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Larry W. Lake 1 Contributors: Anastasia Ilgen 2 , Hilary C. Olson 1 , Grant Heffelfinger 2 1 University of Texas at AusDn 2 Sandia NaDonal Laboratories July 2425 , 2017 Center for Frontiers of Subsurface Energy Security

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Page 1: Center for Frontiers of Subsurface Energy Security (Lake... · Multiphase Flow Theme: Experimentally tested invasion percolation modeling of buoyancy-driven flow - Sand pack 6 •

Larry  W.  Lake1  Contributors:  Anastasia  Ilgen2,  Hilary  C.  Olson1,  Grant  Heffelfinger2    

   1University  of  Texas  at  AusDn  2Sandia  NaDonal  Laboratories  

 July  24-­‐25  ,  2017  

Center for Frontiers of Subsurface Energy Security

Page 2: Center for Frontiers of Subsurface Energy Security (Lake... · Multiphase Flow Theme: Experimentally tested invasion percolation modeling of buoyancy-driven flow - Sand pack 6 •

EAB Steve  Bryant    

Michael  Carney  Charles  Christopher  

Don  DePaolo  Derek  Elsworth  ScoQ  Frailey  Kurt  House  Jean  Roberts  

THEME:    FLUID-­‐ASSISTED  GEOMECHANICS  

   

Ma@  Balhoff,  Tom  Dewers    

D.  N.  Espinoza,  B.  Ganis,  A.  Ilgen,    M.  MarDnez,  P.  Newell,  M.  Prodanovic,  M.  

Wheeler,  G.  Xu  ,  H.  Yoon,  N.  Hayman    

C.  Choens      

M.  Aman,  M.  Mirabolghasemi,  C.  Nwachukwu,      M.  Shafiei  ,  I.  Shovkun,  Z.  Sun,  H.  Yang  

         

Management  Team Larry  W.  Lake  –    Director  

Grant  Heffelfinger–  Associate  Director  Anastasia  Ilgen,  Hilary  Olson  –  Assistant  Directors  

AdministraNve  Associate  

Barb  Messmore  

THEME:    BUOYANCY-­‐    DRIVEN  MULTIPHASE  FLOW  

 

Tip  Meckel,  Mario  MarNnez      

B.  Cardenas,  D.  DiCarlo,  M.  Hesse,  S.  Hovorka,    K.  Johnston,  A.  Kucala,  T.  Larson,  C.  Yang,  H.  Yoon  

 L.  Trevisan,  L.  Wang,  B.  Wen  

 

D.  Akhbari,  S.  Alzobaidi,  C.  Da,  E.  GuilDnan,      P.  Krishnamurthy,  C.  McNeece,  S.  Senthinalthan  

 

 

CFSES Overview, Mission & Personnel Mission:  to  pursue  scienDfic  understanding  of  mulDscale,  mulDphysics  processes  to  ensure  safe  and  economically  feasible  storage  of  carbon  dioxide  and  other  byproducts  of  energy  producDon  without  harming  the  environment.  

www.utcfses.org    

The  University  of  Texas  at  AusNn  Sandia  NaNonal  Laboratories  

Page 3: Center for Frontiers of Subsurface Energy Security (Lake... · Multiphase Flow Theme: Experimentally tested invasion percolation modeling of buoyancy-driven flow - Sand pack 6 •

Challenge  1  

Challenge  2  

Challenge  3  

Sustaining  large  storage  rates  

Using  pore  space  with  unprecedented  

efficiency    

Controlling  undesired  or  unexpected  

behavior    

SAFE  &  ECONOMICAL  

Page 4: Center for Frontiers of Subsurface Energy Security (Lake... · Multiphase Flow Theme: Experimentally tested invasion percolation modeling of buoyancy-driven flow - Sand pack 6 •

CO2 Rock Mechanical Alteration: Strength and Stiffness of Outcrop Samples from the Crystal Geyser Analog

Espinoza  D.N,  Jung  H.,  Major,  J.R.,  Sun,  Z.,  Ramos,  M.J.,  Eichhubl,  P.,  Balhoff,  M.T.,  Choens,  R.C,  Dewers,  T.A.  Rock  Mechanical  AlteraDon  Due  to  Flow  of  CO2-­‐Charged  Brine:  Strength  and  SDffness  of  Outcrop  Samples  from  the  Crystal  Geyser  Analog.  In  review  –  IJGHG.    

Aman  M.,  Espinoza  D.N,  Ilgen  A.,  Major,  J.R.,  Eichhubl,  P.,  Dewers,  T.A.  CO2-­‐induced  Chemo-­‐Mechanical  AlteraDon  in  Reservoir  Rocks  assessed  via  Batch  ReacDon  Experiments  and  Scratch  TesDng.  In  review  –  GHG  Sci.  &  Tech.    

Scientific Achievement •  Proved  CO2-­‐induced  mechanical  degradaNon  over  geological  Nme  •  IdenNfied  and  reproduced  micromechanical  controls  of  CO2-­‐induced  degradaNon  in  sandstone  

Significance and Impact •  Mineral  dissoluNon  can  affect  in  situ  local  stresses  and  induce  reservoir  strains  

•  Increased  rock  ducNlity  because  of  dissoluNon  reduces  propensity  to  localized  fractures  and  ensuing  leaks  through  fractures  

 

Experimental  Results   Modeling  Results  Petrographic  Analysis  

Unaltered  (Strong  and  briQle)  

Altered  (Weak  and  ducDle)  

Page 5: Center for Frontiers of Subsurface Energy Security (Lake... · Multiphase Flow Theme: Experimentally tested invasion percolation modeling of buoyancy-driven flow - Sand pack 6 •

Multiphase Flow Theme: Experimentally tested invasion percolation modeling of buoyancy-driven flow - Sandstone

Scientific Achievement •Demonstration of buoyancy dominated CO2 flow under reservoir conditions. •Highlight strengths and weaknesses of each model. • Need for better small scale characterization of porous media. Significance and Impact • Post injection migration of CO2 will occur in buoyancy and capillary dominated flow regime. • Points out need to accurately model and predict CO2 movement and trapping in heterogeneous reservoirs.

 

Sandstone,  core-­‐scale  CO2  flood  experiments,  modeling  using  invasion  percolaDon  (IP)  and  

Darcy-­‐based  flow  models.    

Page 6: Center for Frontiers of Subsurface Energy Security (Lake... · Multiphase Flow Theme: Experimentally tested invasion percolation modeling of buoyancy-driven flow - Sand pack 6 •

Multiphase Flow Theme: Experimentally tested invasion percolation modeling of buoyancy-driven flow - Sand pack

6

•  Scientific Achievement •  • CO2 migration pathway show interplay between

capillary and gravity forces. •  • Impact on the non-wetting buoyancy depends

on knowledge of lithofacial hierarches.

•  Significance and Impact •  • Integrated benchmark approach of real-time

CO2 gas migration experiments and multiple numerical models (IP and Darcy-based continuum models) to quantify the transition from compact flow to capillary flow.

•  • Multiple fingers at the top can be represented by a stochastic approach of heterogeneity using computationally-efficient invasion percolation approaches.

Trevisan,  L.,  Yoon,  H.,  Krishnamurthy,  P.  G.,  Wang,  L.,  Kucala,  A.,  Chang,  K.  W.,  Meckel,  T.,  Cardenas,  B.,  DiCarlo,  MarDnez,  M.  J.  (in  prep),  Promises  and  piballs  of  invasion  percolaDon  and  Darcy-­‐based  models  applied  to  benchmark  flowcell  experiments  (100%  CFSES  supported,  fully  collaboraDve  work  between  SNL  and  UT)

(a)  Experimental  heterogeneous  sand  structure  (26  cm  wide)  of  Glass  et  al.  (2000)  [Dark-­‐fine,  gray-­‐medium,  and  light-­‐coarse  sands].  CO2  injecDon  port  is  shown  in  the  boQom.  (b)  Experimental  CO2  saturaDon  image  (0  to  1).  (c)  Entry  pressure  (kPa)  field  for  IP  models.  (d)  IP  result  (pore  filling)  in  one  realizaDon.  (e)  Probability  of  invasion  per  each  pixel  for  100  realizaDons.  (f)  CO2  saturaDon  based  on  Darcy-­‐based  conDnuum  model.    

Page 7: Center for Frontiers of Subsurface Energy Security (Lake... · Multiphase Flow Theme: Experimentally tested invasion percolation modeling of buoyancy-driven flow - Sand pack 6 •

New theoretical and experimental methods to understand CO2 permeability

Chen,  X.  and  D.A.  DiCarlo,  “A  new  unsteady-­‐state  method  of  determining  two-­‐phase  relaDve  permeability  illustrated  by  CO  2  -­‐brine  primary  drainage  in  Berea  sandstone,”  Advances  in  Water  Resources,  96,  251-­‐265  (2016)

Scientific Achievement Developed  a  method  for  obtaining  accurate  and  fast  measurements  of  high  pressure  CO2  relaNve  permeability.  

Significance and Impact RelaNve  permeability  important  for  predicNng  fate,  transport,  and  trapping  of  CO2  on  reservoir  scales.    

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A  new  unsteady-­‐state  method  for  obtaining  CO2  relaNve  permeability  

Pore-­‐scale  drainage  modeling  using  the  Conformal  DecomposiNon  Finite  Element  

Method  (CDFEM).    

SimulaNon  of  scCO2  (white)  drainage  in  brine  (blue)  at  Ca=1E-­‐5  in  random  2D  ladce  

network.  

Dynamic  angle  vs.  CL  velocity  

Scientific Achievement •  Developed  a  validated  numerical  dynamic  contact  angle  wedng  model.  

•  Model  used  to  simulate  pore  scale  drainage  in  heterogeneous  pore  networks  over  a  range  of  reservoir  we@ability  and  fluid  properNes.  

Noble,  Kucala  and    MarDnez,  M  “A  CDFEM  method  for  dynamic  welng  applicaDons,”    Proc.  ASME  FEDSM2017,  (2017).

Page 8: Center for Frontiers of Subsurface Energy Security (Lake... · Multiphase Flow Theme: Experimentally tested invasion percolation modeling of buoyancy-driven flow - Sand pack 6 •

Director’s  Review  of  Each  AcDvity  in  Year  2  •  Could  you  do  your  research  without  your  partner  insDtuDon?  •  What  does  failure  look  like?  •  What  does  success  look  like?  

IniDated  Awards  for  PublicaDons    •  Jan  2017  annual  meeDng  gave  out  awards  for  47  publicaDons  

•  Highlighted  Inter-­‐InsDtuDonal  PublicaDons  

Page 9: Center for Frontiers of Subsurface Energy Security (Lake... · Multiphase Flow Theme: Experimentally tested invasion percolation modeling of buoyancy-driven flow - Sand pack 6 •

CFSES Talks

9

Tip  Meckel   UT  Advances  in  Understanding  Buoyancy-­‐Dominated  Flow  in  Heterogeneous  Geologic  Systems  

Pania  Newell   SNL  Performance  Assessment  of  Jointed/Faulted  Caprock  During  CO2  SequestraDon  

MaQ  Balhoff   UT  Rock  Mechanical  AlteraDon  Due  to  Flow  of  CO2-­‐Charged  Brine:  Shear  Strength  of  Crystal  Geyser  Outcrop  Samples  

•  Leakage •  Wellbores •  Faults

•  Injection induced damage •  Brine migration to overlying

aquifers •  Induced seismicity

abandoned  well   fault  

caprock  caprock  joinDng  

Page 10: Center for Frontiers of Subsurface Energy Security (Lake... · Multiphase Flow Theme: Experimentally tested invasion percolation modeling of buoyancy-driven flow - Sand pack 6 •

CFSES Posters

10

abandoned  well   fault  

caprock  caprock  joinDng  

Choens,  Charles   SNL   The  Effect  of  Hydrous  SupercriDcal  Carbon  Dioxide  on  the  Mohr  Coulomb  Failure  Envelope  in  Boise  Sandstone  

Krishnamurthy,  Prasanna   UT   Engineered  Heterogeneity  in  Sand  Packs  for  EvaluaDng  CO2  SaturaDon  During  Buoyancy-­‐Driven  Flow  

MarDnez,  Mario   SNL   Fluid  Dynamics  Model  for  Pore-­‐Scale  Welng  Phenomena  Sun,  Zhuang   UT   P4-­‐Discrete  Element  Modeling  of  Rock  Mechanical  AlteraDon  Due  to  CO2-­‐

Charged  Brine  Wang,  Lichun   UT   Universal  Linear  Time-­‐Dependence  of  Permeability  Through  Dissolving  Fractures  

Induced  by  Acidic  Fluid