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Ciba Specialty Chemicals Coating Effects Value beyond chemistry Product Selection Guide for Powder Coatings

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Page 1: ciba

Ciba Specialty Chemicals

Coating Effects Value beyond chemistry

Product Selection Guidefor Powder Coatings

Page 2: ciba

Ciba® CHIMASSORB® Ciba® FILOFIN® Ciba® IRGAPHOR® Ciba® ORACET®

Ciba® CINQUASIA® Ciba® HORNA® Ciba® IRGAPLASTOL® Ciba® ORASOL®

Ciba® CROMOPHTAL® Ciba® HORNACHROME® Ciba® IRGAROL® Ciba® RHEOVIS®

Ciba® DAROCUR® Ciba® HORNATHERM Ciba® IRGASPERSE® Ciba® TINOPAL®

Ciba® DISPEX® Ciba® IRGACOLOR® Ciba® IRGAZIN® Ciba® TINUVIN®

Ciba® GLASCOL® Ciba® IRGACURE® Ciba® LIGNOSTAB® Ciba® UNISPERSE®

Ciba® GRAPHITAN® Ciba® IRGAFOS® Ciba® MICRANYL® Ciba® UVITEX®

Ciba® EFKA® Ciba® IRGAGUARD® Ciba® MICROLEN® Ciba® VISCALEX®

Ciba® FILAMID® Ciba® IRGALITE® Ciba® MICROLITH®

Ciba® FILESTER® Ciba® IRGANOX® Ciba® MICROSOL®

Ciba Specialty Chemicals trademarks (All trademarks mentioned are either property of or licensedto Ciba Specialty Chemicals and registered in relevant countries)

Page 3: ciba

Contents

Pigments 5Organic and Inorganic Powder Pigments 5, 6

Ciba® CINQUASIA®, Ciba® CROMOPHTAL®, Ciba® IRGACOLOR®, Ciba® IRGALITE®, Ciba® IRGAZIN®

Chrome Yellow and Molybdate Orange Powder Pigments 7Ciba® HORNACHROME®, Ciba® HORNA®

Pigment preparations 8Ciba® MICROLEN®

Light Stabilizers 9Ultraviolet Light Absorbers (UV-Absorbers) 9

Ciba® TINUVIN®

Hindered Amine Light Stabilizers (HALS) 9Ciba® CHIMASSORB®, Ciba® TINUVIN®

HALS Blend 9Ciba® TINUVIN®

Antioxidants 10Ciba® IRGAFOS®, Ciba® IRGANOX®

Optical Brightener 11Ciba® UVITEX®

Photoinitiators 12Ciba® IRGACURE®

Appendix 13Absorption Spectra of Ultraviolet Light Absorbers (UV-Absorbers) 13Absorption Spectra of Photoinitiators 13Test methods – Fastness Properties of Pigments 14, 15

Page 4: ciba

Introduction

Ciba Specialty Chemicals is a member of: Ecological and Toxicological Association of Dyes and Organic Pigments Manufacturers

Key to Symbols and Application Suitability

® Registered trademark RecommendedOther potential uses

Let us help you create effects that improve the quality of life!

Products, processes and services from Ciba Specialty Chemicals enable you to create effects that add performance, protection, color and strength to your coatings.

Product Selection Guide for Powder Coatings Ciba Specialty Chemicals 2005

4

This booklet provides a comprehensive list of the pigments and additives in the Ciba Specialty Chemicalsranges for powder coatings.

The products are divided into five main categories: pig-ments, light stabilizers, antioxidants, optical brighteners, photoinitiators.The pigment classes are subdivided into organic andinorganic pigments, chrome yellow and molybdateorange pigments, pigment preparations.

Suitable fields of application are indicated next to eachproduct, but it must be stressed that these are onlyintended as a general guide.

For more detailed information on specific applicationsand product control please consult our marketingdepartments or local sales organizations.

Further technical product information and details on usein food packaging materials, toys and other consumergoods (EHS data) are available on our Internet site at:

• www.cibasc.com Product Search

Page 5: ciba

Product Selection Guide for Powder Coatings Ciba Specialty Chemicals 2005

5

Organic and Inorganic Powder Pigments

Ciba® IRGAZIN®, Ciba® CROMOPHTAL® and Ciba® CINQUASIA® products are high-performance organic and inorganicpigments that combine very good tinctorial properties with excellent fastness to light, weather, chemicals and solvents.They fulfill the requirements of the most critical applications.The Ciba® IRGALITE® range consists of classical organic pigments. Ciba® IRGACOLOR® pigments are inorganic pigmentswith outstanding resistance to heat, weather and chemicals.

Pigments

IRGAZIN® Yellow 2093

IRGAZIN® Yellow 2094

CROMOPHTAL® Yellow 8GN

IRGAZIN® Yellow 3RLTN

IRGALITE® Orange MOR

IRGAZIN® DPP Scarlet EK

IRGALITE® Red CLO

IRGAZIN® Red 2029

IRGAZIN® Red 2030

IRGAZIN® Red 2031

IRGAZIN® DPP Red BO

IRGAZIN® DPP Red Ultra Opaque

CINQUASIA® Red Y RT-759-D

IRGAZIN® Red A2BN

IRGAZIN® Magenta 2012

CINQUASIA® Violet R NRT-201-D

CROMOPHTAL® Violet GT

IRGAZIN® Blue A3RN

IRGALITE® Blue BSP

IRGALITE® Blue 2234

IRGALITE® Blue PG

IRGALITE® Green GLN

Bismuth vanadate771740 Pigment Yellow 184Bismuth vanadate771740 Pigment Yellow 184Azo condensation20037 Pigment Yellow 128Tetrachloroisoindolinone56280 Pigment Yellow 110Dianisidine Orange21160 Pigment Orange 16Diketo-pyrrolo-pyrrole- Pigment Red 255Lake Red C (Ba)15585:1 Pigment Red 53:1Diketo-pyrrolo-pyrrole/Azo- -Diketo-pyrrolo-pyrrole56110 Pigment Red 254Diketo-pyrrolo-pyrrole- -Diketo-pyrrolo-pyrrole56110 Pigment Red 254Diketo-pyrrolo-pyrrole

Pigment Red 264Quinacridone73900 Pigment Violet 19Anthraquinone65300 Pigment Red 177Quinacridone

Pigment Red 282Quinacridone73900 Pigment Violet 19Dioxazine51319 Pigment Violet 23Indanthrone69800 Pigment Blue 60Cu-Phthalocyanine (α)74160 Pigment Blue 15:1Cu-Phthalocyanine (α non-flocc)74160 Pigment Blue 15:2Cu-Phthalocyanine (β)74160 Pigment Blue 15:3Cu-Phthalocyanine (halogenated)74260 Pigment Green 7

Product nameChemical typeCI No CI Generic name A

rchi

tect

ural

Gen

eral

indu

stry

Ap

plia

nce

Den

sity

(g/

cm3 )

Surf

ace

area

(m

2 /g)

Hea

t st

abili

ty (

°C)/

Ove

rpai

nt r

esis

tanc

e

Aci

d-fa

stne

ss/

Alka

li-fa

stne

ss

Full

shad

e

1/25

ISD

Op

acity

(m

ed =

med

ium

)

Col

or s

tren

gth

(1/2

5 IS

D)

PES/

TGIC

(p

art

TiO

2fo

r 1

par

t p

igm

ent)Fastness

PES/TGICApplications

9.6

9.1

85

27

22

15

51

18

27

25

14

32

20

62

60

64

58

53

64

58

57

41

2205

2205

2005

2205

2004-5200

52004-5220

5220

5200

5220

52004-5220

5220

5220

5220

5220

5220

5220

5220

5220

5200

5

4-55

4-555555

55

4-555555555555555555555555555555

4-5

4-5

4-5

4

4

4-5

3-4

4-5

4

4-5

4-5

4-5

4-5

4-5

4-5

4-5

5

4-5

4

4-5

4-5

4-5

4

4

4

4

4

4

4-5

4-5

4-5

4-5

4

4-5

4-5

4-5

4

4

high

high

low

med

high

high

low

med

med

high

high

high

med

med

med

high

low

low

high

high

med

med

1:19

1:21

1:49

1:60

1:82

1:54

1:87

1:80

1:111

1:125

1:77

1:105

1:50

1:87

1:87

1:67

1:225

1:61

1:133

1:130

1:159

1:71

5.9

6.1

1.5

1.8

1.4

1.4

1.8

1.6

1.6

1.4

1.6

1.5

1.5

1.4

1.5

1.5

1.5

1.6

1.5

1.6

2.2

Page 6: ciba

Product Selection Guide for Powder Coatings Ciba Specialty Chemicals 2005

6

IRGACOLOR® Yellow 3GLM

IRGACOLOR® Yellow 3RLM

IRGACOLOR® Yellow 5RLM

IRGACOLOR® Yellow 14247

IRGALITE® Yellow BRM

IRGALITE® Yellow BAWP

IRGAZIN® Yellow 2GLTE

IRGAZIN® Yellow 2RLT

CROMOPHTAL® Orange 2G

IRGAZIN® Orange 2037

IRGALITE® Red LCB

IRGALITE® Red FBL

IRGALITE® Red 2BY

IRGALITE® Red 2BSP

IRGALITE® Rubine 4BP

IRGAZIN® Red 2027

CHROMOPHTAL® Red A3B

IRGAZIN® DPP Rubine TR

CINQUASIA® Magenta B RT-343-D

CHROMOPHTAL® Pink PT

CINQUASIA® Violet R NRT-887-D

CINQUASIA® Violet R NRT-891-D

CINQUASIA® Violet R NRT-795-D

CROMOPHTAL® Violet B

IRGALITE® Blue BSNF

IRGALITE® Blue GBP

IRGALITE® Green GLNP

Bismuth vanadate771740 Pigment Yellow 184Bismuth vanadate

Bismuth vanadate

Bismuth vanadate

Diarylide o-Toluidide21095 Pigment Yellow 14Diarylide m-Xylidide

Pigment Yellow 13Isoindolinone56284 Pigment Yellow 109Tetrachloroisoindolinone56280 Pigment Yellow 110Tetrachloroisoindolinone11265 Pigment Orange 61Diketo-pyrrolo-pyrrole/isoindoline

Lake Red C (Ba)Pigment Red 53:1

Azo 2B-toner (Mn)15865:4 Pigment Red 48:4Azo 2B-toner (Sr)

Pigment Red 48:3Azo 2B-toner (Sr)

Pigment Red 48:3Azo 4B-toner (Ca)

Pigment Red 57:1Diketo-pyrrolo-pyrrole/Azo- -Anthraquinone65300 Pigment Red 177Diketo-pyrrolo-pyrrole- Pigment Red 264Quinacridone73907 Pigment Red 202Quinacridone73915 Pigment Red 122Quinacridone73900 Pigment Violet 19Quinacridone73900 Pigment Violet 19Quinacridone73900 Pigment Violet 19Dioxazine51345 Pigment Violet 37Cu-Phthalocyanine (α non-flocc)74160 Pigment Blue 15:2Cu-Phthalocyanine (β)74160 Pigment Blue 15:3Cu-Phthalocyanine (halogenated)74160 Pigment Green 7

Product nameChemical typeCI No CI Generic name A

rchi

tect

ural

Gen

eral

indu

stry

Ap

plia

nce

Den

sity

(g/

cm3 )

Surf

ace

area

(m

2 /g)

Applications

11

12

7.8

33

11

30

49

53

18

54

36

36

83

27

113

100

72

63

64

35

35

61

53

43

a greenish yellow bismuth vanadate pigmentwith excellent weather fastness, high saturation

reddish bismuth vanadate

reddish bismuth vanadate

a yellow bismuth vanadate pigment with good weather resistance

semi transparent classical yellow

semi transparent classical yellow

very pure greenish yellow with good allround properties

transparent reddish yellow pigment

orange with good weather resistance

high saturated opaque orange pigment

classical red for deep shade applications

classical bluish red for deep shade applications

classical red

classical red

classical bluish red

blue shade red with good weather fastness and opacityred pigment with high color strength andgood weather resistancetransparent DPP red pigment with outstanding

color strength, excellent durability and saturation

saturated transparent blue shade magenta

saturated blue shade magenta

high-performance pigment with excellent heat stability and durabilityhigh-performance pigment with excellent heat stability and durability

bluish red with excellent durability

high-performance pigment with excellent colorstrength used mainly as shading componentvery clean red shade alpha phtalocyanine blue with high color strengthhighly heat stable beta phtalocyanine blueoffering good allround properties

5.6

5.3

4.9

5.8

1.4

1.3

1.9

1.8

1.7

1.6

1.6

1.8

1.8

1.6

1.6

1.4

1.4

1.6

1.5

1.5

1.5

1.5

1.4

1.6

2.1

Page 7: ciba

Product Selection Guide for Powder Coatings Ciba Specialty Chemicals 2005

7

Chrome Yellow and Molybdate Orange Powder Pigments

Ciba® HORNACHROME® Yellow and Ciba® HORNA® Chrome Yellow pigments are widely used in many application fields.HORNACHROME®-A products are distinguished by extremely high color strength and opacity. The standard hues canvary from greenish to reddish yellow (lowest number indicates to most greenish hue, highest number most reddishhue). The HORNA® Chrome Yellow GU range consists of stabilized, brilliant shade yellows. HORNA® Chrome Yellow GMproducts are highly stabilized. HORNA® Chrome Yellow GMX products are highly stabilized and SO2-resistant.The standard hue of Ciba® HORNA® Molybdate Orange product ranges from yellowish to bluish orange (lowest numberindicates yellowest hue, highest number bluest hue). The HORNA® Molybdate Orange ML range offers higher light fastness and SO2-resistance.

HORNA® Chrome Yellow GUA-19

HORNA® Chrome Yellow GUAH-26

HORNA® Chrome Yellow GUAH-35

HORNA® Chrome Yellow GMH-35

HORNA® Chrome Yellow GMXH-35-SQ

HORNACHROME® Yellow GMXAH-25

HORNACHROME® Yellow GMXAH-35

HORNA® Molybdate Orange AAH-3-SQ

HORNA® Molybdate Orange MLH-74-SQ

HORNA® Molybdate Orange MLH-79-SQ

Lead (sulfo) chromate77603 Pigment Yellow 34Lead (sulfo) chromate77603 Pigment Yellow 34Lead chromate77600 Pigment Yellow 34Lead chromate77600 Pigment Yellow 34Lead chromate77600 Pigment Yellow 34Lead (sulfo) chromate 77603 Pigment Yellow 34Lead chromate77600 Pigment Yellow 34Mix crystal lead-(sulfo)-chromate-molybda77605 Pigment Red 104Mix crystal lead-(sulfo)-chromate-molybda77605 Pigment Red 104Mix crystal lead-(sulfo)-chromate-molybda77605 Pigment Red 104

Product nameChemical typeCI No CI Generic name A

rchi

tect

ural

Gen

eral

indu

stry

Ap

plia

nce

Den

sity

(g/

cm3 )

% S

olub

le le

ad

Hea

t st

abili

ty (

°C)/

Ove

rpai

nt r

esis

tanc

e

Aci

d-fa

stne

ss/

Alka

li-fa

stne

ss

Solv

ent

fast

ness

/SO

2re

sist

ance

Full

shad

e

1:10

TiO

2

Op

acity

Col

or s

tren

gth

(1/2

5 IS

D)

(g p

igm

ent/

100

g Ti

O2)

Weatherfastness

Applications

-

< 2%

< 2%

< 5%

< 2%

< 3%

< 2%

< 2%

< 2%

< 2%

2005

2005

2005

2005

2005

2005

2005

2005

2005

2005

4144443444

3-44-5241

3-41

4-51

3-4

525555535555555

4-55

4-55

4-5

4

4

4

4

4

4

4

4-5

4-5

4-5

4

4

4

4

4

4

4

4-5

4-5

4-5

high

high

high

high

high

high

high

high

high

high

1:20

1:25

1:34

1:13

1:13

1:13

5.2

5.0

5.0

5.5

5.0

5.0

5.1

6.2

6.2

6.2

Page 8: ciba

Product Selection Guide for Powder Coatings Ciba Specialty Chemicals 2005

8

Pigment Preparations

Ciba® MICROLEN®-UAThe MICROLEN®-UA pigment concentrate range consists of well proven pigments in a finely dispersed, free flowing anddust-free form, especially suitable for the pigmentation of powder coatings. Pigment content is about 50% in a specialUrea Aldehyde carrier.

MICROLEN® Red 2030-UA

MICROLEN® Blue 4GNP-UA

MICROLEN® Green GFN-UA

MICROLEN® Black B-UA

Diketo-pyrrolo-pyrrole56110 Pigment Red 254Cu-Phthalocyanine (β) 74160 Pigment Blue 15:3Cu-Phthalocyanine (halogenated)74260 Pigment Green 7

- -

Product nameChemical typeCI No CI Generic name A

rchi

tect

ural

Gen

eral

indu

stry

Ap

plia

nce

Hea

t st

abili

ty (

°C)

Full

shad

e

1/25

ISD

Op

acity

(m

ed =

med

ium

)

Col

or s

tren

gth

(1/2

5 IS

D)

PES/

TGIC

(p

art

TiO

2fo

r 1

par

t p

igm

ent)Fastness

PES/TGICApplications

4-5

4-5

4-5

4-5

4

4-5

4-5

5

med

med

med

high

1:51

1:90

1:38

1:78

220

220

220

220

Page 9: ciba

9

Product Selection Guide for Powder Coatings Ciba Specialty Chemicals 2005

The Ciba® TINUVIN® and the Ciba® CHIMASSORB® ranges consist of light stabilizers with different chemistries. The rangecontains two types of light stabilizer: Ultraviolet Light Absorbers (UV-A) and Hindered Amine Light Stabilizers (HALS).UV-A filter harmful UV light and prevent mainly discoloration and delamination of coatings. HALS trap free radicals oncethey are formed and are mainly effective to retain surface properties such as gloss and prevent cracking and chalking of paints. HALS and UV-A show when used in combination a synergistic effect. Some of the HALS presented below inaddition to their light stabilizers properties enhance triboelectric charging activity of powder coatings.Our extended product range enable to offer solutions for nearly all types of coatings technologies, including conventional and UV-curable powder.

For Absorbance Spectra of selected Ultraviolet Light Absorbers (UV-Absorbers), see Appendix.

Light Stabilizers

Product name Chemical type Arc

hite

ctur

al

Gen

eral

indu

stry

Ap

plia

nce

Phys

ical

for

m

Vola

tility

/the

rmal

sta

bilit

y(a

ctiv

e su

bsta

nce)

Mol

ecul

ar w

eigh

t (g

/mol

)

Basi

city

pK b

Mel

t p

oint

(°C

)

Den

sity

at

20°C

(g/

cm3 )

Mai

n ef

fect

Applications

non-volatilenon-

volatilenon-

volatile

non-volatilenon-

volatilenon-

volatile

non-volatile

141

113

74-77

146-150115-150

81-85

115-150

1.22

1.14

-

1.03

1.05

-

Light stabilizer

Light stabilizer

Light stabilizer

Light stabi-lizer Tribo

Tribo

Light stabilizer

Light stabi-lizer Tribo

solid

solid

solid

solid

solid

solid

solid

448

442

584

685

2286

481

-

-

-

-

5.5

-

5.0

-

Ultraviolet Light Absorbers (UV-Absorbers)

TINUVIN ®900 Benzotriazole

TINUVIN® 928 Benzotriazole

TINUVIN® 405 Triazine

Hindered Amine Light Stabilizers (HALS)

TINUVIN® 144 Hindered amine

CHIMASSORB® 119 FL Hindered amine

TINUVIN® 770 DF Hindered amine

HALS® Blends

TINUVIN® 111 FDL Hindered amine

Page 10: ciba

10

Product Selection Guide for Powder Coatings Ciba Specialty Chemicals 2005

Ciba® IRGANOX® and Ciba® IRGAFOS® antioxidants hinder thermally induced oxidation of polymers in coatings. Theytrap free radicals formed upon heating in presence of oxygen and prevent discoloration or change of resins mechanicalproperties.

Antioxidants

Product name Chemical type Arc

hite

ctur

al

Gen

eral

indu

stry

Ap

plia

nce

Phys

ical

for

m

Vola

tility

Mol

ecul

ar w

eigh

t (g

/mol

)

Mel

t p

oint

(°C

)

Den

sity

at

20°C

(g/

cm3 )

Applications

non-volatilenon-

volatilenon-

volatilenon-

volatilenon-

volatilenon-

volatilenon-

volatilenon-

volatile

110-12550-5576-79

183-186

>160

-

100-175

-

1.15

1.02

1.14

1.02

1.15

-

-

-

solid

solid

solid

solid

solid

solid

solid

solid

1178

531

587

647

604

-

-

-

IRGANOX® 1010 Phenolic

IRGANOX® 1076 Phenolic

IRGANOX® 245 Phenolic

IRGAFOS® 168 Phosphite

IRGAFOS® 126 Phosphite

IRGANOX® B225 Phenolic/Phosphite

IRGAFOS® XP 60 Lactone/Phosphite

IRGANOX® XP 620 Lactone/Phosphite/Phenolic

Page 11: ciba

Product Selection Guide for Powder Coatings Ciba Specialty Chemicals 2005

11

Ciba® UVITEX® optical brightener is designed to brighten coatings and to mask yellowing. Optical brightening agentcan also be used with the purpose to provide means of registration and coatings identification. Limited light fastnessimply use for indoor applications.

Optical Brighteners

Product name Chemical type Arc

hite

ctur

al

Gen

eral

indu

stry

Ap

plia

nce

Phys

ical

for

m

Vola

tility

Mol

ecul

ar w

eigh

t (g

/mol

)

Mel

t p

oint

(°C

)

Den

sity

at

20°C

(g/

cm3 )

Applications

non-volatile

197-202 1.26solid 430.6UVITEX® OB Benzoxazole

Page 12: ciba

Product Selection Guide for Powder Coatings Ciba Specialty Chemicals 2005

12

Ciba® IRGACURE®

The IRGACURE® range is part of Ciba Specialty Chemicals’ photoinitiators offer for Ultra Violet cured coatings. The tablebelow presents a selection of the photoinitiators which are suited to the specific requirements of UV-curable powders.IRGACURE® 2959 is mainly used for clear coats while in the case of pigmented coatings a combination of IRGACURE®

2959 and IRGACURE® 819 is needed.

Photoinitiators

Product name Chemical type Gen

eral

indu

stry

Furn

iture

Phys

ical

for

m

Vola

tility

Mol

ecul

ar w

eigh

t (g

/mol

)

Mel

t p

oint

(°C

)

Den

sity

at

20°C

(g/

cm3 )

Applications

non-volatilenon-

volatile

UV/

VIS

Abs

orp

tion

pea

ks (

nm)

in m

etha

nol

86-90

127-133

1.3

1.2

276,331

370,405

solid

solid

224

418

IRGACURE® 2959 α-Hydroxyketone

IRGACURE® 819 Bis Acyl Phosphine

For Absorbance Spectra of selected Photo-initiators, see Appendix.

Page 13: ciba

Product Selection Guide for Powder Coatings Ciba Specialty Chemicals 2005

13

Absorption Spectra of Ultraviolet Light Absorbers (UV-Absorbers)

Absorption Spectra of Photoinitiators

Appendix

TINUVIN® 405

0.0280 300

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8c = 20 mg/l in Toluene; path = 1 cm

Wavelength (nm)

Ab

sorb

ance

320 340 360 380 400 420

TINUVIN® 928

0.0280 300

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8c = 20 mg/l in Toluene; path = 1 cm

Wavelength (nm)A

bso

rban

ce

320 340 360 380 400 420

IRGACURE® 819

0200 225

0.5

1

1.5

2

2.5

3% in Acetonitrile

Wavelength (nm)

Exti

nct

ion

250 275 300 325 350 375 400 425 450 475

IRGACURE® 2959

0200 220

0.5

1

1.5

2

2.5

3% in Acetonitrile

Wavelength (nm)

Exti

nct

ion

240 260 280 300 320 340 360 380 400 420

0.10.010.001

0.10.010.001

Page 14: ciba

Product Selection Guide for Powder Coatings Ciba Specialty Chemicals 2005

14

Test Methods – Fastness Properties of PigmentsThe test methods used to assess chemical and physical fastness properties of Ciba Specialty Chemicals coatings pigmentproducts are described below.

Color IndexNames and numbers refer to entries in the Colour IndexInternational, Society of Dyers and Colorists, Bradford,England, 2000.

DensityMeasured in accordance to ISO 787/X and quoted ing/cm3 at 20°C.

Surface Area (Specific Surface)Determined by the “BET” nitrogen adsorption methodand is expressed in m2/g. (Ref. Brunauer, Emmet, Teller,“Journal Amer. Chem. Soc.” 57, 1954.)

Heat StabilityPowder coated panels of PES/TGIC are cured at differenttemperatures from 20 min. at 160 °C up to 20 min. at220°C. The panels are assessed versus the 20 min. at160°C panel. The classical pigments are tested in anepoxy polyester resin, In this case the temperatures rangeis between 20 min. at 140°C and 20 min. at 200°C. Thegiven value is the temperature at which only a very slightdiscoloration occurs.

Overpaint Resistance/BleedingDetermination carried out on full strength PES/TGICstoved finish coated with white alkyd melamine paintand restoved for 30 minutes at 130 °C. Discolorationagainst white background assessed using the ISO GrayScale 105 A02 (1–5) for color change (scale: 1 = severechange, 5 = no change).

Chemical FastnessResistance was tested on a PES/TGIC film against the ISOGray Scale 105 A02 (1–5) for color change (0.5 N HCl,2.5% NaOH) (scale: 1 = severe change, 5 = no change).

Fastness to Weathering ISO11341Resistance to weathering is determined on panels coatedwith PES/TGIC powder coating. Exposure was carried outin ATLAS Weather-0-Meter according to ISO11341(Method 1, Cycle A). The panels were exposed for2000 hrs. The assessment was made by using the GrayScale ISO 105 A02 (1 = lowest rating, 5 = highest).

OpacityThe opacity/hiding power was assessed in full shadebased on the contrast (∆E-value) over a black/whitepanel (Description: low = low opacity, transparent;med = medium opacity; high = high opacity).

Color Strength ISO 784/24The data for the color strength indicate how many partstitanium dioxide to one part color pigment or one part color pigment preparation. The higher the white pigment content needed, the higher the color strength.The data were determined in a Polyester/TGIC powdercoating system, the dispersion was carried out on a double screw extruder. These figures should be takenonly as a guide. Absolute ISD data is influenced verymuch by the specific polymer system used and by individual processing conditions.

Pigments – Organic and Inorganic Powder Pigments

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Product Selection Guide for Powder Coatings Ciba Specialty Chemicals 2005

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Color Index – Density – Oil Absorption –Heat Stability – Overpaint Resistance/Bleeding –Color Strength – Opacitysee above: Pigments – Organic and Inorganic Powder Pigments.

Soluble LeadMeasured in accordance to ISO 6713-2 and quoted aspercentage of soluble lead.

Chemical Fastness0.5% of dry pigment was mixed with 15 ml 5% HCI or1% NaOH solution. After 1 hour, the color differenceswere assessed against the ISO Gray Scale 105 A02 (1–5)(scale: 1= severe change, 5 = no change).

Solvent Fastness0.2 g of pigment was suspended in 10 ml of solvent in afolded filter. After 24 hrs the filter containing the pigmentwas removed and the staining of the solvent wasassessed using the ISO Gray Scale 105 A02 (1–5) (scale:1= severe change, 5 = no change).

SO2 ResistancePES/TGIC coated full strength panels were exposedaccording to DIN 50018 (3 cycles, 2 liters SO2). Assessment versus ISO Gray Scale 105 A02 (1–5) (scale:1= severe change, 5 = no change).

Weathering/DurabilityPanels at full shade and at 1:10 white reduction (TiO2)based on a PES/TGIC resin system were exposed for1000 hours in an Atlas Weather-0-Meter (Xenon burner,DIN 53–387). Assessment was made using the ISO GrayScale 105 A02 (1–5) for color change (scale: 1 = severechange, 5 = no change).

Pigments – Chrome Yellow and Molybdate Orange Powder Pigments

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Edition 2005Copyright© 2005 Ciba Specialty Chemicals Inc. All rights reserved.All trademarks mentioned are either property of or licensed to Ciba Specialty Chemicals and registered in relevantcountries.

IMPORTANT: The following supersedes Buyer’s documents. SELLER MAKES NO REPRESENTATION OR WARRANTY,EXPRESS OR IMPLIED, INCLUDING OF MERCHANTABILITY OR FITNESS FOR PURPOSES OTHER THAN THE INTEND-ED PURPOSE. No statements herein are to be construed as inducements to infringe any relevant patent. Under nocircumstances shall Seller be liable for incidental, consequential or indirect damages for alleged negligence, breachof warranty, strict liability, tort or contract arising in connection with the product(s). Buyer’s sole remedy and Seller’ssole liability for any claims shall be Buyer’s purchase price. Data and results are based on controlled or lab work andmust be confirmed by Buyer by testing for the intended conditions of use. The product(s) has (have) not been tested for, and is (are) therefore not recommended for, uses for which prolonged contact with mucous membranes,abraded skin, or blood is intended; or for uses for which implantation within the human body is intended.Please note that products may differ from country to country. If you have any queries, kindly contact your localCiba Specialty Chemicals representative. Further information at website: www.cibasc.com/coatingeffects

Ciba Specialty Chemicals is a member of: Ecological and Toxicological Association of Dyes and Organic Pigments Manufacturersc-26/2005, Printed in Switzerland Value beyond chemistry