chapter 5 diffusion and resistivity 5.1 diffusion and mobility in weakly ionized gases 5.2 decay of...

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Chapter 5 Diffusion and resistivity 5.1 Diffusion and mobility in weakly ionized gases 5.2 Decay of a plasma by diffusion 5.3 Steady state solutions 5.4 Recombination 5.5 Diffusion across a magnetic field 5.6 Collisions in Fully ionized plasma 5.7 The Single-fluid MHD equations 5.8 Diffusion in fully ionized plasmas 5.9 Solutions of the diffusion equation 5.10 Bohm diffusion and neoclassical diffusion

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Page 1: Chapter 5 Diffusion and resistivity 5.1 Diffusion and mobility in weakly ionized gases 5.2 Decay of a plasma by diffusion 5.3 Steady state solutions 5.4

Chapter 5 Diffusion and resistivity

5.1 Diffusion and mobility in weakly ionized gases5.2 Decay of a plasma by diffusion5.3 Steady state solutions5.4 Recombination5.5 Diffusion across a magnetic field5.6 Collisions in Fully ionized plasma5.7 The Single-fluid MHD equations5.8 Diffusion in fully ionized plasmas5.9 Solutions of the diffusion equation5.10 Bohm diffusion and neoclassical diffusion

Page 2: Chapter 5 Diffusion and resistivity 5.1 Diffusion and mobility in weakly ionized gases 5.2 Decay of a plasma by diffusion 5.3 Steady state solutions 5.4

Coulomb collisions

Cross section for scattering of an electron by a neutral atom:

Mean free path:

Collision frequency:

20~ an

1)( nnmfp n

n n nn v

Page 3: Chapter 5 Diffusion and resistivity 5.1 Diffusion and mobility in weakly ionized gases 5.2 Decay of a plasma by diffusion 5.3 Steady state solutions 5.4

Collision with charged particles

b

b0

2tan

20

2

0 4 mv

zeb

Page 4: Chapter 5 Diffusion and resistivity 5.1 Diffusion and mobility in weakly ionized gases 5.2 Decay of a plasma by diffusion 5.3 Steady state solutions 5.4

In a plasma, most encounter : small angle deflection.

Consider an electron with initial velocity v, suppose that it undergoes a large number of small angle scattering events.

Each deflection gives a small perpendicular velocity component

1g

0bb

20

0

)/(1

)/(2sin

bb

bbvvv

0 v2)( v Increase with time

Page 5: Chapter 5 Diffusion and resistivity 5.1 Diffusion and mobility in weakly ionized gases 5.2 Decay of a plasma by diffusion 5.3 Steady state solutions 5.4

Because of Debye shielding, electron cannot fell the electric field of an ion at a distance

integration bound

Energy conservation

Db

],0[ D

ln,/

2

ln

])/(1[

)/(8)(

0

220

42

220

2032

b

vm

ezn

bb

bdbbbvnv

dt

d

D

ii

Coulomb logarithm

2)( v //v

High temperature plasma is collisionless!

Page 6: Chapter 5 Diffusion and resistivity 5.1 Diffusion and mobility in weakly ionized gases 5.2 Decay of a plasma by diffusion 5.3 Steady state solutions 5.4

Neutral particle diffusion:

Diffusion coefficient D is proportional to temperature, mean free path ….

0n

t

D n

2 0n

D nt

Page 7: Chapter 5 Diffusion and resistivity 5.1 Diffusion and mobility in weakly ionized gases 5.2 Decay of a plasma by diffusion 5.3 Steady state solutions 5.4

5.1 Diffusion and mobility in weakly ionized gases

Any realistic plasma will have a density gradient. The central problem in controlled thermonuclear reaction

is to impede the rate of diffusion by using magnetic field. It is called as weakly ionized gas when the collisions with

neutral atoms are dominant.

Page 8: Chapter 5 Diffusion and resistivity 5.1 Diffusion and mobility in weakly ionized gases 5.2 Decay of a plasma by diffusion 5.3 Steady state solutions 5.4

• Collision Parameters

Scattering cross section

The fraction of the slab blocked by atom is

Flux:

dxnAAdxn nn /

mn xxn

n

n

ee

n

dxdxd

dxn

/00

'

'

/)(/

)1(

Page 9: Chapter 5 Diffusion and resistivity 5.1 Diffusion and mobility in weakly ionized gases 5.2 Decay of a plasma by diffusion 5.3 Steady state solutions 5.4

Mean free path:

Mean time between collision

Mean frequency of collision

Collision frequency

nm n

1

vm /

mv /1

nn vν

Page 10: Chapter 5 Diffusion and resistivity 5.1 Diffusion and mobility in weakly ionized gases 5.2 Decay of a plasma by diffusion 5.3 Steady state solutions 5.4

Diffusion Parameters The fluid equation of motion including collision is

Considering a steady state, and assuming sufficiently small. Then

Mobility

Diffusion coefficient

vmnpEenvvt

vmn

dt

vdmn

])([

v

n

n

m

KTE

m

ev

m

q

m

KTD

Page 11: Chapter 5 Diffusion and resistivity 5.1 Diffusion and mobility in weakly ionized gases 5.2 Decay of a plasma by diffusion 5.3 Steady state solutions 5.4

Einstein relation:

the flux of the jth species can be written

If mobility is zero, the above equation change into Fick’s law

KT

Dq

nDEnvn jjj

nD j

Page 12: Chapter 5 Diffusion and resistivity 5.1 Diffusion and mobility in weakly ionized gases 5.2 Decay of a plasma by diffusion 5.3 Steady state solutions 5.4

5.2 Decay of a plasma by diffusion

Ambipolar diffusion

Continuity equation:

It is clear that if and were not equal, a serious charge imbalance would soon arise, an electric field is set up of such a polarity as to retard the imbalance. The required E field is found by setting

0

jj t

nvn

t

n nDEnvn jjj

i

e

ei

nDEnnDEn eeii

n

nDDE

ei

ei

Page 13: Chapter 5 Diffusion and resistivity 5.1 Diffusion and mobility in weakly ionized gases 5.2 Decay of a plasma by diffusion 5.3 Steady state solutions 5.4

If , then

For ,

nDnDD

ei

eiie

nDt

n 2

ie

ei

eiie DDD

ii

ei

e

eii D

T

TD

DDD

KT

Dq

ie TT iDD 2

Page 14: Chapter 5 Diffusion and resistivity 5.1 Diffusion and mobility in weakly ionized gases 5.2 Decay of a plasma by diffusion 5.3 Steady state solutions 5.4

• Diffusion in a slab:

Separation of Variables:

)()(),( rStTtrn

nDt

n 2

)()()(

)( 2 rStTDdt

tdTrS

1

)()(

)(

)(

1 2 rSrS

D

dt

tdT

tT

SD

S

eTT t

12

/0

Page 15: Chapter 5 Diffusion and resistivity 5.1 Diffusion and mobility in weakly ionized gases 5.2 Decay of a plasma by diffusion 5.3 Steady state solutions 5.4

In slab geometry,

Boundary conditions S=0 at

2/12/1

2

2

)(sin

)(cos

1

D

xB

D

xAS

SDdx

Sd

Lx

L

xenn

DL

t

2cos

2

/0

2

Page 16: Chapter 5 Diffusion and resistivity 5.1 Diffusion and mobility in weakly ionized gases 5.2 Decay of a plasma by diffusion 5.3 Steady state solutions 5.4

In general,

2

/ /0

1

( 1/ 2)

( 1/ 2)( cos sin )l m

l

t tl m

l m

L

l D

l x m xn n a e b e

L L

Page 17: Chapter 5 Diffusion and resistivity 5.1 Diffusion and mobility in weakly ionized gases 5.2 Decay of a plasma by diffusion 5.3 Steady state solutions 5.4

Diffusion in a cylinder

))(

(

011

2/10

2

2

D

rJS

SDsr

dS

rdr

Sd

Page 18: Chapter 5 Diffusion and resistivity 5.1 Diffusion and mobility in weakly ionized gases 5.2 Decay of a plasma by diffusion 5.3 Steady state solutions 5.4

5.3 Steady state solutions

)(2 rQnDt

n

In steady state, we have

• For constant Ionization function , Q=Zn

The solution is Cosine or Bessel function.

0t

n

)(12 rQD

n

nD

Zn 2

Page 19: Chapter 5 Diffusion and resistivity 5.1 Diffusion and mobility in weakly ionized gases 5.2 Decay of a plasma by diffusion 5.3 Steady state solutions 5.4

Plane source

Line source

)0()( 0QrQ

)1(

)0(

0

02

2

L

xnn

D

Q

dx

nd

)/ln(

0)(1

0 rannr

nr

rr

Page 20: Chapter 5 Diffusion and resistivity 5.1 Diffusion and mobility in weakly ionized gases 5.2 Decay of a plasma by diffusion 5.3 Steady state solutions 5.4

5.4 Recombination

Recombination need the third body, Because of the conservation of momentum.

• Radiative recombination

emitted photon

• Three-body recombination

with a particle

The loss of plasma by recombination will be proportional to .2nnn ei

Page 21: Chapter 5 Diffusion and resistivity 5.1 Diffusion and mobility in weakly ionized gases 5.2 Decay of a plasma by diffusion 5.3 Steady state solutions 5.4

the continuity equation without diffusion is

is called recombination coefficient.

This equation is a nonlinear equation.

Its solution is

2nt

n

trntrn

)(

1

),(

1

0

Page 22: Chapter 5 Diffusion and resistivity 5.1 Diffusion and mobility in weakly ionized gases 5.2 Decay of a plasma by diffusion 5.3 Steady state solutions 5.4

5.5 Diffusion across a magnetic field

The rate of plasma loss by diffusion can be decreased by a magnetic field. This is the problem of confinement in controlled fusion research.

Charge particle will

move along B by

diffusion and mobility

z

nDnEzz

Page 23: Chapter 5 Diffusion and resistivity 5.1 Diffusion and mobility in weakly ionized gases 5.2 Decay of a plasma by diffusion 5.3 Steady state solutions 5.4

If there are no collisions, particle will not diffuse at all in the perpendicular direction.

Particle will drift across B because of electric fields or gradients in B.

When there are collisions, particle migrate across B along the gradients.

Diffusion across B can be slowed down by decreasing

Larmor radius; that is by increasing B

Page 24: Chapter 5 Diffusion and resistivity 5.1 Diffusion and mobility in weakly ionized gases 5.2 Decay of a plasma by diffusion 5.3 Steady state solutions 5.4

Fluid equation of motion:

0)( vmnnKTBvEen

dt

dvmn

Bebvy

nKTenEvmn

Bebvx

nKTenEvmn

xyy

yxx

xc

yy

yc

xx

vy

n

n

DEv

vx

n

n

DEv

1

Page 25: Chapter 5 Diffusion and resistivity 5.1 Diffusion and mobility in weakly ionized gases 5.2 Decay of a plasma by diffusion 5.3 Steady state solutions 5.4

x

n

neB

KT

B

E

y

n

n

DEv

y

n

neB

KT

B

E

x

n

n

DEv

cx

cyy

cy

cxx

1

1

2222

2222

)/(1 22c

DE VV

n

nDEv

where

x

n

neB

KTV

y

n

neB

KTV

B

EV

B

EV

DyDx

xEy

yEx

11

2222 11

cc

DD

Page 26: Chapter 5 Diffusion and resistivity 5.1 Diffusion and mobility in weakly ionized gases 5.2 Decay of a plasma by diffusion 5.3 Steady state solutions 5.4

When , the magnetic field significantly retards

the rate of diffusion across B.

122 c

Lmmc rvm

Bq// vm /

mv

BqrL

22222

1

ccc m

KT

m

KTDD

/~~

/~~

22

22

2

22

Lth

Lth

c

mth

rV

rV

m

KTD

Vm

KTD

Page 27: Chapter 5 Diffusion and resistivity 5.1 Diffusion and mobility in weakly ionized gases 5.2 Decay of a plasma by diffusion 5.3 Steady state solutions 5.4

• Ambipolar diffusion across B

Page 28: Chapter 5 Diffusion and resistivity 5.1 Diffusion and mobility in weakly ionized gases 5.2 Decay of a plasma by diffusion 5.3 Steady state solutions 5.4

5.6 Collisions in Fully ionized plasma

• Collisions between like particles

• Collisions between unlike

particles

• Collsions between like particles

give rise to very little diffusion.

Page 29: Chapter 5 Diffusion and resistivity 5.1 Diffusion and mobility in weakly ionized gases 5.2 Decay of a plasma by diffusion 5.3 Steady state solutions 5.4
Page 30: Chapter 5 Diffusion and resistivity 5.1 Diffusion and mobility in weakly ionized gases 5.2 Decay of a plasma by diffusion 5.3 Steady state solutions 5.4

• Unlike particle collisions

give rise to diffusion.

Page 31: Chapter 5 Diffusion and resistivity 5.1 Diffusion and mobility in weakly ionized gases 5.2 Decay of a plasma by diffusion 5.3 Steady state solutions 5.4

Plasma Resistivity

The fluid equation of motion including the effects of charged-particle collisions may be written as

eieeee

ieiiii

PpBvEendt

vdmn

PpBvEendt

vdMn

)(

)(

eiie PP

Page 32: Chapter 5 Diffusion and resistivity 5.1 Diffusion and mobility in weakly ionized gases 5.2 Decay of a plasma by diffusion 5.3 Steady state solutions 5.4

)(

)(22

ei

eieiei

VVne

VVmnP

m

neei

2

The constant is the specific resistivity of the

plasma.

Page 33: Chapter 5 Diffusion and resistivity 5.1 Diffusion and mobility in weakly ionized gases 5.2 Decay of a plasma by diffusion 5.3 Steady state solutions 5.4

• Mechanics of Coulomb Collisions

90

20

2

0

02

00

2

4

4)(

mV

er

V

r

r

etFmVmV

Vn

r

ei

2

0

Page 34: Chapter 5 Diffusion and resistivity 5.1 Diffusion and mobility in weakly ionized gases 5.2 Decay of a plasma by diffusion 5.3 Steady state solutions 5.4

2/320

2/12

320

2

2

)()4(

16

e

ei

KT

me

mV

e

ne

m

If considering the small angle collisions,

0

2/320

2/12

/

ln)()4(

r

KT

me

D

e

Page 35: Chapter 5 Diffusion and resistivity 5.1 Diffusion and mobility in weakly ionized gases 5.2 Decay of a plasma by diffusion 5.3 Steady state solutions 5.4

Physical Meaning of

Let us suppose that an electric field E exists in a plasma and that the current that it drives is all carried by the electrons. Let B=0 and KTe=0. Then in steady state, the electron equation of motion reduces to

( )ee e e ei

dvmn en E v B p P

dt

eiPEen

jenVVneP eiei

)(22

)( ei VVenj

jE

This is simply Ohm’s Law. is the specific resistivity

Page 36: Chapter 5 Diffusion and resistivity 5.1 Diffusion and mobility in weakly ionized gases 5.2 Decay of a plasma by diffusion 5.3 Steady state solutions 5.4

is independent of density

In weakly ionized plasma,

the current is proportional to the plasma density

is proportional to . As a plasma is heated,

the coulomb cross section decreases, and the resistivity

drops rather rapidly.

The plasma becomes such a good conductor at

temperatures above 1kev that ohmic heating is a very slow

process in that range.

ln)()4( 2/32

0

2/12

eKT

me

EneVenj ee

2/3)( eKT

Page 37: Chapter 5 Diffusion and resistivity 5.1 Diffusion and mobility in weakly ionized gases 5.2 Decay of a plasma by diffusion 5.3 Steady state solutions 5.4

The fast electrons in the tail of the velocity distribution make very few collisions.

The current is therefore carried mainly by these electrons rather than by the bulk of the electrons in the main body of the distributions.

If an electric field is suddenly applied to a plasma, a phenomenon known as electron runaway can occur.

A few electrons which happen to be moving fast in the direction of –E when the field is applied will have gained so much energy that they can make only a glancing collision.

If E is large enough, runaway electrons never make a collision.

3220

4

20

16 Vm

neVn

r

ei

Page 38: Chapter 5 Diffusion and resistivity 5.1 Diffusion and mobility in weakly ionized gases 5.2 Decay of a plasma by diffusion 5.3 Steady state solutions 5.4

numerical values of

Spitzer resistivity

For KTe= 100eV,

mohmeVT

)(

ln102.5

2/35

//

mohm 7105

Page 39: Chapter 5 Diffusion and resistivity 5.1 Diffusion and mobility in weakly ionized gases 5.2 Decay of a plasma by diffusion 5.3 Steady state solutions 5.4

5.7 The Single-fluid MHD equations

The equation of magnetohydrodynamics (MHD)

Mass density

Mass velocity

Current density

)( mMnmnMn ei

mM

VmVMVmnVMnV ei

eeii

)(

1

)()( eieeii VVneVnVnej

Page 40: Chapter 5 Diffusion and resistivity 5.1 Diffusion and mobility in weakly ionized gases 5.2 Decay of a plasma by diffusion 5.3 Steady state solutions 5.4

The motion equation of ion and electron :

eieee

ieiii

PgmnpBvEendt

vdmn

PgMnpBvEendt

vdMn

)(

)(

ei

eiei

ppp

gmMnpBVVenVmVMt

n

)()()(

gpBjt

V

The single fluid equation

of motion.

Page 41: Chapter 5 Diffusion and resistivity 5.1 Diffusion and mobility in weakly ionized gases 5.2 Decay of a plasma by diffusion 5.3 Steady state solutions 5.4

Generalized Ohm’s Law

eieee

ieiii

PgmnpBvEendt

vdmn

PgMnpBvEendt

vdMn

)(

)(

eiei

eiei

PmMpMpm

BvMvmenEmMenvvt

Mmn

)(

)()()(

ne

jmMV

n

vvmvvMvmvMvMvm eiieeiei

)(

)()(

Page 42: Chapter 5 Diffusion and resistivity 5.1 Diffusion and mobility in weakly ionized gases 5.2 Decay of a plasma by diffusion 5.3 Steady state solutions 5.4

For slow motion, m/M 0.

jepMpm

BjmMBVeEen

j

te

Mmn

ei

)()(

]

)()([1

ei pMpm

BjmMn

j

te

Mmn

ejBVE

)(1

epBjen

jBVE

This is the generalized Ohm’s Law. The last term often is small, can be neglected.

Page 43: Chapter 5 Diffusion and resistivity 5.1 Diffusion and mobility in weakly ionized gases 5.2 Decay of a plasma by diffusion 5.3 Steady state solutions 5.4

The set of MHD equations is

jBVE

gpBjt

V

0)(

Vt

0

jt

Together with Maxwell’s equations is often used to described the equilibrium state of the plasma.

Page 44: Chapter 5 Diffusion and resistivity 5.1 Diffusion and mobility in weakly ionized gases 5.2 Decay of a plasma by diffusion 5.3 Steady state solutions 5.4

5.8 Diffusion in fully ionized plasmas

In the absence of gravity, MHD equation for a steady state plasma become

The parallel component of the latter equation is

this is a ordinary Ohm’s law.

pBj

jBVE

////// jE

Page 45: Chapter 5 Diffusion and resistivity 5.1 Diffusion and mobility in weakly ionized gases 5.2 Decay of a plasma by diffusion 5.3 Steady state solutions 5.4

For The perpendicular component is

The first term is just the drift velocity.

The second term is the diffusion velocity.

The diffusion coefficient is

pBB

BEV

pBVBE

pBjBBVBE

22

2

)(

KT

B

nD

2

2cm

KTD

For weakly ionized gas

Page 46: Chapter 5 Diffusion and resistivity 5.1 Diffusion and mobility in weakly ionized gases 5.2 Decay of a plasma by diffusion 5.3 Steady state solutions 5.4

Diffusion comparing with weakly ionized plasma

1. Both is proportional to

2. One is proportional to n, another is independent to n

3. Decreases with temperature increasing

opposite in weakly ionized plasma.

2

1

B

ln)()4( 2/32

0

2/12

eKT

me

Page 47: Chapter 5 Diffusion and resistivity 5.1 Diffusion and mobility in weakly ionized gases 5.2 Decay of a plasma by diffusion 5.3 Steady state solutions 5.4

5.9 Solutions of the diffusion equation

is not a constant in a fully ionized gas.

We define A which is a constant

For case:

The equation of continuity

KT

B

nD

2

D

2B

KTA

ei TT nAD 2

22

)2()(

nAt

n

nnAnDt

n

Page 48: Chapter 5 Diffusion and resistivity 5.1 Diffusion and mobility in weakly ionized gases 5.2 Decay of a plasma by diffusion 5.3 Steady state solutions 5.4

Time dependence

separation of variables: )()(),( rStTtrn

1

)()(

)(

)(

1 222

rSrS

A

dt

tdT

tT

t

TtT

0

1

)(

1

0)(1

)(22 rSA

rS

Page 49: Chapter 5 Diffusion and resistivity 5.1 Diffusion and mobility in weakly ionized gases 5.2 Decay of a plasma by diffusion 5.3 Steady state solutions 5.4

Time-independent solutions

222 )( nrnA recombination

22

22

nAx

n

For 1-dimension: ])(exp[ 2/120

2 xA

nn

Page 50: Chapter 5 Diffusion and resistivity 5.1 Diffusion and mobility in weakly ionized gases 5.2 Decay of a plasma by diffusion 5.3 Steady state solutions 5.4

5.10 Bohm diffusion and neoclassical diffusion

Bohm’s semi-empirical Formula

This formula was obeyed in a surprising number of

different experiments. Diffusion following this law is called

Bohm diffusion.

Be D

eB

KTD 16

1

Page 51: Chapter 5 Diffusion and resistivity 5.1 Diffusion and mobility in weakly ionized gases 5.2 Decay of a plasma by diffusion 5.3 Steady state solutions 5.4
Page 52: Chapter 5 Diffusion and resistivity 5.1 Diffusion and mobility in weakly ionized gases 5.2 Decay of a plasma by diffusion 5.3 Steady state solutions 5.4

In absolute magnitude, is also much larger than .

For example, For a 100-eV plasma in 1-T field,

If the density is .

The disagreement is 4 orders of magnitude.

BD D

.sec/25.6 2mDB

31910 m

.sec/1049.52 24

2m

B

nKTD

Page 53: Chapter 5 Diffusion and resistivity 5.1 Diffusion and mobility in weakly ionized gases 5.2 Decay of a plasma by diffusion 5.3 Steady state solutions 5.4

Explanations:

1. There is the possibility of magnetic field errors.

In a complicated geometries used in fusion research, it is not always clear the the lines of fore either close upon themselves or even stay within the chamber.

2. There is the possibility of asymmetric electric fields.

3. There is the possibility of oscillating electric field arising from unstable plasma waves.

Page 54: Chapter 5 Diffusion and resistivity 5.1 Diffusion and mobility in weakly ionized gases 5.2 Decay of a plasma by diffusion 5.3 Steady state solutions 5.4

Let the escape flux be proportional to the drift velocity:

Because of Debye shielding, the maximum potential in the plasma is

This leads to flux

BE

BnEnV /

eKTe max

eR

KT

RE e max

max

nDneB

KT

eB

KT

R

nB

ee