columbia river overview superfund process conceptual site models data gap analysis
DESCRIPTION
Columbia River Overview Superfund Process Conceptual Site Models Data Gap Analysis. Woodard & Curran Used a Phased Approach Focusing on Analytes and Areas. Phase 1 - Define study area Phase 2 - Compile existing data Phase 3 - Review existing reports Including relevant risk assessments - PowerPoint PPT PresentationTRANSCRIPT
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▀ Columbia River Overview▀ Superfund Process▀ Conceptual Site Models
▀ Data Gap Analysis
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Woodard & Curran Used a Phased Approach Focusing on Analytes and Areas
Phase 1 - Define study area Phase 2 - Compile existing data Phase 3 - Review existing reports
▀ Including relevant risk assessments
Phase 4 - Screen specific analytes against criteria Phase 5 – Evaluate existing data by area Phase 6 - Identify potential data gaps
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Columbia River Sampling Points
Focus study area -Priest Rapids to McNary Dam
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1964 and 1976 Core Sampling is Instrumental in Understanding Radionuclide Deposition
▀ Nelson/Robertson completed core samples in sediment at downstream dams
▀ Estimated depositional rate shows conflicting timing; not significant to sediment profile
▀ Robertson completed a total inventory of radionuclide in sediment behind McNary Dam
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Estimated Inventories of Radionuclides Behind McNary Dam as Sampled in 1976
Robertson, 1977Data Value in Curies
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Percentage Radionuclides Remaining in 2007 after Half-life Decay
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Cesium-137 Concentrations at Depth Intervals Behind Columbia River Dams
Columbia River Component Data Evaluation Summary Report – July 2006
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Cesium-137 Concentrations Behind Columbia River Dams with Depth
Columbia River Component Data Evaluation Summary Report – July 2006
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Plutonium-239/240 Relative Concentrations Behind Columbia River Dams With Depth
Columbia River Component Data Evaluation Summary Report – July 2006
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Cobalt-60 and Cesium-137 Measurements Behind McNary Dam From 1942 to Present
Columbia River Component Data Evaluation Summary Report – July 2006
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Cobalt-60 Relative Concentrations Behind Columbia River Dams with Depth
Columbia River Component Data Evaluation Summary Report – July 2006
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Support for Priest Rapids Dam to McNary Dam Study Area
▀ Dam Construction vs. Inventory Radionuclide Production▀ Numerous studies demonstrate highest Hanford related inventory
present behind McNary Dam:▀ Nelson 1964 – “…measurements… made indicate that extensive ‘permanent’
sedimentation occurs only in the reservoir of the McNary Dam and in the estuary.”
▀ Robertson 1977 – “…the total inventory of radionuclides in the sediments behind McNary Dam, which has been shown during this and earlier studies to be the major reservoir of residual Hanford origin radionuclides in the Columbia River system.”
▀ WDH 1994 – “In all cases the highest concentrations were found in McNary sediments.”
▀ Cooperative Environmental Monitoring Project 2005 – “The concentrations of most radionuclides in the lower Columbia River sediments were similar to background values measured upstream of the Hanford site.”
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Hanford Reach Cross-Section Study Area Definition
Columbia River
West East
CRC Study Area
Hanford Site
100/300 Study Areaand Inter-Area
Green line
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Hanford Reach Islands
▀ Data Gap focus area includes the islands along the Hanford Reach. Data gaps have been separately addressed for each island based on the following criteria: ▀ Is there a source directly up stream? ▀ Has Island been characterized in previous studies? ▀ Are there potential exposure routes?
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1. Identify human health and ecological screening criteria for surface water and sediments.
Criteria for Identifying Data Gaps Columbia River Corridor
2. Compile comprehensive database and review existing documentation
for CRC.
3. Compare existing data by media and criteria. Do results exceed criteria?
4. Are detections above PQLs?
10. Develop DQO document to adequately evaluate the nature and distribution of COPCs.
9. Is there sufficient data to meet project objectives?
5. Is analyte known site contaminant (e.g., COPC)?
6. Do results exceed upstream or background concentrations?
7. Is source and/or migration of contaminant covered under other Operable Unit?
8. Has media and or analyte been adequately addressed in previous study (e.g., previous risk assessment concluded no unacceptable risk)?
No Additional Data Needed
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Step 1a – Identify Risk Screening Criteria
▀ Existing data was compared against applicable risk criteria by media: ▀ 100/300 Area Risk Assessment▀ USEPA Region 6▀ WDOE CLARC ▀ MCLs▀ NRWQC
Note: Region 10 recommends use of Region 6 screening criteria
No Additional Data Needed
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Step 1a – Human Health Screening Criteria by Media
Sediment Surface Water
Region 6 RBCs Region 6
EPA SSLs MCLs
WDOE CLARCs WDOE CLARCs
DOE NRWQC
DOE
100/300 Area RA 100/300 Area RA
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Step 1b - Identify Ecological Screening Criteria
▀ Existing data is compared against applicable ecological criteria by media: ▀ 100/300 Area Risk Assessment▀ EPA SSLs▀ WDOE CLARCS
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Step 1b - Identify Ecological Screening Criteria by Media
Sediment Surface Water Soil
ODEQ DOE (Oak Ridge) WDOE
USEPA USEPA DOE (Oak Ridge)
ANL ANL CH2M Hill
LANL LANL ANL
OMOE (Canada) LANL
100/300 Area RA 100/300 Area RA 100/300 Area RA
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Step 2 - Compile existing data
▀ Combined three extensive databases▀ WCH CRC data base▀ GiSdt Data 100/300 Area RCBRA Data
Management web-based ▀ USACE data
▀ Totals ▀ Surface water
▀ 5,832 sample locations▀ 54,286 analytical results
▀ Sediment ▀ 2,710 sample locations▀ 40,993 analytical results
No Additional Data Needed
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Existing Biota Data
▀ Several biota sampling events have been completed within the Study Area. These data have been reviewed as part of this data gaps analysis. ▀ Additional biota sampling will be considered during the
DQO process and during the ‘problem formulation phase’ of the Ecological Risk Assessment.
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Step 3 – Data Assessment
▀ Existing data is compared to Human Health and Ecological Screening Criteria:▀ Do analytes exceed applicable HH or
Eco criteria?▀ Yes = retain for further evaluation▀ No = not a data gap
No Additional Data Needed
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Step 4 – Review Data for QA/QC
▀ Results are compared to laboratory QA/QC▀ Are detections above PQLs and
exceed applicable HH or Eco criteria? ▀ Yes = retain for further evaluation ▀ No = retain for further evaluation
▀ Was analyte reported in laboratory blank? ▀ Yes = possible laboratory contaminant▀ No = retain for further evaluation
No Additional Data Needed
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Step 5 –Site Related Contaminant
▀ Based on previous sampling results or operational history, is analyte known to be site-related? ▀ Yes = COPC and retain for further
evaluation▀ No = not a data gap
▀ If frequency of detection is less than 5% excluded compound; not a data gap (EPA RAGs, 1989)
No Additional Data Needed
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Step 6 – Background Results
▀ When sample results are compared to background or upstream results, do results exceed average background conditions? ▀ Yes = COPC and retain for further
evaluation ▀ No = not a data gap
No Additional Data Needed
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Step 7 – Covered Under Other Study Areas and Other Assessments
▀ Is source and/or migration of contaminant covered under study area and other assessments? ▀ Yes = not data gap ▀ No = COPC and retain for further
evaluation
No Additional Data Needed
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Step 8 – Already Addressed
Has media and or analyte been adequately addressed in previous study?▀ Yes = not data gap ▀ No = COPC and retain for further
evaluation
No Additional Data Needed
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Step 9 – Identified as Data Gap
Is there sufficient data to meet project objectives?
▀ Yes = not data gap ▀ No = continue to DQO process
No Additional Data Needed
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Step 9 – Identified as Data Gap
Data gaps fall within two categories:
1. Areas or analytes that have not been previously studied. Example: areas along the east side of the river.
2. Areas that need additional data to meet DQOs development
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Step 10 – Develop DQOs
▀ Identified data gaps will need to be addressed. ▀ To ensure data collected meets the
needs of its intended end use, a data quality objective analysis will be completed for all identified data gaps.
No Additional Data Needed
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Data Assessment Results – Sediments - Inorganics
Human Health AluminumAntimonyArsenicBariumBerylliumBoronCadmiumChromiumCobaltCopperFluorideHexavalent-ChromiumIronLeadManganeseMercuryMolybdenumNickelNitrogen in NitrateNitrogen in NitriteSeleniumSilverStrontium (elemental)ThalliumUraniumVanadiumZinc
List of COPCs
Ecological AluminumAntimonyArsenicBariumBerylliumCadmiumChromiumCopperHexavalent-ChromiumIron ManganeseLeadLithiumMercuryMolybdenumNickelSeleniumSilverThalliumZinc
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Elements That Exceed Screening Criteria
Ecological
AluminumAntimonyBariumCadmiumManganese NickelSilverZinc
Data Assessment Results – Sediments - Inorganics
Human Health
AntimonyArsenicChromiumIronManganeseVanadium
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Elements That Exceed Screening Criteria and Background
Data Assessment Results – Sediments - Inorganics
Ecological
AntimonyBariumCadmiumManganese NickelZinc
Human Health
ArsenicChromiumManganese
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Potential Inorganic Sources - Sediments
Inorganics Source Site Natural Fallout Irrigation Upstream
Arsenic X X X X
Barium X X X
Cadmium X X
Chromium X X
Manganese X X
Nickel X X
Zinc X X X
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CSM Inorganic Sources - Sediments
Site-RelatedArsenicBariumChromiumManganese
Upstream and NaturalIrrigationArsenicBariumZinc
ArsenicCadmiumManganeseNickelZinc
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Data Assessment Results – Sediments - Organics List of COPCs
AcenaphtheneAcenaphthyleneAcetoneAldrinAnthraceneAroclor 1242Aroclor 1248Aroclor 1254Aroclor 1260Aroclor 1262BenzeneBenzo(a)anthraceneBenzo(a)pyreneBenzo(b)fluorantheneBenzo(ghi)peryleneBenzo(k)fluorantheneAlpha-BHCbeta-1,2,3,4,5,6-HexachlorocyclohexaneDelta-BHCBis(2-ethylhexyl) phthalate1-Butanol2-Butanone2-ButoxyethanolButylbenzylphthalate2-secButyl-4,6-dinitrophenol(DNBP)CarbazoleCarbon disulfideCarbon tetrachlorideCyanide
Human Health EcologicalAcenaphtheneAcenaphthyleneAnthraceneBenzo(a)anthraceneBenzo(a)pyreneBenzo(b)fluorantheneBenzo(ghi)peryleneBenzo(k)fluorantheneChryseneFluorantheneFluoreneIndeno(1,2,3-cd)pyreneNaphthalenePhenanthreneAroclor-1248Aroclor-1254Aroclor-1260AldrinAlpha-BHCalpha-Chlordanebeta-1,2,3,4,5,6-HexachlorocyclohexaneDelta-BHCDichlorodiphenyldichloroethaneDichlorodiphenyldichloroethyleneDichlorodiphenyltrichloroethaneDieldrin
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ChlordaneChloroformChryseneDalaponDicambaDichlorodiphenyldichloroethaneDichlorodiphenyldichloroethyleneDichlorodiphenyltrichloroethane2,4-Dichlorophenoxyacetic acid4-(2,4-Dichlorophenoxy)butanoic acidDibenz[a,h]anthraceneDibenzofuranDi-n-butylphthalate1,4-Dichlorobenzene1,2-Dichloroethanecis-1,2-DichloroetheneDichloropropDieldrinDiethyl etherDiethylphthalateDi-n-octylphthalateEndosulfan IEndosulfan IIEndosulfan sulfateEndrinEndrin aldehydeEndrin ketoneEthylene glycolFluoranthene
Endosulfan IEndosulfan IIEndosulfan sulfateEndrin aldehydeEndrin ketonegamma-ChlordaneHeptachlorHeptachlor epoxideMethoxychlor2-MethylnaphthaleneBis(2-ethylhexyl) phthalateCarbazoleDibenzofuranDiethylphthalateDi-n-butylphthalatePhenolPentachlorophenolFluorideNitrogen in NitrateNitrogen in Nitrite
List of COPCs (continued)
Human Health EcologicalFluoreneHeptachlorHeptachlor epoxideIndeno(1,2,3-cd)pyreneIsophoroneMethoxychlorMethyl isobutyl ketoneMethylenechloride2-Methylnaphthalene3+4 Methylphenol (cresol, m+p)NaphthalenePentachlorophenolPhenanthrenePhenolPicloramPyrene1,1,2,2-TetrachloroethaneTetrachloroetheneTolueneTrichloroetheneTrichloromonofluoromethane2,4,5-Trichlorophenoxyacetic acid2-(2,4,5-Trichlorophenoxy)propionic acid
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Benzo(a)pyrene*Benzo(a)anthracene*Benzo(b)fluoranthene*Benzo(k)fluoranthene*Dibenz(a,h)anthracene*Cyanide*
Compounds That Exceed Screening Criteria
* detected at less than 5% and are not from on-site sources, therefore eliminated as data gaps.
Human Health EcologicalEndosulfan IEndosulfan II
Data Assessment Results – Sediments - Organics
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▀ No Data Gaps▀ PCB Discussion
Data Assessment Results – Sediments - Organics Compounds That Exceed Screening Criteria and Background
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PCB Discussion
▀ PCB results are all non-detect in sediment and surface water
▀ PCBs detection level is higher than screening level▀ PCBs were used in localized areas at Hanford Reservation▀ PCB issue will be addressed in the 100/300 Area risk
assessment▀ PCBs have been detected in fish in the Columbia River▀ PCB congener data may be a data gap – will be discussed
during DQO process
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Americium-241 Carbon-14Cesium-137Cobalt – 60Europium-152 Europium-154Europium-155Nickel-63Plutonium 238Plutonium-239/240Plutonium-241Potassium-40Radium-226Radium-228Strontium-90TritiumThorium-228Thorium-232Uranium-233/234Uranium-234Uranium-235Uranium-238
Data Assessment Results – Sediments - Radionuclide List of COPCs
Human Health EcologicalAmericium-241 Carbon-14Cesium-137Cesium-134Cobalt – 60Europium-152 Europium-154Europium-155Nickel-63Plutonium 238Plutonium-239/240Plutonium-241Potassium-40Radium-226Radium-228Strontium-90TritiumThorium-228Thorium-232Uranium-233/234Uranium-235Uranium-238
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Cesium-137Cobalt-60Europium-152Strontium-90Thorium-232Uranium-234Uranium-238
Data Assessment Results – Sediments - Radionuclide Compounds That Exceed Screening Criteria
Human Health EcologicalEuropium-152*
* maximum concentrations reported above Ice Harbor Dam
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Cobalt-60Europium-152Thorium-232Uranium-234Uranium-238
No data gaps
Human Health: Ecological:
Data Assessment Results – Sediments - Radionuclide Compounds That Exceed Screening Criteria and Background
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Potential Radionuclide Sources - Sediments
Radionuclides Source Site Natural Fallout Irrigation Upstream
Cobalt-60 X
Europium-152 X X X
Thorium - 232 X
Uranium-234 X X
Uranium-238 X X
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CSM Radionuclide Sources - Sediments
Site-RelatedCO-60EU-152Thorium-232U-234U-238
Upstream and Natural
Europium-152U-234U-238
AtmosphericFallout
Europium-152
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Aluminum AntimonyArsenic BariumBerylliumBoronCadmiumChromiumCobaltCopperHexavalent-ChromiumIronLeadLithiumManganeseMolybdenumNickelSeleniumSilverStrontiumThalliumTin TitaniumVanadiumZinc
Data Assessment Results – Surface Water- Inorganics
Human Health Ecological
List of COPCs
AluminumAntimonyArsenic BariumBerylliumCadmiumChromiumCobaltCopperCyanideIronHexavalent-ChromiumLeadManganeseMercuryNickelSelenium SilverThalliumTin UraniumVanadiumZinc
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AntimonyArsenicBerylliumCopperLeadThallium
Aluminum AntimonyBariumBerylliumCadmiumChromiumCopperCyanideIronLeadManganeseMercurySeleniumSilverUraniumVanadiumZinc
Data Assessment Results – Surface Water- InorganicsCompounds That Exceed Screening Criteria
Human Health Ecological
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AntimonyArsenic
Data Assessment Results – Surface Water- InorganicsElements That Exceed Screening Criteria and Background
Human Health Ecological
Aluminum BariumCadmiumChromiumCopperLeadManganeseZinc
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Potential Inorganic Sources – Surface Water Inorganics Source Site Natural Fallout Irrigation Upstream
Aluminum x x
Antimony x
Arsenic x x x x
Barium x x x
Cadmium x xChromium x xCopper x
Lead xManganese x x
Zinc x x
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AcenaphtheneAcenaphthyleneAnthraceneBenzo(a)anthraceneBenzo(a)pyreneBenzo(b)fluorantheneBenzo(ghi)peryleneBenzo(k)fluorantheneChryseneFluorantheneFluoreneIndeno(1,2,3-cd)pyreneNaphthalenePhenanthreneAroclor-1248Aroclor-1254Aroclor-1260AldrinAlpha-BHCalpha-Chlordane
Data Assessment Results – Surface Water - OrganicsList of COPCs
Human Health Ecological:AcenaphtheneAcenaphthyleneAnthraceneBenzo(a)anthraceneBenzo(a)pyreneBenzo(b)fluorantheneBenzo(ghi)peryleneBenzo(k)fluorantheneChryseneCyanideFluorantheneFluoreneIndeno(1,2,3-cd)pyreneNaphthalenePhenanthreneAroclor-1248Aroclor-1254Aroclor-1260AldrinAlpha-BHCalpha-Chlordane
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beta-1,2,3,4,5,6-HexachlorocyclohexaneDelta-BHCDichlorodiphenyldichloroethaneDichlorodiphenyldichloroethyleneDichlorodiphenyltrichloroethaneDieldrinEndosulfan IEndosulfan IIEndosulfan sulfateEndrin aldehydeEndrin ketonegamma-ChlordaneHeptachlorHeptachlor epoxideMethoxychlor2-MethylnaphthaleneBis(2-ethylhexyl) phthalateCarbazoleDibenzofuranDiethylphthalateDi-n-butylphthalatePhenolPentachlorophenolFluorideNitrogen in NitrateNitrogen in Nitrite
List of COPCs (continued)
Human Health Ecologicalbeta-1,2,3,4,5,6-HexachlorocyclohexaneDelta-BHCDichlorodiphenyldichloroethaneDichlorodiphenyldichloroethyleneDichlorodiphenyltrichloroethaneDieldrinEndosulfan IEndosulfan IIEndosulfan sulfateEndrin aldehydeEndrin ketonegamma-ChlordaneHeptachlorHeptachlor epoxideMethoxychlor2-MethylnaphthaleneBis(2-ethylhexyl) phthalateCarbazoleDibenzofuranDiethylphthalateDi-n-butylphthalatePhenolPentachlorophenolFluorideNitrogen in NitrateNitrogen in Nitrite
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CSM Inorganic Sources – Surface Water
Site-RelatedArsenicBariumChromiumManganese
Upstream and Natural
AluminumAntimonyArsenicBariumCadmiumLeadManganeseZinc
Irrigation
AluminumArsenicBariumCadmiumZinc
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DichlorodiphenyldichloroethyleneDieldrin1,1,2- trichloroethane1,2-dichloroethane ChloroformBis(2-ethylhexyl)phthalate
Data Assessment Results – Surface Water - Organics
Human Health Ecological
Compounds That Exceed Screening Criteria
CyanideMethoxychlor TPH
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1,1,2- trichloroethane1,2-dichloroethane Chloroform
Data Assessment Results – Surface Water - OrganicsCompounds That Exceed Screening Criteria and Background
Human Health EcologicalNo Data Gaps
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Potential Organic Sources – Surface Water
Organics Source
Site Natural Fallout Irrigation Upstream
1,1,2-trichloroethane X
1,2-dichloroethane X
Chloroform X
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CSM Organic Sources – Surface Water
Site-Related (300 Area Only)1,1,2 – TCA1,2 – DCAChloroform
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Americium-241Cesium-137Europium-154Strontium-90Thorium-232TritiumUranium-234Uranium-235Uranium-238
Data Assessment Results – Surface Water - Radionuclide
List of COPCs
Human Health Ecological
Cesium-134 Cesium-137Plutonium-239/240Potassium-40Radium-226Radium-228Strontium-90Thorium-228Thorium-232Uranium-233/234Uranium-235Uranium-238
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Americium-241Cesium-137Europium-154Strontium-90Thorium-232TritiumUranium-234 Uranium -238
Data Assessment Results – Surface Water - Radionuclide
Elements That Exceed Screening Criteria
Human Health Ecological:
Cesium-134Radium-226Radium-228Uranium-238
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Strontium-90TritiumUranium-234Uranium-238
Data Assessment Results – Surface Water - Radionuclide
Elements That Exceed Screening Criteria and Background
Human Health: Ecological:None
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Potential RadionuclideSources – Surface Water
Radionuclides Source
Site Natural Fallout Irrigation Upstream
Strontium-90 X X
Tritium X X X
Uranium-234 X X
Uranium-238 X X
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CSM Radionuclide Sources – Surface Water
Naturally Occurring
TritiumU-234U-238
Site-RelatedStrontium-90TritiumU-234U-238
Atmospheric FalloutSR-90Tritium
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Sediment Data Gap Summary -Inorganics
Metal Human Health Ecological
Antimony X
Arsenic X
Barium X
Chromium X
Cadmium X
Manganese X X
Nickel X
Zinc X
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See Map Package #1
Sediment Data Gap Summary -Inorganics
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Inorganics Human Health Ecological
Aluminum X
Antimony X
Arsenic X
Barium X
Cadmium X
Chromium X
Copper X
Manganese X
Lead X
Zinc X
Surface Water Data Gap Summary -Inorganics
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Surface Water Data Gap Summary -Inorganics
See Map Package #2
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Compound Human Health Ecological
None None None
Sediment Data Gap Summary -Organics
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Compound Human Health Ecological
1,1,2-trichloroethane X None
1,2-dichloroethane X None
Chloroform X None
Surface Water Data Gap Summary -Organics
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Surface Water Data Gap Summary-Organics
See Map Package #3
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Element Human Health Ecological Cobalt-60 X
Thorium-232 X
Uranium-234 X
Uranium-238
Europium-152
X
X
Sediment Data Gap Summary -Radionuclide
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Sediment Data Gap Summary -Radionuclide
See Map Package #4
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Element Human Health Ecological Strontium-90 X
Tritium X
Uranium-234
Uranium-238
X
X
Surface Water Data Gap Summary -Radionuclide
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Surface Water Data Gap Summary -Radionuclide
See Map Package #5
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Potential Data Gaps to Discuss During DQO Process
▀ Sediment and Surface Water sampling on the east side of river.
▀ Sediment sampling at previously uncharacterized islands
▀ PCB congener sampling (pending outcome of 100/300 risk assessment)
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Next Steps / Path Forward
Closing Statements / Feedback