co ordination compound
TRANSCRIPT
-
8/15/2019 Co Ordination Compound
1/23
-
8/15/2019 Co Ordination Compound
2/23
-
8/15/2019 Co Ordination Compound
3/23
KO- OSEIFDUIOF KOAZO\FE[ ;
www.tgifmiit.if
(k) Flutrdh hi`dfes drl fdale ds sukg
Ltgyhlfleidaifl
K>G
<F Zyrieifl
(K>G
<)
;Z Uripglfyhpgospgifl
Cut - nor G3O wl wihh writl dquo.
FG;
Daaifl
KO Kdrcofyh
Fo FitrosyhFdal on tgl einnlrlft hi`dres if tgl sdal koaphlx koapoufe wihh cl if dhpgdcltikdh orelr.
• Zrlnix aofo, ei, tri ltk. drl usle to ifeikdtl tgl fuaclr on ifeivieudh hi`dfes if tgl koaphlx. In tglhi`dfe is d koaphlx aohlkuhl tglf nor two hi`dfes wl writl cis. [iaihdrity nor tgrll koaphlx hi`dfes wlwritl tris dfe nor nour koaphlx hi`dfes wl wihh writl tltrdmis. Dntlr writtif` cis, tris or tltrdmis wl writltgl fdal on hi`dfe if pdrlftglsls.Lxdaphl (d) ]Ko(lf)
;QKh
;1
Fdal wihh cl Uris (ltgyhlfl eidaifl) kocdht(III) kghoriel.
• Oxiedtiof stdtl on altdh if kdtiof, dfiof or flutrdh koaphlx is ifeikdtle cy roadf fualrdh ifpdrlftglsls.
I[OALSI[A IF KOOSEIFDUIOF KOAZO\FE[Koapoufes gdvif` sdal aohlkuhdr norauhd cut einnlrlft strukturls drl kdhhle isoalrs dfe tglpglfoalfof is mfowf ds isoalrisa. Isoalrs drl eiviele ifto two kdtl`orilsv. [trukturdh isoalrs
i. Iofisdtiof isoalrsii. Kooreifdtiof isoalrsiii. Hifmd`l isoalrs
w. [tlrlo isoalrs
[US\KU\SDH I[OALS[Iofizdtiof isoalrsKoapoufes wgikg gdvl sdal aohlkuhdr norauhd cut ̀ ivl einnlrlft iofs if sohutiof drl kdhhle iofizdtiofisoalrs.Lxdaphl]Ko(FG
;)
<CrQ3+ [O
5
3-
Croao plftdaaifl kocdht (III) suhpgdtl (^oihlt kohour)]Ko(FG;)
<[O
5Q+ Cr -
[uhpgdtohlftdaaifl kocdht (III) Croaiel (rle kohour)If tgl dcovl lxdaphl tgl viohlt kohour koapoufe ̀ ivls [O
5
3- iof if sohutiof dfe rle kohour koapoufe`ivls Cr - iof if sohutiof. Cotg koapoufes drl gdvif` sdal aohlkuhdr norauhdl. Ugly drl kdhhleiofizdtiof isoalrs.
Kooreifdtiof isoalrsUgis typl on isoalrisa okkurs wglf cotg tgl kdtiof dfe dfiof drl koaphlxls.Nor lxdaphl -]Ko(lf)
;Q ]Kr(KF)
>Q dfe ]Kr(lf)
;Q ]Ko(KF)
>Q
Glrl hi`dfes drl iftlrkgdf`le cut cotg koapoufes drl gdvif` sdal aohlkuhdr norauhd. Fdal on
]Ko(lf) ; Q ]Kr(KF) >QUris (ltgyhlfl eidaifl) Kocdht (III) glxd kydfo kgroadte (III).[iaihdrhy fdal on ]Kr(lf)
;Q ]Ko(KF)
>Q is tris (ltgyhlfs eidaifl) kgroaiua (III) glxdkydfo kocdhtdtl
(III).
-
8/15/2019 Co Ordination Compound
4/23
KO- OSEIFDUIOF KOAZO\FE[ 5
www.tgifmiit.if
Hifmd`l isoalrsUgus typls on isoalrs drl octdifle wglf ofl hi`dfe dttdkgle witg klftrdh altdh dtoa if two wdys.Nor lxdaphl FO
3
- if d hi`dfe dfe it kdf dttdkg to klftrdh altdh dtoa tgrou`g fitro`lf or oxy`lf. In itis cofe tgrou`g fitro`lf strukturl on
hì dfe wihh cl dfe in it is tgrou`g O, tglf strukturl on hi`dfe wihh cl - O - F 1 O.
Lxdaphl 2 ]Ko(FG;)
<FO
3QKh
3 dfe ]Ko(FG
;)
<OFOQKh
3
Fdal on nirstofl is plftdaififl fitro kocdht (III) kghoriel dfe fdal on slkofe koapoufe is plftdaaiflfitrito kocdht (III) kghoriel.Ugl ufielftdtl hi`dfes wgikg kdf cife to tgl klftrdh altdh dtoa tgrou`gtwo possichl eofor dtoas drl dhso kdhhle dacielft hi`dfes. [oal lxdaphls drl ds ufelr
[tlrlo isoalrs[tlrloisoalrs drl tgosl isoalrs wgikg gdvl tgl sdal positiof on dtoas or `roups cut tgly einnlr iftgl spltidh drrdf`lalfts droufe tgl klftrdh altdh dtoa. Ugly drl on two typlsx. @loaltrikdh isoalrsy. Optikdh isoalrs
@LOALUSIKDH I[OALS[In tgl sdal mife on hi`dfes okkupy positiof debdklft to ldkg otglr it is kdhhle kis nora dfe in tglhi`dfes drl oppositl to ldkg otglr it is kdhhle trdfs nora.]Zt(FG
;)
3Kh
3Q lxist if kis dfe trdfs noras
kis nora trdfs nora[qudrl phdfdr koaphlxls sgow tgis typl on isoalrisa. Ultrdglerdh koaphxls eo fot sgow `loaltrikdhisoalrisa clkdusl tgl rlhdtivl positiof on hi`dfes witg rlsplkt to ldkg otglr wihh cl tgl sdal. Oktdglerdhkoaphlxls witg kooreifdtiof fuaclr six dhso lxist if kis dfe trdfs nora. Pl kdf tdml df lxdaphl on ]KO(FG
;)
5Kh
3Q+
Optikdh isoalrs
Ugis typl on isoalrisa is lxgicitle cy tgl kgirdh aohlkuhls i.l aohlkuhls wgikg eo fot gdvl phdfl on
syaaltry. Uglsl isoalrs drl fof-suplriaposdchl airror iad`ls on ldkg otglr. Ugly drl optikdhhy
dktivl dfe rotdtl tgl phdfl on pohdrizle hi`gt lqudhhy cut if oppositl eirlktiofs.
Ugl isoalrs wgikg rotdtl tgl phdfl on pohdrisle hi`gt towdres ri`gt is kdhhle elxtrorotdtory (e) dfe
isoalrs wgikg rotdtl tgl phdfl on pohdrisle hi`gt towdres hlnt is kdhhle hdlvordtory (h)
-
8/15/2019 Co Ordination Compound
5/23
KO- OSEIFDUIOF KOAZO\FE[ <
www.tgifmiit.if
Koaphlxls witg kooreifdtiof fuaclr six gdvif` cielftdtl hi`dfes proviel lxdaphl on optikdh isoalrisa.
Lxdaphl ]Ko(lf);Q;+ kdf cl writtlf if tgl nohhowif` wdy
]Ko(lf);Q;+ lxist if elxtro dfe hlvo nora. Its
kofni`urdtiof wihh cl ds ufelr.
e dfe h nora on isoalrs drl kdhhle lfdftioalrs.
COFEIF@ IF KOOSEIFDUIOF KOAZO\FE[Plrflr wds tgl nirst to lxphdif tgl cofeif` if kooreifdtiof koapoufes. Gowlvlrs witg tgl elvlhopalfton aoelrf tglorils himl vdhdfkl cofe tglory, hi`dfe nilhe tglory aohlkuhdr orcitdh tglory, it gds cllf
possichl to lxphdif tgl proplrtils on tglsl koapoufes sukg ds kohour, ̀ loaltry dfe ad`fltik proplrtilsltk. Glrl wl wihh eiskuss vdhlfkl cofe tglory wgikg is vlry siaphl. Ugis wds proposle cy Zduhif`.Dkkoreif` to Zduhif`, tgl altdh dtoa or iof kdf usl tgl ;e, 5s, 5p orcitdh nor gycrieizdtiof to yilhe dslt on lquivdhlft orcitdhs on elnifitl `loaltry himl squdrl phdfdr, tltrdglerdh, oktdglerdh dfe so of.Uglsl gycrieizle orcitdhs drl dhhowle to ovlrhdp witg tgosl hi`dfes orcitdhs tgdt kdf eofdtl df lhlktrofpdir nor cofeif`. Glrl, it ady cl fotle tgdt e orcitdh ifvohvle if tgl gycrieizdtiof ady cl litglr ifflre orcitdhs i.l. (f-4)e or outlr e orcitdh i.l fe. Nor lxdaphl if tgl kdsl on oktdglerdh gycrieizdtiof itady cl e 3sp ; or sp ; e 3
okkupy tgl six gycrie orcitdhs. Ugl prlslfkl on tgrll ufpdirle lhlktrofs if tgl rladifif` orcitdh on Kr(III) admls tgl koaphlx iof or koapoufe if pdrdad`fltik if fdturl.(c) Fi(KO)
5 Ultrd Korcofyh Fikmlh(O)
-
8/15/2019 Co Ordination Compound
6/23
KO- OSEIFDUIOF KOAZO\FE[ >
www.tgifmiit.if
glrl dtoaik fuaclr on Fi is 37 dfe oxiedtiof stdtl on Fi if Fi(KO)5 is zlro.
If tgl dcovl koapoufe s dfe p orcitdh on Fi gycrieizle ds sp ; to ̀ ivl nour lquivdhlft orcitdhs, drrdf`letltrdglerdhhy. Ldkg KO ̀ roup (hi`dfe) eofdtl d pdir on lhlktrof to nora tltrdglerdh koaphlx. Ad`fltikstueils rlvldh tgdt tgl koapoufe is eidad`fltik if fdturl dfe tgus supports tgl norkle pdirif` on 5slhlktrofs witg ;e lhlktrofs.
tgl koaphlx iof ]Fi(KF)5Q3- is eidao`fltik ds sllf nroa tgl dcslfkl on ufpdirle lhlktrofs. Koapoufe
gds squdrl phdfdr `loaltry.
[UDCIHIUY ON KOOSEIFDUIOF KOAZO\FE[ Ugl noradtiof on d kooreifdtiof koapoufes ifvohvltgl rldktiof cltwllf d altdh or altdh iof dfe hi`dfes. In tgl norkl or cofeif` cltwllf altdh iof dfehi`dfe is strof`, tglf wl `lt d stdchl koaphlx. @lflrdhhy koaphlx iofs drl gi`ghy stdchl. Cut soaltials koaphlx iofs ady eissokidtl to d sadhh lxtlft.Ugl rldktiof cltwllf altdh dfe d hi`dfe kdf cl
rlprlslftle cy tgl nohhowif` lquhhicriua.
glrl Ms is kdhhle stdcihity kofstdft. In tgl vdhul on Ms is aorl tglf it kdf cl sdie tgdt koaphlx iof isaorl stdchl. Ugl ad`fituel on tgl stdcihity kofstdft ̀ ivls df ifeikdtiof on tgl stdcihity on tgl koaphlxls
if sohutiof.
-
8/15/2019 Co Ordination Compound
7/23
KO- OSEIFDUIOF KOAZO\FE[ 0
www.tgifmiit.if
glrl Ms nor ]Ku(KF)5Q3- is vlry gi`g dfe ifeikdtls tgdt koaphlx ]Ku(KG)
5Q3- is aorl stdchl tgdf
]Ku(FG ; ) 5Q3+ glrl KF - is d rlhdtivlhy strof`lr hi`dfe tgdf FG ; dfe tgus noras aorl stdchl koaphlx.In tgl kgdr`l elfsity oa tgl klftrdh altdh iof is aorl, tglf it wihh nora d stdchl koaphlx.[iaihdrhy aorl cdsik hi`dfe wihh nora aorl stdchl koaphlx iof clkdusl tgly kdf eofdtl tgl lhlktrofldsihy.
DZZHIKDUIOF ON KOOSEIFDUIOF KOAZO\FE[ Kooreifdtiof koapoufes nife adfy dpphikdtiofif our hinl. Ugl dcihity on altdh iofs to nora koaphlxls witg einnlrlft aohlkuhls (hi`dfes) gdvl einnlrlftpgysiko-kglaikdh proplrtils wgikg kdf cl usle if adfy wdys.z. Gdreflss on wdtlr is lstiadtle cy siaphl titrdtiof witg LEUD. Ugl Kd 3+ dfe A` 3+ iofs norastdchl koaphlxls witg LEUD. Ds tgl stdcihity kofstdfts on kdhkiua dfe ad`flsiua koaphlxls on LEUDdrl einnlrlft, slhlktivl lstiadtiof on tglsl iofs is possichl.
dd. Adfy kooreifdtiof koaphlxls drl usle ds lhlktrohytls nor lhlktrophdtif`. Uglsl koaphlxlselhivls tgl altdh iofs if koftrohle adfflr. Nor lxdaphl, nor sihvlr phdtif` tgl koaphlx M]D`(KG)
3Q is
usle.cc. [ihvlr dfe `ohe drl lxtrdktle nroa tglir rlsplktivl orls cy trldtalft witg FdKF sohutiof.D` + (dq) + 3FdKF(dq) ―――6 Fd]D`(KF)
3Q(dq) + Fd +
Du + (dq) + 3FdKF(dq) ―――6 Fd]Du(KF)3Q(dq) + Fd +
kk. Fi 3+ iofs drl lstiadtle ds tglir ule koaphlx witg eialtgyh ̀ hyoxial (EA@). Kd 3+ dfe A` 3+ iofsdrl lstiadtle ds tglir koaphlxls witg KEUD.Ugl koaphlx on Kd 3+ witg LEUD is usle to trldt hldepoisiofif`. Ifsiel tgl coey kdhkiua if tgl koaphlx is rlphdkle cy Zc dfe aorl stdchl Zc - LEUDkoaphlx is lhiaifdtle tgrou`g urifl.
ee. Ugl Zt koaphlx kis phdtif kis - ]Zt(FG;)
3Kh
3Q is usle ds df dftituadr d`lft if tgl trldtalft on
kdfklr.
ll. Adfy cioho`ikdh iaportdft fdturdh koapoufes lxist ds kooreifdtiof koaphlxls. Nor lxdaphlKghoropgyph - d koaphlx on A` 3+
Gdlao`hocif - d koaphlx on Nl 3+
^itdaif C43 - d koaphlx on KO 3+
KOAZO\FE[ KOFUDIFIF@ ALUDH KDSCOF COFEOr`dfoaltdhhik koapoufes gdvl ofl or aorl altdh kdrcof cofes. Ugus koapoufes wgikg drl gdvif`altdh kdrcof cofes drl kdhhle or`dfo altdhhik koapoufe. Ugl koapoufes on altdhhoies sukg ds @l,
[c dfe fof- altdhhik lhlalfts sukg ds C dfe [i drl dhso ifkhuele ufelr tgis khdssinikdtiof. Adfyor`dfo altdhhik koapoufes drl iaportdft rld`lfts wgikg drl usle nor tgl syftglsis on or`dfikkoapoufes.Or`dfoaltdhhik koapoufes drl on two typlsnn. ϋ cofele koapoufes``. ϊ cofele koapoufes.gg ϋ cofele koapoufes If tglsl koapoufes or`dfik ̀ roup is cofele to d altdh dtoa tgrou`gd foradh 3 lhlktrof kovdhlft cofe. [oal lxdaphls drl
-
8/15/2019 Co Ordination Compound
8/23
-
8/15/2019 Co Ordination Compound
9/23
-
8/15/2019 Co Ordination Compound
10/23
KO- OSEIFDUIOF KOAZO\FE[ 4:
www.tgifmiit.if
5. Zrlpdrdtiof on altdh kdrcofyhs - Niflhy eiviele Fi rldkts witg KO dt rooa tlaplrdturl to noraFi(KO)
5.
Fi + 5KO ―――6 Fi(KO)5
Irof rldkts witg KO dt gi`g tlaplrdturl dfe prlssurl. Nl +
-
8/15/2019 Co Ordination Compound
11/23
KO- OSEIFDUIOF KOAZO\FE[ 44
www.tgifmiit.if
[OH^LE ZSOCHLA[T.4 Elnifl tgl tlras2 kooreifdtiof lftity, klftrdh altdh, hì dfe, eofor dtoa, kooreifdtiof fuaclr
dfe oxiedtiof fuaclr.Dfs. (i) Kooreifdtiof lftity. It kofstitutls d klftrdh altdh dt dtoa / iof, `lflrdhhy on d altdh, to wgikg
drl dttdkgle d nixle fuaclr on otglr dtoas or `roups ldkg on wgikg is kdhhle d hi`dfe. It ady cl dflutrdh or d kgdr`le splkils. l.`.]Ko(FG ; ) >Q
;+ , ]ZtKh 5 Q3‛ , ]Nl(KF) >Q
;‛ , ]FiKh 3(G 3O) 5Q ltk.
(ii) Klftrdh altdh. It is tgl dtoa or iof if d koaphlx to wgikg d nixle fuaclr on hi`dfes drl cofeleif d elnifitl `loaltrikdh drrdf`lalft droufe it l.`. if ]Nl(KF) >Q
5‛ , tgl klftrdh altdh iof is Nl 3+ .(iii) Hi`dfes. It is df iof or d aohlkuhl tgdt is coufe to tgl klftrdh altdh dtoa or iof on tgl koaphlx.It `lflrdhhy gds d hofl pdir on lhlktrofs l.`. Cr ‛ , Kh‛ , KF ‛ , OG ‛ , O 3‛ , FG ; , G 3 O ltk.(iv) Eofor dtoa. Ugl dtoa wgikg eofdtls tgl pdir on lhlktrofs to tgl klftrdh altdh dtoa is kdhhleeofor dtoa l.`. If FG ; , F is tgl eofor dtoa. If G 3O, O is tgl eofor dtoa.(v) Kooreifdtiof Fuaclr. Ugl fuaclr on hi`dfes eirlkthy cofele to tgl klftrdh altdh iof if elnifitl`loaltrik drrdf`lalft is tgl kooreifdtiof fuaclr on tgl altdh dtoa l.`. If ]Ko(FG ; ) >Q
;+ tgl > FG ; ,aohlkuhls drl cofele to Ko ;+ dtoa so kooreifdtiof fuaclr on Ko +; is six.(vi) Oxiedtiof Fuaclr. It is tgl kgdr`l of tgl klftrdh dtoa tgdt it wouhe kdrry wglf dhh tgl hi`dfes
drl rlaovle. l.`. if ]Ko(FG ; ) >Q;+
tgl oxiedtiof fuaclr on kocdht (Ko) is + ;.T.3 Pgdt is aldft cy tgl elftikity on d hi`dfe? @ivl lxdaphls on d ufielftdtl dfe d eielftdtl
hi`dfe.Dfs. Elftikity on d Hi`dfe. It is tgl fuaclr on si`ad ( ϋ) lhlktrof pdir eofor ̀ roups. It ady cl 4, 3, ;, 5,
> ltk.Elftikity FoalfkhdturlLxdaphl
4. ufi elftdtl 3. ci elftdtl;. trielftdtl5. trielftdtl. glxdelftdtl.
T.; Pgikg postuhdtls eie Plrflr usl to lxphdif tgl cofeif` if kooreifdtiof koapoufes? Pgdtis tgl adif wldmflss on Plrflr’s tglory?
Dfs. Adif postuhdtls on Plrflr’s Uglory.(i) Altdhs posslss two typls on vdhlfkils i.l. priadry (iofisdchl) dfe slkofedry(fof ‛ iofisdchl).(ii) Zriadry vdhlfkils drl sdtisnile cy fl`dtivl iofs dfe it is lqudh to tgl oxiedtiof stdtl on tgl altdhiof.(iii) Ugl slkofedry vdhlfkils kdf cl sdtisnile cy flutrdh or fl`dtivl iofs / `roups. It is lqudh to tglkooreifdtiof fuaclr on tgl altdh dfe is d nixle fuaclr.(iv) Ugl iofs / `roups coufe cy slkofedry hifdm`l gdvl kgdrdktlristik spdtidh drrdf`lalftkorrlspofeif` to einnlrlft oxiedtiof fuaclrs. [ukg drrdf`lalfts drl kdhhle kooreifdtiof pohyglerd.Of tgl cdsis on tglsl postuhdtls, Plrflr norauhdtle tgl kooreifdtiof koapoufesKoKh ; .>FG ; , KoKh ; .QKh; = ]Ko(FG ; )
-
8/15/2019 Co Ordination Compound
12/23
KO- OSEIFDUIOF KOAZO\FE[ 43
www.tgifmiit.if
(ii) It ndihle to lxphdif tgl eirlktiofdh proplrtils on cofes if kooreifdtiof koapoufes.(iii) It ndihle to lxphdif tgl kgdrdktlristik ad`fltik dfe optikdh proplrty on tgl kooreifdtiof koapoufes.
T.5 Pgdt is ufelrstooe cy2
(d) d kglhdtif` hi`dfe,
(c) df dacielftdtl hì dfe?
Dfswlr usif` splkinik lxdaphls.
Dfs. (d) Kglhdtif̀ Hì dfe. Pglf tgl kooreifdtiof on aorl tgdf ofl si`ad ‛ lhlktrof pdir eofor `roup
(i.l. cielftdtl or pohyelftdtl) nroa tgl hi`dfe to tgl sdal altdh iof okkur, it is kdhhle kglhdtiof dfe
sukg d hi`dfe is kdhhle ds kglhdtif` hi`fde l.`. K 3 O53‛ (oxdhdto).
(c) Dacielft Hi`dfes. Ugl aofoelftdtl hi`dfe wgikg kdf kooreifdtl witg tgl klftrdh altdh dtoa
tgrou`g aorl tgdf ofl sitl drl kdhhle dacielft hi`dfes l.`. KF ‛ , FO 3‛ ltk.
T.< Koaphltl tgl nohhowif̀ stdtlalfts nor tgl kooreifdtiof lftity (koaphlx iof) ]KrKh 3 (OW) 3 Q;‛
2(d) OW is dccrlvidtiof nor __________________ (c) Ugl oxiedtiof fuaclr on kgroaiua is __________________ (k) Ugl kooreifdtiof fuaclr on kgroaiua is _______________ (e) ___________ is d eielftdtl hi`dfe.
Dfs. (d) Oxdhdtl iof
KOO|KOO
or K 3O53‛
(c) + ;(k) >(e) oxdhdtl iof or K 3 O5
3‛ iof .
T.> [plkiny tgl oxiedtiof fuaclrs on tgl altdhs if tgl nohhowif` kooreifdtiof lftitils2
(d) ]Ko(KF)(G 3 O)(lf) 3 Q3+
(c) ]ZtKh 5 Q3‛
(k) ]KrKh ; (FG ; ) ; Q
(e) ]KoCr 3 (lf) 3 Q+ (l) M ; ]Nl(KF) >Q.
Dfs. (d) ]Ko(KF)(G 3 O)(lf) 3Q;+ ‛ O. F. on Ko is +; (c) ]ZtKh5Q
3‛ ‛ Ugl O. F. on Zt is +3
(k) ]KrKh; (FG ; ) ; Q ‛ Ugl O. F. on Kr is +; (e) ]KoCr 3 (lf) 3Q+ ‛ Ugl O. F. on Ko is +;
(l) M; ]Nl(KF) >Q ‛ Ugl O. F. on Nl is +;.T.0 \sif` I\ZDK foras writl tgl norauhdl nor tgl nohhowif`2
(d) Ultrdgyeroxozifkdtl (III) (c) Glxddaifl kocdht (III) suhpgdtl(k) Zotdssiuatltrdkghoropdhhdedtl (II) (e) Zotdssiua tri (oxdhdto) kgroadtl (III)(l) Eidaaifleikghorophdtifua (II) (n) Glxddaaiflphdtifua (I^)
(`) Zotdssiua tltrdkydfofikmlhdtl (II) (g) Ultrdcroaokuprdtl (II)(i) Zlftddaaiflfitrito ‛ O ‛ kocdht (III) (b) Zlfltddaaiflfitrito ‛ F ‛ kocdht (III)
Dfs. (d) ]Rf (OG) 5Q3‛ (c) ]Ko (FG ; ) >Q3([O 5) ; (k) M3 ]ZeKh 5 Q (e) M3 ]Kr(K 3 O5) 3 Q
(l) ]ZtKh 3 (FG) ; Q3 (n) ]Zt (FG ; ) >Q5+ (`) M3 ]Fi(KF) 5Q (g) ]KuCr 5Q
3‛
(i) ]Ko(OF)(FG ; ) Q Kh; (c) ]KoKh(FO 3 ) (FG ; ) 5 QKh(k) ]Fi(FG ; ) >QKh3 (e) ]ZtKh (FG 3 KG ; ) (FG ; ) 3 QKh(l) ]Af(G 3 O) >Q
3+ (n) ]Ko(lf) ; Q;+
(`) ]Ui(G 3 O) >Q;+
(g) ]FiKh 5 Q3‛
(i) ]Fi(KO) 5 QDfs. (d) Glxdaaifl kocdht (III) kghoriel
(c) Ultrdaaifl kghoro fitro kocdht (III) kghoriel
-
8/15/2019 Co Ordination Compound
13/23
KO- OSEIFDUIOF KOAZO\FE[ 4;
www.tgifmiit.if
(k) Glxddaifl kghoro (altgyhdaifl) phdtifua (II) kghoriel(e) Eidaaifl kghoro (altgyhdaifl) phdtifua (II) kghoriel(l) Glxddqud adfd`dflsl (II)(n) Uris (ltgyhlfleidaifl) kocdht (II)(`) Glxddqud titdfiua (III)(g) Ultrdkgoro fikmhdtl (II)(i) Ultrdkdrcofyh fikmlh (O).
T.9 Lxphdif witg lxdaphls ̀ loaltrik dfe optikdh isoalrisa.Dfs. @loaltrikdh Isoalrisa. Ugis typl on isoalrisa drisls if kooreifdtiof koapoufes eul to tgl einnlrlfkl
if ̀ loaltrikdh drrdf`lalft on tgl hi`dfes droufe tgl klftrdh altdh dtoa / iof. Ugis is dhso mfowf dskis ‛ trdfs isoalrisa.
If tltrd kooreifdtl squdrl phdfdr koaphlx tgl kis ‛ isoalr gds tgl sdal `roups of tgl sdal sielwglrl ds if trdfs ‛ isoalr tgl sdal `roups drl of oppositl siels. l.`.
Ugis typl on isoalrisa is dhso sgowf cy oktdglerdh koaphlxls l.`. Ko(FG ; ) 5Kh3
Optikdh Isoalrisa. Optikdh isoalrs drl fof ‛ suplriaposdchl airror iad`ls on ldkg otglr. Uglyposslss tgl proplrty on kgirdhity. Ugly gdvl ielftikdh pgysikdh dfe kglaikdh proplrtils cut einnlr ifoptikdh rotdtiof. Ofl on tgla rotdtls tgl phdfl pohdrizle hi`gt towdre ri`gt dfe is kdhhle elxtro ‛rotdtory (e ‛ isoalr) dfe tgl otglr rotdtls phdfl pohdrizle ri`gt towdres hlnt dfe is kdhhle hdlvorotroty (h ‛ isoalr) l.`. ]Kr(K 3O5) ; Q
;‛
-
8/15/2019 Co Ordination Compound
14/23
KO- OSEIFDUIOF KOAZO\FE[ 45
www.tgifmiit.if
T.4: [plkiny wgikg out on tgl nohhowif` koaphlx strukturls lxgicit ̀ loaltrik isoalrisa2(d) hifldr (c) squdrl ‛ phdfdr (k) tltrdglerdh (e) oktdglerdh
Dfs. Ugl nohhowif` wihh sgow `loaltrikdh isoalrisa.(c) ‛ [qudrl phdfdr(e) ‛ tltrdglerdh.
T.44 Gow adfy `loaltrik isoalrs drl possichl if tgl nohhowif` kooreifdtiof lftitils2(d) ]Kr(OW) ; Q
;‛ (c) ]KoKh ; (FG ; ) ; Q
Dfs. (d) Uwo (c) Uwo
T.43 Erdw tgl strukturl on optikdh isoalrs on2(d) ]Kr(OW) ; Q
;‛ (c) ]ZtKh 3 (lf) 3 Q3+ (k) ]KrKh 3 (lf) (FG ; ) 3 Q
+
Dfs. (d) Slnlr to T. 9.
(c)
(k) Optikdh Isoalrisa. Optikdh isoalrs drl fof ‛ suplriaposdchl airror iad`ls on ldkg otglr.Ugly posslss tgl proplrty on kgirdhity. Ugly gdvl ielftikdh pgysikdh dfe kglaikdh proplrtils cut einnlrif optikdh rotdtiof. Ofl on tgla rotdtls tgl phdfl pohdrizle hi`gt towdre ri`gt dfe is kdhhle elxtro ‛rotdtory (e ‛ isoalr) dfe tgl otglr rotdtls phdfl pohdrizle ri`gt towdres hlnt dfe is kdhhle hdlvorotroty (h ‛ isoalr) l. .̀ ]Kr(K 3O5 ) ; Q
;‛
T.4; Erdw dhh tgl isoalrs (`loaltrik dfe optikdh) on2(d) ]KoKh 3 (lf) 3 Q
+
(c) ]KoKh (lf) 3 (FG ; )Q3+
(k) ]KoKh 3 (lf) (FG ; ) 3 Q+
Dfs. (d)
-
8/15/2019 Co Ordination Compound
15/23
KO- OSEIFDUIOF KOAZO\FE[ 4<
www.tgifmiit.if
(c) Optikdh Isoalrs
@loaltrikdh Isoalrs
T.45 Erdw tgl strukturls on2(d) Kis ‛ eikghorotltrdkydfo ‛ kgroadtl (III)(c) Alr ‛ tridaaifltri kghorokocdht (III)(k) Ndk ‛ tridqudtrifitor ‛ F ‛ kocdht (III).
Dfs.
T.4< Ihhustrdtl witg df lxdaphl ldkg on tgl nohhowif̀ 2(d) iofizdtiof isoalrisa(c) hifmd`l isoalrisa
(k) kooreifdtiof isoalrisa.
Dfs. (d) ]Ko(FO;)(FG
;)
<Q[O
5 dfe ]Ko(FG
;)
<[O
5Q FO
;drl iofizdtiof isoalrs.
(c) ]Ko(FG ; ) Q dfe ]Ko(FG ; ) >Q ]Kr(KF) >Q drl kooreifdtiof isoalrs.
-
8/15/2019 Co Ordination Compound
16/23
KO- OSEIFDUIOF KOAZO\FE[ 4>
www.tgifmiit.if
T.4> [mltkg tgl `loaltrikdh sgdpls on tgl nohhowif` slts on gycrie orcitdhs2(d) esp 3 (c) esp ;
(k) e 3 sp ; (e) sp ;
Dfs. (d) esp 3 (c) sp ; e or esp ;
(k) sp ; e 3 or e 3 sp ; (e) sp ;
T.40 Lxphdif of tgl cdsis on vdhlfkl cofe tglory, tgl lxplrialftdh nifeif̀ tgdt ]Fi(KF) 5 Q3‛ iof
witg d squdrl ‛ phdfdr strukturl is eidad`fltik dfe tgl ]FiKh 5 Q3‛ iof witg tltrdglerdh ̀ loaltry
is pdrdad`fltik.Dfs. ]Fi(KF) 5 Q
3‛
Pglrl WW rlprlslfts tgl hofl pdir on lhlktrofs nroa KF ‛ .
Clkdusl on esp 3 gycrieizdtiof, it is squdrl phdfdr koaphlx.
[ifkl tglrl is fo ufpdirle lhlktrof so it is eidad`fltik.
]FiKh 5 Q3‛
WW is lhlktrof pdir eofdtle cy ldkg Kh.
Clkdusl on sp ; gycrieizdtiof it is tltrdglerdh eul to tgl prlslfkl on two ufpdirle lhlktrofs it is
pdrdad`fltik.
-
8/15/2019 Co Ordination Compound
17/23
KO- OSEIFDUIOF KOAZO\FE[ 40
www.tgifmiit.if
T.47 Pritl tgl korrlkt norauhdl nor tgl nohhowif̀ kooreifdtiof koapoufes2(d) KrKh ; .>G 3 O (viohlt, witg ; kghoriel iofs / ufit norauhd)(c) KrKh ; .>G 3 O (hi`gt `rllf kohour, witg 3 kghoriel iofs / ufit norauhd)(k) KrKh ; .>G 3 O (edrm `rllf kohour, witg 4 kghoriel iofs / ufit norauhd)]Gift2 [oal on tglsl koapoufes ady lxist ds gyerdtlsQ.
Dfs. (d) ]Kr(G 3O) >QKh;(c) ]Kr(G 3O) Q
5‛ (c) ]NlN >Q;‛
(k) ]Ko(OW) ; Q;‛ (e) ]KoN >Q
;‛ .Dfs. (d) [ifkl it is d koaphlx koapoufe so it gds kooreifdtl cofes cltwllf hi`dfes KF ‛ dfe klftrdh altdh
Nl 3+
(c) Kooreifdtl cofes cltwllf Nl ;+ dfe N ‛
-
8/15/2019 Co Ordination Compound
18/23
KO- OSEIFDUIOF KOAZO\FE[ 47
www.tgifmiit.if
(k) Kooreifdtl cofes cltwllf Ko ;+ dfe K 3O53‛ (hi`fde)
(e) Kooreifdtl cofes cltwllf Ko ;+ dfe N ‛ .
T.33 Pritl tgl vdhlfkl cofe elskriptiof on2(d) ]Fi(KF) 5 Q
3‛ (c) ]Fi Kh 5 Q3‛ .
Dfs. Slnlr to T. 40 on tgis slktiof.
T.3; Pgdt is ufelrstooe cy tgl `lflrdhizdtiof, ‗ad`fltik kritlrid on tgl cofe typl’? Ihhustrdtl
your dfswlr witg suitdchl lxdaphls.
Dfs. Cy ad`fltik kritlriof on cofe typl wl aldfs tgdt it is possichl to prleikt tgl ̀ loaltry on tgl kooreifdtl
lftity in wl mfow its ad`fltik clgdviour. l.`. ]Fi(KF) 5Q3‛
is eidad`fltik, so wl kdf prleikt tgdt it gdsufelr`ofl esp 3 gycrieizdtiof dfe gds d squdrl phdfdr `loaltry cut sifkl ]FiKh 5Q
3‛ is pdrdad`fltik=
so it gds sp ; gycrieizdtiof dfe tgus tltrdglerdh sgdpl.T.35 Erdw ni`url to sgow sphittif` on el`lflrdtl e orcitdhs if df oktdglerdh krystdh nilhe.Dfs. Ul sphittif` on e ‛ orcitdh if df oktdglerdh nilhe is sgowf clhow.
T.3< [tdtl tgl lsslftidh rlquirlalfts nor rl`dreif` d koapoufe ds df or`dfoaltdhhik. Pgikgdaof`st tgl nohhowif` drl or`dfoaltdhhik koapoufes2(d) C(KG ; ) ; (c) C(OKG ; ) ;(k) [iKh ; (KG ; ) (e) F(KG ; ) ;
Dfs. Ugl lsslftidh rlquirlalft nor rl`dreif` d koapoufe ds or`dfoaltdhhik koapoufe is tgdt it aust gdvld altdh ‛ kdrcof cofe
On tgl `ivlf koapoufes (d) dfe (k) ady cl khdssinile ds or`dfoaltdhhik koapoufes.
T.3> Pritl tgl norauhdl on tgl nohhowif`2(d) altgyhhitgiua(c) tltrdaltgysihdfl(k) trialtgyhcisautg(e) trialtgyhdrsdfl(l) glxdaltgyheidhuaifiua(n) trialtgyhcorof.
Dfs.
-
8/15/2019 Co Ordination Compound
19/23
KO- OSEIFDUIOF KOAZO\FE[ 49
www.tgifmiit.if
3>. (d) G; K ‛ Hi (c) [i(KG ; ) 5 (k) Ci(KG ; ) ;(e) Ds(KG ; ) ; (l) Dh3(KG ; ) > i.l.(n) C(KG ; ) f
T.30 [mltkg tgl strukturl on tgl or̀ dfoaltdhhik koapoufes `ivlf if 4:.3>.
Dfs. (d) (c) (k) (e)
(l)
(n)
T.37 @ivl I\ZDK fdal dfe erdw tgl strukturl on2
(d) Fi(KO) 5 (c) Nl(KO) < (k) ]ZtKh ; (K 3 G 3 )Q‛
(e) ]Kr(KO) >Q.Dfs. (d) Ultrdkdrcofyh ‛ fikmlh (O)=
(c) Zlftdkdrcofyh irof (O)=
(k) Urikghoroltglflphdtifdtl (II). It is mfowf ds zlisl sdht.
(e) Glxdkdrcofyh kgroaiua (O).
-
8/15/2019 Co Ordination Compound
20/23
KO- OSEIFDUIOF KOAZO\FE[ 3:
www.tgifmiit.if
T.39 Dssì f oxiedtiof fuaclr to tgl altdh dtoa if tgl koapoufes `ivlf if 4:.37.Dfs. (d) Fi 1 : (c) Nl 1 :
(k) Zt 1 + 3 (e) Kr 1 :.
T.;: Eiskuss tgl fdturl on cofeif` if ]Fi(KO) 5 Q.Dfs. If Fi(KO) 5 , wl nife tgdt cotg ϋ or ϊ cofes drl norale. [i`ad ( ϋ) cofes is norale cy eofdtiof on hofl
pdir on lhlktrof cy KO to vdkdft e ‛ orcitdhs on fikmlh. Ugl pi ( ϊ ) cofes is norale cy cdkm eofdtiof on pdir on lhlktrofs nroa nihhle e ‛ orcitdhs on fikmlh to vdkdft dfitcofeif` orcitdh on KO.
T.;4 Eiskuss crilnhy tgl rohl on kooreifdtiof koapoufes if2
(d) cioho`ikdh systlas,
(c) dfdhytikdh kglaistry,
(k) aleikifdh kglaistry, dfe (e) lxtrdktiof / altdhhur`y on altdhs.
Dfs. Sohl on kooreifdtiof koapoufes
(d) If cioho`ikdh systlas. Gdlao`hocif, d koaphlx on irof dkts ds kdrrilr on oxy`lf if dfiadhs dfe
guadf clif`s. Kghoropgyhh, d koaphlx on A` is glhpnuh if tgl proklss on pgotosyftglsis. It is prlslft
if `rllf phdfts.
(c) If Dfdhytikdh kglaistry. Uo eltlraifl tgl gdrflss on wdtlr wl usl LEUD. If hdcordtory LEUD (dkoaphlx koapoufe) is usle if tgl lstiadtiof on Kd 3+ , A` 3+ iofs. Dfotglr koaphlx mfowf ds EA@
(Eialtgyh `hyoxial) is usle if tgl lstiadtiofs on Fi 3+ .
(k) If Aleikifls. Kis ‛ phdtif dfotglr kooreifdtiof koapoufe is usle ds df dfti ‛ kdfklr d`lft if
tgl trldtalft on kdfklr.
(e) If Altdhhur̀ y. If tgl altdhhur`y on D` dfe Du wl nirst prlpdrl tglir kydfiel koaphlxls wgikg
drl tglf rleukle witg zifk altdh to `lt purl D` or Du.
-
8/15/2019 Co Ordination Compound
21/23
KO- OSEIFDUIOF KOAZO\FE[ 34
www.tgifmiit.if
LWLSKI[L - I
\F[OH^LE ZSOCHLA[T.4 ]FiKh 5Q
3‛ is pdrdad`fltik wgihl ]Fi(KO) 5Q is eidad`fltik tgou`g cotg drl tltrdglerdh. Pgy
T.3 ]Nl(G 3 O) >Q;+ is strof`hy pdrdad`fltik wglrlds ]Nl(KF) >Q
;‛ is wldmhy pdrdad`fltik. Lxphdif.
T.; Lxphdif ]Ko(FG ; ) >Q;+ is df ifflr orcitdh koaphlx wglrlds ]Fi(FG ; ) >Q
3+ is df outlr orcitdh koaphlx.
T.5 Zrleikt tgl fuaclr on ufpdirle lhlktrofs if tgl squdrl phdfdr ]Zt(KF) 5Q3‛ iof.
T.< Ugl glxddquoadf`dflsl (II) iof koftdifs nivl ufpdirle lhlktrofs wgihl tgl glxdkydfo iof koftdifsofhy ofl ufpdirle lhlktrof. Lxphdif usif` krystdh nilhe tglory.
T.> Kdhkuhdtl tgl ovlrdhh koaphlx eissokidtiof lquihicriua kofstdft nor tgl Ku (FG 5)3+
5 iof, `ivlf tgdt γ5nor tgis koaphlx is 3.4 Ð 4: 4; .
T.0 Lxphdif tgl cofeif̀ if kooreifdtiof koapoufes if tlras on Plrflr's posituhdtls.
T.7 Nl[O 5 sohutiof aixle witg (FG 5) 3[O 5 sohutiof if 4 2 4 aohdr rdtio `ivls tgl hlst on Nl3+ cut Ku[O 5
sohuitof aixle witg dqulous daaofid if 4 2 5 aohdr rdtio eols fot `ivl tgl tlst on Ku 3+ iof. Lxphdifwgy ?
T.9 Lxphdif witg two lxdaphls ldkg on tgl nohhowif̀Kooreifdtiof lftity, hi`dfe, kooreifdtiof fuaclr, kooreifdtiof pohyglerof, goaohlptik dfe gltlrohlptik.
T.4: Pgdt is aldft cy ufielftdtl, eielftdtl dfe dacielftdtl hi`dfes ? @ivl two lxdaphl nor ldkg.
T.44 [plkiny tgl oxiedtiof fuaclrs on tgl altdhs if tgl nohhowif` kooreifdtiof lftitils.(i) ]Ko(G 3O) (KF) (lf) 3Q
3+
(ii) ]ZtKh 5Q3― (iii) ]Kr(FG ; ) ; Kh; Q
(iv) ]KoCr 3 (lf) 3Q+ (v) M ; Nl (KF) >
T.43 \sif` I\ZDK foras, writl tgl norauhdl on tgl nohhowif` 2(i) Ultrdgyeroxozifkdtl (II) (ii) Glxddaaiflkocdht (III) suhpgdtl(iii) Zotdssiua tltrdkghorieopdhhdedtl (II) (iv) Zotdssiuatrioxdhdtokgroadtl (III)(v) Eidaaifleikghorieophdtifua (II) (vi) Glxddaaiflphdtifua (I^)(vii)Zotdssiua tltrdkydfofikmlhdtl (II) (viii) Ultrdcroaieokuprdtl (II)(ix) Zlftddaaiflfitrito-O-kocdht (III) (x) Zlftddaaiflfitrito-F-kocdht (III)
T.4; Hist tgl vdrious typls on isoalrisa possichl nor kooreifdtiof koapoufes, `ivif` df lxdaphl on ldkg.
T.45 Gow adfy `loaltrikdh isoalrs drl possichl if tgl nohhowif` kooreifdtiof lftitils ?
T.4< Erdw tgl strukturl on optikdh isoalrs on (i) ]ZtKh 3Q (lf) 3Q
3+ (ii) ]Kr(FG ; ) 3Kh3(lf) 3Q+
T.4> Erdw dhh tgl isoalrs ( l̀oaltrikdh dfe optikdh) on (i) ]Ko(FG ; )Kh(lf) 3Q
3+ (ii) ]Ko(FG ; ) 3Kh3 (lf)Q+
T.40 Pritl dhh tgl ̀ loaltrikdh isoalrs on ]Zt(FG ; ) (Cr) (Kh) (py)Q dfe gow adfy on tglsl wihh lxgicit optikdhisoalrisa ?
T.47 Dqulous kopplr suhpgdtl sohutiof (chul if kohour) ̀ ivls (i) d ̀ rllf prlkipitdtl witg dqulous potdssiua
nhuoriel, dfe (ii) d cri`gt `rllf sohutiof witg dqulous potdssiua kghoriel. Lxphdif tglsl lxplrialftdhrlsuhts.
T.49 Pgdt is tgl kooreifdtiof lftity norale wglf lxklss on dqulous MKF is deele to df dqulous sohutiofon kopplr suhpgdtl ? wgy is tgdt fo prlkipitdtl on kopplr suhpgiel is octdifle wglf G 3 [ (`) is pdssletgrou`g tgis sohutiof ?
T.3: Eiskuss tgl fdturl on cofeif` if tgl nohhowif` kooreifdtiof lftitils of tgl cdsis on vdhlfkl cofetglory 2(i) ]Nl(KF) >Q
5‛ (ii) ]NlN >Q;‛ (ii) ]Ko(K 3O5) ; Q
;‛ (iv) ]FiKh 5Q3‛
T.34 Erdw d ni`url to sgow sphittif` on el`lflrdtle orcitdh if df oktdglerdh krystdh nilhe.
T.33 Pgdt is splktrokglaikdh slrils ? Lxphdif tgl einnlrlfkl cltwllf d wldm nilhe hi`dfe dfe d strof` nilhehi`dfe.
-
8/15/2019 Co Ordination Compound
22/23
KO- OSEIFDUIOF KOAZO\FE[ 33
www.tgifmiit.if
LWLSKI[L - II
CODSE ZSOCHLA[T.4 Elskricl nor dfy two on tgl nohhowif̀ koaphlx iofs, tgl typl on gycrieizdtiof, sgdpl dfe ad`fltik
proplrty 2 ]KC[L 3::0Q(i) ]Nl (G 3 O) >Q
3+ (ii) ]Ko (FG ; ) >Q;+
(iii) ]FiKh 5Q3‛
(Dt. Fos. Nl 1 3>, Ko 1 30, Fi 1 37)
T.3 (d) Pgdt is d hì dfe ? @ivl df lxdaphl on d cielftdtl hi`dfe.(c) Lxphdif ds to gow tgl two koaphlxls on fikmlh, ]Fi(KF) 5Q
3‛ dfe Fi(KO) 5 , gdvl einnlrlft strukturlscut eo fot einnlr if tglir ad`fltik clgdviour. (Fi 1 37) ]KC[L 3::7Q
T.; Nor tgl koaphlx ]Nl(lf) 3Kh3 QKh, (lf 1 ltgyhlfl eidaifl), ielftiny(i) tgl oxiedtiof fuaclr on irof.(ii) tgl gycrie orcitdhs dfe sgdpl on tgl koaphlx(iii) tgl ad f̀ltik clgdviour on tgl koaphlx(iv) tgl fuaclr on `loaltrikdh isoalrs.(v) wgltglr tglrl is df optikdh isoalr dhso, dfe(vi) fdal on koaphlx. (Dt. fo. on Nl 1 3>) ]KC[L 3::9Q
T.5 Koapdrl tgl nohhowif̀ koaphlxls witg rlsplkt to tglir sgdpl, ad`fltik clgdviour dfe tgl gycrieorcitdhs ifvohvle 2(i) ]KoN 5Q
3‛ (ii) ]Kr(G 3 O) 3(K 3O5) 3Q‛
(iii) ]Fi(KO) 5Q(Dtoaik fuaclr 2 Ko 1 30, Kr 1 35, Fi 1 37) ]KC[L 3::9Q
T.< @ivif` d suitdchl lxdaphl nor ldkg, lxphdif tgl nohhowif` 2(i) Krystdh nilhe sphittif`(ii) Hifmd`l isoalrisa(iii) Dacielftdtl h ì dfe. ]KC[L 3::9Q
T.> Koapdrl tgl nohhowif` koaphlxls witg rlsplkt to tglir aohlkuhdr sgdpl dfe ad`fltik clgdviour(i) ]Kr(FG ; ) >Q
;+ (ii) ]Nl(KF) >Q5‛
(iii) ]FiKh 5Q3‛
(Dt. Fo. Kr 1 35, Nl 1 3>, Fi 1 37) ]KC[L 3::9Q
T.0 (d) Pgdt gdpplf wglf(i) kghorifl ̀ ds is pdssle tgrou`g d got kofklftrdtle sohutiof on FdOG ?(ii) suhpgur eioxiel ̀ ds is pdssle tgrou`g df dqulous sohutiof on d Nl(III) sdht ?(c) Dfswlr tgl nohhowif` 2(i) Pgdt is tgl cdsikity on G ; ZO ; dfe wgy(ii) Pgy eols nhuorifl fot phdy tgl rohl on d klftrdh dtoa if iftlrgdho l̀f koapoufes ?(iii) Pgy eo fochl ̀ dsls gdvl vlry how coihif` poifts ? ]KC[L 3:44Q
T.7 Pritl tgl stdtl on gycrieizdtiof, tgl sgdpl dfe tgl ad̀ fltik clgdviour on tgl nohhowif̀ koaphlxlftitils.(i) ]Kr(FG ; ) 5 Kh3QKh (ii) ]Ko(lf) ; QKh; (iii) M 3]Fi(KF) 5Q ]KC[L 3:44Q
T.9 Fdal tgl nohhowif` kooreifdtiof koapoufes dfe erdw tglir strukturls 2(i) ]KoKh 3 (lf) 3QKh (ii) ]Zt (FG ; ) 3QKh(FO3)Q(Dt. fo. Ko 1 30, Zt 1 07) ]KC[L 3:44Q
T.4: Nor tgl koaphlx ]Nl(lf) 3Kh3 QKh, ielftiny tgl nohhowif` 2(i) Oxiedtiof fuaclr on irof.(ii) Gycrie orcitdhs dfe sgdpl on tgl koaphlx(iii) Ad`fltik clgdviour on tgl koaphlx(iv) Fuaclr on its l̀oaltrikdh isoalrs(v) Pgltglr tglrl ady cl optikdh isoalr dhso
(vi Fdal on tgl koaphlx ]KC[L 3:44QT.44 [tdtl rldsofs nor ldkg on tgl nohhowif` 2
(i) Dhh tgl Z―Kh cofes if ZKh < aohlkuhl drl fot lquivdhlft.(ii) [uhpgur gds `rldtlr tlfelfky nor kdtlftiof tgdf oxy`lf. ]KC[L 3:44Q
-
8/15/2019 Co Ordination Compound
23/23
KO- OSEIFDUIOF KOAZO\FE[ 3;
T.43 [tdtl rldsofs nor ldkg on tgl nohhowif` 2(i) Ugl F―O cofe if FO 3
‛ is sgortlr tgdf tgl F―O cofe if FO ;‛ .
(ii) [N > is mifltikdhy df iflrt sucstdfkl. ]KC[L 3:44Q
T.4; Koaphltl tgl nohhowif` kglaikdh lqudtiofs 2
(i) KG ; KG3KhFdKF (D)
rleuktiofFi/G 3
(C)
(ii) K>G
<F
3Kh + G
;ZO
3 + G
3O ↓
(iii) S―K―FG 3
OHiD/G 5G O3
]KC[L 3:44Q
T.45 Nor tgl koaphlx ]FiKh 5Q3‛ , writl
(i) tgl I\ZDK fdal.(ii) tgl gycrieizdtiof typl.(iii) tgl sgdpl on tgl koaphlx.(Dtoaik fo. on Fi 1 37)
OS Pgdt is aldft cy krystdh nilhe sphittif` lflr`y ? Of tgl cdsis on krystdh nilhe tglory, writl tgl lhlktrofikkofni`urdtiof on e 5 if tlras on t 3` dfe l ` if df oktdglerdh nilhe wglf(i) : 6 Z (ii) : 8 Z ]KC[L 3:4;Q