Chem. Rev. 2010, 110, 1435–1462

Chem. Rev. 2010, 110, 1435–1462

K. Inamoto et al. JOC, 2009, 694, 389–396

K. Inamoto et al. JOC, 2009, 694, 389–396

David J. Michaelis et al. Acs Catal. 2018, 8, 86-89

David J. Michaelis et al. Acs Catal. 2018, 8, 86-89

David J. Michaelis et al. Acs Catal. 2018, 8, 86-89

310 mg

1 mmol

300 mg

1.3 mmol 500 mg

Yield : 92 %

120°C

3 h

David J. Michaelis et al. Acs Catal. 2018, 8, 86-89

270 mg

0.5 mmol

+

61 mg

0.65 mmol

THF 5 mL

6 h, r.t

Methylallyl nickel

chloride dimer

in 3 mL toluene

75 mg 0.25 mmol

+

puffy white solid

in 2 mL toluene

250 mg 0.5 mmol

2 h, r.t.

puffy white solid

(226 mg, Yield : 90 %)

(260 mg, Yield : 80 % )

David J. Michaelis et al. Acs Catal. 2018, 8, 86-89

dissolved in

benzene/Hexane

(V:V, 2:11)

and passed

through celite

dissolved in

benzene

and passed

through celite

J. Am. Chem. Soc. 2015, 137, 15600–15603

Evaluation of Catalysts for Synthesis of 1,1,1- Tris(boronate) 1oa from Styrene and B2pin2

J. Am. Chem. Soc. 2015, 137, 15600–15603

Co-Catalyzed Synthesis of 1,1,1-Tris(boronates) from Various Vinylarenes

Future work