coral getino et al- unimolecular decay lifetimes and intramolecular energy redistribution in hooh:...
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8/3/2019 Coral Getino et al- Unimolecular Decay Lifetimes and Intramolecular Energy Redistribution in HOOH: Sensitivity to P
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8/3/2019 Coral Getino et al- Unimolecular Decay Lifetimes and Intramolecular Energy Redistribution in HOOH: Sensitivity to P
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0 ,`mfppk`fm ~xfog`~c x{+- Hxcwugx g~ fm" ,p~f~kp~k`fm fn kfhf~k``lfbbgm+3 fbn Pw it~gx fbn ^lcitpcb ,~xfog`~cx{ fbn Icb~g@fxmc ~f~k kp ~k`fm+%R fx g `cbpkp~gb~ uk~l mkjg~kigp kb ~lg xfbe g 0"7)5"4tp jcx wCL9 : kbjgxxgn jxci g|tgxkigb~fm ptg`~xf//( cb ~lgfppwit~kcb ~lf~ ~l g ncikbfb~ `cb ~xkhw~kcb ~c ~lg czgx~cbg mkbgukn~l kp nw g ~c wbkicmg`wmfx ng`f{"^l g tc~gb~kfm gbgxe{ pwxjf`g wpgn kb ~lg ~xfog`~cx{ `fm`wmf~kcbpcj Wgx g~ fMK> kb`cxtcxf~gn ptg`~xcp`ctk` fb n ~lgxicn{b fik`nf~f fbn icngmgn ~lg CL bn 44 hcbn p~xg~`lgp fp Icxpgcp`kmmf~cxp fbn ~lg LCC hgbnp fp lfxi cbk` Cp`kmmf~cxp" ,^cxpkcbfmic~kcb ufp jxcgb kb ~lg i focxk~{ cj ~lg `fm`wmf~kcbp xgtcx~gnkb xgj 6>"+ Tc~gb~kfm `cwtmkbe hg~uggb ~l g gxc~l)cxngx icngpufp kb~xcnw`gn kb ~uc uf{p? cjj)nkfecbfm ~gxip kb ~lg J)if~xk|fbn puk~`lkbe jwb`~kcbp ngp`xkhkbe ~lg f~~gbwf~kcb cj ~lg LCClfxicbk` hgbn jcx`g `cbp~fb~ h{ p~xg~`lkbe cj ~lg fnof`gb~ LCcx 44 hcbn"84)88^lg tc~gb~kfm pwxjf`g cj Wgx g~ fm" ufp lcugzgx wbpf~kpjf`~cx{kb pgzgxfm xgptg`~p ,fp bc~gn h{ ~lgpg fw~lcxR%R+" ^lg puk~`lkbejwb`~kcbp wpgn kb xgj 6> f`~wfmm{ ngp`xkhg p~xg~`l)hgbn tc~gb~kfm`cwtmkbe kb f @@ L jxfeigb~184 puk~`lkbe jwb`~kcbp fttxctxkf~gjcx ~lg CC L jxfe igb ~ lfzg pkb`g hg`cig fzfkmfhmg"86/88 b fn)nk~kcb- ~lg cjj)nkfecbfm J)if~xk| gmgigb~p g|lkhk~ wbtl{pk`fmhglfzkcx f ~ mfxeg zfmwgp cj ~lg 44 hcbn mgbe~l- fp ~lg{ fxg bc~f~~gbwf~gn kb f tl{pk`fmm{ fttxct xkf~g jfplkcb f p ~lg icmg`wmg jfmmpftf x~" Ft fx~ jxci k~p gjjg`~ cb ~lg n{bfik`p- ~lkp wbtl{pk fmfp{i t~c~k` hglfzkcx cj ~lg tc~gb~kfm i gfbp ~lf ~ k~ kp bc~ tcppkhmg
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%Gbpgihmg cj icmg`wmgp uk~l xc~f~kcbfm gbgxe{ gvwkzfmgb~ ~c ^ 904 4 A" Gbpgihmg cj bcbxc~f~kbe icmg`wmgp"~c ch~fkb ugmm)ngjkbgn xc~f~kcb)zkhxf~kcb p~f~g nkp~xkhw~kcbp cj ~lgCL xfeigb~p jcx `citfxkpcb uk~l g|tgxkigb~"pKb ~lkp Mg~~gx ug txgpgb~ xgpwm~p cj vwfpk`mfppk`fm ~xfog`~cx{`fm`wmf~kcbp cj czgx~cbg)kbnw`gn wbkicmg`wmfx ng`f{ cj LCCLwpkbe f tc~gb~kfm pwxjf`g kb ulk`l ~lg fhczg plcx~`cikbep lfzghggb `cxxg`~gn" Ug fmpc g|fikbg ~lg xgmf~kcb hg~uggb ~lg ~kigp`fmg jcx `mfppk`fm wbkicmg`wmfx ng`f{ fbn ~lf~ jcx kb~xficmg`wmfxzkhxf~kcbfm gbgxe{ xgnkp~xkhw~kcb"Tc~gb~kfm Gbgxe{ Pwxjf`g jcx LCCLKb hxkgj- ~lg tc~gb~kfm pwxjf`g wpgn lgxg ,`j" xgj 801 jwx~lgxng~fkmp fbn ~xfog`~cx{ xgpwm~p jcx c~lgx icngm pwxjf`gp fxg ekzgbkb xgj 6; + kp fb fh kbk~kc#gitkxk`fm pwxjf`g cj ~lg jcxi wpgn h{Wgx g~ fm"-K> kb ulk`l ~lg ngjk`kgb`kgp bc~gn fhczg lfzg hggbxgignkgn"Jkxp~- ~lg tc~gb~kfm hglfzgp kb f tl{pk`fmm{ xgfpcbfhmg jfplkcbfp xcc ) " ^lwp- cjj)nkfecbfm lfxicbk` jcx`g jkgmn tc~gb~kfm`cwtmkbe ~gxip fxg jk~ ~c f pwi cj bcbhcbngn Mgbbfxn)Ocbgpkb~gxf`~kcbp- ulk`l ng`f{ ~c gxc fp xcc ) 0" Kb fnnk~kcb- ~lgCL hcbn jcx`g `cbp~fb~p xgmf| ~c ~lgkx zfmwgp jcx jxgg CL- fb n~lg ~cxpkcbfm tc~gb~kfm kp xgtxgpgb~gn fp f Jcwxkgx pgxkgp uk~l`cgjjk`kgb~p ~lf ~ ec ~c gxc fp ~l g icmg`wmg nkppc`kf~gR"%R/RRPg`cbn- f h kbk~kc `fm`wmf~kcbp , P@ J uk~l :)0 6E//hfpkp wpkbe~l g EFWPPKFB tf`afeg>+ lfzg hggb wpgn ~c ng~gxi kbg ~lgpuk~`lkbe jwb`~kcb P,xcc+ ~lf~ n g~gxikbgp ~lg tc~gb~kfm gbgxe{`cwtmkbe hg~uggb ~lg LCC gbn fbn ~lg xgf`~kcb `ccxnkbf~g" ^lgjwb`~kcb wpgn lfp ~lg jcxi
P,xcc+ 9 6 ) ~fbl ,4"68747Fxccp+ ,8 +^l g puk~`lkbe jwb`~kcb P,x4L+ ngp`xkhkbe ~lg f~~gbwf~kcb cj ~lgL C C hgbn jcx`g cbp~fb~ h{ ~lg CL p~xg~`l kp ~l f~ ekzgb kb xgj88 " lg puk~`lkbe jwb`~kcbp fxg tmc~~gn kb Jkewxgp 6 fb n 8- ceg~lgxuk~l ~l g puk~`lkbe jwb`~kcbp wpgn kb xgj 6>" Jcx hc~l ~lg CL fb n44 p~xg~`lgp- ~l gxg fx g fttxg`kfhmg nkjjgxgb`gp hg~uggb ~lg ~ucjwb`~kc bp" Pkb`g ~l g p~xg~`l)hgbn `cwtmkbe kbnw`gn h{ ~lg
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8/3/2019 Coral Getino et al- Unimolecular Decay Lifetimes and Intramolecular Energy Redistribution in HOOH: Sensitivity to P
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Mg~~gxp ^lg Ocwxbfm cj Tl{pk`fm @lgikp~x{- Zcm" ;0 - Bc" 64- 6;" Ng~fkmgn g|fi kbf~kcb cj `mfppk fm ~xfog ~cxkgp6>O; plcup~lf~ gbgxe{ kbk~kfmm{ kb f b g|`k~gn mc`fm icng ncgp bc~ jmcu nkxg`~m{jxci ~lg C L hcbn kb~c ~lg xgf`~kcb `ccxnkbf~g ,44 hcbn+ hw~f``wiwmf~gp kb ~lg 44 cbn cbm{ xgmf~kzgm{ pmcum{" ^l g pgtfxf~kcbcj ~kig p`fmgp jcwbn lgxg xgjmg`~p ~lg pgvwgb~kfm bf~wxg cj ~lg`mfppk`fm wbkicmg`wmfx nkppc`kf~kcb"Czgx~cbg xgmf|f~kcb xf~gp jcx ~l g bcbnkppc kf~kbe p~f~gp zCL 9> fbn 7 fxg fmpc plcub kb ^fhmg K" ,F pifmm bwihg x cj ~xfog`~cxkgpnkppc`kf~g jcx ~lgpg p~f~gp fp f `cbpgvwgb`g cj (fnkfhf~k` mgfa("08^lg `mfppk`fm ~xfog`~cx{ xgpwm~p kbnk`f~g ~lf~ kbk~kfm gbgxe{ jmcucw~ cj ~l g g|`k~gn CL hcbn kp zgx{ iw`l pmcugx jcx zCL9 > fbn7" Jcx zC L 9 :- ~lg g|`k~gn CL hcbn kp kbk~kfmm{ kb f 7?8 Jgxikxgpcbfb`g uk~l ~l g fnof` gb~ hgbn16; f mcu)cxngx xgpcb fb`g kp bc~txgpgb~ jcx zCL 9 > fbn 7"Ug bc~g ~lf~ ~lg vwfpk`mfppk`fm gjjg`~kzg czgx~cbg mkbg ukn~l`fm`wmf~gn jcx fb gbpgihmg cj xc~f~kbe icmg`wmgp uk~l zCL 9 :,4"56 `i)K+ kp kb p~xkakbem{ eccn fexg gigb ~ uk~l ~lg zgx{ xg`gb~g|tgxkigb~fm xgpwm~ ,4"< `i)%+ cj Mwc%g~ fm" jcx ~lg xc~f~kcbfm p~f~g, O - A + 9 ,68- 8+"( Pw` l fexggi gb~ kp kb fmm txchfhkmk~{ gb~kxgm{jcx~wk~cwp" Kb fnnk~kcb ~c wb`gx~fkb~kgp `cb`gxbkbe hc~l ~l g tc)~gb~kfm pwxjf`g fbn ~lg nktcmg pwxjf`g- ulgxg ~lg mf ~~gx ng~gxikbgp~lg bf~wxg cj ~lg kbk~kfmm{ txgtfxgn p~f~g- ~lg vwfpk`mfppk`fm ft)txc|kif~kcb jcx `fm`wmf~kbe mkbg plftgp kp cj nwhkc wp zfmknk~{ kb~lg txgpgb~ `cb~g|~" F bg`gppfx{ `cbnk~kcb jcx ~l g vwfpk`mfppk`fmtxc`gnwxg ~c {kgmn f xgfpcbfhmg fttxc|kif~kcb ~c ~lg gbzgmctg
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8/3/2019 Coral Getino et al- Unimolecular Decay Lifetimes and Intramolecular Energy Redistribution in HOOH: Sensitivity to P
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