.5 331.7876.4 331.3956.1 324.5

1345.7 315.51001.9 369.51003.9 348.4

Partial pressure,

in pptv, at recharge

temperature

CFC-11 CFC-12

267.6 495.2259.8 480.3268.5 615.4259.5 484.5265.5 474.1286.9 499.2298.6 477.3299.4 499.9294.1 480.8298.9 507.2229.3 392.0249.9 412.6266.3 400.1269.7 436.6246.5 404.7268.6 476.0252.8 337.0244.4 334.2251.7 304.1234.3 309.8244.0 337.9219.5 302.6341.5 286.7276.8 334.9251.1 402.4252.1 411.3248.8 330.0234.1 339.2243.4 416.1242.6 370.1300.0 504.0288.6 507.6428.8 468.7296.9 471.1302.2 487.3230.4 491.6221.3 401.3298,9 474.9302.4 490.7410.4 448.1302.6 474.2296.1 476.0285.7 475.4311.6 465.7438.6 452.8326.6 530.3327.2 499.9

Model CFC -based

recharge dates

CFC-11 CFC-12

1989.5 1990.51989.0 1989.51990.0 Modern1989.0 1989.51989.5 1989.0

Modern 1991.0Modern 1989.5Modern 1991.0Modern 1989.5Modern 1991.5

1986.0 1985.01987.5 1986.01989.5 1985.51990.5 1987.01987.5 1985.51990.0 1989.01988.0 1981.51987.5 1981.51988.0 1979.51986.5 1980.01987.5 1981.51985.5 1979.5

C 1978.0Modern 1981.5

1988.0 1985.51988.0 1986.01987.5 1981.51986.5 1982.01987.5 1986.01987.5 1983.5

C ModernModern Modern

C 1988.5C 1989.0C 1990.0

1986.5 1990.51985.5 1985.5

C 1989.0C 1990.0C 1987.5C 1989.0

Modern 1989.0Modern 1989.0

C 1988.5C 1988.0C ModernC Modern

No. of samples,

Julian date,

age in years,

standard deviation,

CFC-11 CFC-12

5.00 5.001989.40 1990.07

2.47 1.800.37 1.02

5.00 5.00Modern 1990.50

0.00 1.75 0.84

6.00 6.001988.50 1986.33

2.39 4.561.61 1.34

6.00 6.001987.17 1980.58

3.72 10.310.90 0.93

Modern 1979.75 11.14

6.00 6.001987.50 1984.08

3.39 6.810.50 1.86

1 5.00Modern 1990.10 0.76 1.24

1986.50 1990.501985.50 1985.50

5.75 5.751 5.00

Modern 1988.90 1.96 0.80

1 5.00Modern 1989.44 1.41 1.20

44

Appendix B. - Summary of chlorofluorocarbon data (cont.)

Well

no.

34

34

Well

name

Gb 42-08Gb 42-08

34 Gb 42-0834343535353535353535353536363636363636363737373838383838383939393939

Gb 42-08Gb 42-08Gb 42-05Gb 42-05Gb 42-05Gb 42-05Gb 42-05Gb 42-05Gb 42-05Gb 42-05Gb 42-05Gb 42-05Gb 42-07Gb 42-07Gb 42-07Gb 42-07Gb 42-07Gb 42-07Gb 42-07Gb 42-07Gb 42-09AGb 42-09AGb 42-09AGb41-06Gb41-06Gb41-06Gb 41-06Gb 41-06Gb 41-06Gb41-07Gb41-07Gb41-07Gb41-07Gb 41-07

39Gb 41 -074040414141414141

Gb41-05Gb41-05QAFd2QAFd2QAFd2QAFd2QAFd2QAFd2

Local

identiCer

CY302

CY302CY302CY302CY302CY202CY202CY202CY202CY202CY202CY202CY202CY202CY202CY104CY104CY104CY104CY104CY104CY104CY104CY204CY204CY204VD32VD32VD32VD32VD32VD32VD33VD33VD33VD33VD33VD33VD31VD31WY102WY102WY102WY102WY102WY102

Vial

no.

1

2

3

4512345123452345234523412345612345612123456

Sampling

date

mo/d/yr

03/30/92

03/30/9203/30/9203/30/9203/30/9211/08/9011/08/9011/08/9011/08/9011/08/9003/30/9203/30/9203/30/9203/30/9203/30/9211/08/9011/08/9011/08/9011/08/9003/30/9203/30/9203/30/9203/30/9204/02/9104/02/9104/02/9111/20/9011/20/9011/20/9011/20/9011/20/9011/20/9011/20/9011/20/9011/20/9011/20/9011/20/9011/20/9011/20/9011/20/9011/02/9011/02/9011/02/9011/02/9011/02/9011/02/90

Time

1710171517231730173911101117112211321136155216001607161416251436145815201530140914141422143017181724172910341039104410481053105813311336133913431346134914401443100610111016102210271032

Concentration

in solution.

inpg/kg

CFC-11 CFC-12

772.3 374.4743.6 349.3772.8 370.2760.1 354.7791.9 368.4735.0 260.5702.7 264.0711.6 258.3711.7 250.7722.9 262.4574.8 288.6583.0 270.9587.8 287.2581.5 274.6583.2 283.8533.7 144.6795.8 117.0591.8 146.3643.0 150.3452.6 278.1448.8 215.4443.9 201.8441.7 207.9580.8 218.7691.0 215.7581.4 213.346.0 107.847.9 107289.6 55.538.0 74.749.1 109.531.5 93.7

1602.5 106.11391.8 124.61260.0 89.31152.0 8721014.2 124.1992.3 114.3

1530.9 321.11438.0 319.7

23.1 0.027.3 0.015.0

16.1 1.326.7 0.026.3

Partial pressure,

in pptv, at recharge

temperature

CFC-11 CFC-12

251.8 537.4242.4 501.4251.9 531.2247.8 509.0258.1 528.6239.6 373.9229.0 378.8231.9 370.7219.3 342.1235.6 376.6187.4 4142190.0 388.8191.6 412.2189.5 394.0190.1 407.3174.0 207.6259.4 167.9192.9 210.0209.6 215.7147.5 399.1146.3 309.1144.7 289.6144.0 298.3189.3 313.92252 309.5189.5 306.115.0 154.715.6 153.8292 79.712.4 107216.0 157210.3 134.4

522.4 152.3453.7 178.8410.7 1282375.5 125.2330.6 178.1323.5 164.0499.0 460.9468.7 458.8

7.5 6.08.9 0.04.9

5.3 1.98.7 0.08.6

Model CFC -based

recharge dates

CFC-11 CFC-12

1988.0 Modern1987.0 1991.51988.0 Modern1987.5 1991.51988.5 Modern1987.0 1984.01986.0 1984.01986.5 1983.51985.5 1982.01987.0 1984.01982.0 1986.01982.5 1984.51982.5 1986.01982.0 1985.01982.5 1985.51980.5 1974.01989.0 1972.01982.5 1974.01984.5 1974.51977.0 1985.51977.0 1980.01977.0 1978.51977.0 1979.51982.0 1980.51986.0 1980.01982.0 1979.51962.0 1971.51962.0 1971.51965.5 1966.01961.0 1968.51962.0 1971.51959.5 1970.0

C 1971.5C 1972.5C 1970.0C 1969.5C 1972.5C 1972.0C 1988.0C 1988.0

1958.0 1940.01959.0 1940.01956.0

1956.0 1945.51958.5 1940.01958.5

No. of samples,

Julian date,

age in years,

standard deviation,

CFC-11 CFC-12

5.00 5.001987.80 1991.95

4.45 0.300.51 0.37

5.00 5.001986.40 1983.50

4.46 7.360.58 0.77

5.00 5.001982.30 1985.40

9.95 6.85024 0.584.00 4.00

1984.13 1973.636.73 17.233.15 0.964.00 4.00

1977.00 1980.881525 11.370.00 2.72

1983.33 1980.007.92 11251.89 0.41

6.00 6.001962.00 1969.83

28.89 21.061.80 2.03

6 6.00C 1971.33

19.56, 1.18

C 1988.00 2.89

6.00 4.001957.67 1941.38

33.17 49.46121 2.38

45

Appendix B. Summary of chlorofluorocarbon data (cont)

Well Well

no. name

41QAFd2 41QAFd242 QA Ed 39 42 QA Ed 39 42 QA Ed 39 42 QA Ed 39 42 QA Ed 39 42 QA Ed 39 42 QA Ed 39 42 QA Ed 39 42 QA Ed 3943 QA Ed 38 43 QA Ed 3844 QA Ed 38 44 QA Ed 38 44 QA Ed 38 44 QA Ed 38 44 QA Ed 38 44 QA Ed 3845 CO DC 146 45 CO DC 146 45 CO DC 146 45 CO DC 146 45 CO DC 146 45 CO DC 146 45 CO DC 146 45 CO DC 14646 Nd 41 -04 46 Nd 41 -04 46 Nd 41 -0447 Og 43-02 47 Og 43-02 47 Og 43-02 47 Og 43-0248 Nb 24 -03 48 Nb 24-03 48 Nb 24-03 48 Nb 24-03 48 Nb 24 -0349 Pg 14-01 49 Pg 14-01 49 Pg 14-01 49 Pg 14-01 49 Pg 14-01 49 Pg 14-01

Local V

identifer n

WY102 WY102QA402 QA402 QA402 QA402 QA402 QA402 QA402QA402 QA402QA302 QA302TA101 TA101 TA101 TA101 TA101 TA101CA102 CA102 CA102 CA102 CA102 CA102CA102 CA102SX202 SX202 SX202SX206 SX206 SX206 SX206SX301 SX301 SX301 SX301 SX301SX205 SX205 SX205 SX205 SX205 SX205

ial Sampling

o. date Time

mo/d/yr

1 04/03/91 1028 3 04/03/91 10521 11/02/90 806 2 11/02/90 808 3 11/02/90 812 4 11/02/90 818 5 11/02/90 823 6 11/02/90 828 7 11/02/90 8401 04/03/91 800 3 04/03/91 8301 04/03/91 859 3 04/03/91 9131 11/01/90 1551 2 11/01/90 1555 3 11/01/90 1542 4 11/01/90 1607 5 11/01/90 1611 6 11/01/90 16151 11/01/90 1427 2 11/01/90 1432 3 11/01/90 1436 4 11/01/90 1441 5 11/01/90 1445 6 11/01/90 14501 04/03/91 1257 3 04/03/91 13221 04/03/91 1041 2 04/03/91 1044 4 04/03/91 11131 04/03/91 1247 2 04/03/91 1250 3 04/03/91 1300 4 04/03/91 13032 11/01/90 1246 3 11/01/90 1256 4 11/01/90 1302 5 11/01/90 1306 6 11/01/90 13101 10/30/90 1518 2 10/30/90 1522 3 10/30/90 1530 4 10/30/90 1534 5 10/30/90 1540 6 10/30/90 1547

Concentration

in solution,

in pg/kg

CFC-11 CFC-12

34.9 9.2 27.1 9.4

568.4 219.3 569.0 214.3 571.4 188.8 548.3 222.9 554.9 211.7 570.1 221.5 549.0 223.1541.3 226.6 590.1 241.9182.8 113.0 174.4 605.7 261.5 586.6 248.1 588.6 181.8 580.8 238.5 608.0 247.0 587.6 229.07105 301.9 708.2 298.0 744.0 270.9 671.9 298.1 690.2 257.7 684.2 303.6680.7 3145 664.3 303.4

1076.7 356.8 830.6 362.8 765.0 324.9663.5 319.3 774.6 381.1 773.5 308.1 632.7 290.0161.7 192.9 155.2 152.0 157.5 164.9 175.1 197.0 154.9 163.7641.6 280.8 628.6 2855 638.6 232.3 633.5 301.2 632.4 284.3 614.1 2715

Partial pressure,

in pptv, at recharge

temperature

CFC-11 CFC-12

11.4 13.2

8.8 13.5

185.3 314.7 185.5 307.6 1865 271.0 178.7 319.9 180.9 303.8 185.8 317.9 178.9 3205176.4 325.2 192.4 347.159.6 1625<£ 8J\t*O

197.4 375.3 191.2 356.0 191.9 260.9 189.3 342.3 198.2 354.5 191.5 328.6231.5 433.2 230.8 427.7 242.5 388.8 219.0 427.8 225.0 369.8 223.0 435.7221.9 450.9 216.5 435.4351.0 512.1 270.7 520.7 249.4 466.2216.3 458.3 252.5 547.0 252.1 442.2 206.2 4165

52.7 276.9 50.6 218.1 51.3 236.6 57.1 282.8 50.5 235.0

2095 402.9 204.9 409.3 208.2 333.3 206.5 432.3 206.1 408.1 200.2 3895

Model CFC-based

recharge dates

CFC-11 CFC-12

1960.5 1953.0 1958.5 1953.51982.0 1980.5 1982.0 1980.0 1982.0 1977.5 1981.0 1981.0 1981.0 1979.5 1982.0 1981.0 1981.0 1981.01980.5 1981.0 1982.5 1982.51970.0 1972.0 1969.5 1983.0 1984.0 1982.5 1983.0 1982.5 1977.0 1982.0 1982.0 1983.0 1982.5 1982.5 1981.51986.5 1987.0 1986.5 1987.0 1987.0 1984.5 1985.5 1987.0 1986.0 1983.5 1985.5 1987.01985.5 1987.5 1985.0 1987.0

C 1992.0 1991.0 Modern 1987.5 1988.51985.0 1988.0 1988.0 Modern 1988.0 1987.5 1984.0 1986.01969.0 1977.5 1969.0 1974.5 1969.0 1975.5 1969.5 1978.0 1968.5 1975.51984.5 1985.5 1984.0 1986.0 1984.5 1981.5 1984.0 1987.0 1984.0 1986.0 1983.5 1985.0

No. of samples,

Julian date,

age in years,

standard deviation,

CFC-11 CFC-12

1959.50 1953.25 31.76 38.01

1.00 055

7.00 7.00 1981.57 1980.07

9.27 10.77 0.49 1.18

1981.50 1981.75 9.76 9.51

1969.75 1972.00 21.51 1956 055

6.00 6.00 1982.58 1981.67

8.25 9.17 0.34 253

6.00 6.00 1986.17 1986.00

4.67 4.84 0.55 1.44

1985.25 198755 6.01 4.01

1989.25 1990.59 2.01 0.67 1.75 1.514.00 4.00

198655 1988.19 5.01 3.07 1.79 1.92

5.00 5.00 1969.00 1976.20

21.84 14.64 0.32 1.33

6.00 6.00 1984.08 1985.17

6.75 5.66 0.34 1.75

46

Appendix B. Summary of chloroQuorocarbon data (cont.)

Well Well

no. name

50 Oi 51-1250 Oi 51-1250 Oi 51-1250 Oi 51 -1250 Oi 51 -1250 Oi 51-1251 Oi 51-1151 Oi 51-1151 Oi 51-1151 Oi 51-1151 Oi 51-1151 Oi 51-1152 Oh 54-152 Oh 54-152 Oh 54-152 Oh 54-152 Oh 54-152 Oh 54-152 Oh 54-152 Oh 54-1

53 Ph 13-0353 Ph 13-0353 Ph 13-0353 Ph 13-0353 Ph 13-0353 Ph 13-0354 Ph 13-1654 Ph 13-1654 Ph 13-1655 Ph 13-1755 Ph 13-1755 Ph 13-1755 Ph 13-1755 Ph 13-1756 Ph 13-1856 Ph 13- 1856 Ph 13-1856 Ph 13- 1857 Ph 13-0457 Ph 13-0458 Ph 13-2358 Ph 13-2359 Ph 13-2459 Ph 13-24

Local

identifer

SX309

SX309SX309SX309SX309SX309SX209SX209SX209SX209SX209SX209 _ _*__-.___..___. -_.

__ _ _ _____ _ _ _____ ____ ____ -

Via

no.

1

23456123456B

FlF2F3

334

T?*>r__.

i23456136234561256131313

Sampling

date

mo/d/yr

11/01/90

11/01/90

11/01/90

11/01/9011/01/9011/01/9011/01/9011/01/9011/01/9011/01/9011/01/9011/01/9005/22/8905/22/8905/22/8905/22/8905/22/8905/22/8905/22/8905/22/8910/31/9010/31/9010/31/9010/31/9010/31/9010/31/9010/31/9010/31/9010/31/9010/31/9010/31/9010/31/9010/31/9010/31/9010/31/9010/31/9010/31/9010/31/9004/04/9104/04/9104/04/9104/04/9104/04/9104/04/91

Time

905

918

921925930940812818822829834838 _ «__.«__.«__.

164716521702171417201725936950

101011011105111111161127833839855900

104410561219131511301144

Concentration

in solution,

in pg/kg

CFC-11 CFC-12

508.0 218.4

531.5 201.5509.5 160.5503.5 1872549.7 198.5506.5 188.7488.3 185.4474.4 184.1458.6 1532466.4 168.04652 185.6433.9 165.8

126 341 5414 12

107 446 3863 1

3 136 4

674.8 628.849227.1 312.871090.0 247.845999.3 233.348682.4 308.648473.6 227.0

542.7 236.7626.4 249.9514.5 2042571.5 177.16422 193.0536.0 442.7576.7 178.4496.7 1192110.9 55.6108.5 52.095.5 65.486.4 48.4

671.2 284.7651.5 279.1589.7 2652575.3 255.7414.4 205.2403.9 226.8

Partial pressure,

in pptv, at recharge

temperature

CFC-11 CFC-12

165.6 313.5173.3 289.2166.1 230.4164.1 268.6179.2 284.9165.1 270.9159.2 266.1154.6 264.3149.5 219.9152.0 241.1151.6 266.3141.4 238.040.9 4.313.2 77.54.4 17.2

34.8 5.814.9 53.620.5 1.0

1.0 17.91.8 6.0

220.0 902.516046 448.923173 355.614994 334.914998 421.115801 325.8176.9 339.7204.2 358.6167.7 293.0186.3 254.1209.3 277.0174.7 635.4188.6 256.0161.9 171.136.1 79.835.4 74.731.1 93.828.2 69.5

218.8 408.6212.4 400.6192.2 380.5187.5 367.0135.1 294.5131.7 325.4

Model CFC-based

recharge dates

CFC-11 CFC-12

1979.5 1980.51980.0 1978.51979.5 1975.01979.5 1977.51981.0 1978.01979.5 1977.51978.5 1977.01978.0 1977.01977.5 1974.51978.0 1976.01978.0 1977.01976.5 1975.5

1967.50 1948.001961.00 1966.001955.50 1955.001966.50 1949.001961.50 1963.001963.50 1943.501951.50 1955.00195250 194900±yj£tfj\j iy+y*\nj

1985.5 CC 1987.5 1982.5 1981.5C 1986.5C 1981.0

1980.5 1982.01984.0 1983.01979.5 1978.51982.0 1976.51984.5 1977.51980.5 C1982.0 1976.51979.0 1972.51966.5 1966.01966.5 1965.51965.5 1967.51965.0 1965.01985.5 1986.01984.5 1985.51982.5 1984.51982.0 1983.51976.0 1979.01976.0 1981.0

No. of samples,

Julian date,

age in years,

standard deviation,

CFC-11 CFC-12

6.00 6.001979.83 1977.83

11.00 13.000.55 1.62

6.00 6.001977.75 1976.17

13.09 14.670.63 0.94

1.00 1.001951.50 1943.50

37.89 45.89^

-i

1.00 5.001985.50 1983.80

5.33 7.03 2.68

1981.33 1981.179.50 9.671.93 1.93

5.00 4.001981.60 1975.75

923 15.081.83 1.924.00 4.00

1965.88 1966.0024.96 24.83

0.65 0.941985.00 1985.75

626 551198225 1984.00

9.01 7.261976.00 1980.00

1526 11.26

47

Appendix B. Summary of chlorofluorocarbon data (cont)

Well Well Local

no. name identife

60 Ph 13-25 - 60 Ph 13-25 -61 Ph 13-26 - 61 Ph 13-2662 Ph 23-10 - 62 Ph 23-10 -

62 Ph 23-10 62 Ph 23-10 -

62 Ph 23-10 - 62 Ph 23-10 - 62 Ph 23-10 -

62Ph23-10 62Ph23-10 63 Ph 23-12 -

63 Ph 23-12 63Ph23-12 -63 Ph 23-12 63 Ph 23-12

63 Ph 23-12 63 Ph 23-12 -64Ph23-13 - 64Ph23-13 -

64Ph23-13 64Ph23-13 64Ph23-13 - 64 Ph 23-13 - 64Ph23-13 - 64Ph23-13 -65 Ph 23-14 -

65 Ph 23-14 - 65Ph23-14 65 Ph 23-14 - 65Ph23-14 - 65 Ph 23-14 '

65Ph23-14 65 Ph 23-14 - 65Ph23-14 -

65 Ph 23-14 66 Pg 15-03 66 Pg 15-03 66 Pg 15-03 -

66 Pg 15-03

Vial Sampling

r no. date Time

mo/d/yr

1 04/04/91 859 3 04/04/91 9121 04/04/91 954 3 04/04/91 10151 10/31/90 1458 2 10/31/90 1504 4 10/31/90 1516 5 10/31/90 1520 6 10/31/90 15251 04/04/91 1212 2 04/04/91 1218 3 04/04/91 1242 4 04/04/91 12452 10/31/90 1546 5 10/31/90 1604 6 10/31/90 16081 04/05/91 1105 2 04/05/91 1110 3 04/05/91 1135 4 04/05/91 11401 10/31/90 1357 2 10/31/90 1410 5 10/31/90 1432 6 10/31/90 14381 04/04/91 1010 2 04/04/91 1017 3 04/04/91 1034 4 04/04/91 10400 10/31/90 1250 1 10/31/90 1256 2 10/31/90 1301 3 10/31/90 1306 4 10/31/90 1311 5 10/31/90 1316 6 10/31/90 13231 04/04/91 903 2 04/04/91 909 4 04/04/91 9401 05/22/89 2 05/22/89 3 05/22/89 F 05/22/89 -

Concentration

in solution,

in pg/kg

CFC-11 CFC-12

216.8 99.1 247.8 205.6208.4 98.5 205.8 92.1822.1 399.6 872.1 580.1 793.1 378.8 844.1 406.6 798.4 404.5865.1 382.1 7392 330.0 869.3 381.4 722.1 404.7452.8 238.0 404.6 191.8 412.3 199.5685.1 274.9 576.6 233.6 7072 2742 579.5 231.0419.4 135.4 454.8 1772 456.5 176.8 403.7 151.1442.1 163.7 371.8 118.3 443.6 163.8 122.4

407.7 26.8 2812 136.4 261.1 114.9 300.1 1522 431.6 5062 269.1 136.0 234.7 101.7287.9 122.6 94.8 842

598 314 775 810 542 249

5924 299

Partial pressure,

in pptv, at recharge

temperature

CFC-11 CFC-12

70.7 142.3 80.8 295.067.9 141.4 67.1 132.1

268.0 573.5 284.3 832.5 258.5 543.6 275.1 583.6 260.3 580.5282.0 548.4 241.0 473.6 283.4 547.4 235.4 580.8147.6 341.6 131.9 275.2 134.4 286.3223.3 394.5 187.9 3352 230.5 393.5 188.9 331.4136.7 194.4 148.3 254.3 148.8 253.8 131.6 216.9144.1 235.0 1212 169.8 144.6 235.1 175.6

132.9 38.5 91.7 195.8 85.1 164.9 97.8 218.4

140.7 726.5 87.7 1952 76.5 145.993.8 175.9

136.0 T- 120.9

1942 448.3 251.5 1157.6 175.9 356.3

1923.1 427.9

Model CFC-based

recharge dates

CFC-11 CFC-12

1971.0 1970.5 1972.0 1979.01970.5 1970.5 1970.5 1970.01990.0 Modern

Modern C 1988.5 Modern

Modern Modern 1989.0 Modern

Modern Modern 1987.0 1989.0

Modern Modern 1987.0 Modern1977.0 1982.0 1976.0 1977.5 1976.0 1978.01985.5 1985.0 1982.0 1981.5 1986.5 1985.0 1982.0 1981.51976.5 1973.5 1977.5 1976.5 1977.5 1976.5 1976.0 1974.51977.0 1975.5 1975.0 1972.5 1977.0 1975.5 1972.5

1976.0 1960.5 1973.0 1973.5 1972.5 1972.0 1973.5 1974.5 1976.5 C 1972.5 1973.5 1971.5 1971.01973.0 1972.5 1970.5 1969.5

1982.50 1987.50 1988.00 C 1980.50 1983.00

C 1987.00

No. of samples,

Julian date,

age in years,

standard deviation,

CFC-11 CFC-12

1971.50 1974.75 19.76 16.51

1970.50 1970.25 20.76 21.01

5.00 4.00 1989.83 Modern

1.00 0.00 0.95

4.00 4.00 1989.13 1990.69

2.13 0.56 2.13 0.983.00 3.00

1976.33 1979.17 0.47 2.014.00 4.00

1984.00 1983.25 7.26 8.01 2.03 1.754.00 4.00

1976.88 1975.25 13.96 15.58 0.65 1.303.00 4.00

1976.33 1974.00 14.92 17.26 0.94 1.50

7.00 6.00 1973.64 1970.83

17.19 20.00 1.75 4.76

1973.00 1970.83 18.26 20.42 L25

3.00 3.00 1983.67 1985.83

5.72 3.56 3.17 2.01

48

Appendix B. Summary of chloroffuorocarbon data (cont.)

Well Well

no. name

67 Pg 15 -0267 Pg 15 -0267 Pg 15-0267 Pg 15-0267 Pg 15-0268 Ph 22-1268 Ph 22- 1268 Ph 22- 1268 Ph 22- 1269 Ph 22- 1169 Ph 22- 1169 Ph 22- 1169 Ph 22-1170 Ph 13 -3070 Ph 13 -3070 Ph 13-3070 Ph 13-3071 Phl3-2971 Phl3-2971 Phl3-2971 Phl3-2971 Ph 13 -2971 Ph 13-2971 Ph 13-2971 Ph 13-2971 Ph 13-2971 Ph 13-2971 Ph 13-2971 Ph 13-2971 Ph 13-2971 Ph 13 -2972 DO Ce 8972 DO Ce 8972 DO Ce 8972 DO Ce 8972 DO Ce 8972 DO Ce 8973 DO Cg 4673 DO Cg 4673 DO Cg 4673 DO Cg 4673 DO Cg 4673 DO Cg 46

Local

identifer

----

____

- -

____

__

____

____

____

_

____

____

____

SX201SX201SX201SX201SX101SX101SX101SX101SX101SX101SX101SX101SX101SX101SX101SX101SX101SX101DO 401DO 401DO 401DO 401DO 401DO 401D0403SDO403SDO403SD0403SDO403SD0403S

Vial

no.

FlF2

123123F123F1234

Fl2451234561234123456123456

Sampling

date

mo/d/yr

05/22/8905/22/8905/22/8905/22/8905/22/8905/22/8905/22/8905/22/8905/22/8905/22/8905/22/8905/22/8905/22/8904/03/9104/03/9104/03/9104/03/9105/22/8905/22/8905/22/8905/22/8910/30/9010/30/9010/30/9010/30/9010/30/9010/30/9004/03/9104/03/9104/03/9104/03/9111/16/9011/16/9011/16/9011/16/9011/16/9011/16/9011/13/9011/13/9011/13/9011/13/90il/13/9011/13/90

Time

___

---

_

___

_

_

___

___

___

_

___

_

___

1529153515411545____________

1733173717401745175017551434143914521502152115261531153515401544170317061709171617191722

Concentration

in solution,

in pg/kg

CFC-11

31574348909

876612834

574957842

7267436663410473

375.8____

336.9280.88503

63335

68120.1112.6102.788.5

106.082.0

148.81292145.21302199.7179.7172.7187.4177.8167.1103.651.688.5

114.673283.7

CFC-12

152192

116919415623593681049

10673

15585

295.2282.5305.2269.6

2351

50142

28.425.844.037.725.237.652.137.451.237.616.68.30.00.07.90.0

111.697.485.1

100.692.792.4

Partial pressure,

in pptv, at recharge

temperature

CFC-11

1024.8

1411.42952

2845.34165.8

186.3310.7273.3

2359.0141.4215.3133.0153.6122.5

_ _

109.891.5

2760.120.4

108.721.939.136.733.528.834.526.748.542.147.342.465.158.656.361.158.054.533.816.828.937.423.927.3

CFC-12

217.4274.3

1670.1276.6223.0335.9

1337.91157.8

70.7152.1103.92212121.1423.7405.5437.9386.9

32.372.9

716.660240.837.163.154.136253.974.753.673.454.023.811.90.00.0

11.30.0

1602139.8122.1144.4133.0132.6

Model CFC-based

recharge dates

CFC-11

C

cModern

CC

1982.00C

ModernC

1976.501985.001976.001978.00

1975.0__

1974.51973.0

C1963.501974.001963.50

1967.01966.51966.01965.51966.51965.01968.51967.51968.51967.51970.51969.51969.51970.01969.51969.01966.01962.51965.51967.01964.01965.0

CFC-12

1974.501977.50

C1977.501975.001981.50

CC

1965.001971.501968.001975.001969.501986.51985.51987.01984.5

1959.501965.50

C1964.00

1961.01960.51964.51963.01960.01963.01965.51963.01965.51963.01957.01952.51940.01940.01952.01940.01971.51970.51969.51971.01970.01970.0

No. of samples,

Julian date,

age in years,

standard deviation,

CFC-11 CFC-12

1.00 4.00Modern 1976.13 1327

1.391.00 1.00

1982.00 1981.507.39 7.89

4.00 4.001978.88 1971.00

10.52 18.393.61 2.623.00 4.00

1974.17 1985.8817.09 5.380.85 0.963.00 3.00

1967.00 1963.0022.39 26.39

4.95 2.55

6.00 6.001966.08 1962.00

24.75 28.830.67 1.614.00 4.00

1968.00 1964.252326 27.01

0.50 1.25

6.00 6.001969.67 1946.92

21.21 43.960.47 7.10

6.00 6.001965.00 1970.42

25.87 20.451.44 0.67

49

Appendix B. - Summary of chlorofluorocarbon data (cont.)

Well Well

no. name

74 DO Cg 45 74 DO Cg 45 74 DO Cg 45 74 DO Cg 45 74 DO Cg 45 74 DO Cg 4575 WIBe 52 75 WI Be 52 75 WIBe 52 75 WIBe 52 75 WIBe 52 75 WIBe 5276WIBgl8 76WIBgl8 76 WI Bg 18 76WIBgl8 76WIBgl8 76 WIBg 1877 WI Bg 17 77 WI Bg 17 77WIBgl7 77WIBgl778 WO Bf 87 78 WO Bf 87 78 WO Bf 87 78 WO Bf 87 78 WO Bf 87 78 WO Bf 8779 WO Bf 86 79 WO Bf 86 79 WO Bf 86 79 WO Bf 86 79 WO Bf 86 79 WO Bf 8680 WO Cg 80 80 WO Cg 80 80 WO Cg 80 80 WO Cg 80 80 WO Cg 80 80 WO Cg 80 80 WO Cg 80 80 WO Cg 80 80 WO Cg 80 80 WO Cg 80

Local Vial

identifer no.

DO403D 1 DO403D 2 DO403D 3 DO403D 4 DO403D 5 DO403D 6W0404D 1 WO404D 2 WO404D 3 W0404D 4 WO404D 5 WO404D 6WO 405S 2 W0405S 3 WO 405S 4 W0405S 5 W0405S 6WO 405S 1WO405D 2 WO405D 5W0405D 1 WO405D 3

WR402S 1 WR402S 2 WR402S 3 WR402S 4 WR402S 5 WR402S 6WR402D 1 WR402D 2 WR402D 3 WR402D 4 WR402D 5 WR402D 6WR403S 1 WR403S 2 WR403S 3 WR403S 4 WR403S 5 WR403S 6WR 403S 1 WR403S 2 WR403S 3 WR403S 4

Sampliag

date Time

mo/d/yr

11/13/90 1618 11/13/90 1621 11/13/90 1627 11/13/90 1632 11/13/90 1636 11/13/90 163911/12/90 827 11/12/90 838 11/12/90 843 11/12/90 905 11/12/90 908 11/12/90 91411/02/90 1050 11/12/90 1057 11/12/90 1103 11/12/90 1107 11/12/90 111804/04/91 165511/12/90 1205 11/12/90 122204/03/91 1601 04/03/91 161511/12/90 1408 11/12/90 1417 11/12/90 1423 11/12/90 1428 11/12/90 1437 11/12/90 145011/12/90 1532 11/12/90 1536 11/12/90 1541 11/12/90 1544 11/12/90 1548 11/12/90 155211/13/90 1321 11/13/90 1326 11/13/90 1330 11/13/90 1333 11/13/90 1337 11/13/90 134004/04/91 1520 04/04/91 1525 04/04/91 1545 04/04/91 1550

Concentration

in solution,

in pg/kg

CFC-11 CFC-12

46.5 42.8 44.0 11.9 35.3 13.1 60.2 31.9 40.0 5.9 61.9 32.7

564.3 245.2 518.5 219.0 501.8 211.3 548.3 241.0 502.9 207.6 539.9 249.0

1942.6 167.7 218.4

242.0 180.2 176.1 165.4 238.2 179.0160.3 183.045.8 44.8 38.0 35.324.5 7.8 20.8 5.7

524.9 214.7 521.0 222.7 539.4 197.1 604.6 488.9 492.7 207.7 483.7 200.2437.4 198.7 510.6 215.7 204.9 90.2

465.2 190.5 510.3 211.0 473.2 188.1367.1 216.5 89.4 196.8

377.8 214.6 396.6 193.7 79.9 197.3

379.7 196.5252.5 128.4 220.1 116.1 241.5 122.4 213.7 113.9

Partial pressure,

in pptv, at recharge

temperature

CFC-11 CFC-12

15.2 61.4 13.5 16.3 11.5 18.8 19.6 45.8 13.0 8.4 20.2 46.9

183.9 352.0 169.0 314.3 163.6 303.3 178.7 345.8 163.9 298.0 176.0 357.4633.2 240.7 71.2

78.9 258.6 57.4 237.4 77.6 256.952.3 262.714.9 64.4 12.4 50.68.0 11.3 6.8 8.2

171.1 308.1 169.8 319.7 175.8 282.9 197.1 701.7 160.6 298.1 157.7 287.3142.6 285.1 166.4 309.6 66.8 129.4

151.6 273.3 166.4 302.9 1543 270.0119.7 310.7 29.2 282.4

123.2 308.0 129:3 278.0 26.0 283.1

123.8 282.082.3 184.3 71.7 166.6 78.7 175.7 69.7 163.4

Model CFC-based

recharge dates

CFC-11 CFC-12

1962.0 1964.0 1961.5 1954.5 1960.5 1955.5 1963.0 1962.0 1961.0 19505 1963.5 1962.01981.5 1982.5 1979.5 1980.5 1979.0 1979.5 1981.0 1982.0 1979.5 1979.5 1980.5 1983.0

C 1976.0 1971.0

1972.0 1976.5 1969.5 1975.5 1971.5 1976.51969.0 1977.01961.5 1964.5 1961.0 1962.51958.0 1952.0 1957.0 1950.51980.0 1980.0 1980.0 1981.0 1980.5 1978.0 1983.0 C 1978.5 1979.5 1978.5 1978.01976.5 1978.0 1979.5 1980.0 1970.5 1970.0 1978.0 1977.5 1979.5 1979.5 1978.0 1977.51975.0 1980.0 1965.5 1978.0 1975.5 1980.0 1975.5 1978.0 1964.5 1978.0 1975.5 1978.01972.0 1973.0 1971.0 1972.0 1972.0 1972.5 1971.0 1972.0

No. of samples,

Julian date,

age in years,

standard deviation,

CFC-11 CFC-12

6.00 6.00 1961.92 1958.08

28.95 32.79 1.06 4.88

6.00 6.00 1980.17 1981.17

10.70 9.70 0.90 1.40

4.00 4.00 1971.00 1976.13

19.87 14.74 0.94 0.41

1969.00 1977.001961.25 1963.50

29.62 27.371957.50 1951.25

33.76 40.01

0.50 0.75

6.00 5.00 1980.08 1979.30

10.78 1157 1.51 1.17

6.00 6.00 1977.00 1977.08

13.87 13.78 3.08 3.31

6.00 6.00 1971.92 1978.67

18.95 12.20 4.90 0.944.00 4.00

1971.50 1972.38 19.76 18.88 0.50 0.41

50

Appendix B. Summary of chloroffuorocarbon data (cont.)

Well Well

no. name

81 WO Cg 79 81 WO Cg 79 81 WO Cg 79 81 WO Cg 79 81 WO Cg 79 81 WO Cg 79 81 WO Cg 79 81 WO Cg 79 81 WO Cg 79 81 WO Cg 79 81 WO Cg 79 81 WO Cg 79 81 WO Cg 79 81 WO Cg 79 81 WO Cg 79

Local Vial

identifer no.

WR403D 1

WR403D 2 WR403D 3 WR403D 4 WR403D 5 WR403D 6WR403D 1 WR403D 2 WR403D 3 WR403D 4WR403D 4 WR403D 5 WR403D 6 WR403D 7 WR403D 8

82 WO Cg 78 P 28S 1 82WOCg78 P28S 2 82 WO Cg 78 P 28S 3 82 WO Cg 78 P28S 4 82 WO Cg 78 P 28S 5 82WOCg78 P28S 683 WO Cg 77 83 WO Cg 77 83 WO Cg 77 83 WO Cg 77 83 WO Cg 77 83 WO Cg 77 83 WO Cg 77 83 WO Cg 77 83 WO Cg 77 83 WO Cg 7784 WO Cg 76 84 WO Cg 76 84 WO Cg 76 84 WO Cg 7685 WI Ch 56 85 WI Ch 56 85 WI Ch 56 85 WI Ch 56 85 WI Ch 56 85WICh56 85 WI Ch 56 85WICh56 85 WI Ch 56 85 WI Ch 56

P28I 1 P28I 2 P28I 3 P28I 4 P28I 5 P28I 6P28I 1 P28I 2 P28I 3 P28I 4P28D 1 P28D 2 P28D 3 P28D 4WS106 1 WS106 2 WS106 3 WS106 4 WS106 5 WS106 6WS106 1 WS106 2 WS106 3 WS106 4

Sampling

date Time

mo/d/yr

11/13/90 1221 11/13/90 1226 11/13/90 1230 11/13/90 1235 11/13/90 1239 11/13/90 124204/04/91 1430 04/04/91 1435 04/04/91 1440 04/04/91 144912/23/92 1053 12/23/92 1057 12/23/92 1102 12/23/92 1106 12/23/92 111311/13/90 922 11/13/90 928 11/13/90 932 11/13/90 935 11/13/90 940 11/13/90 94411/13/90 827 11/13/90 837 11/13/90 844 11/13/90 851 11/13/90 855 11/13/90 90004/04/91 1730 04/04/91 1740 04/04/91 1800 04/04/91 180504/04/91 1830 04/04/91 1833 04/04/91 1837 04/04/91 184011/14/90 1045 11/14/90 1050 11/14/90 1057 11/14/90 1102 11/14/90 1110 11/14/90 111504/05/91 916 04/05/91 920 04/05/91 932 04/05/91 935

Concentration

in solution,

in pg/kg

CFC-11 CFC-12

132 1.6 12.7 1.5 12.5 1.3 14.1 9.6 15.0 0.0 27.7 10.946.6 3.1

0.0 33.4 0.0

0.0

0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0

250.1 233.0 251.5 235.7 254.4 164.6 274.4 199.1 261.7 241.1 286.2 199.7124.7 13.4 52.1 12.8 28.3 32.6 24.1 33.2 59.1 12.8 17.8 31.830.8 80.8 45.5 51.7 32.4 48.0 34.8 4225.6 2.5

0.0 3.8 0.0 5.7 0.0

299.5 206.7 339.4 214.6 289.4 149.6 341.1 188.2 306.6 243.7 339.7 189.1376.6 284.0 318.6 256.0 370.6 288.7 304.3 279.0

Partial pressure,

in pptv, at recharge

temperature

CFC-11 CFC-12

4.3 2.3 4.1 2.2 4.1 1.9 4.6 13.7 4.9 0.0 9.0 15.6

152 4.5 0.0

10.9 0.0 0.0

0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0

81.5 334.4 82.0 338.2 82.9 236.2 89.4 285.7 85.3 346.1 93.3 286.540.6 19.3 17.0 18.4 9.2 46.8 7.9 47.6

19.3 18.4 5.8 45.6

10.0 115.9 14.8 742 10.6 68.9 11.3 60.5

1.8 3.6 0.0

12 0.0 1.9 0.0

97.6 296.6 110.6 308.0 94.3 214.7

1112 270.1 100.0 349.7 110.7 271.4122.7 407.6 103.9 367.4 120.8 414.4 99.2 400.4

Model CFC-based

recharge dates

CFC-11 CFC-12

1955.5 1946.0 1955.5 1946.0 1955.0 1945.5 1955.5 1953.5 1956.0 1940.0 1959.0 1954.51962.0 1948.0 1940.0 1960.0 1940.0 1940.0

1945.0 1940.0 1945.0 1940.0 1945.0 1940.0 1945.0 1940.0 1945.0 1940.01972.0 1981.5 1972.0 1982.0 1972.0 1975.5 1972.5 1978.0 1972.5 1982.0 1973.0 1978.01967.5 1955.5 1962.5 1955.5 1959.0 1962.0 1958.0 1962.5 1963.0 1955.5 1956.5 1962.01959.5 1969.0 1961.5 1965.5 1960.0 1965.0 1960.5 1964.01952.5 1947.0 1940.0 1951.5 1940.0 1952.5 1940.01973.5 1979.5 1974.5 1980.0 1973.0 1974.5 1974.5 1977.5 1973.5 1982.5 1974.5 1977.51975.0 1985.5 1974.0 1983.5 1975.0 1986.0 1973.5 1985.5

No. of samples,

Julian date,

age in years,

standard deviation,

CFC-11 CFC-12

6.00 6.00 1956.08 1947.58

34.79 43.29 1.34 5.002.00 4.00

1961.00 1942.00 30.26 49.26

1.00 3.46

5.00 5.00 1945.00 1940.00

47.98 52.98 0.00 0.00

6.00 6.00 1972.33 1979.50

18.54 11.37 0.37 2.48

6.00 6.00 1961.08 1958.83

29.79 32.04 3.69 3.344.00 4.00

1960.38 1965.88 30.88 25.38 0.74 1.883.00 4.00

1952.17 1941.75 39.09 49.51 0.47 3.03

6.00 6.00 1973.92 1978.58

16.96 1229 0.61 2.494.00 4.00

1974.38 1985.13 16.89 6.14 0.65 0.96

51

Appendix B. Summary of chlorofluorocarbon data (cont.)

Well Well

no. name

85 WI Ch 5685 WI Ch 5685 WI Ch 5685 WI Ch 5685WICh5685 WI Ch 5686WICh5786WICh5786 WI Ch 5786WICh5786WICh5786 WI Ch 5786WICh5786 WI Ch 5786 WI Ch 5786 WI Ch 5786WICh5786 WI Ch 5786 WI Ch 5786 WI Ch 5786WICh5786 WI Ch 5786 WI Ch 5786WICh5786 WI Ch 5786 WI Ch 5786WICh5786WICh5786 WI Ch 5786WICh5787WIBhll87WIBhll87WIBhll87WIBhll87WIBhll87WIBhll87WIBhll87WIBhll88WIBh888WIBh888WIBh888WIBh889 WI Bh 989 WI Bh 989WIBh989 WI Bh 9

Localidentifer

WS106

WS106WS106WS106WS106WS106WS206WS206WS206WS206WS206WS206WS206WS206WS206WS206WS206WS206WS206WS206WS206WS206WS206WS206WS206WS206WS206WS206WS206WS206WS210WS210WS210WS210WS210WS210WS210WS210WS108WS108WS108WS108WS208WS208WS208WS208

Vialno.

1

2

3

4561234561234135123454567891234561312341234

Sampling

date

mo/d/yr

12/23/92

12/23/9212/23/9212/23/9212/23/9212/23/9211/14/9011/14/9011/14/9011/14/9011/14/9011/14/9004/05/9104/05/9104/05/9104/05/9111/15/9111/15/9111/15/9104/01/9204/01/9204/01/9204/01/9204/01/9212/23/9212/23/9212/23/9212/23/9212/23/9212/23/9211/14/9011/14/9011/14/9011/14/9011/14/9011/14/9004/05/9104/05/9104/05/9104/05/9104/05/9104/05/9104/05/9104/05/9104/05/9104/05/91

Time

1345

13491359140414081412858907914922933938813840853900

132413391353135414011407141314241514151815231527153015351410142314341439144614511222123011211125113011351040104510551103

Concentration

in solution,

in Pg/kg

CFC-11 CFC-12

454.0 305.6453.3 296.4468.9 328.1465.5 300.9470.6 302.6466.4 300.3306.1 146.0291.7 149.1276.4 86.8332.3 122.7294.2 1422375.8 128.0298.7 165.6259.4 132.3332.5 170.6251.3 151.5381.2 263.9222.1 279.0232.8 330.9238.1 223.5234.9 203.0231.5 226.9230.1 194.3241.0 224.4113.7 211.0116.0 223.8111.6 2302111.4 2122108.1 213.1113.5 224.059.3 5.241.6 2.462.4 0.068.1 55.0 0.992.5 0.043.3 0.025.9 0.072.0 14.8963 36.470.6 12.9

107.6 15.335.9 0.044.6 0.0342 0.055.4 0.0

Partial pressure,

in pptv, at recharge

temperature

CFC-11 CFC-12

148.0 438.6147.8 425.4152.8 470.8151.7 431.9153.4 434.3152.0 430.999.8 209.595.1 214.090.1 124.6

108.3 176.095.9 204.1

122.5 183.697.4 237.684.5 189.9

108.4 244.981.9 217.4

124.3 378.772.4 400.475.9 475.077.6 320.876.6 291.375.5 325.675.0 278.978.6 322.137.1 302.837.8 321236.4 330.3363 304.635.2 305.937.0 321.519.3 7.513.6 3.420.3 0.0222 17.9 1.4302 0.014.1 0.08,5 0.0

23.5 21231.5 52.223.0 18.635.1 22.011.7 0.014.5 0.0112 0.018.1 0.0

Model CFC-based

recharge dates

CFC-11 CFC-12

19773 1987.01977.5 1986.51978.0 1989.01978.0 1987.01978.0 1987.01978.0 1987.01973.5 1974.01973.0 1974.51973.0 1969.51974.0 1972.51973.0 1974.01975.0 1973.01973.5 1975.51972.5 1973.51974.0 1976.01972.0 1974.51975.5 1984.01971.0 1985.51971.5 1989.01971.5 1981.019713 1978.519713 1981.01971.5 1978.01972.0 1981.01967.0 1979.51967.0 1981.01966.5 1981.51966.5 1979.519663 1979.51967.0 1981.01963.0 1950.01961.5 1947.01963.5 1940.01964.0 1962.5 1944.51965.5 1940.01961.5 1940.01958.5 1940.01964.0 1956.51966.0 1963.01964.0 1955.51966.5 1956.51960.5 1940.01961.5 1940.01960.0 1940.01962.5 1940.0

No. of samples.

Julian date,age in years,

standard deviation,

CFC-11 CFC-12

6.00 6.001977.83 198725

15.15 5.73024 0.80

6.00 6.001973.58 1972.92

17.29 17.960.73 1.674.00 4.00

1973.00 1974.881826 16.390.79 0.96

1972.67 1986.171921 5.712.01 2.09

5.00 5.001971.60 1979.90

20.65 12.35020 1.36

6.00 6.001966.75 198033

26.23 12.65025 0.85

6.00 5.001963.33 1944.30

27.54 46.571.25 3.92

1960.00 1940.0031.26 51264.00 4.00

1965.13 1957.8826.14 33.39

1.14 2.994.00 4.00

1961.13 1940.0030.14 51260.96 0.00

52

Appendix B. Summary of chlorofluorocarbon data (cont.)

Well Well

no. name

89WIBh9 89WIBh9 89 WI Bh 9 89WIBh990WIBh4 90WIBh4 90WIBh4 90WIBh4 90WIBh4 90WIBh4 90WIBh4 90WIBh4 90WIBh4 90WIBh491WIBh5 91 WIBh59266M41 9266M41 9266M41 9266M41 9266M41 9266M41 9266M41 9266M41 9266M41 9266M41 9266M41 9266M41 9266M419366M19 9366M19 9366M19 93 66M 19 93 66M 19 93 66M 199466M42 9466M42 9466M42 9466M42 9466M42 9466M429566M44 9566M44 9566M44 9566M44 9566M44 9566M44

Local Via

identifer no.

WS208 1 WS208 2 WS208 3 WS208 4WS 103 1 WS 103 2 WS 103 4 WS 103 5WS 103 1 WS 103 3 WS 103 5WS 103 1 WS 103 3 WS 103 4WS203 1 WS203 2AC201D 1 AC201D 2 AC201D 3 AC 201D 4 AC201D 5 AC201D 6AC201D 1 AC201D 3AC201D 5 AC201D 6 AC201D 7 AC201D 8 AC201D 9SOW 1101 1sow no: 2 sow no: 3 sowiio: 4 sow no: 5 sow no: 6AC203S 1 AC203S 2 AC 203S 3 AC203S 4 AC203S 5 AC203S 6AC204S 1 AC 204S 2 AC204S 3 AC204S 4 AC204S 5 AC204S 6

Sampling

date Time

mo/d/yr

04/01/92 1532 04/01/92 1542 04/01/92 1547 04/01/92 155904/05/91 1447 04/05/91 1450 04/05/91 1500 04/05/91 150311/15/91 1444 11/15/91 1503 11/15/91 152104/01/92 1658 04/01/92 1711 04/01/92 171704/05/91 1410 04/05/91 142511/15/90 1600 11/15/90 1605 11/15/90 1609 11/15/90 1613 11/15/90 1619 11/15/90 162504/04/91 1618 04/04/91 164712/22/92 1502 12/22/92 1507 12/22/92 1514 12/22/92 1519 12/22/92 185911/16/90 847 11/16/90 850 11/16/90 854 11/16/90 858 11/16/90 901 11/16/90 90511/16/90 1020 11/16/90 1024 11/16/90 1030 11/16/90 1038 11/16/90 1040 11/16/90 104811/15/90 1710 11/15/90 1714 11/15/90 1719 11/15/90 1726 11/15/90 1731 11/15/90 1735

Concentration

in solution,

in pg/kg

CFC-11 CFC-12

134.1 4.0 125.6 4.0 106.4 2.7 130.9 3.6498.0 237.8 414.8 142.4 4452 159.3 460.3 161.5587.9 324.7 595.9 309.2 571.0 307.2497.4 244.9 507.1 241.8 515.9 235.4443.9 131.5 387.4 114226.7 6.3 73.9 6.4 20.9 1.5 27.6 12.3 24.2 7.6 25.1 11237.6 10.0 29.4 8.42.8 52 1.4 7.6 2.7 5.7 1.3 7.0 1.4 4.3

68.8 25.9 69.6 23.0

3.0 191.9 56.8 10.3 67.6 23.5 63.5 8.6642 4.9

1.8 65.8 1.8 892 0.0 76.4 32 89.1 0.087.8 268.8 942 256.4 71.7 201.6 83.8 231.0 87.1 274.6 80.4 229.5

Partial pressure,

in pptv, at recharge

temperature

CFC-11 CFC-12

43.7 5.8 40.9 5.7 34.7 3.9 42.7 52

162.3 341.3 1352 204.3 145.1 228.6 150.0 231.7191.6 466.0 1942 443.8 186.1 440.8162.1 351.5 165.3 347.0 1682 337.8144.7 188.8 126.3 163.9

8.7 9.1 24.1 92

6.8 2.1 9.0 17.7 7.9 10.9 8.2 16.1

12.3 14.4 9.6 12.00.9 7.4 0.4 10.9 0.9 82 0.4 10.0 0.4 6.2

22.4 37.2 22.7 33.0 '1.0 275.4 18.5 14.8 22.0 33.8 20.7 12.420.9 7.1

2.6

21.4 2.6 29.1 0.0 24.9 4.6 29.1 0.028.6 385.8 30.7 368.0 23.4 289.3 27.3 331.4 28.4 394.1 262 329.4

Model CFC-based

recharge dates

CFC-11 CFC-12

1968.0 1949.0 1967.5 1949.0 1966.5 1947.5 1967.5 1948.51979.0 1982.0 1976.0 1974.0 1977.0 1975.0 1977.5 1975.51982.5 1988.5 1982.5 1987.5 1982.0 1987.01979.0 1982.5 1979.5 1982.0 1979.5 1981.51977.0 1973.0 1975.5 1972.01958.5 1951.0 1964.5 1951.0 1957.0 1945.5 1959.0 1955.0 1958.0 1952.0 1958.5 1954.51960.5 1953.5 1959.5 1952.51951.0 1950.0 1949.5 1952.0 1951.0 1950.5 1949.5 1951.5 1949.5 1949.01964.0 1960.5 1964.0 1959.5 1951.0 1977.5 1963.0 1954.0 1964.0 1959.5 1963.5 1952.51963.5 1949.5 1946.5 1963.5 1946.5 1965.5 1940.0 1964.5 1948.0 1965.5 1940.01965.0 1984.5 1965.5 1983.5 1964.0 1978.5 1965.0 1981.5 1965.0 1985.0 1964.5 1981.5

No. of samples,

Julian date,

age in years,

standard deviation,

CFC-11 CFC-12

4.00 4.00 196738 194850

24.88 43.75 0.54 0.614.00 4.00

1977.38 1976.63 13.89 14.64 1.08 3.15

1982.33 1987.67 9.54 421 024 0.62

1979.33 1982.00 12.92 1025 0.24 0.41

197625 1972.50 15.01 18.76 0.75 0.50

6.00 6.00 195925 1951.50

31.62 39.37 2.43 3.11

1960.00 1953.00 3126 3826 0.50 0.505.00 5.00

1950.10 1950.60 42.88 42.38 0.73 1.07

6.00 6.00 1961.58 1960.58

2929 3029 4.75 8.14

5.00 6.00 1964.50 1945.08

26.38 45.79 0.89 3.74

6.00 6.00 1964.83 1982.42

26.04 8.46 0.47 2.21

53

Appendix B. Summary of chlorofluorocarbon data (cont.)

Well Well

no. name

Local Vial

identifer no.

9666M45 AC204D 1 9666M45 AC204D 2 9666M45 AC204D 3 9666M45 AC204D 4 9666M45 AC204D 5 9666M45 AC204D 69766M46 9766M46 9766M46 9766M46 9766M469863F25 9863F25 98 63F25 9863F25 9863F25 9863F259963F25 9963F25 9963F25 9963F25 9963F25

10063F49 10063F49 10063F49 10063F49 10063F49 10063F49 10063F4910163F44 10163F44 10163F44 10163F44 10163F44 10163F44 10163F4410263F45 10263F45 10263F45 10263F45 10263F45 10263F45 10263F45 10263F45

AC205S 1 AC205S 2 AC205S 3 AC205S 4 AC205S 6Well 1 1 Well 1 2 Well 1 3 Well 1 4 Well 1 5 Well 1 6Well 2 2 Well 2 3 Well 2 4 Well 2 5 Well 2 6WelUE 1 Well4E 2 Well 4E 4 WelUE 5 WelUE 6WelUE 1 Well 4E 3Well 4B 2 WelUB 3 WelUB 4 Well 4B 5 Well 4B 6Well 4B 1 WelUB 3WelUC 1 WelUC 2 WelUC 3 Well 4C 4 WelUC 5 Well 4C 6Well 4C 1 Well 4C 3

Sampling

date Time

mo/d/yr

11/15/90 1617 11/15/90 1620 11/15/90 1624 11/15/90 1631 11/15/90 1636 11/15/90 164311/15/90 1435 11/15/90 1439 11/15/90 1446 11/15/90 1453 11/15/90 150111/14/90 951 11/14/90 956 11/14/90 1001 11/14/90 1006 11/14/90 1014 11/14/90 101711/14/90 909 11/14/90 912 11/14/90 916 11/14/90 921 11/14/90 92411/14/90 1717 11/14/90 1720 11/14/90 1730 11/14/90 1734 11/14/90 173704/05/91 1335 04/05/91 135611/14/90 1348 11/14/90 1353 11/14/90 1357 11/14/90 1401 11/14/90 140604/05/91 1229 04/05/91 125511/14/90 1451 11/14/90 1456 11/14/90 1459 11/14/90 1504 11/14/90 1507 11/14/90 151104/05/91 1114 04/05/91 1154

Concentration

in solution,

in Pg/kg

CFC-11 CFC-12

429.5 85.1 70.5 106.0

292.3 65.8 72.2 75.4

116.0 93.0 75.8 55.3

462.1 172.3 455.6 165.4 375.6 424.8 433.8

250.1 94.5 258.3 115.6 262.2 98.0 262.1 106.1 252.4 116.8 255.5 107.7605.5 255.4 578.1 228.1 613.0 253.9 589.6 252.0 549.4 226.7

34081.1 245.5 38063.6 204.1 18839.4 223.4 49414.8 213.2- 26140.5 248.259740.1 266.8 51508.2 255.7

471.6 199.6 444.9 182.8 452.8 201.1 458.7 198.0 473.2 201.7484.6 202.5 491.3 202.7262.9 159.4 261.6 154.9 247.5 135.0 266.0 153.4 260.0 153.1 270.4 151.5331.3 155.2 319.9 159.7

Partial pressure,

in pptv, at recharge

temperature

CFC-11 CFC-12

140.0 122.1 23.0 1522 953 94.5 235 1082 37.8 133.5 24.7 79.4

150.6 247.3 1485 237.4 122.4 138.5 - 141.4

106.3 171.9 109.9 210.4 111.5 178.4 111.5 193.0 107.3 212.5 108.7 195.9257.5 464.6 245.8 415.0 260.7 462.0 250.7 458.5 233.6 412.514492 446.6 16186 371.3 8011 406.5

21013 387.9 11116 451.625403 485.4 21903 46522005 363.1 1892 332.5 192.6 365.8 195.1 360.3 2012 366.9206.1 368.5 208.9 368.8111.8 290.0 1112 281.9 105.3 -245.7 113.1 279.1 110.6 278.5 115.0 275.6140.9 282.4 136.0 290.7

Model CFC -based

recharge dates

CFC-11 CFC-12

1976.5 19695 1964.0 19715 1973.0 1967.5 1964.0 19685 1967.0 1970.0 1964.5 1966.01977.5 1976.0 1977.5 19755 1975.0 1976.5 -

1976.5 - 1974.0 19725 1974.5 1974.5 1974.5 19725 19745 19735 1974.0 19745 1974.0 197351988.5 19885 1987.5 1986.0 1989.0 19885 1988.0 1988.0 1986.5 1986.0

C 1987.5 C 19835 C 1985.5 C 1984.5 C 1987.5C 1990.0 C 1988.5

1983.5 1983.0 1982.0 1981.5 19825 1983.0 1983.0 1983.0 19835 1983.51984.0 1983.5 1984.5 1983.51974.5 1978.5 1974.5 1978.0 1974.0 1976.0 1974.5 1978.0 1974.5 1978.0 1974.5 197751976.5 1978.0 1976.5 1978.5

No. of samples,

Julian date,

age in years,

standard deviation.

CFC-11 CFC-12

6.00 6.00 1968.17 1968.83

22.71 22.04 4.87 1.77

5.00 2.00 1976.60 1975.75

1427 15.12 0.92 025

6.00 6.00 197425 197350

16.62 17.37 0.25 0.82

5.00 5.00 1987.90 1987.40

2.97 3.47 0.86 1.16

5.00 5.00 C 1985.70

5.17 1.60

C 198925 2.01

5.00 5.00 1982.90 1982.80

7.97 8.07 0.58 0.68

198425 1983.50 7.01 7.76

6.00 6.00 1974.42 1977.67

16.46 1321 0.19 0.80

1976.50 197825 14.76 13.01

54

Appendix B. Summary of chlorofluorocarbon data (cont.)

Well Well

no. name

10363F4610363F4610363F4610363F4610363F4610363F4610363F4610363F4610363F4610363F4610463F2910463F2910463F2910463F2910463F2910563F4710563F4710563F4710563F4710563F4710563F4710663F3010663F3010663F3010663F3010663F3010763F3110763F3110763F3110763F3110763F3110763F3110863F4810863F4810863F4810863F4810863F4810863F4810963F3210963F3210963F3210963F3210963F3210963F32

Localidentifer

WelUDWelUDWell 4DWell 4DWell 4DWelUDWell 4DWell 4DWell 4DWell 4DWell 5AWell 5AWell 5AWell 5AWell 5AWell 5BWell 5BWell 5BWell 5BWell 5BWellSBWell 6Well 6Well 6Well 6Well 6Well7AWell7AWell 7AWell 7AWell7AWell7AWell 7BWell7BWell7BWellTBWell 7BWell7BWell 8Well 8Well 8Well 8Well 8WellS

Vial

no.

1

2345678132345612345623456123456123456123456

Sampling

date

mo/d/yr

11/14/90

11/14/90

11/14/9011/14/9011/14/9011/14/9011/14/9011/14/9004/05/9104/05/9111/14/9011/14/9011/14/9011/14/9011/14/9011/14/9011/14/9011/14/9011/14/9011/14/9011/14/9011/15/9011/15/9011/15/9011/15/9011/15/9011/15/9011/15/9011/15/9011/15/9011/15/9011/15/9011/15/9011/15/9011/15/9011/15/9011/15/9011/15/9011/15/9011/15/9011/15/9011/15/9011/15/9011/15/90

Time

1605

1611

161516211626163116371639101010391228123112381241124411441151115411571201120411471152115612001205948952955959

10021006901907915920925929

104710501055105911021105

Concentration

in solution,

inpg/kg

CFC-11 CFC-I2

14.9 4.932.8 6.315.6 19.122.9 17.620.4 1218.6 16.217.3 6.516.5 14.932.3 11.232.2 8.7

654.9 247.1603.5 176.6674.5 215.0710.6 247.0691.6 213.9350.8 181.5323.3 142.4323.1 128.7304.5 122.3319.3 140.4304.1 120.3685.8 255.1673.4 239.2640.1 229.4684.6 262.3679.2 247.8

10286.1 272.617011.2 267.56747.1 223.04604.7 236.9

22004.6 261.03588.0 240.6215.0 83.2208.4 74.9235.7 66.8199.4 72.9203.2 75.4199.3 81.7

31611.2 244.144412.8 246.426609.1 208.315277.4 244.138603.9 245.515547.7 233.5

Partial pressure,

in pptv, at recharge

temperature

CFC-11 CFC-12

63 9.013.9 11.46.6 34.89.7 32.18.7 13.17.9 29.47.4 11.87.0 27.0

13.7 20.313.7 15.8

278.5 449.6256.6 321.4286.8 391.1302.2 449.5294.1 389.3149.2 330.2137.5 259.0137.4 234.1129.5 222.5135.8 255.4129.3 218.9291.6 464.1286.4 435.3272.2 417.3291.1 477.3288.8 450.8

4373.9 496.07233.6 486.72869.0 405.71958.1 431.19357.0 475.01525.7 437.8

91.4 151.588.6 136.3

100.2 121.584.8 132.686.4 137.284.8 148.6

13442 444.118886 448.211315 379.06496 444.1

16415 446.86611 424.8

Model CFC -based

recharge dates

CFC-11 CFC-12

1957.0 1951.01961.5 1952.51957.0 1960.01959.5 1959.51958.5 1953.01958.0 1958.51957.5 1952.51957.5 1958.01961.5 1956.01961.5 1954.5

Modern 1987.51988.5 1981.0

Modern 1985.0C 1987.5

Modern 1985.01977.5 1981.51976.5 1977.01976.5 1975.51975.5 1975.01976.0 1976.51975.5 1974.5

Modern 1988.5Modern 1987.0Modern 1986.5Modern 1989.5Modern 1987.5

C ModernC 1990.0C 1985.5C 1987.0C 1989.0C 1987.0

1973.0 1971.51972.5 1970.51973.5 1969.51972.5 1970.01972.5 1970.51972.5 1971.0

C 1987.5C 1987.5C 1984.0C 1987.5C 1987.5C 1986.5

No. of samples.

Julian date,

age in years.

standard deviation.

CFC-11 CFC-12

8.00 8.00

1958.31 1955.6332.56 35.25

1.43 3.461961.50 1955.25

29.76 36.01

4.00 5.001990.28 1985.20

0.59 5.671.03 2.38

6.00 6.001976.25 1976.67

14.62 14.210.69 2.32

5.00 5.001990.87 1987.80

0.00 3.070.00 1.08

6.00 6.00C 1988.25

2.62 1.91

6.00 6.001972.75 1970.50

18.12 20.370.38 0.65

6.00 6.00C 1986.75

4.12 1.28

55

Appendix B. Summary of chloroffuorocarbon data (cont.)

Well Well Local Vial

no. name identifer no.

110 Stream near Well 2 110 Stream near Well 2 110 Stream near Well 2111 Stream near WR 403 111 Stream near WR 403112 Cypress Branch 112 Cypress Branch 112 Cypress Branch113 Chesterville Branch 113 Chesterville Branch 113 Chesterville Branch 112114 Chesterville Branch Spr115 Chesterville Branch Spr116 Pocomoke River 116 Pocomoke River

Sampling

date Time

mo/d/yr

11/14/90 840 11/14/90 845 11/14/90 84511/13/90 1300 11/13/90 130011/08/90 850 11/08/90 85004/02/91 165411/06/90 900 11/06/90 90004/02/91 181504/02/91 103704/02/91 183004/05/91 1300 04/05/91 1300

Concentration

in solution,

inpg/kg

CFC-11 CFC-12

756.6 321.7 685.1 357.2 692.0 338.8820.6 367.1 935.4 430.9921.2 295.5

1161.6 345.7520.9 229.8

1050.1 295.9 1091.6 231.7702.0 340.5605.5 292.1796.5 582.8687.2 389.3 748.6 347.2

Partial pressure,

in pptv, at recharge

temperature

CFC-11 CFC-12

265.0 492.3 239.9 546.5 242.3 518.4261.5 516.4 298.1 606.2308.8 434.8 389.3 508.6192.5 369.0351.9 435.3 365.9 340.9266.5 559.8204.1 431.9292.8 931.2272.0 664.5 296.3 592.5

Model CFC -based

recharge dates

CFC-11 CFC-12

1989.5 1990.5 1987.0 Modern 1987.0 Modern1989.0 Modern

Modern CC 1987.0 C Modern

1982.5 1983.5C 1987.0 C 1982.0

1989.5 Modern1984.0 1987.0

Modern C1991.0 C

Modern Modern

No. of samples.

Julian date,

age in years,

standard deviation,

CFC-11 CFC-12

1987.83 1990.75 3.04 0.12 1.18 0.18

1989.93 Modern 0.93 -C 1989.25

1.611982.50 1983.50

C 1984.50 6.35

1989.50 Modern1984.00 1987.00

Modern C1991.13 Modern

0.13

56 *U.S. G.P.O.:1993-301-077:80047