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2000 stereochemistry stereochemistry (general, optical resolution) O 0030 14 - 036 Highly Stereoselective Reduction of Acyclic α-Sulfinyl Ketimines: Synthesis of Enantiomerically Pure β-Aminosulfoxides. — Reduction of α-sulfinyl imines with DIBAL in the presence of Lewis acids proceeds with excellent stereoselectivity controlled by the configuration of the sulfinyl group. — (GARCIA RUANO, JOSE L.; CIFUENTES, MARTA M.; LORENTE, ANTONIO; RODRIGUEZ RAMOS, JESUS H.; Tetrahedron: Asymmetry 10 (1999) 23, 4607-4618; Dep. Quim. Org., Univ. Auton., Cantoblanco, E-28049 Madrid, Spain; EN) 1

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Page 1: ChemInform Abstract: Highly Stereoselective Reduction of Acyclic α-Sulfinyl Ketimines: Synthesis of Enantiomerically Pure β-Aminosulfoxides

2000 stereochemistry

stereochemistry (general, optical resolution)O 0030

14 - 036Highly Stereoselective Reduction of Acyclic α-Sulfinyl Ketimines:Synthesis of Enantiomerically Pure β-Aminosulfoxides. — Reductionof α-sulfinyl imines with DIBAL in the presence of Lewis acids proceeds withexcellent stereoselectivity controlled by the configuration of the sulfinyl group.— (GARCIA RUANO, JOSE L.; CIFUENTES, MARTA M.; LORENTE,ANTONIO; RODRIGUEZ RAMOS, JESUS H.; Tetrahedron: Asymmetry 10(1999) 23, 4607-4618; Dep. Quim. Org., Univ. Auton., Cantoblanco, E-28049Madrid, Spain; EN)

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