central regional laboratory · quant1 tation limit is estimated. ul * not detected. ouantitation...

EPA Region IIICentral Regional Laboratory

NOVAK SANITARY LANDFILL

SUPERFUND ENF ACCT. NO. TGB03NPQ2

REQ 9300052

______FEBRUARY 23. 1993

VALIDATEDWATERS ^A _'____ANALYTICAL

>ATA

LEGALTESTIMONY

SCIENTIFICEXPERTISE

P»U»,_i| ^ r __ ^

ZExcettence and Purpose in ActionflR308l*2Q

UNITED STATUS FNVIKONMKNTAU PROTKCTION AUKNCVRKGIOMII

CENTRAL RKGIONA1. LABORATORY839 BESTtJATE ROAD

ANNAPOLIS, MARYLAND 21401- 3013(410) S73 - 2799

DATE : February 23, 1993

SUBJECT: Analytical Results for Novak Sanitary Landfill (REQ 9300052)

FROH : Frederick Dreisch, Chief faLaboratory Branch (3ES20)

TO : Caeser Lee

Attached are the analytical results for Volatile Gas Chromatography/MassSpectrometry Analyses determinations of site samples submitted to theCentral Regional Laboratory on January 29, 1993.

If you have any questions or comments, please call me at (410) 573-2646,or Charles Veisberg. Chief, Organic Section (410) 573-2681.

cc: Michael Heffron (DYNAMAC)

Attachments

J.

Excellence and Purpose In Action --- Environmental Services Division

frinttd on Rtcycltd Paptr

I'SITKD STMF.S IA v il< AMI NT A! I1..Oil ' TION A(iKVYRIXJIO.N HI

CENTRAL kKCIONALl ABORATORVX.V> UESTl'JATE ROAD

ANNAPOLIS. MARYLAND 21401-3013(410) 573 - 2799

DATE : February 23, 1993

SUBJECT: Open Memo on Changes to CRL Analytical Report Formats

FROH : Frederick Dreisch (3ES20)ft>Chief, Laboratory Branch **

TO : CRL Data Users

The Central Regional Laboratory will supply you with a new automated re-port that combines information from the laboratory. This new report isour effort to make the information from CRL easier to read and understand.I hope this new report satisfies your needs and eventually will replaceour old customary analytical report formats.

To understand this report, the following conventions and explanations arein order:

The first page provides CRL sample numbers and a brief des-cription of what each sample was. Included is the beginningand ending collection dates and what matrix CRL identified thesample to be. This table page also contains signatures of theappropriate approving officials. During the interim period,reports without the QCO signature indicate that this report isnot the "official" report. The manually-generated report isthe report of record until the transition is complete. Bothmanual and automatic summary reports have been reviewed by theanalyst(s) and have passed a second review.

The second page provides the information on which tests CRLperformed on the requested samples and the names of thosetests CRL uses. CRL has defined the most commonly requestedanalyses in a simple five (5) character code. Generally thefirst three characters are close to the analytical name, e.g.EXT for extractables, VGA for volatiles, and so on. Thefourth character is the version number. It is CRL's intentionto maintain data over several years. Changes in TEST defi-nitions (additions, corrections, deletions) require thecreation of new codes while maintaining the old information.Thus, the need for a version code. The final character of theTEST definition is the matrix code:

1 - Aqueous/water2 - Soil/Sed.

trinltd on Reeycltd Paper

3 - Oil4 - Tissue5 - Wipe samples

The body of the report has several characteristics; each set ofsamples are broken down into the service groups CRL uses:

EX - Extractable organic compounds by GC/HSOR - PCBs and Pesticides by GCVO - Volatile organic compounds by GC and GC/HSME - MetalsQC - Quality ControlIN - Inorganic parameters

The full name and GAS number (Chemical Abstracts System) arepresented when the compound is found in any of the samples ina request. Units for the compounds are found to the right ofthe compound name and CAS number.

Under most TESTs, there are • several compound names. Only '-compounds that were detected are reported. If a compound isfound in one sample of the set but not for the specificsample, a dashed line appears. CRL has defined differentTESTs for the same compounds. The primary reason differenttests are assigned is because different matrices requiredifferent units. If the space under the sample number isblank, this means that the TEST (for this matrix) was notrequested for this sample.

If you have any comments or concerns with this new report, pleasecall me at (410)266-9180.

Excellence and Purpose in Action --• Environmental Services Division

U.S. EPA Region III Section:Central Regional Laboratory

Annapolis, Md. 2140102/17/93

Request No. REQ9300052 Site: NOVAK LANDFILL

Account No. T6B03NPQ2 Program: SUPERFUND ENF

Collection DatesSample Umber Description Beginning Ending Hatrix

93012901 ML-RW-12-01, STA. RU-12 01/28/93 - 01/28/93 Ground Water93012902 HL-RU-01-01, STA. RU-01 01/28/93 - 01/28/93 Crowd Water93012903 NL-RW-06-01, STA. RW-06 01/28/93 - 01/28/93 Ground Water93012904 NL-RW-06-02, STA, RW-06 01/28/93 - 01/28/93 Grand Water93012905 NL-BL-01, STA. BL-01 01/28/93 • 01/28/93 Ground Water93012906 CRL LAB BLANK 02/01/93 • 02/01/93 Aqueous

Passed Analyst Data

Reviews: .organ. Sec. Chief N Date QCOChief^

Laboratory Branch Chief Approval For Release:

Date

I Date

U.S. EPA Region III Section: ACentral Regional Laboratory Page : 2

Annapolis, Hd. 2140102/17/93

Saoptc Test Description

95012901 VOA47 HETHOO 524, Aqueous long list93012902 VOA47 METHOD 524, Aqueous long list93012903 VOA47 METHOD 524, Aqueous long list93012904 VOA47 METHOD 524, Aqueous long list93012905 VOA47 METHOD 524, Aqueous long list93012906 VCA47 METHOD 524. Aqueous long list

AR3Q8l*25

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central Regional Laboratory - Region III Section: cVolatile Organics Analysis Page : 4

Nominal Quantitation Limits (NQL)'•.

Units: Aqueous » ug/L Non-aqueous « ug/Kg (Wet) NPTC * Non-Priority Pollutant Target CompoundTest: Water * VOA45 Soil * VOA46 Actual Quantitation Limit * (Dilution Factor) x NQL

| CAS Number | Analyte |HQL| | CAS Number | Analyte |NQL|1(75-71-8(74-87-3J75-01-4(74-83-91 75-00-3| 75-69-4J75-35-4|75- 15-0J67-64-1J75-09-2| 156-60-5(75-34-3j 108-05-4J590-20-7| 156-59-4J78-93-3J74-97-5J65-66-3 'J71-55-6J56-23-5J563-58-6(71-43-2J107-06-2J79-01-6J78-87-5J74-95-3J75-27-4j 110-75-3(10061-01-6J103-10-1j 108-88-310061*01-5(79-00-5(127-18-4

1|0 1 ch I orodf f luoromethane(Chloromethant(Vinyl Chloride(Brofflcroe thane(Chloroethane(Trichlorofluoromethane(1,1-Dichloroethylene(Carbon Disulf ide NPTC(Acetone NPTC(Methylem Chloride|trans-1,2-Dichlorotthene|1,1-Dichloroethane.(Vinyl Acetate NPTC(2,2-Diehloropropanejcts-1,2-Dichloroethene NPTC|2-8utanone NPTC(Branch loromethane NPTC| Chloroformjl.l.l-Trichloroethane(Carbon Tetrachloride(1.1-Olchloro-l-propena(Benzene(1,2-Dfchloroethane(Trichloroethylene(1,2-Dfchloropropane(Dibromcaethane NPTC(Bromodichloromethane|2-Chloroethylvinyletherjtrans-1.3-[>ichloropropene NPTC|4-Methyl-2-pentanon» NPTC(Toluene|cis-1,3-Dichloropropene(1,1,2-Trichloroethane(Tetrachloroethytene

5555555555555555555555555555255855

1(142-28-9(591-78-6(124-48-1(106-93-4(103-90-7(630-20-6(100-41-4(108-38-3(106-42-3(95-47-6(100-42-5(75-25-2(98-32-8| 108-86-1(79-34-5(96-18-4(103-65-1(95-49-8(106-43-4(108-67-8(98-06-6(93-63-6(135-98-8(541-73-1(106-46-7(99-87-6(95-50-1| 104-51 -8(96-12-8(120-82-1(91-20-387-63-3|WI WW

(87-61-6

I(1,3-Dichloropropane NPTC|2-Hexanone NPTC(Dibromochloromethane|1.2-Dibromoethane (EOS) NPTC(Chlorobenzene(1,1,1,2-Tetrachloroethane NPTCJEthyl benzenejm-Xylene > (m 4 p isomers NPTCjp-Xylene together) NPTC|o-xylene NPTC(Styrene NPTC(Bromoform| I sopropy 1 benzene NPTC(Bromobenzene NPTC(1 ,1 ,2,2-Tetrachloroethan*(1.2.3-Trtchloropropane NPTC(n-Propylbenzene NPTC|2-Chlorotoluene NPTC|4-Chlorotoluene NPTC|1.3,5-Trimethylbenzen« NPTCjtert-Butylbenzene NPTC(1,2,4-Trimethylbenzene NPTCjsec-Butylbenzene NPTC| 1 ,3-Di ch lorobenzene1 1 ,4-D i ch I orobenzene|p-Isopropyltoluene NPTC|1.2-Dichlorcbenzenejn-Butylbenzene NPTC|1,2-Dibromo-3-chloroprcpaneNPTC(1,2,4-Trichlorobenzen*(Naphthalene| Hexach lorobutadi ene(1,2,3-Trichlorobenzene NPTC

555555555555555555555555555555555

The "Nominal Quantitation Limit11 listed for each target compound is based on the Superfund CLP protocol. These have beenverified at the Central Regional Laboratory using the method detailed by Uillian Budde, et al., "Trace Analyses forWastewater" Environmental Science and Technology. Volume 15. No. 12, December 1981, p. 1426-1435. The Actual QuantitationLimits are related to the NQLs by a dilution factor. "This dilution factor reflects procedural steps, e.g., sampledilution, which influence the quantitation limits. The equations used for this dilution factor are as follows:

Dilution 5mL (Ideal Sample Vol.) X (Ext D. F.) Dilution 1* 5gm (Ideal Sample Ut.) X (Ext D. F.)Factor « •————————————— Factor * ——————————————(water) Actual Sample Vol. (nt) (nonaqueous) Actual Sample Ut. (gm)

The "Ext. D.F." in these equations refers to the extract dilution factor in the case of soils and the sample dilutionfactor in the case of aqueous samples.

October 1992

AR308-*27

REGION III Section: DCENTRAL REGIONAL LABORATORY Page : 5

QUALIFIER CODES

A * Quality Control value U outside acceptance limits.

B » Not detected substantially above (10 times) the level reported in the laboratory or field blanks (includes field,trip, rfnsate, and equipment blanks).

C « See report narrative for analyst's observations concerning this result.

0 * Sample and duplicate value below quantitat Ion limit. Quantitatton limit reported.

E * Value exceeds a theoretically equivalent or greater value (e.g. dissolved > total, orthophosphate > totalphosphorus). However, the difference is within the expected precision of the analytical techniques and isnot statistically significant.

I * An interference exists which masks true response. See report narrative for explanation.

J « Analyte present. Reported value is estimated; concentration is below the level for accurate quantl ration.

K * Analyte present. Reported value may be biased high. Actual value is expected to be lower.

L • Analyte present. Reported value may be biased low. Actual value is expected to be higher.

HSA« Method of Standard Additions

N * Presumptive evidence Indicates the presence of compound. Special methods and/or method modifications nay beneeded to confirm its presence or absence in future sanpling efforts.

NA * Analysis was not requested.

Q « No analytical results. See report narrative for explanation.

R * Unreliable results, Analyte may or may not be present in the cample. Supporting data is necessary to confirm results.

RFC* Results for method duplicates are expressed as the mean and the relative percent difference.

T » Tentatively identified compound. Identified as a result of.a library search using the EPA/NIH Mass Spectral Library.Authentic standards were not available to properly identify and quantitate the compound. The reported concentration isan estimate.

TD • Spike recovery too dilute for accurate quantltation.

UJ * Not detected. Quant1 tation limit is estimated.

UL * Not detected. Ouantitation limit is probably higher.

•— * Not detected. Actual Ouantitation Limit * Nominal Quantitation Limit times the dilution factor.

< * Sample value below quantitation limit, fiuantitatlon limit reported.S « Reported value Is estimated. Sample analyzed In duplicate, one value is equal to or above the quantitation limit

and one below. Average of quantitation limit and detected value reported.

Numbers in parentheses are analytical (post-digestion) spike recoveries.Numbers in brackets are matrix [pre-digestion] spike recoveries.

(OCCOOES February 1993) * Environmental Services Division

flR3U8lf28

• . • • r !, -•.-.-. ./ ; .- • . • • ' ' •

Environmental Services Assistance Teams Phone: (410) 268-7705??Xp!)3 __. _ Fax:(410)268-84721419 Forest Drive. Suite 104Annapolis; Maryland 21403

DATE: February 11, 1993

SUBJECT: Volatile Gas Chromatography/Mass Spectrometry Analysesof Samples from the Novak Sanitary LF Site forSuperfund-Enforcement (TGB03NPQ2) . (02/03/93 to02/08/93); Samples: 930129-01 thru 930129-06; ESATTID No.: 03921014; ESAT Task No.: 2249; ESAT PWO No.232-31-104.

PROM: Sue RaupukOrganic Analytical Chemist

TO: Frederick OreischChief, Laboratory Branch

THRU: Kenneth W. CurryESAT Assistant Team Manager

OVERVIEW

Five (5) aqueous samples and one (1) CRL Lab Blank sample werereceived at CRL on January 29, 1993 for analyses of bothhazardous substance list (HSL) and priority pollutant list (PPL)volatile organic compounds. Samples were analyzed on February 3,1993 following methods from the "USEPA Contract LaboratoryProgram Statement of Work for Organics Analysis", February, 1988and EPA Method 624, "Purgeables" , Federal Register. October,1984. Instrumentation utilized consisted of a purge and trapapparatus (Tekmar ALS 2016/LSC 2000) interfaced to a gas -chromatograph/mass spectrometer (HP 5890/HP 5970) equipped with afused silica capillary column (VOCOL 105m x 0.53mm ID x 3.0umfilm thickness) . The samples that were received for analyses aredescribed in the following table.

SAMPLE IDENTIFICATION;

Sample No. Description

930129-01 Novak Sanitary LF, NL-RW-12-01, Sta. RW-12930129-02 Novak Sanitary LF, NL-RW-01-01, Sta. RW-01930129-03 Novak Sanitary LF, NL-RW-06-01, Sta. RW-06930129-04 Novak Sanitary LF, NL-RW-06-02, Sta. RW-06930129-05 Novak Sanitary LF, NL-BL-01, Sta. BL-01930129-06 Novak Sanitary LF, CRL Lab Blank

AR308l*29

Site Name: Novak Sanitary LF page 2 of 3Sample Nos.: 930129-01-06Analysis: Volatile Organic Compounds

KOTES

A lower detection limit (1.0 ppb) was requested for theanalysis of these samples. In order to achieve thisdetection limit, the following modifications -to the abovemethods were implemented: 1) twenty-five (25) millilitersof sample were purged, 2) the initial calibration curve wasanalyzed at 1.0, 5.0, 10.0, 20.0 and 40.0 ug/L and 3) thedaily calibration check standard was analyzed at aconcentration of 10.0 ug/L.

The target compounds' concentrations were calculated usingrelative response factors based on the closest elutinginternal standard. The internal standard and surrogatemixes were added immediately prior to analyses.

All HSL and PPL compounds which were positively identifiedare reported on the volatile analysis data sheet. Thecontaminants found below their nominal guantitation limit(NQL) are qualified WJ" for estimated.

All other eluting peaks with an area above ten. percent ofthe nearest internal standard were compared to the NBS massspectral library for tentative identification. There wereno compounds in these samples which were identified usingthis procedure .

All compounds which were found in both a method blank and/ora field blank and a sample were qualified "B" if theconcentration of the compound in the sample was less thanten times (lOx) the compound's concentration in the blank.

All samples were analyzed only after correct systemperformance was confirmed to meet EPA approved tuningcriteria for Bromof luorobenzene (BFB) .

All samples were found properly preserved at pH = 2 at theanalytical bench and were analyzed within the fourteen dayholding time.

Thirty-five (35) out of thirty-six (36) surrogate recoverieswere within Region III CRL Q.C. limits. (Refer to theVolatile Surrogate Recovery Data Sheet - FORM II) . A matrixspike and matrix spike duplicate were analyzed with thissample set and all recoveries and %RPDs were within RegionIII CRL Q.C. limits (Refer to the Matrix Spike %RecoveryData Sheet - FORM III) .

AR3Q8l*30

Site Name: Movak Sanitary LF page 3 of 3Sample Nos.: 930129-01-06Analysis: Volatile Organic Compounds

NOTES (Contd.l

o A Laboratory Control Sample (LCS) was analyzed with thissample set and all compound recoveries monitored by ESATwere found to be within Region III CRL Q.C. Limits (Refer tothe ESAT LCS % Recovery Data.Sheet - FORM XI).

o All compounds exhibited a %D less than twenty-five (25)percent when comparing the daily calibration standard andthe initial calibration curve. The %RSDs for methylenechloride and 2-chloroethylvinyl ether in the initialcalibration standards were above thirty (30) percent. Thesecompounds are qualified "Jn, estimated, for the positiveresults and "UJ", undetected estimated, for non-positiveresults in the affected samples.

Attachments

1. Appendix A - Glossary of Data Qualifier Codes

2. Appendix B - Data and Q.C. Summary; Results as Reported andQualified by the Laboratory

SR302A03.NLF

AR3Q8l*3l

APPENDIX A

Glossary of Data Qualifier Codes

AR308t>32

Region MlCentral Regional Laboratory Qualifier Codes

A » Quality control value outside acceptance limits.

B » Not detected substantially above (10 times} the level reported in the laboratory or field blanks(includes field, trip, rinsate and equipment blanks).

C * See report narrative for analyst's observations concerning this result.

D * Sample and duplicate value belou quantitation limit. Quantitation limit reported.

E * Value exceeds a theoretically equivalent or greater value (e.g. dissolved > total, orthophosphate >total phosphorus). However, the difference is within the expected precision of the analyticaltechniques and is not statistically significant.

I » An interference exists which mask true response. See report narrative for explanation.

J * Analyte present. Reported value is estimated; concentration is below the level for accuratequantitation.

K » Analyte present. Reported value may be biased high. Actual value is expected to be lower.

L * Analyte present. Reported value may be biased low. Actual value is expected to be higher.

MSA« Method of Standard Additions.

N * Presumptive evidence indicates the presence of compound. Special methods and/or method —••'modifications may be needed to confirm its presence or absence in future sampling efforts.

NA » Analysis was not requested.

Q • No analytical results. See report narrative for explanation.

R * Unreliable results. Analyte may or may not be present in the sample. Supporting data is necessaryto confirm results.

RPD» Results for method duplicates are expressed as the mean and the relative percent difference.

T - Tentatively identified compound. Identified as a result of a library search using the EPA/MIH MassSpectral Library. Authentic standards were not available to properly identify and quantitate thecompound. The reported concentration is an estimate.

TO « Spike recovery too dilute for accurate quantitation.

UJ » Not detected. Quantitation limit is estimated.

UL » Not detected. Quantitation limit probably higher.

— » Not detected. Actual Ouantitation Limit * Nominal Quantitation Limit times the correction factor.

< • Sample value below quantitation limit. Quantitation limit reported.

< • Reported value is estimated. Sample analyzed in duplicate, one value is equal to or above the~ quantitation limit and one below. Average of quantitation limit and detected value reported.

Numbers in parentheses are analytical spike recoveries (e.g. post-digestion spikes).

Numbers in brackets are matrix spike recoveries (e.g. pre-digestion spikes).

(QCCOOES February 1993) —

&R308U33

APPENDIX B

Data and Q.C. Summary

BR3G8U3U

1A ERA SAMPLEVOLATILE ORGAN I CS ANALYSIS DATA SHEET

I II NL-RLJ-12-01 I

Lab Name: EPA REGION III CRL Contract: LOCKHEED I ______________ I

Lab Code: ESAT Case No.: NOUAK SAS No.: N/A SDG No.: N/A

Matrix: (soil/water) WATER Lab Sample ID: 930129-01

Sample wt/vol: 25.0 <g/ml) ML Lab File ID: >B8134

Level: (low/med) LOW Date Received: 01/29/93

% Moisture: not dec. N/A Date Analyzed: 02/03/93

Column: (pack/cap) CAP Dilution Factor: 1.0

CONCENTRATION UNITS:CAS NO. COMPOUND (ug/L or ug/Kg) ug/L Q

75-71-874-87-375-01-0474-83-975-00-375-69-475-35-475-15-067-64-175-09-275-34-3156-60-5108-05-4594-20-7156-59-278-93-374-97-567-66-371-55-656-23-5563-58-671-43-2107-06-279-01-678-87-574-95-375-274110-75-810061-01-5108-10-179-00-5108-88-310061-02-6591-78-6

Dich lorodif luorome thaneChloromethaneUinyl ChlorideBromome thaneCh loroethaneTr ichlorof luorome thane1 , 1-Dich loroetheneCarbon DisulfideAcetoneMethylene Chloride1, 1-Dich loroethaneTrans-l.,2-D ich loroetheneUinyl Acetate2,2-Dich loropropanaCis-l,2-Dich loroethene2-ButanoneBromoch lor ome thaneChloroform1,1,1-Trich loroethaneCarbon Tet rachior ide1 , 1-Dich loro-1-propeneBenzene1,2-D ich loroethaneTr ich loroethene1,2- Dich loropropaneDibromome thaneBromodi chloromethane2-Chloroethyl vinyletherCis-l,3-Dichloropropene4- Me thy 1-2 -pent anone1,1,2-Tr ich loroethaneTo lueneTrans-1 , 3-D ich loropropene2-Hexanone jtj

1.01.01.01.01.01.01.01.01.0.21.01.01.01.01.01.01.0.31.01.01.01.0.3

1.01.01.01.01.01.01.01.0.1

IR308WS

1IUIUIUIUIUIUIUIUIUIBIUIUIUIUIUIUIUIBIUIUIUIU1 JIUIUIUIUIUJIUIUIUIBIUIU1

U = UNDETECTED

1A-2 ERA SAMPLE NO.VOLATILE ORGAN ICS ANALYSIS DATA SHEET ______________

I !I NL-RW-12-01 I

Lab Name: EPA REGION III CRL Contract: LOCKHEED I______________I



Sample wt/vol: 25.0 (g/ml> ML Lab File ID: >B6134

Level: (low/med) LOW Date Received: 01x29/93

« Moisture: not dec. N/A Date Analyzed: 02/03/93



127-18-4142-28-9124-48-1106-93-4630-20-6108-90-7100-41-4100-42-5

95-47-675-25-298-82-8108-86-179-34-596-18-4103-65-195-49-8106-43-4108-67-898-06-695-63-6135-98-8541-73-1106-46-795-50-199-87-6104-51-896-12-8120-82-191-20-387-68-387-61-6

Tet rach loroethene1,3-Dich loropropaneDibromochl or ome thane1,2-Dibromoethane (EDB)1, lf 1,2-Tet rach lo roe thaneChlorobenzeneEthy IbenzeneStyrenem&p-Xy leneso-Xy leneBromoformI sop ropy IbenzeneBromobenzene1,1,2,2-Tetrach lo roe thane1,2,3-Tr ich loropropanen-Propy Ibenzene2-Ch loro to luene4-Ch loroto luene1,3 ,^-Tr i me thy I benzenete r t -But y Ibenzene1 ,2 ,4-Tr imethylbenzenesec-Butylbenzene1 , ?-0 ich lorobenzene1 ,4-Dich lorobenzene1 ,2-Di chlorobenzenep-Isopropyl to luenen-Buty Ibenzene1 ,2-Di bromo-3-ch loropropane1,2,4-Trich lorobenzeneNaphtha leneHexachlorobutadiene1 ,2 ,3-Tr ich lorobenzene

•

1.01.01.01.01.01.01.01.01.01.01.01.01.01.01.01.01.01.01.01.01.01.01.01.01.01.01.01.01.01.01.01.0

«- AR308b36*j i

1tuIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIU111

U - UNDETECTED

1ft ERA SAMPLEVOLATILE ORGAN ICS ANALYSIS DATA SHEET

I II NL-RU-01-01 I

Lab Name: EPA REGION III CRL Contract: LOCKHEED I ______ I

Lab Code: ESAT Case No.: NOVAK SAS No.: N/A SDG No.: N/A


Sample wt/vol: 25.0 (g/ml> ML Lab File ID: >BB131

Level: (low/mod) LOU Date Received: 01/29/93

J4 Moisture: not dec. N/A Date Analyzed: 02/03/93



75-71-874-87-375-01-0474-83-975-00-375-69-475-35-475-15-067-64-175-09-275-34-3156-60-5108-05-4594-20-7156-59-278-93-374-97-567-66-371-55-656-23-5563-58-671-43-2107-06-279-01-678-87-574-95-375-274110-75-810061-01-5108-10-179-00-5108-88-310061-02-6591-78-6

Dich lorodi f luorome thaneCh lorome thaneUinyl ChlorideBromome thaneChloroethaneTr ich lore f luorome thane1 , 1-DichloroetheneCarbon DisulfideAcetoneMethylene Chloride1,1-Di ChloroethaneTrans-l,2-DichloroetheneUinyl Acetate2 ,2-Dich loropropaneCis-l,2-Dichloroethene2-ButanoneBromoch lorome thaneCh loroform1,1,1-Tr i ChloroethaneCarbon Tetrachlor ide1 , 1-Dichloro-l-propeneBenzene1 ,2-Di ChloroethaneTr ichloroethene1,2 -Dich loropropaneDibromome thaneBromodich lorome thane2-Chloroethyl vinyl etherCi»-l,3-Dich loropropene4-Methy 1-2-pentanone1,1,2-TrichloroethaneTo lueneTrans-1 , 3-D ich loropropene

1.01.01.01.01.01.01.01.01.0.2

1.01.01.01.01.01.01.0.31.01.01.01.0.3

1.01.01.01.01.01.01.01.01.01.0

2-Hexanone £ A R 3 0 8 4 !} 7 l-°

1IUIUIUIUIUIUIUIUIUIBIUIUtuIUIUIUIUIBIUIUIUIU1 3IUIUIUIUIUJIUIUIUIUIUIU1

U = UNDETECTED

1ft-2 EPA SAMPLE NO.VOLATILE ORGAN ICS ANALYSIS DATA SHEET ______________

I II NL-RW-01-01 I



Matrix: (soil/water) UATER Lab Sample ID: 930129-02

Sample wt/vol: 25.0 <g/ml) ML Lab File ID: >BB131


K Moisture: not dec. N/A Date Analyzed: 02/03/93


CONCENTRATION UNITS:CAS NO. COMPOUND • (ug/L or ug/Kg) ug/L Q

127-18-4142-28-9124-48-1106-93-4630-20-6108-90-7100-41-4100-42-5

95-47-675-25-298-82-8108-86-179-34-596-18-4103-65-195-49-8106-43-4108-67-898-06-695-63-6135-98-8541-73-1106-46-795-50-199-87-6104-51-896-12-8120-82-191-20-387-68-387-61-6

.Tet rach lo roe thene1 ,3-DichloropropaneDibromoch loromethane1,2-Dibromoethane. (EDB)1,1,1 ,2 -Tet rach lo roe thaneCh lorobenzeneEthylbenzeneStyrenem&p-Xyleneso-XyleneBromoformI sop ropyl benzeneBromobenzene1,1,2 ,2- Tet rach IQ roe thane1,2,3-Trichloropropanen-P ropyl benzene2 -Ch loroto luene4-Ch loroto luene1,3,5-Tr ime thy 1 benzenetert-Buty 1 benzene1 ,2 ,4-Tr i methyl benzenesec-Butylbenzene1,3-Dich lorobenzene1 ,4-Dich lorobenzene1 ,2-Oich lorobenzenep-Isop ropyl to luenen-Butylbenzene1 ,2-Dibromo-3-chloropropane1,2, 4- Trich lorobenzeneNaphtha leneHexach lorobutad iene1,2,3-Tr ich lorobenzene

7

1.01.01.01.01.01.01.01.01.01.01.01.01.01.01.01.01.01.01.01.01.01.01.01.01.01.01.01.01.0.41.01.0

1IUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIBIUIU111

U - UNDETECTED

1M ERA SAMPLE NO.VOLATILE ORGANICS ANALYSIS DATA SHEET ______________

I II NL-RtJ-06-01 I


Lab Code: ESAT Case No.: NOUAk SAS No.: N/A SDG No.: N/A


Sample wt/vol: 25.0 (g/ml> ML Lab File ID: >B8132

Level: (low/med) LOU Date Received: 01/29/93

9i Moisture: not dec. N/A Date Analyzed: 02/03/93



75-71-874-87-375-01-0474-83-975-00-375-69-475-35-475-15-067-64-175-09-275-34-3156-60-5108-05-4594-20-7156-59-278-93-374-97-567-66-371-55-656-23-5563-58-671-43-2107-06-279-01-678-87-574-95-375-274110-75-810061-01-5108-10-179-00-5108-88-310061-02-6591-78-6

Dichlorodif luorome thaneChloromethaneUinyl ChlorideBromomathaneChloroethaneTrichlorof luorome thane1 ,1-DichloroetheneCarbon DisulfideAcetoneMethylene Chloride1,1-Di chloroethaneTrans-l,2-Dich loroetheneUinyl Acetate2 ,2-Dich loropropaneCis-1 ,2-Dich loroethene2-ButanoneBromochl or ome thaneChloroform1,1,1-Trichlo roe thaneCarbon Tet rachlor ide1 , 1-Dich loro-1-propeneBenzene1 ,2-Dich lo roe thaneTrich loroethene1,2-DichloropropaneDibromo me thaneBromod ich lorome thane2-Ch loroethy I vinyl etherCis-1, 3-D ich loroprop one4-Methyl-2-pentanone1,1,2-TrichloroethaneTo lueneTrans-l,3-Dichloropropene

1.91.01.01.01.0.81.01.01.0.2.9

1.01.01.0.6

1.01.01.0.5

1.01.01.0.3.3

1.01.01.01.01.01.01.01.01.0

2-Hexanone ^ AR30^39 1<0

11IUIUIUIU1 JIUIUIUIB1 JIUIUIU1 JIUIUIU1 JIUIUIU1 J1 JIUIUIUIUJIUIUIUIUIUIU1

U = UNDETECTED

1A-2 EPA SAMPLE NU.UOLATILE ORGAN1CS ANALYSIS DATA SHEEI _____________

I II NL-RW-06-01 I




Sample wt/vol: 25.0 (g/ml) ML Lab File ID: >BB132


5i Moisture: not dec. N/A Date Analyzed: 02/03/93



127-18-4142-28-9124-48-1106-93-4630-20-6108-90-7100-41-4100-42-5

95-47-675-25-298-82-8108-86-179-34-596-18-4103-65-195-49-8106-43-4108-67-898-06-695-63-6135-98-8541-73-1106-46-795-50-199-87-6104-51-896-12-8120-82-191-20-387-68-387-61-6

Tet rach loroethene1 ,3-DichloropropaneDibromochlorome thane1,2-Dibromoethane (EDB)1,1,1 ,2-Tet rach lo roe thaneCh lorobenzeneEthylbenzeneStyrenem&p-Xyleneso-XyleneBromoformI s op ropy 1 benzeneBromobenzene1, 1, 2, 2-Tet rach Joroe thane1,2,3-Trichloropropenen-Propylbenzene2-Chlorotoluene4-Ch loro toluene1 ,3 ,5-Tr ime thy 1 benzeneter t-Buty Ibenzene1,2 ,4-Tr i me thy Ibenzenesec-Buty Ibenzene1 ,3-Dich lorobenzene1 ,4-Dich lorobenzene1 ,2-Dich lorobenzenep-Isopropylto luenen-Buty Ibenzenel,2-Dibromo-3-chloropropane1,2,4-Trich lorobenzeneNaphtha leneHexachlorobutad iene1 ,2 ,3-Tr ich lorobenzene

•

7

.31.01.01.01.01.01.01.01.01.01.01.01.01.01.01.01.01.01.01.01.01.01.01.01.01.01.01.01.01.01.01.0

11 JIUIUIUIUIDIUIUIUIUIUIUIUIUIUIUIU(UIUIUIUIUIUIUIUIUtuIUIUIUIUIUI

BR308l»lt!0U = UNDETECTED

1A EPft SAMPLEVOLATILE ORGAN I CS ANALYSIS DATA SHEET

I II NL-RU-06-02 I

Lab Name: EPA REGION III CRL Contract: LOCKHEED I ______________ I


Matrix: (soil/water) UIATER Lab Sample ID: 930129-04

Sample wt/vol: 25.0 <g/ml) ML Lab File IO: >BB133


H Moisture: not dec. N/A Date Analyzed: 02/03/93


CONCENTRATION UNITS:CAS NO. COMPOUND (ug/L or ug/Kg ) ug/L Q

75-71-874-87-375-01-0474-83-975-00-375-69-475-35-475-15-067-64-175-09-275-34-3156-60-5108-05-4594-20-7156-59-278-93-374-97-567-66-371-55-656-23-5563-58-671-43-2107-06-279-01-678-87-574-95-375-274110-75-810061-01-5108-10-179-00-5108-88-310061-02-6591-78-6

Dichlorodi f luorome thaneChloromethaneUinyl ChlorideBromomethaneChloroethaneTr ich lorof luorome thane1,1-Dich loroetheneCarbon DisulfideAcetoneMethylene Chloride1 , 1-Dich lo roe thaneTrans-l,2-D ich loroetheneUinyl Acetate2,2-Dich loropropaneCi a- 1,2-D ich loroethene2-ButanoneBromoch lorome thaneCh loroform1 ,1 ,1-Tr i chloroethaneCarbon Tet rach lor ide1 , 1-Dichloro-l-propeneBenzene1 ,2-Di chloroethaneTrichloroethene1 ,2- D ich loropropaneDibromome thaneBromodich lorome thane2-Ch loroe thy 1 vinyl etherCis-l,3-Dich loropropene4-Methy 1-2-pentanone1,1,2-Tr ich loroe thaneTo lueneTrans-l,3-Dich loropropene2-Hexanone AR/308^^1

1&

2.01.01.01.01.0.8

1.01.01.0.2.9

1.01.01.0.5

1.01.01.0.5

1.01.01.0.4.31.01.01.01.01.01.01.01.01.01.0

11IUIUIUIU1 JIUIUIUIB1 JIUIUIU1 JIUIUIU1 JIUIUIU1 J1 JIUIUIUIUJIUIUIUIUIUIU1

II = UNDETECTED

1A-2 ERA SAMPLE NO.VOLATILE ORGANICS ANALYSIS DATA SHEET _____________

I II NL-RW-06-02 t

Lab Name: ERA REGION III CRL Contract: LOCKHEED I______________I



Sample wt/vol: 25.0 (g/ml) ML Lab File ID: >B8133

Level: (low/med) LOW Date Received: 01X29/93

K Moisture: not dec. N/A Date Analyzed: 02/03/93



127-18-4142-28-9124-48-1106-93-4630-20-6108-90-7100-41-4100-42-5

95-47-675-25-298-82-8108-86-179-34-596-18-4103-65-195-49-8106-43-4108-67-898-06-695-63-6135-98-8541-73-1106-46-795-50-199-87-6104-51-896-12-8120-82-191-20-387-68-387-61-6

Tet rech loroethene1 , 3-D ich loropropaneDibromoch lorome thane1,2-Dibromoethane (EDS)1,1,1 ,2-Tet rachloroe thaneChlorobenzeneEthylbenzeneStyrenem&p-Xy leneso-XyleneBromof ormI sop ropy IbenzeneBromobenzene1,1,2,2-Tetrachlp.roethane1 ,2 ,3-Tr ich loropropanen-Propyl benzene2-Chlorotoluene4-Chloroto luene1,3,5-Tr i me thy Ibenzenetert-Buty Ibenzene1,2 ,4- Tr i me thy Ibenzenesec-Buty Ibenzene1 ,3-Di chlorobenzene1,4- D ich lorobenzene1, 2- Dich lorobenzenep-Isop ropyl to luenen-Buty Ibenzenel,2-Dibromo-3-ch loropropane1, 2, 4- Tr ich lorobenzeneNaphthaleneHexachlorobutadiene1 ,2,3-Tr ich lorobenzene

.31.01.01.01.01.01.01.01.01.01.01.01.01.01.01.01.01.01.01.01.01.01.01.01.01.01.01.01.0.21.01.0

11 JIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIBuu

U - UNDETECTED

Itt EPA SAMPLE NO..VVOLATILE ORGANICS ANALYSIS DATA SHEET ______________.

I II TRP BLK I


Lab Code: ESAT Case No.: NOUAK SftS No.: N/A SDG No.: N/A



Level: (low/mod) LOW Date Received: 01/29/93

% Moisture: not dec. N/A Date Analyzed: 02/03/93


CONCENTRATION UNITS:CAS NO. COMPOUND Cug/L or ug/Kg) ug/L Q

75-71-874-87-375-01-0474-83-975-00-375-69-475-35-475-15-067-64-175-09-275-34-3156-60-5108-05-4594-20-7156-59-278-93-374-97-567-66-371-55-656-23-5563-58-671-43-2107-06-279-01-678-87-574-95-375-274110-75-810061-01-5108-10-179-00-5108-88-310061-02-6591-78-6

Dichlorodif luorome thaneChloromethaneUinyl ChlorideBromomethaneChloroethaneTrichlorof luorome thane1,1-DichloroetheneCarbon DisulfideAcetoneMethylene Chloride1 ,1-Dich lor oe thaneTrans-l,2-DichloroetheneUinyl Acetate2,2-DichloropropaneCis-1 ,2-Dichloroethene2-ButanoneBromoch loromethaneCh loroform1,1,1-Trich lo roe thaneCarbon Tetrachlor ide1 ,1-Dich loro-1-propeneBenzene1,2-DichloroethaneTrichloroethene1,2-DichloropropaneDibromomethaneBrornod ich loromethane2-Chloroethy IvinyletherCis-1 ,3-Dich loropropene4-Me thy I -2 -pen tan one1 , 1 ,2-Tr ich lo roe thaneTo lueneTrans-l,3-Dichloropropene

1.01.01.01.01.01.01.01.07.71.11.01.01.01.01.01.01.0

15.41.01.01.01.01.01.01.01.01.11.01.01.01.0.1

1.02-Hexanone ^ ft R 3 p 8 U 3 1'°

1IUIUIUIUIUIUIUIU1IBIUIUIUIUIUIUIU1IUIUIUIUIUIUIUIU1IUJmIUIUIBIUIU1

U - UNDETECTED

y 1A-2 ERA SAMPLE NO.UOLATILE ORGANICS ANALYSIS DATA SHEET ______________.

I iI TRP BLK I


Lab Code: ESAT — Ge.se No.: NOUAK SAS No.: N/A SDG No»: N/A


Sample wt/vol: 25.0 Cg/ml) ML Lab File ID: >BB130


5J Moisture: not dec. N/A Date Analyzed: 02/03/93


CONCENTRATION UNITS:CAS NO. . COMPOUND (ug/L or ug/Kg) ug/L Q

127-16-4142-28-9124-48-1106-93-4630-20-6108-90-7100-41-4100-42-5

95-47-675-25-298-82-8108-86-179-34-596-18-4103-65-195-49-8106-43-4108-67-898-06-695-63-6135-98-8541-73-1106-46-795-50-199-87-6104-51-896-12-8120-82-191-20-387-68-387-61-6

.Tet rachloroethene1,3-DichloropropaneDibromochlorome thane1,2-Dibromoethane (EDB)1,1,1 , 2-Tet rachlo roe thaneCh lorobenzeneEthy IbenzeneStyrenem&p-Xy leneso-Xy leneBromof ormI sop ropy IbenzeneBromobenzene1,1,2,2-Tetnach lo roe thane1,2,3-Tr ichloropropanen-Propy Ibenzene2-Ch lorotoluene4-Chloroto luene1,3,5-Tr i me thy Ibenzenetert-Buty Ibenzene1,2 ,4-Tr i me thy Ibenzenesec-Buty Ibenzene1 ,3-Dich lorobenzene1,4-Dich lorobenzene1,2-Dich lorobenzenep-Isopropyl to luene•n-Butyl benzene1 ,2-Dibromo-3-chloropropane1,2 ,4-Tr ich lorobenzeneNaphthaleneHexach lorobutad iene1,2,3-Tr ich lorobenzene

£ AR3

1.01.01.01.01.01.01.01.01.01.01.01.01.01.01.01.01.01.01.01.01.01.01.01.01.01.01.01.01.01.01.01.0

Q8l»lfU

1IUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIU111

U = UNDETECTED

Itt ERA SAMPLEVOLATILE ORGAN I CS ANALYSIS DATA SHEET

I II CRL LAB BLK !

Lab Name: ERA REGION III CRL Contract: LOCKHEED I ______________ I



Sample wt/vol: 25.0 <g/ml) ML Lab File ID: >B8129

Level: (low/mad) LOU Date Received: 02/03/93

H Moisture: not dec. N/A Date Analyzed: 02/03/93



75-71-874-87-375-01-0474-83-975-00-375-69-475-35-475-15-067-64-175-09-275-34-3156-60-5108-05-4594-20-7156-59-278-93-374-97-567-66-371-55-656-23-5563-58-671-43-2107-06-279-01-678-87-574-95-375-274110-75-810061-01-5108-10-179-00-5108-88-310061-02-6591-78-6

Dich lor odifluorome thaneChlorotna thaneUinyl ChlorideBromo methaneChloroethaneTr ichlorof luorome thane1,1-DichloroetheneCarbon DisulfideAcetoneMethylene Chloride1 , 1-Dich loroe thaneTrans-l,2-Dichlo root noneUinyl Acetate2,2- Dich loropropaneCis-1 ,2-Dichlo root none2-ButanoneBromoch loromethaneChloroform1,1, 1-Tr ich loroe thaneCarbon Tetrachlor ide1,1-Dichloro-l-propeneBenzene1,2-Di chloroethaneTr ichloroethene1 ,2 -Dich loropropaneDibromo me thaneBromo d ich loromethane2-Ch loroe thy I vinyl etherCis-l,3-Dichloropropene4- Me thy 1-2- pen tan one1,1,2-TrichloroethaneTo lueneTrans-l,3-Dich loropropene2-Hexanone ^ fl R 'J Q f]

1.01.01.01.01.01.01.01.01.02.41.01.01.01.01.01.01.01.01.01.01.01.01.01.01.01.01.01.01.01.01.0.1

1.01*1*5 i.o

1IUIUIUIUIUIUIUIUIUIJ-IUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUJIUIUIUIJ'IUIU1

I I

1A-2 ERA SAMPLE NO.VOLATILE ORGANICS ANALYSIS DATA SHEET _____________

I II CRL LAB BLK I

Lab Name: ERA REGION III CRL Contract: LOCKHEED I______________I


Matrix: (soil/water) UATER Lab Sample ID: 93U129-06

Sample wt/vol: 25.0 <g/ml) ML Lab File ID: >BB129


H Moisture: not dec. N/A Date Analyzed: 02/03/93•

Column:', (pack/cap) CAP Dilution Factor: 1.0

CONCENTRATION UNITS: 'CAS NO. COMPOUND Cug/L or ug/Kg) ug/L Q

127-18-4142-28-9124-48-1106-93-4630-20-6108-90-7100-41-4100-42-5

95-47-675-25-298-82-8108-86-179-34-596-18-4103-65-195-49-8106-43-4108-67-898-06-695-63-6135-98-8541-73-1106-46-795-50-199-87-6104-51-896-12-8120-82-191-20-387-68-387-61-6

Tet rach loroethene1,3-DichloropropeneDibromoch lorome thane1,2-Dibromoethane (EDB)1,1,1,2-TetrachloroethaneChlorobenzeneEthylbenzeneStyrenem&p-Xy leneso-XyleneBromof ormI a op ropy 1 benzeneBromobenzene1,1,2,2-Tetrachloroethene1 ,2 ,3-Tr ichloropropanen-Propyl benzene2-Chloro to luene4-Ch loroto luene1, 3, 5-Tri methyl benzenetert-Buty 1 benzene1,2 ,4- Tr i methyl benzenesee-But yl benzene1,3-Dich lorobenzene1,4-Dich lorobenzene1,2-Dich lorobenzenep-Isopropylto luenen-Butylbenzenel,2-Dibromo-3-chloropropane1,2,4-Trich lorobenzeneNaphtha leneHexach lorobu tad iene1, 2, 3-Trich lorobenzene

I5"

1.01.01.01.01.01.01.01.01.01.01.01.01.01.01.01.01.01.01.01.01.01.01.01.01.01.01.01.01.0.2

1.01.0

n ft f\ /***

1IUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIUIJIUIU

81*1*61U = UNDETECTED

UOLATILE ORGANICS ANALYSIS DATA SHEET SAMPLE I.D.TENTATIVELY IDENTIFIED COMPOUNDS ___________

I II NL-RU-12-01 I


Lab Code: ESAT Case No.: NOUAK SDG No.: N/A




S Dry Weight: N/A Ph: 2 Date Analyzed: 02/03/93Time Analyzed: 17:02


CONCENTRATION UNITS:Number of TICs found_0___ (ug/L or ug/Kg) ug/L

CAS NO.

——————————

——————————

——————————

——————————

COMPOUND IDENTIFICATION

NONE DETECTED

————————————————————————————————

————————————————————————————————

-

— ——— ——————————————————————— ———

————————— ——————————————————————

R.T. (min)

———————

———————

———————

__ _ _ _ _ _ _ _

IEST. CONC

—————— _

———————

AR308M7FORM I UOA-TIC

VOLATILE ORGANICS ANALYSIS DATA SHEET SAMPLE I.D.TENTATIVELY IDENTIFIED COMPOUNDS ______

I II NL-RU-01-01 I


Lab Code: ESAT Case No.: NOvAK SDG No.: N/A


Sample wt/vol: 25.0 (g/ml) ML Lab File ID: >B8131


% Dry Uleight: N/A Ph: 2 Date Analyzed: 02/03/93Time Analyzed: 14:21

Column: (pack/cap) CAP ' Dilution Factor: 1.0

CONCENTRATION UNITS:Number of TICs found_0___ (ug/L or ug/Kg) ug/L

I CAS NO.f

____________

f _ _ _ _ _ _ _ _ _ _ _ _1

COMPOUND IDENTIFICATION————————————————— . ——— _ _ _ _ _ _ _ _ _ _ _ _ _ _

NONE DETECTED

————————————————————————————————

———— _ ————— ——————— _ — ————— i ———

___ _ _ _ _ _ _ _ _ _ ___ __ __ „___ __

'

————————— — — — __ — ———— —————— ——

R.T. (min)——— ————

_________

_ _ _ _ _ _ _ _ _

EST. CONC

/? AR3Q8UU8FORM I UOA-TIC

VOLATILE ORGANICS ANALYSIS DATA SHEET SAMPLE I.D.TENTATIVELY IDENTIFIED COMPOUNDS ___________

I II NL-RU-06-01 I


Lab Code: ESAT Case No.: NOUAK SDQ No.: N/A



Level: (lou/med) LOUI Date Received: 01/29/93

% Dry Weight: N/A Ph: 2 Date Analyzed: 02/03/93Time Analyzed: 15:14


CONCENTRATION UNITS:Number of TICa found_0___ (ug/L or ug/Kg) ug/L

CAS NO.

— — _ — ————

——————————

_


NONE DETECTED

————— _ —————————————————————————

————————————— ,. —————————————————

———————— ———————————————————————

————————————————————————————————

—— —————————————————————————————

————————————————————————————————

————————————————————————————————

——— - —— ———————— —— —————————————

————————————————————————————————

_ — _ — _ ———— _ ————— —— _ ———— _ ———— —

IR.T. (min)

———————

———————

———————

———————

———————

EST. CONC

FORM , JL AR308HW

UOLATILE ORGAN ICS ANALYSIS DATA SHEET SAMPLE I.D.TENTATIVELY IDENTIFIED COMPOUNDS ___________

I II NL-RU-06-02 l


Lab Code: ESAT Case No.: NOUAK SDG No.: N/A



Level: (low/med) LOW Date Received: 01X29/93

X Dry Weight: N/A Ph: 2 Date Analyzed: 02/03/93Time Analyzed: 16:08


CONCENTRATION UNITS:Number of TICs found_0___ <ug/L or ug/Kg) ug/L

CAS NO.

— —— ——— ._ —

——————————

——————————

——————————•

——————————


NONE DETECTED——————————— . ———————————————————

————————————————————————————————

—— -. —————————————————————————————

-n -*, ww r, « .• »

R.T. (min)———————

EST. CONC

———————

———————

———————

———————

————— —

———————

AR308U50FORM I VOA-TIC

VOLATILE ORGAN ICS ANALYSIS DATA SHEET SAMPLE I.D.TENTATIVELY IDENTIFIED COMPOUNDS

L<

L(

M<

S<

Lc

%

C(

1 11 TRP BLK 1

ab Name: EPA REGION III CRL Contract: LOCKHEED 1 1

ab Code: ESAT Case No.: NOUAK SDG No.: N/A

atrix: (soil/water) LJATER Lab Sample ID: 930129-0?

ample wt/vol: 25.0 <g/ml> ML Lab File ID: >BB130

svel: (low/mod) LOU Date Received: 01/29/93

Dry Weight: N/A Ph: 2 Date Analyzed: 02/03/93Time Analyzed: 13:28

Dlurnn: (pack/cap) CAP Dilution Factor: 1.0

CONCENTRATION UNITS:Number of TICs found _ 0 ___ (ug/L or ug/Kg) ug/L

CAS NO.

——————————

——————————

——————————

—————— ———

—————— _ ———

— —— _______

___ ____

COMPOUND IDENTIFICATION————————————— _ _____________________

NONE DETECTED——————————————————— _ ——— ________

.

R.T. (min)

———————

———————

———————

_________

———————

EST. CONC_________

_________

V- •

^

AR308U5IFORM I UOA-TIC

WATER UOLATILE SURROGATE RECOVERY

Lab Name: ERA REGION III CRL Contract: LOCKHEED

Lab code: ESAT Case No.: NOUAK SAS No.: N/A SDG No.: N/A

1 ERA1 SAMPLE NO.I............

011930129-06021930129-05031930129-02041930129-03051930129-04061930129-0107I-01MS08I-01MSD09ILCS101111121131141151161171181191201211221231241251261271281291301

SI(DCE>*

1058598103108106107101101

S2(FLB)#

10210010099100101100102100

S3(TOD*

95106969785 A98969899

S4(BFB)ft

1029397105104102102100100

-

TOTOUT

000010000

QC LIMITSSI (DCE) - l,2-Dichloroethane-d4((76-114>£2 (FLB) »= Fluorobenzene(SURR) C8U-120)S3 (TOD - Toluene-d8(SURR) (88-110)S4 (BFB) - Bromof luorobenzene (SURC86-115 )

# Column to be used to flag recovery valuesA Quality control value is outside acceptance limitsREC: 1 out of 36 outside limits

P,9e_ ., _. HR308U52FORM II UOA-1 1/87 Rev

3AWATER VOLATILE MATRIX SPIKE/MATRIX SPIKE DUPLICATE RECOVERY

Lab Name: EPA REGION III CRL Contract: LOCKHEED

Lab code: ESAT Case No.: NOUAK SAS No.: N/A SDG No.: N/A

Matrix Spike - EPA Sample No.: 930129-01

COMPOUND

1,1-DichloroetheneBenzeneTrichloroetheneTo lueneCh lorobenzene

SPIKEADDED(ug/L)

1010101010

SAMPLECONCENTRATION

(ug/L)

000

0.10

MSCONCENTRATION

(ug/L)

9.710.010.29.89.9

MS 1 PCX {LIMITS

REC *l REC.

97 161-145100 175-130102 171-12097 176-12599 176-1"

1

COMPOUND

1,1-DichloroetheneBenzeneTrichloroetheneTo lueneCh lorobenzene

SPIKEADDED(ug/L)

1010105050

MSDCONCENTRATION

(ug/L)

9.29.89.79.69.7

1 MSD\REC *

9298979597

'

MEANHREC

94991009698

*RPD

52522

RPDQC

LIMITS

141114

. 1313

# column to be used to flag recovery and RPD values with an "A"

A - Quality control value is outside acceptance limits

RPD: 0 out of 5 outside limits

Spike Recovery: 0 out of 10 outside limits

COMMENTS:

FORM III UOA-1 1/B7 Rev.

11A ERA SAMPLE NO.UOLATILE ORGANICS LAB CONTROL SPIKE _____________

I II LCS 02/03/93 I


Lab Code: ESAT Case No.: NOUAK

Matrix: (soil/water) WATER Lab Sample ID: LCS

Sample vo 1: 25ML Units: UG/L Lab File ID: >B8137

Level: (low/med) LOW

Date Analyzed: 02/03/93

Column: (pack/cap) CAP Dilution Factor: 1.0LCS MEAS. X X Rec

COMPOUND SPIKE Cone Cone Rec QC LIMITS

1,1-DichloroetheneBenzeneTr ichloroetheneTo lueneChlorobenzene

1010101010

10.09.49.89.69.5

10094989695

61-14576-12771-12076-12575-130

A « Quality control value outside acceptance limits.Rec: 0 out of 5 Outside Limits.

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PYMAMACCORPORATIONEnvironmental Services

80 W. Lancaster AvenueDevon. PA 19333

Telephone: 215-989-9400Fax:215-989-9414

February 1, 1993

Ms. Linda VaughanUSEPA Region III CRL839 Bestgate RoadAnnapolis, Maryland 21401

SUBJECT: Memorandum To FileNovak Sanitary Landfill SiteOrafield, Lehigh County, Pennsylvania

•Dear Ms. Vaughan:

Please note the following sample designations for the duplicatesample and the trip blank sample which were not properly identifiedon the Chain of Custody. The samples were shipped with Chain ofCustody 3-13201, via Federal Express (Airbill # 6051034286) onJanuary 28, 1993.

Station No.RW-06

BL-01

Station LocationNL-RW-06-02

NL-BL-01

RemarksDuplicate ofNL-RW-06-01

Trip Blank

Dynamac apologizes for any inconvenience this may have caused.

Sincerely,

Michael HeffronProject Manager

cc: Annette Loge RSCCCarl Rodzewich, DynamacMichele Hayes, DynamacFile C03021, P025-C01

Corporate Headquarters: The Dynamac Building. 2275 Research Boulevard. Rockville, MD 20850-3268

erfo U

,$ J f *>Jv /7J

AR3081(S8

central regional laboratory · quant1 tation limit is estimated. ul * not detected. ouantitation...

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