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  • .

    Chapter 8: Energy and

    Metabolism Why do organisms need energy? How do organisms

    manage their energy needs?

    Defining terms and issues:

    energy and thermodynamics

    metabolic reactions and energy transfers

    Harvesting and using energy

    ATP is the main energy currency in cells

    energy harvesting (redox reactions)

    Regulating reactions: Enzymes

    http://www.auburn.edu/academic/classes/biol/1020/bowling/

  • .

    Discuss energy conversions and the 1st

    and 2nd law of thermodynamics.

    Be sure to use the terms

    work

    potential energy

    kinetic energy

    entropy

    What are Joules (J) and calories (cal)?

    http://www.auburn.edu/academic/classes/biol/1020/bowling/

  • .

    Chapter 8: Energy and

    Metabolism Why do organisms need energy? How do organisms

    manage their energy needs?

    Defining terms and issues:

    energy and thermodynamics

    metabolic reactions and energy transfers

    Harvesting and using energy

    ATP is the main energy currency in cells

    energy harvesting (redox reactions)

    Regulating reactions: Enzymes

    http://www.auburn.edu/academic/classes/biol/1020/bowling/

  • .

    Energy and Thermodynamics

    energy for work: change in state or motion of matter

    http://www.auburn.edu/academic/classes/biol/1020/bowling/

  • .

    Energy and Thermodynamics

    energy for work: change in state or motion of matter

    expressed in Joules or calories

    1 kcal = 4.184 kJ

    http://www.auburn.edu/academic/classes/biol/1020/bowling/

  • .

    Energy and Thermodynamics

    energy for work: change in state or motion of matter

    expressed in Joules or calories

    1 kcal = 4.184 kJ

    energy conversion: energy form change

    potential / kinetic

    http://www.auburn.edu/academic/classes/biol/1020/bowling/

  • .

    Energy and Thermodynamics potential energy (capacity to do work)

    http://www.auburn.edu/academic/classes/biol/1020/bowling/

  • .

    Energy and Thermodynamics potential energy (capacity to do work)

    kinetic energy (energy of motion, actively performing work)

    chemical bonds: potential energy

    work is required for the processes of life

    http://www.auburn.edu/academic/classes/biol/1020/bowling/

  • .

    Discuss energy conversions and the 1st

    and 2nd law of thermodynamics.

    Be sure to use the terms

    work

    potential energy

    kinetic energy

    entropy

    What are Joules (J) and calories (cal)?

    http://www.auburn.edu/academic/classes/biol/1020/bowling/

  • .

    Energy and Thermodynamics

    Laws of thermodynamics describe the constraints on

    http://www.auburn.edu/academic/classes/biol/1020/bowling/

  • .

    The laws of thermodynamics are

    sometimes stated as:

    Explain.

    http://www.auburn.edu/academic/classes/biol/1020/bowling/

  • .

    Laws of Thermodynamics

    First law:

    the total amount of energy (+ matter) in a closed system remains constant

    http://www.auburn.edu/academic/classes/biol/1020/bowling/

  • .

    Laws of Thermodynamics

    First law:

    the total amount of energy (+ matter) in a closed system remains constant

    also called conservation of energy

    http://www.auburn.edu/academic/classes/biol/1020/bowling/

  • .

    Laws of Thermodynamics

    First law:

    the total amount of energy (+ matter) in a closed system remains constant

    also called conservation of energy

    note:

    the universe is a closed system

    living things are open systems

    http://www.auburn.edu/academic/classes/biol/1020/bowling/

  • .

    Laws of Thermodynamics

    First law:

    the total amount of energy (+ matter) in a closed system remains constant

    also called conservation of energy

    note:

    the universe is a closed system

    living things are open systems

    http://www.auburn.edu/academic/classes/biol/1020/bowling/

  • .

    Laws of Thermodynamics

    Second law: in every energy conversion

    some energy is converted to heat energy

    heat energy is lost to the surroundings

    heat energy cannot be used for work

    http://www.auburn.edu/academic/classes/biol/1020/bowling/

  • .

    Laws of Thermodynamics

    Second law: in every energy conversion

    some energy is converted to heat energy

    heat energy is lost to the surroundings

    heat energy cannot be used for work

    energy converted to heat in the surroundings

    increases entropy (spreading of energy)

    http://www.auburn.edu/academic/classes/biol/1020/bowling/

  • .

    Laws of Thermodynamics

    Second law: in every energy conversion

    some energy is converted to heat energy

    heat energy is lost to the surroundings

    heat energy cannot be used for work

    energy converted to heat in the surroundings

    increases entropy (spreading of energy)

    thus, this law can also be stated as:

    Every energy conversion increases the entropy

    of the universe.

    http://www.auburn.edu/academic/classes/biol/1020/bowling/

  • .

    Laws of Thermodynamics Second law:

    Upshot: no energy conversion is 100% efficient

    Just to maintain their current state, organisms must get a constant influx of energy because of energy lost in conversions

    http://www.auburn.edu/academic/classes/biol/1020/bowling/

  • .

    The laws of thermodynamics are

    sometimes stated as:

    Explain.

    http://www.auburn.edu/academic/classes/biol/1020/bowling/

  • .

    Differentiate between:

    anabolism and catabolism

    exergonic and endergonic reactions

    http://www.auburn.edu/academic/classes/biol/1020/bowling/

  • .

    Metabolism: anabolism + catabolism

    metabolism divided into

    anabolism (anabolic reactions)

    anabolic reactions are processes that build complex molecules from simpler ones

    http://www.auburn.edu/academic/classes/biol/1020/bowling/

  • .

    Metabolism: anabolism + catabolism

    metabolism divided into

    anabolism (anabolic reactions)

    anabolic reactions are processes that build complex molecules from simpler ones

    catabolism (catabolic reactions)

    catabolic reactions are processes the break down complex molecules into simpler ones

    http://www.auburn.edu/academic/classes/biol/1020/bowling/

  • .

    Differentiate between:

    anabolism and catabolism

    exergonic and endergonic reactions

    http://www.auburn.edu/academic/classes/biol/1020/bowling/

  • .

    Chemical Reactions and Free Energy

    Chemical reactions involve

    changes in chemical bonds

    http://www.auburn.edu/academic/classes/biol/1020/bowling/

  • .

    Chemical Reactions and Free Energy

    Chemical reactions involve

    changes in chemical bonds

    changes in substance concentrations

    http://www.auburn.edu/academic/classes/biol/1020/bowling/

  • .

    Chemical Reactions and Free Energy

    Chemical reactions involve

    changes in chemical bonds

    changes in substance concentrations

    changes in free energy

    free energy = energy available to do work in a chemical reaction (such as: create a chemical bond)

    free energy changes depend on bond energies and concentrations of reactants and products

    bond energy = energy required to break a bond; value depends on the bond

    http://www.auburn.edu/academic/classes/biol/1020/bowling/

  • .

    Chemical Reactions and Free Energy

    left undisturbed, reactions will reach dynamic equilibrium when the relative concentrations of reactants and products is correct

    forward and reverse reaction rates are equal; concentrations remain constant

    http://www.auburn.edu/academic/classes/biol/1020/bowling/

  • .

    Chemical Reactions and Free Energy

    left undisturbed, reactions will reach dynamic equilibrium when the relative concentrations of reactants and products is correct

    forward and reverse reaction rates are equal; concentrations remain constant

    cells manipulate relative concentrations in many ways so that equilibrium is rare

    http://www.auburn.edu/academic/classes/biol/1020/bowling/

  • .

    Chemical Reactions and Free Energy

    exergonic reactions the products have less free

    energy than reactants

    the difference in energy is released and is available to do

    work

    http://www.auburn.edu/academic/classes/biol/1020/bowling/

  • .

    Chemical Reactions and Free Energy exergonic reactions the products have less free energy than reactants

    the difference in energy is released and is available to do work

    exergonic reactions are thermodynamically favored; thus, they are spontaneous, but not necessarily fast (more on activation energy later)

    http://www.auburn.edu/academic/classes/biol/1020/bowling/

  • .

    Chemical Reactions and Free Energy

    catabolic reactions are usually exergonic

    ATP + H2O ADP + Pi is highly exergonic

    http://www.auburn.edu/academic/classes/biol/1020/bowling/

  • .

    Chemical Reactions and Free Energy

    endergonic reactions the products have

    more free energy than the reactants

    the difference in free energy must be supplied

    (stored in chemical bonds)

    http://www.auburn.edu