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Page 1: DAFTAR PUSTAKA - repository.ipb.ac.idrepository.ipb.ac.id/jspui/bitstream/123456789/23230/19/Daftar... · work charge density on ion exchange properties of zeolites. J. Chem. Soc

DAFTAR PUSTAKA

Page 2: DAFTAR PUSTAKA - repository.ipb.ac.idrepository.ipb.ac.id/jspui/bitstream/123456789/23230/19/Daftar... · work charge density on ion exchange properties of zeolites. J. Chem. Soc

DAFTAR PUSTAKA

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LAMPIRAN .

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Tabel Lampiran 1. Klasifikasi Mineral Zeolit Berdasarkan Topologinya (Gotardi, 1978)

- -

Ke lompok Tipe Nama Komposisi Unit Sel Struktur Spesies

Kat ion Dominan

(Cincin 4 rongga) Phillipsit Phillipsit (CaOa5, Na, K)6 (A16Si10032) 12H20 Ca atau Na, K' Phillipsit Harmotom Ba2 A1 Si 0 12H20 Ba

'8 32 14H20 Gismondin Gismondin Ca4 AlgSi8 32 ca Gismondin Garronit Na Ca2 A1 Si 0 14H20 Ca Leusit Analsim Na16 ~ ' 1 6 ~ ~ 3 2 ~ 9 6 lo 3216H20 Na Leusit Wairakit Ca8 A116Sr32096 16H 0 Ca Paulingit Paulingit (K2, Na2, Ca. Ba) (Af152Si52501354) K

700H-0 4

Laurnontit Laurnontit Ca4 A 8Si16049 16H20 Yugawaralit Yugawaralit Ca2 Ai4Si120j2 8H20

2. Kelom~ok Khabazit

(Cincin 6 tunggal Khabazit Khabazit Ca2 A14SigOZ4 13H20 Ca atau Na dan ganda) Gmelinit Gmelinit Nag A18Si16048 24H20 Na atau Ca

Faujasit Faujasit Na12Ca12Mgll A15gSiAq303g4 234H 0 Na Erionit Erionit (K2~Ca~Mg~Na2)4.5 9Sr27 0.72 2 3 ~ ~ 0 Ca atau Na, K Offretit Offretit (K2,MgrCa,Na2)2.5 A15Sr13036 15H20 Ca atau Mg Levyn Levyn Ca3 A1 Si 0 18H20 Ca Mazzit Mazzit K2Mg2Cal. 5 12A3iSi27072 28H20 Mg

3. Kelom~ok Natrolit

Cincin 4-1) Natrolit Natrolit Na16 A116Si24080 16H20 Na Natrolit Tetr. NatrolNa16 A116Si240e0 16H20 Na Natrolit Mesolit Na16Ca A148Sr720 40 64H20 Na atau Ca Natrolit Scolecit Ca8 Af:6Si24!80 2aH 0 Ca ~homsoiit Thomsonit Na4Cag A120~r200go 1 4 ~ ~ 0 Ca Thomsonit Gonnardit Na Ca A1 Sr 0 14H20 Na Edingtonit Edingtonit Ba: il4Si;O2i2 ife20 Ba

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Tabel Lampiran 1 ( l a n j u t a n )

K e lompok Tipe Nama Komposisi U n i t S e l S t r u k t u r S p e s i e s

K a t i o n Dominan

4. Kelompok Mordenit

( C i n c i n 5-1) Mordenit Mordenit N a 8 A18Si40096 24H20 Ca a t a u Na D a c h i a r d i t D a c h i a r d i t Na5 A15Si 040 12H20 Ca a t a u Na F e r r i e r i t F e r r i e r i t N a l . $ f g 2 5Si30. 18H20 MS E p i s t i l b i t E p i s t i l b i t C a 2 A16Si18048 15H20 ~a B i k i t a i t B i k i t a i t LL Al2Sl4OI2 2H20 L i

5. Kelompok Heuland i t

(Cinc in 4-4-1) S t e l l e r i t S t e l l e r i t Ca4 A18Si28072 28H20 S t e l l e r i t S t i l b i t 34H20 S t e l l e r i t B a r r e r i t

Na A110Si260$2H20 ~ a i t18s t 2 8 ~ 7 2 B r e w s t e r i t B r e w s t e r i t SR2 A14S112z32 10H20 Heulandi t Heu land i t Ca4 A18Sr28 72 24H20 Heulandi t K l i n o p t i l o l i N a 6 A16Sr30072 24H20

Ca Ca a t a u Na N a S t Ca N a

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Tabel Lampiran 2. Jarak d Penciri Mineral-mineral di Daerah Penelitian

Nama Mineral ....................................................................... d.(AO) Cikembar d(AO) Bayah A(AO) Cikalong

Montmor ilonit Montmori lonit Montmorilonit Mordenit mika Mordenit Klinoptilolit Mordenit Mordenit Mordenit Klinoptillolit Montmorilonit Mika Montmorilonit Mordenit Klinopt ilolit Montmorilonit Klinoptilolit Kuarsa Mika Mordenit Plagioklas Klinoptilolit Plagioklas Plagioklas Mordenit Mika Montmorilonit Kuarsa Mordenit Plagioklas Montmorilonit Klinoptilolit Plagioklas Klinoptilolit

Montmorilonit Mordenit Kuarsa

Montmorilonit

Mordenit Mordenit Klinoptilolit Klinopt ilolit Klinopt ilolit Mordenit Mordenit

Klinot ilolit Montmorilonit Montmorilonit Klinoptilolit Mordenit Kuarsa Klinopt ilolit Mordenit Klinoptilolit Plagioklas Mordenit Mordenit Montmorilonit Mordenit

Kuarsa Montmmorilonit Plagioklas Klinoptilolit Plagioklas

Klinoptilolit Mordenit Plagioklas Klinoptilolit

Montmorilonit Mordenit

Montmorilonit Montmorilonit Mordenit Klinoptilolit Klinoptilolit Klinoptilolit Mordenit Mordenit Mordenit Klinoptilolit Klinoptilolit Montmorilonit Montmorilonit Mordenit Montmorilonit Klinoptilolit Kuarsa Klinopt ilolit Mordenit Kl inopt ilolit Mordenit Mordenit Kuarsa Montmorilonit Mordenit Montmorilonit Klinoptilolit Morden it Klinoptilolit Montmorilonit Mordenit

* Joint Committee on Powder Diffracttion Standars, 1974

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Tabel Lampiran 3. Konsentrasi Basa-basa Zeolit Cikembar yang Dapat Dipertukarkan Dengan NH4C1

Normalitas NH C1 ,,,,,,,,,,--,,4,,, Ca Mg K Na Total ........ ........ Perlakuan Aktifasi (me/100g)

Tabel Lampiran 4. Konsentrasi Basa-basa Zeolit Ba ah yang Dapat Dlpertukarkan Dengan N H ~ C ~

Normalitas NH C1 Ca Mg K Na ,,,,,,,,,,,,,,4,,, Total ........ Perlakuan Aktifasi (me/ 100g) ....... Konfjrol

HC1 0.5 NaOH 0. NaOH 0.

HC1 0.50 NaOH 0.2 NaOH 0.5

NaOH 0.25 NaOH 0.5 N

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Tabel Lampiran 5. Konsentrasi gasa-basa Zeolit Cikalon yang Dapat Dlpertukarkan Dengan NH4C 9

Normalitas NH C1 ,,,,,,,,,-,--,4-,, Ca Mg K Na Total

Perlakuan Aktifasi ........ (me/100g) ....... Konhrol)

t e:~c,{ HC1 0.25 N HC1 0.50

N& NaOH 0.25 NaOH 0.5 N]

Konhrol)

t ::or ] HC1 0.25 N HC1 0.50

Ne NaOH 0.25 NaOH 0.5 N]

Tabel t am pi ran 6. Konsentrasi Basa-basa Zeolit Cikembar yang Dapat Dipertukarkan Dengan KC1

Normalitas KC1 ------------------ Ca Mg Na Total

Perlakuan Aktifasi ........ (me/100g) ......

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Tabel Lampiran 7. Konsentrasi Basa-basa Zeolit Bayah yang Dapat Dipertukarkan Dengan KC1

Normalitas KC1 Ca Mg Na _________________- Total ........ Perlakuan Aktifasi (me/ 100g) ...... 6.41 9.85 75.41 5.89 10.01 65.56

46.74 5.47 9.51 61.52 4.61 6.82 40.64 3.33 5.43 30.52 0.17 22.53 75.28 0.05 24.78 65.61

Tabel Lampiran 8. Konsentrasi Basa-basa Zeolit Cikalong yang Dapat Dipertukarkan Dengan KC1

Normalitas KC1 Ca Mg Na _________________- Total ...... ........ Perlakuan Aktifasi (me/100g)

4.60 16.19 77.16 4.32 16.73 75.97 4.40 16.44 82.18 4.40 12.51 37.97 1.77 11.80 31.10 0.03 25.41 60.50 0.01 26.82 51.60

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Tabel Lampiran 9. Konsentrasi Basa-basa Zeolit Cikembar yang Dapat Dlpertukarkan Dengan NaCl

Normalitas NaCl ------------------ Ca Mg Na Total ...... ........ Perlakuan Aktifasi (me/ 100g)

Tabel t am pi ran 10. Konsentrasi Basa-basa Zeolit Bayah yang Dapat Dipertukarkan Dengan NaCl

Normalitas NaCl ------------------ Ca Mg Na Total

Perlakuan Aktifasi ........ (me/100g) ......

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Tabel Lampiran 11. Konsentrasi pasa-basa Zeolit Cikalong yang Dapat Dipertukarkan Dengan NaCl

Normalitas NaCl Ca Mg Na ______________--_- Total Perlakuan Aktifasi ........ (me/100g) ......

KonGrol)

2'8:oE] HC1 0.25 N HC1 0.50 Ni NaOH 0.25 NaOH 0.5 N1

Konfjrol) :82011 'HC1 0.25 N 'HC1 0.50 Ni 'NaOH 0.25 :NaOH 0.5 N]

Tabel Lampiran 12. Konsentrasi Basa-basa Zeolit Cikembar yang Dapat Dipertukarkan Dengan CaC12

orm ma lit as CaCl Ca Mg Na ,,,---,-,-,,-,--2- Total Perlakuan Aktifasi ........ (me/100g) ......

HC1 0.50 Nl NaOH 0.25 NaOH 0.5 N]

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Tabel t am pi ran 13. Konsentrasi Qasa-basa Zeolit Bayah yang Dapat Dipertukarkan Dengan CaC12

Normalitas CaCl ,,-,,,-,,,,,--,-2, Ca MS Na Total

Perlakuan Aktifasi ........ (me/ 100g) ......

2.50 2.85 3.76 9.11 1.68 4.10 3.95 9.73 1.64 4.20 3.88 9.72 0.48 0.95 1.49 2.92

HC1 0.50 Nk 0.26 0.61 1.11 1.98 NaOH 0.25 0.62 3.85 38.18 42.65 NaOH 0.5 Nj 0.51 3.39 41.63 45.53

HC1 0.50 Ni NaOH 0.25 NaOH 0.5 N]

Tabel Lampiran 14. Konsentrasi Basa-basa Zeolit Cikalong yang Dapat Dipertukarkan Dengan CaC12

Normalitas CaCl ,,,,,,,,,,,,,,,,2, Ca Mg Na Total

Perlakuan Aktifasi ........ (me/100g) ......

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Tabel Lampiran 15. Konsentrasi $asa-basa Zeolit Cikembar vanq Dapat Dipertukarkan Dengan MgC12 * - -

or ma lit as MgCl Ca Mg Na -____-_----------- Total ...... ........ P-lakuan ~ktifasi (me/100g)

10.20 0.32 1.93 12.45 7.55 1.66 2.12 11.33

0.79 1.99 9.50 0.00 0.43 2.46 0.00 0.38 1.72 0.92 18.95 27.42 1.12 21.89 32.24

14.33 0.55 1.738 16.61 11.82 1.35 1.99 15.16 11.96 1.44 2.30 15.76 2.68 0.16 0.55 3.39

0.16 0.38 2.80 1.12 19.64 34.99 1.08 18.92 33.18

12.11 2.23 2.02 16.36 10.39 1.65 2.31 14.35 12.57 1.35 2.30 16.22 1.85 0.28 0.41 2.54

0.44 0.54 2.53 1.22 19.63 35.83 1.62 21.09 40.33

Tabel Lampiran 16. ~onsentrasi Basa-basa ~eolit Bayah yang Dapat Dipertukarkan Dengan MgC12

Normalitas MgCl Ca Mg Na _________-________ Total ...... ........ Perlakuan ~ktifasi (me/100g)

9.94 0.81 1.51 12.26 7.43 1.03 1.54 10.00

1.09 1.59 10.15 0.00 0.24 1.33 0.27 0.25 1.65 1.89 20.71 31.02 1.81 25.01 38.77

13.62 1.58 1.35 16.53 1.49 1.58 14.36 1.53 1.74 15.98 0.27 0.39 3.17 0.45 0.25 3.08 1.84 20.67 37.28 1.62 24.99 44.36

17.52 1.36 1.16 20.04 13.23 1.90 1.57 16.70 12.92 1.69 1.78 16.39

1.26 0.38 3.51 0.52 0.23 2.41 1.62 20.17 36.81 1.98 23.74 45.15

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Tabel Lampiran 17. Konsentrasi Basa-basa Zeolit Cikalong yang Dapat Dipertukarkan Dengan MgC12

or ma lit as MgCl Ca Mg Na _______--_--_--_-_ Total Perlakuan Aktifasi ........ (me/100g) ......

KonGrol)

::so: ] HC1 0.25 N HC1 0.50 Nl NaOH 0.25 NaOH 0.5 Nj

Kontjrol)

:82oE]

IE: 8 2 8 1)3 NaOH 0.25 NaOH 0.5 N]

'Kon&rol) ;g;.g] 'HC1 0.25 N 'HCl 0.50 N 'NaOH 0.25 INaOH 0.5 N

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Tabel Lampiran 18. Rasio Oksida Si Terhadap A1 Zeolit Sebagai Akibat Perlakuan Aktifasi

Rasio Si/A1 Macam Aktifasi ...........................................

Cikembar Bayah Cikalong

Kontrol

Suhu

NaOH

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Fraks i Pasir Fraks i D e b u Fraksi L i a t P e d o n S i m b o l K e d a l a m a n .................................. --------------

H o r i s o n (cm) Sangat K a s a r Sedang H a l u s Sangat K a s a r Sedang H a l u s K a s a r H a l u s kasar h a l u s ...................................................................................................

( 1 ) ( 2 ) ( 3 ) ( 4 ) ( 5 ( 6 ) ( 7 ) ( 8 ) ( 9 ) ( 1 0 )

P 1 A ( C i k e m - E l b a r ) E2

B t l B t 2

I I B t 3 I I B C I I C

P 2 AP ( C i k e m - A 1 b a r ) B 2 1

B2 2 BC

' C

P 3 ( C i k e m - %

b a r ) B t l B t 2 BC

P 4 AP ( B a y a h ) AB

BW

P5 AP ( B a y a h ) B t l

B t 2 BC C

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Tabel Larnpiran 1 9 ( l a n j u t a n )

F r a k s i P a s i r F r a k s i Debu F r a k s i L i a t Pedon Simbol Kedalaman .................................. ------------------- --------------

Horison (cm) Sangat Kasar Sedang Halus Sanga t Kasar Sedang Halus Kasar Halus k a s a r h a l u s ...................................................................................................

( 1 ) ( 2 ) ( 3 ) ( 4 ) ( 5 ) ( 6 ( 7 ( 8 ) ( 9 ) ( 1 0 )

P 7 A (Cika- AB long) B t

BC

P8 A (Cika- B t l l ong) Bt2

C

P9 - A (Cika- B t l l ong) Bt2

C

Keterangan:

P a s i r : - P a s i r s a n g a t k a s a r = 2 - 1 mm - Kasar - - 1 - 0 . 5 mm - .Sedang = 0.5 - 0.25 mm - Halus = 0.25 - 0.10 mm - Sangat h a l u s = 0.10 - 0.05 mm

Debu : - Kaaar - Sedng - Halus

L i a t : - Kasar - Halus

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Tabel Larnpiran M. Kelas Tekstur dan Ukuran Butir peda Pedon p t ~ D i t e l i t i

Total Fraksi Nisbah Kelas S i h l Kedalaman . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - a -----------------

Pedon Horison (cm) Pasir Oebu L ia t Oebu + Liat Dekr/ l ia t Oebu halus/ L iat halus/ Tekstur Ukuran Total L ia t Total L int Total But i r

_ _ _ - - - _ _ _ _ _ _ - - _ _ _ - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - * - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - -

( 1 ) ( 2 ) (3) ( 4 ) ( 5 ) (6 ) ( 7 ) (8) ( 9 )

P-1 A (Cikambsr) A21

A22 B t l Bt2 Bt3 BC C

P-2 Ap (Cikembar) A1

821 822 BC C

c l . 1 FS c l . 1 FS c l . 1 FC c l . 1 FC c l . 1 FS

P-3 Ap (Cikembar) AB

B t l Bt2 BC

sicl.1 FC s ic1 FC sicl.1 FC s 1 CS

P-4 Ap (Bayah) AB

BU C

P-5 A (Bayah) B t l

Bt2 BC

. %.

C

s ic1 FC c 1 FC c 1 FC s ic1 FC s l CS

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Tabel Lanpiran 20 ([anjutan)

Total Fraksi Nisbah Ke l as S i h l Kedalaman . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . - - - - - - - - - - - - - - - - - - - - - - - - e m - - - - - - - - - - - - - - - - - - - - - - - - - - - -

Pedon Horison (cm) Pasir Debu L i a t Debu + L i a t Debu/Liat Debu halus/ L i a t hatus/ Tekstur Ukuran Tota l L i a t Total L i a t Tota l But i r . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

(11) (12) (13) (14) (15) (16) (17) (18) (19)

P-6 A (Bayah) AB

Bt BC C

P-7 A (Cikalong) AB

Bt BC D

P-8 A (Cikalong) B t l

Bt2 C

P-9 A (Cikalong) B t l

Bt2 C

s i c 1 FC s ic l .1 FS s i c 1 FC s i c l . 1 FS s ic l .1 FC

cl .1 FS c l c l FC c l FC s i 1 CS

Keterangan: 1 : lemppng s i c 1 : l i a t berdebu c 1 : l i a t s i c l .1 : Lemptng l i a t berdebu c l .1 : lempung b e r l i a t s i 1 : L-ng berdebu 1s : pasi r kr lerrpung CS : coarse s i l t y ( d e b kasar) s l : lenpung berpasir FS : f i n e s i l t y (debu halus)

FC : f i n e clayey ( L i a t halus)