Chemical Homeland Security SystemChemical Homeland Security System

C-HoSSC-HoSS(s)(s)

Chemical Compliance Systems, Inc.Chemical Compliance Systems, Inc.706 Route 15 South, Suite 207 • Lake Hopatcong, NJ 07849 • 973-663-2148 • (fax) 973-663-2378

georgethompson@chemply.com • www.chemply.com

CHEMICAL HOMELANDSECURITY SYSTEM

[C-HoSS]

BIOLOGICAL HOMELANDSECURITY SYSTEM

[B-HoSS]

RADIOLOGICAL HOMELANDSECURITY SYSTEM

[R-HoSS]

CCS CapabilitiesCCS Capabilities

MUNITIONS ANALYTICAL COMPLIANCE SYSTEM

[MACS]

CENTRALIZED CHEMICAL HAZARDand ENVIRONMENTAL

MANAGEMENT SYSTEM[C-CHEMS]

ISO 14001 EMSWeb-based ISO 14001 System

reduces implementation time

and cost by 300-400 manhours

ISO 14001 drawsregulatory data

(Air, Water, etc.)to expedite compliance,

highlight conformance and reduce

wastestreams

SecureWeb Access

Options

GISData

Sources

SensorDataInput

WirelessCommunication

Options

BIOLOGICAL HOMELANDSECURITY SYSTEM

[B-HoSS]

Regulations

Biological Agents

Radioisotopes

Security Factors

Agent Simulants

Chemical Agents

Chemicals

Munitions

Commercial Products

CCSCentralizedDatabase

Radioisotopes

Organisms

CCS Homeland Security Systems (HoSS)CCS Homeland Security Systems (HoSS)

Chemicals

CCSCentralizedDatabase

RADIOLOGICAL HOMELANDSECURITY SYSTEM

(R-HoSS)

• Preparation & Planning• Surveillance• First Responders• Hospital Staff• Security• Risk Assessment• Emergency Response• Training

BIOLOGICAL HOMELANDSECURITY SYSTEM

(B-HoSS)• Preparation & Planning• Surveillance• First Responders• Hospital Staff• Laboratory• Risk Assessment• Emergency Response• Training

CHEMICAL HOMELANDSECURITY SYSTEM

(C-HoSS)• Security & Containment• Chemical Tracking• Munitions Suite• Hazardous Waste• Storage Tanks• Air• Water• Pesticides• Toxics• Industrial Hygiene• Chemical Safety• Solid Waste

SecureWeb Access

Options

WirelessCommunication

Options

GISData

Sources

SensorDataInput

2,125,000

COMPENDIUM OF TOXIC EFFECTS OF

CHEMICAL SUBSTANCES

A compilation of acuteand chronic health effects

for 140,000 chemicals

500,000

CHEMICAL CROSS REFERENCE DICTIONARY

A cross-referencing system of CAS numbers and their

associated synonyms

450,000

LIST OF LISTSReference listings for

4,650 regulated hazardous chemicals and associated data found on 430 local, state, federal and international lists

2,500

CAMEOInformation data for

responders to hazardous chemical emergencies

(firefighting, health, first aid, etc.)

1,050

OIL & HAZARDOUS MATERIALS TECHNICAL

ASSISTANCE DATA SYSTEM

Information relating to spill response and

harmful effects

1,100

CHEMICAL HAZARD RESPONSE

INFORMATIONSYSTEM

Comprehensive source of preventive, precautionary

and response data

6,400

SAFE CHEMICAL STORAGE CODESChemical hazard and

compatible family storage classifications for 3,200

chemicals

Master Chemical Reference Data

(3,176,950 References)

CCS

4,500

CHEMICAL COMPOUND

DICTIONARYTabulation of 4,500

specific chemicals within 58 compound categories

6,400

CHEMICAL DISPOSAL CODESDisposal and compatible chemical family storage

classifications for 3,200 chemicals

80,000

RATING INFORMATION OF

CHEMICAL HAZARDSA rating classification covering health, fire,

reactivity, environmental,protective equipment,

etc., for 3,200 chemicals

265,000

MANUFACTURERSDetailed information for 8,200 manufacturers of

chemical products

Master Product Reference Data

(11,000,000 References)

CCS

6,925,000

ITEM INDEX & PRODUCT

DESCRIPTIONSUnique identifiers for

over 100,000 chemical product items 3,000,000

PRODUCT COMPONENTS

Specific descriptors for more than 300,000

product components

375,000

PRODUCT USER DIRECTORY

Dictionary listing of organizations that use

each of the 75,000 unique items

360,000

MSDS INDEXSearchable parameters for each of our 60,000

imaged MSDSs

75,000

MSDS IMAGESMode 4 TIF multi-page images of manufacturer

MSDSs

670

PROCESS CODESDictionary of USN, DA

and MD categories used to track HM usage and

HW generation

413

GENERIC CATEGORIES

Product classification codes derived from

federal/state commodity lists that categorize

similar products

The CCS “Core” Chemical DatabaseThe CCS “Core” Chemical Database

DiagramsDrawingsSpecifications Standards

Enhanced MIDAS Database LibraryEnhanced MIDAS Database LibraryMunitions [6566] RRD Inventory [Stockpile]

Components [19,771] Parts [67,503]

Bulk Item Materials [3062] PEP Materials [1824] Inert Materials [2957]

Bulk Compounds [7917] PEP Compounds [7188]

Parts Environmental Disposition

Compound Elements

Regulatory Database

MCNLibrary

MilSpecReview

CAS # and Synonyms Dictionary

Alloy MetalContent Nonmetal Chemical

Content

Inert Compounds [19,104]

Regulated Hazardous ChemicalsRegulated Hazardous ChemicalsAcute Hazard OrientationAcute Hazard Orientation

ChemicalSecurity

RisksList

Chemical AgentsNeurotoxins

ExtremeToxins

RadioactivesExplosives

Shock SensitivesCorrosivesFlammable

OxidizersHazardous Air Pollutants

Persistent Bioacccumulative ToxinsPriority Pollutants

ACGIHDEADOTEPAOSHACaliforniaIowaMarylandNevadaNew JerseyEuropean Community

Canada Export Control Lists

DOC Export Restrictions

CPSC Specialty Regulated Substances

DEA Precursor Chemicals

DEA Essential Chemicals

IATA Air Transport Forbidden

EU Black/Gray Lists

IATA Regulated Substances

IATA Passenger Transport Forbidden

UN/FAO Prior Informed Consent

UK The Red List (Water)

Precursor ChemicalPrecursor ChemicalSecurity Risks ListSecurity Risks List

Properties Toxicology Data Hazards Incompatibilities Storage

Recommendations

Chemical Agents and SimulantsChemical Agents and Simulants

—Structure—Chemical—Physical

—Human—Animal—In Vitro

—Protection—Decontamination—Persistence—Use

—Chemical—Conditions—Containers

—Container—Conditions—Distances—HSASa Variables

____________________________________a HSAS = Homeland Security Advisory System

Toxic Industrial Chemicals/Toxic Industrial Toxic Industrial Chemicals/Toxic Industrial Materials (TICs/TIMs)Materials (TICs/TIMs)

Selected Examples

Industrial Feedstocks: Acrylamide, Chlorine, Hydrogen Chloride, Phosgene

Carbamate Insecticides: Baygon, Mobam, Temik, Zectran

Organochlorine Insecticides: Aldrin, Dieldrin, Endrin, Lindane, Heptachlor

Organophosphate Insecticides: Disulfotan, Mevnphos, Parathion, Methylparathion

Insecticide Synergists: Piperonyl Butoxide

Fungicides: Pentachlorophenol, Hexachlorobenzene, Maneb, Naban, Zineb

Seed Disinfectants: Methylmercury Acetate, Methylmercury Cyanide

Fumigants: Calcium Cyanide, Methyl Bromide, Phosphine

GOALS: [1] Identify all chemicals with severe to extreme acute toxicity[2] Identify all chemicals in product classes with similar mechanisms of action

Incompatible Chemical DatabaseIncompatible Chemical Database

ChemicalClass Chemical

IncompatibleChemical

I.C. Class

InteractionHazard

Corrosives

Flammables

Reactives

Products

Acetic AcidNitric AcidChlorine

AcetoneBenzene

Carbon Disulfide

NitrotolueneNitroethaneAcrylonitrile

Toilet Bowl CleanerBleach

Paint Solvent

Hydrogen PeroxideAcetylene

Aluminum Powder

ChloroformChlorine

Potassium

Sulfuric AcidHydrocarbons

Bromine

Metal PowdersAmmonia

Chloroform

OxidizerFlammable

Metal

CarcinogenCorrosive

Flammable

CorrosiveCombustible

Corrosive

MetalsProduct

Carcinogen

ExplosionExplosion

Spontaneous Fire

ExplosionExplosion

Violent Explosion

ExplosionExplosionExplosion

ExplosionPoisonous Gas

Explosion

Radioisotopes DatabasesRadioisotopes Databases

Regulations

Biological Agents

RadioisotopesSecurity Factors

Agent Simulants

Chemical Agents

Chemicals

Munitions

Commercial Products

CCSCentralizedDatabase

Generic Families

Properties

Cellular Effects

Systemic Effects

Biophysical Actions

Storage & Security

Diagnosis

Treatment

Infection Management

Decontamination

Regulation Images & Index

Planning & Response

Date Received

Location

Container Data

Product Transaction & Cumulative Chemical Database with Local, Standardized

Materials Management Analyses

Master Chemical Reference

Data

Master Inventory Reference

Data

Item Index

Product Desc.

Product Comp.

Cont. & Storage Codes

Process Codes

Mfr. Table NSNs Locations

MSDS Index

MSDS Images

PPE

Dispose

Storage

Spill

Exting.

Environ. Hazards

Special Hazards

Chemical Hazard Rating

Physical Data

Air, Water, Soil Data

Oxydizers, Radioactives, H2O-Reacts.

Physical Hazards

Health Hazards

Synonym/ CAS #

Dictionary

List of Lists

Generic Dictionaries

C-CAS Centralized Database Module

Bar Code

QuantityDisposal Code

Mfr. Date

Exp. Date

Manufacturer

Trade Name

ComponentsSize

Local Data

Physical State

Storage Code

Unit of Issue

Item Number

Process Data

C-CASSite Data Acquisition Module

(multiple locations)

Area Inventory

Automated Usage Scales

Container Bar Code

User Bar Code

C-CASManufacturing Data Acquisition Module

User ID ManifestLocation

Waste Code

Container Bar Code

Waste Profile

Type of Generation

Waste ProcessQuantity

Disposed

Label Placard

C-CASWaste Module Recycled

Treated Energy

Chemical Compliance Analytical System (C-CAS)Chemical Compliance Analytical System (C-CAS)

Totals

Mfrs.

Chems.

EPA

DOT

State

Carcin.

Neurot.

TLVs

PELs

Acute

Chronic

Flam.

Explos.

Corros.

Units

Prods.

Locat.

OSHA

NRC

Int'l.

Terato.

Procurement Analyses

Activity/Tenant Analyses

Specific Regulations

Combination Regulations

Combination Hazards

Environmentally Preferable

Product Analyses

Environmental Safety & Health

Analyses

Regulatory Impact Analyses

HierarchicalMaterials

Management Analyses

C-CAS Analytical Report Module

Specific Hazards

C-CAS Communication Module

(connects multiple locations)

Proprietary Capabilities Provided as a Service from CCS

AnalyticalReports

Local User

Data Input

CustomizedCompliance Management

Software

CentralizedDatabases

UnassessedComponents

ComponentAssessment

Turnkey SupportExisting/Proven SOPs

Inventories Research

The CCS Approach forThe CCS Approach for Total Systems Customization and MaintenanceTotal Systems Customization and Maintenance

Regulations

Security Factors

Agent Simulants

Chemical Agents

Chemicals

Munitions

Commercial Products

CCS Core CCS Core DatabaseDatabase

Centralized and Relational Databases

Air (A-CAS)Permits

ProcessesTest Results

Locations & TypesProcesses

Test Results

Industrial Hygiene (IH-CAS)

Toxics (T-CAS)

Locations & TypesInspectionsTest Results

Pesticides (P-CAS)

PermitsSchedulesInspections

Product Security & Containment(PS-CAS)

Chemical RisksProduct Storage Codes

Security Standards

Solid Waste (SW-CAS)

Locations & TypesSchedules

Dispositions

Hazardous Waste (HW-CAS)

Locations & PermitsSchedules

Dispositions

Storage Tanks (ST-CAS))Types & History

PermitsInspection Criteria

Munitions (M-CAS))MIDAS Characterization

ConstraintsDispositions

Chemical Safety (CS-CAS))Hazards

IncompatibilitiesStorage

Water (W-CAS))Permits

TreatmentsTest Results

Chemical Tracking (C-CAS)or Existing System

Chemicals/ProductsMSDS Images/ Index

Location

Chemical Homeland Security System (C-HoSS)Chemical Homeland Security System (C-HoSS)

SecureWeb Access

Options

WirelessCommunication

Options

GISData

SourcesSensorDataInput

•Theft Risk Grades (1-4) (per product)

C-HoSS Security Criteria and StandardsC-HoSS Security Criteria and Standards

•Chemical Hazard Class Rankings (by Hazard Class)•Chemical Hazard Grades (1-4) (within each ranking)•Product Concentration Grades (1-4)

•Accessibility Factor Levels (Storage Constraint Levels and Descriptors) (0.5 - 4.5)

Chemical Hazard Factor (CHF) = Ranking Grade Concentration

Chemical Security Risk Factor (CSRF) = Ranking Grade Concentration Theft Risk

CMRF Accessibility Factor (AF) = Vulnerability Factor (VF)

•Population at Risk Grades (1-4)

Chemical Mortality Risk Factor (CMRF) = Ranking Grade Concentration Theft Risk Population Risk

C-HoSS Capabilities vs. Chemical Security ProceduresC-HoSS Capabilities vs. Chemical Security Procedures

Security Procedure Phases

Integration of C-HoSS w/ the chemical tracking systemDaily C-HoSS correlation w/ the Homeland SecurityAdvisory System

C-HoSS Capabilities

Phase I Vulnerability AssessmentIdentify chemical hazards, security risks, mortality risks

Phase II Countermeasures ImplementationReduce vulnerabilities

Phase III Verification AuditIndependently confirm counter measure adequacy

Phase IV Management System IntegrationIntegrate chemical security procedures into line management functions

Chemical Hazard Factor ReportChemical Security Risk Factor ReportChemical Mortality Risk Factor ReportChemical Vulnerability Risk Factor Report

Accessibility Factor (Storage Constraint) Report(per chemical/material)

Chemical Vulnerability Factor “Report Card”(to the local fire department)

First Responder System to Prevent Chemical ExposuresFirst Responder System to Prevent Chemical Exposures(FRST-PCE) Database(FRST-PCE) Database

Agents

NameFormula

CodeCAS

Number

State@

20OCSolidColor

VaporColor Odor

VaporDensity(Air=1) Stability

PhysicalAction Action

FieldDetection

Choking PhosgeneCOCl2

CG

75-44-5 Gas n/a Colorless New Mown HayGreen Corn

3.4 Stable inDry Steel

Drums

Lungs Delayed Odor

Nerve SarinCH3PO(F)OCH(CH3)2

GB

107-44-8 Liquid n/a Colorless None 4.9 Stable Breathing Quick Alarms (5)Papers (2)

Blood HydrogenCyanide

HCNAC

74-90-8 Gasor

Liquid

n/a Colorless Bitter Almonds 1.0 Stable Interferes withO2 Use

Quick Alarms (4)

Blister Mustard(ClCH2CH2)2S

HD

505-60-2 Liquid n/a PaleYellow

GarlicHorseradish

5.4 Stable inSteel/Al

DestroysTissue

Delayed Papers (5)

Vomiting Diphenylchloroarsine(C6H5)2 AsCl2

DA

696-28-6 Solid Whiteto

Brown

n/a None FormsLittleVapor

Stable Cold/FluSymptoms

Former RiotControl

None

Tear ChloroacetophenoneC6H5COH2Cl

CN

532-27-4 Solid ? n/a Apple Blossoms 5.3 Stable Eye/LungIrritation

Riot Control None

Incapacitating 3-quinuclidinyl benzilate

BZ

6581-06-2 Crystals White n/a None 11.6 Adequate HR Dizzy

Disorientation

DelayedFormer

Incapacitation

None

Binary Methylphosphonic-difluorideCH3POF2

DF

676-99-3 Liquid n/a ? Pungent 3.5 StableReactive

Eye/LungStrong Irritant

Forms GB n/a

Contact

Dr. George R. Thompson973-663-2148

georgethompson@chemply.com

706 Route 15 South, Suite 207 • Lake Hopatcong, NJ 07849 • 973-663-2148 • (fax) 973-663-2378georgethompson@chemply.com • www.chemply.com

For more information . . .

C-HoSSC-HoSS