ciba
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Ciba Specialty Chemicals
Coating Effects Value beyond chemistry
Product Selection Guidefor Powder Coatings
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Ciba® CHIMASSORB® Ciba® FILOFIN® Ciba® IRGAPHOR® Ciba® ORACET®
Ciba® CINQUASIA® Ciba® HORNA® Ciba® IRGAPLASTOL® Ciba® ORASOL®
Ciba® CROMOPHTAL® Ciba® HORNACHROME® Ciba® IRGAROL® Ciba® RHEOVIS®
Ciba® DAROCUR® Ciba® HORNATHERM Ciba® IRGASPERSE® Ciba® TINOPAL®
Ciba® DISPEX® Ciba® IRGACOLOR® Ciba® IRGAZIN® Ciba® TINUVIN®
Ciba® GLASCOL® Ciba® IRGACURE® Ciba® LIGNOSTAB® Ciba® UNISPERSE®
Ciba® GRAPHITAN® Ciba® IRGAFOS® Ciba® MICRANYL® Ciba® UVITEX®
Ciba® EFKA® Ciba® IRGAGUARD® Ciba® MICROLEN® Ciba® VISCALEX®
Ciba® FILAMID® Ciba® IRGALITE® Ciba® MICROLITH®
Ciba® FILESTER® Ciba® IRGANOX® Ciba® MICROSOL®
Ciba Specialty Chemicals trademarks (All trademarks mentioned are either property of or licensedto Ciba Specialty Chemicals and registered in relevant countries)
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Contents
Pigments 5Organic and Inorganic Powder Pigments 5, 6
Ciba® CINQUASIA®, Ciba® CROMOPHTAL®, Ciba® IRGACOLOR®, Ciba® IRGALITE®, Ciba® IRGAZIN®
Chrome Yellow and Molybdate Orange Powder Pigments 7Ciba® HORNACHROME®, Ciba® HORNA®
Pigment preparations 8Ciba® MICROLEN®
Light Stabilizers 9Ultraviolet Light Absorbers (UV-Absorbers) 9
Ciba® TINUVIN®
Hindered Amine Light Stabilizers (HALS) 9Ciba® CHIMASSORB®, Ciba® TINUVIN®
HALS Blend 9Ciba® TINUVIN®
Antioxidants 10Ciba® IRGAFOS®, Ciba® IRGANOX®
Optical Brightener 11Ciba® UVITEX®
Photoinitiators 12Ciba® IRGACURE®
Appendix 13Absorption Spectra of Ultraviolet Light Absorbers (UV-Absorbers) 13Absorption Spectra of Photoinitiators 13Test methods – Fastness Properties of Pigments 14, 15
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Introduction
Ciba Specialty Chemicals is a member of: Ecological and Toxicological Association of Dyes and Organic Pigments Manufacturers
Key to Symbols and Application Suitability
® Registered trademark RecommendedOther potential uses
Let us help you create effects that improve the quality of life!
Products, processes and services from Ciba Specialty Chemicals enable you to create effects that add performance, protection, color and strength to your coatings.
Product Selection Guide for Powder Coatings Ciba Specialty Chemicals 2005
4
This booklet provides a comprehensive list of the pigments and additives in the Ciba Specialty Chemicalsranges for powder coatings.
The products are divided into five main categories: pig-ments, light stabilizers, antioxidants, optical brighteners, photoinitiators.The pigment classes are subdivided into organic andinorganic pigments, chrome yellow and molybdateorange pigments, pigment preparations.
Suitable fields of application are indicated next to eachproduct, but it must be stressed that these are onlyintended as a general guide.
For more detailed information on specific applicationsand product control please consult our marketingdepartments or local sales organizations.
Further technical product information and details on usein food packaging materials, toys and other consumergoods (EHS data) are available on our Internet site at:
• www.cibasc.com Product Search
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Product Selection Guide for Powder Coatings Ciba Specialty Chemicals 2005
5
Organic and Inorganic Powder Pigments
Ciba® IRGAZIN®, Ciba® CROMOPHTAL® and Ciba® CINQUASIA® products are high-performance organic and inorganicpigments that combine very good tinctorial properties with excellent fastness to light, weather, chemicals and solvents.They fulfill the requirements of the most critical applications.The Ciba® IRGALITE® range consists of classical organic pigments. Ciba® IRGACOLOR® pigments are inorganic pigmentswith outstanding resistance to heat, weather and chemicals.
Pigments
IRGAZIN® Yellow 2093
IRGAZIN® Yellow 2094
CROMOPHTAL® Yellow 8GN
IRGAZIN® Yellow 3RLTN
IRGALITE® Orange MOR
IRGAZIN® DPP Scarlet EK
IRGALITE® Red CLO
IRGAZIN® Red 2029
IRGAZIN® Red 2030
IRGAZIN® Red 2031
IRGAZIN® DPP Red BO
IRGAZIN® DPP Red Ultra Opaque
CINQUASIA® Red Y RT-759-D
IRGAZIN® Red A2BN
IRGAZIN® Magenta 2012
CINQUASIA® Violet R NRT-201-D
CROMOPHTAL® Violet GT
IRGAZIN® Blue A3RN
IRGALITE® Blue BSP
IRGALITE® Blue 2234
IRGALITE® Blue PG
IRGALITE® Green GLN
Bismuth vanadate771740 Pigment Yellow 184Bismuth vanadate771740 Pigment Yellow 184Azo condensation20037 Pigment Yellow 128Tetrachloroisoindolinone56280 Pigment Yellow 110Dianisidine Orange21160 Pigment Orange 16Diketo-pyrrolo-pyrrole- Pigment Red 255Lake Red C (Ba)15585:1 Pigment Red 53:1Diketo-pyrrolo-pyrrole/Azo- -Diketo-pyrrolo-pyrrole56110 Pigment Red 254Diketo-pyrrolo-pyrrole- -Diketo-pyrrolo-pyrrole56110 Pigment Red 254Diketo-pyrrolo-pyrrole
Pigment Red 264Quinacridone73900 Pigment Violet 19Anthraquinone65300 Pigment Red 177Quinacridone
Pigment Red 282Quinacridone73900 Pigment Violet 19Dioxazine51319 Pigment Violet 23Indanthrone69800 Pigment Blue 60Cu-Phthalocyanine (α)74160 Pigment Blue 15:1Cu-Phthalocyanine (α non-flocc)74160 Pigment Blue 15:2Cu-Phthalocyanine (β)74160 Pigment Blue 15:3Cu-Phthalocyanine (halogenated)74260 Pigment Green 7
Product nameChemical typeCI No CI Generic name A
rchi
tect
ural
Gen
eral
indu
stry
Ap
plia
nce
Den
sity
(g/
cm3 )
Surf
ace
area
(m
2 /g)
Hea
t st
abili
ty (
°C)/
Ove
rpai
nt r
esis
tanc
e
Aci
d-fa
stne
ss/
Alka
li-fa
stne
ss
Full
shad
e
1/25
ISD
Op
acity
(m
ed =
med
ium
)
Col
or s
tren
gth
(1/2
5 IS
D)
PES/
TGIC
(p
art
TiO
2fo
r 1
par
t p
igm
ent)Fastness
PES/TGICApplications
9.6
9.1
85
27
22
15
51
18
27
25
14
32
20
62
60
64
58
53
64
58
57
41
2205
2205
2005
2205
2004-5200
52004-5220
5220
5200
5220
52004-5220
5220
5220
5220
5220
5220
5220
5220
5220
5200
5
4-55
4-555555
55
4-555555555555555555555555555555
4-5
4-5
4-5
4
4
4-5
3-4
4-5
4
4-5
4-5
4-5
4-5
4-5
4-5
4-5
5
4-5
4
4-5
4-5
4-5
4
4
4
4
4
4
4-5
4-5
4-5
4-5
4
4-5
4-5
4-5
4
4
high
high
low
med
high
high
low
med
med
high
high
high
med
med
med
high
low
low
high
high
med
med
1:19
1:21
1:49
1:60
1:82
1:54
1:87
1:80
1:111
1:125
1:77
1:105
1:50
1:87
1:87
1:67
1:225
1:61
1:133
1:130
1:159
1:71
5.9
6.1
1.5
1.8
1.4
1.4
1.8
1.6
1.6
1.4
1.6
1.5
1.5
1.4
1.5
1.5
1.5
1.6
1.5
1.6
2.2
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Product Selection Guide for Powder Coatings Ciba Specialty Chemicals 2005
6
IRGACOLOR® Yellow 3GLM
IRGACOLOR® Yellow 3RLM
IRGACOLOR® Yellow 5RLM
IRGACOLOR® Yellow 14247
IRGALITE® Yellow BRM
IRGALITE® Yellow BAWP
IRGAZIN® Yellow 2GLTE
IRGAZIN® Yellow 2RLT
CROMOPHTAL® Orange 2G
IRGAZIN® Orange 2037
IRGALITE® Red LCB
IRGALITE® Red FBL
IRGALITE® Red 2BY
IRGALITE® Red 2BSP
IRGALITE® Rubine 4BP
IRGAZIN® Red 2027
CHROMOPHTAL® Red A3B
IRGAZIN® DPP Rubine TR
CINQUASIA® Magenta B RT-343-D
CHROMOPHTAL® Pink PT
CINQUASIA® Violet R NRT-887-D
CINQUASIA® Violet R NRT-891-D
CINQUASIA® Violet R NRT-795-D
CROMOPHTAL® Violet B
IRGALITE® Blue BSNF
IRGALITE® Blue GBP
IRGALITE® Green GLNP
Bismuth vanadate771740 Pigment Yellow 184Bismuth vanadate
Bismuth vanadate
Bismuth vanadate
Diarylide o-Toluidide21095 Pigment Yellow 14Diarylide m-Xylidide
Pigment Yellow 13Isoindolinone56284 Pigment Yellow 109Tetrachloroisoindolinone56280 Pigment Yellow 110Tetrachloroisoindolinone11265 Pigment Orange 61Diketo-pyrrolo-pyrrole/isoindoline
Lake Red C (Ba)Pigment Red 53:1
Azo 2B-toner (Mn)15865:4 Pigment Red 48:4Azo 2B-toner (Sr)
Pigment Red 48:3Azo 2B-toner (Sr)
Pigment Red 48:3Azo 4B-toner (Ca)
Pigment Red 57:1Diketo-pyrrolo-pyrrole/Azo- -Anthraquinone65300 Pigment Red 177Diketo-pyrrolo-pyrrole- Pigment Red 264Quinacridone73907 Pigment Red 202Quinacridone73915 Pigment Red 122Quinacridone73900 Pigment Violet 19Quinacridone73900 Pigment Violet 19Quinacridone73900 Pigment Violet 19Dioxazine51345 Pigment Violet 37Cu-Phthalocyanine (α non-flocc)74160 Pigment Blue 15:2Cu-Phthalocyanine (β)74160 Pigment Blue 15:3Cu-Phthalocyanine (halogenated)74160 Pigment Green 7
Product nameChemical typeCI No CI Generic name A
rchi
tect
ural
Gen
eral
indu
stry
Ap
plia
nce
Den
sity
(g/
cm3 )
Surf
ace
area
(m
2 /g)
Applications
11
12
7.8
33
11
30
49
53
18
54
36
36
83
27
113
100
72
63
64
35
35
61
53
43
a greenish yellow bismuth vanadate pigmentwith excellent weather fastness, high saturation
reddish bismuth vanadate
reddish bismuth vanadate
a yellow bismuth vanadate pigment with good weather resistance
semi transparent classical yellow
semi transparent classical yellow
very pure greenish yellow with good allround properties
transparent reddish yellow pigment
orange with good weather resistance
high saturated opaque orange pigment
classical red for deep shade applications
classical bluish red for deep shade applications
classical red
classical red
classical bluish red
blue shade red with good weather fastness and opacityred pigment with high color strength andgood weather resistancetransparent DPP red pigment with outstanding
color strength, excellent durability and saturation
saturated transparent blue shade magenta
saturated blue shade magenta
high-performance pigment with excellent heat stability and durabilityhigh-performance pigment with excellent heat stability and durability
bluish red with excellent durability
high-performance pigment with excellent colorstrength used mainly as shading componentvery clean red shade alpha phtalocyanine blue with high color strengthhighly heat stable beta phtalocyanine blueoffering good allround properties
5.6
5.3
4.9
5.8
1.4
1.3
1.9
1.8
1.7
1.6
1.6
1.8
1.8
1.6
1.6
1.4
1.4
1.6
1.5
1.5
1.5
1.5
1.4
1.6
2.1
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Product Selection Guide for Powder Coatings Ciba Specialty Chemicals 2005
7
Chrome Yellow and Molybdate Orange Powder Pigments
Ciba® HORNACHROME® Yellow and Ciba® HORNA® Chrome Yellow pigments are widely used in many application fields.HORNACHROME®-A products are distinguished by extremely high color strength and opacity. The standard hues canvary from greenish to reddish yellow (lowest number indicates to most greenish hue, highest number most reddishhue). The HORNA® Chrome Yellow GU range consists of stabilized, brilliant shade yellows. HORNA® Chrome Yellow GMproducts are highly stabilized. HORNA® Chrome Yellow GMX products are highly stabilized and SO2-resistant.The standard hue of Ciba® HORNA® Molybdate Orange product ranges from yellowish to bluish orange (lowest numberindicates yellowest hue, highest number bluest hue). The HORNA® Molybdate Orange ML range offers higher light fastness and SO2-resistance.
HORNA® Chrome Yellow GUA-19
HORNA® Chrome Yellow GUAH-26
HORNA® Chrome Yellow GUAH-35
HORNA® Chrome Yellow GMH-35
HORNA® Chrome Yellow GMXH-35-SQ
HORNACHROME® Yellow GMXAH-25
HORNACHROME® Yellow GMXAH-35
HORNA® Molybdate Orange AAH-3-SQ
HORNA® Molybdate Orange MLH-74-SQ
HORNA® Molybdate Orange MLH-79-SQ
Lead (sulfo) chromate77603 Pigment Yellow 34Lead (sulfo) chromate77603 Pigment Yellow 34Lead chromate77600 Pigment Yellow 34Lead chromate77600 Pigment Yellow 34Lead chromate77600 Pigment Yellow 34Lead (sulfo) chromate 77603 Pigment Yellow 34Lead chromate77600 Pigment Yellow 34Mix crystal lead-(sulfo)-chromate-molybda77605 Pigment Red 104Mix crystal lead-(sulfo)-chromate-molybda77605 Pigment Red 104Mix crystal lead-(sulfo)-chromate-molybda77605 Pigment Red 104
Product nameChemical typeCI No CI Generic name A
rchi
tect
ural
Gen
eral
indu
stry
Ap
plia
nce
Den
sity
(g/
cm3 )
% S
olub
le le
ad
Hea
t st
abili
ty (
°C)/
Ove
rpai
nt r
esis
tanc
e
Aci
d-fa
stne
ss/
Alka
li-fa
stne
ss
Solv
ent
fast
ness
/SO
2re
sist
ance
Full
shad
e
1:10
TiO
2
Op
acity
Col
or s
tren
gth
(1/2
5 IS
D)
(g p
igm
ent/
100
g Ti
O2)
Weatherfastness
Applications
-
< 2%
< 2%
< 5%
< 2%
< 3%
< 2%
< 2%
< 2%
< 2%
2005
2005
2005
2005
2005
2005
2005
2005
2005
2005
4144443444
3-44-5241
3-41
4-51
3-4
525555535555555
4-55
4-55
4-5
4
4
4
4
4
4
4
4-5
4-5
4-5
4
4
4
4
4
4
4
4-5
4-5
4-5
high
high
high
high
high
high
high
high
high
high
1:20
1:25
1:34
1:13
1:13
1:13
5.2
5.0
5.0
5.5
5.0
5.0
5.1
6.2
6.2
6.2
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Product Selection Guide for Powder Coatings Ciba Specialty Chemicals 2005
8
Pigment Preparations
Ciba® MICROLEN®-UAThe MICROLEN®-UA pigment concentrate range consists of well proven pigments in a finely dispersed, free flowing anddust-free form, especially suitable for the pigmentation of powder coatings. Pigment content is about 50% in a specialUrea Aldehyde carrier.
MICROLEN® Red 2030-UA
MICROLEN® Blue 4GNP-UA
MICROLEN® Green GFN-UA
MICROLEN® Black B-UA
Diketo-pyrrolo-pyrrole56110 Pigment Red 254Cu-Phthalocyanine (β) 74160 Pigment Blue 15:3Cu-Phthalocyanine (halogenated)74260 Pigment Green 7
- -
Product nameChemical typeCI No CI Generic name A
rchi
tect
ural
Gen
eral
indu
stry
Ap
plia
nce
Hea
t st
abili
ty (
°C)
Full
shad
e
1/25
ISD
Op
acity
(m
ed =
med
ium
)
Col
or s
tren
gth
(1/2
5 IS
D)
PES/
TGIC
(p
art
TiO
2fo
r 1
par
t p
igm
ent)Fastness
PES/TGICApplications
4-5
4-5
4-5
4-5
4
4-5
4-5
5
med
med
med
high
1:51
1:90
1:38
1:78
220
220
220
220
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9
Product Selection Guide for Powder Coatings Ciba Specialty Chemicals 2005
The Ciba® TINUVIN® and the Ciba® CHIMASSORB® ranges consist of light stabilizers with different chemistries. The rangecontains two types of light stabilizer: Ultraviolet Light Absorbers (UV-A) and Hindered Amine Light Stabilizers (HALS).UV-A filter harmful UV light and prevent mainly discoloration and delamination of coatings. HALS trap free radicals oncethey are formed and are mainly effective to retain surface properties such as gloss and prevent cracking and chalking of paints. HALS and UV-A show when used in combination a synergistic effect. Some of the HALS presented below inaddition to their light stabilizers properties enhance triboelectric charging activity of powder coatings.Our extended product range enable to offer solutions for nearly all types of coatings technologies, including conventional and UV-curable powder.
For Absorbance Spectra of selected Ultraviolet Light Absorbers (UV-Absorbers), see Appendix.
Light Stabilizers
Product name Chemical type Arc
hite
ctur
al
Gen
eral
indu
stry
Ap
plia
nce
Phys
ical
for
m
Vola
tility
/the
rmal
sta
bilit
y(a
ctiv
e su
bsta
nce)
Mol
ecul
ar w
eigh
t (g
/mol
)
Basi
city
pK b
Mel
t p
oint
(°C
)
Den
sity
at
20°C
(g/
cm3 )
Mai
n ef
fect
Applications
non-volatilenon-
volatilenon-
volatile
non-volatilenon-
volatilenon-
volatile
non-volatile
141
113
74-77
146-150115-150
81-85
115-150
1.22
1.14
-
1.03
1.05
-
Light stabilizer
Light stabilizer
Light stabilizer
Light stabi-lizer Tribo
Tribo
Light stabilizer
Light stabi-lizer Tribo
solid
solid
solid
solid
solid
solid
solid
448
442
584
685
2286
481
-
-
-
-
5.5
-
5.0
-
Ultraviolet Light Absorbers (UV-Absorbers)
TINUVIN ®900 Benzotriazole
TINUVIN® 928 Benzotriazole
TINUVIN® 405 Triazine
Hindered Amine Light Stabilizers (HALS)
TINUVIN® 144 Hindered amine
CHIMASSORB® 119 FL Hindered amine
TINUVIN® 770 DF Hindered amine
HALS® Blends
TINUVIN® 111 FDL Hindered amine
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10
Product Selection Guide for Powder Coatings Ciba Specialty Chemicals 2005
Ciba® IRGANOX® and Ciba® IRGAFOS® antioxidants hinder thermally induced oxidation of polymers in coatings. Theytrap free radicals formed upon heating in presence of oxygen and prevent discoloration or change of resins mechanicalproperties.
Antioxidants
Product name Chemical type Arc
hite
ctur
al
Gen
eral
indu
stry
Ap
plia
nce
Phys
ical
for
m
Vola
tility
Mol
ecul
ar w
eigh
t (g
/mol
)
Mel
t p
oint
(°C
)
Den
sity
at
20°C
(g/
cm3 )
Applications
non-volatilenon-
volatilenon-
volatilenon-
volatilenon-
volatilenon-
volatilenon-
volatilenon-
volatile
110-12550-5576-79
183-186
>160
-
100-175
-
1.15
1.02
1.14
1.02
1.15
-
-
-
solid
solid
solid
solid
solid
solid
solid
solid
1178
531
587
647
604
-
-
-
IRGANOX® 1010 Phenolic
IRGANOX® 1076 Phenolic
IRGANOX® 245 Phenolic
IRGAFOS® 168 Phosphite
IRGAFOS® 126 Phosphite
IRGANOX® B225 Phenolic/Phosphite
IRGAFOS® XP 60 Lactone/Phosphite
IRGANOX® XP 620 Lactone/Phosphite/Phenolic
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Product Selection Guide for Powder Coatings Ciba Specialty Chemicals 2005
11
Ciba® UVITEX® optical brightener is designed to brighten coatings and to mask yellowing. Optical brightening agentcan also be used with the purpose to provide means of registration and coatings identification. Limited light fastnessimply use for indoor applications.
Optical Brighteners
Product name Chemical type Arc
hite
ctur
al
Gen
eral
indu
stry
Ap
plia
nce
Phys
ical
for
m
Vola
tility
Mol
ecul
ar w
eigh
t (g
/mol
)
Mel
t p
oint
(°C
)
Den
sity
at
20°C
(g/
cm3 )
Applications
non-volatile
197-202 1.26solid 430.6UVITEX® OB Benzoxazole
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Product Selection Guide for Powder Coatings Ciba Specialty Chemicals 2005
12
Ciba® IRGACURE®
The IRGACURE® range is part of Ciba Specialty Chemicals’ photoinitiators offer for Ultra Violet cured coatings. The tablebelow presents a selection of the photoinitiators which are suited to the specific requirements of UV-curable powders.IRGACURE® 2959 is mainly used for clear coats while in the case of pigmented coatings a combination of IRGACURE®
2959 and IRGACURE® 819 is needed.
Photoinitiators
Product name Chemical type Gen
eral
indu
stry
Furn
iture
Phys
ical
for
m
Vola
tility
Mol
ecul
ar w
eigh
t (g
/mol
)
Mel
t p
oint
(°C
)
Den
sity
at
20°C
(g/
cm3 )
Applications
non-volatilenon-
volatile
UV/
VIS
Abs
orp
tion
pea
ks (
nm)
in m
etha
nol
86-90
127-133
1.3
1.2
276,331
370,405
solid
solid
224
418
IRGACURE® 2959 α-Hydroxyketone
IRGACURE® 819 Bis Acyl Phosphine
For Absorbance Spectra of selected Photo-initiators, see Appendix.
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Product Selection Guide for Powder Coatings Ciba Specialty Chemicals 2005
13
Absorption Spectra of Ultraviolet Light Absorbers (UV-Absorbers)
Absorption Spectra of Photoinitiators
Appendix
TINUVIN® 405
0.0280 300
0.1
0.2
0.3
0.4
0.5
0.6
0.7
0.8c = 20 mg/l in Toluene; path = 1 cm
Wavelength (nm)
Ab
sorb
ance
320 340 360 380 400 420
TINUVIN® 928
0.0280 300
0.1
0.2
0.3
0.4
0.5
0.6
0.7
0.8c = 20 mg/l in Toluene; path = 1 cm
Wavelength (nm)A
bso
rban
ce
320 340 360 380 400 420
IRGACURE® 819
0200 225
0.5
1
1.5
2
2.5
3% in Acetonitrile
Wavelength (nm)
Exti
nct
ion
250 275 300 325 350 375 400 425 450 475
IRGACURE® 2959
0200 220
0.5
1
1.5
2
2.5
3% in Acetonitrile
Wavelength (nm)
Exti
nct
ion
240 260 280 300 320 340 360 380 400 420
0.10.010.001
0.10.010.001
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Product Selection Guide for Powder Coatings Ciba Specialty Chemicals 2005
14
Test Methods – Fastness Properties of PigmentsThe test methods used to assess chemical and physical fastness properties of Ciba Specialty Chemicals coatings pigmentproducts are described below.
Color IndexNames and numbers refer to entries in the Colour IndexInternational, Society of Dyers and Colorists, Bradford,England, 2000.
DensityMeasured in accordance to ISO 787/X and quoted ing/cm3 at 20°C.
Surface Area (Specific Surface)Determined by the “BET” nitrogen adsorption methodand is expressed in m2/g. (Ref. Brunauer, Emmet, Teller,“Journal Amer. Chem. Soc.” 57, 1954.)
Heat StabilityPowder coated panels of PES/TGIC are cured at differenttemperatures from 20 min. at 160 °C up to 20 min. at220°C. The panels are assessed versus the 20 min. at160°C panel. The classical pigments are tested in anepoxy polyester resin, In this case the temperatures rangeis between 20 min. at 140°C and 20 min. at 200°C. Thegiven value is the temperature at which only a very slightdiscoloration occurs.
Overpaint Resistance/BleedingDetermination carried out on full strength PES/TGICstoved finish coated with white alkyd melamine paintand restoved for 30 minutes at 130 °C. Discolorationagainst white background assessed using the ISO GrayScale 105 A02 (1–5) for color change (scale: 1 = severechange, 5 = no change).
Chemical FastnessResistance was tested on a PES/TGIC film against the ISOGray Scale 105 A02 (1–5) for color change (0.5 N HCl,2.5% NaOH) (scale: 1 = severe change, 5 = no change).
Fastness to Weathering ISO11341Resistance to weathering is determined on panels coatedwith PES/TGIC powder coating. Exposure was carried outin ATLAS Weather-0-Meter according to ISO11341(Method 1, Cycle A). The panels were exposed for2000 hrs. The assessment was made by using the GrayScale ISO 105 A02 (1 = lowest rating, 5 = highest).
OpacityThe opacity/hiding power was assessed in full shadebased on the contrast (∆E-value) over a black/whitepanel (Description: low = low opacity, transparent;med = medium opacity; high = high opacity).
Color Strength ISO 784/24The data for the color strength indicate how many partstitanium dioxide to one part color pigment or one part color pigment preparation. The higher the white pigment content needed, the higher the color strength.The data were determined in a Polyester/TGIC powdercoating system, the dispersion was carried out on a double screw extruder. These figures should be takenonly as a guide. Absolute ISD data is influenced verymuch by the specific polymer system used and by individual processing conditions.
Pigments – Organic and Inorganic Powder Pigments
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Product Selection Guide for Powder Coatings Ciba Specialty Chemicals 2005
15
Color Index – Density – Oil Absorption –Heat Stability – Overpaint Resistance/Bleeding –Color Strength – Opacitysee above: Pigments – Organic and Inorganic Powder Pigments.
Soluble LeadMeasured in accordance to ISO 6713-2 and quoted aspercentage of soluble lead.
Chemical Fastness0.5% of dry pigment was mixed with 15 ml 5% HCI or1% NaOH solution. After 1 hour, the color differenceswere assessed against the ISO Gray Scale 105 A02 (1–5)(scale: 1= severe change, 5 = no change).
Solvent Fastness0.2 g of pigment was suspended in 10 ml of solvent in afolded filter. After 24 hrs the filter containing the pigmentwas removed and the staining of the solvent wasassessed using the ISO Gray Scale 105 A02 (1–5) (scale:1= severe change, 5 = no change).
SO2 ResistancePES/TGIC coated full strength panels were exposedaccording to DIN 50018 (3 cycles, 2 liters SO2). Assessment versus ISO Gray Scale 105 A02 (1–5) (scale:1= severe change, 5 = no change).
Weathering/DurabilityPanels at full shade and at 1:10 white reduction (TiO2)based on a PES/TGIC resin system were exposed for1000 hours in an Atlas Weather-0-Meter (Xenon burner,DIN 53–387). Assessment was made using the ISO GrayScale 105 A02 (1–5) for color change (scale: 1 = severechange, 5 = no change).
Pigments – Chrome Yellow and Molybdate Orange Powder Pigments
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Edition 2005Copyright© 2005 Ciba Specialty Chemicals Inc. All rights reserved.All trademarks mentioned are either property of or licensed to Ciba Specialty Chemicals and registered in relevantcountries.
IMPORTANT: The following supersedes Buyer’s documents. SELLER MAKES NO REPRESENTATION OR WARRANTY,EXPRESS OR IMPLIED, INCLUDING OF MERCHANTABILITY OR FITNESS FOR PURPOSES OTHER THAN THE INTEND-ED PURPOSE. No statements herein are to be construed as inducements to infringe any relevant patent. Under nocircumstances shall Seller be liable for incidental, consequential or indirect damages for alleged negligence, breachof warranty, strict liability, tort or contract arising in connection with the product(s). Buyer’s sole remedy and Seller’ssole liability for any claims shall be Buyer’s purchase price. Data and results are based on controlled or lab work andmust be confirmed by Buyer by testing for the intended conditions of use. The product(s) has (have) not been tested for, and is (are) therefore not recommended for, uses for which prolonged contact with mucous membranes,abraded skin, or blood is intended; or for uses for which implantation within the human body is intended.Please note that products may differ from country to country. If you have any queries, kindly contact your localCiba Specialty Chemicals representative. Further information at website: www.cibasc.com/coatingeffects
Ciba Specialty Chemicals is a member of: Ecological and Toxicological Association of Dyes and Organic Pigments Manufacturersc-26/2005, Printed in Switzerland Value beyond chemistry