chemistry, electrolysis (iva kubištová)

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1 Chemistry, Electrolysis (Iva Kubištová) Time 90 min Topic experimental study of electrolysis Lesson goals Students (16 – 18) via experimental methods learn principle of electrolysis. They will improve their experimental skills. Whole task first Usually, in lab works the students get only an exact list of instructions, what to do. In this laboratory work they get at first the main question, than they have to explain principle of it. The question is : What is principle your experiment? The students can choose easy task (Task one), midly easy task (Task two) or difficult task (Task three). They will have a manual for experiments and after execution groups need find their own and then common principle of it. Task one (SIMPLE ELECTRICAL CELL) Student use mold making ice, zinc galvanized nails, Cu wires and LED diode for construction simple electrical cell. MANUAL for SIMPLE ELECTRICAL CELL Materials mold making ice with separate spaces for water 7 or more zinc galvanized nails (about 6 cm long) 7 or more Cu wires (about 6 cm long) 5 % solution NaCl LED diode Procedure 1. Prepare nails and wires as is in the picture below. 2. Pour NaCl solution (5g of NaCl in 95mL of water) into shapes in mold making ice. 3. Place nails and wires as is in picture below. 4. Connect LED diode as is in picture. 5. Explain, what was happen.

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Page 1: Chemistry, Electrolysis (Iva Kubištová)

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Chemistry,Electrolysis(IvaKubištová)Time90minTopicexperimentalstudyofelectrolysisLessongoalsStudents(16–18)viaexperimentalmethodslearnprincipleofelectrolysis.Theywillimprovetheirexperimentalskills.Wholetaskfirst

Usually,inlabworksthestudentsgetonlyanexactlistofinstructions,whattodo.Inthislaboratoryworktheygetatfirstthemainquestion,thantheyhavetoexplainprincipleofit.Thequestionis:Whatisprincipleyourexperiment?Thestudentscanchooseeasytask(Taskone),midlyeasytask(Tasktwo)ordifficulttask(Taskthree).Theywillhaveamanualforexperimentsandafterexecutiongroupsneedfindtheirownandthencommonprincipleofit.

Taskone(SIMPLEELECTRICALCELL)Studentusemoldmakingice,zincgalvanizednails,CuwiresandLEDdiodeforconstructionsimpleelectricalcell.MANUALforSIMPLEELECTRICALCELL

Materials

• moldmakingicewithseparatespacesforwater• 7ormorezincgalvanizednails(about6cmlong)• 7ormoreCuwires(about6cmlong)• 5%solutionNaCl• LEDdiode

Procedure

1. Preparenailsandwiresasisinthepicturebelow.2. PourNaClsolution(5gofNaClin95mLofwater)intoshapesinmoldmakingice.3. Placenailsandwiresasisinpicturebelow.4. ConnectLEDdiodeasisinpicture.5. Explain,whatwashappen.

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moreonlink:

https://nationalmaglab.org/education/magnet-academy/watch-play/interactive/simple-electrical-cell

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Tasktwo(VOLTAGEINPOTATO)Studentusepotatoestocreatevoltage.MANUALforVOLTAGEINPOTATO

Materials

• afreshpotato• aselectrodetwononfatnails,Alligatorclips/Leads,9Vbattery• 20%solutionKI

Procedure

1. Takeapotatoandmakeholewithnonfatnails(about2,5cmdeep).2. PourKIsolution(20gofKIin80mLofwater)intoholes.3. PlacetwoelectrodesandconnectAlligatorclips/Leadsand9Vbattery.4. Disconnectitandcutpotatoasinthepictureafter15minutes.5. Surroundingsofoneelectrodeisblue.6. Putphenolphthaleinnearsecondelectrode.7. Explain,whatwashappeninpotatoafterconnectingandafter15minutes?

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Taskthree(TINMAN)Electrolysisof tin(II) chloridegrowabeautiful “tin-man”crystal treeby runninganelectric currentthroughasolutionoftin(II)chloride.MANUALforTINMAN

Materials

• Tin(II)chloride,SnCl2,5g• Water,distilledordeionized,100mL• Petridish,Beaker250-mL• Supportstand,funnelandfilterflask,filterpaper• Battery,9-V,Batterycapwithalligatorclip,leads• Paperclips,small,2

Procedure

1. AttachtwopapersclipstooppositesidesofacleanglassPetridish.Besurethelongendsofthepaperclipsareontheinsideofthedish,nearlytouchingthebottom.

2. Dissolve5goftin(II)chloridein100mLofdistilledordeionizedwaterina250-mLbeaker. 3. Filterthetin(II)chloridesolutionandallowtheliquidtodripintothePetridish. 4. CollectenoughliquidtojustcoverthebottomofthePetridish.Attachthealligatorclipsfromthe

9-Vbatterycaptoeachpaperclip. 5. Hookthebatterycaptothe9-Vbatteryandobservethechangesattheanodeandthecathode.A

milkywhiteprecipitateoftin(IV)chlorideappearsattheanodeandmetallictin(0)crystalsformatthecathode.

6. Allowthecurrenttorunforapproximatelyoneminutetoseethecontinuedgrowth.Thetin(0)crystalsformfeatherlikeprojectionsandgrowacrossthedish.

7. Explain,whatwashappen.

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Allprocedure(andmore)youcanseeonlink:https://www.flinnsci.com/api/library/Download/2a738661a20c47b6a1d9f28fc30735be

CunclusionofwholelessonAllstudentareworkingingroups,andcomparingtheirresults.Theteacherhelpstofinishtheformulas.Notesforteachers:

Teachercanusedtheseexperimentsfornexttermsornames:wetcell,voltaic(orgalvanic)electricalcell,electrochemistry,LuigiGalvani,AlessandroVolta,battery,electrolyte,redoxprocesses(oxidation,reduction), potential (voltage) difference, circuit, flowof electrons, flowof ions, electrode (anode,cathode),conductionofelectricity(polarization),ioniccurrent

Sourceofpicturesauthor