Please note that though we try our best to correct all errors in reprint, not all changes involving figure will be incorporated into book reprints, but they are listed here so that you know we are aware of the error.

Chapter Page # Issue Correction (highlighted

where applicable) Image from text(where Applicable)

Preface xxxiii A name was omitted from the list of acknowledgments.

Laurie Butler, University of Chicago

1 3 Chapter opening image: The wrong image was used in this figure.

Correct image

1 18 Equation 1.2: a = (eme)E

Equation 1.2 should be:

1 19 Line 2: t = ℓv t = ℓ/v

1 19 Line 4: L/ℓ Insert “2” in front of (L/ℓ).

1 19 Line 5

Additional sentence should be inserted after line 5: This magnification factor is not exact, but is a very good approximation for small deflection, achieved when L >> S, which is the common condition for these experiments.

1 19 Unnumbered figure

The blue curve representing deflection of the particle should remain collinear with the undeflected beam to the left of the plates labeled + and -. The deflection away from the undeflected beam direction should start only after the particle has entered the space “between” the plates. The blue curve should transition to a straight line to the right of the plates, to signify the particle is not being accelerated in this region.

1 19Equation 1.5 Insert 2 in front of L/ℓ

Remove the factor ½

1 19 Equation 1.6: FE = eE = Delete = after eE

3 98 1st paragraph, line 5: sodium ion Should be: potassium ion

4 147 2 lines above Equation 4.3: osc

Equation 4.3: oscShould be: Eosc

4 155 Equation 4.14b

Insert minus sign to the right of the equals sign.

4 156

2 lines above Equation 4.15: “light is emitted…”

1st line after Equation 4.16: “from a photon as it undergoes…”

Should be: “light of frequency is emitted” (this is the lowercase Greek “nu).

“from light as it undergoes...”

4 175

1st paragraph below Figure 4.27:“middle panel” (line 7)“right hand panel” (line 9)“left hand panel” (line 10)

Should be: “left panel” (line 7)“middle panel” (line 9)“right hand panel” (line 10)

5 196 Equation 5.2b

Equation 5.2 b should read as follows:

5 201 Figure 5.7, part c

1. The red curve for should be re-drawn so its minimum intersects the vertical line that comes down from the point 2a0 in part b; at present the minimum in the red curve is too far to the right. 2. The red curve for should be re-drawn so its second minimum intersects the vertical line that comes down from the point 7.1a0 in part b; at present the second minimum in the red curve is too far to the right.

5 204

After p Orbitals heading:2, 1 1 (paragraph 1, line 4), 5 1 (paragraph 1, line 6)21,0, and 11 (paragraph 1, line 6)

(paragraph 2, line 5)

Should be:2ℓ + 1

-1, 0, and +1

5 213 2 lines above Equation 5.9: “We use Єn…”Equation 5.9: Єn

In both places, the Є should be replaced with the Greek letter epsilon, ε.

5 214

2nd paragraph, itemized list, item 1, line 2: (2s)

Example 5.3, Solution line 1: Є1s

Should be:(2s, 2p)

ε1s (this is the Greek epsilon)

5 222 Equation 5.12: -ЄαReplace Є with Greek letter epsilon, to read -εα

5 227

After “Electron Affinity” heading, 1st sentence:

“The electron affinity, EA, of an atom is the energy released when an electron is added to it (see Section 3.5).”

Sentence should be:

“The electron affinity, EA, of an atom X is the energy required to detach an electron from the anion X- and give the free atom X (See Section 3.5)”

5 233 Problem 30:Column of numbers on left side, 4th entry: s

Should be:3s

6 264

Figure 6.21Right hand side of label d: Right hand side of label b: *

Image

Changes in the labels:(d) replace with * (b) replace * with

Make the changes in the images that appear in the right-hand column of the figure:Parts (a), (b), and (d) have two black dots along with the red and blue shapes. These pairs of black dots should be aligned vertically. 1. The images in (b) and (a) should be shifted horizontally to the right so their black dots align vertically with the black dots in (d).2. The image in (c) horizontally should be shifted to the right so its single black dot is vertically aligned with the right-hand black dot in (d), (b), and (a).

6 272

Left-hand column, 4th figure (diagram for NH3:

The diagram for NH3 should have an unshared pair of electrons placed above the N atom.

6 275 Figure 6.28, parts (b) and (d)

The following changes should be made in the figure:1. In part (b), the upper and lower red-blue objects should be shifted horizontally so their black dots are aligned vertically.2. In part (d), two black dots should be added. The red objects should be shifted horizontally so their black dots are aligned vertically.

6 279 Figure 6.34, part (a): “pi bond” label Change the label “pi bond” to read “ bond”

6 306 Problem 60, line 1: localized π Should be: localized σ

9 410

Figure 9.11 caption: “Velocity is shown by an arrow of length v. It can be separated into three components, vx, vy, and vz, along the three Cartesian coordinate axes and projected into the x-y plane.”

Figure 9.11 caption should be: “Velocity is shown by an arrow of length v. It can be separated into three components, vx, vy, and vz, along the three Cartesian coordinate axes and projected into the x-y plane.”

9 412Paragraph after equation 9.12:

mu2Delete extra space between

and mu2

9 420Equation 9.22:

Delete extra space before -

9 424 1st paragraph, line 2: NA and NBN should be italicized: NA and NB

9 428

Right hand column, 2nd paragraph, chemical formulas: UO2(SO4)3

4− & UO2(CO3)3

4−

Right hand column, 4th paragraph, chemical formulas in equation:2NH3 + 2UO2(SO4)3

4− (NH4)2U2O7 + 4SO4

2−

Chemical formulas should be:2nd paragraph:

& 4th paragraph: 2NH3 + 2

(NH4)2U2O7 + −

9 429 Let hand column, chemical equation: UF4 + F2 = UF6

Chemical equation should be:UF4 + F2 = UF6

9 431 Chapter summary, Section 9.2, 1st bullet, 7th line: height h: P = ρgh

Font of h needs to match font used in equation immediately following:

height h: P = ρgh

9 435 Answers, part (c): Chemical formula should be:

12 537Text to the right of Table 12.2:

Add lowercase Greek “mu” to end of equation. Equation should read:

12 540 Caption for Figure 12.12

End of caption should include: (Adapted from Donald R. Olander, General Thermodynamics, New York, CRC Press, 2007)

12 541 Paragraph 1, line 3 end: “…3R, which is 24.9 J K-1.”

Should be: “…3R, or 24.9 J K-1 mol-1.”

12 541Example 12.5, line 8: text reads, “The vibrational contribution= 36.02=29.10=6.92 J mol-1 K-1” The second equal sign, should be

Text should read, “The vibrational contribution= 36.02-29.10=6.92 J mol-1 K-1”

a minus sign.

12 548Example 12.8, line 13(4th from last line in text): The subscript on the first “H” should be 2, not 1.

Should read, ΔH2 = 2ΔH°

f (NO2)

12 555

1st sentence above Figure 12.20: “Figure 12.20 compares the adiabatic expansion of this to the isothermal expansionof Example 12.11.”

Sentence should be: “Figure 12.20 compares the adiabatic expansion of Example 12.11 to the isothermal expansion of Example 12.10.”

12 557 Last paragraph, line 2: “We know from Chapter 4 that …”

Sentence should start: “We know (Chap.3 page 103) that…”

12 559 Figure 12.21, caption last line: CO Should be: Br2

12 567 Problem 54, The equation should have a factor “2” in front of the right hand side. Should be: 2 HgAl(Cl)2(g)

13 581Caption for Unnumbered figure in Margin: “performs 10 kJ or work on its surroundings”

Caption for Unnumbered figure in Margin: “performs 10 kJ of work on its surroundings”

13 586

Example 13.6, equations at bottom of page: −M (0.46 J K−1 g−1)(273.15 K − 373.15 K) = (10.0 g)(334 J g−1)M = 73 g

Replace M with m (x2):−m (0.46 J K−1 g−1)(273.15 K − 373.15 K) = (10.0 g)(334 J g−1)m = 73 g

13 588 Example 13.7, below the box, line 1 of text: Insert the word “isothermal” in italics

Should read: “For reversible and irreversible isothermal processes connecting the same pair…”

15 671 Acid-Base reaction: 2nd half of reaction incorrectly labeled

Positions of “Acid2” and “Base1” need to be swapped.

15 672 Acid-Base reaction: 1st half of reaction incorrectly ordered H2O(ℓ) + NH3(aq)Acid1 Base2

Positions of H2O with label “Acid1” should be swapped with NH3 with label “Base2”NH3(aq) + H2O(ℓ)

Base2 Acid1

15 677Autoionization of Water, Lewis Structures: acid/base labels in incorrect positions

Base(1) should be Acid1

Acid(2) should be Base2

Acid(1) should be Acid2

Base(2) should be Base1

15 678 Strong Acids and Bases: labels under reaction - Base(2), Acid(1), Acid(2), Base(1)

Delete parentheses around numbers and subscript all numbers – Base2, Acid1, Acid2, Base1

15 679 Labels under reactions - Base(2), Acid(1), Acid(2), Base(1)

Delete parentheses around numbers and subscript all numbers in both reactions – Base2, Acid1, Acid2, Base1

17 777Top of page, 1st 2 equations:O2 + 2 H2O + 4 e− 4 OHO3 + H2O + 2 e− O2 + 2 OH

Add superscript negative/minus sign after OH - O2 + 2 H2O + 4 e− 4 OH−

O3 + H2O + 2 e− O2 + 2 OH−

18 873Middle of page, paragraph starting “We could solve…”:Line 3: [ET]

Should be: [ET]

18 874

First paragraph, third line from end:Vmax = k2[ET]

Figure 18.23

Should be: Vmax = k2[ET]

The figure should be modified as follows: Delete "Km = " from the label on the left-hand side. Follow the horizontal dashed line from "Vmax/2" to its intersection with the dark red curve. From this intersection point, drop a vertical dashed line downward until it intersects the horizontal axis. Label this new point of intersection as "Km"

20 949 Equation 20.4a: J 2 = J(J +1)(h/2π)2

Equation 20.4 a should read as follows:

20 950 Equation 20.6

The Greek delta should be deleted from the left side of the equation.In the last line J should have a subscript i, Ji.

20 956-957

Equation 20.10, p. 956Figure 20.15, p. 957

x in Equation 20.10 and in Figure 20.15 represents R - Re.

20 957 Figure 20.15 All vibrational levels should be moved down by 1/2 h nu so that E = 1/2 nu for v (vee) = 0.

20 961 Figure 20.18

The upper horizontal red line is in the wrong position. It should be lowered to coincide with the lowest grayish-green line, which is the vibrational ground state. The double arrow labeled D0 should be extended downward to meet the upper red line in its new position.

20 975

7th line from bottom: “…where NA is Avogadro’s number.”Last three equations:

For all these instances:

NA should just be N.

20 987 Figure 20.39

The vibrational wave function in the upper state is not correct.  It should be the v = 5 (italic lower case vee) wave funtion, which has considerably more overlap with the ground state wave function than does the v = 2 wave function shown in the current figure.

Add the following sentence to caption:"In this illustration the maximum overlap occurs between the v = 0 (italic lower case vee) vibrational level in the electronic ground state to the v = 5 (italic lower case vee) vibrational level in the electronic excited state."  

20 1026

Problem 26:H3CCH2CH2(CH3)CH2OH(CH3)3OCH3

Chemical formulas should be:H3CCH2CH(CH3)CH2OH(CH3)3COCH3

Appendix G A.67

Chapter 12, Problem 13:Minus sign must be inserted on right side of equation, and C should be changed to c.

Desired result:

Appendix G A.72

Answers to problems 35 through 55 have been scrambled. The problems are numbered correctly at the end of Chapter 16, and the solutions are numbered correctly in the Student Study Manual. This error appears only in this group of answers in App. G.

Change the “Present Number” to become the “Correct Number.” After the answers have been re-numbered, re-arrange them into the proper numerical sequence according to the newly added "Correct numbers"Present No. Correct No.

35 43

37 45

39 47

41 49

43 51

45 53

47 55

49 35

51 37

53 39

55 41

Index/Glossary I.22 Entry for Probability Function:

(P[X])

Should be:

[P(X)]

Back cover

Inside sheet

Physical Constants entry for Permittivity of vacuum: C-2J-1m-1

Conversions Factor entry for Liter: 10-3m-3

Should be:

C2 J-1 m-1

10-3m3