cheminform abstract: synthesis and conformational analysis of 2,6-dimethyl-1,5-diaza-cis-decalins

2001 diastereoselective syntheses, enantioselective syntheses diastereoselective syntheses, enantioselective syntheses (incl. cis/trans-isomerism) O 0031 37 - 033 Synthesis and Conformational Analysis of 2,6-Dimethyl-1,5-diaza- cis-decalins. — The diastereoselective syntheses of the title compounds (IV) and (VIII) with the dimethyl groups syn or anti to the angular hydrogens are performed starting from cis-1,5-diaza-decalin derivatives (I) and (V). By reversal of the hydrogenation/deprotection steps, starting from dimethylene derivative (VI), both target diastereomers are available as major products. — (KOZLOWSKI, MARISA C.; XU, ZHENRONG; SANTOS, A. GIL; Tetrahe- dron 57 (2001) 21, 4537-4542; Dep. Chem., Univ. Pa., Philadelphia, PA 19104, USA; EN) 1

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Page 1: ChemInform Abstract: Synthesis and Conformational Analysis of 2,6-Dimethyl-1,5-diaza-cis-decalins

2001 diastereoselective syntheses, enantioselective syntheses

diastereoselective syntheses, enantioselective syntheses (incl. cis/trans-isomerism)O 0031

37 - 033Synthesis and Conformational Analysis of 2,6-Dimethyl-1,5-diaza-cis-decalins. — The diastereoselective syntheses of the title compounds(IV) and (VIII) with the dimethyl groups syn or anti to the angular hydrogensare performed starting from cis-1,5-diaza-decalin derivatives (I) and (V). Byreversal of the hydrogenation/deprotection steps, starting from dimethylenederivative (VI), both target diastereomers are available as major products. —(KOZLOWSKI, MARISA C.; XU, ZHENRONG; SANTOS, A. GIL; Tetrahe-dron 57 (2001) 21, 4537-4542; Dep. Chem., Univ. Pa., Philadelphia, PA 19104,USA; EN)

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