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Newcastle University Safety Office King’s Gate Newcastle upon Tyne NE1 7RU Tel 0191 222 6274
Safety Office
February 2011
Chemical Safety Training Course
This handout contains the slides from the course, and two example COSHH risk assessments.
Fuller guidance is available on the University Safety Office website at www.safety.ncl.ac.uk Please refer to the website as the internal authoritative source of information.
The materials provided in this session have been developed by the University Safety Office and are for internal University use only. If versions of this material are required for in house training please contact the University Safety Office for PowerPoint and other files.
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Chemical Safety v4 15/02/2011
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Safety Office
Chemical Safety
Safety OfficeObjectives
Legal requirements for control of hazardous and dangerous substances
www.safety.ncl.ac.uk
How hazardous and dangerous substances can be harmful to health, safety and environment at work
Risk assessment and control for hazardous and dangerous substances to protect to health, safety and environment
Safety Office
Risk Assessment
www.safety.ncl.ac.uk
Safety OfficeChemical Safety Law
Health and Safety at Work Act and Regulations
Environment Acts and Regulations
C t l f S b t H d t H lth R l ti
www.safety.ncl.ac.uk
Control of Substances Hazardous to Health Regulations (COSHH)
Dangerous Substances and Explosive Atmospheres Regulations (DSEAR)
Health and Safety Executive (HSE) regulator for chemical safety
Safety Office
COSHH and DSEAR Risk Assessment and Control
Responsibility of managers and principal investigators
Assess risks to health, safety and environment
Hazardous and dangerous substances
Who or what might be harmed and how
www.safety.ncl.ac.uk
Containment and controls
Preventing or adequately controlling exposure and release
Maintenance, inspection and testing of control measures
Monitoring exposure and health surveillance
Emergency procedures and specific first aid measures
Information, instruction, training and supervision
Review and revise risk assessments
Safety Office
Standards, Guidance and Information
Websites
University Safety Office - Chemical Safety
University Occupational Health Service
Health and Safety Executive
Institution of Chemical Engineers
www.safety.ncl.ac.uk
Institution of Chemical Engineers
Royal Society of Chemistry
International Agency for Research on Cancer
Publications
Chemistry handbooks and textbooks
Chemical safety books
Scientific papers and internet searches
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Safety OfficeHazards and Risks
Hazard
Hazardous and dangerous substances
www.safety.ncl.ac.uk
Risk
Hazardous and dangerous substances and potential for harm to health, safety and environment
Safety OfficeHazardous Substances
Very toxic, toxic, harmful, irritant, corrosive, carcinogenic, mutagenic, sensitising, toxic to reproduction, highly flammable, flammable or dangerous to environment
Substance assigned workplace exposure limits
www.safety.ncl.ac.uk
Substance that is carcinogenic, mutagenic or toxic to reproduction
Dust in substantial concentrations in air
Biological agent
Any substance which creates a hazard to health or safety
Safety OfficeDangerous Substances
Substances or mixtures of substances classified as explosive, oxidising, extremely flammable, highly flammable or flammable
www.safety.ncl.ac.uk
Any kind of dust that when spread in air to form a cloud or an explosive atmosphere can explode
Any substances or mixtures of substances which because of their physical properties and way in which they are present in workplace create a risk to safety from fires and explosions
Safety OfficeWhy Worry About All This?
You or other people might be injured or killed in an accident
You or other people might suffer illness or death from exposure to hazardous or
www.safety.ncl.ac.uk
death from exposure to hazardous or dangerous substances
Serious impacts of accidents and exposure on people, organisations and society
Think about what you are doing and plan your work carefully!
Safety Office
COSHH and DSEAR Risk Assessment
1. University Safety Office website - COSHH Risk Assessment, DSEAR Risk Assessment and Carcinogen Registration
2. Complete COSHH risk assessment form
www.safety.ncl.ac.uk
3. Complete DSEAR risk assessment form
4. Read and follow guidance (HSE)
5. Contact School Safety Officer for advice on COSHH and DSEAR risk assessments
Safety OfficeGuidance
COSHH
HSE Control of substances hazardous to health ACoP and guidance
DSEAR
HSE Dangerous substances and explosive atmospheres
www.safety.ncl.ac.uk
HSE Dangerous substances and explosive atmospheres ACoP and guidance
HSE Design of plant equipment and workplaces ACoP and guidance
HSE Control and mitigation measures ACoP and guidance
HSE Storage of dangerous substances ACoP and guidance
HSE Safe maintenance repair and cleaning procedures ACoP and guidance
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Safety OfficeCOSHH Risk Assessment Form
COSHH risk assessment form - Hazardous substances
www.safety.ncl.ac.uk
Safety OfficeCOSHH Risk Assessment Form
www.safety.ncl.ac.uk
Safety OfficeDSEAR Risk Assessment Form
DSEAR risk assessment form - Dangerous substances
www.safety.ncl.ac.uk
Safety OfficeDSEAR Risk Assessment Form
www.safety.ncl.ac.uk
Safety Office
COSHH and DSEAR Risk Assessment Form
Section 1: Project
Section 2: Hazards
www.safety.ncl.ac.uk
Section 3: Risks
Section 4: Controls
Section 5: Emergency Procedures
Section 6: Approval
Safety OfficeDoing a COSHH Risk Assessment
1. COSHH risk assessments must be done before starting work
2. Guidance on COSHH risk assessment and carcinogen registration on USO website
3 Managers and supervisors must provide clear advice to
www.safety.ncl.ac.uk
3. Managers and supervisors must provide clear advice to assessors, check and sign risk assessments
4. Contact School Safety Officer if additional advice needed
5. Check workers are using controls and they are effective
6. Review and revise COSHH risk assessment and controls
7. Revise risk assessments by saving original and making changes to new versions (eg v1, v2, v3)
8. Keep records of all versions
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Safety OfficeDoing a DSEAR Risk Assessment
1. DSEAR risk assessments must be done before starting work
2. Guidance on DSEAR risk assessment on USO website
3. Managers and supervisors must provide clear advice to assessors check and sign risk assessments
www.safety.ncl.ac.uk
assessors, check and sign risk assessments
4. Contact School Safety Officer if additional advice needed
5. Check workers are using controls and they are effective
6. Review and revise DSEAR risk assessment and controls
7. Revise risk assessments by saving original and making changes to new versions (eg v1, v2, v3)
8. Keep records of all versions
Safety OfficeCarcinogen Registration
Carcinogens must be registered before use using
carcinogen registration forms
Project Registration Form
Complete one form for each chemical
www.safety.ncl.ac.uk
Complete one form for each chemical
COSHH category 1 and 2 carcinogens
User Registration Form
Complete one form for each person
Signed copies needed for user, School Safety
Officer and University Safety Office
Safety Office
Assess Risks to Health, Safety and Environment
People may be exposed to different types of hazardous and dangerous substances in work
Laboratories, offices, cleaning, engineering or other work
Harm to people and environment
How and to what could people be exposed
www.safety.ncl.ac.uk
How and to what could people be exposed
Potential for exposure or release
Scale, amounts, concentrations and frequency
Processes and substances used or generated
Reactions and interactions
Routes and consequences of exposure or release
Rapid or delayed effects
Safety Office
Risks to Health, Safety and Environment
Workers
People sharing workplace
Visitors
Public
Land
Water
Air
Microorganisms
www.safety.ncl.ac.uk
Public
Contractors
Pregnant women
Lone workers
Young or inexperienced workers
Microorganisms
Animals
Plants
Soils
Food
Safety OfficeExposure Routes
Inhalation
Breathing solids, liquids or gases
Ingestion
Swallowing solids or liquids
www.safety.ncl.ac.uk
Swallowing solids or liquids
Injection
Sharps injuries with solids, liquids or gases
Absorption
Contact with intact skin or mucous membranes of solids, liquids or gases
Safety OfficeInformation on Hazards and Risks
Information on labels as symbol, letter or standard words
Toxic, harmful, irritant, corrosive, oxidising, carcinogenic, mutagenic, sensitising, toxic to reproduction, flammable, explosive or dangerous to environment
Safety data sheets (SDS)
www.safety.ncl.ac.uk
Risk phrases (R phrase)
Safety phrases (S phrase)
Workplace exposure limits (WEL)
Supplier catalogues
Reference books and research literature
Chemical safety books
Chemical safety databases (eg Sigma-Aldrich, RSC, ICSC)
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Safety OfficeHazard Symbols
Harmful / Irritant
Corrosive
Oxidising
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Toxic / Very Toxic
Highly Flammable / Extremely Flammable
Explosive
Dangerous for Environment
Safety OfficeSafety Data Sheets
Safety data sheets available for hazardous and dangerous substances and preparations (Mixtures of substances)
Suppliers must provide SDS
General information about hazards, risks and controls
www.safety.ncl.ac.uk
General information about hazards, risks and controls
SDS do not define all risks and controls for your specific work
You have to do that in your risk assessment
No SDS for novel chemicals and many reaction intermediates produced in research
SDS available on supplier and safety websites
Safety OfficeInformation on Safety Data Sheets
1. Identification of substance and preparation
2. Hazards identification
3. Composition and information on ingredients
9. Physical and chemical properties
10.Stability and reactivity
11.Toxicological information
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on ingredients
4. First aid measures
5. Fire fighting measures
6. Accidental release measures
7. Handling and storage
8. Exposure controls and personal protection
12.Ecological information
13.Disposal considerations
14.Transport information
15.Regulatory information
16.Other information
Safety OfficeRisk Phrases
Risk (R) phrases provide important information on risks
Example R phrases
• R2 Risk of explosion by shock, friction, fire or other source of ignition
R11 Hi hl fl bl
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• R11 Highly flammable
• R23 Toxic by inhalation
• R45 May cause cancer
Chemicals can have multiple risk phrases
• Phenol: R24 R25 R34 R36 R37 R38
• Hydrofluoric acid: R26 R27 R28 R35
• Hexane: R11 R20 R38 R48 R51 R53 R62 R65 R67
Safety OfficeSafety Phrases
Safety (S) phrases provide important information on controls
Example S phrases
• S16 Keep away from sources of ignition
• S23 Do not breathe in vapour
www.safety.ncl.ac.uk
• S24 Avoid contact with skin
• S30 Never add water to this product
• S36 Wear suitable protective clothing
Chemicals can have multiple safety phrases
• Phenol: S28 S45
• Hydrofluoric acid: S26 S28 S36 S37 S39 S45
• Hexane: S16 S36 S37 S39 S45 S53
Safety OfficeWorkplace Exposure Limit
Workplace exposure limits (WEL) published for hazardous substances
HSE EH40 Workplace Exposure Limits
WEL assigned for inhalation risks
www.safety.ncl.ac.uk
Long term exposure limit (LTEL) over 8 hour period
Short term exposure limit (STEL) over 15 minute period
Levels should not normally exceed one quarter of WEL
Levels must be calculated by method in EH40
EH40 provides LTEL, STEL, R phrases, carcinogenic and skin absorption risks
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Safety OfficeHealth and Safety Effects
Dangerous and hazardous substances may cause accidents, injury, ill health, disease, fires, explosions and death
Harm to workers and public
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p
Health effects may be acute, chronic or fatal
Safety effects may be temporary or permanent
Damage may occur to equipment, buildings and environment
Safety Office
Harmful Effects of Exposure or Release
Harm to organs and tissues (eg eyes, skin, lungs, brain, muscles, blood, nerves, liver, kidneys and bladder)
Independent or synergistic effects of substances
Short or long term effects
Effects may be reversible or irreversible
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Effects may be reversible or irreversible
Carcinogens may cause cancer
Chemicals may cause irritant contact dermatitis
Sensitizers may cause asthma or allergic contact dermatitis
Asphyxiants can cause rapid loss of consciousness, suffocation and death
Chemicals may cause burns, fires and explosions
Environmental contamination and pollution
Safety OfficeCarcinogens and Mutagens
Carcinogens may cause cancer
COSHH category 1 or 2 carcinogenic substances
Carcinogen risk phrases R40, R45 and R49
Mutagen risk phrase R46
www.safety.ncl.ac.uk
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IARC international classification of common carcinogens
Register project, carcinogen and users with carcinogen registration forms
COSHH risk assessment using stringent controls required
Safety OfficeIARC Information on Carcinogens
Category 1: Agent or mixture is carcinogenic to humans. Exposure circumstance entails exposures carcinogenic to humans
Category 2A: Agent or mixture is probably carcinogenic to humans. Exposure circumstance entails exposures
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probably carcinogenic to humans
Category 2B: Agent or mixture is possibly carcinogenic to humans. Exposure circumstance entails exposures possibly carcinogenic to humans
Category 3: The agent, mixture or exposure circumstance not classifiable for carcinogenicity to humans
Category 4: The agent, mixture or exposure circumstance probably not carcinogenic to humans
Safety OfficeFires and Explosions
Fires and explosions are risks of work with dangerous and hazardous substances
Substances may be flammable or explosive
Redox reactions
www.safety.ncl.ac.uk
Redox reactions
Fire triangle (Combustion)
Fuels, oxidisers and ignition sources
Flash point (Can ignite)
Spillages and leaks of solids, liquids, gases and vapours
Deflagrations and detonations (Fires and explosions)
Ignition source
Safety OfficeFlammable Limits and Range
Lower explosive limit (LEL) and upper explosive limit (UEL) are limits of flammability
Flammable range is concentration of vapour or gas and air mixture which can be ignited to cause fire or explosion (LEL UEL)
www.safety.ncl.ac.uk
(LEL - UEL)
Examples of flammable ranges
• Hydrogen: 6 - 71%
• Acetylene: 2 - 82%
• Xylene: 1 - 7%
Substances with broad flammable ranges are particularly hazardous
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Safety OfficeFires and Explosions
Common fire and explosion hazards are organic solvents and pressurised gases or vapours
Chemical reactions may involve flammable or explosive reactants, intermediates or products
G li d ( h d t l )
www.safety.ncl.ac.uk
Gas cylinders (eg hydrogen, acetylene)
Dusts can combust or explode
Some substances can combust without external oxidiser
Pyrophoric chemicals combust on contact with air
Explosions may be caused by chemical or physical events
Some substances may detonate and explode on ignition, heating or impact (eg acetylene)
Safety OfficeRisk Estimation
Risk is estimated by combining severity of harm were it to
occur and likelihood of occurrence in specific circumstances
Severity of harm (severe, moderate, minor, negligible)
www.safety.ncl.ac.uk
Likelihood of harm (high, medium, low, negligible)
Risk = Likelihood x Severity
Risk = Effectively zero, Low, Low/Medium, Medium or High
Safety OfficeRisk Estimation Matrix
Severity of Harm
Likelihood of Harm
High Medium Low Negligible
Severe High High Medium Effectively zero
www.safety.ncl.ac.uk
Moderate High Medium Medium/Low Effectively zero
Minor Medium/Low Low Low Effectively zero
Negligible Effectively zero
Effectively zero
Effectively zero
Effectively zero
Safety Office
Controls
www.safety.ncl.ac.uk
Safety Office
Control of Hazardous and Dangerous Substances
COSHH and DSEAR require exposure to and release of hazardous and dangerous substances to be prevented or adequately controlled
Control measures must be proportionate to risks, practical and sustainable
www.safety.ncl.ac.uk
Control measures must be used, monitored, maintained and regularly reviewed
Good practice in control of hazardous substances are given in COSHH to enable selection of appropriate control measures
Good practice in control of dangerous substances are given in DSEAR to enable selection of appropriate control measures
Safety Office
Principles of Good Practice for Control of Exposure
1. Design and operate processes and activities to prevent and control exposure, release and spread of hazardous substances
2. Controls must be relevant to routes of exposure
3. Control exposure by measures proportionate to health and safety risks
4. Choose most effective controls to minimise exposure
www.safety.ncl.ac.uk
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5. Provide suitable personal protective equipment
6. Check and review regularly controls for effectiveness
7. Provide health surveillance and monitor exposure where required
8. Hygiene measures
9. Inform and train workers on hazards and risks of substances and use of control measures
10.Ensure control measures does not increase overall risk to health and safety
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Safety OfficeControl Measures
Totally enclose processes and handling systems
Partially enclose processes, general ventilation and local exhaust ventilation
Processes, systems and procedures which minimise generation or release of substances spillages and leaks
www.safety.ncl.ac.uk
generation or release of substances, spillages and leaks
Reduce quantities of substances used or produced
Minimise number of people exposed and exposure time
Regular cleaning or disinfecting of surfaces and equipment
Safe handling, storage, transport and disposal of hazardous substances and waste
Washing, changing and storage of clothing and PPE, and prohibiting eating and drinking
Safety OfficeHierarchy of Risk Control
Fundamental concept in risk control
1. Elimination
2. Substitution
www.safety.ncl.ac.uk
3. Engineering controls
4. Administrative controls
5. Personal protective equipment
Highest and most effective controls must be selected and
implemented before lower and less effective ones
Safety OfficeContainment and Control
Policies, risk assessments and standard operating procedures
Laboratories and other workplaces
Safe work practices for use, storage, transport, inactivation and waste disposal
Maintenance and testing of controls
www.safety.ncl.ac.uk
Maintenance and testing of controls
Checking controls are used and are effective
Hygiene
Personal protective equipment
Health surveillance and monitoring exposure
Emergency plans and procedures
Information, instruction, training and supervision
Safety OfficeLaboratories
www.safety.ncl.ac.uk
Safety Office
Laboratories and Hazardous Areas
Benches, floors and walls impervious, resistant and cleanable
Design safe experiments and methods and seek expert advice
Ventilation, fume cupboards, safety cabinets and LEV
Use spill trays, screens and enclosures
Keep equipment and surfaces clean
www.safety.ncl.ac.uk
Keep equipment and surfaces clean
Hazard signs (eg chemicals, gas cylinders)
Electronic monitors for gas detection and warning of danger (eg H2, O2, CO2, CO, H2S and organic vapours)
Hand wash sink, emergency wash hose and shower
Chemical spillage kits
Special fire fighting equipment (eg Firetrace)
Special first aid equipment (eg Medical oxygen for CN)
Safety Office
Fume Cupboards and Local Exhaust Ventilation
Control of hazardous and dangerous substances to protect workers and environment
Total or partial containment
Air flow through cabinet contains and dilutes substances
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Substances captured by air flow into LEV
LEV requires effective distance from source, capture and transfer velocities
Discharge contaminated air outside building to atmosphere
Substances may be collected using filters, scrubbers or extractors
Must be properly used and maintained
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Safety OfficeFume Cupboards
Check fume cupboards and safety cabinets are working properly before use
Use correct type of cabinet
Put clear details about experiment and reactions on cabinet
www.safety.ncl.ac.uk
Work with sash down as much as possible
Look through screen not opening
Work in centre of cabinet
Work carefully to minimise disturbance to airflow
Deal with spillages immediately
Do not store unnecessary equipment and materials in fume cupboards and safety cabinets
Safety Office
Control of Exposure to Carcinogens
COSHH requires use of specific control measures for carcinogens
in addition to general controls
a) Totally enclosing process and handling systems if possible
b) Prohibiting eating and drinking in areas used for carcinogens or
www.safety.ncl.ac.uk
b) Prohibiting eating and drinking in areas used for carcinogens or mutagens
c) Cleaning floors, walls and other surfaces at regular intervals and when necessary
d) Designating areas and installations which may be contaminated by carcinogens or mutagens and using warning signs
e) Storing, handling and disposing of carcinogens or mutagens safely, including using closed and clearly labelled containers
Safety Office
Carcinogen Standard Operating Procedures
1. Chemical properties, state and carcinogenicity of substances
2. Quantities to be used
3. Storage procedures
4. Where and how carcinogens are weighed and dispensed
5 Cleaning of room equipment and surfaces
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5. Cleaning of room, equipment and surfaces
6. Monitoring effectiveness of procedures
7. Segregation and signage for hazardous areas
8. PPE
9. Waste disposal procedures
10.Statement of training arrangements for users
11.Summary of staff involved in project and roles
12.Emergency and spillage procedures
Safety OfficeSharps Controls
Exercise caution with sharps to reduce risks of exposure to hazardous substances
Do not use sharps if safer alternatives exist
Use plasticware instead of glassware
www.safety.ncl.ac.uk
Store sharps safely
Never resheath needles
Dispose of used sharps immediately after use in sharps container
Put sharps bin where sharps used
Use PPE and cut resistant gloves
Use safe procedures to prevent sharps accidents
Safety OfficeSharps Controls
G
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ice
www.safety.ncl.ac.uk
Ba
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Dispose of sharps immediately after use
Put sharps bins where sharps used
Dispose of sharps bins on reaching level
Do not dispose of sharps in ordinary bins
Never re-sheath needles
Do not transfer used sharps to other workers
Safety OfficePersonal Protective Equipment
PPE must be used where required by local rules and risk assessments
Body, hand, eye, face and breathing protection
Lab coats, aprons and gloves
S f t t l l d f hi ld
www.safety.ncl.ac.uk
Safety spectacles, goggles and face shields
Respiratory protective equipment
Decontaminated if contaminated
Disposed where damaged or contaminated
Use of PPE is compulsory in laboratories
PPE must not be worn outside laboratories and buildings
PPE must be clean and cleaned by School
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Safety OfficeLaboratory Coats and Other PPE
Laboratory coats must be worn for hazardous activities
At least two for each person so can be cleaned
Wear sizes large enough to allow for flexibility
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g g yand shrinkage
Should be clean and properly fastened
Aprons, visors and boots used if risk splashing with hazardous substances
Chemical protection suits for high level protection
Safety OfficeGloves
Suitable gloves must be used for hazardous activities
Select correct gloves for specific hazards using selection criteria on supplier websites
www.safety.ncl.ac.uk
Disposable nitrile gloves offer good protection against many chemicals
Thicker gloves may be required for work with many hazardous chemicals
Special gloves for specific chemical and physical hazards
Use cut resistant gloves for work with sharps
Safety Office
Spectacles, Goggles and Face Shields
Eye protection must be worn for hazardous activities to protect against splashes, aerosols and explosions
Normal prescription glasses do not give protection
Suitable safety spectacles
www.safety.ncl.ac.uk
Suitable safety spectacles
Goggles
Face shield visors to protect whole face
Specialist spectacles, goggles and face shields for chemical and physical hazards
Safety OfficeEye Protection is Essential
Glassware explosion accident
Small glass fragments ejected everywhere
Person’s eyes were protected because
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they used lab spectacles
Chemicals or other materials in eyes could cause serious eye damage or blindness
Wear your lab spectacles!
Safety OfficeRespiratory Protective Equipment
RPE may be required for some hazardous activities
Disposable mask (FFP1, FFP2 and FFP3)
Half or full face respirator
Powered respirator
www.safety.ncl.ac.uk
Powered respirator
Breathing apparatus
RPE must be face fit tested to each individual person
Information and training in use required
RPE must be clean and properly maintained and stored
Safety OfficeGood Personal Practices
Safety glassesNo eating, drinking or chewing
Long hair tied back
www.safety.ncl.ac.uk
No dangling clothingor jewellery
Sensible flat shoes
Legs covered
Laboratory coat(clean)
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Safety Office
Health Surveillance and Monitoring Exposure
University Occupational Health Service provides health surveillance for occupational diseases or conditions for research workers
Check people not harmed by exposure to hazardous b t ( i t i iti )
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substances (eg carcinogens, toxins, sensitizers)
Diseases and conditions (eg dermatitis, asthma and cancer)
Monitoring exposure to substances where required
New and expectant mothers (Contact Occupational Health)
Questionnaire, interview, risk assessment, examination, tests, biological monitoring and clinical referrals
Safety OfficePersonal Hygiene
Never do any of the following in laboratories and anywhere you could be exposed to hazardous substances
Eat Drink
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Drink Chew Apply cosmetics Store food or drink Avoid touching the face
Do not store personal possessions in laboratories (eg outdoor clothes and bags)
Safety OfficeHand Washing
Hands must be washed if contaminated and when work completed
Handwash sink should be near doors
Should operate without using hands
www.safety.ncl.ac.uk
Should have emergency wash hose
Liquid soap
Paper towels
Handwash sink must not be used for lab work
Hand creams may be useful to protect hands
Emergency wash hose for cleaning eyes, mouth, skin or body in case of injury or personal contamination
Safety Office
Storage of Hazardous and Dangerous Substances
Store properly to prevent accidental exposure or release of hazardous and dangerous substances
Minimise quantities of chemicals purchased and stored
Label samples, containers and cabinets
www.safety.ncl.ac.uk
Segregate incompatible chemicals (eg acids, bases, oxidisers, organic solvents, flammables)
Use suitable robust containers and bunded cabinets
Store flammables in flame resistant cabinets (eg solvents, gas cylinders)
Do not overfill cabinets, fridges and freezers
Dispose of unwanted chemicals
Safety Office
Internal Transport of Hazardous and Dangerous Substances
Transport properly to prevent accidental exposure or release of hazardous and dangerous substances
Use bottle carriers for large bottles
Use multiple containment for transporting
www.safety.ncl.ac.uk
Use multiple containment for transporting hazardous chemicals
Use suitable robust containers with hazard warning sign labels
Use trolleys where necessary
Take spill kit if necessary in case of accidents
Safety Office
External Transport of Hazardous and Dangerous Substances
Complex legal requirements for carriage of dangerous goods
HSE Carriage of Dangerous Goods Manual
UN hazard classes 1 - 9
Use UN approved packaging containers
www.safety.ncl.ac.uk
Package carefully and provide documentation
Use competent carriers (eg Dangerous Goods International or World Courier)
Communicate details of shipments to recipients
Ensure consignment is acceptable to carrier and recipient
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Chemical Safety v4 15/02/2011
12
Safety OfficeUN Hazard Classes
Class 1: Explosive
Class 2: Gases
Class 3: Flammable liquids
Class 4: Flammable solids
www.safety.ncl.ac.uk
Class 4: Flammable solids
Class 5: Oxidizing substances and organic peroxides
Class 6: Toxic and infectious substances
Class 7: Radioactive substances and articles
Class 8: Corrosive substances
Class 9: Miscellaneous dangerous substances
Safety Office
Transport Methods and Packaging Systems
Categorise substances or materials into UN hazard class
Get advice from transport carrier company and Dangerous Goods Safety Adviser (DGSA)
Use correct UN approved packaging system containers
www.safety.ncl.ac.uk
suitable for hazards
Containers must be robust, with seal and leakproof
Containers must be properly labelled
Double or triple packaging systems may be required for some hazards
Shipping documents and contact details
Safety OfficeExample Packaging System
www.safety.ncl.ac.uk
Safety OfficeWaste Management
Hazardous and dangerous substances must be safely handled using appropriate containers and waste route
Put into clearly labelled waste containers
Do not mix incompatible chemicals
www.safety.ncl.ac.uk
Use sharps containers for sharps
Do not overfill containers
Do not put waste down sinks unless previously agreed with Safety Officer
Do not stockpile chemical waste and dispose regularly
Use specialist chemical waste contractors
Waste must be safely stored, transported and disposed
Safety OfficeEmergency Procedures
Emergency procedures must be prepared in risk assessment and standard operating procedures
Accidental spillages and release of hazardous and dangerous substances
Workers must be able to implement emergency procedures
www.safety.ncl.ac.uk
Workers must be able to implement emergency procedures
Assess situation before taking action
Inform others of accidents and isolate area or evacuate
Seek assistance and use PPE
Seek first aid and medical treatment if required
Decontaminate area or laboratory
Report accidents and incidents immediately to manager
Complete USO accident report form
Safety OfficeChemical Accidents
Spillage of liquids or solids
Release of gases
Fire
Explosion
www.safety.ncl.ac.uk
Explosion
Accidental exposure
Acute toxicity
Allergic sensitisation or reaction
Pharmacological effect
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Chemical Safety v4 15/02/2011
13
Safety OfficeSpillages
Spillage standard operating procedure
Spillage kits and PPE
Notify other workers and isolate area
Evacuate lab if serious risks
www.safety.ncl.ac.uk
Contain spills with tissues or granules
Allow sufficient contact time before clean up
Gather debris but do not use brush
Pick up broken glass carefully (eg forceps or swabs)
Put debris in suitable container for safe disposal
Clean and decontaminate area, surfaces and equipment
Safety Office
Contained Chemical Spillages and Releases
Spillages in fume cupboard or spill tray
Be prepared in advance
Wear appropriate lab coat, gloves and spectacles
N t li ( id d b )
www.safety.ncl.ac.uk
Neutralise (eg acids and bases)
Destroy (eg reactives)
Absorb onto solid (eg paper, absorption granules)
Transfer to specified chemical waste
Safety Office
Uncontained Chemical Spillages and Releases
Chemical spillor gas release
Minoror Minor Major
www.safety.ncl.ac.uk
Major
Evacuatebuilding
Phone 6666
Highhazard
As forcontainedspillage
EvacuatelaboratorySeek Help
No Yes
Safety OfficeFire Safety Actions
Ensure safe to fight fires and escape route is not compromised
Small fire
1. Smother with beaker or fire blanket
www.safety.ncl.ac.uk
2. Tell others
3. Use appropriate fire extinguisher
Large fire
1. Activate fire alarm
2. Call Fire and Rescue Service (Security x 6666)
3. Evacuate building immediately
Safety OfficePersonal Contamination or Injury
Remove contaminated clothing quickly and leave in lab
Remove contamination from eyes, mouth and skin by washing with water
Minor cuts and small puncture wounds should be encouraged to bleed
www.safety.ncl.ac.uk
Wash wounds and contaminated skin with water
Dress wounds
Use PPE when helping injured persons
Seek help if required (eg First aider, GP or Hospital)
Emergencies should go to hospital
Call ambulance if required (Security x 6666)
Explain incident and hazards substances to medical staff
Safety OfficeEmergency First Aid
Skin contact
Remove contaminated clothing
Rinse with flowing water
Seek first aid
Ingestion
Rinse mouth with flowing water
Seek first aid
Seek medical assistance
www.safety.ncl.ac.uk
Seek first aid
Safety shower
Seek medical assistance
Eye contact
Rinse with flowing water using eye wash station
Seek first aid
Seek medical assistance
Seek medical assistance
Injection
Seek medical assistance
Inhalation
Remove from source
Seek first aid
Seek medical assistance
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Chemical Safety v4 15/02/2011
14
Safety OfficeEmergency Wash Hose or Shower
Use handwash sink to wash contaminated hands
Use emergency wash hose to clean eyes, mouth, skin and body for personal contamination or injury
www.safety.ncl.ac.uk
y p j y
Use emergency drench shower to decontaminate body for serious personal contamination
Safety Office
Cyanides and Nitriles - Example Acetonitrile
Highly toxic, moderate irritant and possible systemic effects
Medical effects:
Ingestion: Burning sensation in throat, nausea, vomiting, dizziness, rapid breathing, unconsciousness and convulsions
www.safety.ncl.ac.uk
convulsions
Skin: May be absorbed through skin
Eye: Irritation, redness, pain and corneal burns
Respiratory tract: Severe irritant, shortness of breath, chest pains, agitation, unconsciousness and convulsions
Systemic effects: Metabolism: cyanide effect, nausea, vomiting, shortness of breath; and Kidney, Liver and Bone: possible long term effects
Safety OfficeCyanides and Nitriles First Aid
Medical assistance should be sought immediately
Onset of symptoms may be delayed 1-12 hours
Medical oxygen must be available before works starts
Skin contact: Remove all contaminated clothing immediately d i ith d t
www.safety.ncl.ac.uk
and rinse with soap and water
Eye contact: Rinse with flowing water and transfer to hospital
Ingestion: Give 100% medical oxygen by mask, do not perform mouth-to-mouth or mouth-to-nose ventilation, and transfer to hospital
Inhalation: Give 100% medical oxygen by mask, do not perform mouth-to-mouth or mouth-to-nose ventilation, and transfer to hospital
Safety OfficeAcetonitrile Poisoning
Case 1
Adult male, 60kg. Suicidal ingestion of ~5 mL of acetonitrile. No severe symptoms of intoxication. Elimination t½ = 32 hrs for acetonitrile and 15 hrs for cyanide
Case 2
www.safety.ncl.ac.uk
Case 2
Adult female. Post-mortem blood concentrations of 31 and 56 mg/dL of acetonitrile and 4.4 ug/mL of cyanide
Case 3
Adult female. Self-poisoning resulting in cyanide poisoning 11 hrs later. Conversion t½ = 40 hrs. Harmful blood cyanide levels for 24 hrs after ingestion
Conclusion: Monitoring of acetonitrile poisoning for 24-48 hrs
Safety OfficePhenol and Phenols
Highly toxic and corrosive
Medical effects:
Ingestion: Abdominal pain, vomiting and diarrhoea
Skin: Burning redness and may be major route of entry
www.safety.ncl.ac.uk
Skin: Burning, redness and may be major route of entry
Eye: Pain, redness, watering and blurred vision
Respiratory tract: Irritant, sore throat and shortness of breath
Systemic effects: CNS: drowsiness, dizziness, headache, collapse and coma; Kidney: extensive damage; and Skin: ochronosis
Safety OfficePhenol First Aid
PEG-300 solution and protective gloves must be available before work starts
Skin contact: Remove all contaminated clothing immediately, rinse with PEG-300 for 30 minutes and
www.safety.ncl.ac.uk
ytransfer to hospital
Eye contact: Rinse with flowing water not PEG-300 and transfer to hospital
Ingestion: Transfer to hospital
Inhalation: Transfer to hospital
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Chemical Safety v4 15/02/2011
15
Safety OfficeHydrofluoric Acid and Fluorides
Very highly toxic, corrosive and possible long term effects
Medical effects:
Ingestion: Abdominal pain, vomiting and diarrhoea
Skin: Deep burns and may be delayed
www.safety.ncl.ac.uk
Skin: Deep burns and may be delayed
Eye: Severe eye damage
Respiratory tract: Severe irritant, cough, difficulty breathing and possible systemic effects
Systemic effects: Lungs: pulmonary oedema (delayed), adult respiratory distress syndrome; and Bones: fluorosis
Safety OfficeHydrofluoric Acid First Aid
Calcium gluconate gel must be available before works starts
Skin contact: Remove all contaminated clothing immediately, rinse with water, apply calcium gluconate gel
www.safety.ncl.ac.uk
y pp y g gand transfer to hospital
Eye contact: Rinse with flowing water and transfer to hospital
Ingestion: Transfer to hospital
Inhalation: Transfer to hospital
Safety Office
Any questions?
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Ref:
COSHH Risk Assessment - Hazardous Substances v5 Page 1 of 3
Newcastle University
COSHH Risk Assessment A COSHH risk assessment is required for work with hazardous substances including source materials, products, known intermediates and by-products. The form should be completed electronically and approved and signed by the principal investigator or responsible person. Carcinogens and users of carcinogens must both be registered using the Carcinogen Registration forms on the Chemical Safety section of the Safety Office website. Guidance on completing this form is provided in the COSHH Risk Assessment section of the Safety Office website.
Title of project or activity [ENTER DETAILS HERE]
Principal investigator / Responsible person
[ENTER DETAILS HERE]
School [ENTER DETAILS HERE]
Date of assessment dd/mm/yyyy
Location of work (Buildings and room numbers)
[ENTER DETAILS HERE]
Section 1 Project or Activity 1.1: Brief description of project or activity [ENTER DETAILS HERE]
Section 2 Hazards 2.1: Hazardous substances used and generated Hazardous substance Risk Phrases Safety Phrases Workplace exposure
limit (WEL) Chemicals [ENTER DETAILS HERE] [ENTER DETAILS
HERE] [ENTER DETAILS HERE]
[ENTER DETAILS HERE]
Carcinogens, mutagens or reproductive toxins
[ENTER DETAILS HERE] [ENTER DETAILS HERE]
[ENTER DETAILS HERE]
[ENTER DETAILS HERE]
Dusts or fumes [ENTER DETAILS HERE] [ENTER DETAILS HERE]
[ENTER DETAILS HERE]
[ENTER DETAILS HERE]
Asphyxiants [ENTER DETAILS HERE] [ENTER DETAILS HERE]
[ENTER DETAILS HERE]
[ENTER DETAILS HERE]
Other substances hazardous to health
[ENTER DETAILS HERE] [ENTER DETAILS HERE]
[ENTER DETAILS HERE]
[ENTER DETAILS HERE]
Section 3 Risks 3.1: Human diseases, illnesses or conditions associated with hazardous substances [ENTER DETAILS HERE]
3.2: Potential routes of exposure Inhalation Ingestion Injection Absorption Other Select all that apply [ENTER DETAILS HERE]
3.3: Use of hazardous substances Small scale Medium scale Large scale Fieldwork Animals Plants Maintenance Cleaning Other
Select all that apply
[ENTER DETAILS HERE]
3.4: Frequency of use Daily Week Monthly Other Select one [ENTER DETAILS HERE]
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Ref:
COSHH Risk Assessment - Hazardous Substances v5 Page 2 of 3
3.5: Maximum amount or concentration used Negligible Low Medium High Select one [ENTER DETAILS HERE]
3.6: Potential for exposure to hazardous substances Negligible Low Medium High Select one [ENTER DETAILS HERE]
3.7: Who might be at risk (*Contact the University Occupational Health Service) Staff Students Visitors Public Young people (<18yrs) *New and expectant mothers Other [ENTER DETAILS HERE]
3.8: Assessment of risk to human health (Prior to use of controls) Level of risk
Effectively zero Low Medium/low Medium High
Select one
3.9: Assessment of risk to environment (Prior to use of controls) Level of risk
Effectively zero Low Medium/low Medium High
Select one
Section 4 Controls to Reduce Risks as Low as Possible 4.1: Containment Laboratory Room Controlled area Total containment Glove box Fume cupboard Local exhaust ventilation (LEV) Access control Other
Select all that apply
[ENTER DETAILS HERE]
4.2: Other controls [ENTER DETAILS HERE]
4.3: Storage of hazardous substances [ENTER DETAILS HERE]
4.4: Transport of hazardous substances [ENTER DETAILS HERE]
4.5: Personal protective equipment (PPE) Lab coat Overalls Chemical suit Disposable clothing Apron Spectacles Goggles Face shield Gloves Special headwear Special footwear Other
Select all that apply
[ENTER DETAILS HERE]
4.6: Respiratory protective equipment (RPE) Disposable mask Filter mask Half face respirator Full face respirator Powered respirator Breathing apparatus Other
Select all that apply
[ENTER DETAILS HERE]
4.7: Waste management and disposal Liquid Solid Gas Inorganic Organic Aqueous Mixed Other [ENTER DETAILS HERE]
4.8: Monitoring exposure (If you need advice contact the University Occupational Health Service) [ENTER DETAILS HERE]
4.9: Health surveillance (If you need advice contact the University Occupational Health Service) [ENTER DETAILS HERE]
4.10: Instruction, training and supervision Special instructions are required to safely carry out the work (If yes enter details below) Yes
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Ref:
COSHH Risk Assessment - Hazardous Substances v5 Page 3 of 3
[ENTER DETAILS HERE] Special training is required to safely carry out the work (If yes enter details below) Yes [ENTER DETAILS HERE] A: Work may not be carried out without direct personal supervision (If yes enter details below) Yes B: Work may not be started without the advice and approval of supervisor (If yes enter details below) Yes C: Work can be carried out without direct supervision Yes Supervisor(s) [ENTER DETAILS HERE]
Section 5 Emergency Procedures 5.1: Emergency procedures [ENTER DETAILS HERE]
5.2: Minor spillage or release Specify procedure [ENTER DETAILS HERE]
Other actions Evacuate and secure laboratory / area Yes
Inform competent person (eg principal investigator / school safety officer etc) Yes
5.3: Major spillage or release Specify procedure [ENTER DETAILS HERE]
Other actions Evacuate building by fire alarm Yes
Call security and fire brigade (6666 on campus) Yes Inform competent person (eg principal investigator / school safety officer etc) Yes
5.4: Fire Precautions Carbon dioxide Water Powder Foam Blanket Automatic fire suppression Other [ENTER DETAILS HERE]
5.5: First aid Wash with copious amounts of water and apply polyethylene glycol (PEG) 300 for phenol Wash with copious amounts of water and apply calcium gluconate gel for hydrofluoric acid Remove affected clothing and wash with copious amounts of water for skin contact Oxygen for cyanide Eye wash station Emergency shower Other [ENTER DETAILS HERE]
5.6: Emergency contacts Name Position Telephone
[ENTER DETAILS HERE] Principal Investigator / Responsible person [ENTER DETAILS HERE] [ENTER DETAILS HERE] [ENTER DETAILS HERE] [ENTER DETAILS HERE]
Section 6 Approval 6.1: Assessor Name Signature Date [ENTER DETAILS HERE] [ENTER DETAILS HERE] [ENTER DETAILS HERE]
6.2: Principal investigator / Responsible person Name Signature Date [ENTER DETAILS HERE] [ENTER DETAILS HERE] [ENTER DETAILS HERE]
Risk Estimation Matrix Severity of harm Likelihood of harm
High
Medium Low Negligible
Severe High High Medium Effectively zero Moderate High Medium Medium/low Effectively zero Minor Medium/low Low Low Effectively zero Negligible Effectively zero Effectively zero Effectively zero Effectively zero
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Ref:
DSEAR Risk Assessment - Dangerous Substances v1 Page 1 of 4
Newcastle University
DSEAR Risk Assessment A DSEAR risk assessment is required for work with dangerous substances which could cause fire or explosion including source materials, products, known intermediates and by products. The form should be completed electronically and approved and signed by the person responsible for the work. Guidance on completing this form is provided in the DSEAR Risk Assessment section of the Safety Office website. The risks from the dangerous substances and explosive atmospheres identified in this risk assessment must be reduced to the lowest level reasonably practicable.
Title of project or activity [ENTER DETAILS HERE]
Principal investigator / Responsible person
[ENTER DETAILS HERE]
School [ENTER DETAILS HERE]
Date of assessment dd/mm/yyyy
Location of work (Buildings and room numbers)
[ENTER DETAILS HERE]
Section 1 Project or Activity 1.1: Brief description of project or activity [ENTER DETAILS HERE]
Section 2 Hazards 2.1: Dangerous substances used and generated and explosive atmospheres Dangerous substance Risk Phrases Safety Phrases Lower
explosive limit (LEL %)
Upper explosive limit (UEL %)
Flammable range (LEL–UEL %)
Explosive [ENTER DETAILS HERE]
Oxidising [ENTER DETAILS HERE]
Extremely flammable [ENTER DETAILS HERE]
Flammable [ENTER DETAILS HERE]
Release of vapour, gas or dust could cause an explosive atmosphere
[ENTER DETAILS HERE]
Section 3 Risks 3.1: Use of dangerous substances or generation of explosive atmospheres Small scale Medium scale Large scale Storage Other Select all that apply [ENTER DETAILS HERE]
3.2: Frequency of use of dangerous substances Daily Week Monthly Other Select one [ENTER DETAILS HERE]
3.3: Maximum amount or concentration used Negligible Low Medium High Select one [ENTER DETAILS HERE]
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Ref:
DSEAR Risk Assessment - Dangerous Substances v1 Page 2 of 4
3.4: Ignition sources Are there any sources of ignition Yes [ENTER DETAILS HERE]
3.5: Explain how substances used or generated could cause a fire or explosion [ENTER DETAILS HERE]
3.6: Who might be at risk Staff Students Visitors Public Contractors Other [ENTER DETAILS HERE]
3.7: Assessment of risk (Prior to use of controls) Level of risk
Effectively zero Low Medium/low Medium High
Select one
Section 4 Controls to Reduce Risks as Low as Possible 4.1: Control measures Has quantity of dangerous substance held or used been reduced to minimum Yes Have steps been taken to avoid or minimise releases (intentional or unintentional) Yes Have steps been taken to control releases at source Yes Have steps been taken to prevent formation of an explosive atmosphere Yes Have steps been taken to collect or contain and remove any releases to safe place (eg ventilation) Yes Have steps been taken to avoid adverse conditions (eg exceeding temperature limits or other control settings)
Yes
Are incompatible substances kept apart in storage and so far as practicable in use (eg oxidisers and flammables)
Yes
Has number of people exposed to dangerous substances or explosive atmosphere been reduced to minimum
Yes
Is plant in use explosion resistant Yes Is explosion suppression or relief provided on equipment Yes Have adequate measures been taken to control or minimise spread of fire or explosion Yes Has suitable personal protective equipment been provided and have staff been trained how to wear it properly
Yes
[ENTER DETAILS HERE]
4.2: Workplace or process and management systems appropriate to nature of activity or operation Is workplace designed, constructed and maintained so as to provide adequate fire-resistance and or explosion relief
Yes
Is any assembly, construction, installation, rig, plant, equipment, protection system etc, designed in such a manner as to minimise risk of fire and or explosion
Yes
Is any assembly, construction, installation, rig, plant, equipment, protection system etc, used in such a way as to minimise risk of fire and or explosion
Yes
Have appropriate safe systems of work, or other required procedural systems of organising work, been developed and communicated to all persons who might need to know, either by way of this form or another document such as a method statement
Yes
Is a permit to work scheme required for working with substances or in work area, and are these strictly enforced
Yes
[ENTER DETAILS HERE]
4.3: Zoning and control of explosive atmospheres Contact the University Safety Office if it is considered that zoning is required Is zoning required Yes [ENTER DETAILS HERE]
4.4: Monitoring of flammable or explosive atmospheres Will you use any gas monitors with detection and alarm Yes Will you use fire detection Yes [ENTER DETAILS HERE]
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Ref:
DSEAR Risk Assessment - Dangerous Substances v1 Page 3 of 4
4.5: Storage of dangerous substances Are all dangerous substances kept in suitable fire resistant storage Yes Are all quantities of dangerous substances in excess of 50L kept in dedicated and appropriately protected flammable stores
Yes
Are incompatible substances stored apart (eg flammables, oxidisers, combustibles, flammable gases, LPG) Yes Where appropriate, have storage areas been designed to provide explosion relief or resistance Yes [ENTER DETAILS HERE]
4.6: Transport of dangerous substances Will dangerous substances be transported Yes [ENTER DETAILS HERE]
4.7: Personal protective equipment (PPE) Lab coat Overalls Chemical suit Disposable clothing Apron Spectacles Goggles Face shield Gloves Special headwear Special footwear Other
Select all that apply
[ENTER DETAILS HERE]
4.8: Respiratory protective equipment (RPE) Disposable mask Filter mask Half face respirator Full face respirator Powered respirator Breathing apparatus Other
Select all that apply
[ENTER DETAILS HERE]
4.9: Waste management and disposal Liquid Solid Gas Inorganic Organic Aqueous Mixed Other [ENTER DETAILS HERE]
4.10: Waste disposal Have suitable procedures been developed, communicated to personnel and implemented to deal with safe transport and disposal of dangerous substances
Yes
[ENTER DETAILS HERE]
4.11: Information, instruction, training and supervision Has appropriate information, instruction and training, commensurate with the potential danger of the dangerous substances or process been provided to personnel as regards product detail, hazard, risk reduction control methods to be employed, management systems to be followed, emergency systems etc
Yes
Special instructions are required to safely carry out the work (If yes enter details below) Yes [ENTER DETAILS HERE] Special training is required to safely carry out the work (If yes enter details below) Yes [ENTER DETAILS HERE] A: Work may not be carried out without direct personal supervision (If yes enter details below) Yes B: Work may not be started without the advice and approval of supervisor (If yes enter details below) Yes C: Work can be carried out without direct supervision Yes Supervisor(s) [ENTER DETAILS HERE]
4.12: Safe system of work Has a safe system of work been established for all aspects of the use and storage of dangerous substances. Provide full details of your safe system of work
Yes
[ENTER DETAILS HERE]
Section 5 Emergency Procedures 5.1: Emergency procedures Have suitable emergency procedures been developed and communicated to personnel to deal with adverse process conditions (eg exceeding limits of temperature, or other control settings)
Yes
Have suitable emergency procedures been developed and communicated to personnel to deal with fire and evacuation
Yes
Have suitable emergency procedures been developed and communicated to personnel to deal with a Yes
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Ref:
DSEAR Risk Assessment - Dangerous Substances v1 Page 4 of 4
spillage of dangerous substances [ENTER DETAILS HERE]
5.2: Minor spillage or release Specify procedure [ENTER DETAILS HERE]
Other actions Evacuate and secure laboratory / area Yes
Inform competent person (eg principal investigator / school safety officer etc) Yes
5.3: Major spillage or release Specify procedure [ENTER DETAILS HERE]
Other actions Evacuate building by fire alarm Yes
Call security and fire brigade (6666 on campus) Yes Inform competent person (eg responsible person / school safety officer etc) Yes
5.4: Fire Precautions Carbon dioxide Water Powder Foam Blanket Automatic fire suppression Other [ENTER DETAILS HERE]
5.5: Emergency contacts Name Position Telephone
[ENTER DETAILS HERE] Principal Investigator / Responsible person [ENTER DETAILS HERE] [ENTER DETAILS HERE] [ENTER DETAILS HERE] [ENTER DETAILS HERE]
Section 6 Approval 6.1: Assessor Name Signature Date [ENTER DETAILS HERE] [ENTER DETAILS HERE] [ENTER DETAILS HERE]
6.2: Principal investigator / Responsible person Name Signature Date [ENTER DETAILS HERE] [ENTER DETAILS HERE] [ENTER DETAILS HERE]
Risk Estimation Matrix Severity of harm Likelihood of harm
High
Medium Low Negligible
Severe High High Medium Effectively zero Moderate High Medium Medium/low Effectively zero Minor Medium/low Low Low Effectively zero Negligible Effectively zero Effectively zero Effectively zero Effectively zero