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    A CORRELATION FOR RESERVOIR CHARACTERIZATION

    USING RECORDED REAL-TIME SURFACE DRILLING

    PARAMETERS AND WELL LOG DATA

    by

    Simone Steinecker

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    c Copyright by Simone Steinecker, 2014

    All Rights Reserved

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    A thesis submitted to the Faculty and the Board of Trustees of the Colorado School of

    Mines in partial fulfillment of the requirements for the degree of Master of Science (Petroleum

    Engineering).

    Golden, Colorado

    Date

    Signed:

    Simone Steinecker

    Signed:Dr. Alfred Eustes

    Thesis Advisor

    Signed:Dr. Mark Miller

    Thesis Advisor

    Golden, Colorado

    Date

    Signed:Dr. Will Fleckenstein

    Professor and HeadDepartment of Petroleum Engineering

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    ABSTRACT

    Recent economic developments of the US gas market and enhanced technological im-

    provements lead towards an increase of future operations in the sector of shale gas plays.

    The Eagle Ford field in Texas, being amongst the youngest US shale plays, serves as a good

    example of how correlating recorded real-time surface drilling parameters and well log data

    can be used to improve reservoir characterization. Variations of properties occurring hor-

    izontally and vertically, across the entire play or even along the wellbore are regarded as

    a major challenge directly affecting the economic development of shale gas reservoirs. An

    enormous amount of data is collected at present but not analyzed and evaluated in detail.

    Instead the trend is evolving that more data is generated, resulting in the incapability to

    integrate the data. Regression analysis is used to determine quantitative relationships be-

    tween a real-time surface drilling parameter and petrophysical logging data for wells located

    in the same geographic and geologic area. This research describes how the rate of penetration

    correlates with the gamma and acoustic log (slowness of elastic waves) for the predominant

    shale section of each well and how the regression outputs contribute to optimize reservoir

    characterization. Within the shale formation, the gamma log (GR) shows a good correlation

    with the rate of penetration. Information from mudlogs and daily drilling reports is used

    to identify possible reasons for misfits between the actual and the calculated rate of pen-

    etration. Studying a defined set of data in depth has proven to be a reliable indicator for

    comparing and categorizing wells. The results depict similarities and differences amongst

    the wells based on the properties of the formation they were drilled in. It is expected that

    additional real-time surface drilling parameters besides the rate of penetration are useful to

    obtain improved results. They can be used to normalize the rate of penetration to optimize

    the comparison between wells and to detect misfits between the regression output and the

    actual rate of penetration measured on a real-time base.

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    3.2 Real-Time Surface Drilling Data. . . . . . . . . . . . . . . . . . . . . . . . . . 24

    3.3 Data Analysis . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 26

    3.3.1 Comparison of Studied Wells. . . . . . . . . . . . . . . . . . . . . . . . 28

    3.3.2 Regression Analysis . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 30

    3.3.3 Data Correlations . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 33

    CHAPTER 4 RESULTS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 40

    4.1 Crossplots . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 40

    4.1.1 Internal Log Crossplots. . . . . . . . . . . . . . . . . . . . . . . . . . . 40

    4.1.2 Log to ROP Crossplots . . . . . . . . . . . . . . . . . . . . . . . . . . . 41

    4.2 Regression Analysis . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 41

    4.2.1 Well BC 1-1 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 48

    4.2.2 Well GE A1H . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 53

    4.2.3 Well PE A2H . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 59

    4.2.4 Well LK B1H . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 65

    4.2.5 Well PE A1H . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 69

    4.2.6 Well PE A2H ST . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 70

    4.2.7 Well RR A3H . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 75

    4.2.8 Well WL A1H . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 76

    4.2.9 Well WL A1H ST. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 81

    4.3 Inverted Regressions for GR as a Function of ROP . . . . . . . . . . . . . . . 84

    4.4 Empirical Relationships BetweenVP andVS- Castagna Equation . . . . . . . 84

    4.4.1 Well BC 1-1 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 87

    4.4.2 Well GE A1H . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 88

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    4.4.3 Well PE A2H . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 90

    4.5 Summarizing Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 90

    CHAPTER 5 CONCLUSION. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 94

    REFERENCES CITED . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 98

    APPENDIX A - PYTHON SCRIPT . . . . . . . . . . . . . . . . . . . . . . . . . . . 102

    A.1 Python Script for Crossplots . . . . . . . . . . . . . . . . . . . . . . . . . . . 102

    APPENDIX B - WELL LOGGING TOOLS . . . . . . . . . . . . . . . . . . . . . . . 103

    B.1 Gamma Log . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 103

    B.2 Acoustic/Sonic Log . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 105

    APPENDIX C - CROSSPLOTS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 107

    C.1 Crossplots Not Used for Regression Analysis . . . . . . . . . . . . . . . . . . 107

    APPENDIX D - REGRESSION ANALYSIS . . . . . . . . . . . . . . . . . . . . . . . 110

    D.1 Simple Linear Regression Analysis. . . . . . . . . . . . . . . . . . . . . . . . 110

    APPENDIX E - INFORMATION PROVIDED BY COMPANIES . . . . . . . . . . . 112

    E.1 Areas of Interest Stated by Companies . . . . . . . . . . . . . . . . . . . . . 112

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    LIST OF FIGURES

    Figure 1.1 US total natural gas production by source between 1990-2035 . . . . . . . . 3

    Figure 1.2 Map of lower 48 states shale plays in the US . . . . . . . . . . . . . . . . . 4

    Figure 1.3 Stratigraphic column and correlation in the upper Cretaceous interval,US Gulf Coast . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5

    Figure 1.4 Eagle Ford shale map showing the wells permitted and completed in thefield. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7

    Figure 1.5 Eagle Ford shale map including producing oil and gas wells andshowing the three sections of the field . . . . . . . . . . . . . . . . . . . . . 7

    Figure 1.6 Eagle Ford shale map showing the geologic structure of the shale play . . . 8

    Figure 1.7 Lateral extent of Eagle Ford shale play in South Texas showing thewells used in this research. . . . . . . . . . . . . . . . . . . . . . . . . . . . 8

    Figure 2.1 Anisotropy and heterogeneity. . . . . . . . . . . . . . . . . . . . . . . . . 17

    Figure 2.2 Measured permeability anisotropy in shales with permeability measured

    parallel and perpendicular to bedding and SEM image of Kimmeridgeshale . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 18

    Figure 3.1 P-wave and S-wave velocities for clay, quartz, calcite and dolomite . . . . 25

    Figure 3.2 Overview of the wells studied located in the Eagle Ford field inMcMullen country in Texas. Scale of the map 1:326,670. . . . . . . . . . . 26

    Figure 3.3 Wellbore schematic for horizontal wells illustrating informationobtained from daily drilling reports. . . . . . . . . . . . . . . . . . . . . . 29

    Figure 3.4 Comparing information from daily drilling reports with informationfrom mudlogs . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 31

    Figure 3.5 Internal log crossplot for well GE A1H showing DTC versus DTS andMD as a third dimension . . . . . . . . . . . . . . . . . . . . . . . . . . . 37

    Figure 3.6 Crossplot for well GE A1H showing GR versus ROP and MD as a thirddimension . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 38

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    Figure 3.7 Simple linear regression correlating ROP and GR for well GE A1H . . . . 39

    Figure 4.1 Internal log crossplots illustrating the relationship between thecompressional slowness DTC and the shear slowness DTS.. . . . . . . . . 42

    Figure 4.2 Internal log crossplots illustrating the relationship between gamma rayGR and compressional slowness DTC . . . . . . . . . . . . . . . . . . . . 43

    Figure 4.3 Internal log crossplots illustrating the relationship between gamma rayGR and shear slowness DTS . . . . . . . . . . . . . . . . . . . . . . . . . 44

    Figure 4.4 Correlations illustrating the relationship between the compressionalslowness DTC and the rate of penetration ROP . . . . . . . . . . . . . . 45

    Figure 4.5 Correlations illustrating the relationship between the shear slownessDTS and the rate of penetration ROP . . . . . . . . . . . . . . . . . . . . 46

    Figure 4.6 Correlations illustrating the relationship between gamma ray GR andthe rate of penetration ROP . . . . . . . . . . . . . . . . . . . . . . . . . 47

    Figure 4.7 Data set used for regression analysis for well BC 1-1 . . . . . . . . . . . . 49

    Figure 4.8 Simple linear regression analysis for well BC 1-1 . . . . . . . . . . . . . . 50

    Figure 4.9 Multiple linear regression analysis for well BC 1-1 . . . . . . . . . . . . . 52

    Figure 4.10 Data set used for regression analysis for well GE A1H . . . . . . . . . . . 54

    Figure 4.11 Simple linear regression analysis for well GE A1H . . . . . . . . . . . . . 56

    Figure 4.12 Multiple linear regression analysis for well GE A1H . . . . . . . . . . . . 58

    Figure 4.13 Data set used for regression analysis for well PE A2H . . . . . . . . . . . 60

    Figure 4.14 Simple linear regression analysis for well PE A2H . . . . . . . . . . . . . 61

    Figure 4.15 Multiple linear regression analysis for well PE A2H . . . . . . . . . . . . 63

    Figure 4.16 Data set used for regression analysis for well LK B1H . . . . . . . . . . . 66

    Figure 4.17 Simple linear regression analysis for well LK B1H . . . . . . . . . . . . . 67

    Figure 4.18 Data set used for regression analysis for well PE A1H . . . . . . . . . . . 69

    Figure 4.19 Simple linear regression analysis for well PE A1H . . . . . . . . . . . . . 71

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    Figure 4.20 Data set used for regression analysis for well PE A2H ST . . . . . . . . . 72

    Figure 4.21 Simple linear regression analysis for well PE A2H ST . . . . . . . . . . . 73

    Figure 4.22 Data set used for regression analysis for well RR A3H . . . . . . . . . . . 75

    Figure 4.23 Simple linear regression analysis for well RR A3H . . . . . . . . . . . . . 77

    Figure 4.24 Data set used for regression analysis for well WL A1H . . . . . . . . . . . 78

    Figure 4.25 Simple linear regression analysis for well WL A1H . . . . . . . . . . . . . 80

    Figure 4.26 Data set used for regression analysis for well WL A1H ST . . . . . . . . . 81

    Figure 4.27 Simple linear regression analysis for well WL A1H ST . . . . . . . . . . . 83

    Figure 4.28 Gamma ray GR estimate from rate of penetration ROP indicating shaleand non-shale sections for the wells. . . . . . . . . . . . . . . . . . . . . . 85

    Figure 4.29 Simple linear regression analysis for well PE A1H calculating GR fromROP . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 86

    Figure 4.30 Correlation of the compressional and shear slowness with influence ofgamma ray for well BC 1-1.. . . . . . . . . . . . . . . . . . . . . . . . . . 87

    Figure 4.31 Correlation of the compressional and shear slowness with influence of

    gamma ray for well GE A1H. . . . . . . . . . . . . . . . . . . . . . . . . . 89

    Figure 4.32 Correlation of the compressional and shear slowness with influence ofgamma ray for well PE A2H. . . . . . . . . . . . . . . . . . . . . . . . . . 90

    Figure 4.33 Summary for simple linear regressions.. . . . . . . . . . . . . . . . . . . . 92

    Figure 4.34 Categories for simple linear regressions using gamma ray. . . . . . . . . . 93

    Figure 5.1 Splitting up the well into three sections for enhanced regression analysis.. 97

    Figure A.1 Crossplot analysis based on Excel database using Python script. . . . . 102

    Figure B.1 Gamma ray logging tool . . . . . . . . . . . . . . . . . . . . . . . . . . 104

    Figure B.2 Acoustic/sonic logging tool . . . . . . . . . . . . . . . . . . . . . . . . . 106

    Figure C.1 Internal log crossplots illustrating the relationship between gamma rayGR and the ratio of the compressional to the shear slowness DTC/DTS 107

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    Figure C.2 Internal log crossplots illustrating the relationship between gamma rayGR and compressional DTC2 or shear DTS2 slowness . . . . . . . . . . 108

    Figure C.3 Correlations illustrating the relationship between the compressionalshear slowness DTC2 and the rate of penetration ROP. . . . . . . . . . 109

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    LIST OF TABLES

    Table 2.1 Common sources for reservoir properties . . . . . . . . . . . . . . . . . . . 16

    Table 2.2 Key reservoir parameters and their data source . . . . . . . . . . . . . . . 16

    Table 2.3 Logging tool response in shale gas reservoirs . . . . . . . . . . . . . . . . . 20

    Table 2.4 Summary of methods to determine TOC from logs . . . . . . . . . . . . . 21

    Table 3.1 Measured distances between wells in McMullen country, Texas . . . . . . . 27

    Table 3.2 Measurement intervals for each well. . . . . . . . . . . . . . . . . . . . . . 28

    Table 3.3 Information on drilling parameters from daily drilling reports . . . . . . . 32

    Table 3.4 Formula map of regression statistics output . . . . . . . . . . . . . . . . . 33

    Table 3.5 Formula map of ANOVA output . . . . . . . . . . . . . . . . . . . . . . . 34

    Table 3.6 Various combinations for crossplot analysis using well log parametersand ROP . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 35

    Table 4.1 Output for regression 1 for well BC 1-1 . . . . . . . . . . . . . . . . . . . . 51

    Table 4.2 Output for regression 2 for well BC 1-1 . . . . . . . . . . . . . . . . . . . . 51

    Table 4.3 Output for regression 3 for well BC 1-1 . . . . . . . . . . . . . . . . . . . . 51

    Table 4.4 Output for regression 4 for well BC 1-1 . . . . . . . . . . . . . . . . . . . . 53

    Table 4.5 Output for regression 1 for well GE A1H . . . . . . . . . . . . . . . . . . . 55

    Table 4.6 Output for regression 2 for well GE A1H . . . . . . . . . . . . . . . . . . . 55

    Table 4.7 Output for regression 3 for well GE A1H . . . . . . . . . . . . . . . . . . . 57

    Table 4.8 Output for regression 4 for well GE A1H . . . . . . . . . . . . . . . . . . . 57

    Table 4.9 Output for regression 1 for well PE A2H . . . . . . . . . . . . . . . . . . . 62

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    Table 4.10 Output for regression 2 for well PE A2H . . . . . . . . . . . . . . . . . . . 62

    Table 4.11 Output for regression 3 for well PE A2H . . . . . . . . . . . . . . . . . . . 64

    Table 4.12 Output for regression 4 for well PE A2H . . . . . . . . . . . . . . . . . . . 64

    Table 4.13 Summary of simple linear regression curve misfits for well LK B1H . . . . 65

    Table 4.14 Regression output for the lower section of well LK B1H. . . . . . . . . . . 68

    Table 4.15 Regression output for the upper section of well LK B1H . . . . . . . . . . 68

    Table 4.16 Regression output for well PE A1H . . . . . . . . . . . . . . . . . . . . . . 70

    Table 4.17 Regression output for well PE A2H ST . . . . . . . . . . . . . . . . . . . . 74

    Table 4.18 Summary of simple linear regression curve misfits for well PE A2H ST . . 7 4

    Table 4.19 Regression output for well RR A3H . . . . . . . . . . . . . . . . . . . . . . 76

    Table 4.20 Summary of simple linear regression curve misfits for well RR A3H . . . . 76

    Table 4.21 Regression output for well WL A1H . . . . . . . . . . . . . . . . . . . . . 79

    Table 4.22 Summary of simple linear regression curve misfits for well WL A1H . . . . 7 9

    Table 4.23 Regression output for well WL A1H ST . . . . . . . . . . . . . . . . . . . 82

    Table 4.24 Summary of simple linear regression curve misfits for well WL A1H ST . . 8 2

    Table 4.25 Parameters c and d for GR estimate from ROP . . . . . . . . . . . . . . . 84

    Table 4.26 DTC correlated with DTS and the resulting equations for well BC 1-1. . . 8 8

    Table 4.27 DTC correlated with DTS and the resulting equations for well GE A1H. . 89

    Table 4.28 DTC correlated with DTS and the resulting equations for well PE A2H. . 91

    Table B.1 Volume of investigation for gamma log . . . . . . . . . . . . . . . . . . . 103

    Table B.2 Operational constraints for gamma log . . . . . . . . . . . . . . . . . . . 103

    Table B.3 Volume of investigation for acoustic/sonic log . . . . . . . . . . . . . . . 105

    Table B.4 Operational constraints for acoustic/sonic log . . . . . . . . . . . . . . . 105

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    Table D.1 Summary of simple linear regression outputs correlating ROP with DTC 110

    Table D.2 Summary of simple linear regression outputs correlating ROP with GR . 111

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    LIST OF SYMBOLS

    Bulk compressional modulus. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . k

    Bulk density . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

    Capillary pressure . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Pc

    Compressional interval transit time . . . . . . . . . . . . . . . . . . . . . . . . . . . . tP

    Compressional wave modulus . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . M

    Compressional wave velocity . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . VP

    Lames first parameter . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

    Poissons ratio . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

    Shear interval transit time . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . tS

    Shear modulus . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

    Shear wave velocity. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . VS

    Youngs modulus . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . E

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    LIST OF ABBREVIATIONS

    American Petroleum Institute . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . API

    Analysis of variance . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ANOVA

    Barns per electron . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . b/e

    Compressional wave travel time . . . . . . . . . . . . . . . . . . . . . . . . . . . . . DTC

    Condensate gas ratio . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . CGR

    Dipole shear imager . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . DSI

    Feet . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ft

    Flow rate . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Q

    Fourier transform infrared spectroscopy. . . . . . . . . . . . . . . . . . . . . . . . . FTIR

    Gallons per minute . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . gpm

    Gamma ray . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . GR

    Inch . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . in

    Inductively coupled plasma mass spectrometry. . . . . . . . . . . . . . . . . . . . ICP-MS

    Injection fall-off test . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . IFOT

    Kickoff point . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . KOP

    Log ASCII standard . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . LAS

    Measured depth. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . MD

    Measuring while drilling . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . MWD

    Mechanical specific energy . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . MSE

    Mercury injection capillary pressure. . . . . . . . . . . . . . . . . . . . . . . . . . . MICP

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    Millimeter . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . mm

    Million cubic feet . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . mcf

    Nanometer . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . nm

    Normalized rate of penetration . . . . . . . . . . . . . . . . . . . . . . . . . . . . . NROP

    Nuclear magnetic resonance log . . . . . . . . . . . . . . . . . . . . . . . . . . . . . NMR

    Oil based mud . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . OBM

    Overhead lines . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . OHL

    Parts per million . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ppm

    Photo-luminescence. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . PL

    Photodiode array detector . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . PDA

    Photoelectric index . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Pe

    Pound-force . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . lbf

    Pressure volume temperature . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . PVT

    Rate of penetration. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ROP

    Revolutions per minute. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . RPM

    Rotations per minute. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . RPM

    Scanning electron microscopy . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . SEM

    Shear wave travel time . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . DTS

    Sidetrack . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ST

    Standard pipe pressure . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . SPP

    Standard resolution formation density . . . . . . . . . . . . . . . . . . . . . . . . . RHOZ

    Steady state & unsteady state permeability test . . . . . . . . . . . . . . . . . . SS&USS

    Total organic carbon . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . TOC

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    Trillion cubic feet . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Tcf

    United States . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . US

    United States Dollars. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . USD

    Vitrinite reflectance . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Ro

    Water based mud . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . WBM

    Weight on bit . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . WOB

    X-Ray diffraction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . XRD

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    ACKNOWLEDGMENTS

    First of all, I would also like to thank Dr. Alfred Eustes. He made it possible for

    me to write this thesis as part of a cooperation between the Colorado School of Mines

    and Montanuniversitat Leoben. His way of not making anything more complicated than

    necessary and challenging students to think beyond the book, makes him an honorable

    professor. Although Dr. Eustes was on his SPE distinguished lecture tour during my second

    semester as graduate student at the Colorado School of Mines, he kept in touch with me in

    order to support me whenever necessary. I really appreciate his help throughout my time

    at CSM and beyond. He is a great adivsor. My thanks also go to my co-advisor Dr. Mark

    Miller. His input helped me to keep on track with my work . Especially when it comes to

    the correct layout and format of my thesis. From the Colorado School of Mines, I would

    also like to thank Dr. Azra Tutuncu for letting me be part of her research group within

    the Unconventional Natural Gas Institute (UNGI). She granted me the stipend I needed to

    be able to finish my graduate studies in the USA. Tom Bratton played an important part

    while I was writing my thesis. He helped a lot with his input and ideas. Tom Bratton

    has the experience from many year in the industry and the petrophysical background that I

    needed. It was nice that I could come by his office any time he was there to ask questions.

    I would also like to thank the UNGI sponsors. Without their data and feedback at the

    sponsoring meetings, this research would have not been possible. At last, Denise and Terri

    have my deepest respect for the daily work they do to help make a students life easier and

    less bureaucratic.

    From the Montanuniversity in Leoben, I would like to thank my advisor Dr. Gerhard

    Thonhauser and my co-advisor Dr. Jurgen Schon.

    This project would never have succeeded without the almost daily support from my

    family, my hosts Ann and Dave, my closest friends Margit, Mike, Nihal and Mathias and

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    CHAPTER 1

    INTRODUCTION

    The projected growth of the United States (US) energy demand is dominated by the

    industrial and electric power sectors with an increase of natural gas consumption of 5.1 Tcf

    between 2011 and 2040 (EIA, 2013). To meet the present and future developments of US

    energy demands the production of natural gas from fine-grained clastic sedimentary rocks

    known as shale is of significant importance. This rock type is composed mainly of clay

    and silt-sized particles and in some cases even contains sand-sized particles as well (Schon,

    2011). Developments in horizontal drilling technology and improved techniques of hydraulic

    fracturing over the last 15 years contribute to an enhanced recovery of shale gas and thus to

    an economically justifiable production (Bazan, Lattibeaudiere and Palisch,2012). According

    to Holditch(2003), the production from shale gas reservoirs is the exploitation of natural

    gas from so-called unconventional reservoirs. These unconventional reservoirs are the largest

    source of US natural gas supplies, estimated to make up 49 % of US total natural gas

    production in 2035 (Figure 1.1). The shale gas production is supposed to increase from 5.0

    Tcf in 2010 to 13.6 Tcf in 2035. Recent developments will enable the US to change its role

    of being a net importer to becoming an exporter in 2020. In 2010, 11 % of US natural gas

    supply came from imports. By 2035 the expected US net natural gas exports are 1.4 Tcf

    (EIA,2012). Although the optimistic projections with regard to future shale gas production

    remain promising throughout the next two decades, the EIA (2012) states that achieving

    economic gas-flow rates for commercial purposes continues to be a critical issue looking atthe historic development of the natural gas market prices and future developments.

    1.1 General Aspects of the Problem

    The economic development of shale resources offers opportunities but also faces numer-

    ous challenges (Bustin et al.,2008). According toKennedy, Gupta and Kotov(2012) finding

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    Figure 1.1: US total natural gas production by source between 1990-2035. Figure fromEIA(2012).

    and targeting the so-called sweet spots in shale gas reservoirs is the key issue to produce

    the natural gas at economic rates. The widespread diversity of reservoir specific properties

    requests the use of a minimum set of techniques to characterize the fields individually and

    identify the unique properties of each shale gas reservoir. Understanding the nature of shale

    gas reservoirs by improving reservoir characterization helps to reduce existing uncertainties

    and develop the field economically (Mullen,2010). Martin et al. (2011) describe shale for-

    mations as low permeability formations that act as both, the source for the natural gas and

    the reservoir. Compared to the production from conventional reservoirs, more data from un-

    conventional reservoirs is needed to address the issue of reservoir characterization. Holditch

    (2006) mentiones that due to their high diversity, identifying and characterizing these types

    of reservoirs is complex. Unconventional reservoirs do not show a typical trend as proven

    byHayden and Pursell (2005) who compared organic shale properties of six different shale

    plays.

    The first well producing directly from a shale formation was drilled in 1821 ( Sondergeld

    et al., 2010). Since then almost 200 years have passed. In the 1980s the Barnett shale started

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    Figure 1.3: Stratigraphic column and correlation in the upper Cretaceous interval, US GulfCoast. Figure fromSondhi(2011).

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    thickness ranges between 50 ft and up to approxiametely 350 ft. Although the Eagle Ford

    formation is regarded as a shale formation, up to 70 % can be carbonate content which makes

    the formation more brittle and easier to stimulate using hydraulic fracturing. With a total

    organic carbon (TOC) of 1-7 %, the Eagle Ford shale is split into an Upper and Lower Eagle

    Ford formation whereas the Lower Eagle Ford has more organically rich material and thus

    produces more hydrocarbons (Bazan, Lattibeaudiere and Palisch, 2012). Due to the large

    extent of the Eagle Ford formation, the field is split into three areas depending on the type of

    hydrocarbons. In the north of the Eagle Ford field the reservoir produces oil (green), whereas

    the middle part of the field is referred to as the condensate (yellow) window. Here, both

    condensates and natural gas can be found. The area in the south is a dry gas (red) producer

    (Figure 1.5). Mullen, Lowry and Nwabuoku(2010) agree that characterizing the Eagle Ford

    shale bears challenges. Besides the different hydrocarbons produced in different geographic

    areas, the shale formations structure changes across the entire play indicated by Figure 1.6

    showing the diverse geologic structure of the play. The gross height and the formations

    depth can vary significantly. For successful developments of shale plays, it is important that

    each shale is characterized individually. Shale formations can even vary significantly across

    the play itself and therefore studying und understanding the local reservoir is recommended.

    By way of example, Ramurthy et al. (2011) show that the successful surface-area fracture

    treatment for Barnett shale does not achieve the same results for other shales. As the Eagle

    Ford field is one of the youngest shale gas reservoirs in the US, characterizing the field is still

    in progress with issues and challenges related to it. Examples of topics companies regard as

    important to learn about are petrophysical and geomechanical characterization, production

    and completion design and optimization, drilling design and rock mechanics, etc. (AppendixE).

    For this research, multiple wells from the Eagle Ford field were selected. The wells

    are all located in the area of McMullen County, approxiametely 60-70 miles south of San

    Antonio, Texas. Figure 1.7 gives an overview of an excerpt of the Eagle Ford field. The

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    Figure 1.4: Eagle Ford shale map showing the wells permitted and completed in the field.Figure fromRailroad Commission of Texas (2013).

    Figure 1.5: Eagle Ford shale map including producing oil and gas wells and showing thethree sections of the field, the oil window (green), the wet gas/condensate window (yellow)and the dry gas window (red). Figure from EIA (2010).

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    Figure 1.6: Eagle Ford shale map showing the geologic structure of the shale play. FigurefromChesapeake Energy(2013).

    Figure 1.7: Lateral extent of Eagle Ford shale play in South Texas showing the wells usedin this research. Figure modified by Statoil taken fromRoberson(2013).

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    wells for this research are located in the central part. The selection is based on wells to

    be in the same geographic and geologic area, i.e. reduced variations in terms of organic

    matter, mineralogy, rock composition and depositional environment are expected. This is

    important when studying the shale reservoirs characteristics and potential relationships

    between the wells. Pointing out similarities as well as differences amongst these wells cannot

    solve the complexity involved when trying to characterize an entire shale play. However, by

    picking out a pre-defined number of parameters from the data sets available and analyzing

    them in more detail, an improved or even new approach can enhance shale gas reservoir

    characterization. Increased knowledge and improved understanding of the area studied is

    expected to contribute to future drilling operations.

    1.3 Motivation of Study

    Considering the significant amount of data collected by operators drilling in the same

    geographic and geologic area from the wells on a daily basis justifies the presumption that

    selected data can be extracted for the purpose of analyzing it in more detail. The results

    obtained can improve real-time drilling operations and enhance reservoir characterization in

    the area of study. A relationship between petrophysical properties obtained from well logsand drilling parameters can be expected. The comparison of operational drilling parameters

    to the known properties from the reservoir can be applied for future real-time analysis during

    drilling operations. Both groups are controlled by porosity, clay content or rock composition,

    water content and the internal rock structure implementing the bonding forces between

    constituents. The weight of these properties influences on the individual parameters is

    different. Therefore the expected correlation is dominated by a complexity of these factors.

    A simple correlation as detected for sandstone between velocity and drilling parameters or

    strength will not be successful and will result in great scatter of data points. Therefore, as an

    additional parameter, a property describing lithological effects like the clay influence should

    be considered by implementing the results of the gamma ray log. In a comparable direction

    could be a variation of organic content. Thus, as a mathematical instrument, simple and

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    multiple linear regressions are to be applied. The development/derivation of correlations is -

    from the present knowledge - directed by two dominant input parameters: elastic properties

    (e.g. acoustic log, density) and lithology or shale typing properties (e.g. natural gamma,

    density-neutron) as stated by Fjaer et al. (2008), Schon (2011) and Somerton, Esfandiari

    and Singhal (1969). The motivation of this research is to use available data, analyze it in

    detail and give recommendations of how this approach can be realized and applied to future

    drilling operations.

    1.4 Objectives

    The main task of this proposed thesis research is to develop a log-to-drilling parameters

    model represented in form of simple and multiple linear regressions to present correlations

    for the wells drilled in the same geologic and geographic region of the Eagle Ford field. At

    this stage, no research has been conducted to show if drilling parameters, as for example,

    the rate of penetration (ROP) can be described as a variable, dependent on several other

    independent variables for this particular field of study. The proposed research is aimed to

    achieve the following objectives as part of three phases:

    1. Gathering and extracting relevant logging data and drilling parameters from the data

    sets received for each well for a defined depth interval. For various combinations of

    measured well log data and drilling parameters, the data is processed, analyzed and

    presented in crossplots. Two different correlations will be studied: correlations of

    selected well log data with a drilling parameter and internal correlations using well log

    data only to prove internal consistency of petrophysical properties. The primary goal

    is to determine the best set of parameters where significant correlations can be found.

    2. Developing a correlation for the drilling parameter and the well log data using sim-

    ple and multiple linear regressions to obtain a best-fit curve that represents the

    relationship of the data analyzed.

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    3. Determining possible reasons for a mismatch of the regression model and the actual

    drilling parameter in the form of a misfit occurring for a certain depth interval. Inte-

    grating information from daily drilling reports, mud log reports and additional logging

    data will be used.

    4. At last, the conclusion obtained from this study will be used to give recommendations

    for future operations and also state how the outcome of this study can be improved by

    taking additional data in the form of other real-time surface drilling parameters into

    account.

    1.5 Thesis Outline

    This thesis covers four main topics:

    crossplots using log-to-log correlations and log-to-drilling parameters correlations to

    study the relationships between the parameters;

    regression analysis using a drilling parameter as the dependent variable and log pa-

    rameters as the independent variables to predict trends for the area of interest;

    inverted regression analysis for estimating gamma ray as a function of the rate of

    penetration;

    empirical relationships between VP andVS - Castagnas equation.

    The crossplots are used to compare and interpret the data measurements. Internal cor-

    relations of log data help to understand internal cosistency and show the quality of the data

    used. Additionally, the influence of a third parameter is used to determine the dependency

    of the correlated parameters on it, e.g. measured depth, gamma ray or rate of penetra-

    tion. Empirical relationships (Castagna, Batzle and Eastwood, 1985) used for seismic can

    be studied and verified using these internal log-log correlations. Next, correlations using

    one drilling and one log parameter show the relationship between the two. The crossplots

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    serve as a qualitive measure to determine which parameters are correlating strongly with the

    drilling parameter. The regression analysis quantify the relationships between the drilling

    parameter and the log data based on the results obtained from the crossplots. Comparing

    the regressions of the wells assist in verifying that they are located in the same geologic area

    and that they were drilled under comparable drilling conditions. For this research it was

    expected to receive additional real-time surface drilling data for enhanced research in the

    sense of improved interpretation of the results and further comparisons. As no additional

    data was delivered in the time frame of this study, the recommendations will include how

    additional drilling data can be integrated to improve the results of this research.

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    CHAPTER 2

    LITERATURE REVIEW

    The economic development of shale gas reservoirs, the opportunities as well as the chal-

    lenges going along with the characterization of these reservoirs have been subject to numerous

    studies carried out by multiple authors. Kennedy, Gupta and Kotov(2012) say that target-

    ing the so-called sweet spots in shale gas reservoirs as the key issue to produce the natural

    gas at economic rates. By September2013, Baker Hughes recorded 85 % of the wells drilled

    in the Eagle Ford field in Texas to be horizontal, 11 % to be directional and only 4 % to be

    vertical wells. In the second quarter of 2013, a total of 1,050 wells were drilled. The majority

    of wells drilled have low flow rates ranging between 560-8,400 m3/day or 20-300 mcf/day.

    Wells producing at these rates show a slow decline trend with an average production duration

    of 20-40 years. Initially higher flow rates usually experience a fast decline within the first

    months or years (Rokosh et al., 2009). These numbers already show that many horizontal

    wells have to be drilled in order to achieve economic rates of hydrocarbon production.

    2.1 Lithological Classification

    Throughout the literature, authors use different approaches to define shale, shale gas and

    sweet spots. Some use the terms very loosely while others describe them based on a more

    lithological attempt. Arthur, Langhus and Alleman(2008) define shale to be a sedimentary

    rock type with particles the size of fine-grained clay particles rich in organic content. Shale

    gas is described to be a predominantely dry natural gas containing>90 % methane although

    in some areas wet gas can occur. Sondhi (2011) specifies the clay particle size to be

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    an unconventional reservoir system. Attempts to describe shale can cause confusion. For

    this research a more systematic sedimentological approach is used to provide a thoughtful

    description of shale (Fjaer et al., 2008;Schon, 2011). Shale belongs to the clastic sedimentary

    rocks which come from pre-existing rocks that formed into smaller fragments by mechanical

    and/or chemical weathering and erosion processes. Water and wind are the main transport

    mechanisms for depositing the fragments. Sedimentation is followed by compaction and dia-

    genesis of the material. At this stage, the sediment transforms into a rock, i.e. clay to shale.

    According to the classification schematic of clastic sediments, clay particles are smaller than

    0.002 mm in diameter. Shale is a mixture of primarily these clay-sized particles and silt-sized

    particles (0.002-0.063 mm). It may also contain some sand-sized particles (0.063-2.0 mm).

    Due to its high clay content, shale is dominated by the clay minerals and these influence

    the rocks properties significantly, e.g. permeability, porosity, gamma radiation. Pore sizes

    in shales range between 5-25 nm in diameter, although this changes depending on the clay

    minerals existant. We also distinguish between dispersed, laminated and structural clay dis-

    tribution in shales and this fact is often neglected by many authors. In the case of the Eagle

    Ford shale, up to 70 % of the formation can come from carbonates, consisting primarily of

    the mineral dolomite or calcite. In comparison to shale, carbonates are chemically not as

    stable and are highly complex in their pore space and geometry. Carbonates can occur as

    limestone or dolomite. Taking into account postdepositional processes like dissolution or

    dolomitization increasing porosity and stress fracturing resulting in areas of high permeabil-

    ity, carbonates are regarded as high quality reservoirs. They are estimated ...to hold 60 %

    of the worlds petroleum reserves and presently account for 40 % of the worlds total hy-

    drocarbon production. (Chopra, Chemingui and Miller,2005). The simultaneous presenceof both, shale and limestone or dolomite in the Eagle Ford field increases the complexity

    involved when studying this area. The physical rock properties are influenced with a greater

    diversity by its parameters and dependencies. In order to maintain consistency through-

    out this research, the term shale is used when describing the Eagle Ford play although

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    carbonates are present in the depth intervals of interest too.

    2.2 Shale Reservoir Characterization

    Interestingly many authors use the term sweet spot but only few describe it in more

    detail like Baihly et al. (2010) who see it as a zone of high production. For this research

    the study carried out by Mullen (2010) on the petrophysical properties of the Eagle Ford

    shale offers an interesting approach. He found out that the zone of interest, namely the

    shale formation, can be detected from mudlogs that show an increase in the rate of pene-

    tration influenced by existing natural fractures and high amounts of total gas. His objective

    is to integrate data from various sources like mudlogs, well logs and core analysis into a

    petrophysical model. The model should help to characterize the reservoir by locating zones

    with high total organic content and zones with geomechanical properties ideal for fracturing.

    Other authors likeChen et al. (2011) point out that the characterization typically includes

    geological, geochemical and mineralogical as well as petrophysical and petrographic analy-

    sis. Thus, numerous tools, techniques and methods to address the need for integrated shale

    gas reservoir characterization are in use nowadays. Additionally to core tests and well logs,

    measurements to obtain reservoir properties also come from different pressure test methods.Table 2.1andTable 2.2give an overview of reservoir properties considered as key reservoir

    parameters and how they can be obtained from various data sources.

    Again, studying the literature with respect to shale reservoir characterization, it is noted

    that authors use different terms that relate to the same concept. For this research, the

    focus lies on the mineralogical (nuclear/radioactive properties like gamma ray) and geophys-

    ical characteristics (elastic properties like wave velocities) coming from surface and borehole

    measurements. Both, mineralogical and geophysical properties originate from the physical

    properties of the rock, called petrophysics. According toSchon(2011), the shale content

    from the natural gamma log is a scalar underlying no directional dependence. Elastic prop-

    erties do have a directional depence and are described by a tensor and discussed by Melaku

    (2008). This is important knowing that anisotropy in shales can differ at high magnitudes as

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    Table 2.1: Common sources for reservoir properties. Table fromSondergeld et al. (2010)

    Reservoir properties Data source

    Elastic properties DSI (dynamic), core-based compression

    test (static)Fluid properties Mud log, PVT, PDA, pressure gradients

    Fracture and closure stress IFOT, Frac job, log-based (DSI)Free and sorbed gas Visual Ro, maserals, RockEval (calc)

    Maturity SS&USS, IFOT, MICP, PDA, NMR (calc)Permeability IFOT, PDA, log-based, dip-inPore pressure Gas expansion, MICP, NMR, log-based

    Porosity XRD, TS point counts, FTIR, ICP-MS,

    EDAS (SEM)

    Rock composition XRD, TS point counts, FTIR, ICP-MS,

    EDAS (SEM)Temperature OHL, PL, frac job, IFOT

    TOC Leco TOC, RockEval (calc)Water saturation Core extraction, Pc, log-based

    Table 2.2: Key reservoir parameters and their data source. Table from Kennedy(2010)

    Reservoir parameters Data Source

    Brittle rock DSI (dynamic), core-based compression

    test (static)

    Stress regime Mud log, PVT, PDA, pressure gradientsOver-pressure IFOT, frac job, log-based (DSI)

    Local lithology variations Visual Ro, maserals, RockEval (calc)faults, karsts, water SS&USS, IFOT, MICP, PDA, NMR (calc)

    Organic content IFOT, PDA, log-based, dip-inMicro-porosity Gas expansion, MICP, NMR, log-based

    Thermal Mmaturity XRD, TS point counts, FTIR, ICP-MS,

    EDAS (SEM)

    mentioned byKing(2010) andWaters, Lewis and Bentley(2011). Figure 2.1gives a graphi-

    cal overview of what is meant by the terms isotropic-homogeneous (Figure 2.1(a)), isotropic-

    inhomogeneous (Figure 2.1(b)), anisotropic-homogeneous (Figure 2.1(c)) and anisotropic-

    inhomogeneous (Figure 2.1(d)). In comparison to an isotropic material, an anisotropic ma-

    terial shows a change in magnitude dependent on its direction. Homogeneity refers to no

    change of property at different locations within the volume.

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    Variations of properties occur horizontally and vertically, across the entire play or even

    along the wellbore. Shale is characterized typically by its widespread textural anisotropy re-

    sulting from depositional differences of clay, other minerals and organic components creating

    laminations. These differences have an impact on several rock properties like permeability,

    electrical resistivity, elastic wave velocities, derived properties (Youngs modulus, shear mod-

    ulus and Poissons ratio) and strength properties. Regardless of how the anisotropic fabric

    of gas shales impacts its mechanical properties, it undoubtedly can be considered as one of

    the major components for shale gas reservoir characterization (Sondergeld et al.,2010). Fig-

    ure 2.2shows the permeability anisotropy measured parallel and perpendicular to bedding

    on core plugs and a SEM image of a shale with clay and silt particles.

    Figure 2.2: Measured permeability anisotropy in shales with permeability measured paralleland perpendicular to bedding. Figure fromSondergeld et al.(2010). SEM (scanning electronmicrophotograph) image of Kimmeridge shale. Figure fromMelaku(2008).

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    2.3 Openhole Petrophysical Measurements

    The question that arises after studying researches carried out by various authors is the

    availability and practicability of the tools discussed and methods described. In order to

    achieve comparable results amongst wells in the same geologic area, the same data sets

    should be used. Taking the example of interpreting well log data from wireline or measuring

    while drilling (MWD) with the purpose to characterize the near wellbore area in order to

    obtain information about the formations properties of interest was and still is of signifi-

    cant importance for the development of hydrocarbon bearing fields. Existing technologies

    are continuously improved and measurements become more accurate and precise for differ-

    ent applicationsLuthi(2001). Whether it is to estimate the depth for formation and rock

    boundaries, to create a lithological profile, to identify rock properties or even the change of

    properties, logging is considered to be a reliable measurement tool. Schon(2011) mentions

    the importance of the procedure how the target formation is evaluated. Logging is followed

    by the data processing including corrections and inversions. He describes the analysis and

    interpretation as a critical stadium as it shows if additional information is needed for any

    further investigations of the data. Characterizing a shale gas reservoir makes it clear that it

    is a highly integrated process. Consequently, studying one single logging tool is not meet-

    ing the complex demands and challenges when it comes to characterizing unconventional

    reservoirs. The continuing development of methods and combined tools proves this ongoing

    trend. Passey et al. (2010) consider a variety of logs essential for shale gas reservoir char-

    acterization. Gamma ray and spectral gamma ray, resistivity, density, sonic, neutron and

    NMR logs are listed to be valuable sources for shale gas reservoir characterization. These

    logs are requested as a minimum standard for possible correlations. For the purpose of cal-

    ibrating logs to TOC the combined porosity/resistivity methods as well as elemental and

    mineralogical logs and borehole image logs can be applied. The complexity of problems to

    characterize shale and the progress in integrating techniques results in the development of

    specific work flows implementing log data. Table 2.3lists logging tools useful for obtaining

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    measured data for shale gas reservoirs. The data is used to derive meaningful information

    based on the response of each tool in gas shales. Authors especially note that each method

    requires rock-to-logs calibration for validation (Sondergeld et al.,2010). Table 2.4refers to

    Fertl and Rieke(1980) andPassey et al. (2010) who summarize the response in gas shales

    from different logging tools. In comparison to Table 2.3,Table 2.4focuses on methods how

    TOC can be estimated from logs.

    Table 2.3: Logging tool response in shale gas reservoirs. Table from Passey et al.(2010)

    Logging tool Response in gas shales

    Natural gamma ray Type II kerogen has anamalously high

    Uranium content.

    Total gamma rayHigh gamma ray in intensity is related to

    anomalously high Uranium content inorganic matter.

    Bulk densityBulk density will read light because

    organic matter is less dense than matrixminerals in source rocks.

    Sonic Organic matter increases the apparent

    transit time of acoustic logs.

    Neutron Organic matter increases apparent

    neutron porosity.

    Resistivity

    Organic matter is non-conductive.Resistivity increases with the presence ofTOC. With maturation and conversion of

    kerogen to hydrocarbons, resistivityincreases dramatically.

    It can be concluded that logging is a reliable method for petrophysical characterization.

    However, only for a minority of wells log measurements suggested by authors are available

    due to cost reasons. The objective of this study is to work with common logs and use them

    together with the rate of penetration to find possible correlations. If a relationship between

    the drilling parameter and the log measurement exists, it can be used as an indicator to

    identify organic-rich zones with a high organic content on a real-time basis while drilling.

    This work is carried out on behalf of the claim stated byKennedy, Gupta and Kotov(2012)

    that especially US operators rely too much on information obtained from the high number

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    Table 2.4: Summary of methods to determine TOC from logs. Table taken in part fromSondergeld et al.(2010)

    Method Description

    Spectral GR - Uranium enrichment Linear relationship of Uranium (ppm) toTOC for Appachian Devonian blackshales.

    Gamma ray intensity Derivation of TOC volume from total GR

    intensity.

    Bulk density Empirical relationship of bulk density to

    TOC weight %.

    Gamma ray intensity - formation density

    Derivation of a TOC volume from therelationship of GR intensity and

    formation density in a Devonian blackshale of the Appalachian basin.

    Delta log R Scaled porosity log resistivity overlay

    method.

    Neural networks Usage of conventional well logs to predict

    TOC.

    Pulsed neutron - spectral gamma rayPulsed neutron mineralogy and spectral

    gamma ray methodology used todiscriminate excess carbon.

    of offset wells being drilled in the major plays. They tend not to invest in any additional

    methods of reservoir characterization. In comparison, countries like China, Latin America

    or Saudi Arabia beginning to enter the area of shale gas development with only limited

    access to offset wells seem to pay more attention to new technologies. The amount of

    data sets generated from each single drilling rig including drilling data records, mudlogs

    and completion and work-over reports on a daily basis raises the question of how this data

    treasury can contribute to optimize reservoir characterization of shale gas reservoirs. Lagreca

    et al.(2008),Staveley and Thow(2010) andIyoho et al.(2004) state that it is still unclear

    how and for what purposes the data should be used for. Considering the amount of drilling

    data and the complexity of shale gas reservoir characterization evokes the idea to search for

    a missing link that provides useful information for future real-time drilling operations and

    improved methods for reservoir characterizations.

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    CHAPTER 3

    METHODOLOGY

    This chapter gives a brief outline of the physical rock properties and their related petro-

    physical interpretation techniques used in this research to convey an integrated work. The

    data analysis part describes the method of the data selection process and how the data was

    processed. It also contains a short theoretical background on why crossplots and regression

    analysis are used to generate the results.

    3.1 Petrophysical Interpretation

    To describe the fundamentals and the theory of nuclear/radioactive and elastic properties

    and their petrophysical interpretation techniques, reference is made to Schon (2011) and

    Krygowski(2003) respectively. Specific technical details about each openhole petrophysical

    measurement introduced in this study are given in B.

    3.1.1 Nuclear/Radioactive Properties

    Considerable and measurable amounts of natural gamma radiation in rocks originate

    from the emitted radiation when the elements uranium, thorium and potassium undergo a

    decaying process. The unit of measurement for the gamma radiation is API units. All three

    elements in sedimentary rocks are found in shale (or clay minerals), particularly uranium.

    Potassium, for example, is found in micaceous clay, thorium in shales and uranium is a good

    indicator for the presence of organic material. Under the assumption that no other radioac-

    tive materials besides shale or clay are present, radiation increases with higher shale content

    in sedimentary rocks. The gamma log is thus regarded as a reliable shale indicator. It

    helps to distinguish between shale/clay and sand layers but also helps to determine the clay

    content and the clay types. In general, the gamma ray measurement is used for correlating

    formations, determining gross lithologies and identifying source rocks. The purpose of using

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    the gamma log in this research is to study the correlation between the gamma ray measure-

    ment for the formation of interest and the rate of penetration for this particular interval. To

    determine the interaction of the emitted gamma radiation from an additional source as part

    of the probe with the rock the photoelectric effect (PE), a supplementary measurement by

    modern density logging tools is used. PE gives information about the mineralogy, i.e. the

    mineral composition and is measured in barns per electron (b/e). Rock forming minerals like

    quartz show typical values of PE=1.81 b/e, calcite of PE=5.08 b/e and dolomite of PE=3.15

    b/e. If the mud contains barite, high PE values of approxiametly 267 b/e are recorded. The

    PE log can give information on whether a change of lithology occured, e.g. dolomite to

    limestone.

    3.1.2 Elastic Properties

    In the context of this study, the theory of elastic wave velocities known as elastic wave

    propagation is described. Equation3.1shows how the compressional or P-wave velocity is

    expressed using elastic moduli like Youngs modulus E, the compressional wave modulusM,

    the bulk compressional modulusk , the shear modulus or Poissons ratio . Equation3.2

    shows likewise for the relationship between the shear or S-wave and the elastic moduli. and are known as the Lame parameters, constants for isotropic material. is the bulk

    density.

    VP =

    M

    =

    E

    1

    (1 +)(12)=

    + 2

    =

    k+ (4/3)

    (3.1)

    VS=

    =E

    12(1 +)

    (3.2)

    The inverse of the compressional velocity and the shear velocity is used to evaluate the

    formation. The inverted velocity is the compressional wave slowness, DTC (3.3) and the

    shear wave slowness, DTS (3.4).

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    tP =DT C=V1P (3.3)

    tS=DT S=V

    1

    S (3.4)

    Velocities are measured in m/s or ft/s whereas the slowness is defined by time over

    distance usually given in s/m or s/ft. The interval transit time, DT is obtained from

    sonic or acoustic logs. As elastic properties are a direct indicator of the rocks properties

    influenced by minerals and fluids present, they are regarded to have an effect on drilling

    parameters measured. However, in the case of sedimentary rocks velocities show a great

    diversity ranging from high for dense rocks with low porosities to low velocities for more

    porous, most likely gas-bearing rocks. For shales the range can go from 1,000-5,000 m/s

    or approxiametly 3,300-16,500 ft/s. In general, velocities tend to decrease with increasing

    clay content influenced by clay-water bonds. It can be concluded that mechanically compact

    material with high elastic moduli results in high velocities and low slowness values and vice

    versa. The relationship betweenVP/VS (3.5) discussed byCastagna, Batzle and Eastwood

    (1985) for seismic applications introducing the concept of the mudrock line (Figure 3.1)

    will also be discussed here. These correlations are purely empirical and formation specific,

    i.e. influenced by the compositon of the rock, porosity and shale content. As both, DTC

    and DTS are available from the sonic/acoustic logs, linear regressions for VP andVScan be

    shown for the wells studied.

    VPVS

    =

    2

    1

    12 (3.5)

    3.2 Real-Time Surface Drilling Data

    During the drilling process, a great data treasury is collected and if analysed in detail,

    useful information from drill cuttings, drilling mud and most important of all, drilling pa-

    rameters is obtained. It is essential to understand how surface drilling data, in this case,

    surface drilling parameters are measured. Conclusions on how drilling parameters as for ex-

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    Figure 3.1: P-wave and S-wave velocities for clay, quartz, calcite and dolomite. Figure fromCastagna, Batzle and Eastwood(1985).

    ample the rate of penetration or weight on bit are effected by the rock penetrated can assist

    in interpreting physical properties of the formation a well is drilled in. Different sensors are

    used to gather surface data at the rig site. Primarily, the rate of penetration is studied as it

    is the only drilling parameter available.

    A depth-tracking sensor is an electronic device that counts the number of rotational

    movements of the sheave when the drilling line moves up or down. Two sensors in an ap-

    proximate distance of 178 cm or 7 in apart, track the movement the draw-work drums make.

    Every count that is recorded by the sensor equals a certain distance traveled and represents

    increasing or decreasing depth movement. In comparison to a depth-based sensor, the time-

    based counter gives either an instantaneous or an average rate of penetration measure in feet

    per hour (ft/hr) or meters per hour (m/hr). No data from drill-monitoring sensors like the

    electronic hook load sensor or the hydraulic torque sensor to measure revolutions per minute

    (RPM), rotary torque and hook load are provided for the studied wells.

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    3.3 Data Analysis

    Out of nine wells, seven wells are presented in this research and all wells studied have

    encrypted names due to confidentiality reasons (Figure 3.2). Two wells, namely AY 1 and

    YR 1-1 are not part of this research as both wells do not have any ROP measurements. Wells

    LK B1H and PE A2H have well log data for the sidetracks (ST). Distances between wells are

    given in (Table 3.1). After Cronquists classification of hydrocarbon fluids (Whitson,1993),

    wells GE A1H, PE A1H and PE A2H are in the black oil window with a condensate/gas

    ratio (CGR) of 570 and above. Well BC 1-1 is in the volatile oil window with a CGR

    range between 313-570, whereas well LK B1H lies between the volatile oil and retrograde

    gas window with 67-312 CGR. RR A3H is in the wet gas window with 10-67 CGR.

    Figure 3.2: Overview of the wells studied located in the Eagle Ford field in McMullen countryin Texas. Scale of the map 1:326,670.

    Well log data were measured by MWD or wireline logging, stored and exchanged as a Log

    ASCII Standard (LAS) file. The log data and the ROP from the depth-tracking sensor were

    merged into one single Excel database to overcome the high number of LAS files for various

    depth intervals displaying measurements taken at varying measurement intervals for each

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    Table 3.1: Measured distances between wells in McMullen country, Texas

    Wells Distance (miles) Distance (kilometers)

    BC 1-1 - GE A1H 24.80 40.0

    BC 1-1 - LK B1H 22.70 36.50BC 1-1 - PE A1H 22.10 35.60BC 1-1 - PE A2H 22.10 35.60BC 1-1 - RR A3H 15.90 25.50BC 1-1 - WL A1H 25.20 40.50

    GE A1H - LK B1H 2.41 3.89GE A1H - PE A1H 3.23 5.20GE A1H - PE A2H 3.23 5.20GE A1H - WL A1H 1.37 2.21LK B1H - PE A1H 2.72 4.38

    LK B1H - PE A2H 2.72 4.38LK B1H - RR A3H 10.80 17.50LK B1H - WL A1H 2.50 4.00RR A3H - PE A1H 8.76 14.00RR A3H - PE A2H 8.76 14.00WL A1H - PE A1H 4.28 6.88WL A1H - PE A2H 4.28 6.88WL A1H - RR A3H 13.00 20.90

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    about changes in drilling parameters are obtained. Additionally, the mudlogs are used for

    comparative reasons (Figure 3.4). As for example, the kickoff point of each well is given

    by both, the daily drilling reports and the mudlogs. Additionally the mudlogs indicate

    graphically with remarks from the geologist whether the well was drilled in rotating or

    sliding mode as indicated byFigure 3.4(b). The daily drilling reports also include comments

    on rotating and sliding mode (Figure 3.4(a)). This information is useful for identifying

    any possible curve misfits between the actual ROP measured and the ROP calculated as a

    function of well log data. Table 3.3summarizes the operational drilling parameters from the

    daily drilling reports. These parameters are reported for the depth intervals considered for

    the regression analysis. The top section of well PE A2H and LK B1H is drilled with a 12

    1/4 in drill bit and water based mud (WBM) whereas the other wells are drilled with oil

    based mud (OBM) for the entire depth interval investigated for the regression analysis.

    (a) Well BC 1-1 (b) Well GE A1H (c) Well PE A2H

    (d) Well LK B1H (e) Well RR A3H (f) Well WL A1H

    Figure 3.3: Wellbore schematic for horizontal wells illustrating information obtained fromdaily drilling reports.

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    3.3.2 Regression Analysis

    Regression analysis is used to quantify the relationship between the rate of penetration

    and various well log measurements. According to Orlov (1996) regression models are an

    accepted method in modern science to study the relationship between variables. To be more

    accurate, the relationship of an independent variable y on numerous independent variables

    xi expressed by the regression function is studied. Unknown parameters bi in the regression

    function are also existant. We distinguish between linear and non-linear regression models

    in case the regression function is non-linear in its parameters. If a regression model has

    multiple independent variables, it is referred to as a multiple linear model, otherwise it is a

    simple linear model. The following notations are directly taken from Orlov(1996).

    y dependent variable (predicted by a regression model)

    y* dependent variable (experimental value)

    p number of independent variables (number of coefficients)

    xi(i=1,2,...p) ith independent variable from total set of p variables

    bi(i=1,2,...p) ith coefficient corresponding to xi

    b0 intercept (or constant)

    k=p+1 total number of parameters including intercept (constant)

    n number of observations ( experimental data points)

    i=1,2. . . p independent variables index

    j=1,2,. . . n data points index

    As we study ROP as a function of different log parameters, the simple linear and the multiple

    linear model are used. Expressing ROP as a function of more than one independent variable,

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    (a) Information from daily drilling reporting on drilling mode (rotating and sliding)

    for the depth interval between 11,654-12,138 ft MD

    (b) Mudlog shows graphically that the wellwas drilled in sliding mode starting at 11,700ft MD

    Figure 3.4: Comparing information from daily drilling reports with information from mud-logs. Figure 3.4(a)shows that the well was drilled in rotating and sliding mode from 11,654-12,138 ft MD.Figure 3.4(b)shows where exactly the well was drilled in sliding mode withinthe depth interval given by the daily drilling report.

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    Table 3.3: Information on drilling parameters from daily drilling report

    Well Depth interval

    (ft MD)

    Bit size (in)/

    Bit model

    Nozzles

    (/32 in)

    WOB

    (1,000 lbf)

    RP

    (rp

    BC 1-1

    5,585-6,486 9 7/8 in, FX 55D 16/16/16/16/16 16 12

    6,486-8,626 9 7/8 in, FX 55D 16/16/16/16/16 10 128,626-10,500 9 7/8 in, FX 55D 16/16/16/16/16 16 12

    10,500-10,954 8 3/4 in, FX 63 16/16/16/16/16 5 0

    10,954-11,434 8 3/4 in, FX 63 16/16/16/16/16 18 5

    11,434-11,947 8 3/4 in, FX 63 16/16/16/16/16 11 5

    11,947-12,042 8 3/4 in, FX 63 16/16/16/16/16 4 5

    PE A2H

    3,003-5,244 12 1/4 in, MD 519 15/15/15/15/15/15/15 7 10

    5,254-6,916 8 1/2 in, SDi 513 no information 10 7

    6,916-8,996 8 1/2 in, SDi 513 no information 10 7

    8,996-10,980 8 1/2 in, SDi 513 no information 15 6

    10,980-11,286 8 1/2 in, SDi 513 no information 15 6

    GE A1H 3,342-5,041 12 1/4 in, MDi 519 13/13/13/13/13/13/13 5 7

    10,617-11,109 8 1/2 in, SDi 513 14/14/14/14/14/14/14 8 6

    LK B1H

    2,174-4,919 12 1/4 in, MSi 616 no information 10 20

    4,919-6,088 12 1/4 in, MSi 616 no information 10 20

    6,088-6,795 8 1/2 in, SDi 513 no information 3 6

    6,795-6,805 8 1/2 in, SDi 513 no information 5 0

    6,805-11,231 8 1/2 in, SDi 513 no information 8/12 0/

    11,231-11,615 8 1/2 in, SDi 513 no information 1 12

    11,615-12,835 8 1/2 in, SDi 513 no information 10 12

    RR A3H

    5,598-7,332 8 1/2 in, SDi 413 15/15/15/15/15/15 8 19

    7,332-10,067 8 1/2 in, SDi 413 15/15/15/15/15/15 12 2010,067-12,285 8 1/2 in, SDi 413 15/15/15/15/15/15 14 20

    12,285-12,580 8 1/2 in, SDi 413 15/15/15/15/15/15 9 20

    WL A1H

    9,369-9,445 8 1/2 in, SDi 513 20/22/20/20 0 0

    9,690-9,708 8 1/2 in, SDi 513 20/22/20/20 10 2

    10,165-10,670 8 1/2 in, SDi 513 20/22/20/20 15 2

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    Equation3.7or Equation3.8is used. For determining ROP as a function of only one simple

    independent variable, Equation3.6 is used.

    y= b0+b1x1 (3.6)

    y= b0+b1x1+b2x2+bpxp (3.7)

    y= b0+i

    bixi, i= 1, 2,...p (3.8)

    The objective of using linear regression models is to predict the experimental or actual

    ROP tracked in the field for each well. By determining the unknown parameters, the calcu-

    lated ROP values should display values close to experimental ROP values. The regression

    analysis is carried out using Microsoft Excel following the steps explained by Orlov(1996).

    In the case of a misfit of the regression curve, possible reasons and the origin of this mismatch

    have to be identified and evaluated.

    To test the accuracy of the regression model representing the experimental data, several

    output options are taken into account, e.g. regression statistics and the analysis of variance

    (ANOVA). Table 3.4 and Table 3.5 are used as a reference to create an overview of the

    outputs generated by Microsoft Excel. The numbers in the parenthesis are not part of the

    output but refer to equations to calculate the regression output variables not stated in this

    research. For further explainations,Gupta(2000) can be used.

    Table 3.4: Formula map of regression statistics output. Table fromOrlov(1996)

    Multiple R (36)R Square (R2) (34)

    Adjusted R Square (Radj2) (35)

    Standard Error (Sy) (33)Observations (n)

    3.3.3 Data Correlations

    To define the set of well log parameters for the regression analysis, two-dimensional

    crossplots are used as a qualitative interpretation tool. These so-called scatter plots are

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    Table 3.5: Formula map of ANOVA output. Table from Orlov(1996)

    Coefficients(bi)

    StandardError (se(bi))

    t Stat(ti)

    P-value

    (Pi)

    Lower 95%(bL,(1Pi))

    Upper 95%(bU,(1Pi))

    Intercept (b0) (26) (25)

    (27) (31) (31a)

    X Variable 1(x1)

    (26) (25)

    (27) (31) (31a)

    X Variable 2(x2)

    (26) (25)

    (27) (31) (31a)

    widely accepted for petrophysical and engineering data interpretation purposes. One variable

    is plotted on the vertical axis (y-axis) and the other on the horizontal axis (x-axis). Any

    third dimension is represented using a color legend. Identical scales for plotting the same

    parameter are used to ensure that comparisons between the plots can be made. To determine

    meaningful relationships, linear and quadratic functions as well as ratios between parameters

    are plotted. As a primary selection criteria, standard logs are used. The gamma log and

    acoustic log was measured for the majority of wells. Both log parameters, gamma ray

    and slowness are expected to correlate well with the rate of penetration. The formation

    density (RHOZ) was only available for three wells whereas well AY 1 did not have ROP

    measurements. RHOZ was therefore not considered for further investigations. For three

    wells - BC 1-1, GE A1H and PE A2H - a complete data set including ROP, GR, DTC and

    DTS is available. Here, multiple linear regression analysis is used. For the wells LK B1H,

    PE A1H, PE A2H ST (sidetrack), RR A3H, WL A1H and WL A1H ST (sidetrack) only

    ROP and GR is available. Simple linear regression is calculated. Table 3.6gives an overview

    of all combinations for each well.

    First, internal log crossplots using two well log parameters like for example DTC on

    the x-axis and DTS on the y-axis to study the quality and internal cosistency of the data

    are generated (Figure 3.5). Although not considered to be directly part of this research,

    these correlations are expected to serve as reference values for any correlations with ROP.

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    Table 3.6: Various combinations for crossplot analysis using well log parameters and ROP

    Parameter on

    x-axis

    Parameter on

    y-axis Color code Well names

    DTC ROP MD BC 1-1, GE A1H, PE A2HDTC ROP GR BC 1-1, GE A1H, PE A2H

    DTS ROP MD BC 1-1, GE A1H, PE A2H

    DTS ROP GR BC 1-1, GE A1H, PE A2H

    DTC2 ROP MD BC 1-1, GE A1H, PE A2H

    DTC2 ROP GR BC 1-1, GE A1H, PE A2H

    DTS2 ROP MD BC 1-1, GE A1H, PE A2H

    DTS2 ROP GR BC 1-1, GE A1H, PE A2H

    DTC DTS MD BC 1-1, GE A1H, PE A2H

    DTC DTS GR BC 1-1, GE A1H, PE A2H

    DTC DTS ROP BC 1-1, GE A1H, PE A2H

    DTC/DTS ROP MD BC 1-1, GE A1H, PE A2H

    DTC/DTS ROP GR BC 1-1, GE A1H, PE A2H

    GR DTC MD BC 1-1, GE A1H, PE A2H

    GR DTC GR BC 1-1, GE A1H, PE A2H

    GR DTC2 MD BC 1-1, GE A1H, PE A2H

    GR DTC2 ROP BC 1-1, GE A1H, PE A2H

    GR DTS MD BC 1-1, GE A1H, PE A2H

    GR DTS GR BC 1-1, GE A1H, PE A2H

    GR DTS2 MD BC 1-1, GE A1H, PE A2H

    GR DTS2 ROP BC 1-1,