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Comprehensive Castor Oil Derivatives Report

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Comprehensive Castor Oil Derivatives Report

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What is the objective of the report?

The goal of the Comprehensive Castor Oil Derivatives Report is to present a comprehensive

status report on the current and future potential of the castor oil derivatives industry. Written

by professionals who have been observing the industry for many years and who interact

continuously with all the key industry players, the report will assist you to clearly understand

the potential and prospect of the industry.

Answers the most important questions that entrepreneurs, investors and businesses

have regarding castor oil derivatives

Provides critical inputs on the key derivatives and their market potential

Provides useful details on the production methods of the various derivatives.

Lists details and profiles of the prominent companies making key castor oil derivatives

Developed by CastorOil.in, the definitive and most referenced resource for the global

castor oil industry

Who will benefit from this report?

This report will be invaluable to entrepreneurs and industry professionals venturing into

castor oil derivatives and keen on understanding the market structure and potential before

they make their investment decisions.

What are the key questions answered in the report?

This insightful report provides precise inputs for the following questions

What are the various derivatives of castor oil and their applications?

What is the current and future market potential for castor oil derivatives?

Which of the castor oil derivatives are likely to have significant growth in the short

term?

Which are the emerging castor oil derivatives to look out for the medium term?

What is the brief manufacturing process of key castor oil grades and derivatives?

Comprehensive Castor Oil Derivatives Report

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What are the main end use markets for castor oil derivatives and what are the

characteristics of these markets?

Which are the prominent companies worldwide for castor oil derivatives?

What is the status of castor oil use in high growth markets such as biopolymers and

cosmetics?

What are the key growth challenges faced by prominent castor oil derivatives?

What are the prominent ventures and partnerships that happened in recent years?

What is exclusive about this report?

This is the only comprehensive report available for castor oil derivatives anywhere in the

world.

Using its unique position as a boutique research firm in castor oil, and also given the fact that

we run the web’s most popular web portal for castor oil ( www.castoroil.in), the CastorOil.in

team has been interacting with a number of castor oil industry participants for many years

now. This list includes manufacturers and processors, castor bean cultivators, castor oil and

castor oil derivative chemicals users, economists, machinery suppliers and trade bodies. Using

this collective intelligence and inputs gained over these years, CastorOil.in has prepared this

comprehensive report.

Comprehensive Castor Oil Derivatives Report

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List of Contents

Chapter 1 – Castor Oil Derivatives – Introduction & Production

1.1. Production Process for Key Castor Oil Grades and Derivatives

1.1.1. Castor Oil Grades and Derivatives Production - Basics

1.1.2. Castor Oil Derivatives Production – Processes, Reactions & Stages

1.1.3. Properties - Chemical, Physical Properties and Specifications of Castor Oil Grades and

Derivatives

Chapter 2 – Castor Oil Derivatives Market

Insights on current and future demand/supply estimates, consumption and import/export of various

castor oil derivatives

2.1 The Global Castor Oil Derivatives Market

2.1.1 Overall Growth Trends in the Global Castor Oil Derivatives Market

2.1.2 Growth Trends in Terms of:

2.1.2.1 Geography

2.1.2.2 Derivative

2.1.2.3 End Uses

2.2 Supply and Demand of Castor Oil Derivatives

2.2.1 Castor Oil Derivatives Supply Trends

2.2.2 Castor Oil Derivatives Demand Trends

2.2.3 Short & Medium Term Demand-Supply Analysis in Castor Oil Derivatives

2.3 Indian Castor Oil Derivatives Industry

India being a near-monopoly for the supply of castor oil, we have a special section dedicated to the

Indian castor oil industry in the context of castor oil derivatives.

2.3.1 Indian Castor Oil Derivatives Production – Historical & Current Scenario

2.3.2 Indian Castor Oil Derivatives Exports – Historical & Current Scenario

2.3.3 Indian Castor Oil Derivatives Imports

2.3.4 Emerging Trends in India for Production of New Castor Oil Derivatives

Chapter 3 – End Uses for Castor Oil Derivatives

3.1 Current End Uses for Castor Oil and Derivatives

3.1.1 End Uses - By Castor Oil Grade / Derivative

3.1.2 Castor Oil & Castor Oil Derivatives Uses - By Industry

3.2 Future Possible End Uses and End User Industries for Castor Oil and Derivatives

3.2.1 Biopolymers and Castor Oil

3.2.2 Cosmetics and Castor Oil

3.2.3 Other Emerging End Uses

Comprehensive Castor Oil Derivatives Report

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Chapter 4 – Emerging Trends in Applications, Partnerships & Research

4.1 Emerging Trends in End Uses

4.2 Business Partnerships in Castor Oil Derivatives

4.3 Past & Emerging Research in Castor Oil Derivatives

Chapter 5 – Prominent Castor Oil Derivatives Producers

5.1 Producers in Asia

5.2 Producers in Europe

5.3 Producers in North America

5.4 Other Producers and Suppliers

Comprehensive Castor Oil Derivatives Report

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Chapter Contents

1.1 Production Process for Key Castor Oil Grades and Derivatives

1.1.1 Castor Oil Grades and Derivatives Production - Basics

1.1.2 Castor Oil Derivatives Production – Processes, Reactions & Stages

1.1.3 Properties - Chemical, Physical Properties and Specifications of Castor Oil Grades

and Derivatives

======================SAMPLE CONTENT====================

1. Castor Oil Derivatives – Introduction & Production

Comprehensive Castor Oil Derivatives Report

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Castor Oil

Main Grades

Commercial, FSG, BSS

First Pressed Degummed

Grade Castor Oil

Refined Castor Oil – Extra Pale

Grade

Castor Oil Pharmaceutical

Grade

Blown Castor Oil

Urethane Grade

Pale Pressed Grade

Generation I Derivatives

Dehydrated Castor Oil

EthoxylatedCastor Oil

Hydrogenated Castor Oil

12-Hydroxy Stearic Acid (12-

H.S.A)

Sulfonated Castor Oil – Turkey Red

Oil

Generation II Derivatives

Sebacic acid

Heptaldehyde

Undecylenic Acid

Polyols

Ricinoleic Acid

Other Dimer Acids

UndecylenicAldehydes

2-Heptanol

2-Octanol

Generation III Derivatives

Zinc Ricinoleate

Zinc Undecylenate

Methyl 12-HSA

Methyl Ricinoleate

Methyl Undecylenate

Calcium Umndecylenate

Others?

Comprehensive Castor Oil Derivatives Report

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1.1.1 Key Derivatives of Castor Oil, Starting Material & Methods of

Production

Product Name Starting Product Method of Production Commercial Castor Oil Castor Seed Crushing & Expelling

First pressed Degummed Grade Castor Oil

Commercial Castor Oil Degumming

Refined Castor Oil (F.S.G./B.S.S.) Commercial Castor Oil Bleaching

Refined Castor Oil (Extra Pale Grade)

Commercial Castor Oil Bleaching

Refined Castor Oil (Pale Pressed Grade)

Commercial Castor Oil Neutralization and Bleaching

Neutralized Castor Oil Commercial Castor Oil Neutralization and Bleaching

Refined Castor Oil (DAB-10) Commercial Castor Oil Neutralization and Bleaching

Castor Oil Pharmaceutical (I.P/B.P./U.S.P.)

Commercial Castor Oil Neutralization

Turkey Red Oil Commercial Castor Oil Sulphonation and Neutralization

Blown Castor Oil (10 to 250 Poise)

Refined Castor Oil (F.S.G./B.S.S.) Oxidation

Ricinoleic Acid Refined Castor Oil (F.S.G./B.S.S.) Saponification and Acidification

Methyl Ricinoleate Refined Castor Oil (F.S.G./B.S.S.) Esterification

Hydrogenated Castor Oil (Flakes/Powder/Granules)

Refined Castor Oil (F.S.G./B.S.S.) Hydrogenation

12-Hydroxy Stearic Acid (12-H.S.A.) (Flakes/Powder/Granules)

Hydrogenated Castor Oil Liquid Saponification and Acidification

Methyl-12-Hydroxy Stearate (Flakes)

Methyl Ricinoleate Hydrogenation

Urethane Modified Castor Oil (UMCO)

Refined Castor Oil (F.S.G./B.S.S.) Urethane Reaction

Glyceryl-Tri-(12-Acetyl Ricinoleate)

Refined Castor Oil (F.S.G./B.S.S.) Acetylation

Dehydrated Castor Oil (Commercial)

Commercial Castor Oil Dehydration

Glycerin Spent Glycerin Lye Treatment, Evaporation and Distillation

Comprehensive Castor Oil Derivatives Report

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Generic Chemical Reactions of Castor Oil for Manufacture of Various

Grades & Derivatives

Reaction Type Nature of Reaction Added Reactants Type of Products

Ester Linkage Hydrolysis Acid, enzyme or Twitchell reagent catalyst

Fatty acids, glycerol

Esterification Monohydric alcohols Esters

Alcoholysis Glycerol, glycols, pentaerythritol, and other compounds

Mono- and diglycerides, monoglycols, etc.

Saponification Alkalies, alkalies plus metallic salts

Soluble soaps, insoluble soaps

Reduction Na reduction Alcohols

Amidation Alkyl amines, alkanolamines, and other compounds

Amine salts, amides

Double Bond Oxidation, polymerization

Heat, oxygen, crosslink agent Polymerized oils

Hydrogenation Hydrogen (moderate pressure) Hydroxystearates

Epoxidation Hydrogen peroxide Epoxidized oils

Halogenation Cl2, Br2, I2 Halogenated oils

Addition reactions S, maleic acid Polymerized oils, factice

Sulphonation H2SO4 Sulphonated oils

Hydroxyl Group Dehydration, hydrolysis, distillation

Catalyst (plus heat) Dehydrated castor oil, octadecadienoic acid

Caustic fusion NaOH Sebacic acid, capryl alcohol

Pyrolysis High heat Undecylenic acid, heptaldehyde

Halogenation PCl5, POCl3 Halogenated castor oils

Alkoxylation Ethylene and/or propylene oxide

Alkoxylated castor oils

Esterification Acetic-, phosphoric-, maleic-, phthalic anhydrides

Alkyl and alkylaryl esters, phosphate esters

Urethane reactions Isocyanates Urethane polymers

Sulphation H2SO4 Sulphated castor oil (Turkey red oil)

Comprehensive Castor Oil Derivatives Report

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1.1.2 Reactions for Sebacic Acid Production

1.1.3 Castor Oil Derivatives Properties

Ricinoleic Acid

Ricinoleic Acid (12-hydroxy-9-octadecenoic acid) is obtained by the hydrolysis of Castor Oil. It is a light

coloured liquid with a ricinoleic content of approximately 90%. Primary uses include, coatings, plastics,

inks and cosmetics

Biochemical studies have revealed that ricinoleic acid is produced in castor by the direct hydroxylation

of the common fatty acid, oleic acid (18:1). The hydroxylation reaction is catalysed by a single, highly

efficient enzyme, the fatty acid hydroxylase.

IUPAC Name– (E)-12-hydroxyoctadec-9-enoic acid

Synonyms– 12-hydroxy-(cis)-9-octadecenoic acid

Alkali Fusion @ 250 degrees C

Pyrolysis

Alkali Fusion @ 200 deg C

CH3(CH2)5CH(OH)CH2CH:CH(CH2)7COOH

Ricinoleic Acid

CH3(CH2)5CHO + CH2=CH(CH2)8COOH

Heptaldehyde Undecanoic Acid

CH3(CH2)5COCH3 + CH2(OH)(CH2)8COOH

2 Octanone 10-Hydroxydecanoic Acid

CH3(CH2)5CH(OH)CH3 ) + COOH(CH2)8COOH + H2

2-Octanol Sebacic Acid

Comprehensive Castor Oil Derivatives Report

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CAS Number 5323-95-5

Chemical Formula C18H34O3

Mol Wt. 298.46

Physical State Viscous yellow liquid

Melting Point 5.5oC

Boiling Point 245oC

Specific Gravity 0.94

Solubility in Water Insoluble

Vapour Density 10.3

Flash Point 224oC

Stability Stable under ordinary conditions

Appearance Viscous yellow liquid

Acid Value 175 min

Hydroxyl Value 150 min

Iodine Value 80-91

Saponification Value 180 min

Colour, Gardner 8 max

Comprehensive Castor Oil Derivatives Report

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Chapter Contents

2.1 The Global Castor Oil Derivatives Market

2.1.1 Overall Growth Trends in the Global Castor Oil Derivatives Market

2.1.2 Growth Trends in Terms of:

2.1.2.1 Geography

2.1.2.2 Derivative

2.1.2.3 End Uses

2.2 Supply and Demand of Castor Oil Derivatives

2.2.1 Castor Oil Derivatives Supply Trends

2.2.2 Castor Oil Derivatives Demand Trends

2.2.3 Short & Medium Term Demand-Supply Analysis in Castor Oil Derivatives

2.3 Indian Castor Oil Derivatives Industry

India being a near-monopoly for the supply of castor oil, we have a special section dedicated

to the Indian castor oil industry in the context of castor oil derivatives.

2.3.1 Indian Castor Oil Derivatives Production – Historical & Current Scenario

2.3.2 Indian Castor Oil Derivatives Exports – Historical & Current Scenario

2.3.3 Indian Castor Oil Derivatives Imports

2.3.4 Emerging Trends in India for Production of New Castor Oil Derivatives

======================SAMPLE CONTENT====================

2.1.2.3 Growth of Key End-user Industry Segments for Castor Oil Derivatives

Industry Global Market Size % Growth (CAGR)

Bioplastics 4.2 million tons (2016) –

75% durable bio-plastics

10% (2016-2020)

Biolubricants $1.9 billion (2015) 5.3% (2016-22)

Organic Personal Care

Products

$10.2 billion (2015) 13% (2016-21)

Organic Surfactants 0.36 million tons (2015) 5% (2015-23)

Green coatings $61 billion (2012), est

$86 B (2018)

6% (2012-18)

2. Castor Oil Derivatives Market Insights on current and future demand/supply estimates, consumption and import/export of various castor oil derivatives

Comprehensive Castor Oil Derivatives Report

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2.2.3 Current Demand-supply Estimates for the Various Grades of Castor Oil and

Derivatives

Product Demand Current Demand Supply Gap

Castor Seed High Medium

Castor Meal / Castor Residue High Medium

Hydrogenated Castor Oil (HCO) High Low

12 Hydroxy Stearic Acid (12 HSA) Medium Medium

Methyl 12 HSA (Hydroxy Stearate Acid) Low-Medium Medium

Blown Castor Oil Medium Medium

Sulfated/Sulfonated Castor Oil, Turkey Red Oil Medium Medium

COLM (Urethane Grade) Medium-High Medium-High

Commercial Grade Castor Oil Very High Medium

BP Grade Castor Oil Medium Medium

Deodorized/Deodourised Castor Oil Medium Medium

European Pharmacoepia Grade Castor Oil Medium Medium

Extra Pale Grade Castor Oil Low Medium

Pale Pressed Grade (PPG) Grade Castor Oil Medium Medium

First Pressed Degummed Castor Oil Medium-High Medium

First Special Grade (FSG) Castor Oil Very High Medium

United States Pharmacopia (USP) Castor Oil High Medium

Dehydrated Castor Oil (DCO) Medium-High Medium

Ethoxylated Castor Oil Medium High

C 3 Derivatives of Castor Oil

Glycerin Very High Low

C-7 Derivatives of Castor Oil

Heptanoic Acid Low Medium

Heptaldehyde Low Medium

Heptyl Alcohol (Heptanol) Low Medium

C 11 Derivatives of Castor Oil

Undecylenic Acid High1 Low-Medium1

Undecanoic Acid Low NA

Undecylenic Aldehyde Low NA

Undecylenic Alcohol Low NA

Calcium Undecylenate Low NA

Zinc Undecylenate Low NA

Allyl Undecylenate Low NA

Sodium Undecylenate Low NA

Methyl Undecylenate Low NA

Ethyl Undecylenate Low NA

C 18 Derivatives of Castor Oil

Esterols Not known NA

Ricinoleic Acid Medium Medium

Methyl Ricinoleate Low-Medium Medium

Sebacic Acid Very High2 Low-Medium

2-Octanol Medium Low-Medium

Comprehensive Castor Oil Derivatives Report

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1 A very large percentage of Undecylenic Acid is used by Arkema to manufacture Nylon 11

2 Large percentage of Sebacic acid is used for the manufacture of Nylon 6,10

Notations for Demand

Very High: 50,000 T and above per year

High: 30,000 –50,000T per year

Medium-High: 15,000-30,000 T per year

Medium: 5,000-15,000 T per year

Low-Medium: 1,000-5,000 T per year

Low: Less than 1,000 T per year

Notations for Demand-Supply Gap

Medium: There exists some demand over and above supply, but there has not been a significant

amount of demand that has gone unmet

Medium-High: There have been some instances where a significant demand has gone unmet

High: There have been many instances where a significant demand in the market has gone unmet

Low: There have been very few instances when a significant demand has gone unmet

NA: denotes that info on demand supply gap is not available owing to the negligible demand volumes

Comprehensive Castor Oil Derivatives Report

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Chapter Contents

3.1 Current End Uses for Castor Oil and Derivatives

3.1.1 End Uses - By Castor Oil Grade / Derivative

3.1.2 Castor Oil & Castor Oil Derivatives Uses - By Industry

3.2 Future Possible End Uses and End User Industries for Castor Oil and Derivatives

3.2.1 Biopolymers and Castor Oil

3.2.2 Cosmetics and Castor Oil

3.2.3 Other Emerging End Uses

======================SAMPLE CONTENT====================

3.1.1.6 End Uses of Undecylenic Acid

Undecylenic Acid

Undecylenic acid has a long history as antifungal drug. It is used to treat some types of fungus

infections.

Undecylenic acid is a natural fungicide and is FDA approved in over-the-counter medications for skin

disorders. It is the active ingredient in medications for skin infections, and relieves itching, burning,

and irritation. For example, it is used against fungal skin infections such as Athlete's foot, Ringworm,

and Candida albicans. It is also used in the treatment of psoriasis.

Most organic fatty acids are fungicidal and have been used for centuries as antimicrobial agents,

originally in the manufacture of soaps. In the last 50 years, however, they have found use both in vitro

as yeast and mold inhibitors in food stuffs, and as topical and systemic antifungals. Undecylenic acid

is an economical antifungal agent and is the active ingredient in many topical over-the-counter

antifungal preparations. Undecylenic acid has been shown to be approximately six times more

effective as an antifungal agent than caprylic acid, and is effective in maintaining a healthy balance of

intestinal and vaginal flora.

When undecylenic acid is treated with hydrogen bromide in a non-polar solvent in the presence of

peroxide, reverse Markownikoff addition occurs and the main product is x-bromoundecanoic acid. The

product is then treated with ammonia to give x-aminoundecanoic acid, which is a crystalline solid.

Aminoundecanoic acid is the starting material for nylon-11.

Related Chemical Reactions

(CH2=CH(CH2)8COOH) Undecylenic Acid HBr BrCH2.CH2(CH2)8COOH

BrCH2.CH2(CH2)8COOH NH3H2N(CH2)10COOH (w-Aminoundecanoic Acid)

The self-condensation of Castor oil derivative, 11-aminoundecanoic acid yields nylon-11 or

Polyundecanamide. Molten nylon-11 polymer is thermostable stable and can tolerate elevated

temperatures of 215 C. It has an increased half-life and exhibits a minimal susceptibility to oxidative

damage when stored under proper inert atmosphere. The properties of stiffness, specific gravity and

3. End Uses for Castor Oil Derivatives

Comprehensive Castor Oil Derivatives Report

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high initial modulus in nylon 11 makes its way robust to find applications in brush bristles, textile

industries and automobile tire cord market respectively. In addition, the plant based polymer has

appreciable low moisture absorbing and electrical insulation activities.

As nylon 11 has melting point of 189°C, it needs attention when subjected to high temperature

treatments in the general textile units.

Specific applications of undecylenic acid:

An active ingredient in many topical over-the-counter antifungal preparations like the tinea

pedis, diaper rash, and effective against denture stomatitis and herpes. Several studies have

demonstrated that undecylenic acid is 4-5 times powerful an antifungal agent as caprylic acid

in the same dosage.

Undecylenic acid and its derivatives have a bi-functionality: Acts as a surfactant as well as

possess natural bio-resistance properties.

Biocide in soaps and deodorants

Surfactant in hair lotions.

Starting material for Nylon-11

Malodorous/foul smelling paper mill effluents can also be deodorized by treating them with

an effective deodorizing amount – such as an alkyl or polyoxyalkylene ester of undecylenic

acid, for example methyl undecylenate or polyoxyethylene undecylenate.

Malodorous animal feeds can be deodorized by treating them with an effective foodstuff

deodorizing amount of polyoxyalkylene ester of undecylenic acid.

There are instances where malodorous liquid animal manures & sewage sludges are

deodorized by treating the sample with a polyoxyalkylene ester of undecylenic acid.

Biochemistry and Pharmacokinetics for Undecylenic Acid

Wyss et al demonstrated more than 50 years ago, that the greater the number of carbon atoms in the

fatty acid chain, the greater the fungicidal activity, up to the point exceeding eleven carbon atoms,

where solubility becomes the limiting factor. Although the fungistatic and fungicidal effects of fatty

acids have been well documented, they can be somewhat irritating tomucous membranes in certain

people, and commonly used fatty acids such as caprylic and undecylenic acids have ano bjectionable

taste and odor. Consequently, the calcium, magnesium, and sodium salts of these fatty acids have

been offeredas reasonable alternatives. Undecylenate salts have been shown to possess as much as

four times the fungicidal effect of undecylenic acid, and may be over 30 times more effective than

caprylic acid. Unfortunately, the antifungal effects of these fatty acid salts are more sensitive to pH

than the free fatty acids. When tested over a pH range from 4.5 to 6.0, the antifungal activities of both

undecylenic acid and calcium undecylenate are quite pronounced; the minimal inhibitory

concentration of calcium undecylenate against Candida albicans is 200 ppm at pH 6.0. However, above

pH 6.0, the calcium salt is less active than the free acid, perhaps due to the suppression of ionization

of the salt at higher pH levels.

Mechanism of Action

At least one of the mechanisms underlying in its anti-fungal effect is its inhibition of morphogenesis

of Candida albicans. In a study on denture liners, undecylenic acid in the liners was found to inhibit

conversion of yeast to the hyphal form. Hyphae were associated with an active infection. The authors

speculated on possible mechanisms including interference with fatty acid biosynthesis, which can

inhibit germ tube (hyphae) formation. Medium-chain fatty acids have also been shown to disrupt the

pH of the cell cytoplasm by being proton carriers.

Comprehensive Castor Oil Derivatives Report

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Undecylenic Acid for Specific Clinical Applications

Vaginal/Gastrointestinal Candidiasis - Undecylenic acid has been shown to be effective in preventing

fungal overgrowth associated with vaginal and gastrointestinal candidiasis via its fungicidal activity.

Thrush - Since undecylenic acid acts systemically, oral administration can inhibit or even prevent oral

candidiasis, or thrush.

Dermatomycoses- Undecylenic acid is the active ingredient in Desinex cream and a number of other

over-the-counter antifungals. It acts as an anti-fungal agent against organisms such as Candida

albicans, Trichophyton species, Epidermophyton inguinale, and Microsporum audouini.

Herpes Simplex Infection - Undecylenic acid has been shown to have antibacterial and antiviral

properties in vitro and is effective topically against the herpes simplex virus in both animals and

humans.

Denture Stomatitis - Candida albicans is a major cause of denture stomatitis, an inflammation of the

tissues underlying dentures. The organism exists in two cellular morphologies -- the round yeast form

found in asymptomatic carrier states and the branching hyphal form found in active infections.

Resilient liners are frequently used to treat denture stomatitis, and it has been demonstrated that

liners containing undecylenic acid completely inhibited the conversion of the yeast form of Candida

albicans to the hyphal form, thereby inhibiting proliferation of the yeast.

Undecylenic Acid Minor Derivatives (Source: Arkema Inc)

Undecylenic Acid - Ammonium Derivatives

o Undecylenamidopropyl betaine: C11 betaine.

A very mild, active surfactant with a dual water and oil solubility.

Especially suited to use in anti-dandruff shampoos.

A good viscosity regulator.

o Undecylenic Acid - Ethanolamide Derivatives

Ethanolamide derivatives are both oil- and water-soluble and hence can easily be formulated:

High water solubility and high surfactant properties for haircare uses.

o Undecylenic Acid - Undecylenamide MEA

Good fungicidal and bactericidal properties that can be added to:

Shampoos and other products to provide foam stabilization, viscosity

control...

Soaps to provide emolliency, firmness and fungicidal properties

Pharmaceutical creams and oils where fungicidal properties are important

Bubble bath products and shampoos, especially anti-dandruff shampoos

Shaving creams and after-shave lotions.

o Undecylenic Acid - Undecylenamide DEA

Same applications as for undecylenamide MEA, and additionally, any use in which increased

water solubility is required

Thickener and refatting agent for special formulations

Foam stabilization and viscosity control of detergent formulations

Suitable for foot and skincare preparations

Additive for anti-dandruff shampoos.

Comprehensive Castor Oil Derivatives Report

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o Undecylenic Acid - Sulfosuccinate Derivatives

Disodium Undecylenamido MEA-Sulfosuccinate

Contains the powerful solubilizing sulfonate group

A very mild anionic surfactant both to skin and eyes recommended for

application in baby shampoos and cleaning creams forits good skin

compatibility

Anti-dandruff activity: 2% active disodium mono-undecylenamido MEA-

sulfosuccinate is effective in the reduction of itching,scaling and dandruff

associated with seborrhea capitis.

3.2.1.3 Prominent Companies Involved in Making Polyamides from Castor Oil

There are some prominent companies that use castor oil to develop a range of polyamides. The

prominent global companies associated with castor oil based nylon production are:

Company Grades

Arkema 11 (homopolymer)

BASF 6, 10

DuPont 6, 10; 10, 10

DSM 4, 10

EMS 6, 10; 10, 10 '10T' (PPA)

(PPA) 6, 10; 10, 10

Evonik 6, 10

Comprehensive Castor Oil Derivatives Report

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Chapter Contents

4.1 Emerging Trends in End Uses

4.2 Business Partnerships in Castor Oil Derivatives

4.3 Past & Emerging Research in Castor Oil Derivatives

======================SAMPLE CONTENT====================

4.1.2 Emerging Applications of Castor Oil Based Biopolymers

The following table provides an overview of the recent and emerging applications of castor

biopolymers

Recent & Emerging Application Areas in

Biopolymers

• Mobility - Tubing, Air-braking, Liners • Solar – Back panels, Barrier Sheets • Household – Powder Coating • Cables – Jacketing • Filaments - Tooth brushes, Carpets

and Tires • Sports - Shoe Soles, Outdoor

Apparel • Cosmetics - Fine powders • Electronics – Casings

Sports Wear: As folks in the polyurethane

industry would tell you, the sports products

and footwear markets are other hot spots for

bioplastics.

Nike has launched a boot sole plate

made of 50% Pebax Renew (Arkema’s

castor-based thermoplastic elastomer

with about 97% renewable-based

component), and 50% bio-based

thermoplastic polyurethanes (TPU).

In 2011, North Face, an American

outdoor product company, introduced

a water proof breathable castor bean

membrane in one of its jackets

Electronics:

DuPont™ Zytel® RS HTN, a high-

performance castor oil-based

polyamide, has seen a fourfold

growth since its introduction four

years ago especially in the application

of hand-held electronics.

Solvay has launched a new portfolio

of bio-based high-performance

polyamides offered for use in smart

mobile devices such as smart phones,

tablets, laptops, and other smart

mobile electronics.

Biopolymers in Personal Care &

Cosmetics:

In personal care, polyamide based

particles like Nylon 12 powders are

commonly used to enhance the haptic

properties of cosmetic formulations.

They generally act as mattifying

agents in order to reduce the shine on

human skin. Due to their porosity,

these particles are also used to

4. Emerging Trends in Applications, Partnerships & Research

Comprehensive Castor Oil Derivatives Report

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reduce the stickiness and oiliness of

cosmetic products during application.

Moreover, they can act as binders in

pressed powder and other types of

color formulations.

In 2013, Worlee Cosmetics of

Germany developed castor oil based

beads from Hydrogenated Castor Oil

(HCO), which can be used as a

cosmetic rinse-off product, replacing

PE and PP plastic micro particles as an

exfoliant.

Comprehensive Castor Oil Derivatives Report

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Chapter Contents

5.1 Producers in Asia

5.2 Producers in Europe

5.3 Producers in North America

5.4 Other Producers and Suppliers

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5.1.1 Prominent Castor Oil & Derivatives Producers in India

Following are the prominent castor oil and castor derivatives manufacturers in India. The list is based on

a number of parameters, the key among which are the size of the company’s castor oil business, history

and track record.

Jayant Agro Organics

Main Line of Business: Castor Oil & Derivatives Production

Headquarters: Headquartered in Mumbai

Background

Jayant Agro-Organics Limited is a public listed company, traded on Bombay Stock Exchange and the

National Stock Exchange. It is a 100% export oriented unit, and is one of the leading castor based

companies in India. The company has a history of almost five decades. It is one of the largest castor oil

and derivatives companies in the world.

The company has acquired 100 percent subsidiary of Ihsedu Agrochem Pvt Ltd, a crushing unit from

Gujarat Agro Industries Corporation Limited. This plant has a crushing capacity of 350 MT oil / day and

also has solvent extraction plant. The plant is located in Banaskantha – which is one of the largest castor

growing districts in India’s largest castor seed producing state - Gujarat.

Products & Derivatives

The main products manufactured are Castor Oil Commercial Grade, Castor Oil First Special Grade, Castor

Oil Pale Pressed Grade, Castor Oil Extra Pale Grade, Castor Oil Neutralised Grade, Ethoxylated Castor Oil

and Castor Oil Pharma Grade. Notable is the fact that this unit also manufactures all high grade castor oils

including castor oil cold pressed.

5. Prominent Castor Oil Derivatives Producers

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Derivatives produced are HCO, 12-HSA , Methyl 12-HSA , Ricinoleic Acid, Castor Oil Polyols, 2-Octanol.

The company had been focusing more on basic castor grades until a decade back. In the last few years

however, the company has started climbing the value chain and has a high focus on specialty chemicals.

It currently supplies a range of generation I and generation II castor oil derivatives, besides the basic

grades. Our estimate is that it will be supplying about 1,00,000 T of castor oil / derivatives, and about 75-

100,000 T of castor meal per year. In recent years, the company has formed with Japanese chemical giants

to explore production of castor oil based polyols for polyurethane production, and is reportedly exploring

sebacic acid production as well.

For a complete list of their products, please see the following URL –

http://www.jayantagro.com/products.htm

Financials

Revenues of about 86 million US$ – 2015-2016 ($102 million in 2014-15).

Address

Akhandanand, 38, Marol Co-Operative Industrial Estate,

Off. M. V. Road, Sakinaka, Andheri (E)

Mumbai - 400059, India

www.jayantagro.com

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