copper alloys
DESCRIPTION
Copper alloys are metal alloys that have copper as their principal component. They have high resistance against corrosion. The best known traditional types are bronze, where tin is a significant addition, and brass, using zinc instead. Both these are imprecise terms, both having been commonly referred to as lattens in the past. Today the term copper alloy tends to be substituted, especially by museumsTRANSCRIPT
Copper alloys are metal alloys that have copper as their principal component. They have
high resistance against corrosion. The best known traditional types are bronze,
where tin is a significant addition, and brass, using zinc instead. Both these are imprecise
terms, both having been commonly referred to as lattens in the past. Today the
term copper alloy tends to be substituted, especially by museums.[1]
Paduan tembaga adalah paduan logam yang memiliki tembaga sebagai komponen utama mereka.
Mereka memiliki ketahanan yang tinggi terhadap korosi. Jenis tradisional yang paling dikenal
adalah tembaga, mana tin adalah penambahan yang signifikan, dan kuningan, menggunakan seng
sebagai gantinya. Baik ini adalah istilah yang tidak tepat, kedua memiliki telah sering disebut
sebagai lattens di masa lalu. Hari ini istilah paduan tembaga cenderung diganti, terutama oleh
Museum.[1]
Composition
The similarity in external appearance of the various alloys, along with the different
combinations of elements used when making each alloy, can lead to confusion when
categorizing the different compositions. There are as many as 400 different copper and
copper-alloy compositions loosely grouped into the categories: copper, high copper alloy,
brasses, bronzes, copper nickels, copper–nickel–zinc (nickel silver), leaded copper, and
special alloys. The following table lists the principal alloying element for four of the more
common types used in modern industry, along with the name for each type. Historical
types, such as those that characterize the Bronze Age, are vaguer as the mixtures were
generally variable.
Komposisi kesamaan dalam penampilan eksternal dari berbagai paduan, bersama dengan
berbagai kombinasi dari unsur-unsur digunakan ketika membuat setiap paduan, dapat
mengakibatkan kebingungan ketika categorizing komposisi yang berbeda. Ada sebanyak 400
tembaga yang berbeda dan komposisi copper-alloy longgar dikelompokkan ke dalam kategori:
tembaga, tembaga tinggi paduan, brasses, bronzes, tembaga nickels, tembaga � nikel � seng
( nikel perak ), tembaga bertimbal, dan paduan khusus. Berikut daftar meja utama unsur alloying
untuk empat dari lebih jenis umum digunakan di modern industri, bersama dengan nama untuk
setiap jenis. Jenis historis, seperti mereka yang mengkarakterisasi zaman perunggu, apakah
vaguer campuran seperti yang sedang umumnya variabel.
Classification of copper and its alloys
FamilyPrincipal alloying
elementUNS numbers
Copper alloys, brass Zinc (Zn)C1xxxx–C4xxxx,C66400–
C69800
Phosphor bronze Tin (Sn) C5xxxx
Aluminium bronzes Aluminium (Al) C60600–C64200
Silicon bronzes Silicon (Si) C64700–C66100
Copper nickel, nickel
silversNickel (Ni) C7xxxx
Mechanical properties of common copper alloys[2]
Name
Nominal
compositi
on
(percentag
es)
Form
and
conditi
on
Yield
strengt
h (0.2%
offset
,ksi)
Tensil
e
streng
th
(ksi)
Elongati
on in
2 inches
(percent
)
Hardne
ss
(Brinell
scale)
Comments
Copper
(ASTM B1, B2,
B3, B152,
B124, R133)
Cu 99.9Anneal
ed10 32 45 42
Electrical
equipment,
roofing,
screens
" "Cold-
drawn40 45 15 90 "
" " Cold- 40 46 5 100 "
rolled
Gilding
metal (ASTM
B36)
Cu 95.0,
Zn 5.0
Cold-
rolled50 56 5 114
Coins, bullet
jackets
Cartridge
brass (ASTM
B14, B19, B36,
B134, B135)
Cu 70.0,
Zn 30.0
Cold-
rolled63 76 8 155
Good for cold-
working; radia
tors,
hardware,
electrical, dra
wn cartridge
cases.
Phosphor
bronze (ASTM
B103, B139,
B159)
Cu 89.75,
Sn 10.0, P
0.25
Spring
temper— 122 4 241
High fatigue-
strength and
spring
qualities
Yellow or High
brass (ASTM
B36, B134,
B135)
Cu 65.0,
Zn 35.0
Anneal
ed18 48 60 55
Good
corrosion
resistance
" "Cold-
drawn55 70 15 115 "
" "
Cold-
rolled
(HT)
60 74 10 180 "
Manganese
bronze (ASTM
138)
Cu 58.5,
Zn 39.2, Fe
1.0, Sn 1.0,
Mn 0.3
Anneal
ed30 60 30 95 Forgings
" "Cold-
drawn50 80 20 180 "
Naval brass
(ASTM B21)
Cu 60.0,
Zn 39.25,
Sn 0.75
Anneal
ed22 56 40 90
Resistance to
salt corrosion
" "Cold-
drawn40 65 35 150 "
Muntz
metal (ASTM
B111)
Cu 60.0,
Zn 40.0
Anneal
ed20 54 45 80
Condensor tu
bes
Aluminium
bronze (ASTM
B169 alloy A,
B124, B150)
Cu 92.0, Al
8.0
Anneal
ed25 70 60 80 —
" " Hard 65 105 7 210 "
Beryllium
copper (ASTM
B194, B196,
B197)
Cu 97.75,
Be 2.0, Co
or Ni 0.25
Anneal
ed,
solution
-treated
32 70 45
B60
(
Rockwe
ll)
Electrical,
valves,
pumps, oilfield
tools,
aerospace
landing gears,
robotic
welding, mold
making [3]
" "Cold-
rolled104 110 5
B81
(Rockw
ell)
"
Free-cutting
brass
Cu 62.0,
Zn 35.5,
Pb 2.5
Cold-
drawn44 70 18
B80
(Rockw
ell)
Screws, nuts,
gears, keys
Nickel
silver (ASTM
B112)
Cu 65.0,
Zn 17.0, Ni
18.0
Anneal
ed25 58 40 70 Hardware
" "Cold-
rolled70 85 4 170 "
Nickel silver
(ASTM B149)
Cu 76.5, Ni
12.5, Pb
9.0, Sn 2.0
Cast 18 35 15 55
Easy to
machine;
ornaments,
plumbing
Cupronickel (A
STM B111,
B171)
Cu 88.35,
Ni 10.0, Fe
1.25, Mn
0.4
Anneal
ed22 44 45 –
Condensor,
salt-water
pipes
" "
Cold-
drawn
tube
57 60 15 – "
CupronickelCu 70.0, Ni
30.0
Wrough
t– – – –
Heat-
exchange
equipment,
valves
Ounce
metal[4] Copper
Alloy C83600
(also known as
"Red brass" or
Cu 85.0,
Zn 5.0, Pb
5.0, Sn 5.0
Cast 17 37 25 60 —
"composition
metal") (ASTM
B62)
Gunmetal (kno
wn as "red
brass" in US)
Varies Cu
80-90%,
Zn <5%,
Sn ~10%,
+other
elements@
<1%
Mechanical properties of Copper Development Association (CDA) copper alloys[5]
FamilyCD
A
Tensile
strength
[ksi]
Yield
strength
[ksi] Elongation
(typ.) [%]
Hardness
[Brinell
10 mm-
500 kg]
Machinability
[YB = 100]
Min. Typ. Min. Typ.
Red brass
833 32 10 35 35 35
836 30 37 14 17 30 50–65 84
838 29 35 12 16 25 50–60 90
Semi-red brass
844 29 34 13 15 26 50–60 90
848 25 36 12 14 30 50–60 90
Manganese bronze 862 90 95 45 48 20 170–195† 30
863 110 119 60 83 18 225† 8
865 65 71 25 28 30 130† 26
Tin bronze
903 40 45 18 21 30 60–75 30
905 40 45 18 22 25 75 30
907 35 44 18 22 20 80 20
Leaded tin bronze
922 34 40 16 20 30 60–72 42
923 36 40 16 20 25 60–75 42
926 40 44 18 20 30 65–80 40
927 35 42 21 20 77 45
High-leaded tin
bronze
932 30 35 14 18 20 60–70 70
934 25 32 16 20 55–65 70
935 25 32 12 16 30 55–65 70
936 33 30 16 21 15 79-83 80
937 25 35 12 18 20 55–70 80
938 25 30 14 16 18 50–60 80
943 21 27 13 10 42–55 80
Aluminium bronze
952 65 80 25 27 35 110–140† 50
953 65 75 25 27 25 140† 55
954 75 85 30 35 18 140–170† 60
955 90 100 40 44 12 180–200† 50
958 85 95 35 38 25 150-170† 50
Silicon bronze 878 80 83 30 37 29 115 40
† Brinell scale with 3000 kg load
Comparison of copper alloy standards[5]
Family CDA ASTM SAESAE
supersededFederal Military
Red brass 833
836 B145-
836
836 40 QQ-C-390
(B5)
C-2229 Gr2
838B145-
838838
QQ-C-390
(B4)
Semi-red brass
844B145-
844
QQ-C-390
(B2)
848B145-
848
QQ-C-390
(B1)
Manganese bronze
862B147-
862862 430A
QQ-C-390
(C4)C-2229 Gr9
863B147-
863863 430B
QQ-C-390
(C7)C-2229 Gr8
865B147-
865865 43
QQ-C-390
(C3)C-2229 Gr7
Tin bronze
903B143-
903903 620
QQ-C-390
(D5)C-2229 Gr1
905B143-
905905 62
QQ-C-390
(D6)
907 907 65
Leaded tin bronze922
B143-
922922 622
QQ-C-390
(D4)B-16541
923 B143-
923
923 621 QQ-C-390
(D3)
C-15345
Gr10
926 926
927 927 63
High-leaded tin
bronze
932B144-
932932 660
QQ-C-390
(E7)
C-15345
Gr12
934QQ-C-390
(E8)
C-22229
Gr3
935B144-
935935 66
QQ-C-390
(E9)
937B144-
937937 64
QQ-C-390
(E10)
938B144-
938938 67
QQ-C-390
(E6)
943B144-
943943
QQ-C-390
(E1)
Aluminium bronze952
B148-
952952 68A
QQ-C-390
(G6)
C-22229
Gr5
953B148-
953953 68B
QQ-C-390
(G7)
954 B148-
954
954 QQ-C-390
(G5)
C-15345
Gr13
955B148-
955955
QQ-C-390
(G3)
C-22229
Gr8
958QQ-C-390
(G8)
Silicon bronze 878 B30 878
The following table outlines the chemical composition of various grades of copper alloys.
Chemical composition of copper alloys[5][6]
FamilyCD
AAMS UNS
Cu
[%]
Sn
[%]
Pb
[%]
Zn
[%]
Ni
[%]
Fe
[%]
Al
[%]
Other
[%]
Red brass
833 C83300 93 1.5 1.5 4
C83400[7] 90 10
836 4855B C83600 85 5 5 5
838 C83800 83 4 6 7
Semi-red
brass
844 C84400 81 3 7 9
845 C84500 78 3 7 12
848 C84800 76 3 6 15
Manganese C86100[8] 67 0.5 21 3 5 Mn 4
bronze
862† C86200 64 26 3 4 Mn 3
863† 4862B C86300 63 25 3 6 Mn 3
865 4860A C86500 58 0.5 39.5 1 1Mn
0.25
Tin bronze
903 C90300 88 8 4
905 4845D C90500 88 100.3
max2
907 C90700 89 110.5
max
0.5
max
Leaded tin
bronze
922 C92200 88 6 1.5 4.5
923 C92300 87 81
max4
926 4846A C92600 87 10 1 2
927 C92700 88 10 20.7
max
High-leaded
tin bronze
932 C93200 83 7 7 3
934 C93400 84 8 8 0.7
max
935 C93500 85 5 9 10.5
max
937 4842A C93700 80 10 100.7
max
938 C93800 78 7 150.75
max
943 4840A C94300 70 5 250.7
max
Aluminium
bronze
952 C95200 88 3 9
953 C95200 89 1 10
9544870B
4872BC95400 85 4 11
C95410[9] 85 4 11 Ni 2
955 C95500 81 4 4 11
C95600[10] 91 7 Si 2
C95700[11] 75 2 3 8 Mn 12
958 C95800 81 5 4 9 Mn 1
Silicon bronze
C87200[12] 89 Si 4
C87400[13] 83 14 Si 3
C87500[14] 82 14 Si 4
C87600[15] 90 5.5 Si 4.5
878 C87800[16] 80 14 Si 4
C87900[17] 65 34 Si 1
† Chemical composition may vary to yield mechanical properties
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Copper Alloys Brass, C260
Related Metals: C26000Cartridge Brass, C260C260
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Specifications: ASTM B129ASTM B134ASTM B135ASTM B19ASTM B36ASTM B569ASTM B587MIL C-10375MIL S-22499MIL T-20219SAE J461SAE J463UNS C26000
Chemistry Data
Copper 68.5 - 71.5
Iron 0.05 max
Lead 0.07 max
Remainder Each Zn
General Information
Principal Design Features
Brasses (Copper-Zinc Alloy), Cartridge Brass, 70%. C26000 has the highest ductility in the yellow brass series. Easily machined but is more often cold formed.
Applications
Primarily used for hot or cold-formed products.
Machinability
The machinability rating of this alloy is not given. (Where Alloy 360 FC Brass is 100).
Welding
Soldering is rated as "excellent", brazing is rated as "excellent", oxyacetylene welding is rated as "good", gas shielded arc welding is rated as "fair", coated metal arc welding is "not recommended", spot welding is rated as "good", seam welding is "not recommended" and butt welding is rated as "good".
Pengelasan penyolderan ini dinilai sebagai ' baik ', mematri ini dinilai sebagai ' baik ', oxyacetylene pengelasan ini dinilai sebagai ' baik ', gas terlindung arc pengelasan ini dinilai sebagai ' adil ', dilapisi logam arc pengelasan adalah ' tidak dianjurkan ', spot welding ini dinilai sebagai ' baik ', jahitan pengelasan adalah ' tidak dianjurkan ' dan pantat pengelasan ini dinilai sebagai ' baik '.
Forging
The hot forgeability rating of this alloy is not given. (Forging Brass=100). The recommended hot working temperature for this alloy is between 1350 and 1550 F.
Hot Working
This alloy's capacity for being hot formed is rated as "fair".
Cold Working
The capacity for cold working this alloy is rated as "excellent".
Annealing
The annealing temperature for this alloy is between 800 and 1400 F.
Physical Data
Density (lb / cu. in.) 0.308
Electrical Resistivity (microhm-cm (at 68 Deg F))
37
Melting Point (Deg F) 1680
Modulus of Elasticity Tension
16000
Brass property
Properties
Microstructure of rolled and annealed brass (400X magnification)
The malleability and acoustic properties of brass have made it the metal of choice
for musical instruments such as the trombone, tuba, trumpet, cornet,baritone
horn, euphonium, tenor horn, and French horn which are collectively known as the brass
within an orchestra. Even though the saxophone is classified as a woodwind
instrument and the harmonica is a free reed aerophone, both are also often made from
brass. In organ pipes of the reed family, brass strips (called tongues) are used as the
reeds, which beat against the shallot (or beat "through" the shallot in the case of a "free"
reed). Although not part of the brass section, snare drums are also sometimes made of
brass.
Brass has higher malleability than bronze or zinc. The relatively low melting point of brass
(900 to 940 °C, 1652 to 1724 °F, depending on composition) and its flow characteristics
make it a relatively easy material to cast. By varying the proportions of copper and zinc,
the properties of the brass can be changed, allowing hard and soft brasses. The density
of brass is approximately .303 lb/cubic inch, 8.4 to 8.73 grams per cubic centimetre.[5]
Today almost 90% of all brass alloys are recycled.[6] Because brass is not ferromagnetic,
it can be separated from ferrous scrap by passing the scrap near a powerful magnet.
Brass scrap is collected and transported to the foundry where it is melted and recast
into billets. Billets are heated and extruded into the desired form and size.
Aluminium makes brass stronger and more corrosion resistant. Aluminium also causes a
highly beneficial hard layer of aluminium oxide (Al2O3) to be formed on the surface that is
thin, transparent and self-healing. Tin has a similar effect and finds its use especially
in sea water applications (naval brasses). Combinations of iron, aluminium, silicon and
manganese make brass wear and tear resistant.[7]
Copper properties
Physical Properties Metric
Density 7.60 - 8.75 g/cc
Mechanical Properties MetricHardness, Rockwell B 25.0 - 133Hardness, Rockwell F 54.0 - 100Hardness, HR30T 8.00 - 240Tensile Strength, Ultimate 159 - 896 MPaTensile Strength, Yield 69.0 - 683 MPaElongation at Break 3.00 - 68.0 %Reduction of Area 40.0 - 60.0 %Modulus of Elasticity 97.0 - 115 GPaPoissons Ratio 0.280 - 0.375Fatigue Strength 22.0 - 360 MPaMachinability 30.0 - 106 %Shear Modulus 35.0 - 44.0 GPaShear Strength 205 - 415 MPaIzod Impact 43.0 - 45.0 JCharpy Impact 43.0 - 69.0 J
Electrical Properties MetricElectrical Resistivity 0.00000470 - 0.0000280 ohm-cm 0.00000470Magnetic Susceptibility -1.00e-6
Thermal Properties MetricCTE, linear 18.7 - 26.0 µm/m-°CSpecific Heat Capacity 0.375 - 0.380 J/g-°CThermal Conductivity 26.0 - 159 W/m-K 180Melting Point 820 - 1030 °CSolidus 820 - 990 °CLiquidus 890 - 1030 °C
Processing Properties MetricProcessing Temperature 260 °CAnnealing Temperature 425 - 750 °CHot-Working Temperature 625 - 900 °CRecrystallization Temperature 10.0 - 400 °C
Component Elements Properties MetricAntimony, Sb 0.0200 - 0.100 %Copper, Cu 55.0 - 86.0 %Iron, Fe 0.0500 - 2.10 %Lead, Pb 0.0500 - 5.00 %Other 0.150 - 0.500 %Phosphorous, P 0.0200 - 0.150 %Silicon, Si 3.50 - 4.50 %Tin, Sn 0.250 - 5.00 %Zinc, Zn 5.00 - 43.5 %
BRASS
Brass is an alloy of copper and zinc; the proportions of zinc and copper can be varied to
create a range of brasses with varying properties.[1]
By comparison, bronze is principally an alloy of copper and tin.[2] Bronze does not
necessarily contain tin, and a variety of alloys of copper, including alloys
with arsenic, phosphorus, aluminium, manganese, and silicon, are commonly termed
"bronze". The term is applied to a variety of brasses and the distinction is largely
historical,[3] both terms having a common antecedent in the term latten.
Brass is a substitutional alloy. It is used for decoration for its bright gold-like appearance;
for applications where low friction is required such as locks, gears,
bearings, doorknobs, ammunition casings and valves; for plumbing and electrical
applications; and extensively in musical instruments such as horns and bells for its
acoustic properties. It is also used in zippers. Brass is often used in situations where it is
important that sparks not be struck, as in fittings and tools around explosive gases.[4]
Kuningan merupakan paduan tembaga dan seng; proporsi seng dan tembaga dapat bervariasi
untuk menciptakan berbagai brasses dengan berbagai sifat. 1 dengan perbandingan, perunggu ini
terutama aloi tembaga dan timah. 2 perunggu tidak selalu mengandung timah, dan berbagai
paduan dari tembaga, termasuk paduan dengan arsenik, fosfor, aluminium, mangan, dan silikon,
yang umumnya disebut ' perunggu '. Istilah ini digunakan untuk berbagai brasses dan perbedaan
sejarah, sebagian besar 3 memiliki kedua hal yg umum dalam jangka latten. Kuningan adalah
sebuah substitutional paduan. Hal ini digunakan untuk dekorasi untuk yang terang gold-like
penampilan; untuk aplikasi di mana rendah gesekan diperlukan seperti kunci gigi, bantalan,
doorknobs, amunisi casing dan katup; untuk pipa dan aplikasi listrik; dan secara luas di alat musik
seperti tanduk dan lonceng untuk yang acoustic properti. Hal ini juga digunakan dalam zippers.
Kuningan ini sering digunakan dalam situasi di mana hal ini penting bahwa percikan api tidak akan