chapter 2 handouts-reduced chang
TRANSCRIPT
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Atoms, Molecules, and Ions
Chapter 2
Copyright © The McGraw-Hill Companies, Inc. Permission required for reproduction or display.
Dr. Mohammed Tariq SaeedOffice # 138/ 142-A
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Atomic number (Z) = number of protons in nucleus
Mass number (A) = number of protons + number of neutrons
= atomic number (Z) + number of neutrons
Isotopes are atoms of the same element (X) with different numbers of neutrons in their nuclei
XAZ
H11 H (D)2
1 H (T)31
U23592 U238
92
Mass Number Atomic Number
Element Symbol
2.3: Atomic Number, Mass Number, and Isotopes
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The Isotopes of Hydrogen
Give the number of protons, neutrons, and electrons in each of the following species:
(a)
(b)
(c)
(d) Carbon-14
Example 2.1
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2.4: The Modern Periodic Table
PeriodG
roup
Alkali M
etal
Noble G
asH
alogen
Alkali E
arth Metal
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2.5: Molecules and Ions:
A molecule is an aggregate of two or more atoms in a definite arrangement held together by chemical forces.
H2 H2O NH3 CH4
A diatomic molecule contains only two atoms:
H2, N2, O2, Br2, HCl, CO
diatomic elements
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An ion is an atom, or group of atoms, that has a net positive or negative charge.
cation – ion with a positive chargeIf a neutral atom loses one or more electronsit becomes a cation.
Na 11 protons11 electrons Na+ 11 protons
10 electrons
O3, H2O, NH3, CH4
A polyatomic molecule contains more than two atoms:
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A monatomic ion contains only one atom:
A polyatomic ion contains more than one atom:
Na+, Cl-, Ca2+, O2-, Al3+, N3-
OH-, CN-, NH4+, NO3
-
Cl-17 protons18 electronsCl 17 protons
17 electrons
anion – ion with a negative chargeIf a neutral atom gains one or more electronsit becomes an anion.
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Common Ions Shown on the Periodic Table
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Formulas and Models2.6: Chemical Formulas
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A molecular formula shows the exact number of atoms of each element in the smallest unit of a substance.
An empirical formula shows the simplest whole-number ratio of the atoms in a substance.
H2OH2O
molecular empirical
C6H12O6 CH2O
O3 O
N2H4 NH2
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Example 2.2
Write the molecular formula of methanol, an organic solvent and antifreeze, from its ball-and-stick model, shown below.
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Example 2.3Write the empirical formulas for the following molecules:
(a) acetylene (C2H2), which is used in welding torches
(b) glucose (C6H12O6), a substance known as blood sugar
(c) nitrous oxide (N2O), a gas that is used as an anesthetic gas (“laughing gas”) and as an aerosol propellant for whipped creams.
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Ionic compounds consist of a combination of cations and anions.• The formula is usually the same as the empirical formula.• The sum of the charges on the cation(s) and anion(s) in
each formula unit must equal zero.
The ionic compound NaCl
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The most reactive metals (green) and the most reactive nonmetals (blue) combine to form ionic compounds.
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Formulas of Ionic Compounds
Al2O3
2 x +3 = +6 3 x -2 = -6
Al3+ O2-
CaBr2
1 x +2 = +2 2 x -1 = -2
Ca2+ Br-
Na2CO3
2 x +1 = +2 1 x -2 = -2
Na+ CO32-
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Example 2.4Write the formula of magnesium nitride, containing the Mg2+ and N3− ions.Strategy: Compound is electrically Neutral, Total charge on cations = total charge on anions.
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2.7: Naming CompoundsChemical Nomenclature• Binary Ionic Compounds Type-I
– The name of the cation is written first (Metal + non metal)
– In the name of the anion (nonmetal) add “-ide” to root element name(in the last)
BaCl2 Barium chloride
K2O Potassium oxide
Mg(OH)2 Magnesium hydroxideNaCl Sodium chloride
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Cont’d
• Binary Ionic Compounds Type-II– Metals have more than one charge, Add numeral
number to indicate the charge on these ions.– In the name of the anion (nonmetal) add “-ide” to
root element name(in the last)
• Binary Ionic Compounds Type-IExample:Compound Ions present Name
NaI Na+, I- Sodium iodideCaSLi3NMgO
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FeCl3 3 Cl- -3 so Fe is +3 Iron(III) chloride
Cr2S3 3 S-2 -6 so Cr is +3 (6/2) Chromium(III) sulfide
Example: FeCl2 (Fe has +2 charge) written as Iron(II) chloride
Ex. Compound Cations Name FeO
Cr2O4
CuCl2
Al(OH)3
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Example 2.5
Name the following ionic compound with poly atomic ions:
(a) Cu(NO3)2
(b) KH2PO4
(c) NH4ClO3
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Example 2.6
Write chemical formulas for the following compounds:
(a) Mercury(I) nitrite
(b) Cesium sulfide
(c) Calcium phosphate
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• Binary molecular covalent compounds Type-III: Non-metal-Nonmetal(Use prefix and suffix)− The first element in the compound is
named first using the name of the element.
− The second element is named as though it were an anion (using the root name of the element and adding the suffix (-ide).
− Prefixes are used to denote the numbers of each atom present.
− Prefix mono- never used for naming the first element. Ex. CO Carbon monoxide not mono carbonmonoxide
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HI Hydrogen iodide
NF3 Nitrogen trifluoride
SO2 Sulfur dioxide
N2Cl4 Dinitrogen tetrachloride
NO2 Nitrogen dioxide
N2O Dinitrogen monoxide
Molecular Compounds: Nonmetal-nonmetal
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Example 2.7Name the following molecular compounds and chemical formula: (a) SiCl4
(b) P4O10
(c) CO
(d) N2O4
(e) Carbon disulfide
(f) Disilicon hexachloride
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ExampleLearning Check
• Rules: Often drop o and a from the prefix when element begin with vowel– Mono – monoxide, tetra - tetroxide
• Example: Systematic name Common name
• N2O Dinitrogen monoxide Nitrous oxide• NO Nitrogen monoxide Nitric oxide• NO2
• N2O3
• N2O4
• N2O5
Note: Some compound always referred to by their common names not systematic names
Ex. H2O:water; NH3: Ammonia; and H2O2 : Hydrogen peroxide
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An acid can be defined as a substance that yields hydrogen ions (H+) when dissolved in water.For example: HCl gas and HCl in water• Pure substance, hydrogen
chloride dissolved in water (H3O+ and Cl−), aqueous hydrochloric acid is formed
Acid and Base
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If anion of an acid does not contain oxygenUse prefix hydro—and suffix –ic attached to the root name of the element and anion contain ide in last, It means -ic (acid) -ide (anion)
Non oxy Acid
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The acids containing oxygen:The rules for naming oxoanions, anions of oxoacids, are as follows:1. When all the H ions are removed from the
“-ic” acid, the anion’s name ends with “-ate.” 2. When all the H ions are removed from the
“-ous” acid, the anion’s name ends with “-ite.”3. The names of anions in which one or more
but not all the hydrogen ions have been removed must indicate the number of H ions present. For example:– H2PO4
- dihydrogen phosphate– HPO4
2- hydrogen phosphate– PO4
3- phosphate
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An oxoacid is an acid that contains hydrogen, oxygen, and another element. Anion –ate change to suffix ic, -ite change to -ous
HNO3 -NO31- nitrate nitric acid
H2CO3 -CO32-
carbonate carbonic acidH3PO4 -PO4
3- phosphate phosphoric acid
Acid -ate
-ic
Acid -ite -ousHNO2 -NO2
1- nitrite nitrous acid
H2SO3 -SO32-
sulfite sulfurous acid
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Example 2.9Name the following oxo-acid and oxo-anion:
(a)H3PO3
(b)
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Naming Oxo-acids and Oxo-anions
4 O
3 O
2 O
O
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A base can be defined as a substance that yields hydroxide ions (OH-) when dissolved in water.
NaOH sodium hydroxide
KOH potassium hydroxide
Ba(OH)2 barium hydroxide
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Hydrates are compounds that have a specific number of water molecules attached to them.
BaCl2•2H2O
LiCl•H2O
MgSO4•7H2O
Sr(NO3)2 •4H2O
barium chloride dihydrate
lithium chloride monohydrate
magnesium sulfate heptahydrate
strontium nitrate tetrahydrate
CuSO4•5H2O CuSO4
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Organic Chemistry?A branch of chemistry involving the study of carbon-containing chemical compounds.
Why is carbon so special?• Carbon atoms connect with one another
through strong and stable covalent bonds.
• Carbon atoms also readily form bonds with many other types of atoms. This provides for a near infinite number of different kinds of organic compounds.
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HydrocarbonsA chemical compound containing only hydrogen and carbon. Two types of hydrocarbonA. Saturated Hydrocarbon: The molecular formula is (Single bond)The simplest aliphatic compound is alkaneAlkane CnH2n+2
CH4 MethaneCH3-CH3 EthaneCH3- CH3-CH3 Propane
B. Unsaturated Hydrocarbon : They contain double / triple bonds in the compounds. . Alkene CnH2n Ethylene C2H4 CH2=CH2 , Propylene C3H6 CH2=CH-CH3
- Alkynes CnH2n-2 Acetylene,
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Structural IsomerMolecules having the same molecular formula but different structures.
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Structural IsomerFormula Number of possible isomers
C5H12 3C6H14 5C7H16 9C8H18 18...
C20H42366,319
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What is the chemical formula for the following structure?
A. C3H8
B. C4H10 C. C5H12
D. C6H14
Line formula for: C3H8
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Organic chemistry is the branch of chemistry that deals with carbon compounds.
C
H
H
H OH C
H
H
H NH2 C
H
H
H C OH
O
methanol methylamine acetic acid
Functional Groups:
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