cheminform abstract: indium-catalyzed allylation of imines with electrochemically assisted catalyst...

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2002 amines amines (benzene compounds) Q 0120 23 - 084 Indium-Catalyzed Allylation of Imines with Electrochemically As- sisted Catalyst Regeneration. The Barbier-type C–C bond formation of aldimines and ketimines with allyl bromide is achieved by a low valent In(I)-catalyst which is chemo-electrochemically regenerated on an Al-anode. In the case of ketimines and electron-poor aldimines, reduced products are formed as well (as by-products or almost exclusively). — (HILT, GERHARD; SMOLKO, KONSTANTIN I.; WALOCH, CHRISTOPH; Tetrahedron Lett. 43 (2002) 8, 1437-1439; Fachbereich Chem., Ludwig-Maximilians-Univ., D-81377 Muenchen, Germany; EN) 1

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Page 1: ChemInform Abstract: Indium-Catalyzed Allylation of Imines with Electrochemically Assisted Catalyst Regeneration

2002 amines

amines (benzene compounds)Q 0120

23 - 084Indium-Catalyzed Allylation of Imines with Electrochemically As-sisted Catalyst Regeneration. — The Barbier-type C–C bond formationof aldimines and ketimines with allyl bromide is achieved by a low valentIn(I)-catalyst which is chemo-electrochemically regenerated on an Al-anode.In the case of ketimines and electron-poor aldimines, reduced products areformed as well (as by-products or almost exclusively). — (HILT, GERHARD;SMOLKO, KONSTANTIN I.; WALOCH, CHRISTOPH; Tetrahedron Lett. 43(2002) 8, 1437-1439; Fachbereich Chem., Ludwig-Maximilians-Univ., D-81377Muenchen, Germany; EN)

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