めっき皮膜の密着性入門 -...
TRANSCRIPT
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http://www.tri.pref.osaka.jp/group/surface/
Adhision ofPlating films)
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0.3C
0.23C
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,Vol.23No.3p.261985
,31,352(1980)
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SUS304)
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300
330
20200
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JIS
Al-Cr-MoCr-Mo
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2
1
12,46,13(1995)
20.250.5
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(Surface)
(Interface)
etc.
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(pure surface)
(clean surface)(technically clean surface)
Weak boundary
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2kcal/mol
37kcal/mol
20200kcal/mol
50150kcal/mol)
1030kcal/mol
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Mn++neM02H++2eH2
M+H2OMO+H2
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Vol.23,No.31985
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PR
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,33,294(1986)
BC6)Ni-Cr
Cu-Sn
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5104051070
+
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+++
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520
Cu2+ +2e Cu + 0.32V (vs.NHE)
FeFe2+ +2e 0.43V (vs.NHE)
CuCN)2- +e Cu 0.43V (vs.NHE)
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0
10
20
30
40
50
60
0 10 20 30
(A/dm2)
(
/hr
Watt
Wood
y = 0.1291x - 0.0572
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
0 10 20 30Time (hr)
(
m
SUS3040.4/s
Ni1020
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59(1985)
SUS304
+Wood(1um)
0
1
2
3
4
5
6
0 20 40
Time (s)
Int. (a.
u.)
O C Fe Ni Cr
(1um)
0
1
2
3
4
5
6
0 20 40
Time (s)
Int. (a.
u.)
O C Fe Ni Cr
Ni +NiNi
GDS
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SUS304
0
0.2
0.4
0.6
0.8
1
1.2
1.4
1.6
1.8
2
0 20 40
Time (s)
Int. (a.
u.)
NO1 NO2 NO3 NO4
0
0.1
0.2
0.3
0.4
0.5
0.6
0.7
0.8
0.9
1
0 20 40
Time (s)
Int. (a.
u.)
NO1 NO2 NO3 NO4
SUS304NiGDS)No.1+No.2+WoodNo.3No.4
GDS
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Ni
10
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501
,2,29(1989)
650g/cm)
250g/cm)
,2,29(1989)
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Cu+Cu+
,2,29(1989)
JIS8645Ni
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5801
30m
TiCu+Ni-BN
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ADC12
0
0.5
1
1.5
2
2.5
3
3.5
4
4.5
0 10 20 30 40 50
(
(k
gf/cm
)
70 150 200 300
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Cu+
ADC12
M-M-M-M
M-M-M-MO O O O
Poor
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CrO3ESCA
CrO3Fe2p
FeFe
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CrO3-H2SO4
CrO3-H2SO4Fe
NiNi
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Ni
BC6Ni
Cu-Ni
Cu-N-Cri
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Ni-Cr
Ni-Cr
,46,13(1995)
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JISH8504
SUSNi2)
AE1)
1,37,p575(1986)2,48,p687(1997)
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1mm
5mm
1mm
5mm
/
31.4
Ni/Cu 400 28.5 Ni
700 20.2 Ni
34.2
Ni-W/Cu 400 30.7
700
31.7 Ni
Ni-W/Ni 400 25.1 Ni-W
700 22.9 Ni-W
NEDO 133
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(http://www.tri.pref.osaka.jp/group/surface)
13OHP
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1994
1995
211978
,31,352(1980)
,Vol.23No.3p.261985
10,46,13(1995),48,p687(1997)
11,33,294(1986)
12,37,p575(1986)