ChemInform Abstract: Simple Route to Chiral Organophosphorus Compounds

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  • 1996 organo-phosphorus compounds, heterocyclic O,N,S derivatives

    organo-phosphorus compounds, heterocyclic O,N,S derivativesS 0085

    35 - 177Simple Route to Chiral Organophosphorus Compounds. Theglucose derivative (II) is used for the synthesis of chiral phosphorus compoundssuch as (III) and (IX) with very high diastereoselectivity. The usefulness ofcompounds such as (IV) as starting material for the synthesis of other chiralsubstances such as (VII) is shown. (KOLODIAZHNYI, O. I.; GRISHKUN,E. V.; Tetrahedron: Asymmetry 7 (1996) 4, 967-970; Inst. Bioorg. Chem., Natl.Acad. Sci. Ukr., Kiev 253094, Ukraine; EN)

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