cheminform abstract: pd-catalyzed c—c cross-coupling reactions within a thermoresponsive and...

ChemInform 2009, 40, issue 29 © 2009 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim www.cheminform.wiley-vch.de Polyphenyl derivatives Q 0700 Pd-Catalyzed C—C Cross-Coupling Reactions within a Thermoresponsive and pH-Responsive and Chelating Polymeric Hydrogel. — Suzuki and Heck reactions can be performed efficiently within the polymeric hydrogel (N-isopropylacrylam- ide—methacrylic acid ester—methyleneisoacrylamide copolymer). Addition of sur- factant and organic co-solvent is not necessary. It acts as reaction medium, encapsulant for reactants, and support for Pd catalyst. The composite of hydrogel and Pd catalyst can be easily recovered and reused several times without loss of efficiency. — (WANG, Y.; ZHANG, J.; ZHANG*, W.; ZHANG, M.; J. Org. Chem. 74 (2009) 5, 1923-1931; State Key Lab. Funct. Polym. Mater. Adsorp., Nankai Univ., Tianjin 300071, Peop. Rep. China; Eng.) — Jannicke 29- 081

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Page 1: ChemInform Abstract: Pd-Catalyzed C—C Cross-Coupling Reactions within a Thermoresponsive and pH-Responsive and Chelating Polymeric Hydrogel

www.cheminform.wiley-vch.de

Polyphenyl derivativesQ 0700 Pd-Catalyzed C—C Cross-Coupling Reactions within a Thermoresponsive and

pH-Responsive and Chelating Polymeric Hydrogel. — Suzuki and Heck reactions can be performed efficiently within the polymeric hydrogel (N-isopropylacrylam-ide—methacrylic acid ester—methyleneisoacrylamide copolymer). Addition of sur-factant and organic co-solvent is not necessary. It acts as reaction medium, encapsulant for reactants, and support for Pd catalyst. The composite of hydrogel and Pd catalyst can be easily recovered and reused several times without loss of efficiency. — (WANG, Y.; ZHANG, J.; ZHANG*, W.; ZHANG, M.; J. Org. Chem. 74 (2009) 5, 1923-1931; State Key Lab. Funct. Polym. Mater. Adsorp., Nankai Univ., Tianjin 300071, Peop. Rep. China; Eng.) — Jannicke

29- 081

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