chee seminar march 2016 l hubbard v2-pic
TRANSCRIPT
Electrostatic Coating with Ligandless Copper Nanoparticles
Metallic Nanoparticles (NPs): Low Temperature Metallization
Applications Low Temp. Metals
Why Work with Copper
Nanoparticle Formation
Conductive Copper Nanoparticles
Ligands and Charge Compensators
Nanoparticle Ion Cloud
Synthesis and Characterization
Positive Charges: Substrate-Film Formation
Approach to Deposit Blanket Films
Metal-Nanoparticle Thin Films, Features
TEM Bath Coated Cu Films
Films → Properties
Surface Plasmon Resonance
Light Absorbance vs. Ionic Liquid Conc.
Photoluminescence vs. IL Conc.
X-Section High Angle SEM: Void vs. IL Conc.
Ellipsometry Model: Oscillators
Ellipsometry: Polydisperse NPs and Increased Particle Interactions
Properties → 3D Deposition
Polymer Removal
Cu NP Thin Film after 1 min Dep.
Cu NP Multilayer Film, 2 min Dep.
50 nm Discontinuous Film, 1 min Dep.
150 nm Thick Films, 2 min Dep.
Metallized Flexible-Bendable Substrates
Conclusions
Back up
EMA Fractions and Depolarization: Interparticle interactions
Sintering vs. IL
Reaction Mechanism
Cu NP Thin Film after 1 min Dep.
Metal Plating
X-TEM: ≤3 nm Dia. Nanoparticles
Cross Section SEM and Ellipsometry
Other Ellipsometry Parameters
Ellipsometry Parameters
UV-Vis vs. IL Conc.: Max Abs. at 2.1-2.4 mM IL Conc.
Glass and Amine Termination is Influenced by Initial pH of
Substrate
SEM Bath Coated Cu Films
SEM of Bath Coated Cu Films
Copper Nanoparticles: Oxidation
Solution Cycle Coating of Cu NPs
Reaction Coating: Alternate Substrates
Nanoparticle Ion Cloud