cheminform abstract: palladium(ii)- and mercury(ii)-catalyzed rearrangements of propargyl acetates

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2008 Indan derivatives Q 1050 Palladium(II)- and Mercury(II)-Catalyzed Rearrangements of Propargyl Ace- tates. — The substituents at the terminal alkynyl and alkenyl positions of the starting propargyl acetates have a significant influence on the outcome of the reaction which affords [4.3.0]bicycles bearing a cyclopentenone or a cyclopentadiene ring. — (CARUANA, P. A.; FRONTIER*, A. J.; Tetrahedron 63 (2007) 43, 10646-10656; Dep. Chem., Univ. Rochester, Rochester, NY 14627, USA; Eng.) — Klein 05- 088

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Page 1: ChemInform Abstract: Palladium(II)- and Mercury(II)-Catalyzed Rearrangements of Propargyl Acetates

2008

200805.fm Page 96 Friday, December 28, 2007 4:27 PM

Indan derivativesQ 1050 Palladium(II)- and Mercury(II)-Catalyzed Rearrangements of Propargyl Ace-

tates. — The substituents at the terminal alkynyl and alkenyl positions of the starting propargyl acetates have a significant influence on the outcome of the reaction which affords [4.3.0]bicycles bearing a cyclopentenone or a cyclopentadiene ring. — (CARUANA, P. A.; FRONTIER*, A. J.; Tetrahedron 63 (2007) 43, 10646-10656; Dep. Chem., Univ. Rochester, Rochester, NY 14627, USA; Eng.) — Klein

05- 088