chemwest analytical laboratories, inc ...operations of chemwest's analytical laboratories and...

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CHEMWEST ANALYTICAL LABORATORIES, INC.

CHEUWEST STAFF LIST

February 1992 Revision

8-R30257I

CHEMWEST STAFF UST

ENVIRONMENTAL OPERATIONS

February 1992

This page left intentionally blank.

AR3Q2572

CHEMWEST STAFF UST


February 1992

Management/Administration

Steve Sineof General Manager

Joel C. Bird Director of Laboratory Operations

Admintttration/Flnance

Jeannice Perry Administration ManagerJerritee Don* hue Human Resources

i

Lillian Trujillo-Poyrrter Accounting/Purchasing Agent

Gidget Brogden Assistant Accountant

Yolanda Martinez Receptionist/SecretaryDenise Syljuberget Data Specialist

Karen Thomet Data Control Technician

Quality Assurance

Karyl Papenberg Quality Assurance Manager [Quality Assurance Officer]

Jo-Dee Bancroft - Quality Assurance Laboratory Assistant

Doug Kiahold Quality Assurance Laboratory Technician;Standards Preparation

Sales/Marketing

Debbie Pearce Project Manager

Sandy Autry Account Executive

Mary Moran Account Executive

VinceSchmidt Senior Project Manager

Noreen Seehuber Administrative Assistant

CHEMWEtT AnHytte* UfcoiUnriM, ton.

AR302573

CHEMWEST STAFF LIST


February 1992

Sates/Marketing {Continued!

Nathan Frank Corporate Outside Sales

Systems

Harold (Chip) Cray Systems Manager [Systems Manger] [Program Analyst]

Jeff Drewes Systems Support - Personal Computers

Sample Control

Bill McBenge Sample Control Manager [Sample Custodian]

Susan Gilbert Sample Control Technician

Chem Lab

F. Thomas Kwoka Chem Lab Laboratory[Sample Preparation Supervisor]

Scon Pieters Technical Leader[Extractions Concentration Specialist]

Verle Heyer Technical Leader; Sr. Chemist

Tom Helmbrecht Chemist I

Gary Biase Chemist I

Brenda Hudson Laboratory Technician

Ryanne 0' Brian Chemist I•

Mike VTanl Chemist I

CHEUWESTAmlyt!c4

CHEMWEST STAFF LIST


____ February 1992

Metals Laboratory

Allan Wong Metals Laboratory Manager

PamRivera Metals Chemist I

Nancy Melicharek-Harriger Metals Chemist INichole Rucker Laboratory Technician - Metals DigestTheresa Shirley Chemist I - Metals Digest

Kerri Chapin Data Specialist

GC Laboratory

Kirk J. Pocan GC Laboratory Manager [GC LaboratorySupervisor]

Tarek Troy Gayion GC Senior Chemist Supervisor[Pesticide Residue Analysis Expert]

Pam McCorduck GC Chemist II

Laide Duromoia GC Chemist I#

Jane LaTona GC Chemist III [GC/MS Operator]

Vicki McCartney GC Chemist II

Jerry Holycross GC Chemist II

Helen Smpardos GC Chemist II

Wai Wong GC Chemist II

Jimmy Byers Laboratory Technician

Earl Maxson Data Specialist

CHEMWEST Artfytfctf UtenkNlM. toe. P«B«iefa

flR.302575

CHEMWEST STAFF LIST


February 1992

Elaine Wong GC/MS Laboratory Manager [GC/MS Supervisor; MassSpectral Interpretation Specialist; GC/MS Operator]

Rich Henson GC/MS Senior Chemist Supervisor SV & VOA[GC/MSOperator;Mass Spectral Interpretation Specialist]

John Medina GC/MS Senior Chemist Supervisor Dioxin[Dioxin Extraction Specialist; Dioxin Specialist;GC/MSOperator]

Leona Winner Chemist II - Night Supervisor[GC/MS Operator]

Kurt Kulhavy Chemist I[GC/MS Operator]

Diane Page Chemist II[GC/MS Operator;Mass SpectralInterpretation Specialist]

Alice Roach Data Specialist [Organic Data Reporting and DeliverySpecialist]

Theresa Sehmidt Data Specialist[0rganic Data Reporting and DeliverySpecialist]

Greg Brisk! Chemist I Dioxin Extractor

Greg Cole Chemist II Dioxin Extractor[Dioxin Extraction Specialist]

Kathy Kanagaki Chemist I

Chuck Taylor Chemist ll[Diox!n Extraction Spec!alist;GC/MS Operator]

Barbara Adler Data Specialist [Dioxin Data Reporting and DeliverySpecialist]

General Services

Randy Smith In$trumentation[ln-House Service Specialist]Alfonso Vttela Facilities Technician

The titles in brackets, Q, represent EPA functions.

CHEMWESTAnrtytta* UtentMfa*to*. Peg*(ate

flR3Q2576

CHEMWESTManagement/Administration

Joel C. BirdDirector ofLaboratory ~Optrations

Steve Sincoff_ General

Manager

Karyl PaptnbergQuality Asturanct

Manager

Jeannice PerryAdministrationManager (Non-Finance)

Harold (Chip) CraySystemsManager

Debbie PearceProjectManager

Randy SmithGeneral ServicesManager

Open PositionSalesManager

AR302577 Revlslon °21492

CHEMWESTADMINISTRATION/FINANCE

Rick ScottCorporateController Steve

SincoffGeneralManager

Jeannice PerryAdministration

Manager

Jerrilee DonahueHuman ResourcesDepartment

Lillian Trujillo-PoynterAccounting/Purchasing

Gidget BrogdenAssistantAccountant

Yolanda MartinezReceptionist/Secretary

Denise SyljubergetDataSpecialist

Karen ThometData ControlTechnician

AR302578 Revision 021492

CHEMWESTQuality Assurance

\

Robert E. MeiererCorporate V.P

Quality Assurance

Karyl PapenbergQuality Assurance

Manager

Jo-Dee BancroftQuality AssuranceLaboratory Assistant

Doug KlaholdQA Lab. TechnicianStandards Preparation

Steve SineoffGeneralManager

HR302579 Revision °21492

CHEMWESTSales-Marketing/Project Management

Nltltnil •*!•«

Account AdministrativeExecutive Assistant

Steve Sincoff „.General 'OUManager

"""""" " VOpen Position

SalesManager

\

— Sandy AutryAccountExecutive

— Marv Moran

•Debbie Pearce

ProjectManagement

— Vince SchmidtSenior ProjectManager

— Noreen Seehuber

Httktn Fr**k

Outsit* •«!••

flR3Q2580*evision 021492

CHEMWESTSystems

Steve SincoffGeneral Manager

Harold (Chip) CraySystems Manager

Jeff DrewesSystems SupportPersonal ComputerOpen PositionSystems SupportLaboratory Automation

AR30258I

Revision 021492

CHEMWESTSample Control

Joel C. BirdDirector of Laboratory

Operations

Bill McBengeSample Control

Manager

Susan GilbertSample ControlTechnician

Open PositionSample ControlTechnician

Open PositionCourier

AR3Q2582 Revision 021492

CHEMWESTChem Lab

f


Operationa

•

F. Thomas KwokaChem Lab.

Laboratory ManagerX.

V

Verle HeyerSenior Chemist

Technical Leader

.. *

Scott PitteraTechnical Leader

Tom HelmbreehtChemist I

Ryanne O'BrienChemist I

Hike VianiChemist I

Gary BiaseChemist I

Brenda HudsonLaboratoryTechnician

Open PositionChemist I

flR302583

CHEMWESTMetals Laboratory


Operations

Allan WongMetals Laboratory

Manager

Nancy Melicharek-HarrigerMetals Chemist I

Pam RiveraMetalsChemist I

Open PositionMetalsChemist

Nicole RuckerLaboratoryTechnician

Theresa ShirleyChemist I

Kerri ChapinDataSpecialist

Revision 0214924830258!* '

CHEMWESTGC/MS Laboratory

Data Specialist


Operations

i — «— •——

Elaine WongQC/MS Laboratory

Manager

•MMMMNMi .

Rich HensonQC/MS sr. ChemistSupervisor SV & VOA

— Leona WinnerChemist IINight Supervisor

— Kurt KulhavyChemist I

— Diane PageChemist II

— Open PositionChemist

— Alice Roach.Data Specialist

— Theresa Schaidt

John MedinaGC/MS Sr. ChemistSupervisor Dioxin

— Greg Brisk!Dioxin ExtractorChemist Z

_ Greg ColeDioxin ExtractorChemist ZI

— Open PositionDioxin Ext rat ions

— Open PositionDioxin Extractiona

— Kathy KanagakiCheiiat Z

— Chuck TaylorChemist ZZ

Barbara AdlerData Specialist


CHEMWESTGeneral Services

Steve SincoffGeneral Manager

Randy SmithGeneral Services

Manager

— Alfonso VitellaFacilities Technician

AR3Q2S86 Revision 021492

CHEMWESTGC Laboratory


Operations

Kirk. J. PecanGC Laboratory

, Manager

Tarek Troy GaylonGC Sr. Chemist

Supervisor

Pam McCorduckGCChemist II

Laide DuromolaGCChemist I

Jane LaTonaGCChemist IIIVickl McCartneyGCChemist IX

Jerry HolyerossGCChemist ZX

Helen SmpardoaGCChemist IX

wal wongGCChemist ZZ

Jimmy ByeraLaboratoryTechnician

Earl MaxsonDataSpecialist

SR302587' Revlsion °21492

CHEMWESTLaboratory Operations

Steve SincoffGeneralManager


Derations

Bill McBengeSample ControlManager

F. Thomas KwokaOrganic Sample Prep.Laboratory Manager

Kirk J. PocanGC LaboratoryManager

Elaine WongGC/MS LaboratoryManager

Allan WongMetals LabatoryManager


COMPUCHEM WESTERN DIVISION (CHEMWEST)

CHEMWEST RESUMES

JANUARY 1992 REVISION

CempuChcm Wtlttm Division (CH EM WEST)


CompuChtm Wtswm Division (CM EM WEST)

AR302590

STEVEN L SINCOFFGeneral Manager

CompuChem Western Division (CHEMWEST)

ResponsibilHies: Dr. Sincoff was appointed the General Manager of CHEMWESTin December, 1991. He is responsible for the day to dayoperations of CHEMWEST's analytical laboratories and themanagement of the total business function.

Education: Ph.D., 1980, Analytical Chemistry, Ohio State UniversityM.S.,-1972, Chemical Engineering, New Jersey Institute ofTechnologyB.S., 1969, Chemical Engineering, New Jersey Institute ofTechnology

Job Experience: Prior to his appointment at CHEMWEST, Dr. Sincoff held awide variety of positions during a 21 year career in the UnitedStates Air Force. He was the Senior Scientist for a 180 personforensic laboratory. He was responsible for scientific liaison,coordination of laboratory operations and long-term budgeting.Dr. Sincoff was also Chairman of Environmental ProtectionCommittee to ensure compliance with established directives.

He served as the Chief Information Officer at McClellan AirForce Base, CA, for two years. He directed the operation of a$2 million mainframe computer and software system serving480 scientists, engineers and technicians. He was responsiblefor 150 personal computers, software maintenance, andtraining.

. He was selected for a one year assignment as SeniorExecutive Officer, the scientific and technical advisor to theCEO.

Dr. Sincoff was a Laboratory Director for the Gas AnalysisLaboratory at McClellan Air Force Base for four years. Hisresponsibilities included the management of the 37 personlaboratory, including a seven member Research andDevelopment branch. He conceived, designed andimplemented systems to automate the lab.

He was an Associate Professor of Chemistry at the U.S. AirForce Academy. He was the Course Director for five differentcourses, including Freshman Chemistry (1,000 students and 22professors). He also was responsible for an active continuingeducation program for the faculty.

He spent three years as a Chemical Engineer, tasked withhazardous waste minimization of photographic effluent. Duringthat period he was the key advisor to the US Army, Navy, andCoast Guard on their peculiar problems associated with

CompuCh»mW»it»m Division (CHEMWEST)

AR30259I

minimization of photochemical effluent.

Other Training: He has completed over 80 hours of continuing eduation in thepast two years, inluding 'Total Quality Management Methods,"•Techniques for Innovation in the Work Place," "Overview ofNEPA Procedures, and "Data Communications."

Professional: Dr. Sincoff has been a member of the American ChemicalSociety since 1977. He is also a member of Omega ChiEpsilon, the National Chemical Engineering Honor Society, andhas appeared in Who's Who in the West, since 1988.

CompuChim Western Division (CHEMWEST)

RR30Z592

JOEL C. BIRDDirector of Laboratory Operations


Responsibilities: As the Director of Laboratory Operations, Mr. Bird isresponsible for all technical aspects related to managing theday-to-day laboratory system. This includes production,scheduling, method development and technical personnelmanagement.

Education: Mr. Bird received his Bachelor of Science Degree in Biologyfrom California State University, Fresno in 1976 and his Masterof Business Administration from California State University,Sacramento in 1986.

Job Experience: Prior to his appointment to Director of Laboratory Operations,Mr. Bird was Corporate Vice President of EnvironmentalServices for 2 years. He was responsible for the day-to-daytechnical laboratory operation and client project managementof CHEMWEST, for new business development andacquis'rtion(s), market development, business plandevelopment for new products and strategic planning.

Prior to his promotion to Corporate Vice President in 1989, Mr.Bird was President of CHEMWEST Analytical Laboratories, Inc.As President, his responsibilities included complete businessstart-up, from attracting financial backing to laboratory designand build-but. Mr. Bird was also responsible for all technical,financial, marketing, and operational decisions. He recruitedkey staff, developed all laboratory policies, wage scales, stockoption plan, bonus plan and benefit packages. Mr. Bird wasalso responsible for yearly budgetary presentations toCompuChem Board of Directors. In 1989, CompuChemCorporation completed acquisition of CHEMWEST andimplemented many new personnel policies including titlechanges.

Prior to joining CHEMWEST, Mr. Bird was GC/MS Manager forCalifornia Analytical Laboratories-ENSECO (CAL). As GC/MSManager Mr. Bird's responsibilities included oversight ofGC/MS analysis of all volatile and semi-volatile fractions,scheduling for ten GC/MS instruments, supervision oftechnical staff, technical data review, method development,coordinating equipment maintenance and softwaredevelopment

CompuChsm W»st»m Division (CHEMWEST)

AR302593

Prior to his appointment to GC/MS Manager, Mr. Bird was aGC/MS operator for 5 1/2 years performing volatile, semi-volatile and dioxin analyses. Mr. Bird was responsible for theday to day operation, data wrhe-up and review, standardpreparation and development of standard operationprocedures. In total, Mr. Bird has over 10 years of massspectral data interpretation experience.

ProfessionalOrganizations: Mr. Bird is a founding member of the Association of California

Testing Laboratories (ACTLabs) and serves on the Board ofDirectors.In addition, Mr. Bird is also a member of the AmericanChemical Society.

CompuChsm Wsstsm Division (CHEMWEST)

DEMISE SYLJUBERGETData Control Specialist


Responsibilities: Ms. Syljuberget joined CHEMWEST in March, 1988. Ms.Syljuberget is responsible for the preparation of commercialdata for submission to clients. This involves contact wKhlaboratory managers and chemists. Ms. Syljuberget is alsoresponsible for invoicing of commercial reports and resolutionof any questions and/or problems regarding those invoices.

Education: Ms. Syljuberget received an AA degree from ConsumesCollege in March 1988.

Job Experience: Prior to joining CHEMWEST, Ms. Syljuberget was tmployed atCalifornia Analytical Laboratories-ENSECO in the accountingdepartment. Her responsibilities included processing ailaccounts payable, financial data, and sending a monthlypackage to the parent company in Cambridge. Prior to movingto the accounting department, she was a statistical typist atCalifornia Analytical Laboratories, typing client reports anddoing the invoicing for all reports. She has extensivecomputer experience with Basic 4 and Vax on both main frameand personal computers.

CompuChtm Wtsttm Division (CHEMWEST)

AR3Q2595

i KARYLA. PAPENBERGQuality Assurance Manager


Responsibilities: Ms. Papenberg joined CHEMWEST in September, 1989. As theQuality Assurance Manager, Ms. Papenberg is responsible forthe overall Quality Assurance monitoring for CHEMWESTAnalytical Laboratories.

Education: Ms. Papenberg received her Bachelor's degree in Biology fromHumboldt State University, Arcata, CA in 1982.

Job Experience: Prior to her appointment as Quality Assurance Manager, Ms.Papenberg was Senior Quality Assurance Specialist atCHEMWEST for two years.

Prior to joining CHEMWEST, Ms. Papenberg worked for twoyears as Assistant Manager in the Quality AssuranceLaboratory of Carriage House Foods. As Assistant Manager,she was responsible for assisting in establishing andmaintaining the QA program. She monitored adherence toGMP's, FDA and USDA regulations, HACCP and statisticalprocess control programs. In addition, Ms. Papenberg workedfor five years as a Laboratory Technologist with CarriageHouse Foods. In addition to overall quality assuranceresponsibilities, Ms. Papenberg was responsible for analyzingpeanut/peanut butter samples for afiatoxin using HPLC andAOAC methods.

CompuChtm Wsstom Division (CHEMWEST)

HR302596

JO-DEE BANCROFT' Quality Assurance Laboratory Technician


Responsibilities: Ms. Bancroft joined CHEMWEST in June, 1991. Ms. Bancroftis responsible for maintaining the NWQA control charts,assisting the QA Manager with various projects includingreviewing and updating the QAPMP and keeping accurateminutes of each QA committee meeting.

Education: Ms. Bancroft attended El Paso Community College for 6months and holds many certificates in WordPerfect, Lotus andDOS.

Job Experience: Previous to obtaining the position as QA LaboratoryTechnician, Ms. Bancroft was responsible for the preparationof commercia.l and CLP data for submission to clients for tenmonths. This involved contact with laboratory managers andchemists.Prior to joining CHEMWEST, Ms. Bancroft was employed atAmerican Montessor! Academy as an executive assistant.

In addition, she was employed at Boise Urban Stages as astatistical and collection clerk.

Formerly, Ms. Bancroft worked for Bartley CPA and was amember of the United States Army as a combat medicalspecialist

CompuChcm Western Division (CHEMWEST)

4R302597

DEBORAH L PEARCEProject Manager


Responsibilities: Ms. Pearce joined CHEMWEST in October, 1989. As ProjectManager, Ms. Pearce is responsible for overseeing the projectmanagement team, as well as many of CHEMWEST's largerprojects. Ms. Pearce and her staff are the liaisons betweenCHEMWEST clients and the laboratory. Ms. Pearce worksclosely whh all laboratory department managers to ensure thatproduction runs smoothly. Ms. Pearce is also responsible forinteracting with the marketing department

Education: Ms. Pearce attended A. W. Beattie Technical School andAshland College where she studied courses in biology,microbiology and chemistry.

Job Experience: Prior to joining CHEMWEST, Ms. Pearce was a Quality ControlCoordinator for 3 years at Radian Corporation. Whileemployed at Radian, Ms. Pearce worked on major clientprograms which involved reviewing raw data, writing qualitycontrol sections for quarterly reports, auditing field samplingprocedures and writing QAPP updates. She was also the on-s'rte Quality Control Coordinator for remedial investigations andinterfaced with database managers.

Prior to becoming their Quality Control Coordinator, Ms.Pearce was a GC Technician at Radian for 2 years. As a GCTechnician, Ms. Pearce gained experience with analyticaltechniques and data interpretation for various EPA methods.Ms. Pearce was also responsible for data review of all casesgenerated under the EPA Contract Laboratory Program.

Prior to her employment at Radian, Ms. Pearce was a GCOperator and Assistant Manager at Aqualab, Inc. for 3 years. Herresponsibilities included extraction, analysis, and datainterpretation of hazardous waste samples analyzed by both stan-dard EPA methods and by specialized methods. While atAqualab, Ms. Pearce supervised the Inorganic Department, wasinvolved in client interaction, acted as Quality Control Coordi-nator, and reviewed ail laboratory data (GC, GC/MS andInorganic).

CempuChsm Wtstsm Division (CHEMWEST)

RR302598

SANDY AUTRYAccount Executive ,


Responsibilities: Ms. Autry joined CHEMWEST in October, 1991. She isresponsible for the outside marketing and tales for alt clients inthe Western United States.

Education: Ms. Autry received her Bachelor of Science degree in Geneticsfrom the University of California, Davis in 1984.

Job Experience: Prior to joining CHEMWEST, Ms. Autry was an accountrepresentative for Fisher Scientific for three years. As an accountrepresentative, the was responsible for the sales of laboratorysupplies to commercial, medical and governmental industry forNorthern California and Western Nevada.

Previous to Fisher, she was a product development specialist forCalgene, Inc. for three years. As a product developmentspecialist, she was responsible for developing commercialpotential for genetically engineered crop plants using molecularbiology techniques as well as breeding and field practices.

In addition, Ms. Autry was a laboratory technician for ShellDevelopment Company for two years. As a LaboratoryTechnician, she was responsible for exploratory research ofsynthetic herbicides, pesticides, and plant growth regulators.

CompuChwn Wt»t»m Division (CHEMWEST)

AR302599

MARY MORANAccount Executive


Responsibilities: Ms. Moran joined CHEMWEST in November, 1990. She isresponsible for the marketing and sales of analytical services toconsulting firms, industrial companies, utilities, engineering firms,laboratories and state and local government She coordinatesincoming client projects with CHEMWEST production personnel,supervisors and managers and is responsible for responses toinvitations for bids and proposals.

Education: Ms. Moran received her Bachelor of Science degree in BusinessAdministration from California State University, Sacramento in1987.

Job Experience: Prior to joining CHEMWEST, Ms. Moran was employed by ScrippsHoward, Inc. Cable Division for three and one-half yearsperforming duties including sales and marketing, marketinganalysis, promotions, and development and implementation ofmarketing campaigns.

•CompuChim WcsMm Division (CHEMWEST)

RR302600

VINCENT SCHMIDTSenior Project Manager


Responsibilities: Mr. Schmidt joined CHEMWEST in March, 1989 as a GC Chemist*In September 1991, Mr. Schmidt was promoted to Senior ProjectManager. As a Project Manager, Mr. Schmidt is « liaison betweenCHEMWEST clients and the laboratory. In this capacity, heresponds to client calls involving technical questions, suppliesverbal case results, faxes data to clients, and works closely withall laboratory managers and chemists to insure that currentsample status information is available.

Education: Mr. Schmidt received s Bachelors of Scitncs Degree inEnvironmental Toxicology from the University of California atDavis in 1987.

Job Experience: Prior to his promotion to Senior Project Manager, Mr. Schmidtwas responsible for comprehensive gas chromatographoperation, and data interpretation for two and one-half years.

Prior to joining CHEMWEST, Mr. Schmidt was employed for twoyears at California Analytical Laboratories as a Staff Chemist,where he performed analysis of organic compounds. He wasinitially a member of the sample preparation group, involvedprimarily in extractables and GC screening. Afte- approximately 1year, Mr. Schmidt moved to the GC group, whe' ~e contributedin the areas of pesticide and herbicide analyse vnch somevolatile analyses exposure.

Prior to his employment at CAL, Mr. Schmidt was employed part-time as a lab assistant for a pesticide research facility at UCDavis for approximately two years.

CompuChtm Wcsttm Division (CHEMWEST)

SR3Q26QI

HAROLD (CHIP) CRAYSystems Manager


Responsibilities: Mr. Cray has been Systems Manager at CHEMWEST since May,1990. As Systems Manager, Mr. Cray is responsible for theoperation, support and development of the following computersystems: Hewlett Packard HP3000, which will be used to run ourLJMS (sample tracking) system, and our HP 1000, which is used fordata acquisition and analysis for the GC Department In addition,Mr. Cray is responsible for making corrections off the GC/MScomputers from the HP3000 computer and maintaining theEquinox PBX switch that connects all of the above computers.

Education: Mr. Cray has a certificate in Computer Programming from ControlData Institute and three years of undergraduate education inBusiness and History.

Job Experience: Prior to joining CHEMWEST, Mr. Cray was a Programmer/Analystfor CompuChem Corporation, for 1 1/2 years, developing softwareon an HP Spectrum 955 Computer. Mr. Cray was responsible fordeveloping the following software: A) a system to collect andstore results; B) a system to provide the necessary qualitycontrol, initial calibration, blind sample and sample data forinstant retrieval and delivery to the client on request; c) a systemto track samples in process, for a screening laboratory.

Prior to that, Mr. Cray was Systems Manager at ETC, anEnvironmental Laboratory for 1 1/2 years, and was responsible forthe development and system analysis on three HP 3000 computersystems utilizing Hewlett-Packard's 4th generation Rapid/3000package, Cobol and Dsg/3000 Graphics design software.

Mr. Cray has more than six years of experience in the dataprocessing industry as a computer Programmer Analyst and/orSystems Manager.

Mr. Cray is experienced using the HP 3000 series 39,42,48,68,70, 925, and 950 computer and the following software: Cobol,Photos, Transact, Fortran, Quick, Query, Ask, lfs/3000, Dsg/3000,Hpdraw, Ns/3000, Ds/3000, Opt/3000, Brw, Rapid/3000, Vplus,Image, Adager, Compilier Library, Mpe-V Intrinsics, Vesoft/3000,Unispool, Suprtooi, Qedit, Tdp, Quad, Speededft and Mpe-Xl.

CempuChtm Wsstcrn Division (CHEMWEST)

RR302602

JEFF DREWESSystems Support Personal Computer

CompuChem Western Division (CHEMWEST) '

Responsibilities: Mr. Drewes joined CHEMWEST in July, 1991. As a member of theSystems Support group, Mr. Drewes is responsible for PC andSoftware support

Education: Mr. Drewes is currently completing his fourth year of SacramentoState University, Sacramento pursuing his degree in ComputerScience.

Job Experience: Prior to joining CHEMWEST, Mr. Drewes worked for two years asa Shift Manager for McDonalds restaurant

CempuCh.m Wsstsm Division (CHEMWEST)

AR3026-03

BILL McBENGESample Control Manager


Responsibilities: Mr. McBenge joined CHEMWEST in November, 1986. As SampleControl Manager, Mr. McBenge is responsible for the control ofall incoming and outgoing samples.

Education: Two Years of college.

Job Experience: Prior to joining CHEMWEST, Mr. McBenge was smployed atCalifornia Analytical Laboratories- ENSECO as Sample CustodianSupervisor for 4 1/2 years. At CAL, Mr. McBenge designed andorganized Sample Control Department, controlled all incomingand outgoing samples (EPA and non-EPA), completed Chain-of-Custody forms, Traffic Reports, Special Analytical Service forms,and packing lists. Mr. McBenge was also responsible for properdisposal of the samples after analysis.

Prior to CAL-ENSECO Mr. McBenge was employed at CaterpillarTractor Company in Peoria, Illinois. Before his employment atCaterpillar, he was Quality Assurance Inspector and Lab Assistantfor Lehn & Fink Corporation, a Subsidiary of Sterling Drug, wherehe performed water analysis, and inspection of all finishedproducts and was promoted to Plant Supervisor 3rd shift

CompuChcm Western Division (CHEMWEST)

AR30260U

SUSAN GILBERTSample Control Technician


Responsibilities: Ms. Gilbert joined CHEMWEST as a full time employee in March,1991. Ms. Gilbert is responsible for the control of both EPA andnon-EPA incoming samples in the sample control department ofCHEMWEST. Ms. Gilbert's responsibilities include data entry ofnew samples upon receipt, preparation of folders and paperworkgenerated for each sample, disposal of samples according toCAL-OSHA requirements.

Education: Ms. Gilbert attended Sacramento City and Consumnes Collegepursuing classes in Special Education.

Job Experience: Previous to obtaining her full-time position with ChemWest, Ms.Gilbert worked part-time as a Sample Control Technician for twoyears.

Prior to joining CHEMWEST, Ms. Gilbert was employed as anInstructional Assistant for Sacramento County Schools planningdaily lessons for basic academics; preparing materials; recordinggrades and preparing progress reports.

CompuChsm Wttttm Division (CHEMWEST)

^302605

, F. THOMAS KWOKAOrganic Sample Preparation Laboratory ManagerCompuChem Western Division (CHEMWEST)

Responsibilities: Mr. Kwoka joined CHEMWEST in August, 1986. Mr. Kwoka is theOrganic Sample Preparation Laboratory Manager. He isresponsible for managing ail activities of the Sample PreparationLaboratory including scheduling of work, preparation of allstandards and ensuring that high-quality work is performed in atimely and efficient manner.

Education: Mr. Kwoka earned his Bachelor of Science Degree in Chemistryfrom California State University, Sacramento in 1983.

Job Experience: Prior to joining CHEMWEST, Mr. Kwoka worked for three yearsfor California Analytical Laboratories-ENSECO. Mr. Kwoka wasthe supervisor of CAL's Dioxin Laboratory for two years. Mr.Kwoka has 5 1/2 years of experience in the preparation ofstandards and in the extraction and column chromatographyclean-up techniques of polychlorinated dibenzo-p-dioxins andpolychlorinated dibenzo furans. Mr. Kwoka has 1 1/2 yearsexperience using purge-and-trap technique for volatile organies,TCA/TCE and gasoline analysis by GC. Mr. Kwoka has 6 years ofexperience in the preparation of extracts for semivolatiles andorganochlorine pesticides/PCB's including columnchromatography clean-up procedures.

CompoCh.m Wtstsm Division (CHEMWEST)

AR3026Q6

j SCOTT PIETERSOrganic Sample Preparation Supervisor


Responsibilities: Mr. Pieters joined CHEMWEST in June, 1988. Mr. Pieters issupervisor of the Organic Sample Preparation Department He isresponsible for the supervision of the Organic SamplePreparation Technicians and Chemists, as wall as the extractionand concentration of water, soil, and sludge samples for organicanalysis, including priority pollutants. Mr. Pieters is alsoresponsible for column chromatography clean-up procedures, thepreparation of organic standards and the quality control of sol-vents and other materials used in the extraction laboratory. Mr.Pieters' duties also include the analysis of total petroleum hydro-carbons by IR and data reduction utilizing a program on an EpsonEquity II computer system.

Education: Mr. Pieters has earned 62 credits towards an A.S. from the Com-munity College of the Fingerlakes, Canandaigaa NY. Mr. Pieters

i has also attended the Air Force Technical School for LaboratoryFundamentals, and General Physical Sciences. Mr. Pieters iscurrently attending Sacramento City Community College to finishhis A.S. and then plans to complete his education with a B.S. inChemistry at Sacramento State University.

Job Experience: While at CHEMWEST, Mr. Pieters has gained three years and sixmonths experience in preparing soil and water samples for analy-sis by EPA-CLP methods 8010, 8020, 8080, 8140, 8150, 8270, 8280,PCP/TCP, oil and grease, and TPH/IR for GC analysis. Mr. Pietersalso has gained experience in column chromatography clean-upprocedures, extracting EDB for GC analysis and organic lead forICAP analysis.

CompuChsm Wtstsm Division (CHEMWEST)

AR302607

THOMAS HELMBRECHTOrganic Preparation Chemist I


Responsibilities: Mr. Helmbrecht joined CHEMWEST in July, 1991. Mr. Helmbrechtis responsible for the extraction and concentration of water andsoil samples for organic analysis, including priority pollutants.Mr. Helmbrecht is also responsible for column chromatographyclean-up procedures, the quality control of solvents and othermaterials used in the extractions laboratory. Mr. Helmbrecht isalso responsible for the analysis of total petroleum hydrocarbonsby IR and data reduction utilizing a program on an Epson Equity IIcomputer system.

Education: Mr. Helmbrecht received his Bachelor of Science Degree inZoology from the University of Davis, in 1990.

Job Experience: Prior to joining CHEMWEST, Mr. Helmbrecht worked at AN LAB asan Organic Extractor for six months. Prior to that, Mr. Helmbrechtworked at Radian Corporation for six months as a Wet ChemistryAnalyst.

CempuCh«m W.it.rn Division (CHEMWEST)

AR3Q2608

DAN CURRANOrganic Preparation Chemist I


Responsibilities: Mr. Outran joined CHEMWEST in September, 1991. He isresponsible for the extraction and concentration of water and soilsamples for organic analysis, including priority-pollutant*. Mr.Curran is also responsible for column ehromatography clean-upprocedures, the quality control of solvents and other materialsused in the extractions laboratory. Mr. Curran's duties alsoinclude the analysis of total petroleum hydrocarbons by IR anddata reduction utilizing a program on an Epson Equity II computersystem.

Education: Mr. Curran received his Bachelor of Science degree in Zoologyfrom Cal Poly Pomona in 1981. Mr. Curran received his Master ofScience degree in Biology 1986 from Cal Poly Pomona.

Job Experience: Prior to joining CHEMWEST, Mr. Curran worked at Autochem. Tech and Roche Biomedical/Metwest where he analyzed blood

samples for hormone and drug levels. Also, Mr. Curran hasseven years experience as a laboratory instructor at Cal Poly andUCLA where he taught undergraduate biology laboratory students.

CompuChsm W«st*m Division (CHEMWEST)

AR302609

GARY BIASEOrganic Preparation Chemist I


Responsibilities: Mr. Biase is responsible for the extraction and concentration ofwater and soil samples for organic analysis, including prioritypollutants. Mr. Biase is also responsible for column chromatog-raphy clean-up procedures, the quality control of solvents andother materials used in the extractions laboratory. Mr. Biase'sduties also include the analysts of total petroleum hydrocarbonsby IR and data reduction utilizing a program on an Epson Equity IIcomputer system.

Education: Mr. Biase received his Bachelor of Science degree in WildlifeBiology from the University of Nevada, Reno, in 1972.

Job Experience: Prior to his promotion to Organic Preparation Chemist IDecember, 1991, Mr. Biase worked as a Courier and SampleControl Technician for CHEMWEST for 3 years. He wasresponsible for the collection of samples from various clients inthe Bay Area and in maintaining the sample chain-of-custodyrecords. He was also responsible for filling out orders fromclients for sample containers, and the proper preparation andshipment of those sample containers.

Prior to joining CHEMWEST, Mr. Biase was employed by the Cityof Sacramento.

CompyChcm W*st*m Division (CHEMWEST)

&R3Q26IO

BRENDA N. HUDSONLaboratory Technician


Responsibilities: Ms. Hudson joined CHEMWEST in March, 1991. Ms. Hudson isresponsible for the extraction and concentration of water and soilsamples for organic analysis, including priority pollutants. Ms.Hudson is also responsible for column chromatography clean-upprocedures, the quality control of solvents and other materialsused in the extractions laboratory.

Education: Ms. Hudson is currently pursuing a course of general educationat Cosumnes River College, Sacramento, CA,

Job Experience: Prior to her employment at CHEMWEST, Ms. Hudson worked forRadian Corporation for two years and eight months, where sheperformed supervisory responsibilities for five laboratorytechnicians in the corporate sample preparation laboratory. Ms.Hudson was responsible for working with a wide range ofsamples and performed various extraction techniques followingSW-846 and EPA CLP methodology.

CcmpuCh.m Wcstsm Division (CHEMWEST)

AR3026I I

DOUGLAS E. KLAHOLDStandards Preparation • • .


Responsibilities: Mr. Klahold joined CHEMWEST in June, 1990. He isresponsible for the preparation of analytical standards fromneat materials and high concentration solutions. He alsoprepares QC checks for these standards and maintains allpaperwork associated with all standards preparation.

Education: Mr. Klahold has completed 60 units at American River College.

Job Experience: Prior to his promotion to Standards Preparation Technician inJuly, 1990, Mr. Kalhold was responsible for the extraction andconcentration of water and soil samples for organic analysis,including priority pollutants. Mr. Klahold was also responsiblefor column chromatography clean-up procedures, the prepara-tion of organic standards and the quality control of solventsand other materials used in the extractions laboratory. Hisadditional responsiblities included the analysis of totalpetroleum hydrocarbons by IR and data reduction utilizing aprogram on an Epson Equity II computer system.

Prior to joining CHEMWEST, Mr. Klahold was employed by theUS Air Force, for four years, as a Scientific LaboratoryTechnician, where he was responsible for the preparation andmeasurement of various samples for radionuclides and mixedfission products.

CompuChcm W*st*m Division (CHEMWEST)

ALLAN W. WONGMetals Laboratory Manager

CompuChem Western Division (CHEMWEST)Responsibilities: Mr. Wong joined CHEMWEST in October, 1987. As Metais

Manager, Mr. Wong is responsible for scheduling andperforming a variety of trace metals analyses, of water, waste-water, industrial wastes and soils, using ICP, GFAA, Flame AA,and Hydride methods. He is responsible for final data raviawfrom the Metals lab, and the supervision of Metals analystsand digestion personnel.

Education: Mr. Wong received his Bachelors of Science Degree inBiological Sciences from California State University,Sacramento in May, 1979.

Job Experience: Mr. Wong has 9 1/2 years of laboratory experience. He workedat the California Department of Food and Agricultureperforming QA analyses on commercial fertilizers and livestockfeeds, prepared meats and meat products, and fresh fruits andvegetables. Mr. Wong was employed at Sacramento RegionalWastewater Treatment Plant Control Laboratory for 7 1/2 years.He is well versed in EPA "wet chemistry" methodology in theanalyses of wastewater, surface and groundwater, sewage,sludge and industrial wastes. He is also experienced in theBacteriological and Biological examination of those respectivewater types, potable waters, milk, and dairy products.

CompuChom Wssttm Division (CKEMWEST)

AR3026I3

VERLE HEYERWet Chemistry Laboratory Manager


Responsibilities: Mr. Heyer joined CHEMWEST in July, 1989. As the Manager ofthe Wet Chemistry department, Mr. Heyer is responsible forthe scheduling of analyses, training of new personnel, andwriting and reviewing of data. Mr. Heyer is also responsiblefor performing various inorganic analyses as needed.

Education: Mr. Heyer received a Bachelor of Science Degree in ChemicalOceanography and a Bachelor of Arts Degree in Chemistryfrom the University of Washington in Seattle in June, 1980.Area of emphasis was oceanic water chemistry.

Job Experience: Prior to his appointment as Wet Chemistry Manager, in March,1990, Mr. Heyer worked for CHEMWEST for one year as anInorganics Specialist. As an Inorganic Specialist, Mr. Heyerwas responsible for performing various wet chemistryanalyses; i.e., Nitrate/nitrite, chloride, alkalinity, cyanide, pH,and other wet chemistry tests.

Prior to joining CHEMWEST, Mr: Heyer was Chief Chemist andMetals Department Supervisor, for 1 1/2 years at BarringerLabs, in Reno, Nevada. As supervisor of the metalsdepartment he was responsible for the analysis of ore samplesfor various metals, minerals, and precious metals.

Prior to that, Mr. Heyer was employed as a Chemist withLaucks Testing Labs., in Seattle, Washington for 2 years. Hisresponsibilities included wet chemistry analysis as well asbeing main operator of a Jarrell - Ash 2400 ICP and backupoperator for the AA and Graphite Furnace, for analysis ofpollutant metals. Prior to working at Laucks, Mr. Heyer wasemployed with Standard Slag Company in Reno, Nevada as theChief Assay Chemist for 3 1/2 years. He was responsible forall chemical analysis related to the operation of the mininglaboratory.


AR30261U

PAMELLA L RIVERAMetals Chemist I

CompuChem Western Division (CHEMWEST)Responsibilities: Ms. Rivera joined CHEMWEST in February, 1991. As a

Chemist I in the Metals Department, Ms. Rivera is responsiblefor the analysis of water, waste-water, industrial waste and soilsamples for metals analysis by ICP and GFAA using EPA CLPand EPA SW-846 methods, and other specified protocols.

Education: Ms. Rivera received her Bachelor of Science Degree in Botanyfrcm the University of California at Davis in December 1988.

Job Experience: Prior to her employment at CHEMWEST, Ms. Rivera wasemployed as a research assistant at Radian Corporation fromMarch 1989 to February 1991. Her duties in that positionincluded atomic absorption spectrophotometry and dataanalysis, total organic halide extractions and analysis.

Ms. Riveria was also responsible for soil and water samplepreparation for AA & ICP analyses including digestions,distillations & dry weights; nitrate/nitrite analysis with thecontinuous flow apparatus; total petroleum hydrocarbon &oil/grease extractions and analyses by infraredspectrophotometry; and other water chemistry analyses. Priorto her employment with Radian, Ms. Rivera worked as aStudent Assistant in the Entomology Department at theUniversity of Davis.

CompuChcm WcsMm Division (CHEMWEST)

AR3026I5

, NANCY A. MELJCHAREK-HARRIGERMetals Chemist I


Responsibilities: Ms. Melicharek-Harriger joined CHEMWEST in July, 1989. Shewas promoted to Chemist I in the Metals department inNovember of 1990. As a Metals Chemist she is responsible forthe analysis of water, waste-water, industrial waste and soilsamples for metals analysis by ICP and GFAA using EPA CLPand EPA SW-846 methods, and other specified protocols.

Education: Ms. Melicharek-Harriger is presently working toward comple-tion of her bachelor's degree in Microbiology with a minor inChemistry at California State University, Sacramento.

Job Experience: Prior to her promotion to metals Chemist, Ms. Melicharek-Harriger was responsible for the preparation of water, waste-water, industrial waste and soil samples for metals analysis byICP/GFAA. Her additional responsibilities included preparationand analysis of mercury by EPA CLP and EPA SW-846protocols, and analysis of TOC/TIC/POC by EPA method415.1/SW-846 - 9060.

Prior to joining CHEMWEST, Ms. Melicharek-Harriger wasemployed by the State of California Department of Food andAgriculture, for 1 1/2 years, as an Agricultural Aide/LaboratoryTechnician. Her responsibilities included analyzing animalfeed for various compounds, such as vitamin A, aflatoxin, sutfadrugs and antibiotics, using AOAC methods.

In addition, Ms. Melicharek-Harriger has 1 year of experienceworking for the Department of Public Works for the City ofSacramento as a Laboratory Student Trainee. While there, shegained a working knowledge of Atomic AbsorptionSpectroscopy, Gas Chromatography and LiquidChromatography.Ms. Melicharek-Harriger has 3 years of additional laboratoryexperience as a Microbiological Lab Prep. Technician forHumboldt State University and Sacramento State University.

CompuChtm Wssttm Division (CHEMWEST)

AR3026I6

NICOLE COCHRANLaboratory Technician

' CompuChem Western Division (CHEMWEST)

Responsibilities: Ms. Cochran joined CHEMWEST in August, 1990. Ms. Cochrantransferred to the Inorganic Metals Department in June, 1991.As a Laboratory Technician for this department she isresponsible for preparing and digesting soil and water aamplssfor analysis by ICP and GFAA, and by Cold Vapor for Hgcontent. Ms. Cochran is also responsible for complete TCLPand STLC extractions, and Ignitability analysis. Additionalresponsibilities include quality and safety control of variousacids and other materials used in the lab, preparation ofstandards, and occasionally, various Wet Chemistry analyses,including pH, Cyanides, Chlorides, COD, Phosphates andSulfides.

Education: Ms. Cochran completed a general education course of study atContra Costa College in San Pablo, California, in 1987.

Job Experience: prior to her promotion to the Inorganic Metals Department, Ms.Cochran was responsible for extraction and concentration ofwater and soil samples using Methods 8130, 8080, 8270, 8310,604 and TPH/GCFID; BTEX, 8020, 8010; oil and grease/IR,TPH/IR, oil and grease gravimetric for waters and soils;mercury cleanups, and acid wash clean-ups for pesticides.

Prior to joining CHEMWEST, Ms. Cochran was employed on apart-time basis by the clinical division of CompuChemWestern Division for one year.

CompuCh«mW»st«m Division (CHEMWEST)

AR3026I7

Theresa ShirleyChemist I


Responsibilities: Ms. Shirley joined CHEMWEST in January, 1992. As a ChemistI for the Metals Department, she is responsible for preparingand digesting soil and water samples for analysis by ICP andGFAA, and by Cold Vapor for Hg content. Additionalresponsibilities include quality and safety control of variousacids and other materials used in the lab and preparation ofstandards.

Education: Ms. Shirley received her Bachelor of Science degree inEnvironmental Policy Analysis and Planning from theUniversity of California, Davis in 1990.

In addition, Ms. Shirley received Bachelor of Science degreesin Zoology and Botany from North Carolina State University,Raleigh in 1981 and 1982 respectively.

Job Experience: Prior to joining CHEMWEST, Ms. Shirley was a Lab Technicianat Radian Environmental Engineering for six months where sheprepared water and soil samples for inorganic analysis.

Previous to Radian, she was employed by McLarenEnvironmental Engineering for eight months as a LaboratoryTechnician where she worked on asbestos sample analysis.

CompuChtm Wistcm Division (CHEMWEST)

KERRI CHAPINData Specialist


Responsibilities: Ms. Chapin joined CHEMWEST in July,1989. Ms. Chapin isresponsible for the preparation of commercial and CLP datafor submission to clients. This involves contact with laboratorymanagers and chemists.

Education: Ms. Chapin attended Sacramento City Collage for one year.Job Experience: Previous to obtaining the position as a data specialist, Ms.

Chapin was responsible for the control of both EPA and non-EPA incoming samples in the sample control department ofCHEMWEST for nine months.

Prior to joining CHEMWEST, Ms. Chapin was employed at theBank of Alex Brown as a Collection Clerk.

In addition, she was employed at United Courier Inc., as arelief driver and formerly employed as a Dental Assistant forDr. Smith D.D.S.


AR3026I9

MICHAEL VIANIWet Chemistry Chemist I


Responsibilities: Mr. Viani joined CHEMWEST in December, 1991. He isresponsible for preparing and analyzing soil and watersamples for the many analytes of the wet-chemistry area. Healso prepares data for entry on the initial report forms.

Education: Mr. Viani received his Bachelor of Arts degree in Biology fromUCSB in 1981.

Job Experience: Prior to joining CHEMWEST, Mr. Viani was a Manager for CortiBrothers Market for nine years. Mr. Viani was responsible forcost accounting, scheduling, creating weekly ads and acustomer service representative.

Prior to Corti, Mr. Viani was a Laboratory Technician for SantaBarbara Analytical Laboratory for one year. Mr. Viani wasresponsible for QC including making culture media for specificcall lines and insured culture was not contaminated. He alsoassisted Senior Lab Technicians in analyzing the outcome ofcelt lines if they died.

CompuCh«m Wssttm Division (CHEMWEST)

RR302620

RYANNE O'BRIENWet Chemistry Chemist I


Responsibilities: Ms. O'Brien joined CHEMWEST in September, 1991. She isresponsible for preparing and analyzing soil and watersamples for the many analytes of the wet-chemistry area. Sheis also responsible for preparing and calculating data for entryon the initial report forms.

Education: Ms. O'Brien received her Bachelor of Science degree inChemistry from CSUS in 1991.

Job Experience: Prior to joining CHEMWEST, Ms. O'Brien worked as aLaboratory Assistant for the State Department of Food andAgriculture assisting analytical chemists on various analysesrequested on environmental samples; preparing and extractingwater, soli, air and vegetation samples for analysis; andpreparing standard solutions to be used in sample analysisand method developmentMs. O'Brien was employed as a Pharmacy Technician at Medi-Physics Corporation working closely with pharmacist todispense nuclear medicine products, receiving and packagingnuclear medicine products to hospitals, insuring quality controland compliance with health and safety regulations, andmanaging pharmacy inventory, accounts payable andreceivables.

In addition, she was a Chemistry Tutor for high school andcollege level students in various chemistry courses.

CompuCntm Wssttm Division (CHEMWEST)

AR30262!

KIRK J. POCANGC Laboratory Manager


Responsibilities: Mr. Pocan joined CHEMWEST as GC Laboratory Manager inMarch, 1988. As GC Manager, Mr. Pocan is responsible forscheduling of sample analysis, final review of data, training ofchemists and operators, and maintenance of GCinstrumentation.

Education: Mr. Pocan received a Bachelor of Science degree inEnvironmental Science in 1972, from the University of Nevada,Reno. Mr. Pocan also has completed two years of postgraduate education.

Job Experience: Prior to joining CHEMWEST, Mr. Pocan was GC LaboratorySupervisor for California Analytical Laboratories-ENSECO, fortwo years. Prior to his promotion, Mr. Pocan was a staffchemist specializing in pesticide and herbicide extractions andanalysis. Mr. Pocan has over 8 years of GC experience. Mr.Pocan has a complete understanding of EPA 500,600, 8000series methodologies as they relate to chromatographyanalysis. Mr. Pocan has used packed capillary and megaborecolumns, and is fully familiar with the following detectors: FID,EC, TSD, HALL, Coutson, ITD, P1D, UV, and fluorescence.

CompuCh*m W«sl»rn Division (CHEMWEST)

AR302622

TAREK TROY GAYLONGC Senior Chemist Supervisor

CompuChem Western Division (CHEMWEST) . . .

Responsibilities: Mr. Gaylon joined CHEMWEST in November, 1986. He waspromoted to GC Chemist Supervisor in June, 1991. As GCSupervisor, Mr. Gaylon is responsible for the development andapplication of GC methods for samples requiring ECD, FID,PID, NPD, FPD, and HECD detectors. He is also responsiblefor production scheduling and data review.

Education: Mr. Gaylon received a Bachelor of Science degree inChemistry, in 1983, from California Stats University,Sacramento.

Job Experience: Prior to his current position, Mr. Gaylon was GC/MS LaboratorySupervisor at CHEMWEST for one year, and was responsiblefor performing volatile and semi-volatile analyses by GC/MS.He was also responsible for coordinating the scheduling ofsample analyses. In addition, Mr. Gaylon was GC Supervisorfor two years and was responsible for the GC and LC sections.

Prior to joining CHEMWEST, Mr. Gaylon was employed byCanonie Environmental Services Corporation as a supervisorof GC and LC projects in pesticide residue analysis. Heperformed GC and LC analysis on dust, food types,environmental and hazardous wastes.Mr. Gaylon has one year experience in the analyses of metalsusing EPA flame and graphite furnace methods, and four yearsof GC and LC experience in purgeable volatile organics analy-ses, organochlorine pesticide residue and PCB analysis.

ProfessionalOrganizations: Mr. Gaylon is a member of the Air and Waste Management

Association.

CompuCh»m Wtsnm Division (CHEMWEST)

AR302623

PAMELA J. MCCORDUCKChemist I


Responsibilities: Ms. McCorduck, who joined CHEMWEST in January, 1989, hasbeen a Chemist I in the GC Volatile* Department sinceSeptember, 1991. Her duties include analysis of 8020compounds including BTEX, using Method 8020 and 8020direct purge. Ms. McCorduck also performs analysis of TotalFuel Hydrocarbons using the LUFT method.

Education: Ms. McCorduck earned her Bachelor of Science Degree inBiological Conservation with a minor in Chemistry fromCalifornia State University, Sacramento, in May 1989.

Job Experience: Prior to her transfer to the GC VOA Department, Ms.McCorduck was supervisor of the Organic ExtractionDepartment. She was responsible for the supervision ofExtractors, as well as the extraction and concentration ofwater, soil, and sludge samples for organic analysis, includingpriority pollutants. Ms. McCorduck is also responsible forcolumn chromatography clean-up procedures, the preparationof organic standards and the quality control of solvents andother materials used in the extraction laboratory. Ms.McCorduck's duties also include the analysis of total petro-leum hydrocarbons by IR, oil & grease by IR, and oil & greaseby gravimetric and data reduction utilizing a program on theEpson Equity II computer system. Ms. McCorduck is also aSafety Committee member.

Prior to her promotion to Organic Sample PreparationSupervisor, in August of 1990, Ms. McCorduck was an Extrac-tions Specialist at CHEMWEST. As an Extractions Specialist,Ms. McCorduck gained over 18 months experience inpreparing soil.and water samples for analysis by EPA-CLPmethods 8080, 8270, 8150, 8140 and TPH for GC analysis. Ms.McCorduck also has gained valuable experience in columnchromatography clean-up procedures, extracting EDB for GCanalysis, organic lead for ICAP analysis, ABN screening onGC-FID and Pesticide/PCB screening on GC-ECD.

CompuChsm W*sttm Division (CHEMWEST)

AR30262U

LAIDE DUROMOLAGC Chemist II


Responsibilities: Mr. Duromola joined CHEMWEST in December, 1991 as aChemist for the GC VOA Laboratory. Mr. Duromola isresponsible for analyzing samples for the presence of volatileorganic compounds by method 8020 and also for purgeablefuels (gasoline).

Education: Mr. Duromola received his Bachelor of Science degree inClinical Lab Science from CSUS in 1987.

Job Experience: Prior to joining CHEMWEST, Mr. Duromola was tmploysd bythe California State Department of Food and Agriculture -Department of Chemistry for four years, where he analyzedpesticides, performed electro chemistry, formulated standardsand performed wet chemistry analyses.

CempuCnsm Wsswrn Division (CHEMWEST)

AR302625

, I. JANE LaTONAGC Chemist II


Responsibilities: Ms. LaTona joined CHEMWEST in August, 1987. As a GCChemist at CHEMWEST, Ms. LaTona is responsible forperforming Pesticide/PCB analysis using GC/ECD.

Education: Ms. LaTona received her bachelors degree in BiologicalSciences from California State University, Chico in 1982.

Job Experience: Ms. LaTona was promoted to her present position as GCChemist in May, 1989. While at CHEMWEST, Ms. LaTonainitially worked as a data control specialist, and wasresponsible for writing up, reporting and reviewing dioxin data.She then took the position as Safety Officer and QualityAssurance Specialist, where she was responsible for assistingwith the data review, training and overall quality assurancemonitoring for CHEMWEST.

Prior to joining CHEMWEST, Ms. LaTona was employed atCalifornia Analytical Laboratories-ENSECO for 1 1/2 years.Initially, she was an extraction chemist, performing commercialand EPA sample preparations and GC screening. She alsoworked as data control specialist writing up, reporting andreviewing dioxin data.

Ms. LaTona has 1 year of experience as an EnvironmentalHazard Specialist for the California State Department of Foodand Agriculture. She was responsible for the indexing oflexicological tests involved in the registration of pesticides.

CompuCh.m Wtstim Division (CHEMWEST)

AR302626

VICTORIA L McCARTNEYi GC Chemist II


Responsibilities: Ms. McCartney transferred to the GC Extra eta bles Departmentin June, 1991. She is responsible for the scheduling andanalysis of all TPH-Diesel samples; monitoring instrumentationand performing required maintenance of instruments anddetectors related to diesel analysis. Ms. McCartney isresponsible for preparing diesel data summaries anddaiivering completed analysis in a timely manner.

Education: Ms. McCartney received a Bachelor of Science Dagras inBiology from Geneva College in 1966. Additionally, Ms.McCartney completed a one year internship at the School ofMedical Technology in 1966 at Montefiore Hospital.

Job Experience: Ms. McCartney joined CompuChem Western Division'sForensic Drug Testing facility in February 1989, where sheworked as a Analytical Toxicologist In August, 1990, Ms.McCartney transferred to the Environmental Division ofCHEMWEST. Her responsibilities included analysis of soil andwater samples for volatile organic aromatics by GC-FID/PID,including BTEX, 602/8020, and TPH-Gas.

Prior to her employment at CHEMWEST, Ms. McCartney wasemployed as an analytical toxicologist, where she performeddrug testing, clinical chemistry extractions, GC/MS analysis fordrug testing; alcohol testing using GC. She was alsoemployed as a research technologist and a medicaltechnologist. Ms. McCartney has a total of ten years oflaboratory experience prior to her employment at CHEMWEST.

CempuChsm Wssttm Division (CHEMWEST)

AR302627

JERRY HOLYCROSSGC Chemist II


Responsibilities: Mr. Holy cross joined CHEMWEST in October, 1990. Hisresponsibilities include the analysis of soil and water samplesusing 8010/601 methodology.

Education: Mr. Holycross received a Bachelors of Science Degree inBiological Science from the University of California at Davis in1988.

Job Experience: Prior to joining CHEMWEST, Mr. Holycross was employed at.Radian Corporation as a Research Assistant for two years andfour months, where he performed GC analysis and was thetask leader in sample preparation.

CompuChsm Wsstsm Division (CHEMWEST)

RR302628

HELEN N. SMPARDOSGC Chemist II


Responsibilities: As a GC Chemist, Ms. Smpardos is responsible for analyzingPasticide/PCB samples using GC/ECD.

Education: Ms. Smpardos earned her Bachelor of Science-Degree inNutrition Science with a minor in Chemistry from the Universityof California at Davis in March, 1988.

Job Experience: Ms. Smpardos joined CHEMWEST in September, 1988. Prior toher move to the PCB/Pesticide group in September, 1991, Ms.Smpardos was a GC Chemist wrth the Volatiles group for 11/2years. She was responsible for analysis of water and soilsamples by EPA Methods 8010, and 8020. Her additional dutiesincluded analyzing for BTEX and TPH/Purgeables.

Ms. Smpardos was initially responsible for the extraction andconcentration of water and soil samples for organic analysis,

. including priority pollutants. Ms. Smpardos was alsoresponsible for column chromatography clean-up procedures,the analysis of total petroleum hydrocarbons by IR and datareduction utilizing a program on an Epson Equity II computersystem.

CompuChsm Western Division (CHEMWEST)

AR302629

WAI WONGChemist II


Responsibilities: Mr. Wong was promoted to Chemist II in October, 1991. Mr.Wong is responsible for the analysis of Volatile samples EPASW-846 method 8020, 8015 modified, in addition to CA LUFTMethod for TPH/purgeable (gasoline). Mr. Wong is alsoresponsible for include general maintenance of GCinstruments.

Education: Mr. Wong received a Bachelor of Science Degree from theCalifornia State University of Sacramento in 1989.

Job Experience: Mr. Wong joined CHEMWEST in February 1991, as a Chemist I.As a Chemist I, Mr. Wong was responsible for the analysis ofvolatile samples using SW-846 EPA methods: 8020, 6015modified, and CA LUFT Method for TPH/purgeable (gasoline).Mr. Wong's responsibilities also included general maintenanceof GC instruments.

Prior to joining CHEMWEST, Mr. Wong was employed byRadian Corporation from seventeen months, where heperformed analysis of VOA samples with EPA SW-846methods, 8010, 8020, 8015 modified, and CA LUFT MethodTPH/purgeable (gasoline).

CompuChcm Wtstem Division (CHEMWEST)

&R3Q2630

EARL MAXSONData Specialist

CHEMWEST Analytical Laboratories, Inc.Responsibilities: Mr. Maxson joined CHEMWEST in March, 1991. As a Data

Specialist, his duties include the preparation and submittal ofCLP data reports to the EPA or other clients in a timely andaccurate manner.

Education: Mr. Maxson has attended Sacramento State University and SanJoaquin Delta College completing courses in publicadministration and general education.

Job Experience: Prior to joining CHEMWEST, Mr. Maxson was SystemsManager for two years at Chemtech Analytical Laboratories.As Systems Manager, he was responsible for client project •*services, invoicing and the ordering of supplies. Mr. Maxsonwas also responsible for preparing SOPs for preparation ofreporting packages, environmental sampling, samplepreparation and sample classification.

Prior to his move to Chemteeh, Mr. Maxson was employed byCanonie Environmental as a Laboratory Technician for twoyears. Working with the quality control department, Mr.Maxson was responsible for QC analysis of water and soilsamples, data entry, data retrieval and database managementMr. Maxson was also responsible for converting sampleanalysis data into graphs.


AR30263

ELAINE WONGGC/MS Laboratory Manager


Responsibilities: Ms. Wong joined CHEMWEST in November, 1986. As Managerof the CHEMWEST GC/MS laboratory, Ms. Wong is responsiblefor the scheduling of all GC/MS analyses, the work-up andfinal review of alt priority pollutant and dioxin data. She is alsoresponsible for overseeing the operation of GC/MS systems,spectral interpretation and quantitative data analysis.

Education: Ms. Wong received a Bachelor of Science degree inBiology/Chemistry from California State University, SacramentoIn December, 1983.

Ms. Wong has completed courses in Basic Mass Spectrometry,Spectral interpretation and Super Incos Data Systems from theFinnigan Institute in Cincinnati, Ohio.

Experience: Prior to joining CHEMWEST, Ms. Wong worked as a GC/MSoperator for 4 years doing volatile and semivolatile analysesand 3 years of mass spectral data interpretation at CaliforniaAnalytical Laboratories-ENSECO. Ms. Wong has also done sixmonths of dioxin data review and interpretation. Beforebecoming a GC/MS operator, Ms. Wong was supervisor ofInorganic Wet Chemistry for one year at California AnalyticalLaboratories. Ms. Wong was responsible for assigning work,reviewing all wet chemistry analyses, and training of all newpersonnel in this section.

Ms. Wong also worked for the California State Department ofFood and Agriculture for three years doing pesticide, herbicideand fungicide extractions. Ms. Wong also has six months ofGC experience.

CempuCh*m WssMm Division (CHEMWEST)

HR302&32

*

RANDALL D. SMITHGC/MS Instrumentation

CompuChem Western Division (CHEMWEST) • -

Responsibilities: Mr. Smith joined CHEMWEST in 1986 as a GC/MS Chemist I.Mr. Smith is responsible for loading GC/MS samples and isalso responsible for specialized electronic support ofinstrumentation for use by the GC/MS and GC Laboratories.Mr. Smith is responsible for daily interface with majorCHEMWEST vendors.

Education: Mr. Smith racaived his AA Degree in Computer Technologyfrom Control Data Institute in Los Angeles, California. Hereceived extensive training in GC/MS electronic maintenancefrom Finnigan Institute in Cincinnati, Ohio, and from ExtrelCorporation in Pittsburgh, Pennsylvania.

Job Experience: Prior to joining CHEMWEST, Mr. Smith was employed as aGC/MS/DS Hardware Specialist with California AnalyticalLaboratories-ENSECO (CAL), for one year. Ha wasresponsible for all maintenance and repair of 17 GC/MS/DS,HR-GC/MS/DS and DS systems. Mr. Smith was instrumental inplanning the she preparation for the eventual relocation of allexisting HR-GC/MS/DS and GC/MS/DS and DS systems. Thisincluded calculating all electrical and HVAC requirements, aswell as space allocation for systems. Previous to hisemployment with CAL, he was a systems engineer with theFinnigan Corporation for five years. His responsibilitiesrequired specialized skills in electronic circuitry, and theapplication of laboratory instrumentation.

Prior to his employment with Finnigan Corporation, Mr. Smithwas production Supervisor in electrical sub-assemblies forMcDonnell Douglas-Commercial Aircraft Division. Hisresponsibilities included supervising 20 persons in theassembly of electrical power centers and radio racks for theDC-9 aircraft.

CompuChsm WssMm Division (CHEMWEST)

SR302633

RICHARD HENSONGC/MS Senior Chemist Supervisor SV & VOACompuChem Western Division (CHEMWEST)

Responsibilities: Mr. Henson joined CHEMWEST in July, 1988. He isresponsible for running GC/MS analyses using EPA Methods624/8240 and 625/8270 for Volatile and Semi-volatile PriorityPollutants and Hazardous Substances.

Education: Mr. Henson received his Bachelor of Science degree inChemistry from University of California, Davis, in 1986, withemphasis in Environmental Toxicology. He also has attendedthe Hewlett Packard GC/MS Operators course in Paramus, NewJersey, and the Finnigan Institute in Cincinnati, Ohio.

Job Experience: Prior to joining CHEMWEST, Mr. Henson was employed by ,McLaren Environmental Engineering for 1 1/2 years. He wasresponsible for development of McLaren's GC/MS capabilities,doing Method Development and State Certification work forEPA methods 624/8240 and 625/8270. Mr. Henson was alsoresponsible for development of EPA Methods 8080 -Pesticides, 8080 - PCB'S, Total Petroleum Hydrocarbons byGC/FID, 8040 - Phenols, and 8100 - Polynuclear Aromatics, aswell as associated extraction and sample concentration tech-niques. He was responsible for overseeing all organicanalyses. Mr. Henson also worked for 6 months as anundergraduate research assistant involved with enhancedphoto-oxidation of rice herbicides using titanium oxide andzinc oxide catalysts.

CempuChsm W»tt»m Division (CHEMWEST)

AR30263I*

JOHN MEDINA Jr.GC/MS Senior Chemist Supervisor Dioxin


Responsibilities: Mr. Medina, who joined CHEMWEST in November, 1986, isresponsible for operating and maintaining GC/MSinstrumentation, mass spectral interpretation, data reductionand review for volatile, aemivolatile, and dioxin analysis. Mr.Medina is the Supervisor of the Dioxin Extractions Laboratory.

Education: Mr. Medina earned his Bachelor of Science Degree inChemistry from the University of California, Davis in June of1984.

Job Experience: Prior to joining CHEMWEST, Mr. Medina worked for CaliforniaAnalytical Laboratories-ENSECO for two years and threemonths. Mr. Medina worked for the Organic Extractions groupdoing semivolatile and pesticide extractions, metals digest,dioxin extractions, and clean-up. In June of 1985, Mr. Medinajoined the GC/MS group at CAL Mr. Medina worked in theVolatile Organics group from June of 1985 until joining theDioxin group in May of 1986. Mr. Medina has 3 years experi-ence in the GC/MS operations and in mass spectral interpreta-tion. He has attended Finnigan Institute for courses in SuperIncos Data Systems and basic GC/MS operation, and Extrel forGeneral Operations of the Extrel GC/MS.

CempuChsm Western Division (CHEMWEST)

1&302635

i LEONA WINNERGC Chemist I I/Night Supervisor


Responsibilities: Ms. Winner joined CHEMWEST in May, 1990. She isresponsible for the analysis of votatiles and semivolatiles byGC/MS; preparation of volatile standards when necessary;peer review of GC/MS volatile data; and write-ups for volatileand semivolatile analysis. She is also the Night LaboratorySupervisor for the facility, and is responsible for all night-shiftpersonnel.

Education: Ms. Winner received a Bachelor of Arts Degree in BiologicalScience from the University of Davis in June, 1988.

Job Experience: Prior to joining CHEMWEST, Ms. Winner was employed foreighteen months at AN LAB Analytical Laboratory as anEnvironmental Analyst She was responsible for the sampleextraction of water, waste water, soil and fish for pesticides,herbicides, phenols and petroleum hydrocarbons using EPAmethods. Ms. Winner also was responsible for analyzingextracts and volatiles using gas chromatography techniques.Ms. Winner has a total of two years and four months laboratoryexperience prior to her employment with CHEMWEST.

CompuChcm Wssum Division (CHEMWEST)

&R3Q2636

KURT KULHAVY' Chemist I

CompuChem Western Division (CHEMWEST), f

Responsibilities: Mr. Kulhavy joined CHEMWEST in October, 1990. He isresponsible for the analysis of GC/MS volatile samples,preparation of standards used in volatiies, and the write-up ofall volatile sample data.

Education: Mr. Kulhavy received a Bachelor of Science Degree inChemistry from the University of California at Davis in August1986.

Job Experience: Prior to his employment with CHEMWEST, Mr. Kulhavy wasemployed for three years and ten months as a researchscientist with Aquanautics Corporation in Alameda, California,where he performed the analysis of chemical compounds forcommercial use. Mr. Kulhavy has a total of six years, sevenmonths laboratory experience prior to his employment withCHEMWEST.

CompuChtm Wssttm Division (CHEMWEST)

AR302637

DIANE PAGEGC/MS Operator


Responsibilities: Ms. Page joined CHEMWEST in January, 1992. She isresponsible for volatile and semivolatile analysis by GC/MS,preparation of volatile standards when necessary and thewrite-up of data for volatile and semivoiatile analysis.

Education: Ms. Page received a Bachelor of Science degree in Chemistrywith a Minor in Biochemistry in May, 1982, from Colorado StateUniversity.

Ms. Page has completed courses in Interpretation of MassSpectra from American Chemical Society and MSD GC/MStraining courses from Hewlett Packard.

Job Experience: Prior to joining CHEMWEST, Ms. Page was employed asManager of Operations—Inorganic Chemistry at VistaLaboratory, Colorado for 21 months. Ms. Page wasresponsible for all aspects of day-to-day operations of theinorganic chemistry department; supervised and directed astaff of five analysts; was a technical consultant for both staffand clients; reviewed raw data and assisted in the compilationof final reports and was instrumental in expansion anddevelopment of analyses offered as services.

Previous to Vista, she was an Analytical Chemist for RockyMountain Analytical Laboratory for four years. Ms. Pageperformed analysis on prepared samples for trace metals. Herresponsibilities included scheduling of work, maintenance ofinstruments, data review and reduction; performing analysis ona variety of matrices for the determination of volatile organiccompounds utilizing a GC/MS, and writing short programswhich assisted in processing the data in a presentable format

Also, Ms. Page was an Inorganic Analytical Chemist forCalifornia Analytical Laboratory for 15 months. Ms. Pageperformed analysis on samples to determine their elementaland inorganic composition. Her responsibilities includedsample preparation, analysis, and data reduction.

In addition, she was an Analytical Chemist for MetalProcessing Industries for 9 months. Ms. Page performedanalysis on electronic components to determine the1concentration of precious metals. Her duties included samplepreparation and analysis.

CompuCh»m W«st»rn Division (CHEMWEST)

AR302638

ALICE ROACHData Specialist


Responsibilities: Ms. Roach joined CHEMWEST in June, 1991. Ms. Roach isresponsible for the preparation of CLP and commercial datapackages for submission to the EPA and othar.eliants. Thisinvolves contact with laboratory managers and chemistsregarding sample problem resolution.

Education: Ms. Roach received certificate from American River College -1983 in Word Processing

Ms. Roach has working knowledge of IBM-PC, IBM-ON, Wang. OTS 140, IBM Memory, IBM MTST and is experienced withoperating the Finnigan Formsmastar System and SampleAnalysis Management System.

Job Experience: Prior to joining CHEMWEST, Ms. Roach worked for RadianCorporation in the Document Control/Data Managementdepartment for four years. Ms. Roach was responsible fordata entry of organic CLP data packages, reviewing completeddata packages for the EPA, following required detection limits,QC, along with formatting, and electronically transferringreviewed data to the radian sample analysis system.

Prior to that, Ms. Roach was an Assistant Bookkeeper forTrans Cal Associates, for one year and was responsible fordata entry, invoices, general ledger, along with daily andmonthly accounting reports on computer. She also handleddaily bank deposits, accounts payable/receivable and financialstatements.

In addition, Ms. Roach served as a ComputerOperator/Secretary for Plan Services, and was responsible forover the phone inquiries, and taking/entering information intothe IBM On-Line System.

GempuChcm Wtturn Division (CHEMWEST)

AR302639

THERESA SCHMIDT yData Specialist

CHEMWEST Analytical Laboratories, Inc.

Responsibilities: Ms. Schmidt joined CHEMWEST in July 1991. As a DataSpecialist, Ms. Schmidt's duties are to prepare and submit datareports to the EPA or other clients in a timely and accuratemanner.

Education: Ms. Schmidt received her Bachelor of Science degree inBiochemistry from the University of California, Davis in 1989.

In addition, Ms. Schmidt attended Los Medanos College,Pfttsburg for two years.

Job Experience: Ms. Schmidt worked for the Marriott Corporation as a ServiceManager for three years. She was responsible for hiring andtraining new employees, scheduling; supervising dining roomactivities, planning functions and maintaining proper foodhandling procedures.

Prior to Marriott, Ms. Schmidt worked as a Shift Leader forSegundo Dining Commons for two years. She wasresponsible for supervising staff, training service personnel,customer service, and performed various food servicepositions.

Ms. Schmidt also performed seasonal work as a Clerk for JCPenny for one year. She was responsible for handling credittransactions and solve credit problems!


AR3026UO

GREG BRISK!Dioxin Extractions Chemist I


Responsibilities: Mr. Briski joined CHEMWEST in April, 1990. He is responsiblefor dioxin extractions and dioxin column clean-up procedures.

Education: Mr. Brisk! received a Bachelor of Arts Degree in BiologicalScience from Antioch College, Yellow Springs, Ohio, in 1988.

Job Experience: Prior to joining CHEMWEST, Mr. Briski was a ProductionAssistant in 1989 for the California Truffle Company inWoodland, California, where he participated in the preparation,inoculation and harvest of truffle cultures, and maintainedlaboratory equipment

In addition, Mr. Briski has been employed as an EmergencyMedical Technician, and a Herpetology and EntomologyAssistant

CempuCnsm Wcstsrn Division (CHEMWEST)

GREG COLEDioxin Extractions Chemist II . . .


Responsibilities: Mr. Cole joined CHEMWEST in October, 1991. He isresponsible for dioxin extractions and dioxin column clean-upprocedures.

Education: Mr. Cole received his Bachelor of Science degree inPsychobiology from UCLA in 1983.

Job Experience: Prior to joining CHEMWEST, Mr. Cole was a Team Leader in anextractions laboratory for NET Pacific for one yaar.Prior toNET, he was a supervisor in the sample preparation laboratoryfor Radian Corporation for 18 months. Previous to hisemployment at Radian, Mr. Cole was a supervisor in anextractions laboratory for American EnvironmentalManagement Corp. for two years. In addition! he was asupervisor of a sample preparation laboratory for RadianCorporation for 14 months. Prior to his promotion, he workedas a chemical technician in the sample preparation laboratoryfor 15 months.

In the above listed employment history, Mr. Cole wasresponsible for scheduling samples into the laboratory andinputting results into the LIMS system. He also conductedlaboratory staffing and team development, methoddevelopment and standards preparation, laboratory safety andprocuring vendor contracts and ordering supplies

CempuCh*m Wtsttm Division (CHEMWEST)

CHARLES F.TAYLORChemist II


Responsibilities: Mr. Taylor is responsible for the analysis of GC/MS dioxin, samples, preparation of standards used in the dioxin

department, and the write-up of dioxin data.

Education: Mr. Taylor earned his Bachelor of Science Degree in Chemistryfrom California State University, Sacramento in 1987.

Job Expsrianca: Prior to his transfer to the GC/MS Dioxin Department in Juna1991, Mr. Taylor worked in tha GC/MS Volatiles Department forone year. He was responsible for the analysis of GC/MSvolatile samples, preparation of all standards used in volatiles,and the write-up of all volatile samples.

Mr. Taylor joined CHEMWEST in January of 1988, where heworked as an Extraction Specialist until June 1990, He wasresponsible for the extraction and concentration of water andsoil samples for organic analysis, including priority pollutants,dioxins and furans. He was also responsible for columnchromatography clean-up procedures. Mr. Taylor's duties alsoincluded inorganic analyses, such as nitrates/nitrites andcyanides, as well as the analysis of total petroleumhydrocarbons by IR and data reduction utilizing a program onan Epson Equity III computer system. Mr. Taylor was alsoresponsible for the preparation of all dioxin and furanstandards for the extraction lab and GC/MS department

Prior to joining CHEMWEST, Mr. Taylor worked for six monthswith the California Department of Food and Agriculture at theirMeadowview Road Laboratory in the Pesticide Residuasection, extracting soil, waters, and produce samples forpesticides. He has two years of experience preparing soil andwater samples for analysis by EPA-CLP methods 8080,8270,8140, and 8150 including column chromatography clean-upprocedures and TPH for GC analysis. Mr. Taylor has 11/2years experience in the extraction and column chromatographyclean-up techniques of polychlorinated dibenzo-p-dioxins andpofychlorinated dibenzo furans (EPA methods 8280 and 613).Mr. Taylor also has experience analyzing samples forpesticides by GC.

CempuCnsm Wssttm Division (CHEMWEST)

AR3026U3

KATHERINE KANAGAKIChemist II


Responsibilities: Ms. Kanagaki joined CHEMWEST in July, 1989. Ms. Kanagakiwas promoted to Chemist II Trainee in September, 1991. As aChemist II, Ms. Kanagaki is responsible for performing semi-volatile analysis by GC/MS and the data write-up for samplesanalyzed in the semi-volatile area. Ms. Kanagak! isresponsible for utilizing all software involved with GC/MSanalysis of semi-volatiles, including software used on personalcomputers. Ms. Kanagaki is responsible for knowing andfollowing CHEMWEST QA/QC policies as well as EPA CLPQA/QC criteria and applying these criteria to aarnhvolatilesanalysis.

Education: Ms. Kanagaki received her Bachelor of Science Degree inBiological Sciences from the University of California at Davisin 1976.

Job Experience: Prior to her promotion to Chemist II, Ms. Kanagak! worked inthe Inorganics Department as a Chemist I. Her responsibilitiesincluded performing various wet chemistry analysis includingNitrate/nitrite, chloride, alkalinity, pH, and MBAS, as well asother wet chemistry analysis. Ms. Kanagaki was alsoresponsible for the write-up and peer review of data.

Prior to joining CHEMWEST, Ms. Kanagaki was employed withU.C. Davis Medical Center, Nuclear Medicine Department, as aStaff Research Associate III for 3 years. Her responsibilitiesincluded methods development, collection, analysis, andpresentation of data, radio-labeling of proteins, columnchromatography, HPLC, and biochemical analysis of patientand animal plasma. Prior to that, Ms. Kanagaki was a StaffResearch Associate II in the Protein Structure, Health ScienceResearch Lab. of U.C. Davis Medical School for 8 years. Shewas responsible for computer program development, aminoacid analysis, flow cytometry, HPLC, GLC, TLC, and pro-tein/peptide sequencing.

Ms. Kanagaki also has 7 1/2 additional years of laboratoryexperience including 3 months as a Staff Research Associate Iin the Chemistry Department at UC Davis and 4 years as a LabAssistant also with the Chemistry Department at UC Davis. AsStaff Research Associate, Ms. Kanagaki's responsibilitiesincluded operation and maintenance of the x-raydiffractometer, scientific illustration, crystal synthesis and dataentry. As a Lab Assistant, she was responsible for labpreparation for general chemistry, quantitative chemistry, andphysical chemistry courses.

CempuCh.m Wt«»m Division (CHEMWEST)

BARBARA ADLERData Specialist

CHEMWEST Analytical Laboratories, Inc.

Responsibilities: Ms. Adler is responsible for the preparation of dioxin data forsubmission to clients. Ms. Adler works closely with the GC/MSManager, GC/MS Dioxin Suprevisor and dioxin Chemists toensure accurate final report generation. Her additionalresponsibilities included in-housa tracking of all raw dataawaiting report generation.

Education: Ms. Adler has completed courses in Advertising and Marketingat the University of Denver.

Job Experience: Prior to joining CHEMWEST, Ms. Adler was the GeneralManager for the Capitol Plaza Building and the director ofCatering for the Clarion Hotel, Sacramento.

CompuChtm W«i1«m Division (CHEMWEST)

AR3026l*5

CHEMWEST ANALYTICAL

LABORATORIES, INC.

ANALYTICAL EQUIPMENT LISTS


AR3026li6

1 of 13CEZKWIST Analytical Laboratories. Inc.

CHEMWEST ANALYTICAL EQUIPMENT LISTS

February 1992

This page left'intentionally blank.

A J? 362(047

F«ft 2 of 11CHEMWEST Analytical Laboratoriw, Inc.


February 1992

GC/MS Analytical Equipment List

3 - Finnigan 5100SP GC/MS Systems with Turbomolecular Pumps, tocos m/Nova4X Data Systems, including the NBS 42222 compound Mass Spectral Library,and Printronix Printers

2 - Finnigan Incos 50 GC/MS Systems with Turbomolecular Pump, with CTC-A200S,Incos 50/DG Model 10 System - one with the NBS 49999 Compound Mass SpetralLibrary and one with 42222 NBS Compound Mass Spectral Library, Hewlett-Packard 5890 GC, with Printronix Printers

1 - Extrel ELQ-400 GC/MS System with Diffusion Pump, Incos m/Nova 4X DataSystem, including the NBS 42222 compound Mass Spectral Library, andPrintronix Printer

1 - 5100/LGC Varian GC with Turbomolecular Pump Super-Incos with 1DOSm/Nova 4X Data System, including the NBS 42222 compound Mass SpectralLibrary

2 - Finnigan Stand Alone Incos m/Nova 4X Data System, including the NBS 42222compound Mass Spectral Library, and Printronix Printers

2 - Tekmar LSC-2 Purge and Trap Unit with 10-Port Automatic Samplers

2 - 386 Computer with HP Laser Jet H Printers, Interface to Finnigan GC/MS DataSystems, and Finnigan Formaster Software for CLP Forms Generation

1 - 386 SX Computer with Dot Matrix Printers

1 - Top Loading Balance, Scientific Products TL1600

2 - Refrigerator/Freezers

1 - Freezer

Pafa 3 of 13CHEMWEST Analytical Laboratories, Inc.


February 1992

GC Analytical Equipment List

1 - Varian 5560 High Performance Liquid Chromatograph with VariableWavelength UV Detector, Fluorescence Detector, and Automatic Samplers

t

12 - Varian 3400 Gas Chromatographs

1 - Varian 3300 Gas Chromatograph

1 - SRI 8610 Portable Gas Chromatograph

7 - Varian Electron Capture Detectors (ECD)

8 - Varian Flame lonization Detectors (FID)

1 - SRI Flame lonization Detector (FID)

6 - Tracer Photoionization Detectors (PJD)

1 - SRI Photoionization Detector (PID)

3 - OI Electrolytic Conductivity Detectors (ELCD - Hall type)

• 4 - Tracer Electrolytic Conductivity Detectors (ELCD - Hall type)

2 - Varian Thermionic Specific Detectors (TSD)

1 - Varian Flame Photometric Detector (FPD)

3 - Varian Split/Splitless Capillary Injectors

5 - Tekmar LSC-2 Purge and Trap Systems with 10-Port Automatic Samplers

2 - Tekmar LSC-2000 Purge and Trap Systems

2 - Tekmar 2016 Automated Liquid Samples with Heated Sample Jackets

4 - Varian 8035 Automatic Liquid Samplers

1 - Hewlett-Packard "A400" Series Laboratory Data Acquisition System

* of 13CHBiWZST Analytical Laboratoriaa, Inc.

- — v/ *>Jf ft


February 1992

GC Analytical Equipment List (continued)

1 - Hewlett Packard A900 Series Laboratory Data Acquisition System

5 - • Hewlett Packard Quiet Jet Printers

1 - Data Products Laser Model 2600 Laser Printer

1 - Hewlett Packard Jet m Printer

4- Hewlett Packard 150 terminals

1 - Varian 654 Data Acquisition System

5 - IBM-AT Compatible Computer with Dot Matrix Printers

1 - IBM-XT Compatible Computer with Dot Matrix Printer

4 - Refrigerator/Freezers

Paja 5 of 13CHEMWEST Analytical Laboratoriti, Inc.

^302650


February 1992

Metals Equipment List

1 - Thermo Jarrel-Ash Model 61 ICP with Autosampler and IBM PS-2 Model 50Data System and Dot Matrix Printer

2 - Perkin-Elmer 51002 Graphite Furnace AAs with Autosamplers and IBM-ATCompatible Data Systems with Dot Matrix Printers

1 - Instrumentation Laboratories Video 12E AA with Graphite Furnace, 440Organic Vapor Accessory, Data System, and Dot Matrix Printer

1 - Penske-Martens Closed Cup Flashpoint Apparatus

1 - Barnstead Nanopure II with Corning MegaPure MP-3A Still

1 - Leeman PS200 Mercury Analyzer with Autosampler and IBM-compatible datasystem and dot matrix printer

1 - Top Loading Balance, Scientific Products TL1600 - Backup

1 - Lab Line Orbital Shaker

2 - Blue M Magni-Whirl Constant Temperature Water Baths

4 - Hot Plates .

1 - Combination Hot Plate/Stir Plate

1 - Mettler, B132440, Top Loading Balance

Paga 6 of 13CHKMWZST Analytical Laboratories, Inc.

AR30265I


February 1992

Wet Chemistry Equipment List

1 - Fisher Scientific 750G Isotemp Oven (Housed in Metals)

1 - 01 Model 700 Total Organic Carbon Analyzer, with Solid sampler, ALS, andDot Matrix Printer (Housed in Metals)

1 - Perkin-Elmer 1310 Infrared Spectrophotometer

1 - Technlcon TRAAC 800 Autoanalyzer with IBM Data System and Dot MatrixPrinter . •

1 - Dionex Ion Chromatograph with Automatic Sampler and Dionex Integrator(Housed in Metals)

2 - Milton-Roy Spectronic 21 UV/VIS Spectrophotometers

2 - Orion 940 lonanalyzers with RS232 Computer Interface and Specific IonElectrodes for pH, F"' and NH3

1 - Monitek 21 Nephelometer (Turbimeter)

1 - YSI 35 Conductivity Meter

1 - Lars Lande Rotary Extractor for WET/TCLP Extractions

1 - Labconco COD Digestion Unit (plus Hach COD Kit)

1 - Labconco Rapid Still II Auto Distillation/Digestion System (Kjeldahl)

1 - Barnstead Nanopure n

1 - Analytical Balance, Scientific Products SP180

1 - Boekel Desiccator

1 - Electric Autoclave

1 - Refrigerator

F.I. 7 of 13CEEHWEST Analytical Laboratories, Xae.

SR302652


February 1992

Wet Chemistry Equipment List (Continued)

Miscellaneous Laboratory Glassware and Method Apparatus

- CN Distillation Apparatus

- Imhoff Cones

- Titration Apparatus

Paja 9 of 13CEEKWEST Analytical Laboratories, Inc.

SR302653


February 1992

Sample Preparation Equipment List

1 - Hewlett-Packard 5880 Gas Chromatograph with dual Electron CaptureDetectors (BCD) and dual Split/Splitless Injectors, Dual Channel DataSystem, and ALS

1 - Perkin Elmer, Sigma 3B Chromatograph with Flame lonization Detector (FID)and Split/Splitless Injector

2 - Top Loading Balances, Scientific Products TL1600 and Mettler P5404

1 - Analytical Balance, Sartorius A200S

1 - pH Meter, Scientific Products

2 - Rotary Evaporators, Haake Buchler

2 - Steam Baths, 10 Place, Custom

3 - Sonic Dismembrators, Artek Model 300

32 - Soxhlet Extraction Apparatus

20 - Kuderna-Danish Concentration Apparatus

20 - Continuous Liquid-Liquid Extractors

1 - Muffle Furnace, Thermolyne 1400

4 - Ovens, VWR Scientific 1305U .

1 - 40 Place Orbital Shaker, Labline

4 - Nitrogen Slowdown Apparatus

1 - Blue M Laboratory Oven

1 - Dry Bath, Thermolyne

1 - Jovan CT-4-11 Centrifuge

1 - Sand Bath

Page 9 of 13CEEKWEST Analytical Laboratories, Inc.

i CHEMWEST ANALYTICAL EQUIPMENT LISTS

February 1992

Sample Preparation Equipment List (continued)

3 - Refrigerators

1 - Waters Millilab Workstation, GPC Automated Cleanup System with a 590 HPLCpump, 480 UV Detector and Waters fraction Collector

1 - Freezer

1 - Haake, Kryo-Thermat 1100 Chiller Reeirculator

1 - Haake N3-B - Hot Water Circulator

1 - VWR 1140 Chiller Recirculator

1 - SRI 8610 Gas Chromatograph

1 - Hewlett Packard Display Terminal 700/92

Various Sizes of the Following Laboratory Glassware:

- Separatory Funnels

- Flasks

- Beakers

- Chromatography Columns

Page 10 of 13CHTMWrST Analytical Laboratories, Inc.

AR302655'

CHEMWEST ANALYTICAL EQUIPMENT LISTSi

February 1992

Additional Computer Equipment List

1- DEC PDP-11 Computer

10 - 386 Computers

22 - IBM-AT 286 Compatible Computers

3 - IBM-XT 8088 Compatible Computers

1 - IBM-AT Compatible Lap Top Computer

2 - Epson GQ-3500 Laser Printers

1 - Hewlett-Packard Laser Jet n Laser Printer

1 - DEC Laser Printer

7 - Daisy Wheel Letter Quality Printers

17- Dot Matrix Printers

4 - 2400 Baud Modems

1 - . 9600 Baud Modem

2 - 1200 Baud Modems

2 - Stand Alone FAX Machines

1 - Internal FAX Board for AT-Compatible Computer

5 - Copiers

1 - HP 3000 Mini Computer

2 - HP 1000 Lab Automation Computers

1 - Equinox PBX Switch

3 - Hewlett-Packard High Speed line Printers

11 - Hewlett-Packard Terminals

Page 11 of 13CHDJWEST Analytical Laboratories, Inc.

AR302656


February 1992

Additional Computer Equipment List (Continued)

2 - HP Laser n Printers

1 - HP Laser Serial II Printer

1 - Toshiba 3200SX Laptop

5 - Quiet Jet Ink Jet Printers

Page 12 Of 13CHEHWEST Analytical Laboratories, Inc.

AR302657 I


February 1992


Page 13 of 13CHEMWEST Analytical Laboratories, lac.

AR302658

CHEMWEST ANALYTICALy

LABORATORIES, INC.

ANALYTICAL INSTRUMENTATION


CHEMWEST Analytical Laboratories, Inc. Page 1 of 9

AR302659

CHEMWEST ANALYTICAL INSTRUMENTATION

January 1992

This page toft Irrtsrrtjonalty blank.

CKEMWESTAmJyticilUh»ftt*ri««,!ne.


January 1992

GC/MS - Vbtotfiet. Seml-Volattles, Dtoxins

Analyws Model/Instrument Manufacturer Performed Revision

GC/MSID*CW-16N« 13955-0966DATA SYSTEMwlthCW-1EPA/NIHMassSpectral Ubrary

GC/MSIDOCW-2SN« 13955-1-0986DATA SYSTEMwtthCW-2EPA/NIH MassSpectral Ubrary

GC/MSID* CW-3SN# 13378-12MDATA SYSTEMwith CW-3EPA/NIH MassSpeetral Ubrary

GC/MS .ID* CW-4 (FINNEX)SN*DATA SYSTEMwith CW-4EPA/NIH MassSpeetral Ubrary

GC/MSID*CW-5SN« 13954-0387DATA SYSTEMwHhCW-B

GC/MSD«CW-«SN« 13187-0384DATA SYSTEMwhhCW-6EPA/NIH MassSptetal Ubrary

Finnigan

Finnigan

Finnigan

finnigan

Finnigan

Finnigan

Extrel

Finnigan

Finnigan

Finnigan

Finnigan

Finnigan

Dtadn(Commeroial and OP)Seml-VoWiles(Commereial and CLP)Volatilei(Commeroial and CLP)

Semi-Volatiles(Commeroial and CLP)Dioxin(Commeroial and CLP)

Volatiles(Commereial and CLP)

Volatiles(Commereial and CLP)

SemM/olatfles

Dioxin(Commereial and CLP)

i

S100SPSuper-lnoos wfthDOSUI/Nova4X

42222 Compounds

6100SPSuoer-lneos wHhDOS Ill/Nova 4X

42222 Compounds

6100SP

Super-ineos wtthDOS Ill/Nova 4X

42222 Compounds

ELO-400

Super-lneos wtt)IDOSIII/NOVA4X

42222 Compounds

INCOS iCCTCA200SAutosamptorINCOS SO/DOModel 1049900 Compounds6100/LQCVarian GCSuper-lnoos wtti(DOS Ill/Nova 4X

42222 Compounds

InatsJlaHonCMS

(Updates)

vrr

w

1CV86

tO/17

10/89

a/w

CHEMWEST Analytical UtewtoriM. hie. P*9* * ** *


January 1992

GC/MS - Volatiles, SemMfolatUek, Dtoxins (Continued)

Analyses Model/Instrument Manufacturer Performed Revision

GC/MSDfCW-7SN* 037006DATA SYSTEMwtthCW-7EPA/NIH MassSpeetral Library

Purge and Trap101 CW-4SN* 87278006 & 846

Purge and TrapIO*CW-3SN* 88044019 &

1555

Data SystemID* Stand AloneData SystemID* Stand Atone

Data System (PC)ID* Stand Atone

Data System (PC)ID* Stand AtoneData System (PC)ID* Stand AtoneData System (PC)ID* Stand Atone



Finnigan

Finnigan

Tekmar

Tekmar

Finnigan

Finnigan

386 Ctone

NEC

Tandon

3S6 CtoneSX

386 Ctone

386 done

Semt-Volatnes

(Commeroial and CLP)

Volatile* (SampleConosnfretton andIntroduction)

Volatile* (SampleConcentration andIntroduction)

Off-UneDataReduction

On-UneDataReduction

CLP and Off-Une DataReduction

Off-UneDataReduction

Off-UneDataReduction •

CLP and Commereial

Dtoxins

CLP and CommereialVolatiles andSemJvolatfle*(Formatter)

CLP and CommeroialVolatiles andSemivolatfles(Formatter)

MOOS SOCTC A200AutosamplerNCOS SO/DO

49999 Compounds

LCS-2wtthALS

LCS-2 w«h ALS

Euper-tnooe withIDOS Ill/Nova 4XSuper-lncoe withIDOS Ill/Nova 4X

ISM CompatibleComputerFormsmastsrIBM CompatibleComputer

IBM CompatibleComputer


IBM Compatible •Computer


InstallationOats

(Update*)

7/BO

10/17

10/W

t/87

•788

i2/s7

8/B7

12/88

CHEMWEST Antiytiu) Ubermtarwt, Inc. F<9* 4 Of •


January 1992

METALS

InstalattonAnalyse* Model/ Dtte

Instrument Manufacturer Performed - Revision (Updates)

CP10*001036CNi 36882

G M.ID* 001024SN* 134575

GFAA»* 001030SN* 133927

AAID* 001099SN«2365

Mercury Analyzer10*SN* 1048A

Flash PointID*SN* 10AT - 13

Thermo Jaira4-Ash

PerMn-Etmer

PerMn-Eimer

InsfrumenlsUonLaboratories

LeemanUbs

Pen»ke-Martn

Metals(Commeroial and CLP)



Metals(Commercial and CLP)

Mercury

Flashpoint

Modal 61 with ALSand Data System

8100Z wttt ALS andData System

B100Z wKh ALS andData System

Video 12EwHh OFand Data System

PS200

CtoeadCup

7/88

11/S8

. 1/M

1/17

12/81

6V87

CHEMWEST Analytical UMiMeri**, Me. Page I Oft

AR'302663


January 1992

WET CHEMISTRY

metaJetionAnalyaes Model/ Oat*

Instrument Manufacturer Performed Revision (Update*)

TOC»* 001095SN* 8080-9-47

1CK>« 001041SN* 883559

AuteanaryierID* 001018SN*59

UV SpsetrophotomstarID* 001019SN* 3152073028

UVSptctrophotonwterID* 001020SN#081t486A

pH/tonana)yzerID* 001012SN* TVT99A

pH/IonanalyzerID* 001013SN* OV25A - M

Turbid imetsr10*001011SN*L-308S

InfraredSpectrophotometsr(Operated by SamplePrep.)ID*CW1SN* 132287

Conductivity MeterID* 001005SN* 1422

10 Corp.

Dionex

Toohnioon

Milton-Roy

Milton-Roy

Orion

Orion

Monrtek

PerWn-Elmer

YSI

Total Organto Carbon(TOCJlC,POC,eoBds)

IonChromatograpny(tens)

CoiofiTWtric(CN,N03,N02)

Cotorimvtric

Cotoflrnvtric

pH, SpeoHto ton(pH. NH4. F)

pH« Spvciftc Ion(pH.NH«.F)

Turbldrty

Total PetroleumHydrooarbons

Conductivity

Ol 700 with ALS,624PSSoed*Sampler. Dot Mattea e«e ePJIIVT

Dtonax 40001wtth ALS and Spectra-Physios Integrator

TRAAC 800 wtthData System

Spee*onte21D

8peetronie21

940 wtth RS232IftlinftM

940wKhRS232interface

21

1310

35

4/BC

10/18

t/r

11/89

1/88

a/87

7/89

2/87

2/87

2/87

CHEMWEST Analytical Ubontsri**, Inc. PeO.el.ef9

AR30266U' I

CHEMWEST ANALYTICAL INSTRUMENTATIONJanuary 1992

GC-VOLATILES

Instrument

GCVD«1SN* 3400-6048

GCVID* 2SN* 3400-34149119701691168036GCVID* 3SN* 3400-3356873150162229

GCVID* 4SN* 3400-5781

GCVID* 5SN* 3400-4034

GCVID* 6SN* 3400-6043Caggfrsngn'88298007

GCV10*7SN* 8717

GCVID* 13SN* 217

Purge and TrapSN*2229&87315018

Purge and TrapSN* 357 & 1209

Purg* and TrapSN* 357 & 1209

Manufacturer

Vmfmn

Varian

Varian

Varian

Varian

Varian

Varian

SRI

Tekmar

Tekmar

Tekmar

Analyse*Performed

VDKBieS

Volatile*

Volatile*

WnlatltAA

Volatile*Total PetroleumHydrocarbon .Volatiles

VolatilesTPH

Volatiles

Volatilss (SamplePreparation andIntroduction)Volatiles (SamplePreparation andIntroduction)Volatile* (SamplePreparation andIntroduction)

Modal/Revision

8400 with DualELCD

•400 wMn ELCD.PID, and FID

Tekmar 2016 ALSTekmar 2000 LSC8400 wtth DualELCD

ALS TekmarLCS-2 Tekmar

3400 wtth ELCDandPID

3300 with PID,and FID

3400 wtth FID.and PID

Tekmar 2016 ALSTekmar 2000 LCS

3400 wtth PID,FID

6610 wtth FIDand PID

LCS-2 wtth ALS

LSC-4000wtthALSGC-S

LCS-2 wtth AL8

tostalettoDale

(Updatei

8/88

1/87

6/87

R/ae

6/87

7/88

9/91

6/89

ft/87

6/87

1/87

n) Columns

MegatereCapMary

Ii«f8at¥1fl ••*»»«"

MegaboraCapBtoy

MsQsboni Can8ary

Megaboro Capfflary

Megabow CapBlary

Magabore CapBary

Capfiary

NA

NA

NA

CHEMWEST Analytic!) Ubofttorfet, Me. Page 7 oft

*R302665


January 1992

GC-VOLATILES (CONTINUED)

tnatalattonAnalyses Model/ Dale

Instrument Manufacturer Performed Revision (Updates)

Purge and TrapSN* 87294006 &

1103

Purge and TrapSN* 8729401311015

Purge and TrapSN* 88062008 1>68290058

Data SystemSN« 2921A00245

Data System10*6700338

Tekmar

Tekmar

Tekmar

Hewlett Packard

NEC

Volatile* (SamplePreparation andIntroduction)

Volatile* (SamplePreparation and

Volatile* (SamplePreparation andIntroduction)Date* Acquisition(CLP andCommercial)Off-UneDataReduction/DateSystem Terminal

LCS-2 wtth ALS

GC-4

LCS-2 wfchALS

GC-7

LCS-2 wtth ALS

GC-1A900


8/88

1008

7/88

6/91

6/87

Columns

NA

NA

NA

NA

NA

CH EM WEST Antfytiul Ukomttrwt, Inc. F*9* 8 Of 8

&R302666


January 1992

GC-PESTICIDES

fctataBatbnAnalyses Modal/ Oat*

Instrument Manufacturer Performed Revision (Updates)

GC10*1SN* 9400-4035

GCID* 2SN« 3400-2534

GCID* 6SN* 3400-3415

GC10*7SN* 3400-2533

GCD* 11SN* 3400-6047

GCID* Screen 1SN* 2151A-03378(Operated bySample Prep.)

HPLCID* 13SN* 1105

Data SystemSN* 2902A01247

Dita SystemID* A000019

Varian

Varian

Varian

Varian

Varian

Hewlett Packard

Varian

Hewlett Packard

CompuClub

OC Pesticide* andPCS* (Commeroialand CLP)HerbicidesTotal PetroleumrtyorocttfDonPestioldes

OC PesticidesPCBs (Commeroialand CLP)HerbicidesOrganophosphorusPesticide*

OC Pesttoides andPCB* (Commercialand CLP)

CLPOC/PCBPesticide Screens

PorynudearAromaticaCarbamatss

Data Acquisition(Comrrw iJI

Off-UneDataReduction/DataSystem Terminal

3400 wtth DualECO and 8035ALS

8400 wtth FID,ECO, cap. InLand 8035 ALS

3400 wtth DualECO, oap. Inj.and 8035 ALS

3400 wtth DualTSD, oap. InJ.FPD Availableand 8035 ALS

3400 wtth DualECO and 8035ALS

5880 wtth DualECO, dual oap.In], dual PP.Data System,and ALS

5580 wtth UVand Fluor.and ALS400A

CM CompatibleComputer

6/87

12/86

12/86

12/86

12/88

2/88

8/89

3/89

6/88

Columns

Megabore CapBary

CapBary

Megabyte CapBary

Megabore CapUary

Megabore Capiary

CapBary

HPLC

NA

NA

CHEMWEST Analytical Ubemtensi, he. P*S*

3R302667

THE CHEMWEST FACILITY

February 1992

CHEMWEST ANALYTICAL

LABORATORIES, INC.



Page 1 of 7CHEMWEST Analytical Laboratories, Inc.

AR302668


February 1992


Pace 2 of 7CHEMWEST Analytical Laboratories, Inc.


February 1992

Main Facility = 12,600 square feetIndividual Areas Square Feet

o Environment*! Receiving, including: 1,080Walk-In Refrigerator [120]Walk-In Freezer [ 60]

o Environmental Extraction 1,010o Dioxin Extraction 350o GC Lab, including: 1,108 '

GC VOA Room [536]

o GC/MS Lab, including:' 1,009GC/MS VOA Room [364]

o Metals Lab, including: 756ICP/AA Laboratory [306]

o Wet Chemistry 388

o Metals Digest Lab 278o Phase II/Copy Room 272o Maintenance 117o Office Areas 1,739

o Lunch Room 513o Systems • 219o Conference Room . 311o Miscellaneous 3,450

SUBTOTAL . 12,600

Warehouse/Marketing, including:Marketing * [1,391.155]Warehouee [1,973.875]

SUBTOTAL 3,365.03o Warehouse 2,496.00

Total Square Feet 16.461.03


SR302670


February 1992

ANALYTICAL,

LABORATORIES, INC.

FACILITY SQUARE

FOOTAGE

TOTAL FOOTAGE: 12,600

600 VEST N. MARKET BLVD



February 1992

CHEMWEST ANALYTICAL LABORATORIES, INC.MARKETING AND WAREHOUSE

SQUARE FOOTAGS TOTAL HXTAQE: i.ws.

MkRCETINB - 1191.155 WAREHOUSE - 1B7J.i75

4229 NORTHWTE BLVD

160B.W 90 FT

SB JIB FT

Page 5 of 7CEEMWEST Analytical Laboratories, Inc.

flR302672


February 1992

CHEMWEST ANALYTICAL LABORATORIES. INC.WAREHOUSE

SQUARE FOOTAGE

TOTAL SQUARE FOOTAGE: 2,495

4225 NORTHGATE BLVO

MISCELLANEOUS ARCHIVED ITEMS



February 1992

Relationship of the three buildings.

NORTH MARKET IOULEVAKD

Page 7 of 7CHEMWEST Analytical Laboratories, lac.

fiR30267t*

APPENDIX B

CLP 6/91 - Superfund Analytical Methods forLow Concentration Waters for Organics Analysis

ftR302675

SUPERFUND ANALYTICAL METHODS

FOR

LOW CONCENTRATION WATER FOR ORGANICS ANALYSIS

6/91

6/91gr>'-jr%o<""~?/-ARou2676

EXHIBIT B

REPORTING AND DELIVERABLE REQUIREMENTS

6/91

AR3G2677

Table of Contents

Page

SECTION I: Contract Reports/Deliverables Distribution ................ B-3

SECTION II: Report Descriptions and Order of DataDeliverables ...............................:..............B-6

SECTION III: Forms Instruction Guide ...................................B-24

SECTION IV: Data Reporting Forms ......................................B-45

B-2 6/91

'AR302678

SECTION I

CONTRACT REPORTS/DELIVERABLES DISTRIBUTION

The following table reiterates the Contract reporting and deliverablesrequirements specified in the Contract Schedule and specifies thedistribution that is required for each deliverable. NOTE: Specific recipientnames and addresses are subject to change during the term of the contract.SMO will,notify the Contractor in writing of such changes when they occur.

No. Delivery DistributionItem Copies Schedule (1) (2) (3) (4)

1. Updated SOPs 3 60 days after XXXcontract awardand as required inExhibit E.

*2. Sample Traffic 1 3 days after XReports receipt of last

sample in Sample.Delivery Group(SDG).**

***3. Sample Data Summary 1 14 days after XPackage receipt of last

sample in SDG.

***4. Sample Data Package 2 14 days after X Xreceipt of lastsample in SDG.

*** 5. Complete SDG File 1 14 days after X**** receipt of last

sample in SDG.

***6. Data in Computer- 1 14 days after XReadable Form receipt of last

sample in SDG.

Distribution:(1) Sample Management Office (SMO)(2) EMSL-LV(3) Region-Client (Technical Project Officer)(4) NEIC

B-3 6/91

AR302679

No. Delivery DistributionItem Copies Schedule (1) (2) (3) (4)

7. GC/MS Tapes Lot Retain for 365 days As Directedafter data submis-sion, or submit with-in 7 days afterreceipt of writtenrequest.

N.

8. Extracts Lot Retain for 365 days As Directedafter data submis-sion, or submit with-in 7 days afterreceipt of writtenrequest.

9.***** QA plan 3 Copy Submit within 60 days As Directedafter contract award,and as required inExhibit E.

NOTE: Contractor mist be prepared to receive the full contract samplerequirement at the time of contract award.

* Also required in the Sample Data Summary Package.

** Sample Delivery Group (SDG) is a group of samples within a Case,received over a period of 7 days or less and not exceeding 20samples. Data for all samples in the SDG are due concurrently. Thedate of delivery of the SDG or any samples within the SDG is thedate that all samples have -been delivered.

*** Concurrent delivery required. Delivery shall be made such that alldesignated recipients receive the item on the same calendar day.

**** Complete SDG file will contain the original sample data package plusall of the original documents described under Complete SDG Fileparagraph 5.

***** See Exhibit E for a more detailed description.

NOTE: As specified in the Contract Schedule (Section G, GovernmentFurnished Supplies and Materials), unless otherwise instructed bythe CLP Sample Management Office, the Contractor shall dispose ofunused sample volume and used sample bottles/containers no earlierthan sixty (60) days following submission of the reconciled completeSDG file. Sample disposal and disposal of unused samplebottles/containers is the responsibility of the Contractor and

6/91

should be done in accordance with all applicable laws andregulations governing disposal of such materials.

Distribution Addresses:

(1) USEPA Contract Lab ProgramSample Management Office (SMO)P. 0. Box 818Alexandria, VA 22313

For overnight delivery service, use street address:300 North Lee Street, Suite 200Alexandria, VA 22314

(2) USEPA Environmental MonitoringSystems Laboratory (EMSL-LV)P. 0. Box 15027Las Vegas, NV 89114ATTN: Data Audit Staff

For overnight delivery service, use street address:

944 E. Harmon, Executive CenterLas Vegas, NV 89109ATTN: Data Audit Staff

(3) USEPA REGIONS:

The CLP Sample Management Office will provide the Contractor with thelist of addressees for the ten EPA Regions. SMO will provide theContractor with updated Regional address/name lists as necessarythroughout the period of the contract and identify other clientrecipients on a case-by-case basis.

(4) USEPA National Enforcement Investigations Center (NEIC)ATTN: CLP Audit ProgramDenver Federal Center Bldg. 53P.O. Box 25227Denver, CO 80225

B-5 6/91

SECTION II tj

REPORT DESCRIPTIONS AND ORDER OF DATA DELTVERABLES

The Contractor laboratory shall provide reports and other deliverables asspecified in the Contract Schedule (Performance/Delivery Schedule, SectionF). The required content and form of each deliverable is described in thisExhibit.

All reports and documentation MUST BE:

o Legibleo Clearly labeled and completed in accordance with instructions in this

Exhibito Arranged in the order specified in this Sectiono Paginated consecutively in ascending order starting from the SDG Narrative

If submitted documentation does not conform to the above criteria, theContractor will be required to resubmit such documentation with thedeficiencies corrected, at no additional.

Whenever the Contractor is required to submit or resubmit data as a result ofan on-site laboratory evaluation, through a SMO action, or through a RegionalData Reviewer's request, the data must be clearly marked as ADDITIONAL DATAand must be sent to all three contractual data recipients (SMO, EMSL/LV, andRegion). A cover letter shall be included which describes what data arebeing delivered, to which EPA Case(s)/SDGs it pertains, and who requested thedata.

Whenever the Contractor is required to submit or resubmit data as a result ofContract Compliance Screening (CCS) review by SMO, the data must be sent toall three contractual data recipients (SMO, EMSL/LV, and Region), and in allthree instances must be accompanied by a color-coded COVER SHEET (LaboratoryResponse To Results of Contract Compliance Screening) provided by SMO.

Descriptions of the requirements for each deliverable item cited in theContract Performance/Delivery Schedule (Contract Schedule, Section F) arespecified in this Section. Items submitted concurrently MUST BE arranged inthe order listed. The components of each item MUST BE arranged in the orderpresented in this Section when the item is submitted.

Section III contains the form instructions to assist the .Contractor inproviding all the required data. Section IV of this Exhibit contains copies'of the required data repotting forms in specified formats.

'HR3Q268

1. QUALITY ASSURANCE PLAN AND STANDARD OPERATING PROCEDURES

See contract for specifications.

2. SAMPLE TRAFFIC REPORTS

2.1 Original Sample Traffic Report page marked "Lab Copy for Return to SMO"with lab receipt information and signed in original Contractorsignature, for each sample in the Sample Delivery Group.

2.2 Traffic Reports (TRs) shall be submitted in Sample Delivery Group (SDG)sets (i.e., TRs for all samples in an SDG shall be clipped together),with an SDG Cover Sheet attached.

2.3 The SDG Cover Sheet shall contain the following items:

o Lab nameo Contract numbero Sample analysis price - full sample price from contract.o Case numbero List of EPA Sample Numbers of all samples in the SDG,

identifying the first and last samples received, and their datesof receipt (LRDs).

2.4 When more than one sample is received in the first or last SDGshipment, the "first" sample received would be the lowest sample number(considering both alpha and numeric designations); the "last" samplereceived would be the highest sample number (considering both alpha andnumeric designations).

2.5 The EPA Sample Number of the first sample received in the SDG is theSDG number. Each Traffic Report must be clearly marked with the SDGNumber. This information should be entered below the Lab Receipt Dateon the TR. The TR for the last sample received in the last SDGshipment must be clearly marked "SDG - FINAL SAMPLE."

2.6 If samples are received at the laboratory with multi-sample Traffic 'Reports (TRs), all the samples on one multi-sample TR may-notnecessarily be in the same SDG. In this instance, the laboratory mustmake the appropriate number of photocopies of the TR, and submit onecopy with each SDG cover sheet.

3. SAMPLE DATA SUMMARY PACKAGE

3.1 As specified in the Delivery Schedule, one Sample Data Summary Packageshall be delivered to SMO concurrently with delivery of other requiredsample data. The Sample Data Summary Package shall be submittedseparately (i.e., separated by rubber bands, clips or other means)directly preceding the Sample Data Package.

3.2 The Sample Data Summary Package consists of specified items from theSample Data Package in the following order:

B-7 6/91""•*«** 6R302683

o SDG Narrativeo Organics Analysis Data Sheet for target compound results (Form

I) and for tentatively identified compounds (Form I, TIC) byfraction (VOA, SV, PEST) and by sample within each fraction.(No Form I, TIC for PEST fraction.)

o Surrogate Recovery (Form II) by fraction (VOA, SV, PEST)o Laboratory Control Sample Recovery (Form III) by fraction (VOA,

SV, PEST)o Method Blank Summary (Form IV), Organics Analysis Data Sheet for

target compound results (Form I) and for tentatively identifiedcompounds (Form I, TIC) by fraction (VOA, SV).

. o Peak Area and Retention Time Summary of Internal Standards forinitial calibration standards (Form VIII) and samples (FormVIII) by fraction (VOA, SV only).

3.3 Sample data forms shall be arranged in increasing EPA Sample Numberorder.

4. SAMPLE DATA PACKAGE .

4.1 The Sample Data Package shall include data for analyses of all samplesin each Sample Delivery Group, specifically including field samples,reanalyses, dilutions, blanks, Laboratory Control Samples, andPerformance Evaluation Samples. The Sample Data Package is dividedinto the five major units as follows:

o SDG Narrativeo Sample Traffic Reportso Volatiles Datao Semivolatiles Datao Pesticides/Aroclors Data

4.2 The Volatiles, Semivolatiles, and Pesticides/Aroclors data are eachspecific to an analytical fraction. If the analysis of that fractionis not required, then that fraction-specific unit is not a requireddeliverable.

The Contractor shall retain a copy of the sample data package for 365days after final acceptance of data. After this time, the Contractormay dispose of the package.

4.3. SDG Narrative

4.3.1 This document shall be clearly labeled "SDG Narrative". TheSDG Narrative shall contain: laboratory name; Case number; EPASample Numbers in the Sample Delivery Group (SDG),differentiating between initial analyses, dilutions andreanalysis; SDG number; Contract number; and detaileddocumentation of any quality control sample, shipment and/or

B-8 - 6/91AR30268U

analytical problems encountered in processing the samplesreported in the data package. >

4.3.2 Whenever data from sample reanalyses are'submitted, theContractor shall state in the SDG Narrative for eachreanalysis, whether it considers the reanalysis to be billable,and if so, why. A copy of the narrative should be sent to SMOfor their review. The Contractor must also include anyproblems encountered; both technical and administrative, thecorrective actions taken, and resolution.

4.3.3 The Contractor must also list the pH determined for each watersample submitted for volatiles analysis. This information mayappear as a simple list or table in the SDG Narrative. Thepurpose of this pH determination is to ensure that allvolatiles samples were acidified in the field. No pHadjustment is to be performed by the Contractor on watersamples for volatiles analysis.

4.3.4 The SDG Narrative shall contain the following statementverbatim: "I certify that this data package is in compliancewith the terms and conditions of the contract, both technicallyand for completeness, for other than the conditions detailed'above. Release of the data contained in this data package andin the computer-readable data submitted on diskette has beenauthorized by the Laboratory Manager or his designee, asverified by the following signature." This statement shall bedirectly followed by signature of the Laboratory Manager or hisdesignee with a typed line below it containing the signer'sname and title, and the date of signature.

4/3.5 In the event that the Laboratory Manager cannot verify all datareported for each sample, the Laboratory Manager shall providea detailed description of the problems associated with thesamples in the SDG Narrative.

4.3.6 The SDG Narrative itself must be signed with original signatureby the Laboratory Manager or his designee and dated.

4.4 Sample Traffic Reports

Copies of the Sample Traffic Reports for all of the samples in the SDGare also included in the Sample Data Summary Package. The TrafficReports shall be arranged in increasing EPA Sample Number order,considering both letters and numbers in ordering samples. Copies ofthe SDG cover sheet are to be included with the copies of the TrafficReports.

If samples are received at the laboratory with multi-sample TrafficReports (TRs), not all samples on one multi-sample TR are necessarilyin the same SDG. In this instance, the laboratory must make theappropriate number of photocopies of the TR so that a copy is submittedwith each data package to which it applies. In addition, in anyinstance where samples from more than one multi-sample TR are in the

B-9 ' 6/91

SR302685

same data package, the laboratory must submit a copy of the SDG coversheet with copies of the TRs.

4.5 Volatiles Datai

4.5.1 Volatiles QC Summary

If more than a single form is necessary, each type of form mustbe arranged in chronological order by instrument.

i

o Surrogate Recovery (Form II LCV)o Laboratory Control Sample Recovery (Form III LCV)o Method Blank Summary (Form IV LCV)

b GC/MS Tuning and Mass Calibration - BFB (Form V LCV)o Internal Standard Area and Retention Tine Summary (Form

VIII LCV)

4.5.2 Volatiles Sample Data

Sample data, including FES, shall be arranged in packets withboth of the Organic Analysis Data Sheets (Form I LCV and Form ILCV-TIC), followed by the raw data for volatile samples. Thesesample packets should then be placed in increasing EPA SampleNumber order.

4.5.2.1 Organics Analysis Data Sheet for target compoundresults (Form I LCV).

4.5.2.2 Organics Analysis Data Sheet for tentativelyidentified compounds (Form I LCV-TIC). This formmust be included even if no TIC's are found.

4.5.2.3 Reconstructed total ion chromatograms (RIG)

The RIC for each sample, extract, standard, andblank must be normalized to the largest nonsolventcomponent, and must contain the following headerinformation:

o EPA Sample Number

o Date and time of analysis

o GC/MS instrument ID

o Lab file ID

Internal standard and surrogate spiking compoundsare to be labeled with the names of the compounds,either directly out from the peak, or on a print-outof retention times if retention times are printedover the peak.

B-10 6/91AR302686

4.5.2.4 Quantitation Report

If automated data systems are used for quantitationof the target compounds, the complete data systemquantitation report must be included in all sampledata packages, in addition to the reconstructed ionchromatogram. The complete data system quantitationreport shall include all of the information listedbelow. For laboratories which do not use theautomated data system procedures, a laboratory "rawdata sheet" quantitation report containing thefollowing information must be included in the sampledata package in addition to the chromatogram.

o EPA Sample Number


o RT or scan number of identified targetcompounds

o Ion used for quantitation with measuredarea

o Copy of area table from data system


o Lab file ID

In all instances where the data system report hasbeen edited, or where manual Integration orquantitation has been performed, the GC/MS operatormust identify such edits or manual procedures byinitialing and dating the changes made to the reportand include the scan range integration.

4.5.2.5 Target Compound Mass Spectra

For each sample, by each compound identified, copiesof raw spectra and copies of background-subtractedmass spectra of target compounds that are identifiedin the sample and corresponding background-subtracted target compound standard mass spectra arerequired. The raw spectra and the background-subtracted spectra must be labeled with EPA SampleNumber, lab file ID, date and time of analysis, andGC/MS instrument ID. Compound names must be clearlymarked on all spectra.

4.5.2.6 Tentatively Identified Compound Mass Spectra and„ Library Matches ^B^

B-ll 6/91AR3Q2687

For each sample, by each compound identified, copiesof mass spectra of non-target and non-surrogateorganic compounds (Tentatively Identified Compounds)with the associated spectra of the three bestlibrary matches are labeled with EPA Sample Number,lab file ID, date and time of analysis, and GC/MSinstrument ID.

4.5.3 Volatiles Standards Data

4.5.3.1 Initial Calibration

All initial calibration data must be included forall analyses associated with the SDG. When morethan one initial calibration is 'performed, thereconstructed ion chromatograms and quantitationreports and each type of form must be put inchronological order, by instrument.

Initial Calibration Summary (Form VI LCV).

Internal Standard Area and Retention Time Summary(Form VIII LCV)

Volatile standard(s) reconstructed ion chromatogramsand quantitation reports for the initial (fivepoint) calibration are labeled as in Paragraphs4.5.2.3 and 4.5.2.4. Spectra are not required.

4.5.3.2 Continuing Calibration

When more than one continuing calibration isperformed, the reconstructed ion chromatogram andquantitation reports and each type of form must bein chronological order, and by instrument if morethan one instrument is used.

Continuing Calibration Summary (Form VII LCV)

Internal Standard Area and Retention Time Summary(Form VIII LCV)

VOA standard(s) reconstructed ion chromatograms andquantitation reports for all continuing (12 hour)calibrations are labeled as in Paragraph 4.5.2.3 and4.5.2.4. Spectra are not required.

B'12 6/91

4.5.4 Volatiles QC Data

4.5.4.1 GC/MS Tuning Data

GC/MS Tuning - BFB data, for each 12-hour period,shall be arranged in chronological order byinstrument for each GC/MS system utilized.

GC/MS Tuning and Mass Calibration - BFB (Form V LCV)i "

Bar graph spectrum, labeled as in Paragraph 4.5.2.3.

Mass listing, labeled as in Paragraph 4.5.2.3.

4.5.4.2 Blank Data

Blank data shall be arranged in chronological orderby instrument. NOTE: This order is different fromthat used for samples.

Blank data shall be arranged in packets with both ofthe Organic Analysis Data Sheets (Form I LCV andForm I LCV-TIC), followed by the raw data forvolatile samples (see paragraphs 4.5.2.1 to4.5.2.6).

4.5.4.3 Laboratory Control Sample Data

Organics Analysis Data Sheet for target compoundresults (Form I LCV). Form I LCV-TIC is notrequired.

Reconstructed ion chromatogram(s) and quantitationreport(s), labeled as in Paragraph 4.5.2.3 and4.5.2.4. Spectra are not required.

4.6 Semivolatiles Data

4.6.1 Semivolatiles QC Summary

If more than a single form is necessary, each type of form mustbe arranged in chronological order, by instrument.

o Surrogate Recovery (Form II LCSV)o Laboratory Control Sample Recovery (Form III

LCSV)o Method Blank Summary (Form IV LCSV)o GC/MS Tuning and Mass Calibration - DFTPP (Form

V LCSV)

% o Internal Standard Area and Retention TimeSummary (Form VIII LCSV-1, LCSV-2)

B"13 n r Q Q 6/91&R3U2689

4.6.2 Semivolatiles Sample Data

Sample data, including PES, shall be arranged in packets withboth of the Organic Analysis Data Sheets (Form I LCSV and FormI LCSV-TIC), followed by the raw data for sem.ivolatile samples.These sample packets should then be placed in increasing EFASample Number order.

4.6.2.1 Organic Analysis Data Sheet for target compoundresults (Form I LCSV-1, LCSV-2).

4.6.2.2 Tentatively Identified Compounds (Form I LCSV-TIC).This form must be included even if no TICs arefound.

4.6.2.3 Reconstructed total ion chromatograms (RICs)

The RIG for each sample, extract, standard, andblank must be normalized to the largest nonsolventcomponent, and must contain the following headerinformation:

o EPA Sample Number



o Lab file ID

Internal standard and surrogate spiking compoundsare to be labeled with the names of the compounds,either directly out from the peak, or on a print-outof retention times if retention times are printedover the peak. .

4.6.2.4 Quantitation Reports

If automated data system procedures are used forpreliminary identification and/or quantitation ofthe target compounds, the complete data systemquantitation report must be included in all sampledata packages, in addition to the reconstructed ionchromatogram. The complete data system quantitationreport shall include all of the information listedbelow. For laboratories which do not use theautomated data system procedures, a laboratory "rawdata sheet" quantitation report containing thefollowing information must be included in the sampledata package in addition to the chromatogram.

o EPA Sample Number

o Date and tine of analysis

B-14 ' 6/913R30269Q

o RT or scan number of identified targetcompounds

o Ion used for quantitation with measuredarea

o Copy of peak area table from data system


o Lab file ID

In all instances where the data system report hasbeen edited, or where manual integration orquantitation has been performed,- the GC/MS operator•ust identity such edits or manual procedures byinitialing and dating the changes made to the reportand include the scan range integration.

4.6.2.5 Target Compound Mass Spectra

For each sample, by each compound identified, copiesof raw spectra and copies of background-subtractedmass spectra of target compounds that are identifiedin the sample and corresponding background-subtracted target compound standard mass spectra arerequired. The raw spectra and the background-subtracted mass spectra must be labeled with EPASample Number, lab file ID, date and time ofanalysis, and GC/MS instrument ID. Compound namesmust be clearly marked on all spectra.

4.6.2.6 Tentatively Identified Compound Mass Spectra andLibrary Matches

For each sample, by each compound identified, copiesof mass spectra of non-target and non-surrogateorganic compounds (Tentatively Identified Compounds)with the associated spectra of the three bestlibrary matches are labeled with EPA Sample Number,lab file ID, date and time of analysis, and GC/MSinstrument ID.

4.6.3. Semivolatiles Standards Data


Data must be included for all calibration analysespertaining to the SDG. When more than one initialcalibration is performed, the reconstructed ionchromatogram and quantitation reports and each type

% of form must be put in chronological order, byins trument .

6/91

Initial Calibration Data (Form VI LCSV-1, LCSV-2).j

Internal Standard Area and RT Summary (Form VIIILCSV-1, LCSV-2)

Semivolatile standard(s) reconstructed ionchromatograms and quantitation reports for theinitial (five point) calibration are labeled as inParagraphs 4.6.2.3 and 4.6.2.4. Spectra are notrequired.

4.6.3.2 Continuing Calibration

When more than one continuing calibration isperformed, the reconstructed ion chromatogram andquantitation reports and each type of form must bein chronological order, by instrument.

Continuing Calibration Summary(Form VII LCSV-1,LCSV-2).

Internal Standard Area and Retention Time Summary(Form VIII LCSV-1, LCSV-2).

Semivolatile standard(s) reconstructed ionchromatograms and quantitation reports for allcontinuing (12 hour) calibrations are labeled as inParagraphs 4.6.2.3 and 4.6.2.4. Spectra are notrequired.

4.6.4. Semivolatiles QC Data

4.6.4.1 GC/MS Tuning Data

GC/MS Tuning-DFTPP data, for each 12-hour periodshall be arranged in chronological order byinstrument, for each GC/MS system utilized.

'GC/MS Tuning and Mass Calibration-BFB (Form V LCSV)

Bar graph spectrum, labeled as in Paragraph 4.6.2.3.

Mass listing, labeled as in Paragraph 4.6.2.3.

4.6.4.2 Blank Data

Blank data shall be arranged in chronological orderby instrument. NOTE: This order is different fromthat used for samples.

Blank data shall be arranged in packets with both ofthe Organic Analysis Data Sheets (Form I LCSV andForm I LCSV-TIC), followed by the raw data for

8-16 flR302692

Semivolatile samples (see paragraphs 4.6.2.1 to4.6.2.6)

4.6.4.3 Laboratory Control Sample Data

Organic Analysis Data Sheet for target compounds(Form I LCSV-1, LCSV-2). Form I LCSV-TIC is ns£required.

Reconstructed ion chromatogram(s) and quantitationreport(s), are labeled as in Paragraphs 4.6.2.3 and4.6.2.4. Spectra are not required.

4.7 Pesticide/Aroclor Data

4.7.1 Pesticide/Aroclor QC Summary

If more than a single form is necessary, forms must be arrangedin chronological order by instrument.

o Surrogate Percent Recovery Summary (Form II LCP)

o Laboratory Control Sample Recovery (Form III LCP)

o Method Blank Summary (Form IV LCP). If more than a single method blank summary form isnecessary, forms must be arranged in chronological orderby type (method or sulfur blank) by instrument, and bydate of analyses.

4.7.2 Pesticide/Aroclor Sample Data

Sample data, including FES, shall be arranged in packets withthe Organic Analysis Data Sheet (Form I LCP), followed by theraw data for pesticide samples. These sample packets shouldthen be placed in increasing EPA Sample Number order.

4.7.2.1 Organic Analysis Data Sheet for target compounds(Form I LCP).

4.7.2.2 Pesticide Identification Summary for SingleComponent Analytes (Form X LCP-1), only required forpositively identified analytes.

4.7.2.3 Pesticide Identification Summary for MulticomponentAnalytes (Form X LCP-2), only required forpositively identified analytes.

4.7.2.4 Pesticide chromatograms

All chromatograms must be labeled with the following» information:

HR302693

*

o EFA Sample Number

o Volume injected (ul)

o Date and time of analyses

o GC column identification (by stationaryphase and internal diameter)

o GC instrument identification

o Scaling Factor

o Positively identified compounds must belabeled with the names of compounds,either directly out from the peak, oron a print-out of retention times ifretention times are printed over thepeak.

4.7.2.5 Copies of pesticide chromatograms from second GCcolumn, labeled as in Paragraph 4.7.2.4.

4.7.2.6 Data System Printouts

Data system printouts of retention time andcorresponding peak areas or height must accompanyeach chromatogram are labeled with the followinginformation:

i

o EPA Sample Number

o Volume injected (ul)

o Date and time of analyses

o GC column identification (by stationaryphase and internal diameter)

o GC instrument identification

o Scaling Factor

o Positively identified compounds must belabeled with the names of compounds,either directly out from the peak, or 'on a print-out of retention times ifretention times are printed over thepeak.

In all instances where the data system report has» been edited, or where manual integration or

quantitation has been performed, the GC/EC operatormust identify such edits or manual procedures by

B-18 6/91

Initialing and dating the changes made to the reportand include the integration lime range. ,

4.7.2.7 Manual work sheets.

4.7.3 Pesticide/Aroclor Standards Data


Data must be included for all calibration analysespertaining to the SDG. When more than one initialcalibration is performed, the data and each type ofform must be put in chronological order, byinstrument and GC column.

Initial Calibration for Single Component Analytes(Form VI LCP-1, LCP-2).

Initial Calibration for Multicomponent Analytes(Form VI LCP-3).

Resolution Check Summary (Form VI LCP-4).

Analytical Sequence (Form VIII LCP), containinginitial calibration standards.

4.7.3.2 Calibration Verification

Calibration Verification Summary (Form VII LCP) forall GC columns.

When more than one calibration verification isperformed, forms must be in chronological order, byinstrument and GC column.

4.7.3.3 Chromatograms and data system printouts are requiredfor all. standards and arranged in chronologicalorder by instrument and each GC column:

o Resolution Check Mixture.

o Performance Evaluation Mixtures, each initialcalibration and all those that bracket samplesin the SDG.

o Individual Standard Mixture A, at threeconcentrations, each initial calibration,plus all those that bracket samples inthe SDG.

o Individual Standard Mixture B, at threeconcentrations, each initial calibration,

* plus all those that bracket samples inthe SDG.

B-19 ' 6/91

&R3G2695'

9o All multicomponent analytes (Toxaphene

and Aroclors), each initialcalibration.

o All multicomponent analyte standardsanalyzed'for confirmation.

4.7.3.4 Data system printouts of retention times andcorresponding peak areas or peak heights mustaccompany each chromatogram. In addition, allchromatograms and data system printouts are requiredto be labeled with the following:

o EPA Sample Number for the standard,i.e., INDA1, INDA2, etc. (See FormsInstructions for details).

o Label all standard peaks for allindividual compounds either directlyout from the peak or on the printout ofretention times if retention times areprinted over the peak.

o Total nanograms injected for eachstandard.

o Date and time of injection.

o GC column identification (by stationaryphase and internal diameter).

i

o GC instrument identification.

o Scaling factor

In all instances where the data-system report hasbeen edited, or where manual integration orquantitation has been performed, the GC/EC operatorvust identity such edits or manual procedures byinitialing and dating the changes made to the reportand include the integration time range.

4.7.4 Pesticide/Aroclor QC Data

4.7.4.1 Blank Data

Blank data instrument - grouped by type of blank(i.e., method and sulfur) and arranged inchronological order. NOTE: This order is differentfrom that used for samples.

Organics Analysis Data Sheet for target compounds(Form I LCP).

B-20 6/91

AR302696

Blank data shall be arranged, in packets with theOrganics Analysis Data Sheet (Form I LCP) followedby the raw data (paragraph 4.7.2.2, to 4.7.2.7).

4.7.4.2 Laboratory Control Sample

Organics Analysis Data Sheet for target compounds(Form I LCP).

Chromatograms and data system printouts are labeledas in Paragraph 4.7.2.4 and 4.7.2.6.

4.7.4.3 Florisil Cartridge Check

Florisil Cartridge Check (Form IX LCP) , for all lotsof cartridges used to process samples in the SDG.

Each Fora IX LCP shall be followed by thechromatograms and data system printouts , labeled asin 4.7.2.4 and 4.7.2.6.

5. COMPLETE ?r*9 FIT-g

As specified in the Delivery Schedule, one Complete SDG File (CSF)including the original sample data package shall be delivered to theRegion concurrently with delivery of copies of the Sample Data Packageto SMO and EMSL/LV. The contents of the CSF will be numbered accordingto the method described in Section III of Exhibit B. The DocumentInventory Sheet, Form DC-2, is contained in Section IV. The CSF willcontain all original documents where possible. No copies will beplaced in the CSF unless the originals are bound in a logbook which ismaintained by the laboratory. The CSF will contain all originaldocuments specified in Section III, and Form DC-2 of Exhibit B.

The CSF will consist of the following original, documents in the orderlisted in paragraph 5.1 through 5.6 below:

5.1 The original sample data package (see Exhibit B, Section 4).

5.2 A completed and signed Document Inventory Sheet (Form DC-2).

5.3 All original shipping documents, including, but not limited to, thefollowing documents:

. o EPA Chain of Custody Recordi

o Airbillso EPA Traffic Reports.o Sample Tags (if present) sealed in plastic bags.

5.4 All original receiving documents, including, but not limited to, thefollowing documents:

o Form DC-1

B-21 6/91AR302697

o ' Other receiving forms or copies of receiving logbooks

o SDG Cover Sheet5.5 All original laboratory records, not already submitted in the Sample

Data Package, of sample transfer, preparation and analysis, including,but not limited to, the following documents:

o Original preparation and analysis forms or copies of preparationand analysis logbook pages.

o Internal sample and sample extract transfer chain-of-custodyrecords.

o Screening records.o • A1.1 instrument output, including strip charts from screening

activities.5.6 All other original SDG-related documents in the possession of the

laboratory, including, but not limited to, the following documents:

o Telephone contact logso Copies of personal logbook pageso All hand written SDG-specific noteso Any other SDG specific documents not covered by the above.

NOTE: All SDG-related documentation may be used or admitted asevidence in subsequent legal proceedings. Any other SDG-specificdocuments generated after the CSF is sent to EPA, as well as copiesthat are altered in any fashion, are also deliverables to EPA.(Original to the Region and copies to SMO and EMSL/LV).

If the laboratory does submit SDG-specific documents to EPA aftersubmission of the CSF, the documents shall be numbered as an addendumto the CSF and a revised DC-2 form shall be submitted, or the documentsshould be numbered as a new CSF and a new DC-2 form should besubmitted. The revised DC-2 form is sent to the Region only.

6. DATA IN COMPUTER-READABLE FORM

The Contractor shall provide a computer-readable copy of the data ondata reporting Forms I-X for all samples in the Sample Delivery Group,as specified in the Contract Performance/Delivery Schedule.Computer-readable data deliverables shall be submitted on IBM orIBM-compatible, 5.25 inch double-sided, double density 360 K-byte or ahigh density 1.2 M-byte diskette or 3.5 inch double-sided doubledensity 720 K-byte or 1.44 M-byte diskette.

When submitted, diskettes shall be packaged and shipped in such amanner that the diskette(s) cannot be bent or folded, and will not beexposed to extreme heat or cold or any type of electromagneticradiation. The diskette (s)'must be included in the same shipment asthe hardcopy data and shall, at a minimum, be enclosed in a diskettemailer. The data shall be recorded in ASCII text file format, andshall adhere to the file, record and field specifications listed in

B'22 flDOno,-^ 6/91

Exhibit H, Data Dictionary and Format for Data Deliverables inComputer-Readable Format.

7. GC/MS TAPES

See Exhibit E for requirements.

8. EXTRACTS

The Contractor shall store sample extracts.at 4*C (±2*C) inbottles/vials with Teflon-lined septa. Extract bottles/vials shall belabeled with EPA Sample Number, Case number and Sample Delivery Group(SDG) number. A logbook of stored extracts shall be maintained,listing EPA Sample Numbers and associated Case and SDG numbers.

The Contractor is required to retain extracts for 365 days followingdata submission. During that time, the Contractor shall submitextracts and associated logbook pages within seven days followingreceipt of a written request from the Sample Management Office.

B-23 6/91

RR302699

SECTION III

FORM INSTRUCTION GUIDE

This section includes specific instructions for the completion of allrequired forms. Each of the forms is specific to a given fraction (volatile,Semivolatile, pesticide/Aroclor). The Contractor shall submit only thoseforms pertaining to the fractions analyzed for a given sample or samples.For instance, if a sample is scheduled for volatile analysis only, submitonly VOA forms. There are, two pages relating to the Semivolatile fractionfor Forms I, VI, VII, and VIII and four pages relating to thepesticide/Aroclor fraction for Form VI. Whenever Semivolatiles orpesticides/Aroclors are analyzed and one of the above named forms isrequired, all pages (LCSV-1, LCSV-2, etc.) must be submitted. Theseinstructions are arranged in the following order:

1. General Information and Header Information

2. Organic Analysis Data Sheet (Form I, All Fractions)

3. Surrogate Recovery (Form II, All Fractions)

4. Laboratory Control Sample Recovery (Form III, All Fractions)

5. Method Blank Summary (Form IV, All Fractions)

6. GC/MS Tuning and Mass Calibration (Form V LCV, LCSV)

7. Initial Calibration Summary (Form VI, All Fractions)

8. Pesticide Resolution Check Summary (Form VI LCP-4)

9. Continuing Calibration Summary (Form VII LCV, LCSV)

10. Calibration Verification Summary (Form VII LCP)

11. Internal Standard Area and Retention Time Summary (Form VIII LCV,LCSV)

12. Pesticide/Aroclor Analytical Sequence (Form VIII LCP)

13. Pesticide/Aroclor Florisil Cartridge Check (Form IX LCP)

14. Pesticide/Aroclor Identification (Form X LCP)

15. Sample Log-In Sheet (Form DC-1)

16. Document Inventory Sheet (Form DC-2)

B-24 6/91AR3Q27QO

1. GENERAL INFORMATION AND HEADER INFORMATION

1.1 The data reporting forms presented in Section IV have been designed inconjunction with the computer-readable data format specified in ExhibitH, Data Dictionary and Format for Data Deliverables inComputer-Readable Format. The specific length of each variable forcomputer-readable data transmission purposes is given in the datadictionary (Exhibit H). Information entered on these forms must notexceed the size of the field given on the form, including suchlaboratory-generated items as Lab Name and Lab Sample ID.

1.2 Note that on the hardcopy forms (Section IV), the space provided forentries is greater in some instances than the length prescribed for thevariable as written to diskette (see Exhibit H). Greater space isprovided on the hardcopy forms for visual clarity. •

1.3 Values must be reported on the hardcopy forms according to theindividual form instructions in this Section. For example, results forconcentrations of VOA target compounds must be reported to two •significant figures if the value is greater than or equal to 10.Values can be written to the diskette file in any format that does notexceed the field specification as given in the record specificationsand discussed in "Record Structure", in Exhibit H.

1.4 For rounding off numbers to the appropriate level of precision, observethe following common rules. If the figure following those to beretained is less than 5, drop it (round down). If the figure isgreater than 5, drop it and increase the last digit to be retained by 1(round up). If the figure following the last digit to be retainedequals exactly 5, round up if the digit to be retained is odd, andround down if that digit is even.

1.5 All characters which appear on the data reporting forms presented inthe contract (Exhibit B, Section IV) must be reproduced by theContractor when submitting data, and the format of the forms submittedmust be identical to that shown in this Superfund Analytical Method.No information may be added, deleted, or moved from its specifiedposition without prior written approval by SMO. The names of thevarious fields and compounds (i.e., "Lab Code", "Chloromethane") on theuncompleted forms must appear as they do in the this SuperfundAnalytical Method (Section IV of this exhibit), except that the use ofuppercase and lowercase letters is optional.

1.6 Alphabetic entries made onto the forms by the Contractor shall be inALL. UPPERCASE letters. If an entry does not fill the entire blankspace provided on the form, null characters shall be used to remove theremaining underscores that comprise the blank line. (See Exhibit H formore detailed instructions.) However, do not remove the underscores orvertical bar characters that delineate "boxes" on the forms. The onlyexception would be those underscores at the bottom of a "box" that areintended as a data entry line (for instance, see Form II LCV, line 30.If data must be entered on line 30, it will replace the underscores).

B-25 6/91

AR3G27Q!

1.7 Forms II, IV, V, VIII, IX, and X contain a field labeled "page _ of _"in the bottom left-hand corner. If the number of entries required onany of these forms exceeds the available space, continue entries onanother copy of the same fraction-specific form, duplicating all headerinformation. If a second page is required, number them consecutively,as "page 1 of 2" and "page 2 of 2". If a second page is not required,number the page "page 1 of 1." NOTE: These forms arefraction-specific. For example, Form II LCV, Form II LCSV, and Form IILCP are for different data. Therefore, do not number the pages of allthree versions of Form II as "1 of 3, 2 of 3, etc." Only number pageswj-thin a fraction-specific form.

1.8 Six pieces of information are common to the header sections of eachdata reporting form. They are: Lab Name, Contract, Lab Code, Case No.,SAS No., and SDG No. This information, if it applies, must be enteredon every form and must match on every form.

1.8.1 The "Lab Name" shall be the name chosen by the Contractor toidentify the laboratory. It may not exceed 25 characters.

1.8.2 The "Lab Code" is an alphabetical abbreviation of up to 6letters, assigned by SMO, to identify the laboratory and aid in

. data processing. This lab code shall be assigned at the time acontract is awarded, and shall not be modified by theContractor, except at the direction of SMO. If a change ofname or ownership occurs at the laboratory, the lab code willremain the same until the Contractor is directed by SMO to useanother lab code assigned by SMO.

1.8.3 The "Case No." is the assigned Case Number (up to 5 digits)associated with the sample, and reported on the Traffic Report.

1.8.4 The "Contract" is the number of the SMO contract under whichthe analyses were performed.

1.8.5 When more than one sample is received in the first or last SDGshipment, the "first" sample received would be the lowestsample number (considering both alpha and numericdesignations); the "last" sample received would be the highestsample number (considering both alpha and numeric "••designations).

1.8.6 The "SAS No." is the EPA-assigned number for analyses performedunder Special Analytical Services. If samples are to beanalyzed under SAS only, and reported on these forms, thenenter SAS No., and leave Case No. blank. If samples areanalyzed according to the "Routine Analytical Services" (IFB)protocols and have additional "SAS" requirements, list bothCase No. and SAS No. on all forms. If the analyses have no SASrequirements, leave "SAS No." blank. NOTE: Some samples in anSDG may have a SAS No. while others do not.

B-26 6/91

AR302702'

1.9 EPA Sample Number

1.9.1 EPA Sample Number must be entered on several of the forms.This field appears either in the upper right-hand corner of theform, or as the left column of a table, summarizing data from anumber of samples. When "EPA Sample No." is entered into thetriple-spaced box in the upper right-hand corner of the form,it should be entered on the middle line of the three lines thatcomprise the box.

1.9.2 All samples, including Laboratory Control Samples andPerformance Evaluation Samples, blanks, and standards shall beidentified with an EPA Sample Number.

1.9.3 For samples, the EPA Sample Number is the unique identifyingnumber given in the Traffic Report that accompanied thatsample. In order to facilitate data assessment; the followingidentification scheme must be used for samples:

XXXXX - EFA Sample Number assignedXXXXXRE - re-analyzed sampleXXXXXDL - sample analyzed at a dilutionXXXXXDL2 - sample analyzed at a secondary dilution (for PEST

only)

1.9.4 The EPA Sample Number must be unique for each LaboratoryControl Sample within an SDG. The EFA Sample Number for aLaboratory Control Sample must be FLCS##, where:

F - fraction (V for volatiles; S for Semivolatiles; P forpesticides/Aroclors).

LCS - indicates a Laboratory Control Sample.

#* - suffix consisting of characters or numbers or both thatmakes the EPA Sample Number for the LCS unique in the SDG.

1.9.5 The EPA Sample Number gust be unique for each blank within anSDG. Within a fraction, a laboratory must replace the "##"terminator of the identifier with one or two characters ornumbers, or a combination of both. For example, possibleidentifiers for volatile blanks would be VBLK1, VBLK2, VBLKAl,VBLKB2, VBLK10, VBLKAB, etc.

Volatile method blanks shall be identified as VBLK#*.

Volatile storage blank shall be identified in VSBLK##.

Volatile instrument blank shall be identified as VIBLK##.

Semivolatile method blanks shall be identified as SBLK##.

Pesticide/Aroclor method blanks shall be identified as PBLK##.

B-27 6/91AR3027Q3

Pesticide/Aroclor instrument blanks shall be identified asPIBLK##.

If a separate sulfur cleanup blank is required (e.g., when notall Pesticide/Aroclor samples associated with a given methodblank are subjected to sulfur cleanup) the Pesticide/Aroclorsulfur cleanup blanks shall be identified as PCBLKft*.

1.9.6 The EPA Sample Number must be unique for each standard withinan SDG.

. The EPA Sample Numbers for volatile and Semivolatile standardsmust be FSTD###, where:

F - fraction (V for volatiles; S for Semivolatiles).' *

STD - indicates a standard.

### - the concentration in ug/L of volatile standards (i.e.,001, 002, 005, 010) or the amount injected in ng forSemivolatile standards (i.e., 005, 010, 020, 050, and 080).These designations will have to be concatenated with otherinformation to uniquely identify each standard in the SDG.

For pesticide/Aroclor standards, the following scheme shall beused to enter EPA Sample Number.

Name EPA Sample Number

Individual Mix A (low point) INDAL##Individual Mix A (mid point) INDAM##Individual Mix A (high point) INDAH##Individual Mix B (low point) INDBL##Individual Mix B (mid point) INDBM##Individual Mix B (high point) INDBH##Resolution Check RESC##Performance Evaluation Mixture PEM##Toxaphene TOXAPH##Aroclor 1016 AR1016##Aroclor. 1221 AR1221##Aroclor 1232 AR1232##Aroclor 1242 AR1242##Aroclor 1248 AR1248##Aroclor 1254 AR1254##Aroclor 1260 AR1260##Aroclor 1016/1260 AR1660##

The laboratory must create a unique "EPA Sample No." within anSDG by replacing the two-character "##" terminator of theidentifier with one or two characters or numbers , or acombination of both.

«If the standards are injected onto both GC columns on the sameinstrument simultaneously, the same EPA Sample Number may be

B-28 : 6/91

..'AR30270I+

used for reporting data for the standards for both columns. Ifi simultaneous injections are not made, then the same number maynot be used.

1.10 Several other pieces of information are common to the headerinformation on some of the data reporting forms. These include: LabSample ID, Lab File ID, Purge or Sample Volume, GC Column - ID,Instrument ID, Time Analyzed, Date Received, Extracted, and DateAnalyzed.

1.10.1 "Lab Sample ID" is an optional laboratory-generated internalidentifier. Up to 12 alpha-numeric characters may be reportedhere.

i

1.10.2 "Lab File ID" is the laboratory-generated name of the GC/MSdata system file containing information pertaining to aparticular analysis. Up to 14 alpha-numeric characters may beused here.

1.10.3 "Purge Volume" or "Sample Volume" is the total volume of waterthat was purged or extracted, in milliliters.

1.10.4 There are two fields to be entered under "GC Column - ID".Enter the stationary phase of the GC column after "GC Column1'and enter the internal diameter in millimeters after "ID".

1.10.5 "Instrument ID" is the identifier that distinguishes eachinstrument used for analysis in the SDG.

1.10.6 The "Time Analyzed" shall be in military time.

1'. 10.7 "Date Received" is the date of sample receipt at thelaboratory, as noted on the Sample Traffic Report (i.e., theValidated Time of Sample Receipt). "Date Received" is enteredas MM/DD/YY.

1.10.8 Enter the date on which the extraction procedure was gtartedfor "Date Extracted". "Date Extracted" is entered as MM/DD/YY.

1.10.9 For each fraction, the "Date Analyzed" is the date of thesample analysis. The date of sample receipt will be comparedwith the extraction and analysis dates of each fraction toensure that contract holding times were not exceeded. "DateAnalyzed" is entered as MM/DD/YY.

1.11 For pesticide/Aroclors, analyses on two GC columns are required. The, information on the two analyses is differentiated on some of the forms

as "Date Analyzed (1)", "Date Analyzed (2)", etc. The order ofreporting is not important, but must be consistent with the informationreported on Form X. When simultaneous injection is made on both GCcolumns, the dates (and times) will be the same. If simultaneousinjections are sa£ made, the (1) shall refer to the first analysis, and(2) the second. If only one analysis is required, leave blank thefields for the second analysis.

B-29 6/91

AR3G2705

2. ORGANIC ANALYSIS DATA SHEET (FORM I)

2.1 Target Compounds. Form I LCV, LCSV-1, LCSV-2, and LCP

This form is used for reporting the detected concentrations of thetarget compounds in the samples, Laboratory Control Samples,Performance Evaluation Samples, and all blanks analyzed, includingmethod blanks, instrument blanks, sulfur cleanup blanks, and storageblanks.

Complete the header information on each Form I required, according tothe instructions in paragraph 1.

Enter 1 for the "Dilution Factor", if a sample was not diluted orconcentrated for analysis. If a sample has been diluted for analysis,enter the "Dilution Factor" as a single number, such as 100 when asample is diluted by a factor of 100. Enter 0.1 when a sample isconcentrated by a factor of 10.

For volatiles, the "Purge Volume" is the total volume (in mL) purgedfor the analysis.

For Semivolatiles and pesticides, enter the "Concentrated ExtractVolume" and the "Injection Volume" in microliters. The "ConcentratedExtract Volume" is the actual volume of the most concentrated sampleextract. If a dilution of the sample extract is made in a subsequentanalysis, this volume will remain the same, but the dilution factorwill change. Enter the "pH" of the sample before extraction, reportedto 0.1 pH units. Enter "Y" or "N" for "Yes" or "No" under the "SulfurCleanup" for the pesticides.

In the concentration column, for positively identified targetcompounds, the Contractor shall report the concentrations asuncorrected for blank contaminants.

For volatile and Semivolatile results, report analytical results to onesignificant figure if the value is less than 10, and to two significantfigures if greater than or equal to 10.

Report all pesticide/Aroclor results to two significant figures.

If the analytical result is greater than or equal to the quantitationlimit, report the result.

Under the column labeled "Q" for qualifier, flag each result with thespecific Data Reporting Qualifiers listed below. The Contractor isencouraged to use additional flags (however, see "X" below) . Thedefinition of such flags must be explicit and must be included in theSDG Narrative.

For reporting results to the USEPA, the following contract specificqualifiers% are to be used. The nine qualifiers defined below are notsubject to modification by the laboratory. Up to five qualifiers maybe reported on Form I for each compound.

B-30 6/91

AR302706

The nine defined qualifiers to be used are as follows:

U - Indicates compound was analyzed for but not detected. Thenumerical value is the sample quantitation limit and must becorrected for dilution. For example, 5 U for phenol in waterif the sample final volume is the protocol-specified finalvolume. If a 1 to 10 dilution of the extract is necessary, thereported limit is 50 U.

J - Indicates an estimated value. This flag is used either whenestimating a concentration for tentatively identified compoundswhere a 1:1 response is assumed, or when the mass spectral dataindicate the presence of a compound that meets theidentification criteria but the result is less than the samplequantitation limit but greater than zero. For example, if thesample quantitation limit is 10 ug/L, but a concentration of 3ug/L is calculated, report it as 3J. The sample quantitationlimit must be adjusted for dilution as discussed for the Uflag.

N - Indicates presumptive evidence of a compound. This flag isonly used for tentatively identified compounds, where theidentification is based on a mass spectral library search, itis applied to all TIC results. For generic characterization ofa TIC, such as chlorinated hydrocarbon, the N code is not used.

B - This flag is used on the sample Form I when the analyte isfound in the associated blank as well as in the sample. Itindicates possible/probable blank contamination and warns thedata user to take appropriate action. This flag must be usedfor a TIC as well as for a positively identified targetcompound.

The combination of flags "BU" or "UB" is expressly prohibited.Blank contaminants are flagged "B" only when they are detectedin the sample.

E - This flag identifies compounds whose concentrations exceed theinitial calibration range of the instrument for that specificanalysis. If one or more compounds have a response that exceedthe initial calibration range, the sample or extract must bediluted and reanalyzed according to the specifications inExhibit D. All such compounds should have the concentrationflagged with an "E" on the Form I for the original analysis.The dilution of the extract may cause some compounds identifiedin the first analysis to be below the calibration range in thesecond analysis. The results of both analyses shall bereported on separate Forms I. The Form I for the dilutedsample shall have the "DL" (or "DL2") (for pesticide samplesonly) suffix appended to the EPA Sample Number. NOTE: Fortotal xylenes, where three isomers are quantified as two peaks,th,e calibration range of each peak should be consideredseparately, e.g., a diluted analysis is not required for totalxylenes unless the concentration of the peak representing the

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AR302707

single isomer exceeds 25 ng/L or the peak representing the twocoeluting isomers on that GC column exceeds 50 pg/L.

D - If a sample or extract is diluted and re-analyzed, as in the"E" flag above, all concentration values reported on that FormI are flagged with the "D" flag. The "DL" or *DL2" (forpesticide samples only) suffix is appended to the EPA SampleNumber on the Form I for the diluted sample.

A - This flag is not used under this contract, but is reserved.

F - This flag is used for a pesticide/Aroclor target analyte whenthere is greater than 25.0% difference between theconcentration calculated from the two GC columns (see Form X)The lower of the two values is reported on Form I and flaggedwith a "P".

X - Other specific flags may be required to properly define theresults. If used, they must be fully described and suchdescription attached to the Sample Data Summary Package and theSDG Narrative. Begin by using "X". If more than one flag isrequired, use "Y" and "Z", as needed. If more than fivequalifiers are required for a sample result, use the "X" flagto combine several flags, as needed. For instance, the "X"flag might combine the "A", "B", and "D" flags for some sample.

2.2 Non-target Compounds. Form I LCV-TIC and LCSV-TIC

Form I LCV-TIC and LCSV-TIC are used for reporting the tentativeidentification and estimated concentration for up to 10 of the non-surrogate and non-target organic compounds in the volatile fraction andup to 20 of the non-surrogate and non-target organic compounds in theSemivolatile fraction.

Include a Form I LCV-TIC or LCSV-TIC for every volatile andSemivolatile fraction of every sample, Performance Evaluation Sample,and blank analyzed. Form I LCV-TIC or LCSV-TIC must be provided forevery analysis (except for the Laboratory Control Samples) thatrequires a Form I for target compounds, including required dilutionsand reanalyses, even if no TICs are found.

Fill in all header information as section 2.1.

Report tentatively identified compounds (TICs) including CAS number,compound name, retention time, and the estimated concentration(criteria for reporting TICs are given in Exhibit D). Retention timemust be reported in minutes and decimal minutes, not seconds or minutesand seconds.

''ta0If in the opinion of the mass spectral interpretation specialist, novalid tentative iden'reported as unknown.

jN valid tentative identification can be made, the compound shall be

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Total the number of TICs found and enter this number in the "NumberTICs found." If no TICs were found, enter "0" (zero).

If the name of a compound exceeds the 28 spaces in the TIC column,truncate the name to 28 characters. If the compound is an unknown,restrict description to no more than 28 characters (i.e., unknownhydrocarbon , etc . ) .

All TIC results, except "generics" (See N flag) are flagged "JN" in the1Q" column to emphasize the quantitative find qualitative uncertaintiesassociated with these data. This includes "unknowns".

3. SURROGATE RECOVERY. FORM II LCV. LCSV. AND LCP

Form II is used to report the recovery of the surrogate compounds addedto each sample, blank, Laboratory Control Sample, and PerformanceEvaluation Sample.

Complete the header information on each Form II required, according tothe instructions in paragraph 1.

In the table, enter EPA Sample Numbers for each analysis as describedin paragraph 1. For each sample, report the percent recovery for eachsurrogate to the nearest whole number.

Flag each surrogate recovery outside the QC limits with an asterisk(*). The asterisk must be placed in the last space in each appropriatecolumn, under the "#" symbol. In the far right-hand column, total thenumber of surrogate recoveries outside the QC limits for each sample.If no surrogates were outside the limits, enter "0".

If a sample or extract is diluted and the surrogate recovery is belowthe recovery limits in any analysis, enter the calculated recovery or"0" (zero) if the surrogate is not detected. Flag the surrogaterecovery with a "D" in the column under the "#" symbol. Do not includeresults flagged "D" in the total number of recoveries for each sampleoutside the QC limits .

Pesticide/Aroclor samples are analyzed on two GC columns, andsurrogates recoveries must be reported for both analyses . Enter theinformation on the stationary phases and internal diameters of the twoGC columns, as described in paragraph 1.10.4, differentiating the GCcolumns as "(1)" and "(2)". Enter the recoveries of the two surrogatesfor each column in a similar fashion.

Number the Form II pages as described in paragraph 1.7.

4. LABORATORY CONTROL SAMPLE RECOVERY. FORM III LCV. LCSV. AND LCP

Form III is used to report the recovery of the spiked analytes in theLaboratory Control Sample (LCS).

Complete the header information on each Form III required, according tothe instructions in Sections 1 and 2.

B-33 . 6/91BR302709

The "LCS Lot No." is an identification number assigned by the Agency tothe LCS spiking solution, if the solution is provided by the Agency.If the LCS solution is purchased by the Contractor from a third party,report the identification number used by the laboratory under "LCS LotNo.".

The "LCS Aliquot" is the volume in microliters of LCS spiking solutionthat was added to reagent water before purging or extraction.

For pesticides, the LCS is reported for both GC columns. Enter theInstrument ID and GC Column - ID for analyses on both GC columns. Theorder of reporting is not important, but must be consistent with theinformation reported on Form X. If simultaneous injections are notmade, the "Date Analyzed" is the earlier date of the two LCS analyses.

In the upper box in Form III, under "AMOUNT ADDED", enter the amount innanograms of each analyte added to the sample. Under "AMOUNTRECOVERED*, enter the amount in nanograms of each analyte in the samplecalculated from analysis. Calculate the percent recovery of eachcompound in the sample to the nearest whole percent, according toExhibit D, and enter under "% REC". Enter the limits for each analytein the column for "QC LIMITS". The limits should be entered as twowhole numbers (lower and upper limits) separated by a hyphen. Flag allpercent recoveries which do not meet the contract requirements with anasterisk (*). The asterisk must be placed in the last space of thepercent recovery column, under the "#" symbol.

Summarize the values outside the QC limits at the bottom of the page.

5. METHOD BLANK SUMMARY. FORM IV LCV. LCSV. AND LCP

Form IV lists the samples including LCS and FES associated with eachmethod blank. A copy of the appropriate Form IV is required for eachmethod blank. ,

t

Complete the header information on each Form IV required, according tothe instructions in Sections 1.

For Semivolatile and pesticide/Aroclor method blanks, enter the date ofextraction of the blank.

For pesticide/Aroclors, enter the "Date Analyzed", "Time Analyzed","Instrument ID", and "GC Column - ID" for analyses on both GC columns.

For all three fractions, as appropriate, summarize the samples,including LCS and FES associated with a given method blank in the tablebelow the header, entering EPA Sample Number and Lab Sample ID. Forvolatiles, enter the Lab File ID and Time Analyzed for each sample.For Semivolatiles, enter the Lab File ID and Date Analyzed. Forpesticides/Aroclors, enter the Date Analyzed on each GC column for eachsample.

For pestici'des/Aroclors, enter "Y" or "N" (for yes or no) under "SulfurCleanup". If a separate sulfur cleanup blank is prepared, when not all

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samples associated with a method blank are subjected to sulfur cleanup,then complete a separate Form IV for the sulfur cleanup blank, listedthe EPA Sample No. of the blank, as described in paragraph 1.9.6, in -the box in the upper right hand corner of the form. These samplesassociated with the sulfur cleanup blank will be listed in the lowerportion of the form, as well as on a copy of Form IV for theirassociated method blank. Whenever all the samples and their associatedmethod blank are subjected to sulfur cleanup, no separate sulfur blankis required, and only one Form IV needs to be completed.

Number the Form IV pages as described in paragraph 1.7.

6. GC/HS TUNING AND MASS CALIBRATION. FORM V LCV AND LCSV

This form is used to report the results of GC/MS tuning for volatilesand Semivolatiles, and to summarize the date and time of analysis ofsamples, standards, and blanks associated with each GC/MS tune(including Laboratory Control and Performance Evaluation Samples).

Complete the header information on each Form V required, according tothe instructions in paragraph 1.

Enter the "Lab File ID" for the injection containing the GC/MS tuningcompound (BFB for volatiles, DFTPP for Semivolatiles). Enter the dateand time of injection of the tuning compound. Enter injection time asmilitary time.

In the upper table, for each ion listed on the form, enter the %Relative Abundance in the right-hand column. Report relativeabundances to the number of significant figures given for each ion inthe ion abundance criteria column.

Note that for both BFB and DFTPP, one or more of the high mass ions mayexceed the abundance of the ion listed on the form as the base peak(m/z 95 for BFB, and m/z 198 for DFTPP). Despite this possibility, allion abundances are to be normalized to the nominal base peaks listed onForm V (see Exhibit D).

All relative abundances must be reported as a number. If zero, enter"0", not a dash or other non-numeric character. Where parenthesesappear, compute the percentage of the ion abundance of the mass givenin the appropriate footnote, and enter that value in the parentheses.

In the lower half of the form, list all samples, standards, and blanksanalyzed under that tune in chronological order, by time of analysis(in military time). Refer to paragraph 1 for specific instructions foridentifying standards and blanks. Enter "EPA Sample No.", "Lab SampleID", "Lab File ID", "Date Analyzed", and "Time Analyzed" for allstandards, samples including LCS and PES, and blanks.

Number the Form V pages as'described in paragraph 1.7.

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jI

INITIAL PALIBRATION SUMMARY. FORM vi LCV. LCSV-I. LCSV-Z. LCP-I. LCP-2AND LCP-3

For each fraction, after a GC/MS or GC system has undergone an initialcalibration, and after all initial calibration technical criteria havebeen met, the laboratory must complete and submit all Form Vis forinitial calibrations performed relevant to the samples including LCSand FES and blanks in the SDG, regardless of when that calibration wasperformed.

Complete the header information on each Form VI required, according tothe instructions in paragraph 1.

Enter the "Case No." and "SDG No." for the current data package,regardless of the original Case for which the initial calibration wasperformed. Enter "Instrument ID" and "Calibration Date(s)". If thecalendar date changes during the calibration procedure, the inclusivedates should be given on Form VI.

For the volatile and Semivolatile fractions, enter the "Lab File ID"for each of the five calibration standards injected. Complete theresponse factor data for the five calibration points. The relativeresponse factor (RRF) is reported for each target compound andsurrogate. The laboratory must report the average RRF and the, percentrelative standard deviation (%RSD) for the RRFs for each targetcompound and surrogate.

The initial calibration of pesticides and Aroclors involves thedetermination of retention times, retention time windows, andcalibration factors. For single component pesticide target compounds,these data are calculated from the analyses of the Individual StandardMixtures A and B at three different concentration levels. For themulticomponent target compounds, these data are calculated from asingle point calibration.

Complete header information on Form VI, LCP-1 and LCP-2 according tothe instructions in paragraph 1. For the three analyses of IndividualStandard Mixture A (low point, mid point, and high point), and thethree analyses of Individual Standard Mixture B performed on each GCcolumn during an initial calibration, complete one copy of Form VI foreach GC column used. Enter the Instrument ID, GC Column, and ID asdescribed previously. Enter the dates of analysis of the first andlast of the six standards on each form under "Date(s) Analyzed". Under"Level (x low)", enter the concentration of the low point, mid point,and high point calibration standards as a multiplier of the low point.Therefore, for the low point, enter "1.0". The concentration of themid point standard is specified in Exhibit D as four times the lowpoint, therefore, enter "4.0" for "mid". If the concentration is notexactly 4.0 times the low point, enter the appropriate multiplier in asimilar format. The high point standard must be at least 16 times thel°w point, but may be higher if that value lies within the linear rangeof the instrument, as specified in Exhibit D. Therefore, enter theappropriate multiplier to the high point standard concentration to onedecimal place.

AR3D27I2 t/n

For the pesticides/Aroclors fraction, one Form VI (LCP-1 and LCP-2) isrequired for each initial calibration performed on each GC column. Inthe table, on Form VI LCP-1, enter the retention time of each analytein the low, mid, and high point Standard Mixtures A and B in thecolumns labeled "RT of Standards". Use the values from StandardMixture A for the surrogates. Calculate and report in the appropriatecolumn the mean retention time and the retention time windows for eachanalyte. Report the retention time window for each analyte as a rangeof two values, i.e., from 1.44 to 1.54. Enter the lower value of therange in the column under "RT WINDOW" labeled "FROM". Enter the uppervalue of the range in the column under "TO". Do not separate the twovalues with a hyphen, and do not enter the retention time window as aplus /minus value such as ±0.05. NOTE: By definition, the center of theretention time window must be the mean retention time listed to theleft of the retention time window.

On Form VI LCP-2, calculate the calibration factor for each analyte inthe low, mid, and high point Standard Mixtures A and B. Use the valuesfrom Standard Mixture A for the surrogates. Report the values underthe columns labeled "CALIBRATION FACTORS". Calculate the mean of thethree calibration factors and the percent relative standard deviation(%RSD) for the calibration factor values for each analyte. Report thecalculated values under the "MEAN" column the "%RSD" columns,respectively.

On Form VI LCP- 3, for the initial calibration of multicomponentanalytes, enter the amount of standard injected in nanograms of eachanalyte, under the "AMOUNT" column. The number of peaks with anasterisk under the "Peak" column indicates the minimum number of peakscalibrated for each analyte. Enter the retention time of each peakused to quantitate under the "RT" column. Data for two additionalpeaks may be reported for each multicomponent analyte. Calculate andreport the calibration factor for each peak used under "CALIBRATIONFACTOR" .

8. PESTICIDE RESOLUTION CHECK SUMMARY '. FORM VI LCP -4

Pesticide Resolution Check Summary Form VI is used to report theresolution of each analyte in the Resolution Check Mixture analyzed atthe beginning of each initial calibration on each GC column.

Complete the header information on each Form VI required according tothe instructions in paragraph 1.

For each GC column, enter the "EPA Sample Number" of the ResolutionCheck Mixture, as described in paragraph 1.9.7, for the mixtureinjected on the first GC column. Enter the Lab Sample ID, DateAnalyzed (1) , and Time Analyzed (1) .

In the table, under "ANALYTE", enter the name of each analyte as itappears on Form I, in elution order, starting with the first targetanalyte or surrogate to elute. Enter the retention time of each of theanalytes listed under "RT".

AR302713 6/91

Calculate the percent resolution between each pair of consecutive peaksaccording to Exhibit D. Enter the percent resolution of each pair inthe "RESOLUTION" field of the analyte that elutes earlier (the analytelisted first). The resolution must be calculated for each adjacentpeaks so that the resolution of peak 1 and peak 2 is calculated, aswell as peak 2 vs. peak 3, peak 3 vs. peak 4, etc. The "RESOLUTION"field will be left blank for the last analyte in the in the table. Thepercent resolution must meet the QC limits listed at the bottom of thepage.

Complete the information for the second GC column in the same fashion.

9. CONTINUING CALIBRATION SUMMARY. FORM VII LCV. LCSV-1 AND LCSV-2

The Continuing Calibration Summary Form VII is used to verify thecalibration of the GC/MS system by the analysis of specific calibrationstandards. Form VII is required for each 12 hour time period for bothvolatile and Semivolatile analysis.

Complete the header information on each Form VII required, according tothe instructions in paragraph 1.

Enter date and time of continuing calibration standard analysis, theLab File ID of the continuing calibration standard, and date(s) ofinitial calibration. Give inclusive dates if initial calibration isperformed over more than one date. Enter the average relative responsefactor (RRF) for each target compound that was calculated from theinitial calibration data (referred to in the initial calibrationdate(s) analyzed field). Report the relative response factor for eachtarget compound and surrogate from the continuing calibration standardanalysis.

10. PESTICIDE/AROCLOR CALIBRATION VERIFICATION

Calibration Verification Summary. Form VII LCP-1 and LCP-2

The Calibration Verification Summary Form VII is used to report theresults of the Performance Evaluation Mixtures (PEM), instrumentblanks, and Individual Standard Mixtures A and B analyzed at thebeginning and end of a twelve hour sequence. The laboratory mustsubmit this form for each twelve hour sequence analyzed.

Complete the header information on each Form VII required according tothe instructions in paragraph 1.

Enter the initial calibration date(s) analyzed. Give inclusive datesif initial calibration is performed over more than one date.

On Form VII, LCP-1, enter the EPA Sample No., Lab Sample ID, DateAnalyzed, and Time Analyzed for the instrument blank that preceded thetwelve hour sequence (PIBLK). For the PEM that initiated or terminatedthe twelvevhour sequence (PEM), enter the EPA Sample No., Lab SampleID, Date Analyzed, and Time Analyzed.

B-38 Af?3n?7n. 6/91

When reporting data for the PEM at the beginning of the initialcalibration sequence, leave blank the "EPA Sample No.", "Lab SampleID", andf "Date" and "Time Analyzed" fields for the instrument blank(PIBLK), as no instrument blank is analyzed before this PEM. Whenreporting a.ll other PEM analyses, the instrument blank fields must becompleted.

In the table, report the retention time for each analyte in the PEM aswell as the retention time windows. For each analyte in the PEM, enterthe amount of the analyte in nanograms, to three decimal places,calculated to be in the PEM, under "CALC AMOUNT". Enter the nominalamount of each analyte in the PEM under "NOM AMOUNT". Calculate therelative percent difference between the calculated amount and nominalamount for each analyte according to Exhibit D. Report the valuesunder "%D".

Calculate the percent breakdown for endrin and 4,4'-DOT, and thecombined percent breakdown in the PEM according to Exhibit D. Enterthe values for the breakdown of endrin and 4,4'-DOT in their respectivefields immediately under the table.

Form VII LCP-2 is used to report the dates and times of analysis of theinstrument blanks and the results of the analyses of the midpointconcentrations of Individual Standard Mixtures A and B that, along withthe FEM, bracket each 12-hour period of sample analyses. One copy ofFora VII LCP-2 must be completed each time the Individual StandardMixtures are analyzed, for each GC column used. The form is completedin a similar fashion to Form VII LCP-1, entering the EPA Sample No.,Lab Sample ID, Date Analyzed, and Time Analyzed for the instrumentblank immediately preceding the Individual Standard Mixtures A and B,and for the standards themselves. The upper table on the form containsthe retention time and amount data for Individual Standard Mixture Acompounds. The lower table contains the data for Mixture B. Enter thedata in these tables in a fashion similar to that for the PEM.Complete copies of Form VII LCP-1 and 2 for each standard reported inForm VIII LCP.

11. INTERNAL STANDARD AREA AND RETENTION TIME SUMMARY FORM VIII LCV. LCSV-1AND LCSV-2

Form VIII is used to summarize the peak areas and retention times ofthe internal standards added to all volatile and Semivolatile samplesand blanks. Form VIII is also used to check the internal standards inthe initial calibration sequences. The data are used to determine whenchanges in internal standard responses will adversely affectquantitation of target compounds. This form must be completed eachtime an initial calibration or a continuing calibration is performed,

, or when samples are .analyzed under the same GC/MS tune as an initialcalibration.

Complete the header information on each Form VIII required, accordingto the instructions in paragraph 1.

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Enter the Lab File ID, Date Analyzed, and Time Analyzed for thecontinuing calibration standard. If samples are analyzed immediatelyfollowing an initial calibration, before another GC/MS tune and acontinuing calibration, Form VIII shall be completed for the initialcalibration standard that is the same concentration as the continuingcalibration standard. .Enter the Lab File ID, the date and time ofanalysis, the areas and retention times of .this initial calibrationstandard in place of those of a continuing calibration standard.

From the results of the analysis of the continuing calibrationstandard, enter the area measured for each internal standard and itsretention time under the appropriate column in the row labeled "12 HOURSTD". For each volatile internal standard, calculate the area upperlimit as the area of the particular internal standard plus'40 percentof its area, and the area lower limit as the area of the internalstandard minus 40 percent of its area. For each Semivolatile internalstandard, calculate the area upper limit as the area of the particularstandard plus 100% of its area (i.e., two times the area in the 12 HOURSTD box), and the area lower limit as the area of the internal standardminus 50% of its area (i.e., one half the area in the 12 HOUR STD box).Report these values in the boxes labeled "UPPER LIMIT" and "LOWERLIMIT" respectively.

For each volatile and semivolatile internal standard, calculate theretention time (RT) upper limit as the RT of the particular internalstandard plus 0.33 minutes. The lower limit is the RT of the internalstandard minus 0.33 minutes. Report these values in the boxes labeled"UPPER LIMIT" and "LOWER LIMIT" respectively.

For each sample including LCS and PES and blank analyzed under a givencontinuing calibration, enter the EPA Sample Number and the areameasured for each internal standard and its retention time. If theinternal standard area or retention time is outside the upper or lowerlimits calculated above, flag that value with an asterisk (*). Theasterisk must be placed in the far right hand space of the box for eachinternal standard area or retention time, directly under the "#"symbol.

If samples are analyzed immediately following an initial calibration asdescribed above, enter the EPA Sample'Number, internal standard areas,and retention times for all five of the initial calibration standards.

Number the Form VIII pages as described in paragraph 1.7.

12. PESTICIDE/AROCLOR ANALYTICAL SEQUENCE. FORM VIII LCP

Form VIII LCP is required for each analytical sequence for each GCsystem and for each GC column used to analyze pesticide/Aroclors in anSDG.

Complete the header information on each Form VIII required, accordingto the instructions in paragraph 1.

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AR3027I6

Enter the initial calibration date(s). Give inclusive dates if initialcalibration is performed over more than one date.

At the top of the table, report the mean retention time for surrogatestetrachloro-m-xylene and decachlorobiphenyl calculated from the initialcalibration sequence under "TCX" and "DCB", respectively. For everyanalysis associated with a particular analytical sequence starting withthe initial calibration, enter the EPA Sample Number, Lab Sample ID,Date Analyzed, and Time Analyzed. Each sample analyzed as part of thesequence must be reported on Form VIII LCP even if it is not associatedwith the SDG. The laboratory may use the EPA Sample No. of "ZZZZZ" todistinguish all samples that are not part of the SDG being reported.Report the retention time of the surrogates for each analysis under"TCX RT" and "DCB RT". All sample analyses must be bracketed byacceptable analyses of instrument blanks, a PEM, and IndividualStandard Mixtures A and B. Given the fact that the initial calibrationnay remain valid for some time (see Exhibit D), it is not necessary toreport the data from 12-hour periods when po samples in an SDG wererun. The laboratory Bust deliver the Form VIII for the initialcalibration sequence, and Forms that include the FEMs and IndividualStandard Mixtures that bracket any and all samples in the SDG. Whilethe data for time periods between the initial calibration and samplesin the SDG is not a routine deliverable, it must be made available onrequest during on-site evaluations, etc. Here again, non-EPA samplesmay be indicated with "ZZZZZ".

Flag all those values which do not meet the contract requirements byentering an asterisk (#) in the last column, under the "*". If theretention time cannot be calculated due to interfering peaks, leave theRT column blank for that surrogate, enter an asterisk in the last(i.e., under "DCB") column, and document the problem in the SDGNarrative.

Number the Form VIII pages as described in paragraph 1.7.

13. PESTICIDE/AROCLOR FLORISIL CARTRIDGE CHECK. FORM IX LCP

Form IX is required for each lot of Florisil cartridges that is usedwith samples associated with the SDG.

Complete the header information on each Form IX required, according tothe instructions in paragraph 1.

Enter the "Case No." and "SDG No." for the current data package,regardless of the original Case for which the cartridge check wasperformed. Enter the "Florisil Cartridge Lot Number". Enter under the"Date Analyzed", the date the Florisil cartridge check solution wasanalyzed.

In the upper table, enter the amount of spike added and spike recoveredin nanograms for each analyte.

Calculate *to the nearest whole percent, and enter the percent recoveryin the "% REG" field. Flag each spike recovery outside the QC limits

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AR3027I7

with an asterisk (*). The asterisk must be placed in the last space inthe "% Rec" column, under the "#" symbol.

In the lower table, enter the "EPA Sample No.", the "Lab Sample ID",and "Date Analyzed" for each sample and blank that was cleaned up usingthis lot of Florisil cartridges.Number the Form IX pages as described in paragraph 1.7.

14. PESTICIDE/AROCLOR IDENTIFICATION. FORM X LCP-1. LC'P-2

Form X summarizes the data used to identify and quantify allpesticide/Aroclor target analytes detected in a given sample. Form XLCP-1 is required for each sample (including PES and LCS) or blank inwhich any single component analytes is detected. Form X LCP-2 isrequired for each sample (including FES and LCS) or blank in which anymulticomponent analyte is detected. If no single component analyte ormulticomponent analyte is detected in a sample,.no copy of theapplicable Form X is required for that sample.

Complete the header information on each Form X required, according tothe instructions in paragraph 1.

For each target pesticide or Aroclor detected, enter the name of the 'analyte on Form X in the column labeled "Analyte", spelling the name asis appears on Form I. For the multicomponent analytes, there arespaces (fields) for up to 5 peaks for each analyte. The asterisksindicate the number of peaks that are required, and data for additionalpeaks may be reported. The retention time, retention time window, andconcentration are calculated separately for each peak used for amulticomponent analyte. For each GC column, enter the retention timesof the analytes detected in the sample next to the appropriate columndesignation (1 or 2). Enter the retention time windows on each column•of the appropriate standard. The lower value is entered under the"FROM" column, the upper value under the "TO" column. Do not use ahyphen. These data must correspond with those on Form VI, and areentered in a similar manner. Calculate the concentration of the analyteusing the calibration factors derived from the initial calibrationsequence. For the multicomponent analytes, calculate and report themean concentration by averaging the concentration values from the peaksused for quantitation. Calculate and report the percent difference toa tenth of a percent between the concentration values (or meanconcentration values for multicomponent analytes) on the two GC columnsunder "%D" as described in Exhibit D.

Number the Form X pages as described in paragraph 1.7.

THE FOLLOWING ARE DOCUMENT CONTROL FORMS(To be submitted as hardcopy only)

15. SAMPLE LOG-IN SHEET (FORM DC-1)

This form Cs used to document the receipt and inspection of samples andcontainers. One original of Form DC-1 is required for each sample

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shipping container. If the samples in a single sample shippingcontainer (e.g., coolers) must be assigned to more than one SampleDelivery Group, the original Form DC-1 shall be placed with thedeliverables for the Sample Delivery Group with the lowest samplenumber and a copy of Form DC-1 must be placed with the deliverables forthe other Sample Delivery Group(s). The copies should be identified as"copy(ies)," and the location of the original should be noted on thecopies.

Sign and date the airbill (if present). Examine the shipping containerand record the presence/absence of custody seals and their condition(i.e., intact, broken) in item 1 on Form DC-1. Record the custody sealnumbers in item 2.

Open the container, remove the enclosed sample documentation, andrecord the presence/absence of chain-of-custody record(s), SMO forms(i.e., Traffic Reports, Packing Lists), and airbills or airbillstickers in items 3-5 on Form DC-1. Specify if there is an airbillpresent or an airbill sticker in item 5 on Form DC-1. Record theairbill or sticker number in item 6.

Remove the samples from the shipping container(s), examine 'the samplesand the sample tags (if present), and record the condition of thesample bottles (i.e., intact, broken, leaking) and presence of absenceof sample tags in items 7 and 8 on Form DC-1.

Review the sample shipping documents and complete the headerinformation described in Part A. Compare the information recorded onall the documents and samples and mark the appropriate answer in item 9on Form DC-1.

If there are no problems observed during receipt, sign and date(include time) Form DC-1, the chain-of-custody record, and TrafficReport, and write the sample numbers on Form DC-1. Record theappropriate Sample tags and assigned laboratory numbers if applicable.The log-in date should be recorded at the top of Form DC-1 and the dateand time of cooler receipt at the laboratory should be recorded initems 10 and 11. Cross out unused columns and spaces.

If there are problems observed during receipt or an answer marked withan asterisk (i.e., "absent*") was marked, contact SMO and document thecontact as well as resolution of the problem on a CLP CommunicationLog. Following resolution, sign and date the forms as specified in thepreceding paragraph and note, where appropriate, the resolution of theproblem.

Record the fraction designation (if appropriate) and the specific areadesignation (e.g., refrigerator number) in the Sample Transfer blocklocated in the bottom left corner of Form I. Sign and date the SampleTransfer block.

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AR302719 I

16. DOCUMENT INVENTORY SHEET (FORM DC-2)

This form is used to record the inventory of the Complete SDG Filedocuments and count of documents in the original Sample Data Packagewhich is sent to the Region.

Organize all complete SDG file documents as described in Exhibit B,Section II, paragraph 5. Assemble the documents in the order specifiedon Form DC-2, and stamp each page with a consecutive number. (Do notnumber the DC-2 form). Inventory the CSF by reviewing the documentnumbers and recording page number ranges in the columns provided in theForm DC-2. If there are no documents for a specific document type,enter an "NA" in the empty space.

Certain laboratory specific documents related to the CSF may not fitinto a clearly defined category. The laboratory should review DC-2 todetermine if it is most appropriate to place them under No. 7, 8, 9, or10. Category 10 should be used only if there is no appropriateprevious category. These types of documents should be described orlisted in the blanks under each appropriate category.

B-44 6/91

AH3Q2720

SECTION IV

DATA REPORTING FORMS

B-45 6/91

AR30272I

1LCA EPA SAMPLE NO.LOW CONC. WATER VOLATILE ORGANICS ANALYSIS DATA SHEET

Lab Name: Contract:

Lab Code: Case No.: SAS No.: : SDG No.:

Lab Sample ID: __________ Date Received:

Lab File ID: ___________ Date Analyzed:

Purge Volume: _____ (mL) Dilution Factor:CONCENTRATION

CAS NO. COMPOUND (ug/L)

74-87-3——————Chloromethane_7 4 -83-9 ——••——Bromomethane_75-01-4——————Vinyl chloria?e_75-00-3———————Chloroethane75-09-2———————Methylene .chloride67-64-1———————Acetone __75-15-^0——-——Carbon disulfide75-35-4———————1,1-Dichloroethene_____75-34-3———————1,1-Dichloroethane_____156-59-4——————:cis-l, 2-Dichloroethene__156-60-5——————trans-l,2-Dichloroethene_67-66-3———————Chloroform107-06-2——————l,2-Dichloroethane_78-93-3——————2-Butanone74-97-5——————-Bromochloromethane___71-55-6——————1,1, l-Trichloroethane_56-23-5-————Carbon tetrachloride_J75-27-4——————Bromodichloromethane78-87-5———————1,2-Dichloropropane10061-01-5————cis-1,3-Dichloropropene79-01-6———————Trichloroethene

48-1——————Dibromochloromethane_79-00-5———f-——1,l,2-Trichloroethane_71-43-2———————Benzene10061-02-6————trans-l,3-Dichloropropene^75-25-2——————'-Bromoform108-10-1——————4-Methyl-2-pentanone591-78-6——————2-Hexanone127-18-4——————Tetrachloroethene_______79-34-5———————1,1,2,2-Tetrachloroethane_106-93-4——•—--1,2-Dibromoethane108-88-3——•———Toluene _____108-90-7—-————Chlorobenzene_100-41-4——————Ethylbenzene_J100-42-5——————Styrene1330-20-7—————Xylenes (total)__________541-73-1—————1,3-Dichlorobenzene______106-46-7——————1,4-Dichlorobenzene_______95-50-1———————1, 2-Dichlorobenzene_______96-12-8———————1, 2-Dibromo-3-chloropropane_

FORM I LCV M3Drm 6/91

1LCB . EPA SAMPLE NO.LOW CONC. WATER SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET

Lab Name: Contract:

Lab Code: ______ Case No.: _____ SAS No.: _____ SDG No.:

Lab Sample ID: ___________ Date Received: __

Lab File ID: . Date Extracted:__

Sample Volume: _____ (mL) Date Analyzed: ___

Concentrated Extract Volume: _____(uL) Dilution Factor: __

Injection Volume: ___ (uL) pH: ___

CONCENTRATIONCAS NO. COMPOUND (ug/L)

108-95-2——————Phenol______________111-44-4——————bis(2-Chloroethyl)ether_95-57-8——-—:——2-Chlorophenol95-48-7———————2-Methylphenol~108-60-1——————2,2' -oxybis (l-Chloropropane)106-44-5——————4-Methylphenol_621-64-7——————N-Nitroso-di-n-propylamine_67-72-1———————Hexachloroethane________"98-95-3———————Nitrobenzene____________78-59-1———————Isophorone88-75-5———————2-Nitrophenol____________105-67-9——————2,4-Dimethylphenol_______111-91-1——————bis (2-Chloroethoxy) methane_120-83-2——————2,4-Dichlorophenol120-82-1——————1,2,4-Trichlorobenzene_91-20-3———————Naphthalene106-47-8——————4-Chloroaniline_j______87-68-3———————Hexachlorobutadiene59-50-7———————4-Chloro-3-methylphenol91-57-6——————2-Methylnaphthalene_77-47-4———————Hexachlorocyclopentadiene88-06-2——————2,4,6-Trichlorophenol95-95-4———————2,4, 5-Trichlorophenol___91-58-7——————2-Chloronaphthalene_____88-74-4———————2-Nitroaniline131-11-3—————Dimethylphthalate_208-96-8——————Acenaphthylene606-20-2——————2,6-Dinitrotoluene99-09-2———————3-Nitroaniline___~83-32-9———————Acenaphthene_____

FORM I LCSV-1 6/91

AR302723

1LCC EPA SAMPLE NO.LOW CONC. WATER SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET

Lab Name: Contract:Lab Code: ______ Case No.: ____ SAS No.: _____ SDG No.:


Lab File ID: . Date Extracted:

Sample Volume: ;_______ (mL) Date Analyzed: ___

Concentrated Extract Volume: __________(uL) Dilution Factors __

Injection Volume: ___ (uL) pH: ___:-

CONCENTRATIONCAS NO. COMPOUND (ug/L)

51-28-5——————2,4-Dinitrophenol100-02-7—————4-Nitrophenol__~132-64-9——————Dibenzofuran121-14-2——————2,4-Dinitrotoluene84-66-2——————Diethylphthalate_7005-72-3—————4-Chlorophenyl-phenylether_86-73-7——————Fluorene100-01-6——————4-Nitroaniline534-52-1——————4, 6-Dinitro-2-methylphenol_86-30-6———————N-Nitrosodiphenylamine (1) _101-55-3—————4-Bromophenyl-phenylether_____118-74-1——————Hexachlorobenzene_________87-86-5——————Pentachlorophenol________85-01-8——————Phenanthrene_________120-12-7——————Anthracene84-74-2———————Di-n-butylphthalate_206-44-0——————Fluoranthene_____"129-00-0—————Pyrene_85-68-7———————Butylbenzylphthalate91-94-1——————3,3' -Dichlorobenzidine_56-55-3——————Benzo (a) anthracene218-01-9—————Chrysene_117-81-7——————bis(2-Ethylhexyl)phthalate117-84-0————•—Di-n-octylphthalate_____~205-99-2——————Benzo (b) f luoranthene_______207-08-9——————Benzo (k) f luoranthene_____50-32-8——————Benzo(a)pyrene_193-39-5—————Indeno( 1,2,3 -cd)pyrene_53-70-3———————Dibenz (a,h)anthracene__191-24-2——————Benzo (g,h,i)perylene

(1) - Cannot be separated from Diphenylamine

FORM I LCSV-2 6/91

!LCD EPA SAMPLE NO.LOW CONC. WATER PESTICIDE ORGANICS ANALYSIS DATA SHEET

Lab Name: » Contract:

Lab Code: _______ Case No.: ' SAS No.: _____ SDG No.:

Lab Sample ID: __________ Date Received: __

Sample Volume: ______ (mL) Date Extracted: _

Concentrated Extract Volume: _____(uL) Date Analyzed: __

Injection Volume: ___ (uL) Dilution Factor:

Sulfur Cleanup: (Y/N) __ pH: ___

CONCENTRATIONCAS NO. COMPOUND ' (ug/L)'

319-84-6——————alpha-BHC________319-85-7——————beta-BHC_________319-86-8———————delta-BHC _________58-89-9———————gamma-BHC (Lindane)76-44-8———————Heptachlor_______'3 09-00-2——————Aldrin1024-57-3—————Heptachlor epoxide959-98-8———'——Endosulfan I____"60-57-1———————Dieldrin________72-55-9————————4 , 4 ' -DDE_________________72-20-8———————Endrin33213-65-9—————Endosulfan II72-54-8————————4,4'-DDD1031-07-8—————Endosulfan sulfate50-29-3————————4 , 4 ' -DOT_________"72-43-5——————Methoxychlor__53494-70-5————Endrin ketone__7421-36-3———^—Endrin aldehyde5103-71-9—————alpha-Chlordane"5103-74-2—————gamma-Chlordane"8001-35-2—————T'oxaphene_12674-11-2————Aroclor-101611104-28-2————Aroclor-122l"11141-16-5————Aroclor-1232"53469-21-9—————Aroclor-1242~12672-29-6—————Aroclor-1248"11097-69-1—————Aroclor-1254"11096-82-5—————Aroclor-1260"

FORM I LCP 6/91

AR302725 .

1LCE EPA SAMPLE NO.LOW CONC. WATER VOLATILE ORGANICS ANALYSIS DATA SHEET

TENTATIVELY IDENTIFIED COMPOUNDS

Lab Name: __ Contract:________

Lab Code: ______ Case No.: _____ SAS No.: ______ SDG No.:

Lab Sample ID: __________ Date Received: __

Lab File ID: ______'____ Date Analyzed: __

Purge, Volume: ______ (mL) Dilution Factor:

Number TICs found:

CAS NUMBER

1.2.3.4.5.6.7.8.9.10.11.12.13.14.15.16.17.18.19.20.21.22.23.24.25.26.27.28.29.30.

COMPOUND NAME

'

RTEST. CONC.(Ug/L)

•

Q

FORM I LCV-TIC 6/91

AR302726

1LCF EPA SAMPLE NO,LOW CONC. WATER SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET

TENTATIVELY IDENTIFIED COMPOUNDS

Lab Name: ____ Contract:

Lab Code: ______ Case No.: ____ SAS No.: _____ SDG No.:


Lab File ID: ___________ Date Extracted:_____

Sample Volume: _____ (mL) Date Analyzed: __

Concentrated Extract Volume: _____(uL) Dilution Factor:

Injection Volume: ____ (uL) pH: ____

Number TICs found:

CAS NUMBER

1.2.3.4.5.6.7.8.9.10.11.12.13.14.15.16.17.18.19.20.21.22.23.24.25.26.27.28.29.30.

COMPOUND NAME RTEST . CONC .

(ug/L)

.

_

Q

FORM I LCSV-TIC 6/91

&R302727

2LCALOW CONC. WATER VOLATILE SURROGATE RECOVERY

Lab Name: Contract:

Lab Code: Case No.: SAS No.: ______ SDG No.

010203040506070809101112131415161718192021222324252627282930

EPASAMPLE NO.

BFB%REC f

OTHER

—————

TOTOUT

——

QC LIMITS%REC

BFB « Bromofluorobenzene (80-120)

# Column to be used to flag recovery values.* Values outside of contract required QC limits.D Surrogate diluted out.

page _ of _FORM II LCV . 6/91

AR302728

2LCBLOW CONC. WATER SEMIVOLATILE SURROGATE RECOVERY

Lab Name: Contract:

Lab Code: Case No.: SAS No. : _____ SDG No.

010203040506070809101112131415161718192021222324252627282930

EPASAMPLE NO.

NBZ%REC t

FBP%REC f

TPH%REC t

PHL%REC #

2FP%REC t

TBP%REC #

OTHER TOTOUT

QC LIMITS%REC

NBZ « Nitrobenzene-d5 (40-112)FBP » 2-Fluorobiphenyl (42-110)TPH « Terphenyl-dl4 (24-140)PHL « Phenol-d5 (17-113)2FP « 2-Fluorophenol (16-108)TBP « 2,4,6-Tribromophenol (18-126)# Column to be used to flag recovery values.* Values outside of contract required QC limits.D Surrogate diluted out.

page _ of _FORM II LCSV 6/91

6R302729

2LCCLOW CONC. WATER PESTICIDE SURROGATE RECOVERY

Lab Name: Contract:Lab Code: Case No.: SAS No.: SDG No.:

GC Column(1) : ______________ ID: ____(mm) GC Column(2) : ________ ID: ____(mm)

01020.3040506070809101112131415161718192021222324252627282930

EPASAMPLE NO.

TCX(l)%REC t

TCX(2)%REC *

DCB(l)%REC #

DCB(2)%REC #

OTHER(D

OTHER(2)

TOTOUT

QC LIMITS%REC

TCX * Tetrachloro-m-xylene (60-150)DCB = Decachlorobiphenyl (60-150)

# Column to be used to flag recovery values.* Values outside of contract required QC limits.D Surrogate diluted out.

page _ of _FORM II LCP 6/91

JR30273Q

3LCA EPA SAMPLE NO.LOW CONC. WATER VOLATILE LAB CONTROL SAMPLE RECOVERY

Lab Name:___________________. Contract:

Lab Code: ______ Case No.: _____ SAS No.: ______ SDG No.:

Lab Sample ID: ___________ LCS Lot No.: ____

Lab File ID: ___________ Date Analyzed:

Purge Volume: _____ (mL) Dilution Factor:

LCS Aliquot: ______ (uL)

COMPOUND

Vinyl chloride1 , 2-DichloroethaneCarbon tetrachloride1, 2-DichloropropaneTrichloroethene1,1,2 -Tr ichloroethaneBenzenecis-1 , 3 -DichloropropeneBromoformTetrachloroethene1 , 2-Dibromoethane1, 4-Dichlorobenzene

AMOUNTADDED(ng)

AMOUNTRECOVERED'

(ng) %REC #QC

LIMITS

# Column to be used to flag LCS recovery with an asterisk.* Values outside of QC limits.

LCS Recovery:____ outside limits out of _____ total.

COMMENTS:

FORM III LCV 6/91

AR302731

3LCB EPA SAMPLE NO.LOW CONC. WATER SEMIVOLATILE LAB CONTROL SAMPLE RECOVERY

Lab Name: \ Contract:


Lab Sample ID: ___________ LCS Lot No.: _______

Lab File ID: ___________ Date Extracted:.

LCS Aliquot: _____ (uL) Date Analyzed: .

Concentrated Extract Volume: _____(uL) Dilution Factor:

Injection Volume: ____ (uL) pH: ____

COMPOUND

Phenolbis (2-Chloroethyl) ether2-ChlorophenolN-Nitroso-di-n-propyiamineHexachloroethaneIsophorone1,2, 4-Trichlorobenzene ___Naphthalene4-Chloroaniline2,4, 6-Trichlorophenol ___2 , 4-DinitrotolueneDiethylphthalateN-NitrosodiphenylamineHexachlorobenzeneBenzo (a) pyrene

AMOUNTADDED(ng)

J»

AMOUNTRECOVERED

(ng)S*3SS£35SSS£SSS£i53ES g

%REC #ac«»==:=

QCLIMITS

# Column to be used to flag LCS recovery with an asterisk.* Values outside of QC limits.

LCS Recovery: _____ outside limits out of ____ total.

COMMENTS:

FORM III LCSV 6/91

3LCC EPA SAMPLE NOLOW CONC. WATER PESTICIDE LAB CONTROL SAMPLE RECOVERY

Lab Name: ___ Contract:


Lab Sample ID: ____________ LCS Lot No.: ____

LCS Aliquot: _____ (uL) Date Extracted:

Concentrated Extract Volume: _____(uL) Date Analyzed:

Injection Volume: ____ (uL) Dilution Factor: ______

Sulfur Cleanup: (Y/N) __ pH: ____

Instrument ID(1) : _________ GC Column(1) : ________ ID: ____(mm)

COMPOUND

aamma-BHC (Lindane)Heptachlor epoxideDieldrin4,4' -DDEEndrinEndosulfan sulfategamma-Chlordane

AMOUNTADDED(ng)=»=======

.

AMOUNTRECOVERED

(ng) %REC tQC

LIMITS

Instrument ID(2) : _________ GC Column(2) : _________ ID: ____(mm)

COMPOUND

gamma -BHC (Lindane)Heptachlor epoxideDieldrin4,4' -DDEEndrinEndosulfan sulfategamma-Chlordane

AMOUNTADDED(ng)

AMOUNTRECOVERED

(ng) %REC #QC

LIMITS

# Column to be used to flag recovery values with an asterisk.* Values outside of QC limits.LCS Recovery:____ outside limits out of _____ total.

COMMENTS:

FORM III LCP ' 6/91

5R302733

4LCA EPA SAMPLE NO.LOW CONC. WATER VOLATILE METHOD BLANK SUMMARY

Lab Name: Contract:

Lab Code: _________ Case No.: ______ SAS No.: _____ SDG No.: ___"""'"" ------ ~"~~ f , . .

Lab Sample ID: __________ Date Analyzed: ____

Lab File ID: _.__________ Time Analyzed: ________

Instrument ID: _____________

THIS METHOD BLANK APPLIES TO THE FOLLOWING SAMPLES AND LCS:

COMMENTS:

010203040506070809101112131415161718192021222324252627282930

EPASAMPLE NO.

LABSAMPLE ID

LABFILE ID

TIMEANALYZED

page _ of _ . '

FORM IV LCV . 6/91

AR30273I*

4LCB EPA SAMPLE NO.LOW CONC. WATER SEMIVOLATILE METHOD BLANK SUMMARY

Lab Name: Contract:


Lab Sample ID: ___________ Date Extracted:__

Lab File ID: ______________ Date Analyzed: __

Instrument ID: _______ Time Analyzed: __

THIS METHOD BLANK APPLIES TO THE FOLLOWING SAMPLES AND LCS:

COMMENTS:

010203040506070809101112131415161718192021222324252627282930

EPA• SAMPLE NO.

LABSAMPLE ID

LABFILE ID

DATEANALYZED

page _ of _

FORM IV LCSV 6/91

&R3Q2735

4LCC EPA SAMPLE NO.LOW CONC. WATER PESTICIDE METHOD BLANK SUMMARY

Lab Name: Contract:

Lab Code: ______ Case No.: ____ SAS No.: • SDG No.:

Date Extracted: _______ Lab Sample ID: __

Date Analyzed (1): _____________ Date Analyzed (2):

Time,Analyzed (1): _______ Time Analyzed (2):

Instrument ID (l): _______ Instrument ID (2):

GC Column (1) : ________ ID:____(mm) GC Column (2) : ________ ID:____(mm)

Sulfur Cleanup: (Y/N) __THIS METHOD BLANK APPLIES TO THE FOLLOWING SAMPLES AND LCS:

0102030405060708091011121314151617181920212223242526

EPASAMPLE NO.

LABSAMPLE ID

DATEANALYZED 1==========

.

DATEANALYZED 2

COMMENTS:

page _ of _

FORM IV LCP 6/91

AR302736

5LCALOW CONC. WATER VOLATILE ORGANIC GC/MS TUNING AND MASS

CALIBRATION - BROMOFLUOROBENZENE (BFB)

Lab Name: Contract:

ie: Case No.: SAS No.: SDG No.:

Le

ner

unr

ID:

it ID:

i: ID:. (mm)

BFB Injection Date:

BFB Injection Time: .

ION ABUNDANCE CRITERIA

8.0 - 40.0% of mass 9530.0 - 66.0% of mass 95Base peak, 100% relative abundance5.0 - 9.0% of mass 95Less than 2.0% of mass 17450.0 - 120.0% of mass 954.0 - 9.0 % of mass 17493.0 - 101.0%5.0 - 9.0% of

r-H]

01020304050607080910111213141516171819202122

of mass 174mass 176

% RELATIVEABUNDANCE

( ;( ;( ;( ]

1

2

L -Value is % mass 174 2 -Value is % mass 176

CS TUNE APPLIES TO THE FOLLOWING SAMPLES/ LCS, BLANKS, AND STANDARDS

EPASAMPLE NO.

LABSAMPLE ID

LABFILE ID

DATEANALYZED

TIMEANALYZED

1

page _ of _

FORM V LCV 6/91

AR302737

5LCBLOW CONC. WATER SEMIVOLATILE ORGANIC GC/MS TUNING AND MASS

CALIBRATION - DECAFLUOROTRIPHENYLPHOSPHINE (DFTPP)

Lab Name: __ Contract:

Lab Code: ______ Case No.: ____ .SAS No.: _____ SDG No.:

Lab File ID: ______________ DFTPP Injection Date;Instrument ID: ________ DFTPP Injection Time:_

m/e51686970127197198199275365441442443

ION ABUNDANCE CRITERIA

30.0 - 80.0% of mass 198Less than 2.0% of mass 69Mass 69 relative abundanceLess than 2.0% of mass 6925.0 - 75.0% Of mass 198Less than 1.0% of mass 198Base Peak, 100% relative abundance5.0 to 9.0% of mass 19810.0 - 30.0% of mass 198Greater than 0.75% of mass 198Present, but less than mass 44340.0 - 110.0% of mass 19815.0 - 24.0% of mass 442

% RELATIVEABUNDANCE

=:!£============

( )1

( )1

,

( )2

1-Value is % mass 69 2-Value is % mass 442

THIS TUNE APPLIES TO THE FOLLOWING SAMPLES, LCS, BLANKS, AND STANDARDS:

'01020304050607080910111213141516171819202122

EPASAMPLE NO.

LABSAMPLE ID

f

LABFILE ID

DATEANALYZED

TIMEANALYZED/

page _ of _ . FORM V LCSV 6/91

AR302738

6LCALOW CONC. WATER VOLATILE ORGANICS INITIAL CALIBRATION SUMMARY

Lab Name: _____ Contract:

Lab Code: _______ Case No.: ____ SAS No.: _____ SDG No.:

Instrument ID: _______ Calibration Date(s) :_______ _

LAB FILE ID: RRF1 -RRF5 - RRF10-

COMP9UND RRF1

ChloromethaneBromomethane *Vinyl chloride *ChloroethaneMethylene chlorideAcetoneCarbon disulfide1 , 1-Dichloroethene *1 , 1-Dichloroethane *cis-1, 2-Dichloroethenetrans-l , 2-DichloroetheneChloroform *1 , 2-Dichloroethane *2-ButanoneBromochloromethane *1,1, 1-Tr ichloroethane *Carbon tetrachloride *Bromodichloromethane *1 , 2-Dichloropropanecis-1, 3 -Dichloropropene *Trichloroethene *Dibromochloromethane *1, 1,2 -Tr ichloroethane *Benzene *trans-l, 3 -Dichloropropene *Bromoform " *4-Methyl-2-pentanone2-HexanoneTetrachloroethene *1,1,2,2-Tetrachloroethane *1 , 2 -Dibr omoethane *Toluene *Chlorobenzene *Ethylbenzene *Styrene *Xylenes (total) *1,3-Dichlorobenzene *1,4-Dichlorobenzene *l,2-Dichlorobenzene *1, 2-Dibromo-3-chloropropane

Bromofluorobenzene *

RRF2===«==

RRF2 -RRF25-

RRF5

* Compounds with required minimum RRF and maximumAll other compounds must meet a minimum RRF of 0

RRF10 RRF25 RRF%

RSDs===s

**

it*

**

44

—— IM_________——

4*

' 4444

44444444444

i

&RSD values..010. J

FORM VI LCV 6/91

AR302739

6LCBLOW CONC. WATER SEMIVOLATILE ORGANICS INITIAL CALIBRATION SUMMARY

Lab Name: Contract:__ ___


Instrument ID: _____._ Calibration Date(s):_______ _

Calibration Times: ___

LAB FILE ID: RRF5 -RRF20- RRF50-

COMPOUND RRF5

Phenol 'bis (2-Chloroethyl) ether2-Chlorophenol2-Methylphenol2,2' -oxybis ( 1-Chlbropropane)4-MethylphenolN-Nitroso-di-n-propylamineHexachloroethaneNitrobenzeneIsophorone2-Nitrophenol *2,4-Dimethylphenol *bis ( 2 -Chloroethoxy) methane *2,4-Dichlorophenol *1,2, 4-Trichlorobenze"ne" *Naphthalene *4-ChloroanilineHexachlorobutadiene4-Chloro-3-methylphenol *2-Methylnaphthalene *Hexachlorocyclopentadiene2,4, 6-Trichlorophenol *2,4, 5-Trichlorophenol *2-Chloronaphthalene2-NitroanilineDimethylphthalateAcenaphthylene *2,6-Dinitrotoluene *3-NitroanilineAcenaphthene *2 , 4-Dinitrophenbl4-NitrophenolDibenzofuran *2 , 4 -Dinitrotoluene *

RRF10

RRF:RRFi

RRF20

.0=JO-

RRF50

t

RRF80 RRF RSD

*"*"*.I

"*"*"*~4t~4t"*"*"4(~*"*

4t"*

* Compounds with required minimum RRF and maximum %RSD values.All other compounds must meet a minimum RRF of 0.010.

FORM VI LCSV-1 6/91

RR3027UO

6LCCLOW CONC. WATER SEMIVOLATILE ORGANICS INITIAL CALIBRATION SUMMARY

«

Lab Name: Contract:_________


Instrument ID: _______ Calibration Date(s) :_______ _

Calibration Times: _______

LAB FILE ID: RRF5 -RRF20= RRF50=

COMPOUND '

Diethylphthalate4-Chlorophenyl-phenylether *Fluor ene . *4-Nitroaniline4 , 6-Dinitro-2-methylphenolN-Nitrosodiphenylamine (1)4-Bromophenyl-phenylether *Hexachlorobenzene 'Pentachlorophenol *Phenanthrene 'Anthracene 'Di-n-butylphthalateFluoranthene 'Pyrene 'Butylberi'zylphthalate3,3' -Dichlorobenzidine -Benzo (a) anthracene . 'Chrysene 'bis(2-Ethylhexyl)phthalateDi-n-octylphthalateBenzo (b) f luoranthene 'Benzo (k) f luoranthene 'Benzo(a)pyrene 'Indeno(l,2,3-cd)pyrene 'Dibenz (a, h) anthracene 'Benzo (g,h,i)perylene '

Nitrobenzene-d52-Fluorobiphenyl 'Terphenyl-dl4 'Phenol-d5 '2-Fluorophenol '2,4, 6-Tribromophenol

RRF5

kk

kkkkk

kk

kk

kkkkkkii-SK—CK— £«

kkkk

RRF10

RRFJRRF£

RRF20

sss:s£S3--=-

LO-10=

RRF50

-:=KSKS9£

RRF80

Bssszssaca

RRF%

RSD

44

44444

.'

—————— I

144

*•i1•ii4

4444

Cannot be separated from Diphenylamine* Compounds with required minimum RRF and maximum %RSD values.All other compounds must meet a minimum RRF of 0.010.

FORM VI LCSV-2 6/91

ftR3027M

6LCDLOW CONC. WATER PESTICIDE INITIAL CALIBRATION OF SINGLE COMPONENT ANALYTES

iLab Name: Contract:________

Lab Code: __ Case No.: ____ SAS No.: _____ SDG No.:Instrument ID: _________ Level (x low) : low ____ mid ____ high

GC Column: _______ ID: ___(mm) Date(s) Analyzed: ______

COMPOUND

alpha-BHCbeta-BHCdelta-BHCgamma-BHC (Lindane)HeptachlorAldrinHeptachlor epoxideEndosulfan IDieldrin4,4'-DDEEndrinEndosulfan II4,4' -DDDEndosulfan sulfate4,4' -DDTMethoxychlorEndrin ketoneEndrin aldehydealpha-Chlordanegamma-Chlordane

Tetrachloro-m-xyleneDecachlorobiphenyl

RT 0]LOW

«===

' STAND;MID

======

IRDSHIGH

=====

MEANRT

======

RT W]FROM

======

ENDOWTO

—————

_B__;_S EC __;__;

* Surrogate retention times are measured from Ind. Mix A analyses.

Retention time windows are ±0.05 minutes for all compounds thatelute before Heptachlor epoxide, ±0.07 minutes for all othercompounds, except ±0.10 minutes for Decachlorobiphenyl.

FORM VI LCP-1 6/91

6LCELOW CONC. WATER PESTICIDE INITIAL CALIBRATION OF SINGLE COMPONENT ANALYTES

Lab Name: ___ Contract:____________

Lab Code: _____ Case No.: ____ SAS No.: _____ SDG No.:

Instrument ID: ________ Level (x low) : low ____ mid ____ high

GC Column: ________ ID: ____(mm) Date(s) Analyzed: ______

COMPOUND

alpha-BHCbeta-BHCdelta-BHCgamma-BBC (Lindane)HeptachlorAldrinHeptachlor epoxideEndosulfan IDieldrin4,4' -DDEEndrinEndosulfan -II4,4'-DDDEndosulfan sulfate4,4' -DDTMethoxychlorEndrin ketoneEndrin aldehydealpha-Chlordanegamma-Chlordane====================Tetrachloro-m-xyleneDecachlorobiphenyl

LOW

==========

CALIBRATICMID

==========

)N FACTORSHIGH

==========

MEAN

===========

%RSD

'======

* Surrogate calibration factors are measured from Ind. Mix A analyses.

%RSD must be less than or equal to 20.0% for all compounds, except thesurrogates, where %RSD must be less than or equal to 30.0%. Up to twotarget compounds, but not surrogates, may have %RSD greater than 20.0%,but less than or equal to 30.0%.

FORM VI LCP-2 6/91

AR3027l*3

6LCFLOW CONC. WATER PESTICIDE INITIAL CALIBRATION OF MULTICOMPONENT ANALYTES

Lab Name: Contract: ______Lab Code: _______ Case No.: _____ SAS No.: _____ SDG No.:

Instrument ID: _______ Date(s) Analyzed: ______ .

GC Column: .____ ID: ___(mm)

COMPOUND

Toxaphene

Aroclor 1016

Aroclor 1221

Aroclor 1232

Aroclor 1242

Aroclor 1248

Aroclor 1254

Aroclor 1260

AMOUNT(ng) PEAK

*1*2*345*1*2*345*1*2*345*1*2*345*1*2*345*1*2*345*1*2*345*1*2*345

RTRT W]FROM

[NDOWTO

CALIBRATIONFACTOR

-

•r

Denotes required peaks

FORM VI LCP-3 • 6/91

AR3027i*l*

6LCGLOW CONC. WATER PESTICIDE RESOLUTION CHECK SUMMARY

Lab Name: • Contract:

Lab Code: Case No.: ' SAS No.: _____ SDG No.

GC Column (1) : _______ ID: ___(mm) Instrument ID (1) :

EPA Sample No. (Standard 1): _______ Lab Sample ID (1):

Date Analyzed (1) : ________ Time Analyzed (1) :

010203040506070809

ANALYTE RTRESOLUTION

(*)

GC Column (2) : ________ ID: ___(mm) Instrument ID (2) :

EPA Sample No. (Standard 2): ________ Lab Sample ID (2):

Date Analyzed (2): ________ Time Analyzed (2):

010203040506070809

ANALYTE

,

RTRESOLUTION

(%)

Resolution of two adjacent peaks must be calculated as a percentage of theheight of the smaller peak, and must be greater than or equal to 60.0%.

FORM VI LCP-4 6/91

7LCALOW CONC. WATER VOLATILE ORGANICS CONTINUING CALIBRATION SUMMARY

Lab 'Name: _____ Contract:


Instrument ID: Calibration Date:______ Time:_

Lab File ID: ____;______ Init. Calib. Date(s) :

COMPOUND

ChloromethaneBromomethaneVinyl chlorideChloroethaneMethylene chlorideAcetoneCarbon disulfide1 , l-Dichloroethene1 , 1-Dichloroethanecis-1, 2-Dichloroethenetrans-l, 2-DichloroetheneChloroform1 , 2-Dichloroethane2-ButanoneBromochloromethane1,1, 1-Tr ichloroethaneCarbon tetrachlorideBr omodi ch lor omethane1 , 2 -Dichloropropanecis-1 , 3 -DichloropropeneTrichloroetheneDibromochloromethane1,1, 2-TrichloroethaneBenzenetrans-l, 3 -DichloropropeneBromoform4 -Methy 1 -2 -pentanone2-HexanoneTetrachloroethene1,1,2, 2-Tetrachloroethane1 , 2-DibromoethaneTolueneChlorobenzeneEthylbenzeneStyreneXylenes (total)1, 3-Dichlorobenzerie1, 4-Dichlorobenzene1 , 2-Dichlorobenzene1, 2-Dibromo-3-chloropro"pane_

Bromof luorobenzene

RRF

—____.=:——

RRF5

======

MINRRF

0.1000.100

0.1000.2000.100

0.2000.100

0.0500.1000.1000.200

0.2000.3000.1000.1000.5000.1000.050

0.2000.1000.1000.4000.5000.1000.3000.3000.6000.5000.400

0.200

%D

—_ i_SS.—__S

MAX%D

30.030.0

30.030.0

30.030.0

30.030.030.030.0

30.030.030.030.030.030.030.0

30.030.030.030.030.030.030.030.030.030.030.0

30.0

All other compounds must meet a minimum RRF of 0.010.

FORM VII LCV 6/91

7LCBLOW CONC. WATER SEMIVOLATILE ORGANICS CONTINUING CALIBRATION SUMMARY

Lab Name: • Contract:_____________

Lab Code: ______ Case No.: • SAS No.: _______ SDG No.:

Instrument ID: ________ Calibration Date:_______ Time:_

Lab File ID: __________ Init. Calib. Date(s):_________ __

Init. Calib. Times: ________

COMPOUND

Phenolbis (2-Chloroethyl) ether2-Chlorophenol2-Methylphenol2,2' -oxybis ( 1-Chloropropane )4 -Me thy Ipheno 1N-Nitroso-di-n-propylamineHexachloroethaneNitrobenzeneIsophorone2-Nitrophenol2 , 4-Dimethylphenolbis (2 -Chloroethoxy) methane2 , 4-Dichlorophenol1 , 2 , 4-TrichlorobenzeneNaphthalene4-ChloroanilineHexachlorobutadiene4 -Chloro-3 -methy Ipheno 12-HethylnaphthaleneHexachlorocyclopentadiene2,4, 6-Trichlorophenol2,4, 5-Trichlorophenol2 -Chloronaphthalene2-NitroanilineDimethylphthalateAcenaphthy lene2 , 6-Dinitrotoluene3 -NitroanilineAcenaphthene2 , 4-Dinitrophenol4-NitrophenolDibenzofuran2 , 4-Dinitrotbluene

RRF RRF20MINRRF

0.8000.7000.7000.700

0.6000.5000.3000.2000.4000.100.0.2000.3000.2000.2000.700

0.2000.400

0.2000.2000.800

1.3000.200

0.800

0.8000.200

%DMAX%D

25.025.025.025.0

25.025.025.025.025.025.025.025.025.025.025.0

25.025.0

25.025.025.0

25.025.0

25.0

25.025.0

All other compounds must meet a minumum RRF of 0.010.

FORM VII LCSV-1 6/91

AR3027U7

7LCCLOW CONC. WATER SEMIVOLATILE ORGANICS CONTINUING CALIBRATION SUMMARY

Lab Name: __ Contract:___________


Instrument ID: Calibration Date: Time:

Lab File ID: __________ Init. Calib. Date(s):.

Init. Calib. Times:

COMPOUND

Diethylphthalate4-Chlorophenyl-phenyletherFluorene4-Nitroaniline4 , 6-Dinitro-2-methylphenolN-Nitrosodiphenylamine (1)4 -Bromopheny 1 -phenyl etherHexachlorobenzenePentachlorophenolPhenanthreneAnthraceneDi-n-butylphtnai'ateFluoranthenePyreneButylbenzylphthalate3 , 3 '-DichlorobenzidirieBenzo (a) anthraceneChrysenebis (2-Ethylhexyl) phthalateDi-n-octylphthalateBenzo (b) f luorantheneBenzo (k) f luorantheneBenzo(a)pyreneIndeno (1,2, 3-cd) pyreneDibenz (a,h) anthraceneBenzo (g, h, i) perylene============================Nitrobenzene-d52 -Fluor obipheny 1Terphenyl-dl4Phenol-d5Fluorophenol2,4, 6-Tribromophenol

RRF

======

RRF20

======

MINRRF

0.4000.900

0.1000.1000.0500.7000.700

0.6000.600

0.8000.700

0.7000.7000.7000.5000.4000.500

0.0100.7000.5000.8000.600

%D

======

MAX%D

25.025.0

25.025.025.025.025.0

25.025.0

25.025.0

25.025.025.025.025.025.0

25.025.025.025.025.0

(1) Cannot be separated from DiphenylamineAll other compounds must meet a minimum RRF of 0.010.

FORM VII LCSV-2 6/91

AR3027I.-8

7 LCDLOW CONC. WATER PESTICIDE CALIBRATION VERIFICATION SUMMARY

Lab Name: Contract:

Lab Code: ______ Case No.: ____ SAS No.: _______ SDG No.

GC column: __________ ID: ___(mm) Init. Calib. Date(s):____

EPA Sample No.(PIBLK): ________ Date Analyzed :,

Lab Sample ID (PIBLK) :___________ Time Analyzed :_

EPA Sample No.(PEM): ________ Date Analyzed :_

Lab Sample ID (PEM):_________ Time Analyzed :

PEMCOMPOUND

alpha-BHCbeta-BHCgamma-BHC (Lindane)Endrin4,4' -DOTMethoxychlor

RTRT W]FROM

ENDOWTO

====:==

CALCAMOUNT(ng)

NOMAMOUNT(ng)========

%D

=====

4,4'-DDT % breakdown (1): ________ Endrin % breakdown (1): ______

Combined % breakdown (1) : _______

QC LIMITS:

Absolute values of %D of amounts in PEM must be less than or equal to25.0%

4,4'-DOT breakdown must be less than or equal to 20.0%

Endrin breakdown must be less .than or equal to 20.0%

Combined breakdown must be less than or equal to 30.0%

FORM VII LCP-1 6/91

. 7LCELOW CONC. WATER PESTICIDE CALIBRATION VERIFICATION SUMMARY

Lab Name: Contract:

Lab Code: Case No.: SAS No.: SDG No.:

GC Column: _____' ID: ___(mm) Init. Calib. Date(s):.EPA Sample No.(PIBLK): ________ Date Analyzed :.

Lab Sample ID (PIBLK): _________ Time Analyzed :.

EPA Sample No.(INDA): _______ Date Analyzed :

Lab Sample ID (INDA) : __________ Time Analyzed :.

INDIVIDUAL MIX ACOMPOUND

alpha-BHCgamma-BHC (Lindane)HeptachlorEndosulfan IDieldrinEndrin4,4' -DDD4,4' -DOTMethoxychlorTetrachloro-m-xyleneDecachlorobiphenyl

RTRT W]FROM

ENDOWTO

CALCAMOUNT

(ng)

NOMAMOUNT

(ng)%D

-

t

EPA Sample No.(INDB): ________ . Date Analyzed :

Lab Sample ID (INDB) : _________ Time Analyzed :

INDIVIDUAL MIX BCOMPOUND

beta-BHCdelta-BHCAldrinHeptachlor epoxide4,4' -DDEEndosulfan IIEndosulfan sulfateEndrin ketoneEnrin aldehydealpha-Chlordanegamma-ChlorodaneTetrachloro-m-xyleneDecachlorobiphenyl

RT. RT W]FROM

======

ENDOWTO

v

CALCAMOUNT

(ng)========

NOMAMOUNT

(ng)==j=: -===:=:=

i

%D

QC LIMITS: Absolute value of %D of amounts in the Individual Mixes must beless than or equal to 25.0%.

FORM VII LCP-2 .' 6/9l'

AR3G275Q

8LCALOW CONC. WATER VOLATILE INTERNAL STANDARD AREA AND RT SUMMARY

Lab Name: _____ Contract:


Lab File ID (Standard) : ___________ Date Analyzed:_

Instrument ID: _______ Time Analyzed:_

GC Column: _______ ID: ___(mm)

01020304050607080910111213141516171819202122

12 HOUR STDUPPER LIMITLOWER LIMITGZ====3=S!3====

EPA SAMPLENO.

ISl (CBZ)AREA t RT #

IS2(DFB)AREA # RT #

=======

IS3(DCB)AREA #

=======0===

.

RT f

s-ss-s-s-ss:

ISl (CBZ) - Chlorobenzene-d5IS2 (DFB) s 1,4-DifluorobenzeneIS3 (DCB) « l,4-Dichlorobenzene-d4

AREA UPPER LIMIT - +40% of internal standard area.AREA LOWER LIMIT - -40% of internal standard area.RT UPPER LIMIT - +0.33 minutes of internal standard RT.RT LOWER LIMIT - -0.33 minutes of internal standard RT.

# Column used to flag internal standard area and RT values with an asterisk* Values outside of QC limits.

page _ of _FORM VIII LCV 6/91

RR30275

8LCBLOW CONC. WATER SEMIVOLATILE INTERNAL STANDARD AREA AND RT SUMMARY

Lab Name: Contract:_________


Lab File ID (Standard): __________ Date Analyzed:_

Instrument ID: ________ Time Analyzed:

01020304050607080910111213141516171819202122

•

12 HOUR STDUPPER LIMITLOWER LIMIT

EPA SAMPLENO.

ISl (DCB)AREA t

'

RT #IS2 (NPT)AREA t RT f

IS3(ANT)AREA # RT #

ISl (DCB) - l,4-Dichlorobenzene-d4IS2 (NPT) - Naphthalene-d8IS3 (ANT) = Acenaphthene-dlO

AREA UPPER LIMIT - +100% of internal standard area.AREA LOWER LIMIT = -50% of internal standard area.RT UPPER LIMIT « +0.33 minutes of internal standard RT.RT LOWER-LIMIT = -0.33 minutes of internal standard RT.

# Column used to flag internal standard area and RT values with an asterisk.* Values outside of QC limits.

page _ of _FORM VIII LCSV-1 6/91

AR3Q2752

8LCCLOW CONC. WATER SEMIVOLATILE INTERNAL STANDARD AREA AND RT SUMMARY

Lab Name: Contract:

Lab Code: ______ Case No.: _____ SAS No.: _____ SDG No.:

Lab File ID (Standard) : _____________ Date Analyzed:_

Instrument ID: __________ Time Analyzed:_

01020304050607080910111213141516171819202122

12 HOUR STDUPPER LIMITLOWER LIMIT

EPA SAMPLENO.

IS4(PHN)AREA t

•cw :xmK»K-iKKm

RT fISS(CRY)AREA t RT f

.

IS6(PRY)AREA t RT f

IS4 (PHN) » Phenanthrene-dlOIS5 (CRY) - Chrysene-dl2IS6 (PRY) - Perylene-dl2

AREA UPPER LIMIT » +100% of internal standard area.AREA LOWER LIMIT * -50% of internal standard area.RT UPPER LIMIT - +0.33 minutes of internal standard RT.RT LOWER LIMIT - -0.33 minutes of internal standard RT.

# Column used to flag internal standard area and RT values with an asterisk.* Values outisde of QC limits.

page _ of _FORM VIII LCSV-2 6/91

6R302753

8LCDLOW CONC. WATER PESTICIDE ANALYTICAL SEQUENCE

Lab Name: _____> . Contract:________

Lab Code: , Case No.: ____ SAS No.: _____ SDG No.: _____

GC Column: ________ ID: ____(mm) Init. Calib. Date(s):______ __

Instrument ID: _______THE ANALYTICAL SEQUENCE OF PERFORMANCE EVALUATION MIXTURES, BLANKS,

SAMPLES, AND STANDARDS IS GIVEN BELOWi

0102030405060708091011121314151617.181920212223242526272829303132

MEAN SURRO(TCX:

EPASAMPLE NO.

*

SATE RT FROM ]DCB:

LABSAMPLE ID

CNITIAL CAL]

DATEANALYZED

CBRATION

TIMEANALYZED

TCXRT #

DCBRT #

QC LIMITSTCX - Tetrachloro-m-xylene ( + 0.05 MINUTES)DCB = Decachlorobiphenyl (± 0.10 MINUTES)

# Column used to flag 'retention time values with an asterisk.* Values outside of QC limits.

page _ of _ 'FORM VIII LCP " 6/91

flR30275i*

9LCALOW CONC. WATER PESTICIDE FLORISIL CARTRIDGE CHECK

Lab Name: Contract:


Florisil Cartridge Lot Number: ________ Date Analyzed: _____

GC Column(l): ________ ID: ____(mm) GC Column(2): __________ ID: ____(nun)

COMPOUND

alpha-BHCgamma -BHCHeptachlorEndosulfan IDieldrinEndrin4,4' -DDD4,4' -DOTMethoxychlorTetrachloro-m-xyleneDecachlorobiphenyl

SPIKEADDED

(ng)

SPIKERECOVERED

(ng)%REC #

QCLIMITS

80-12080-12080-12080-12080-12080-12080-12080-12080-12080-12080-120

# Column to be used to flag recovery with an asterisk* Values outside of QC limits

*

THIS CARTRIDGE LOT APPLIES TO THE FOLLOWING SAMPLES, BLANKS, AND LCS:

0102030405060708091011121314151617181920212223

EPASAMPLE NO.

LABSAMPLE ID

DATEANALYZED 1

DATEANALYZED 2

page _ of _FORM IX LCP 6/91

RR302755

10LCA EPA SAMPLE NO.LOW CONC. WATER PESTICIDE IDENTIFICATION SUMMARY

FOR SINGLE COMPONENT ANALYTES

Lab Name: ___ Contract:

Lab Code: Case No.: SAS No.: _____ SDG No.:Lab Sample ID : ______' Date(s) Analyzed:

Instrument ID (1): _______ Instrument ID (2):

GC column(l): _______ ID: ___(mm) GC column(2): _______ ID: ___(mm)

ANALYTE

.

t

COL

1

2

1

2

1

2

1

2

1

2

1

2

1

2

1

2

RTRT W]FROM'

ENDOWTO CONCENTRATION %D

page _ of _FORM X LCP-1 6/91

AR302756

10LCB EPA SAMPLE NO.LOW CONC. WATER PESTICIDE IDENTIFICATION SUMMARY

FOR MULTICOMPONENT ANALYTES

Lab Name:__ j Contract:

Lab Code: ______ Case No.: • SAS No.: _____ SDG No.:

Lab Sample ID : _________ Date(s) Analyzed: _____

Instrument ID (1): _______ Instrument ID (2): ____

GC Column(l): ________ ID: ____(mm) GC Column(2): ___________ ID: ____(mm)

ANALYTE

COLUMN 1

COLUMN 2

COLUMN 1

COLUMN 2

COLUMN 1

COLUMN 2

PEAK

*1*2*345

*1*2*345

*1*2*345

*1*2*345

*1*2*345

*1*2*345

RT

=*=:i==3:=-

--,__, SB

t

RT W]FROM

ssssssssss

__.__.__, at.__ «.

:NDOWTO

======

======

CONCENTRATION

============

= — =

MEANCONCENTRATION

•

=============

=============

1%D

====== 1

1

At least 3 peaks are required for identification of multicomponent analytespage _ of _

FORM X LCP-2 6/91

RR302757

SAMPLE LOG-IN SHEET

Lab Name: Page , of———————————— 1 ———————————————————————— . ——————————————— — ———————————————— : ———

Received By (Print Name): „,.._. ,,., , Log-jnDaie:

Received By (Signature):

Case Number:

Simple DeliveryGroup No.:

SAS Number:

REMARKS:

I . Custody Seal(s) Presenl/Abient"1InUct/Broken

2 Custody Seal No< •

3 . Cbaim-of -Custody Present/Absent*Records

4. Tnffic Reports or Present/ Absent"Packing List ' ' ~

S. Airbill Airbill/StickerPresent/Absent* •

6. AiibillNo.:

7. Sample Tags Present/Absent*

Sample Tag Luted/Not LutedNumber* on Chiin-of-

Cuxtody

8. Sample Condition: Intact/Broken*/Leaking

9. Does information oncustody records, trafficreports, and sampleugs agree? Yes/No*

10. Date Received at Lab:

1 1 . Time Received:

Sample Transfer

By: ————————— —————————

°~

EPASAMPLE

*

CORRESPONDING

SAMPLETAG*

ASSIGNEDLAB#

REMARKS:CONDITIONOF SAMPLE

SHIPMENT, ETC.

'

'

* Contact SMO and attach record of resolutionReviewed By: ____________________ Logbook No.: —Date: __________________________ Logbook Page No:

FORM DC-1

AR302758

LOW COHCENTRATION WATER FOR ORGANICS COMPLETE SDG FILE (CSF) INVENTORY SHEET

LABORATORY NAME _____ _______________ CITY/STATE

CASE MO. __________ SOG NO. _______ SOG "OS. TO FOLLOW ________ __________ _________ SASHO. _______

CONTRACT MO. _____________________________________ SOU MO.

All documents delivered in the complete SDG file must be original documentswhere possible. (REFERENCE EXHIBIT B, SECTION II, PARAGRAPH 5, and SECTION III,PARAGRAPH 16.)

PAGE NOs CHECKFROM TO LAB EPA

1. ImrantorY 8h«-t (Form DC-2) (Do not number)2. SDG Case Narrative3. Traffic Report4. Volatile* Qata

a. QC SummarySurrogate Percent Recovery Summary (Form II LCV)Lab Control Sample Recovery (From III LCV)Method Blank Summary (Form IV LCV)Tuning and Mass Calibration (Form V LCV)

b. Sample DataTCL Results - (Form I LCV)Tentatively Identified Compounds (Form I LCV-TIC)Reconstructed total ion chromatograms (RIC)and Quantitation Reports for each sample

For each sample:Raw spectra and background-subtractedmass spectra of target compounds identified

Mass spectra of all reported TICs with threebest library matches

c. Standards Data (All Instruments)Initial Calibration Summary (Form VI LCV)RICs and Quan Reports for all StandardsContinuing Calibration (Form VII LCV)RICs and Quant Reports for all StandardsInternal Standard Area and RT Summary(Form VIII LCV)

d. QC DataBFBBlank DataLCS DataFES Data

5. Sc«iTQl-t.ile« Dataa. QC Summary

Surrogate Percent Recovery Summary (Form II LCSV)Lab Control Sample Recovery (Form III LCSV)Method Blank Summary (Form IV LCSV)Tuning and Mass Calibration (Form V LCSV)

FORM DC-2-1

AR3027596/91 I

LCW CONCENTRATION WATER FOR ORGANICS COMPLETE SDG FILE (CSF) INVENTORY SHEET (Coat.)

CASE NO. • SOG MO. ______ SDG NOS. TO FOLLOW ______ _______ ______ SAS NO.

PAGE NOs . CHECKFROM TO , LAB EPA

5. SemiTol«tila« Data (cont.)

b. Sample Data ___TCL Results (Form I LCSV)Tentatively Identified Compounds (Form I LCSV-TIC)Reconstructed total ion chromatograms (RIC)and Quantitation Reports for each sample

For each sample:Raw spectra and background-subtractedmass spectra of TCL compounds

Mass spectra of TICs with three best library matchesGPC chromatograms (if GPC performed)

c. Standards Data (All Instruments)Initial Calibration Summary (Form VI LCSV)RICs and Quan Reports for all StandardsContinuing Calibration (Form VII LCSV)RICs and Quan Reports for all Standards . .Internal Standard Area and RT Summary(Form VIII LCSV)

d. QC DataDFTPPBlank DataLCS DataFES Data

6. Pesticides

a. QC SummarySurrogate Percent Recovery Summary (Form II LCP)Lab Control Sample Recovery (Form III LCP)Method Blank Summary (Form IV LCP)

b. Sample DataTCL Results - Organic Analysis Data Sheet(Form I LCP)

Chromatograms (Primary Column)Chromatograms from second GC column confirmationGC Integration report or data system printout andcalibration plots

Manual work sheetsFor pesticides/Aroclors confirmed by GC/MS, copiesof raw spectra and copies of background-subtracted massspectra of target compounds (samples & standards)

FORM DC-2-2

4R302760 6/91

LOW CONCENTRATION WATER FOR ORGANICS COMPLETE SDG FILE (CSF) INVENTORY SHEET (Coat.)

CASE MO. _______ SOG MO. ______ SOG NOS. TO FOLLOW _______ _______ ______ SAS M0-

PAGE NOs CHECKFROM TO LAB EPA

6. Pesticides (cont.)

c. Standards DataInitial Calibration Data (Form VI LCP)Calibration Verification (Form VII LCP)Pesticides Analytical Sequence (Form VIII,LCP-1 and -2)

PesticideFlorisil Cartridge Check (Form IX, LCP)Pesticide Identification (Form X LCP)Standard chromato.grams and data system printoutfor all Standards

For pesticides/Aroclors confirmed by GC/MS, copiesof spectra for standards used

d. QC DataBlank DataLCS DataPES Data

7 • Miscellaneous Data

Original preparation and analysis forms or copies ofpreparation and analysis logbook pages

Internal sample and sample extract transferchain-of-custody records

Screening recordsAll instrument output, including strip chartsfrom screening activities (describe or list)

8. EPA Shipping/Receiving Document*

Airbills (No. of shipments __)Chain-of-Custody RecordsSample TagsSample Log-In Sheet (Lab & DC1)SDG Cover SheetMiscellaneous Shipping/Receiving Records

(describe or list)

9. Internal Lab Sajapln Transfer Records and Tracking Sheets(describe or list)

FORM DC-2-3

6/91

LOW CONCENTRATION WATER FOR ORGANICS COMPLETE SDG FILE (CSF) INVENTORY SHEET (Cent.)

CASE NO. ________ SOG NO. ________ SOG NOS. TO FOLLOW _______ ________ _______ SAS NO.

11.

Completed by:

PAGE NOS CHECKFROM TO LAB EPA

10. Other Records (describe or list)\

Telephone Communication Log __ __ ___ __

(CLP Lab) (Signature) (Printed Name/Title) (Date)

Audited by: ________________- _________________________ _______(EPA) (Signature) (Printed Name/Title) (Date)

FORM DC-2-4 ;'

AH302762 6/91

EXHIBIT C

TARGET COMPOUND LIST (TCL) ANDCONTRACT REQUIRED QUANTITATION LIMITS (CRQLs)

NOTE: The values in these tables are quantitation limits, not absolutedetection limits. The amount of material necessary to produce adetector response that can be identified and reliably quantified isgreater than that needed to simply be detected above the background

. noise. Except as noted, the quantitation limits in these tables areset at the concentrations in the sample equivalent to theconcentration of the lowest calibration standard analyzed for eachanalyte .

6/91

&R302763

TARGET COMPOUND LIST (TCL) ANDCONTRACT REQUIRED QUANTITATION LIMITS (CRQL)

Quantitation LimitsWater

_______Volatiles________________CAS Number__________ug/L_________

1. Chloromethane 74-87-3 , 12. Bromomethane 74-83-9 13. Vinyl chloride 75-01-4 14. Chloroethane 75-00-3 15. Methylene chloride 75-09-2 , 2

6. Acetone • 67-64-1 ' 57. Carbon disulfide 75-15-0 18. 1,1-Dichloroethene 75-35-4 19. 1,1-Dichloroethane 75-34O 110. cis-1,2-Dichloroethene 156-59-4 1 '

11. trans-l,2-Dichloroethene 156-60-5 112. Chloroform 67-66-3 113. 1,2-Dichloroethane 107-06-2 114. 2-Butanone 78-93-3 515. Bromochloromethane 74-97-5 * 1

16. 1,1,1-Trichloroethane 71-55-6 117. Carbon Tetrachloride 56-23-5 118. Bromodichloromethane 75-27-4 119. 1,2-Dichloropropane 78-87-5 1

20. cis-1,3-Dichloropropene 10061-01-5 121.' Trichloroethene 79-01-6 122. Dibromochloromethane 124-48-1 123. 1,1,2-Trichloroethane 79-00-5 124. Benzene 71-43-2 1

25. trans-l,3-Dichloropropene 10061-02-6 126. Bromoform 75-25-2 127. 4-Methyl-2-pentanone 108-10-1 528. 2-Hexanone 591-78-6 " 529. Tetrachloroethene 127-18-4 1

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TARGET COMPOUND LIST (TCL) ANDCONTRACT REQUIRED QUANTITATION LIMITS (CRQL)

(CONT'D.)Quantitation Limits

ffater_________Volatiles______________CAS Number____;______ug/L_______

30. 1,1,2,2-Tetrachloroethane 79-34-5 131. 1,2-Dibromoethane 106-93-4 132. Toluene 108-88-3 133. Chlorobenzene 108-90-7 134. Ethylbenzene 100-41-4 1

35. Styrene 100-42-5 136. Xylenes (total) 1330-20-7 137. 1,3-Dichlorobenzene 541-73-1 138. 1,4-Dichlorobenzene 106-46-7 139. 1,2-Dichlorobenzene 95-50-1 1

40. l,2-Dibromo-3-chloropropane 96-12-8 1

NOTE: Except for Methylene chloride, the quantitation limits in this tableare set at the concentrations in the sample equivalent to theconcentration of the lowest calibration standard analyzed for eachanalyte.

In the case of Methylene chloride, the CRQL value in this table isbased on the lowest level of detection in samples contaminated withthis common laboratory solvent that can be achieved by reasonablemeans in a production laboratory.

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TARGET COMPOUND LIST (TCL) ANDCONTRACT REQUIRED OUANTITATION LIMITS (CROP

(CONT'D.)

Quantitation LimitsWater '

Semivolatiles CAS Number

1. Phenol 108-95-2 52. bis-(2-Chloroethyl)ether 111-44-4 53. 2-Chlorophenol 95-57-8 54. 2-Methylphenol 95-48-7 5

5. 2,2'-oxybis(l-Chloropropane) 108-60-1 56. 4-Methylphenol 106-44-5 57. N-Nitroso-di-n-propylamine 621-64-7 58. Hexachloroethane 67-72-1 59. Nitrobenzene 98-95-3 5

10. Isophorone - 78-59-1 511. 2-Nitrophenol 88-75-5 512. 2,4-Dimethylphenol 105-67-9 , 513. bis-(2-Chloroethoxy)methane 11-91-1 . 5

14. 2,4-Dichlorophenol 120-83-2 515. 1,2,4-Trichlorobenzene 120-82-1 516. Naphthalene 91-20-3 517. 4-Chloroaniline 106-47-8 518. Hexachlorobutadiene 87-68-3 5

19. 4-Chloro-3-methylphenol 59-50-7 520. 2-Methylnaphthalene 91-57-6 521. Hexachlorocyclopentadiene 77.47-4 • 522. 2,4,6-Trichlorophenol '88-06-2 523. 2 ,4, 5-Trichlorophenol 95-95-4 20

24. 2-Chloronaphthalene 91-58-7 525. 2-Nitroaniline 88-74-4 • 2026. Dime thy Iphthalate 131-11-3 527. Acenaphthylene 208-96-8 528. 2,6-Dinitrotoluene 606-20-2 5

29. 3-Nitroaniline 99-09-2 2030. Acenaphthene . 83-32-9 531. 2,4-Dinitrophenol 51-28-5 2032. 4-Nitrophenol 100-02-7 2033. Dibenzofuran 132-64-9 5

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TARGET COMPOUND LIST (TCL) ANDj CONTRACT REQUIRED QUANTITATION LIMITS (CRQL)

(CONT'D.)Quantitation Limits

Water___Semivolatiles______________CAS Number__________ug/L________

34. 2,4-Dinitrotoluene 121-14-2 535. Diethylphthalate 84-66-2 536. 4-Chlorophenyl-phenylether 7005-72-3 537. Fluorene 86-73-7 538. 4-Nitroaniline 100-01-6 20

39. 4,6-Binitro-2-methylphenol 534-52-1 2040. N-Nitrosodiphenylamine 86-30-6 541. 4-Bromophenyl-phenylether 101-55-3 542. Hexachlorobenzene .118-74-1 543. Pentachlorophenol 87-86-5 20

44. Phenanthrene 85-01-8 545. Anthracene 120-12-7 546. Di-n-butylphthalate 84-74-2 547. Fluoranthene 206-44-0 548. Pyrene 129-00-0 5

49. Butylbenzylphthalate 85-68-7 550. 3,3'-Dichlorobenzidine 91-94-1 551. Benzo(a)anthracene 56-55-3 552. Chrysene 218-01-9 553. bis-(2-Ethylhexyl)phthalate 117-81-7 5

54. Di-n-octylphthalate 117-84-0 555. Benzo(b)fluoranthene 205-99-2 556. Benzo(k)fluoranthene 207-08-9 557. Benzo(a)pyrene 50-32-8 558. Indeno(l,2,3-cd)pyrene 193-39-5 5

59. Dibenz(a,h)anthracene 53-70-3 560. Benzo(g,h,i)perylene 191-24-2 5

RR302767

TARGET COMPOUND LIST (TCL) ANDi CONTRACT REQUIRED QUANTITATION LIMITS (CRQL)

(CONT'D.)

Quantitation LimitsWater

Pesticides/PCBs_________________ CAS Number________ ug/L_______

1. alpha-BHC 319-84-6 0.012. beta-BHC 319-85-7 0.013. delta-BHC 319-36-8 0.014. gamma-BBC (Lindane) 58-89-9 0.015. Heptachlor 76-44-8 0.01

6. Aldrin 309-00-2 0.017. Heptachlor epoxide 1024-57-3 0.018. Endosulfan I 959-98-8 0.019. Dieldrin 60-57-1 0.0210. 4,4'-DDE 72-55-9 0.02

11. Endrin 72-20-8 0.0212. Endosulfan II . 33213-65-9 0.0213. 4,4'-DDD 72-54-8 0.0214. Endosulfan sulfate 1031-07-8 0.0215. 4,4'-DDT 50-29-3 0.02

16. Methoxychlor 72-43-5 0.1017. Endrin ketone 53494-70-5 0.0218. Endrin aldehyde 7421-36-3 0.0219. alpha-Chlordane 5103-71-9 0.0120. gamma-Chlordane 5103-74-2 0.01

21. Toxaphene 8001-35-2 1.022. Aroclor-1016 12674-11-2 0.2023. Aroclor-1221 11104-28-2 0.4024. Aroclor-1232 11141-16-5 0.2025. Aroclor-1242 • 53469-21-9 0.20

26. Aroclor-1248 12672-29-6 0.2027. Aroclor-1254 11097-69-1 0.2028. Aroclor-1260 11096-82-5 0.20

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SR302768

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