Chemistry 314 - Spring 2015

Problem Set #6 Due: Friday, March 6.

Problems from McQuarrie

5-13

5-15

5-21 (Only show that 𝜓1 (𝑥) satisfies the Schrödinger equation)

5-22 (Only show that 𝜓0 (𝜉) is orthogonal to 𝜓1 (𝜉) and 𝜓2 (𝜉) and that 𝜓1 (𝜉) is

orthogonal to 𝜓3 (𝜉).)

5-26

5-29

5-41 (Use 300. K and 2000. K for significant figures)

Additional Problems

1) For the infrared spectrum of 1H35Cl there is an intense line at 2886 cm−1 .

Calculate the force constant of 1H35Cl.

2) 2H35Cl has the same force constant as 1H35Cl (additional problem #1). What is

the fundamental vibrational frequency of 2H35Cl in wavenumbers (cm−1)?