cheminform abstract: iodine—methanol induced novel fragmentation of bicyclic diones to anisole...

2000 cleavage reactions, decomposition reactions, pyrolysis cleavage reactions, decomposition reactions, pyrolysis O 0100 52 - 037 Iodine–Methanol Induced Novel Fragmentation of Bicyclic Diones to Anisole Derivatives. — Attempted dehydrogenation of cyclic diones (I) with iodine and methanol results in an unexpected fragmentation furnishing anisole derivatives (III). A plausible reaction mechanism is discussed. — (BANERJEE, AJOY K.; CABRERA, ELVIA V.; AZOCAR, JOSE A.; Synth. Commun. 30 (2000) 20, 3815-3821; Cent. Quim., Inst. Venez. Invest. Cient., Caracas 1020-A, Venez.; EN) 1

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Page 1: ChemInform Abstract: Iodine—Methanol Induced Novel Fragmentation of Bicyclic Diones to Anisole Derivatives

2000 cleavage reactions, decomposition reactions, pyrolysis

cleavage reactions, decomposition reactions, pyrolysisO 0100

52 - 037Iodine–Methanol Induced Novel Fragmentation of Bicyclic Diones toAnisole Derivatives. — Attempted dehydrogenation of cyclic diones (I)with iodine and methanol results in an unexpected fragmentation furnishinganisole derivatives (III). A plausible reaction mechanism is discussed. —(BANERJEE, AJOY K.; CABRERA, ELVIA V.; AZOCAR, JOSE A.; Synth.Commun. 30 (2000) 20, 3815-3821; Cent. Quim., Inst. Venez. Invest. Cient.,Caracas 1020-A, Venez.; EN)

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