chapter 4 optimal design

43
4-1 Chapter 4 Optimal Design Contents Chapter 4 Optimal Design ................................................................................................ 4-1 Contents ............................................................................................................................ 4-1 4.1 Introduction .............................................................................................................. 4-2 4.2 Optimal Design for Thermoelectric Generators ...................................................... 4-2 Example 4.1 Exhaust Thermoelectric Generators .......................................................... 4-15 4.3 Optimal Design of Thermoelectric Coolers ........................................................... 4-19 Example 4.2 Automotive Thermoelectric Air Conditioner ............................................ 4-34 Problems ......................................................................................................................... 4-40 References....................................................................................................................... 4-43 The optimum design of thermoelectric devices (thermoelectric generator and cooler) in conjunction with heat sinks is developed using dimensional analysis. New dimensionless groups are defined to represent important parameters of the thermoelectric devices. In particular, use of the convection conductance of a fluid in the denominators of the dimensionless parameters is important, which leads to a new optimum design. This allows us to determine either the optimal number of thermocouples or the optimal thermal conductance. It is stated from the present dimensional analysis that, if two fluid temperatures on the heat sinks are given, an optimum design always exists and can be found with feasible mechanical constraints. The optimum design includes the optimum parameters such as efficiency, power, current, geometry or number of thermocouples, and thermal resistances of heat sinks.

Upload: others

Post on 07-May-2022

3 views

Category:

Documents


0 download

TRANSCRIPT

Page 1: Chapter 4 Optimal Design

4-1

Chapter 4 Optimal Design

Contents

Chapter 4 Optimal Design ................................................................................................ 4-1

Contents ............................................................................................................................ 4-1

4.1 Introduction .............................................................................................................. 4-2

4.2 Optimal Design for Thermoelectric Generators ...................................................... 4-2

Example 4.1 Exhaust Thermoelectric Generators .......................................................... 4-15

4.3 Optimal Design of Thermoelectric Coolers ........................................................... 4-19

Example 4.2 Automotive Thermoelectric Air Conditioner ............................................ 4-34

Problems ......................................................................................................................... 4-40

References ....................................................................................................................... 4-43

The optimum design of thermoelectric devices (thermoelectric generator and cooler) in

conjunction with heat sinks is developed using dimensional analysis. New dimensionless groups

are defined to represent important parameters of the thermoelectric devices. In particular, use of

the convection conductance of a fluid in the denominators of the dimensionless parameters is

important, which leads to a new optimum design. This allows us to determine either the optimal

number of thermocouples or the optimal thermal conductance. It is stated from the present

dimensional analysis that, if two fluid temperatures on the heat sinks are given, an optimum design

always exists and can be found with feasible mechanical constraints. The optimum design includes

the optimum parameters such as efficiency, power, current, geometry or number of thermocouples,

and thermal resistances of heat sinks.

Page 2: Chapter 4 Optimal Design

4-2

4.1 Introduction

Thermoelectric devices (thermoelectric generator and cooler) have found comprehensive

applications in solar energy conversion [1], exhaust energy conversion [2, 3], low grade waste

heat recovery [4-6], power plants [7], electronic cooling [8], vehicle air conditioners, and

refrigerators [7]. The most common refrigerant used in home and automobile air conditioners is

R-134a, which does not have the ozone-depleting properties of Freon, but is nevertheless a

terrible greenhouse gas and will be banned in the near future [9]. The pertinent candidate for the

replacement would be thermoelectric coolers. Many analyses, optimizations, even

manufacturers’ performance curves on thermoelectric devices have been based on the constant

high and cold junction temperatures of the devices. Practically, the thermoelectric devices must

work with heat sinks (or heat exchangers). It is then very difficult to have constant junction

temperatures unless the thermal resistances of the heat sinks are zero, which is, of course,

impossible. This is the rationale that a new design is developed based on Lee (2013) [10].

4.2 Optimal Design for Thermoelectric Generators

Let us consider a simplified steady-state heat transfer on a thermoelectric generator module

(TEG) with two heat sinks as shown in Figure 4.1 (a). Each heat sink faces a fluid flow at

temperature T∞. Subscript 1 and 2 denote hot and cold quantities, respectively. We assume that

the electrical and thermal contact resistances in the TEG are negligible, the material properties

are independent of temperature, and also the TEG is perfectly insulated. The TEG has a number

of thermocouples, each of which consists of p-type and n-type thermoelements with the same

dimensions as shown in Figure 4.1 (b). It is noted that the thermal resistance of heat sink 1 can

be expressed by the reciprocal of the convection conductance 111 Ah , where 1 is the fin

efficiency, 1h is the convection coefficient, and 1A is the total surface area in the heat sink 1. We

hereafter use the convection conductance rather than the thermal resistance.

Page 3: Chapter 4 Optimal Design

4-3

(a) (b)

Figure 4.1 (a) Thermoelectric generator module (TEG) with two heat sinks and (b)

thermocouple.

The basic equations for the TEG with two heat sinks are formulated as

111111 TTAhQ (4.1)

21

2

112

1TT

L

AkRIITnQ

(4.2)

21

2

222

1TT

L

AkRIITnQ

(4.3)

222222 TTAhQ (4.4)

Page 4: Chapter 4 Optimal Design

4-4

RR

TTI

L

21

(4.5)

where np , np kkk , and np . Equations (4.1) – (4.5) can be solved for T1

and T2, providing the power output. However, in order to study the optimization of the TEG,

several dimensionless parameters are introduced. The dimensionless thermal conductance, the

ratio of thermal conductance to the convection conductance in fluid 2, is

222 Ah

LAknN k

(4.6)

The dimensionless convection, the ratio of convection conductance in fluid 1 to fluid 2, is

222

111

Ah

AhN h

(4.7)

The dimensionless electrical resistance, the ratio of the load resistance to the electrical resistance

of thermocouple, is

R

RR L

r (4.8)

The dimensionless temperatures are defined by

2

11

T

TT

(4.9)

2

22

T

TT

(4.10)

2

1

T

TT

(4.11)

Page 5: Chapter 4 Optimal Design

4-5

The two dimensionless rates of heat transfer and the dimensionless power output are defined by

2222

11

TAh

QQ

(4.12)

2222

22

TAh

QQ

(4.13)

2222

TAh

WW n

n

(4.14)

It is noted that the above dimensionless parameters are based on the convection conductance in

fluid 2, which means that 2222 TAh must be initially provided. Using the dimensionless

parameters defined in Equations (4.6) – (4.11), Equations (4.1) – (4.5) reduce to two formulas as:

212

2

21212121

121TT

R

TTZT

R

TTTZT

N

TTN

rrk

h

(4.15)

212

2

21222122

121

1TT

R

TTZT

R

TTTZT

N

T

rrk

(4.16)

where Z is the figure of merit ( kZ 2 ). Equations (4.15) and (4.16) can be solved for

1T and

2T . The dimensionless temperatures are then a function of five independent dimensionless

parameters as

21 ,,,,

ZTTRNNfT rhk (4.17)

Page 6: Chapter 4 Optimal Design

4-6

22 ,,,,

ZTTRNNfT rhk (4.18)

T is the input and 2ZT is the material property with the input, and both are initially provided.

Therefore, the optimization can be performed only with the first three parameters (Nk, Nh, and

Rr). Once the two dimensionless temperatures (

1T and

2T ) are solved for, the dimensionless

rates of heat transfer at both hot and cold junctions of the TEG can be obtained as:

11 TTNQ h (4.19)

122 TQ (4.20)

Then, we have the dimensionless power output as

21 QQWn (4.21)

Accordingly, the thermal efficiency is obtained by

1Q

Wnth

(4.22)

Defining AkILN I , the dimensionless current is obtained by

1

212

r

IR

TTZTN

(4.23)

Also, defining 2 TnVNV , the dimensionless voltage is obtained by

Page 7: Chapter 4 Optimal Design

4-7

kI

nV

NN

WN

(4.24)

With the inputs (

T and 2ZT ), we begin developing the optimization with the dimensionless

parameters (Nk, Nh, and Rr) iteratively until they converge. It was learned from some initial

attempts that both Nk and Rr have optimal values for the dimensionless power output, while Nh

does not have an optimal since the dimensionless power output monotonically increases with

increasing hN . This implies that, if hN is given, the optimal combination of Nk and Rr can be

obtained. However, the dimensionless convection hN actually presents the feasible mechanical

constraints. Thus, we first proceed with a typical value of 1hN for illustration and later

examine a variety of hN with some practical design examples.

Suppose that we have two initial inputs of 6.2

T (two fluid temperatures) and 0.12 ZT

(materials) along with 1hN . We then determine the optimal combination for kN and rR , which

may be obtained either graphically or using a computer program. We first use the graphical method

and later the program for multiple computations. The dimensionless power output

nW and thermal

efficiency th are together plotted as a function of rR , and presented in Figure 4.2 (a). Both

nW

and th with respect to rR indeed have optimal values that appear close. We are interested

primarily in the power output and secondly in the efficiency. However, since they are close each

other, we herein use the power output for the optimization. It should be noted that the

dimensionless maximum power output does not occur at 1rR from Figure 4.2 (a) as usually

assumed for a TEG without heat sinks, but approximately at 7.1rR , because the dimensionless

temperatures

1T and

2T in Figure 4.2 (b) are no longer constant. This is often a confusing factor

in optimum design with a TEG of two heat sinks. We should not assume that rR is equal to one

for a TEG with heat sinks.

Page 8: Chapter 4 Optimal Design

4-8

(a)

(b)

Figure 4.2 (a) Dimensionless power output

nW and efficiency th versus the ratio of load

resistance to resistance of thermocouple rR and (b) dimensionless temperatures

1T and

2T versus

rR . These plots were generated using 3.0kN , 1hN , 6.2

T and 0.12 ZT .

0 1 2 3 4 5 60

0.01

0.02

0.03

0.04

0.05

0

0.03

0.06

0.09

0.12

0.15Wn*

th

Wn*th

Rr

0 1 2 3 4 5 60

1

2

3

4

0

0.02

0.04

0.06

0.08

T1*

&

T2*

T1*

Wn*

Wn*

T2*

Rr

Page 9: Chapter 4 Optimal Design

4-9

With the dimensionless parameters obtained ( 1hN , 7.1rR , 6.2

T , and 0.12 ZT ) in

Figure 4.3 (a), we now plot the dimensionless power output

nW and the thermal efficiency th as

functions of the dimensionless thermal conductance kN defined in Equation (4.6). We find an

optimum

nW approximately at 3.0kN . Actually, the optimal values of kN and rR should be

iterated until the two converge. From 222 AhLAknN k as shown in Equation (4.6), the kN

actually determines the number of thermocouples n if the geometric ratio A/L and 222 Ah are

given or vice versa. The dimensionless power output

nW first increases and later decreases with

increasing kN . It is important to realize that, if 222 Ah is given, there is an optimal number n of

thermocouples (or optimal thermal conductance LAk ) in the thermoelectric module, which is

usually unknown. Physically, the surplus number of thermocouples actually increases the

thermal conduction more than the production of power, which causes the net power output to

decline. There is another important aspect of the optimal dimensionless thermal conductance of

3.0kN , which is that the module thermal conductance LAkn directly depends on the

222 Ah . In other words, the module thermal conductance LAkn must be redesigned on the

basis of the 222 Ah to meet 3.0kN . The dimensionless high and low junction temperatures are

presented in Figure 4.3 (b). As kN decreases towards zero,

1T and

2T approach

T and 1,

respectively. This indicates that the thermal resistances of two heat sinks approaches zero, which

never happens. It is noted that the thermal efficiency approaches the theoretical maximum

efficiency of 0.2 for the given fluid temperatures as kN approaches zero.

Page 10: Chapter 4 Optimal Design

4-10

(a)

(b)

Figure 4.3 (a) Dimensionless power output

nW and thermal efficiency th versus dimensionless

thermal conductance kN , and (b) high and low junction temperatures (

1T and

2T ) versus

dimensionless thermal conductance kN . These plots were generated using 1hN , 7.1rR ,

6.2

T and 0.12 ZT .

0 0.2 0.4 0.6 0.80

0.01

0.02

0.03

0.04

0.05

0.06

0

0.05

0.1

0.15

0.2

0.25

0.3

Wn*

Wn*th

th

Nk

0 0.2 0.4 0.6 0.80

1

2

3

4

0

0.05

0.1

0.15

0.2

th

T1*thT1*

&

T2*

T2*

Nk

Page 11: Chapter 4 Optimal Design

4-11

Since there is an optimal combination of Nk and Rr for a given hN , we can plot the optimal

dimensionless power output

optW and optimal thermal efficiency opt as a function of

dimensionless convection hN , which is shown in Figure 4.4. It is very interesting to note that,

with increasing hN , opt barely changes, while

optW monotonically increases. According to

Equation (4.14), the actual optimal power output optW is the product of

optW and 222 Ah ,

seemingly increasing linearly with 222 Ah . In practice, there is a controversial tendency that hN

may decrease systematically with increasing 222 Ah . As a result of this, it is necessary to

examine the variety of the 222 Ah as a function of hN for the optimal power output. Figure 4.5

reveals the intricate relationship between 222 Ah and hN (or 111 Ah ) along with the optimum

actual power output (not dimensionless), which would lead system designers to a variety of

possible allocations ( 222 Ah and hN ) for their optimal design. Note that the analysis so far is

entirely based on the dimensionless parameters. Now we look into the actual optimal design with

the actual values.

0.1 1 100

0.02

0.04

0.06

0.08

0.1

0.08

0.09

0.1

0.11

0.12

0.13

opt

W*opt opt

W*opt

Nh

Page 12: Chapter 4 Optimal Design

4-12

Figure 4.4 Optimal dimensionless power output

optW and efficiency opt versus dimensionless

convection hN . This plot was generated using 6.2

T and 0.12 ZT .

Figure 4.5 Optimal power output optW versus convection conductance 222 Ah in fluid 2 as a

function of dimensionless convection hN . This plot was generated using T∞2 = 25°C, 6.2

T

and 0.12 ZT .

For example, using Figure 4.4 and Figure 4.5, we develop an optimal design for automobile

exhaust gas waste heat recovery. A thermoelectric generator module with a 5-cm × 5-cm base

area is subject to exhaust gases at 500°C in fluid 1 and air at 25°C in fluid 2. We estimate an

available maximum convection conductance in fluid 1 (exhaust gas) with 8.01 ,

KmWh 2

1 30 , and 2

1 1000cmA and also an available maximum convection conductance in

fluid 2 (air) with 8.02 , KmWh 2

2 30 , and 2

2 1000cmA , which gives

KWAhAh 8.4222111 and 1hN . Note that 1 and 2 are typical fin efficiencies, and h1

and h2 are the reasonable convection coefficients for exhaust gas heating and air cooling. Each

0.1 1 10 1000

20

40

60

80

100

120

140

160

180

200

Nh = 10

Nh = 1

Nh = 0.1

Wopt

(W) . Point

1

. Point

2

η2h2A2

(W/K)

Page 13: Chapter 4 Optimal Design

4-13

area of A1 and A2 is based on 20 fins (2 sides) with a fin height of 5 cm on a 5-cm × 5-cm base

area of the module. The typical thermoelectric material properties are assumed to be p = −n =

220 V/K, p = n = 1.0 × 10-3 cm, and kp = kn = 1.4 × 10-2 W/cmK. The above data

approximately determines three dimensionless parameters as 1hN , 6.2

T and 0.12 ZT .

As mentioned before, the present dimensional analysis enables the three dimensionless

parameters ( 1hN , 6.2

T and 0.12 ZT ) to determine the rest two optimal parameters,

which are found to be 30.0kN and 7.1rR as shown before. This leads to a statement that, if

two individual fluid temperatures on heat sinks connected to a thermoelectric generator module

are given, an optimum design always exists with the feasible mechanical constraints on hN . This

optimal design is indicated approximately at Point 1 in above. Note that there are ways to

improve the optimal power output, increasing either 222 Ah or hN or both, which obviously

depend on the feasible mechanical constraints.

The inputs and optimum results at Point 1 in above are summarized in Table 4.1. The inputs are

the geometry of thermocouple, the material properties, two fluid temperatures, and the available

convection conductance in fluid 2. The dimensionless results are converted to the actual

quantities as shown. The maximum power output is found to be 65.0 W for the 5cm × 5cm base

area of the module. The power density is calculated to be 2.6 W/cm2, which appears significantly

high compared to an available power density of ~ 1 W/cm2 with the similar operating conditions

by NEDO program (Japan) [7].

Table 4.1 Inputs and Results from the Dimensional Analysis for a TEG

Inputs Dimensionle

ss (

optnW , )

Actual

(Wn,opt)

T∞1 = 500°C, T∞2 = 25°C, T∞ = 475 °C Nk = 0.3 n = 254

A = 2 mm2, L = 1 mm Nh = 1 1 h1 A1 = 4.8 W/K

2 = 0.8, h2 = 60 W/m2K, A2 = 1000 cm2 Rr = 1.7 RL = 1.7×n×R = 4.32

Page 14: Chapter 4 Optimal Design

4-14

2 h2 A2= 4.8 W/K 6.2

T T∞1 = 500°C

Base area Ab of module = 5 cm × 5 cm 0.12 ZT 0.12 ZT

p = -n = 220 V/K 172.21 T T1 = 374°C

p = n = 1.0 × 10-3 cm 367.12 T T2 = 137°C

kp = kn =1.4 × 10-2 W/cmK 045.0

nW Wn = 65.0 W

(Z = 3.457 × 10-3 K-1) 108.0th 108.0th

(R = 0.01 per thermocouple) NI = 0.306 I = 3.9 A

( 8.01 , KmWh 2

1 30 , 2

1 1000cmA ) NV = 0.50 V = 16.7 V

(Power Density Pd = Wn/Ab) - Pd = 2.6 W/cm2

Air was used in fluid 2 so far. However, we want to see the effect of 222 Ah or hN by changing

fluid 2 from air to liquid coolant. Otherwise the same conditions were applied to as the previous

example. We then estimate an available convection conductance in fluid 1 (exhaust gas) with the

same one of 8.01 , KmWh 2

1 30 , and 2

1 1000cmA , but an available convection

conductance in fluid 2 (liquid coolant) with 8.02 , KmWh 2

2 3000 , and 2

2 100cmA ,

which gives KWAh 8.4111 and KWAh 24222 , respectively, which yields 1.0hN . The

area of A1 is based on 20 fins (2 sides) with a fin height of 5 cm for the 5-cm × 5-cm base area of

the module and A2 is estimated to be one tenth of A1 (liquid coolant does not require a large heat

transfer area). These inputs and optimum results give all the five dimensionless parameters as

07.0kN , 1.0hN , 5.1rR , 6.2

T and 0.12 ZT , for which the optimum at

KWAh 24222 is indicated at Point 2 in Figure 4.5. The effect of hN on the high and cold

junction temperatures is also presented in Figure 4.6. It is interesting to see that, although a small

variation in the optimal power outputs between Point 1 ( 1hN ) and Point 2 ( 1.0hN ) appears

in Figure 4.5, a significant temperature variation between 1hN and 1.0hN appears in Figure

4.6. This may be an important factor particularly when thermoelectric materials are considered in

the optimal design. The proximity of the power outputs between Points 1 and 2 is an example

Page 15: Chapter 4 Optimal Design

4-15

showing the variety of the mechanical constraints ( 111 Ah and 222 Ah ) even with the same

power outputs .

Figure 4.6 Hot and cold junction temperatures and optimal efficiency versus dimensionless

convection. This plot was generated with T∞2 = 25°C, 6.2

T and 0.12 ZT .

Example 4.1 Exhaust Thermoelectric Generators

A thermoelectric generator (TEG) module is designed using a newly developed material which is

so called TAGS-75 (AgSbTe/GeTe 75%) for exhaust waste heat recovery in a car. The whole

TEG device is shown in Figure E4.1-1a. The device has N modules, each of which consists of n

p- and n-type thermocouples. The material properties for thermoelements are estimated as p =

−n = 218 V/K, p = n = 1.1 × 10-3 cm, and kp = kn = 1.3 × 10-2 W/cmK. The cross-sectional

area and pellet length of the thermoelements are An = Ap = 2.4 mm2 and Ln = Lp = 1 mm,

respectively. The exhaust gases at 750 K enter heat sink 1 while coolant at 312 K flows in heat

sink 2. The convection conductances for the flows, with consideration of the effectiveness of the

heat sinks, are estimated on the 5-cm × 5-cm base areas to be 8.01 , KmWh 2

1 60 , and

0.1 1 100

100

200

300

400

500

0.08

0.09

0.1

0.11

0.12

0.13

T1

.

opt

. optTopt ( °C)

. T2

.

Nh

Page 16: Chapter 4 Optimal Design

4-16

2

1 1000cmA for heat sink 1 (exhaust gases) and 9.02 , KmWh 2

2 1000 , and 2

2 50cmA

for heat sink 2 (coolant).

(a) For the optimal design of one TEG module, determine the number of thermocouples n,

power output, conversion efficiency, hot and cold junction temperatures, current and

voltage.

(b) If a total power output of 1200 W for the whole TEG device is required, determine the

number of modules N (assuming that the module represents the mean value of the modules

in the device).

(a) (b)

Figure E4.1-1 (a) the whole TEG device, and (b) the TEG module.

Solution:

Material properties of TAGS-75: =p − n = 436 × 10-6 V/K, = p + n = 2.2 × 10-5 m,

and k = kp + kn = 2.6 W/mK.

The convection conductances are given as

1 = 0.8, h1 = 60 W/m2K, A1 = 1000 cm2 and 2 = 0.9, h1 = 1000 W/m2K, A1 = 50 cm2.

KWmKmWAh 8.4101000608.0 242

111

KWmKmWAh 5.4105010009.0 242

222

The cross-sectional area and pellet length of the thermoelement are

A = 2.4 × 10-6m2 and L = 1 × 10-3m

Page 17: Chapter 4 Optimal Design

4-17

The figure of merit is

13

5

262

10323.36.2102.2

10436

K

mKWm

KV

kZ

and

037.131210323.3 13

2

KKZT

The dimensionless fluid temperature is

404.2312

750

2

1

K

K

T

TT

The dimensionless convection conductance is

067.15.4

8.4

222

111 KW

KW

Ah

AhNh

From Table B.1 for 12 ZT , we can approximately obtain the optimal parameters using both

40.2

T and 0.1hN as

Rr = 1.638, Nk = 0.305, th = 0.096, 035.0

nW , 032.21 T , 332.12 T , NI = 0.265, and NV =

0.435.

(a) Using Equation (4.6), the number of thermocouples is

95.219

104.26.2

1015.4305.0

26

3

222

mmKW

mKW

kA

LAhNn k

Using Equation (4.14), the power output is

WKKWTAhWW nn 14.493125.4035.02222

The conversion efficiency is

th = 0.096

The hot and cold junction temperatures are

KKTTT 98.633312032.2211

KKTTT 58.415312332.1222

Page 18: Chapter 4 Optimal Design

4-18

Using the dimensionless current in Equation (4.23), the current is

AmKV

mmKW

L

kANI I 79.3

10110436

104.26.2265.0

36

26

Using the definition of dimensionless voltage in Equation (4.24), the voltage is

VKKVTnNV Vn 0.133121043695.219435.0 6

2

(b) Determine the number of modules N if the total power output of 1200W is required.

42.2414.49

12001200

W

W

W

WN

n

Comments: We want to compare the above optimal power output of 49.14 W with the maximum

power output of about 54 W plotted in a conventional way (assuming the constant hot and cold

junction temperatures) using the following equations as

32635 1017.9104.2101102.2 mmmALR

21

2

112

1TT

L

kARIITnQ , RITTInWn

2

21 , and 1Q

Wnth

Page 19: Chapter 4 Optimal Design

4-19

Figure E4.1-2 Power output and efficiency versus current.

The maximum power output of about 54 W at I = 5 A from the figure appears higher than the

optimal power output of 49.14 W obtained with I = 3.79 A. However, it is noted that the 54 W is

attained under the assumption of the constant hot and cold junction temperatures which are no

longer true. This indicates that the predictions with the ideal equations without heat sinks (under

assumption of the constant hot and cold junction temperatures) may lead to the appreciable

errors.

4.3 Optimal Design of Thermoelectric Coolers

Let us consider a simplified steady-state heat transfer on a thermoelectric cooler module (TEC)

with two heat sinks as shown in Figure 4.7. Each heat sink faces a fluid flow at temperature T∞.

Subscript 1 and 2 denote the entities of fluid 1 and 2, respectively. Consider that an electric

current is directed in a way that the cooling power Q1 enters heat sink 1. We assume that the

electrical and thermal contact resistances in the TEC are negligible, the material properties are

independent of temperature, and also the TEC is perfectly insulated. The TEC has a number of

0 2 4 6 8 10 120

10

20

30

40

50

60

0

0.02

0.04

0.06

0.08

0.1

0.12Wn

th

Wn(W)th

Current

(A)

Page 20: Chapter 4 Optimal Design

4-20

thermocouples, of which each thermocouple consists of p-type and n-type thermoelements with

the same dimensions.

Figure 4.7 Thermoelectric cooler module (TEC).

The basic equations for the TEC with two heat sinks are given by

111111 TTAhQ (4.25)

21

2

112

1TT

L

AkRIITnQ

(4.26)

21

2

222

1TT

L

AkRIITnQ

(4.27)

222222 TTAhQ (4.28)

Page 21: Chapter 4 Optimal Design

4-21

where np , np kkk , and np . In order to study the optimization of the

TEC, several dimensionless parameters are introduced. The dimensionless thermal conductance,

which is the ratio of thermal conductance to the convection conductance in fluid 2, is

222 Ah

LAknN k

(4.29)

The dimensionless convection, which is the ratio of convection conductance in fluid 1 to fluid 2,

is

222

111

Ah

AhN h

(4.30)

The dimensionless current is given by

LAk

IN I

(4.31)

The dimensionless temperatures are defined by

2

11

T

TT

(4.32)

2

22

T

TT

(4.33)

2

1

T

TT

(4.34)

The dimensionless cooling power, rate of heat liberated and electrical power input are defined by

Page 22: Chapter 4 Optimal Design

4-22

2222

11

TAh

QQ

(4.35)

2222

22

TAh

QQ

(4.36)

2222

TAh

WW n

n

(4.37)

It is noted that the above dimensionless parameters are based on the convection conductance in

fluid 2, which means that 2222 TAh should be initially provided. Using the dimensionless

parameters defined in Equations (4.29) – (4.34), Equations (4.25) – (4.28) reduce to two

formulas as:

21

2

2

11

2TT

ZT

NTN

N

TTN II

k

h (4.38)

21

2

2

22

2

1TT

ZT

NTN

N

T II

k

(4.39)

Equations (4.38) and (4.39) can be solved for

1T and

2T . The dimensionless temperatures are

then a function of five independent dimensionless parameters as

21 ,,,,

ZTTNNNfT Ihk (4.40)

22 ,,,,

ZTTNNNfT Ihk (4.41)

T is the input and 2ZT is the material property with the input, and both are initially provided.

Therefore, the optimization can be performed only with the first three parameters (Nk, Nh, and

Page 23: Chapter 4 Optimal Design

4-23

NI). Once the two dimensionless temperatures (

1T and

2T ) are solved for, the dimensionless

rates of heat transfer at both junctions of the TEC can be obtained as:

11 TTNQ h (4.42)

122 TQ (4.43)

1Q is called the dimensionless cooling power. Then, we have the dimensionless power input as

12 QQWn (4.44)

Accordingly, the coefficient of performance is obtained by

nW

QCOP 1

(4.45)

Defining 2 TnVNV , the dimensionless voltage is obtained by

kI

nV

NN

WN

(4.46)

With the inputs (

T and 2ZT ), we try to find the optimal combination for the dimensionless

parameters (Nk, Nh, and NI) iteratively until they converge. It is found that both kN and IN have

optimal values for the dimensionless cooling power

1Q , while hN does not since dimensionless

cooling power

1Q monotonically increases with increasing hN . This implies that, if any hN is

given, the optimal combination of kN and IN can be obtained. However, the dimensionless

convection hN actually has feasible mechanical constraints. Thus, we proceed with a typical

Page 24: Chapter 4 Optimal Design

4-24

value of 1hN for illustration and later examine the variety of hN with a practical design

example.

Suppose that we have 967.0

T (two arbitrary fluid temperatures) and 0.12 ZT (materials)

along with 1hN as inputs. Then, we can determine the optimal combination for IN and kN ,

which may be obtained either graphically or using a computer program. We first use the graphical

method and later the program for multiple computations (a Mathematical software Mathcad was

used). The optimal combination of IN and kN for each maximum cooling power are found to be

IN = 0.5 and kN = 0.3, respectively, which are shown in Figure 4.8 and Figure 4.9. The maximum

cooling power of 037.01 Q in both figures is actually the optimal dimensionless cooling power

optQ ,1 . However, the COP also shows an optimal value at 074.0IN , which gives 006.01 Q .

The optimal COP usually gives very small cooling power or sometimes even none, which is

impractical. Therefore, it is necessary to have a practical value for the optimal COP, which is

determined in the present work to be the midpoints of the optimum IN and kN . For example, the

practical optimal COP in this case occurs simultaneously at 25.0IN and 15.0kN , which

leads to 019.01 Q that may be seen after re-plotting with the two values.

Page 25: Chapter 4 Optimal Design

4-25

Figure 4.8 Dimensionless cooling power

1Q , power input

nW and COP versus dimensionless

current IN . This plot was generated with 3.0kN , 1hN , 967.0

T and 0.12 ZT .

Figure 4.9 Dimensionless cooling power

1Q and COP versus dimensionless thermal conductance

kN . This plot was generated with 1hN , 5.0IN , 967.0

T and 0.12 ZT .

The existence of an optimum cooling power as a function of current is a well-known

characteristic of TECs. However, the existence of an optimum kN in TECs has not been found in

0 0.2 0.4 0.6 0.8 10

0.02

0.04

0.06

0.08

0.1

0

0.5

1

1.5

2

2.5

Wn*

COP

Q1*

&

Wn*

COP

Q1*

NI

0 0.2 0.4 0.6 0.8 10

0.01

0.02

0.03

0.04

0.05

0.06

0

0.2

0.4

0.6

0.8

1

1.2

Q1*

Q1* COP

COP

Nk

Page 26: Chapter 4 Optimal Design

4-26

the literature to the author’s knowledge. With Equation (4.29), 222 AhLAknN k , the

optimum of Nk = 0.3 implies that the module thermal conductance LAkn is at optimum since

the 222 Ah is given. This leads to the optimum n (the number of thermocouples) if LAk is

given or vice versa. This is one of the most important optimum processes in the design of a

thermoelectric cooler module. It is good to know from Figure 4.10 that the dimensionless

temperature

1T becomes lowest at the optimal dimensionless cooling power

1Q , not at the

optimum COP.

Figure 4.10 Dimensionless temperatures versus dimensionless thermal conductance. This plot

was generated with 1hN , 5.0IN , 967.0

T and 0.12 ZT .

We also consider two heat sinks as a unit without a TEC to examine the limitation of the use of

the TEC (see Figure 4.11). The geometry of the unit is the same as the one shown in Figure 4.7

except that there is no TEC between the heat sinks. There should be a cooling rate with given

fluid temperatures, which is 0Q . We want to compare the cooling power 1Q with this cooling

rate 0Q to determine the limit of use of the TEC.

0 0.2 0.4 0.6 0.8 10.9

1

1.1

1.2

1.3

1.4

0

0.01

0.02

0.03

0.04

0.05

Q1*

T2*

T1*

&

T2*

Q1*

T1*

Nk

Page 27: Chapter 4 Optimal Design

4-27

Figure 4.11 Heat sinks without a TEC.

The basic equations for the unit can be expressed as

011110 TTAhQ (4.47)

202220 TTAhQ (4.48)

The dimensionless groups for the unit are

2

00

T

TT

(4.49)

2222

00

TAh

QQ

(4.50)

Using Equations (4.30), (4.34), (4.49) and (4.50), Equations (4.47) and (4.48) reduce to

Page 28: Chapter 4 Optimal Design

4-28

1

10

h

h

N

TNT

(4.51)

The dimensionless cooling rate without heat sinks can be obtained by

100 TQ (4.52)

Figure 4.12 Dimensionless cooling power, cooling rate of the unit, and COP versus

dimensionless fluid temperature. This plot was generated with 3.0kN , 1hN , 5.0IN and

0.12 ZT .

0.8 0.9 1 1.1 1.2 1.3 1.40

0.05

0.1

0.15

0.2

0.25

0.3

0

0.25

0.5

0.75

1

1.25

1.5

COP

Q1*

&

Q0*

COP

Q1*

Q0*

T

Page 29: Chapter 4 Optimal Design

4-29

Figure 4.13 Optimal (cooling power optimized) dimensionless cooling power and COP versus

dimensionless convection. This plot was generated with 967.0

T and 0.12 ZT .

The dimensionless cooling power

1Q and cooling rate of the unit

0Q versus the dimensionless

fluid temperature

T along with the COP are presented in Figure 4.12. The crossing point in the

figure is

T = 1.2, which is a design point as the limit of use of the TEC. If the dimensionless

fluid temperature

T is higher than the crossing point, there is no justification for use of the TEC

although the TEC still functions. This crossing point defines the maximum dimensionless

temperature

max,T . There is also a minimum point at 83.0

T , where 01 Q , which is called

the minimum dimensionless temperature

min,T . Note that the TEC can perform effective cooling

within a range from 83.0min,

T to

max,T = 1.2.

Since there is an optimal combination of NI and Nk for a given hN , we can plot the optimal

dimensionless cooling power

optQ ,1 and COPopt as a function of the dimensionless convection hN ,

which is shown in Figure 4.13. It is seen that both

optQ ,1 and COPopt increase monotonically with

increasing hN . According to Equation (4.35), the actual optimal cooling power optQ ,1 is the

0.1 1 100

0.01

0.02

0.03

0.04

0.05

0

0.2

0.4

0.6

0.8

1

Q*1,opt

Q*1 COPCOPopt

Nh

Page 30: Chapter 4 Optimal Design

4-30

product of

optQ ,1 and 222 Ah , seemingly increasing linearly with 222 Ah . In practice, there is a

controversial tendency that hN may decrease systematically with increasing 222 Ah . As a result

of this, it is necessary to examine the variety of the 222 Ah as a function of hN for the optimal

cooling power. Figure 4.14 reveals the intricate relationship between 222 Ah and hN (or 111 Ah )

along with the optimum actual cooling power (not dimensionless), which would lead system

designers to a variety of possible allocations ( 222 Ah and hN ) for their optimal design. Note that

the analysis so far is entirely based on the dimensionless parameters. Now we look into the

actual optimal design with the actual values.

Figure 4.14 Optimal cooling power versus convection conductance in fluid 2 as a function of

dimensionless convection. This plot was generated with T∞2 = 30°C,

967.0

T and 0.12 ZT .

For example, using Figure 4.13and Figure 4.14, we develop an optimal design for an automobile

air conditioner. A thermoelectric cooler module with a 5-cm × 5-cm base area is subject to cabin

air at 20°C in fluid 1 and ambient air at 30°C in fluid 2. We estimate an available maximum

convection conductance in fluid 1 (cabin air) with 8.01 , KmWh 2

1 60 , and 2

1 1000cmA

0.1 1 10 1000

10

20

30

40

50

60

70

80

90

100Nh = 10

Nh = 1

Nh = 0.1

. Q1,opt (W) Point

1

η2h2A2

(W/K)

Page 31: Chapter 4 Optimal Design

4-31

and also an available maximum convection conductance in fluid 2 (ambient air) with 8.02 ,

KmWh 2

2 60 , and 2

2 1000cmA , which gives KWAhAh 8.4222111 and 1hN . Note

that 1 and 2 are fin efficiencies, and h1 and h2 are reasonable convection coefficients for the

cabin air cooling and the ambient air cooling, respectively. Each area of A1 and A2 is based on 20

fins (2 sides) with a fin height of 5 cm on a 5-cm × 5-cm base area of the module. The typical

thermoelectric material properties are assumed to be p = −n = 220 V/K, p = n = 1.0 × 10-3

cm, and kp = kn = 1.4 × 10-2 W/cmK. The above data approximately determines three

dimensionless parameters as 1hN , 967.0

T and 0.12 ZT .

As mentioned before, the present dimensional analysis enables the three dimensionless

parameters ( 1hN , 967.0

T and 0.12 ZT ) to determine the rest of optimal parameters,

which are found to be 3.0kN and 5.0IN as shown before. This leads to a statement that, if

two individual fluid temperatures on heat sinks connected to a thermoelectric cooler module are

given, an optimum design always exists with the feasible mechanical constraints that present hN .

This optimal design is indicated approximately at Point 1 in Figure 4.14. Note that there are

several ways to improve the optimal power output by increasing either 222 Ah or hN or both.

But this depends on the feasible mechanical constraints, whichever is available.

Page 32: Chapter 4 Optimal Design

4-32

Figure 4.15 Two junction temperatures and cooling power versus convection conductance in

fluid 2. This plot was generated with, KWAh 8.4222 T∞2 = 30°C, 967.0

T and

0.12 ZT .

The inputs and optimum results at Point 1 in Figure 4.14 are summarized in the first two columns

of Table 4.2. The inputs are the geometry of thermocouple, the material properties, two fluid

temperatures, and the available convection conductance in fluid 2. The dimensionless results are

converted to the actual quantities. The optimal cooling power is found to be 54.4 W for the 5cm

× 5cm base area of the module. The cooling power density is calculated to be 2.18 W/cm2. When

111 Ah is limited, simply decreasing 222 Ah invokes decreasing hN , which is shown in Figure

4.15. This causes from the fact that the hot and cold junction temperatures must decrease when

more heat is extracted from the limited input, which is a characteristic of the thermoelectric

cooler with heat sinks. The hot and cold junction temperatures are sometimes a design factor,

noting that the optimal cold junction temperature optT ,1 reaches zero Celsius at 4.0hN , which

may cause icing and reducing the heat transfer.

0.1 1 1020

0

20

40

60

80

0

20

40

60

80

100

T2,opt

Q1,opt

T ( °C) Q1(W)

T1,opt

Nh

Page 33: Chapter 4 Optimal Design

4-33

Table 4.2 Inputs and Results from the Dimensional Analysis for a Thermoelectric Cooler Module

Input

optQ ,1 (dimensionless)

optQ ,1

(Actual)

optCOP 2/1

(dimensionless)

optCOP 2/1

(Actual)

T∞1 = 20°C, T∞2 = 30°C Nk = 0.3 n = 257 Nk = 0.15 n = 128 A = 2 mm2, L = 1 mm Nh = 1 1 h1 A1 = 4.8

W/K

Nh = 1 1 h1 A1 = 4.8 W/K

2 = 0.8, h2 =60 W/m2K, NI = 0.5 I = 6.36 A NI = 0.25 I = 3.18 A

A2 =1000 cm2 967.0

T T∞1 = 20°C 967.0

T T∞1 = 20°C

Base area Ab = 5 cm × 5 cm 0.12 ZT 0.12 ZT 0.12 ZT 0.12 ZT

p = -n = 220 V/K 930.01 T T1 = 8.7°C 949.01 T T1 = 14.4°C

p = n = 1.0 × 10-3 cm 145.12 T T2 = 73.9°C 031.12 T T2 = 39.4°C

kp = kn =1.4 × 10-2 W/cmK 037.01 Q Q1 = 54.4 W 019.01 Q Q1 = 26.9 W

(Z = 3.457 × 10-3 K-1) COP = 0.35

COP = 1.49

(R =0.01per thermocouple)

NV = 0.715 Vn = 24.5 V NV = 0.332 Vn = 5.7 V

2.1max,

T T∞1,max = 91.3°C

06.1max,

T T∞1,max = 49.7°C

83.0min,

T T∞1,min = −21.8°C

84.0min,

T T∞1,min = −19.2°C

(Cooling Power Density Pd = Q1/Ab)

- Pd = 2.18 W/cm2

- Pd = 1.08 W/cm2

As mentioned before, the optimal COP is sometimes in demand in addition to the optimal

cooling power. However, the real optimal COP usually gives a very small value of the cooling

power, albeit the high COP. Therefore, in the present work, the midpoints of the optimal IN and

kN are used to provide approximately a half of the optimal cooling power and at least four folds

of the cooling-power-optimised COP. This modified optimal COP is called a half optimal

coefficient of performance COP1/2opt. These results are also tabulated in the last two columns of

Figure 4.2, so that designers could determine which optimum is better depending on the

application. The optimum cooling power is usually selected when the resources (electrical power

or capacity of coolant) are abundant or inexpensive or the efficacy is not important as in

microprocessor cooling, while the half optimum COP is selected when the resources are limited

or expensive or the efficacy is important as in automotive air conditioners.

Page 34: Chapter 4 Optimal Design

4-34

The present work presents the optimal design of thermoelectric devices in conjunction with heat

sinks introducing new dimensionless parameters. The present optimum design includes the

power output (or cooling power) and the efficiency (or COP) simultaneously with respect to the

external load resistance (or electrical current) and the geometry of thermoelements. The optimal

design provides optimal dimensionless parameters such as the thermal conduction ratio, the

convection conduction ratio, and the load resistance ratio as well as the cooling power,

efficiency, and high and low junction temperatures. The load resistance ratio (or the electrical

current) is a well known characteristic of optimum design. However, it is found that the load

resistance ratio would be greater than unity (1.7 in the present case). This is a confusing factor in

optimum design with a TEG. One should not assume that the load resistance ratio RL/R is equal

to unity for a TEG with heat sink(s). The optimal thermal conductance [(n)(A/L)(k)] consists of

the number of thermocouples, the geometric ratio, and the thermal conductivity. It is important

that there is an optimum number of thermocouples n for a given the convection conductance

222 Ah if the optimal thermal conductance A/L is constant or vice versa. These are the optimum

geometry of thermoelectric devices. The information of the optimal thermal conductance is

particularly important in the design of microstructured or thin-film thermoelectric devices.

Furthermore, there is a potential to improve the performance or to provide the variety of the

geometry by reducing the thermal conductivity.

Finally, it is stated from the present dimensional analysis that, if two individual fluid

temperatures on heat sinks connected to a thermoelectric generator or cooler are given, an

optimum design always exists and can be found with feasible mechanical constraints.

Example 4.2 Automotive Thermoelectric Air Conditioner

Current automotive air conditioners have used R-134a for about two decades as a working fluid.

It does not have the ozone-depleting properties of Freon, but it is nevertheless a terrible

greenhouse gas and will be banned in the near future. A thermoelectric air conditioner is

Page 35: Chapter 4 Optimal Design

4-35

designed for the replacement as a green energy application (Figure E4.2a). The analysis indicates

that the cooling load of 600 W per occupant is required. We consider a unit module of 7-cm × 7-

cm base area, which represents a mean value of the modules’ performance of the air conditioner.

Cabin air at 21 °C enters the upper and lower heat sinks while coolant at 34 °C enters the central

flat heat exchanger, so that the TEC modules are installed between each heat sink and the central

exchanger (Figure E4.2b). A newly developed nanostructured material, Bi2Te3, has the properties

p = −n = 208 V/K, p = n = 1.1 × 10-3 cm, and kp = kn = 1.2 × 10-2 W/cmK. The cross-

sectional area and pellet length of the thermoelement are An = Ap = 2.5 mm2 and Ln = Lp = 1.25

mm, respectively. The convection conductances on the 7-cm × 7-cm base areas are estimated to

be 8.01 , KmWh 2

1 40 , and 2

1 1200cmA for heat sink 1 (cabin air) and 8.02 ,

KmWh 2

2 800 , and 2

2 60cmA for heat sink 2 (coolant).

(a) For the optimal cooling power of one TEC module, determine the number of thermocouples

n, cooling power, COP, power input, cold and hot junction temperatures, current and voltage.

(b) For the ½ optimal COP per TEC module, determine the number of thermocouples n, cooling

power, COP, power input, cold and hot junction temperatures, current and voltage.

(c) Estimate the number of TEC modules needed to meet a cooling load of 600 W per occupant

with the ½ optimal COP (assuming that the module obtained represents the mean value of

the modules in the device).

(a) (b)

Page 36: Chapter 4 Optimal Design

4-36

Figure E4.2. (a) Thermoelectric air conditioner, and (b) TEC module.

Solution:

Material properties of Bi2Te3: =p − n = 416 × 10-6 V/K, = p + n = 2.2 × 10-5 m, and k

= kp + kn = 2.4 W/mK.

The convection conductances are given as

1 = 0.8, h1 = 40 W/m2K, A1 = 1200 cm2 and 2 = 0.8, h1 = 800 W/m2K, A1 = 60 cm2.

KWmKmWAh 84.3101200408.0 242

111

KWmKmWAh 84.310608008.0 242

222

The cross-sectional area and pellet length of the thermoelement are

A = 2.5 × 10-6m2 and L = 1.25 × 10-3m

The figure of merit is

13

5

262

10278.34.2102.2

10416

K

mKWm

KV

kZ

and

007.130710278.3 13

2

KKZT

The dimensionless fluid temperature from Equation (4.34) is

961.0307

295

2

1

K

K

T

TT

The dimensionless convection conductance from Equation (4.30) is

0.184.3

84.3

222

111 KW

KW

Ah

AhNh

(a) For the optimum cooling power:

Using Table B.2 for 12 ZT , we can approximately obtain the optimal parameters with both

96.0

T and 0.1hN as

Page 37: Chapter 4 Optimal Design

4-37

NI = 0.510, Nk = 0.286, COP = 0.335, 036.01 Q , 924.01 T , 141.12 T , and NV = 0.727.

Using Equation (4.29), the number of thermocouples is

8.228105.24.2

1025.184.3286.0

26

3

222

mmKW

mKW

kA

LAhNn k

Using Equation (4.35), the cooling power is

WKKWTAhQQ 46.4230784.3036.0222211

The COP is already obtained from Table 2 as

COP = 0.335

The power input from Equations (4.35), (4.36), and (4.45) is

WW

COP

QWn 748.126

335.0

46.421

The cold and hot junction temperatures from Equations (4.32) and (4.33) are

KKTTT 80.283307924.0211

KKTTT 76.350307142.1222

Using Equation (4.31), the current is

A

mKV

mmKW

L

kANI I 88.5

1025.110416

105.24.2510.0

36

26

Using the definition of dimensionless voltage in Equation (4.46), the voltage is

VKKVTnNV Vn 25.21307104168.228727.0 6

2

The number of modules for the cooling load of 600 W per occupant is

13.1446.42

600600

1

W

W

Q

WN

(b) For the ½ optimal COP per one TEC module:

Page 38: Chapter 4 Optimal Design

4-38

Using Table B.3 for 12 ZT , we can approximately obtain the optimal parameters with both

96.0

T and 0.1hN as

NI = 0.255, Nk = 0.143, COP = 1.385, 017.01 Q , 943.01 T , 030.12 T , and NV = 0.342.

Using Equation (4.29), the number of thermocouples is

4.114105.24.2

1025.184.3143.0

26

3

222

mmKW

mKW

kA

LAhNn k

Using Equation (4.35), the cooling power is

WKKWTAhQQ 05.2030784.3017.0222211

The COP is already obtained from Table 2 as

COP = 1.385

The power input from Equations (4.35), (4.36), and (4.45) is

WW

COP

QWn 48.14

385.1

05.201

The cold and hot junction temperatures from Equations (4.32) and (4.33) are

KKTTT 64.289307943.0211

KKTTT 364.316307030.1222

Using Equation (4.31), the current is

A

mKV

mmKW

L

kANI I 94.2

1025.110416

105.24.2255.0

36

26

Using the definition of dimensionless voltage in Equation (4.46), the voltage is

VKKVTnNV Vn 0.5307104164.114342.0 6

2

The number of modules for the cooling load of 600 W per occupant is

92.2905.20

600600

1

W

W

Q

WN

Table E4.2 Summary of the Optimal cooling power and ½ optimal COP.

Page 39: Chapter 4 Optimal Design

4-39

Per TEC Module Optimal Cool. Power COP ½ opt

n number of thermocouples n = 228.8 n = 114.4

Current (A) I = 5.88 A I = 2.94 A

Voltage (V) V n= 21.25 V V n= 5.0 V

COP COP = 0.335 COP = 1.385

Cooling power (W) Q1 = 42.46 W Q1 = 20.05 W

Power input (W) Wn= 126.75 W Wn = 14.48 W

Cold junction temperatureT1 T1 = 10.8°C T1 = 16.6°C

Hot junction temperature T2 T2 = 77.7°C T2 = 43.4°C

N number of modules for 600 W

(Total number of thermocouples)

(Total power consumption)

(Design comments)

N = 14.13

(N × n = 3233)

(126.75W × 14.13 = 1,791 W)

(Too high power consumption

for automobiles)

N = 29.92

(N × n = 3422)

(14.48W × 29.02 = 433 W)

(Acceptable design)

Comments: The optimal design of thermoelectric coolers with heat sinks is challenging because

the distinct optimal COP does not exist although the optimal cooling power clearly exists.

Therefore, a half optimal COP is introduced as a reference for the optimal COP. However, there

is no a strict rule for the optimal COP with heat sinks. If there is no heat sink, it becomes an ideal

device with the constant junction temperatures. The ideal maximum COP and the current are

usually available in the literature, which are

11

1

2

1

1

22

1

12

1max

TZ

T

TTZ

TT

TCOP and 11

)( 12

TZR

TTICOP

Using the cold and hot junction temperatures (16.6 °C and 43.4 °C) obtained for the half optimal

COP information, we calculate the ideal optimal COP and current as

011.0105.2

1025.1102.226

35

m

mmR

993.0

2

36.31664.28910278.3 13

KK

KTZ

Page 40: Chapter 4 Optimal Design

4-40

436.1

1993.01

64.289

36.316993.01

64.28936.316

64.289

2

1

2

1

max

K

K

KK

KCOP

ACCKV

ICOP 45.21993.01011.0

6.164.43104165.0

6

The ideal optimal COP and current are 1.436 and 2.54 A, which appear fortuitously close to the

half optimal COP and current (1.385 and 2.94 A). However, if we calculate the optimal cooling

power in the same way, we find that there are appreciable discrepancies between the optimal

values with heat sinks and the ideal values without heat sinks. In reality, the thermoelectric

device should work with one or two heat sinks and the ideal maximum COP and cooling power

with constant junction temperatures would cause significant errors.

Problems

4.1. As a potential alternative for clean energy generation, a thermoelectric generator (TEG) is

designed to recover exhaust waste energy from a car. An array of N = 36 modules (which

has the base area of 5-cm × 5-cm) is installed on the exhaust of the car (Figure P4.1). A

Page 41: Chapter 4 Optimal Design

4-41

recently developed material to meet the high temperature is nanostructured lead telluride

(PbTe) having the properties asp = −n = 218 V/K, p = n = 1.2 × 10-3 cm, and kp = kn

= 1.18 × 10-2 W/cmK. The cross-sectional area and pellet length of the thermoelement are An

= Ap = 2.6 mm2 and Ln = Lp = 1.2 mm, respectively. The exhaust gases at 720 K enter heat

sink 1 while coolant at 300 K enters heat sink 2. The convection conductances for the flows,

with consideration of the effectiveness of the heat sinks, are estimated on the 5-cm × 5-cm

base areas to be 8.01 , KmWh 2

1 45 , and 2

1 1000cmA for heat sink 1 (exhaust

gases) and 8.02 , KmWh 2

2 900 , and 2

2 500cmA for heat sink 2 (coolant). We want

to know the optimal number of the thermocouples per module for the given information.

(a) For the optimal design of one TEG module, determine the number of thermocouples

n, power output, conversion efficiency, hot and cold junction temperatures, current and

voltage.

(b) Determine the total power output (assuming that the module obtained represents the

mean value of the modules in the device).

(a) (b)

Figure P4.1 (a) the arrangement of the whole TEG device, and (b) the TEG module.

4.2. An automotive thermoelectric air conditioner is designed, which consists of two air heat

sinks and a coolant heat exchanger as shown in Figure P4.2a. We design a unit module

of 4-cm × 4-cm base area, which represents a mean value of the whole system as a

Page 42: Chapter 4 Optimal Design

4-42

simplified concept. Cabin air at 296.2 K enters the upper and lower heat sinks while

coolant at 311.8 K enters the central flat heat exchanger, so that the TEC modules are

installed between each heat sink and the central exchanger (Figure P4-4b). A widely

used material of Bi2Te3 has the properties asp = −n = 210 V/K, p = n = 1.1 × 10-3

cm, and kp = kn = 1.23 × 10-2 W/cmK. The cross-sectional area and pellet length of the

thermoelement are An = Ap = 1.8 mm2 and Ln = Lp = 0.9 mm, respectively. The

convection conductances on the 4-cm × 4-cm base areas are estimated to be 8.01 ,

KmWh 2

1 40 , and 2

1 600cmA for heat sink 1 (cabin air) and 8.02 ,

KmWh 2

2 960 , and 2

2 25cmA for heat sink 2 (coolant).

(a) For the optimal cooling power per one TEC module, determine the number of

thermocouples n, cooling power, COP, power input, cold and hot junction temperatures,

current and voltage.

(b) For the ½ optimal COP per TEC module, determine the number of thermocouples n,

cooling power, COP, power input, cold and hot junction temperatures, current and

voltage.

(c) Estimate the number of TEC modules to meet the cooling load of 600 W per occupant

with the ½ optimal COP (assuming that the module obtained represents the mean value

of the modules in the device).

(a) (b)

Page 43: Chapter 4 Optimal Design

4-43

Figure P4.2. (a) Thermoelectric air conditioner, and (b) TEC module.

References

1. Kraemer, D., et al., High-performance flat-panel solar thermoelectric generators with high

thermal concentration. Nat Mater, 2011. 10(7): p. 532-8.

2. Karri, M.A., E.F. Thacher, and B.T. Helenbrook, Exhaust energy conversion by

thermoelectric generator: Two case studies. Energy Conversion and Management, 2011.

52(3): p. 1596-1611.

3. Hsu, C.-T., et al., Experiments and simulations on low-temperature waste heat harvesting

system by thermoelectric power generators. Applied Energy, 2011. 88(4): p. 1291-1297.

4. Henderson, J. Analysis of a heat exchanger-thermoelectric generator system. in 14th

Intersociety Energy Conversion Engineering Conference. 1979. Boston, Massachusettes.

5. Stevens, J.W., Optimal design of small DT thermoelectric generation systems. Energy

Conversion and Management, 2001. 42: p. 709-720.

6. Crane, D.T. and G.S. Jackson, Optimization of cross flow heat exchangers for

thermoelectric waste heat recovery. Energy Conversion and Management, 2004. 45(9-10):

p. 1565-1582.

7. Rowe, D.M., Thermoelectrics handbook; macro to nano. 2006, Roca Raton: CRC Taylor

& Francis,.

8. Chein, R. and G. Huang, Thermoelectric cooler application in electronic cooling. Applied

Thermal Engineering, 2004. 24(14-15): p. 2207-2217.

9. Vining, C.B., An inconvenient truth about thermoelectrics. Nature Materials, 2009. 8: p.

83-5.

10. Lee, H., Optimal design of thermoelectric devices with dimensional analysis. Applied

Energy, 2013. 106: p. 79-88.