chemistry (chapters 2 – 5)

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Chemistry (Chapters 2 – 5)

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Page 1: Chemistry (Chapters 2 – 5)

Chemistry (Chapters 2 – 5)

Page 2: Chemistry (Chapters 2 – 5)
Page 3: Chemistry (Chapters 2 – 5)
Page 4: Chemistry (Chapters 2 – 5)

neutroncharge: Ømass: 1 amu (or dalton)

protoncharge: +mass: 1 amu (or dalton)

electron (e-)charge: -mass: “0” amu (or dalton)

Page 5: Chemistry (Chapters 2 – 5)

8

16 atomicsymbol

atomic mass(amu or dalton)

atomicnumber

2numberof atoms

Page 6: Chemistry (Chapters 2 – 5)

Mg12

24

N7

14

Na11

22

C6

12

Page 7: Chemistry (Chapters 2 – 5)

C6

11

C6

12

C6

14

isotopes (“iso” = same; “tope” = atom)

radioisotope

Page 8: Chemistry (Chapters 2 – 5)

shells and orbitals . . .

Page 9: Chemistry (Chapters 2 – 5)

shells and energy . . .

Page 10: Chemistry (Chapters 2 – 5)

3 types of chemical bonding(remember atoms “want” 8 e- in their outer most shells)

Page 11: Chemistry (Chapters 2 – 5)

oxidizedred

uced

Page 12: Chemistry (Chapters 2 – 5)
Page 13: Chemistry (Chapters 2 – 5)

3 types of chemical bonding

(“co” = share; “valent” = electron)

Page 14: Chemistry (Chapters 2 – 5)
Page 15: Chemistry (Chapters 2 – 5)
Page 16: Chemistry (Chapters 2 – 5)
Page 17: Chemistry (Chapters 2 – 5)

3 types of chemical bonding

Page 18: Chemistry (Chapters 2 – 5)
Page 19: Chemistry (Chapters 2 – 5)
Page 20: Chemistry (Chapters 2 – 5)

Water and its properties . . .

Page 21: Chemistry (Chapters 2 – 5)

a) universal solvent

b) cohesive molecules

c) stability of temperature and state

d) ice floats

Page 22: Chemistry (Chapters 2 – 5)

universal solvent. . .

Page 23: Chemistry (Chapters 2 – 5)

a) universal solvent

b) cohesive molecules

c) stability of temperature and state

d) ice floats

Page 24: Chemistry (Chapters 2 – 5)
Page 25: Chemistry (Chapters 2 – 5)

a) universal solvent

b) cohesive molecules

c) stability of temperature and state

d) ice floats

Page 26: Chemistry (Chapters 2 – 5)

statesof matter

solid liquid gas

density

high medium low

540 c

alorie

s / gra

m

80 ca

lories

/ gram

Page 27: Chemistry (Chapters 2 – 5)

a) universal solvent

b) cohesive molecules

c) stability of temperature and state

d) ice floats

Page 28: Chemistry (Chapters 2 – 5)

frozenwater (ice)

frozenbenzene

Page 29: Chemistry (Chapters 2 – 5)
Page 30: Chemistry (Chapters 2 – 5)

Density of water

0.00060.0

0.2

0.4

0.6

0.8

1.0

1.2

0 4 20 40 60 80 100

Temperature (C)

Den

sity

(g/m

l)

gas(steam)

Page 31: Chemistry (Chapters 2 – 5)

Density of water

0.9718

0.00060.0

0.2

0.4

0.6

0.8

1.0

1.2

0 4 20 40 60 80 100

Temperature (C)

Den

sity

(g/m

l)

gas(steam)

Page 32: Chemistry (Chapters 2 – 5)

Density of water

0.9832 0.9718

0.00060.0

0.2

0.4

0.6

0.8

1.0

1.2

0 4 20 40 60 80 100

Temperature (C)

Den

sity

(g/m

l)

gas(steam)

Page 33: Chemistry (Chapters 2 – 5)

Density of water

0.9922 0.9832 0.9718

0.00060.0

0.2

0.4

0.6

0.8

1.0

1.2

0 4 20 40 60 80 100

Temperature (C)

Den

sity

(g/m

l)

gas(steam)

Page 34: Chemistry (Chapters 2 – 5)

Density of water

0.9982 0.9922 0.9832 0.9718

0.00060.0

0.2

0.4

0.6

0.8

1.0

1.2

0 4 20 40 60 80 100

Temperature (C)

Den

sity

(g/m

l)

gas(steam)

Page 35: Chemistry (Chapters 2 – 5)

Density of water

1.0000 0.9982 0.9922 0.9832 0.9718

0.00060.0

0.2

0.4

0.6

0.8

1.0

1.2

0 4 20 40 60 80 100

Temperature (C)

Den

sity

(g/m

l)

gas(steam)

gas(steam)

liquid(water)

Page 36: Chemistry (Chapters 2 – 5)

Density of water

1.0000 0.9982 0.9922 0.9832 0.9718

0.00060.0

0.2

0.4

0.6

0.8

1.0

1.2

0 4 20 40 60 80 100

Temperature (C)

Den

sity

(g/m

l)

solid water (ice)denser than liquid

water

therefore, itsinks

gas(steam)

liquid(water)

Page 37: Chemistry (Chapters 2 – 5)

Density of water

0.91501.0000 0.9982 0.9922 0.9832 0.9718

0.00060.0

0.2

0.4

0.6

0.8

1.0

1.2

0 4 20 40 60 80 100

Temperature (C)

Den

sity

(g/m

l)

solid(ice) liquid

(water)

gas(steam)

solid water (ice) isactually less

dense than liquidwater

therefore, itfloats!

Page 38: Chemistry (Chapters 2 – 5)
Page 39: Chemistry (Chapters 2 – 5)

dissociation of water . . .

Page 40: Chemistry (Chapters 2 – 5)

acids = substances that donate H+ (protons) to solutions

bases = substances that absorb H+ (protons) from solutions

HCl H+ + Cl-

H2SO4 H+ + HSO4-

NaOH Na+ + OH-

NH3 + H+ NH4+

Page 41: Chemistry (Chapters 2 – 5)

gastric juice is 104

(10,000) times stronger acid than urine

bleach is 102 (100)times stronger base than milk of magnesia

Page 42: Chemistry (Chapters 2 – 5)

buffers = substances that stabilize or maintain pH therebyensuring homeostasis

NaOH + HCl

Na+ OH- H+ Cl-

NaCl + H2O

Page 43: Chemistry (Chapters 2 – 5)

carbon and life

organic compoundscontain carbon &

hydrogen

C6H12O6

CH4

C17H21NO4

Page 44: Chemistry (Chapters 2 – 5)
Page 45: Chemistry (Chapters 2 – 5)
Page 46: Chemistry (Chapters 2 – 5)

functional groups . . .

Page 47: Chemistry (Chapters 2 – 5)
Page 48: Chemistry (Chapters 2 – 5)

isomers (“iso” = same; “mer” = molecule) . . .

Page 49: Chemistry (Chapters 2 – 5)
Page 50: Chemistry (Chapters 2 – 5)

macromolecules

monomers (“mono” = singular; “mer” = molecule)

polymers (“poly” = many; “mer” = molecule)

thereforemonomer1 + monomer2 + monomer3 + . . . . = polymer

Page 51: Chemistry (Chapters 2 – 5)

puttin’ ‘emtogether!

takin’ ‘emapart!

Page 52: Chemistry (Chapters 2 – 5)

classes of organic molecules

carbohydrates

monomers polymers

glucose, fructose,galactose, ribose,

deoxyribose

maltose, sucrose,starch, cellulose,

chitin

monosaccharides disaccharides,polysaccharides

Page 53: Chemistry (Chapters 2 – 5)
Page 54: Chemistry (Chapters 2 – 5)
Page 55: Chemistry (Chapters 2 – 5)
Page 56: Chemistry (Chapters 2 – 5)
Page 57: Chemistry (Chapters 2 – 5)
Page 58: Chemistry (Chapters 2 – 5)
Page 59: Chemistry (Chapters 2 – 5)

Range: Florida to Mexico and, by introduction, indoors in warm buildings from Antarctica to Greenland.

Range Worldwide, wherever there are frost-free storage areas for food.

Page 60: Chemistry (Chapters 2 – 5)
Page 61: Chemistry (Chapters 2 – 5)
Page 62: Chemistry (Chapters 2 – 5)

classes of organic molecules

monomers polymers

lipids glycerol, fatty (palmitic) acids

triglycerides,fats, waxes, oils,phospholipids,steroids

Page 63: Chemistry (Chapters 2 – 5)
Page 64: Chemistry (Chapters 2 – 5)

triglyceride

Page 65: Chemistry (Chapters 2 – 5)
Page 66: Chemistry (Chapters 2 – 5)

H

C

H

H

C

H

H

C

H

HC

H

H

C

H

H

C

H

H

C

H

H

C

H

HC

H

H

C

H

HH

C

O

OC

H

H

C

O

OC

H

C

H

H

C

H

H

C

H

HC

H

H

C

HC

H

H

C

H

H

C

HC

H

H

C

H

HH

C

O

OC

HH

C

H

H

C

HC

HC

H

H

C

H

H

C

H

H

C

H

H

C

H

HC

H

H

C

H

HH

H

saturated fatunpoly

H

H

Page 68: Chemistry (Chapters 2 – 5)
Page 69: Chemistry (Chapters 2 – 5)

cholesterol

Page 70: Chemistry (Chapters 2 – 5)

Both Sexes:

•Increased risk of mood disturbances including mania and depression

•Increased risk of psychosis•Increased risk of aggressive acts

which may injure self or others•Increased risk of cardiovascular

disease•Increased risk of liver disease and

cancer•Increased risk of kidney disease

and cancer•Risk of HIV and Hepatitis B & C

from contaminated needles•Acne•Decreased sex drive•Baldness•Water retention•Muscle cramps•Aching joints•Increased risk of muscle tears•Increased risk of tendon injuries•Increased risk of nose bleeds•Insomnia•Decrease in immune system

effectiveness•Infertility•Mental Addiction

Men:

•Increased risk of prostate enlargement and cancer

•Decreased testicular size

•Gynecomastia (growth of breasts)

Women:

•Increased risk of cervical and endometrial cancer

•Increased risk of osteoporosis

•Irreversible enlargement of the clitoris

•Irreversible hoarsening and deepening of the voice

•Irreversible increase in facial and body hair

•Decreased breast size

•Amenorrhea

•Uterine atrophy

is it worth it?

Page 71: Chemistry (Chapters 2 – 5)

classes of organic molecules

monomers polymers

proteins amino acids

Page 72: Chemistry (Chapters 2 – 5)

protein functions . . .

Page 73: Chemistry (Chapters 2 – 5)
Page 74: Chemistry (Chapters 2 – 5)
Page 75: Chemistry (Chapters 2 – 5)
Page 76: Chemistry (Chapters 2 – 5)

primary

Page 77: Chemistry (Chapters 2 – 5)

normal red blood cells

Page 78: Chemistry (Chapters 2 – 5)

sickle cell anemia red blood cells

Page 79: Chemistry (Chapters 2 – 5)
Page 80: Chemistry (Chapters 2 – 5)

secondary

Page 81: Chemistry (Chapters 2 – 5)

tertiary

Page 82: Chemistry (Chapters 2 – 5)

quaternary

Page 83: Chemistry (Chapters 2 – 5)

primary to quarternary

Page 84: Chemistry (Chapters 2 – 5)

temperature, pH

Page 86: Chemistry (Chapters 2 – 5)
Page 87: Chemistry (Chapters 2 – 5)

classes of organic molecules

nucleic acids

monomers polymers

nucleotides

ribose nucleicacid (RNA),deoxyribosenucleic acid (DNA)

3 basic components:a) pentose sugar,b) phosphate group,c) nitrogenous base

Page 88: Chemistry (Chapters 2 – 5)

RNA

Page 89: Chemistry (Chapters 2 – 5)

DNA

Page 90: Chemistry (Chapters 2 – 5)
Page 91: Chemistry (Chapters 2 – 5)

Could we really be a monkey’s uncle?

Page 92: Chemistry (Chapters 2 – 5)
Page 93: Chemistry (Chapters 2 – 5)

end of materialfor Test I

Page 94: Chemistry (Chapters 2 – 5)