calcium chloride pellets/powder 95-98% fudix - · pdf filesafety data sheet calcium chloride...

SSAAFFEETTYY DDAATTAA SSHHEEEETT CCaallcc iiuumm cchhlloorr iiddee ppee ll lleettss//ppoowwddeerr 9955--9988%%

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Date issued: 10.08.2006

Date revised: 02.04.2014 Revision №: 2

SECTION 1. IDENTIFICATION OF THE SUBSTANCE / PREPARATION AND OF THE COMPANY / UNDERTAKING

1.1. Product identifier Calcium chloride pellets / powder 95-98% food grade

Trademark: Fudix TM

CHEMICAL NAME: calcium chloride, CaCl2 CAS №: 10043-52-4

EC №: 233-140-8 REACH registration number: 01-2119494219-28-0013

Index № CLP Annex VI Regulation (EC) No 1272/2008: 017-013-00-2

1.2. Relevant identified uses of the substance or mixture and uses advised against

Food industry uses: pH regulation in brewing industry. Fruits and vegetables processing and preservation. Meat tenderization and freezing point decreasing. Ice cream production. Jelly and jam production. Cheese and curd

production for speeding the process of coagulation.

1.3. Details of the supplier of the safety data sheet

MANUFACTURER: Zirax LLC ADDRESS: Microrayon 4, 6 Svetly Yar settlement, 404171 Volgograd region, RUSSIA

Telephone: +7 8442 494999 Fax: +7 8442 499444

e-mail: [email protected]

1.4. Emergency telephone number

+7 8442 49-49-99

SECTION 2. HAZARDS IDENTIFICATION

2.1. Classification of the substance or mixture According to Regulation (EC) No 1272/2008 of the European Parliament:

Hazard statement code: H319: Causes serious eye irritation Hazard Class and category code: Eye Irritation 2

According to Directive 67/548/EEC: Xi; R36 Irritating to eyes

2.2. Label elements

According to Regulation (EC) No 1272/2008

EEC HAZARD PICTOGRAM

GHS07: exclamation mark

SIGNAL WORD: Warning

HAZARD STATEMENT: H319: Causes serious eye irritation PRECAUTIONARY STATEMENTS:

P 264: Wash hands thoroughly after handling. P 280: Wear protective glasses with splash shields or safety goggles/shield.


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P305 + P351 + P338: IF IN EYES Rinse eyes cautiously with water for 15 minutes. Remove contact lenses, if

present and easy to do. Continue rinsing. P337 + P 313 If irritation continued get prompt qualified medical advice / attention.

2.3. Other hazards

Calcium chloride can cause minor skin irritation.

SECTION 3. COMPOSITION / INFORMATION ON INGREDIENTS

3.1. Substances

Component Name CAS Number EC №

Concentration w/w

Classification:

Regulation (EC) No 1272/2008

Calcium Chloride 10043-52-4 233-140-8 95-98% H319: Causes serious eye irritation

Eye Irritation 2 class

SECTION 4. FIRST AID MEASURES

4.1. Description of first aid measures

EYES: Remove contact lenses, if present and easy to do. Rinse cautiously with water for 15 minutes. Seek medical attention.

SKIN: Remove contaminated clothes; wash off any skin contaminations with soap and water. Launder contaminated clothes before re-use.

INGESTION: Get prompt qualified medical attention. If conscious, give 1-2 glasses of water with absorbent carbon.

INHALATION: Remove to fresh air. Keep in warm and at rest. Give oxygen or artificial aspiration if needed. If symptoms persist seek medical attention.

FIRST AID MEASURES: absorbent carbon, saline purge.

4.2. Most important symptoms and effects, both acute and delayed

EYES: Could cause irritant or burn effects to the eyes. SKIN: Could cause irritant effects to the skin. No delayed symptoms after washing contaminated skin.

INGESTION: May cause nausea. May cause GI tract irritation. INHALATION: Dust may cause irritation to mucous membranes and respiratory system.

4.3. Indication of any immediate medical attention and special treatment needed

No special antidotes. If case of ingestion wash mouth with water and give plenty water to drink. Get medical

attention if needed.

SECTION 5. FIRE FIGHTING MEASURES

5.1. Extinguishing media This product is a nonflammable substance. However, hazardous decomposition and combustion products may be

formed in a fire situation. Cool exposed containers with water spray to prevent overheating. Extinguish fire using

agent suitable for type of surrounding fire and/or chemicals. Do not use water directly on material. Heat is generated when product mixed with water.

5.2. Special hazards arising from the substance or mixture

No special hazards.

5.3. Advice for firefighters

Respiratory and eye protection are required for fire fighting personnel. Avoid breathing corrosive vapors.


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SECTION 6. ACCIDENTAL RELEASE MEASURES

6.1. Personal precautions, protective equipment and emergency procedures

Wearing the appropriate personnel protective equipment designated in Section 8, move the container to a containment area or rotate the container so that the opening is above the liquid level.

6.2. Environmental precautions

WATER SPILL: Use appropriate containment to avoid runoff or release to sewer or waterways.

LAND SPILL: Use appropriate containment to avoid runoff or release to ground.

6.3. Methods and material for containment and cleaning up Construct temporary dikes of dirt, sand, or any appropriate readily available material to prevent spreading of the

material. Wearing the appropriate personal protective equipment designated in Section 8, close or cap valves and/or block or plug hole in leaking container and transfer to another container. Remove containers with disposal

from release area.

6.4. Reference to other sections

For addition information see section 13.

SECTION 7. HANDLING AND STORAGE

7.1. Precautions for safe handling

Avoid skin and eye contact and breathing dusts. Use proper protective and respiratory equipment. Not to eat, drink and smoke in work areas. Wash hands thoroughly after handling. Launder contaminated clothing before re-use.

Ventilate area. Sweep or vacuum; do not create dust; place in a dry container for disposal. Clean spill area with water.

7.2. Conditions for safe storage, including any incompatibilities

Store in a cool, dry, well-ventilated place. Keep container closed when not in use. Keep away from incompatible

materials. Protect from atmospheric moisture.

7.3. Specific end use(s) No specific end uses.

SECTION 8. EXPOSURE CONTROLS/ PERSONAL PROTECTION

8.1. Control parameters National occupational exposure limit values: maximum allowable concentration in the air of the working zone – 2 mg/m, aerosol, 3 class of hazard 8.2. Exposure controls ENGINEERING CONTROLS: Where environmental controls are lacking or in enclosed spaces use a NIOSH/MSHA approved respirator for dust/fumes. Provide local exhaust ventilation system. Eye wash station and safety shower should be provided within the immediate work area for emergency use. EXPOSURE LIMITS: No occupational exposure limits established by OSHA/ACGIH/NIOSH. PERSONAL PROTECTIVE EQUIPMENT: EYES: Wear safety glasses with splash shields or safety goggles/shield. BODY: Wear appropriate protective (impervious) clothing. Leather work boots and/or leather products will dehydrate with resultant shrinkage and possible destruction. RESPIRATORY: A respirator is not indicated under normal operating conditions. Use of a NIOSH approved respirator should be based upon the presence of nuisance dust. When warranted, use a face mask particulate respirator with particulate respirator with a NIOSH N95 rating. HANDS AND FEET: Wear appropriate rubber gloves and non-leather protective boots. WORK HYGIENIC PRACTICES: Use reasonable care in handling this product. Wash hands after use and before eating.


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SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

9.1. Information on basic physical and chemical properties

(a) Appearance: White pellets / powder

(b) Odour: Odourless (c) Odour threshold: Not applicable

(d) pH: Neutral or slightly alkaline (e) Melting point/freezing point: 772oC (1,422 Fº)

(f) Initial boiling point and boiling range; >1627°C (g) Flash point: Not applicable

(h) Evaporation rate: Not applicable

(i) Flammability (solid, gas): Not Flammable (j) Upper/lower flammability or explosive limits: Not applicable

(k) Vapour pressure: Not applicable (l) Vapour density: Not applicable

(m) Relative density: Min 700 kg/m3 (50 lb/ft³)

(n) Solubility(ies): Soluble in alcohol, acetic acid and acetone (o) Partition coefficient: n-octanol/water: inorganic substance, not applicable

(p) Auto-ignition temperature: Not applicable (q) Decomposition temperature: Not applicable

(r) Viscosity: Not applicable for a solid product (s) Explosive properties: the substance is non-explosive

(t) Oxidising properties: the substance is non-explosive

9.2. Other information

MOLECULAR WEGHT: 111

SECTION 10. STABILITY AND REACTIVITY

10.1. Reactivity Reacts exothermically with water, acids and alkali.

10.2. Chemical stability

Product is stable under normal / recommended storage and handling conditions.

10.3. Possibility of hazardous reactions

Will not occur.

10.4. Conditions to avoid

To avoid contact of material with incompatible materials.

10.5. Incompatible materials Incompatible with organic materials, acids, alkali, non- ferrous and ferrous metals.

10.6. Hazardous decomposition products

Does not occur under normal temperatures and pressures.

SECTION 11. TOXICOLOGICAL INFORMATION

11.1. Information on toxicological effects Acute toxicity of product is low. The value of DL 50 mg/kg study with animals:

1000-4000 oral, rat 1940 oral, mouse

1384 oral, rabbit

LOCAL EFFECTS: Eye, mucous membrane and skin irritant.


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HEALTH EFFECTS: Moderately toxic by ingestion, slightly toxic by dermal absorption.

CARCINOGENICITY: Not Listed by NTP. Not listed by IARC. Not listed by OSHA.

MUTAGENICITY: Not Available

REPRODUCTIVE TOXICITY REPRODUCTIVE EFFECTS: testing does not appear necessary as calcium chloride will not reach the foetus or the

male and female reproductive organs when exposed orally, dermally orby inhalation, as it does not become

available systemically. TERATOGENIC EFFECTS: Not Available

SENSITIZATION: Not Available

SECTION 12. ECOLOGICAL INFORMATION

12.1. Toxicity

Calcium chloride is not classified as hazardous for the environment. Calcium and chloride are normally occurring ions that don’t have long term negative effect.

Overview of short-term effects on fish

Method Results Remarks Reference

Pimephales promelas freshwater

static

Method: other: EPA/600/4-90/027, EPA/600/6-91/003

LC50 (96 h): 4630 mg/L LC50 (48 h): > 6560 mg/L

LC50 (24 h): > 6660 mg/L

2 (reliable with restrictions) key study

experimental result

Test material (EC name): calcium chloride

Mount, D.R., Gulley, D.D., Hockett, J.R.,

Garrison, T.D. and

Evans, J.M. (1997a)

Lepomis macrochirus freshwater static

Method: other: Doudroff et al., (1951)

(96 h): 9500 — 11300 mg/L 2 (reliable with restrictions)

supporting study experimental result


Cairns, J., Jr. and

Scheier, A. (1959)

Lepomis macrochirus freshwater

static Method: other

LC50 (96 h): 10650 mg/L 2 (reliable with restrictions)

supporting study


Trama, F.B. (1954)

Gambusia affinis freshwater static

Method: other: not mentioned

LC50 (96 h): 13400 mg/L 2 (reliable with restrictions)



Wallen, I.E., Greer,

W.C. and Lasater, R. (1957)

Overview of short-term effects on aquatic invertebrates


Daphnia magna freshwater

static

OECD Guideline 202 (Daphnia sp. Acute Immobilisation Test)

LC50 (48 h): 2400 mg/L based on: mobility

1 (reliable without restriction)

key study

experimental result Test material (EC name):

calcium chloride

de Groot, W.A. and Groeneveld, A.H.C.

(1998)

Ceriodaphnia dubia freshwater

static Method: other: EPA/600/4-

90/027, EPA/600/6-91/003

LC50 (48 h): 1830 mg/L based on: mobility

2 (reliable with restrictions) supporting study


calcium chloride

Mount, D.R., Gulley, D.D., Hockett, J.R.,

Garrison, T.D. and Evans, J.M. (1997b)

other aquatic worm: Tubifex EC50 (96 h): 780 mg/L 2 (reliable with restrictions) Khangarot, B.S.


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tubifex

freshwater semi-static

Method: other

based on: mobility

EC50 (48 h): 1830 mg/L based on: mobility

EC50 (24 h): 2260 mg/L based on: mobility

supporting study


calcium chloride

(1991)

other aquatic crustacea: Cyclops abyssorum prealpinus freshwater static


LC50 (48 h): 19400 mg/L

based on: mortality

2 (reliable with restrictions)

supporting study


calcium chloride

Baudouin, M.F. and

Scoppa, P. (1974a)

other aquatic crustacea: Eudiaptomus padanus padanus freshwater static


LC50 (48 h): 11100 mg/L based on: mortality



calcium chloride

Baudouin, M.F. and Scoppa, P. (1974b)

other aquatic crustacea: Daphnia hyalina

freshwater

static Method: other: not mentioned



experimental result


Baudouin, M.F. and Scoppa, P. (1974a)

Caenorhabditis elegans freshwater static

Method: other

LC50 (24 h): 44400 mg/L

based on: mortality




Tatara, C.P.,

Newman, M.C., McCloskey, J.T. and

Williams, P.L. (1997)

other aquatic crustacea: Nitocra spinipes freshwater static


LC50 (96 h): 1600 mg/L

based on: mortality


supporting study


calcium chloride

Bengtsson, B.-E.

(1978)

Daphnia magna freshwater

static Method: other: not mentioned




calcium chloride

Biesinger, K.E. and Christensen, G.M.

(1972)

Daphnia magna

static Method: other: EPA/600/4-

90/027, EPA/600/6-91/003

LC50 (48 h): 2770 mg/L

based on: mobility




Mount, D.R., Gulley,

D.D., Hockett, J.R., Garrison, T.D. and

Evans, J.M.

Daphnia magna

static Method: other

(48 h): 1062 mg/L based

on: mobility



Test material (EC name):

calcium chloride

Khangarot, B.S. and

Ray, P.K. (1989)

Overview of long-term effects on aquatic invertebrates


Daphnia magna Method: other: not mentioned

EC50 (21 d): 610 mg/L based on: reproductive

impairment

EC16 (21 d): 320 mg/L

2 (reliable with restrictions) key study

experimental result

Test material (EC name):

Biesinger, K.E. and Christensen, G.M.

(1972)


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based on: reproductive

impairment LC50 (21 d): 920 mg/L

based on: mortality

calcium chloride

Overview of effects on algae and aquatic plants


Selenastrum capricornutum (new name: Pseudokirchneriella subcapitata) (algae)

OECD Guideline 201 (Alga, Growth Inhibition Test)

EC50 (72 h): 2900 mg/L based on: biomass

EC50 (72 h): > 4000 mg/L

based on: growth rate EC50 (72 h): 27000 mg/L

based on: growth rate EC20 (72 h): 1000 mg/L

based on: biomass

1 (reliable without restriction)

key study


calcium chloride

de Groot, W.A. (1998)

12.2. Persistence and degradability Test not available as product is inorganic.

12.3. Bioaccumulative potential Product is not biodegrade or accumulate.

12.4. Mobility in soil

In accordance with REACH Annex XI, the study does not need to be conducted as in water; calcium chloride is

dissociated into calcium and chloride ions and chloride ions will not adsorb on particulate matter. The calcium ion may bind to particulate matter or may form stable inorganic salts with sulphate and carbonate ions, but calcium is

naturally present in soil. Therefore, exposure of the soil compartment is unlikely.

12.5. Results of PBT and vPvB assessment According to Annex XIII of the REACH Regulation 1907/2006/EC inorganic substances do not need to be subjected

to a PBT assessment.

12.6. Other adverse effects

None identified.

SECTION 13. DISPOSAL CONSIDERATIONS

13.1. Waste treatment methods

Observe federal, state, and local regulations when disposing of this substance. DISPOSAL METHOD: Dispose of waste at an appropriate waste disposal facility according to current applicable

laws and regulations. FOR LARGE SPILLS: Contain material according to section 6.

PRODUCT DISPOSAL: Dispose of at a supervised incineration facility or an appropriate waste disposal facility

according to current applicable laws and regulations and product characteristics at time of disposal. EMPTY CONTAINER: Rinse drums with a suitable solvent and steam to remove vapors before disposal or reuse in

accordance with applicable regulations

SECTION 14. TRANSPORT INFORMATION

14.1. UN number Not applicable

14.2. UN proper shipping name Not regulated

14.3. Transport hazard class(es) Not applicable


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14.4. Packing group Not applicable

14.5. Environmental hazards Not applicable

14.6. Special precautions for user Not applicable

14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable

SECTION 15. REGULATORY INFORMATION

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture General principles of protection EH 44

15.2. Chemical safety assessment

A chemical safety assessment has been performed for calcium chloride according to REACH.

SECTION 16. OTHER INFORMATION

To the best of our knowledge, this Safety Data Sheet conforms to the requirements of:

- Regulation (EC) №1907/2006 of the European Parliament and of the Council of 18 December 2006 - Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008

- Commission Regulation (RU) №453/2010 of 20.05.2010

List of relevant R phrases, hazard statement, safety phrases and precautionary statement:

According to Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008: HAZARD STATEMENT: H319: Causes serious eye irritation PRECAUTIONARY STATEMENTS:

P 264: Wash hands thoroughly after handling.

P 280: Wear protective glasses with splash shields or safety goggles/shield. P305 + P351 + P338: IF IN EYES Rinse eyes cautiously with water for 15 minutes. Remove contact lenses, if

present and easy to do. Continue rinsing. P337 + P 313 If irritation continued get prompt qualified medical advice / attention.

According to Directive 67/548/EEC: Xi Irritant

R36 Irritating to eyes

S-phrases:

(S2) - keep out of the reach of children S22 - do not breathe dust

S24 - avoid contact with skin

Individuals handling this product should be informed of the recommended safety precautions and should have access to this information. It is the users' responsibility to satisfy themselves as to the suitability and completeness

of such information for their own particular use. We do not accept liability for any loss or damage that may occur

from the use of this information nor do we offer warranty against patent infringement. ZIRAX LLC reserves the right to refuse shipment of this product to any customer who fails to demonstrate the

ability to consistently handle and use it safely and in compliance with all applicable laws, rules and regulations. Such demonstration may require on-site inspection of any or all storage, processing, packaging and other handling

systems that come in contact with it.


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ANNEX 1

The overview of exposure scenarios of Calcium Chloride

Short description of

Identified Use

Product Category

(PC)

Life Cycle Stage(s) covered by the

IU

Sector of use

(SU)

Process Category

(Proc)

Article Category

(AC)

Environmental

Release

Category (ERC)

Ma

nu

factu

re

Fo

rmu

lati

on

End Use

Se

rvic

e

Lif

e

(fo

r

art

icle

)

Ind

ustr

ial

Pro

fessio

na

l

Co

nsu

me

r

ES1: Production of

calcium chloride

Not applicable X SU8 (SU3) PROC1, PROC2, PROC3,

PROC4, PROC6, PROC8a,

PROC8b, PROC9, PROC15, PROC26

Not

applicable

ERC1

ES2: Use of calcium

chloride as chemical intermediate

Not applicable X SU8, SU9, SU14

(SU1, SU3, SU4, SU5, SU6b)

PROC1, PROC2, PROC3,

PROC4, PROC6, PROC8a, PROC8b, PROC9,

PROC15, PROC22a, PROC22b, PROC22c,

PROC23a, PROC23b, PROC23c, PROC261,

PROC27a2, PROC27b3

Not

applicable

ERC6a

1 No specific assessment has been performed with ECTOC TRA for this PROC, but activities for PROC 26 (handling of solid inorganic substances at abient temperature) are covered within this scenario. 2 No specific assessment has been performed with ECTOC TRA for this PROC, but activities for PROC27a (Production of metal powders (hot processes)) are covered within this scenario by PROC22 and PROC23. 3 No specific assessment has been performed with ECTOC TRA for this PROC, but activities for PROC 27b (Production of metal powders (wet processes)) are covered within this scenario.


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Short description of Identified Use

Product

Category

(PC)

Life Cycle Stage(s) covered by the IU

Sector of use (SU)

Process Category (Proc)

Article

Category

(AC)

Environmental

Release Category

(ERC)

Ma

nu

factu

re

Fo

rmu

lati

on

End Use

Se

rvic

e

Lif

e

(fo

r

art

icle

)

Ind

ustr

ial

Pro

fessio

na

l

Co

nsu

me

r

ES3: Formulation and/or

distribution of Calcium Chloride

Not applicable X SU19 (SU1,

SU2a, SU2b,SU3, SU4,

SU5, SU6b, SU8, SU11, SU12,

SU13, SU14,

SU15, SU19, SU20, SU0-

C23.5/ C23.6)


PROC5, PROC6, PROC8a,


PROC261, PROC27a2,

PROC27b3

Not

applicable

ERC2

ES4: Use of calcium chloride as processing aid

Not applicable X

SU3 (SU1, SU2a, SU2b, SU4, SU5,

SU6b, SU8, SU9, SU10, SU11,

SU12, SU13, SU14, SU15,

SU16, SU17)

PROC1, PROC2, PROC3, PROC4, PROC6, PROC7,

PROC8a, PROC8b, PROC9, PROC10,

PROC13, PROC15, PROC22a, PROC22b,

PROC22c, PROC23a,

PROC23b, PROC23c, PROC261, PROC27a2,

PROC27b3

Not applicable

ERC4

ES5: Industrial outdoor use of calcium chloride-

end use

Not applicable X SU3(SU1, SU2a, SU2b)

PROC1, PROC2, PROC5, PROC7, PROC8a,

PROC8b,

Not applicable

ERC4


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Product

Category

(PC)


Sector of use (SU)


Article

Category

(AC)

Environmental

Release Category

(ERC)

Ma

nu

factu

re

Fo

rmu

lati

on

End Use

Se

rvic

e

Lif

e

(fo

r

art

icle

)

Ind

ustr

ial

Pro

fessio

na

l

Co

nsu

me

r

PROC9, PROC13,

PROC19, PROC261,

ES6: Professional indoor

use of calcium chloride

Not applicable X SU22 (SU1,

SU10, SU19, SU20, SU0-

C23.5/ C23.6)


PROC4, PROC5, PROC8a, PROC8b, PROC9

PROC10, PROC11, PROC15, PROC19,

PROC20, PROC261,

Not

applicable

ERC8a,

ERC8d

ES7: Professional outdoor use of calcium chloride

Not applicable X SU22 (SU1, SU5, SU10, SU13,

SU19, SU20, SU0- C23.5/

C23.6)

PROC1, PROC2, PROC5, PROC8a, PROC8b,

PROC9, PROC10 PROC11, PROC13,

PROC19, PROC20

PROC261

Not applicable

ERC8d

ES8: Handling of

(aqueous) calcium

chloride

X X SU3,SU22 (SU1,

SU2a,SU4,SU5,S

U6b,SU8,SU9, SU10,

SU11,SU12,SU13, SU14,SU15

SU19, SU20,



PROC7, PROC8a, PROC8b, PROC9,


PROC15

Not

applicable

ERC1, ERC6a,

ERC2, ERC4,

ERC8a, ERC8d


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Product

Category

(PC)


Sector of use (SU)


Article

Category

(AC)

Environmental

Release Category

(ERC)

Ma

nu

factu

re

Fo

rmu

lati

on

End Use

Se

rvic

e

Lif

e

(fo

r

art

icle

)

Ind

ustr

ial

Pro

fessio

na

l

Co

nsu

me

r

SU0- C23.5/

C23.6)

ES9: Handling of calcium

chloride with low

dustiness

X X SU3,SU22 (SU1,

SU2a,SU4,SU5,S

U6b,SU8,SU9, SU10,

SU11,SU12,SU13, SU14,SU15

SU19, SU20,

SU0- C23.5/ C23.6)



PROC7, PROC8a, PROC8b, PROC9,


PROC15, PROC22a,

PROC22b, PROC22c, PROC23a, PROC23b,

PROC23c

Not

applicable

ERC1, ERC6a,

ERC2, ERC4,

ERC8a, ERC8d

ES10: Use of calcium

chloride by consumers

PC2, PC5,

PC35, PC37,

PC4, PC12, PC 27,PC16, PC0-

UCN code K35100

X SU21 Not applicable Not

applicable

ERC8a,

ERC8d


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9.1. Production of calcium chloride

9.1.1. Exposure scenario – Production (ES1)

Section 1 Exposure Scenario Title

Title Production of calcium chloride; CAS: 10043-52-4

Use Descriptor Sector of Use: Industrial SU8, (SU3)

Process Categories: PROC1, PROC2, PROC3, PROC4, PROC6,

PROC8a, PROC8b, PROC9, PROC15,PROC26

Environmental Release Categories: ERC1

Processes, tasks,

activities covered

Manufacturing of Calcium Chloride, includes recycling/ recovery,

material transfers, storage, maintenance and loading (including marine vessel/barge, road/rail car and bulk container), sampling and

associated laboratory activities.

Section 2 Operational conditions and risk management measures

Field for additional statements to explain scenario if required.

Section 2.1 Control of worker exposure

Product characteristics

Physical form of

product

Solid, medium dustiness [OC2]

Concentration of

substance in product

Covers percentage substance in the product up to 100 % (unless

stated differently) [G13].

Amounts used Not applicable

Frequency and duration of use

Covers daily exposures up to 8 hours (unless stated differently) [G2]

Human factors not

influenced by risk management

Not applicable

Other Operational Conditions affecting

worker exposure

Assumes use at not more than 20°C above ambient temperature, unless stated differently [G15].;

Assumes a good basic standard of occupational hygiene is

implemented [G1].

Contributing Scenarios

Risk Management Measures Note: list RMM standard phrases according to the control hierarchy indicated in the ECHA template: 1. Technical measures to prevent release, 2. Technical measures to prevent dispersion, 3. Organisational measures, 4. Personal protection.

Justification

General measures

(irritants) [G19].

Avoid all skin contact with product, clean up contamination/spills as

soon as they occur. Wear gloves (tested to EN374) if hand contamination likely, wash off any skin contamination immediately.

Provide basic employee training to prevent / minimise exposures and

to report any skin problems that may develop [E3].Use suitable eye protection [PPE26].

General exposures

[CS1]. With sample collection [CS56].

Provide a good standard of general ventilation. Natural ventilation is

from doors, windows etc. Controlled ventilation means air is supplied or removed by a powered fan. [E1].

measured

data, see 9.1.2 (PROC1)

General exposures [CS1]. Continuous

process [CS54]. ;

Provide a good standard of general ventilation. Natural ventilation is from doors, windows etc. Controlled ventilation means air is supplied

or removed by a powered fan. [E1].

measured data, see 9.1.2

(PROC2)


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With sample

collection [CS56].

General exposures

[CS1]. Use in

contained batch processes [CS37].


from doors, windows etc. Controlled ventilation means air is supplied


measured


General exposures (open systems)

[CS16].

Batch process [CS55]. With

sample collection [CS56]. ;

Filling / preparation

of equipment from drums or

containers. [CS45].




(PROC4)

Calendering

(including

Banburys) [CS64]




measured

data, see

9.1.2.(PROC6)

Process sampling

[CS2]. Dedicated

facility [CS81]




measured

data, see 9.1.2

(PROC8b)

Process sampling

[CS2]. Non-dedicated facility

[CS82]


from doors, windows etc. Controlled ventilation means air is supplied or removed by a powered fan. [E1].


(PROC8a)

Drum/batch transfers [CS8].

Transport [CS58].




(PROC9)

Laboratory activities [CS36].




(PROC15)

bulk open loading and unloading

[CS503]Non-dedicated facility

[CS82]


or removed by a powered fan. [E1]. measured data, see 9.1.2

(PROC8a)

bulk closed loading and unloading

[CS501]Dedicated facility [CS81]



measured

data, see 9.1.2 (PROC8b)

Equipment cleaning

and maintenance [CS39]. Non-

dedicated facility

[CS82]


from doors, windows etc. Controlled ventilation means air is supplied or removed by a powered fan. [E1]. measured

data, see 9.1.2

(PROC8a)

Storage

[CS67].General

exposures (closed systems) [CS15].




measured


Storage [CS67].With sample

collection [CS56].




(PROC2)


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9.2. Use of calcium chloride as chemical intermediate

9.2.1. Exposure scenario – Use as an intermediate (ES2)


Title Use of Calcium Chloride as chemical intermediate; CAS: 10043-52-4

Use Descriptor Sector of Use: Industrial SU8, SU9, SU14 (SU1, SU3, SU4, SU5,

SU6b)

Process Categories: PROC1, PROC2, PROC3, PROC4, PROC6,

PROC8a, PROC8b, PROC9, PROC15, PROC22a, PROC22b, PROC22c, PROC23a, PROC23b, PROC23c

Environmental Release Categories: ERC 6a

Processes, tasks, activities covered Use of Calcium Chloride as chemical intermediate. Use as an intermediate. Includes recycling/ recovery, material transfers,

storage, maintenance and loading (including marine vessel/barge,

road/rail car and bulk container), sampling and associated laboratory activities.





Physical form of product Solid, medium dustiness [OC2]

Concentration of substance in product Covers percentage substance in the product up to 100 % (unless stated differently) [G13].


Frequency and duration of use Covers daily exposures up to 8 hours (unless stated differently)

[G2]

Human factors not influenced by risk

management

Not applicable


worker exposure Assumes use at not more than 20°C above ambient temperature,

unless stated differently [G15].; Assumes a good basic standard of occupational hygiene is

implemented [G1].

Contributing Scenarios Risk Management Measures Note: list RMM standard phrases according to the control hierarchy indicated in the ECHA template: 1. Technical measures to prevent release, 2. Technical measures to prevent dispersion, 3. Organisational measures , 4. Personal protection.

General measures (irritants) [G19]. Avoid all skin contact with product, clean up contamination/spills as

soon as they occur. Wear gloves (tested to EN374) if hand

contamination likely, wash off any skin contamination immediately. Provide basic employee training to prevent / minimise exposures

and to report any skin problems that may develop [E3].Use suitable eye protection [PPE26].

General exposures [CS1]. With sample collection [CS56].

No specific measures identified [EI18].

General exposures [CS1].

Continuous process [CS54]. With sample collection [CS56].



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Use in contained batch processes [CS37].



[CS16]. Batch process [CS55].

With sample collection [CS56]. Filling / preparation of equipment from

drums or containers. [CS45].

Provide a good standard of general ventilation (not less than 3 to 5

air changes per hour) [E11], or: Wear a respirator conforming to EN140 with Type A/P2 filter or

better [PPE29]

Calendering (including Banburys) [CS64] Provide a good standard of general ventilation (not less than 3 to 5 air changes per hour) [E11], or:

Wear a respirator conforming to EN140 with Type A/P2 filter or better [PPE29]

Process sampling [CS2]. Dedicated

facility [CS81]


air changes per hour) [E11], or: Wear a respirator conforming to EN140 with Type A/P2 filter or

better [PPE29]

Process sampling [CS2]. Non-dedicated facility [CS82].

Avoid carrying out operation for more than 1 hour [OC11]


Transport [CS58].


air changes per hour) [E11., or: Wear a respirator conforming to EN140 with Type A/P2 filter or

better [PPE29]

Laboratory activities [CS36]. No specific measures identified [EI18].

Bulk open loading and unloading [CS503].

Non-dedicated facility [CS82]

Provide a good standard of general ventilation (not less than 3 to 5 air changes per hour) [E11], or:


bulk closed loading and unloading

[CS501]Dedicated facility [CS81]


air changes per hour) [E11]., or: Wear a respirator conforming to EN140 with Type A/P2 filter or better [PPE29]

Equipment cleaning and maintenance

[CS39]. Non-dedicated facility [CS82].

Drain or remove substance from equipment prior to break-in or

maintenance [E81], or: Wear a respirator conforming to EN140 with Type A/P2 filter or

better [PPE29]

General exposures (closed systems) [CS15]. Elevated temperature [CS111].

Process temperature ≤ melting point Calcium Chloride


General exposures (closed systems)

[CS15]. Elevated temperature [CS111]. Process temperature > melting point

Calcium Chloride

Provide extract ventilation to points where emissions occur [E54],

or: Wear a respirator conforming to EN140 with Type A/P2 filter or

better [PPE29]

Material transfers [CS3]. (open systems) [CS108].

Batch processes at elevated temperatures [CS136].

Process temperature ≤ melting point

Calcium Chloride


Material transfers [CS3].

(open systems) [CS108].


Process temperature > melting point Calcium Chloride

Provide a good standard of controlled ventilation (10 to 15 air

changes per hour) [E40]., or:



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Storage [CS67].

General exposures (closed systems) [CS15].


Storage [CS67].

With sample collection [CS56].


9.3. Formulation and/or distribution of calcium chloride

9.3.1. Exposure scenario – Formulation and/or distribution (ES3)


Title Formulation and/or distribution of Calcium Chloride; CAS:

10043-52-4

Use Descriptor Sector of Use: Industrial SU10 (SU1, SU2, SU3, SU4, SU5, SU6b, SU8,

SU11, SU12, SU13, SU14, SU15, SU19, SU20, SU0- C23.5/ C23.6)

Process Categories: PROC1, PROC2, PROC3, PROC5, PROC 6, PROC8a, PROC8b, PROC9, PROC14, PROC15


Processes, tasks, activities covered Formulation and distribution , packing and re-packing (including drums and small packs) of the Calcium Chloride and its mixtures in batch or

continuous operations, including storage, materials transfers, mixing, large and small scale packing, loading (including marine vessel/barge,

rail/road car and IBC loading), maintenance and associated laboratory

activities. e.g. production of adsorbents, cosmetics, metals, fertilizers, plant protection, cement, haemodialysis solution and general

distributor activities with Calcium Chloride





Physical form of product Solid, medium dustiness [OC2]

Concentration of substance in product Covers percentage substance in the product up to 100 % (unless



Frequency and duration of use Covers daily exposures up to 8 hours (unless stated differently) [G2]


management

Not applicable



unless stated differently [G15]. Assumes a good basic standard of occupational hygiene is

implemented [G1].

Contributing Scenarios Risk Management Measures Note: list RMM standard phrases according to the control hierarchy indicated in the ECHA template: 1. Technical measures to prevent release, 2. Technical measures to prevent dispersion, 3. Organisational measures , 4. Personal protection.




FFUUDDIIXX TT MM

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to report any skin problems that may develop [E3]. Use suitable eye protection [PPE26].


Continuous process [CS54].


General exposures [CS1]. Continuous process [CS54].



General exposures [CS1]. Use in contained batch processes

[CS37].


Mixing operations (open systems)

[CS30].

Provide a good standard of general ventilation (not less than 3 to 5 air

changes per hour) [E11], or:


Calendering (including Banburys)

[CS64]


changes per hour) [E11], or: Wear a respirator conforming to EN140 with Type A/P2 filter or better

[PPE29]

Bulk open loading and unloading

[CS503].





Bulk closed loading and unloading

[CS501]. Dedicated facility [CS81]



[PPE29]


Transport [CS58].


changes per hour) [E11].

or: Wear a respirator conforming to EN140 with Type A/P2 filter or better [PPE29]

Tabletting, compression, extrusion or

pelletisation [CS506].



Process sampling [CS2]. Dedicated facility [CS81]


Wear a respirator conforming to EN140 with Type A/P2 filter or better

[PPE29]

Process sampling [CS2].

Non-dedicated facility [CS82].

Avoid carrying out operation for more than 1 hour [OC11].


[CS39]. Non-dedicated facility [CS82].


maintenance [E81], or: Wear a respirator conforming to EN140 with Type A/P2 filter or better

[PPE29]

Storage [CS67]. General exposures (closed systems)

[CS15].


Storage [CS67].


[CS15]. With sample collection [CS56].



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9.4. Use of calcium chloride as processing aid

9.4.1. Exposure scenario – Use of calcium chloride as processing aid (ES4)


Title Use of Calcium Chloride as processing aid; CAS: 10043-52-4

Use Descriptor Sector of Use: Industrial SU3 (SU1, SU2a, SU2b, SU4, SU5, SU6b, SU8,

SU9, SU10, SU11, SU12, SU13, SU14, SU15, SU16, SU17)

Process Categories: PROC1, PROC2, PROC3, PROC4, PROC6, PROC7, PROC8a, PROC8b, PROC9, PROC10, PROC13, PROC15, PROC22a,

PROC22b PROC22c, PROC23a, PROC23b, PROC23c

Environmental Release Categories: ERC 4

Processes, tasks, activities covered Use of Calcium Chloride as processing aid. Use as a process chemical or extraction agent. Includes recycling/ recovery, material transfers,

storage, maintenance and loading (including marine vessel/barge, road/rail car and bulk container), sampling and associated laboratory

activities. E.g. functions as adsorbent, coagulant, emulsion breaker,

alginates, extraction agent, completion fluid, heat transfer fluid, water treatment chemical or use within the paper industry for example as

antistatic





Physical form of product Solid, medium dustiness [OC2].






management

Not applicable



unless stated differently [G15].; Assumes a good basic standard of occupational hygiene is

implemented [G1].

Contributing Scenarios Risk Management Measures Note: list RMM standard phrases according to the control hierarchy indicated in the ECHA template: 1. Technical measures to prevent release, 2. Technical measures to prevent dispersion, 3. Organisational measures, 4. Personal protection.



Provide basic employee training to prevent / minimise exposures and to report any skin problems that may develop [E3]. Use suitable eye

protection [PPE26].

General exposures [CS1]. Continuous process [CS54].



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Continuous process [CS54]. With sample collection [CS56].



Use in contained batch processes [CS37].



[CS16].

Batch process [CS55]. With sample collection [CS56].

Filling / preparation of equipment from drums or containers. [CS45].




Calendering (including Banburys)

[CS64]



[PPE29]

Spraying [CS10]. Minimise exposure by partial enclosure of the operation or equipment and provide extract ventilation at openings [E60]. or:


[PPE29]






[CS501]. Dedicated facility [CS81]



[PPE29]

Drum/batch transfers [CS8]. Transport [CS58].



[PPE29]

Rolling, Brushing [CS51]. Provide a good standard of general ventilation (not less than 3 to 5 air changes per hour) [E11], or:


Dipping, immersion and pouring

[CS4].




[CS39]. Non-dedicated facility [CS82]


maintenance [E81], or:


Process sampling [CS2].

Dedicated facility [CS81]



[PPE29]

Process sampling [CS2]. Non-dedicated facility [CS82]

Avoid carrying out operation for more than 4 hours [OC12].


[CS15]. Elevated temperature [CS111].




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[CS15]. Elevated temperature [CS111].

Process temperature > melting point

Calcium Chloride

Provide a good standard of controlled ventilation (10 to 15 air changes

per hour) [E40], or: Wear a respirator conforming to EN140 with Type A/P2 filter or better

[PPE29]


(open systems) [CS108].





(open systems) [CS108]. Batch processes at elevated

temperatures [CS136].

Process temperature > melting point Calcium Chloride

Provide a good standard of controlled ventilation (10 to 15 air changes

per hour) [E40], or: Wear a respirator conforming to EN140 with Type A/P2 filter or better

[PPE29]

Storage [CS67].



9.5. Industrial outdoor use of calcium chloride - end use 9.5.1. Exposure scenario – Industrial outdoor use (ES5)


Title ES5: Industrial outdoor use of Calcium Chloride; CAS: 10043-

52-4

Use Descriptor Sector of Use: Industrial SU3 (SU1, SU2)

Process Categories: PROC1, PROC2, PROC5, PROC7, PROC8a,



Processes, tasks, activities covered Industrial outdoor use of Calcium Chloride. Covers the end use of

Calcium chloride either pure or in formulation by spreading, spraying and pouring. Including storage, materials transfers, mixing, loading

and maintenance. E.g. the use of dust suppression - and de-icing-

mixtures.











management

Not applicable


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unless stated differently [G15]. Assumes a good basic standard of occupational hygiene is

implemented [G1].

Outdoor [OC9].





to report any skin problems that may develop [E3]. Use suitable eye protection [PPE26].


[CS30].





Bulk closed loading and unloading [CS501].

Dedicated facility [CS81]


Drum/batch transfers [CS8]. Transport [CS58].


Spraying [CS10]. Minimise exposure by partial enclosure of the operation or equipment

and provide extract ventilation at openings [E60]. or: Wear a respirator conforming to EN140 with Type A/P2 filter or better

[PPE29]

Spraying [CS10].

Avoid carrying out operation for more than 1 hour [OC11], or: Wear a respirator conforming to EN140 with Type A/P2 filter or better

[PPE29]

Spreading Large surfaces [CS46].



[CS30]. Manual [CS34].


Spreading Manual [CS34]. No specific measures identified [EI18].


[CS39].



Storage [CS67].


[CS15].


Storage [CS67].




Section 2.2 Control of environmental exposure

Product characteristics Substance is a unique structure [PrC1].

Inorganic substance.


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Operational conditions Outdoor use [OOC1].

Contributing scenario De-icing agent, application as a mixture of 70% NaCl and

30% of a 20% solution of CaCl2

Amounts used

Annual tonnage of road salt 1.5 tonnes/km

Fraction of CaCl2 in road salt 0.06

Annual tonnage of CaCl2 0.09 tonnes/km


Type of release Dispersive use [FD3].

Emission Days (days/year) [FD4]: 25

Environmental factors not influenced by risk management

Spreading width (m): 10

Other Operational Conditions of use affecting environmental

exposure

Use in open systems.

Release fraction to air from process (initial release prior to RMM) [OOC4]:

0

Release fraction to wastewater from process (release after RMMs are

applied):

0

Release fraction to soil from process (initial release prior to RMM) [OOC6]:

1

Conditions and measures related to municipal sewage treatment

plant

Not applicable as there is no release to wastewater [STP1].

Other environmental control measures additional to above

Avoid spilling salt directly onto plants.

Contributing scenario De-icing agent, application as liquid CaCl2 brine (max. 35%

solution)

Amounts used









Other Operational Conditions of

use affecting environmental exposure


Release fraction to air from process

(initial release prior to RMM) [OOC4]:

0

Release fraction to wastewater from

process (release after RMMs are applied):

0

Release fraction to soil from process


1

Conditions and measures related

to municipal sewage treatment



FFUUDDIIXX TT MM

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plant

Other environmental control

measures additional to above


Contributing scenario De-icing agent, application as solid CaCl2 (up to 100%)

Amounts used


Fraction of CaCl2 in road salt 1








exposure




0


applied):

0


1


plant




Contributing scenario Dust suppressor, application as solid CaCl2 (up to 80%)

Amounts used

Annual tonnage of road salt 3 tonnes/km









exposure



0


applied):

0


1


FFUUDDIIXX TT MM

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to municipal sewage treatment

plant





Contributing scenario Dust suppressor, application as CaCl2 solution (up to 37%)

Amounts used










use affecting environmental

exposure




0



0



1


to municipal sewage treatment plant





9.6. Professional (indoor) use of calcium chloride 9.6.1. Exposure scenario – Professional indoor use (ES6)


Title ES6: Professional use of Calcium Chloride; CAS: 10043-52-4

Use Descriptor Sector of Use: professional SU22 (SU1, SU10, SU19, SU20, SU0- C23.5/

C23.6)

Process Categories: PROC1, PROC2, PROC 3, PROC4, PROC5, PROC8a, PROC8b, PROC9, PROC10, PROC11, PROC15, PROC19, PROC20

Environmental Release Categories: ERC 8a, 8d

Processes, tasks, activities covered Professional use of CaCl2. Covers the end use of Calcium chloride either

pure or in formulation including pouring/unloading from drums or containers; and exposures during mixing/diluting in the preparatory

phase and by spraying, brushing, dipping, wiping automated and by hand. E.g. the use of, washing and cleaning products or use as heat

transfer fluid.




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Concentration of substance in product Covers percentage substance in the product up to 100 % (unless stated

differently) [G13].




management

Not applicable

Other Operational Conditions affecting worker exposure

Assumes use at not more than 20°C above ambient temperature, unless stated differently [G15].;

Assumes a good basic standard of occupational hygiene is implemented

[G1].


General measures (irritants) [G19]. Avoid all skin contact with product, clean up contamination/spills as soon as they occur. Wear gloves (tested to EN374) if hand contamination

likely, wash off any skin contamination immediately. Provide basic

employee training to prevent / minimise exposures and to report any skin problems that may develop [E3].

Use suitable eye protection [PPE26].

General exposures (open systems) [CS16].

Batch process [CS55]. With sample collection [CS56].

Filling / preparation of equipment from drums or containers [CS45].



Application of cleaning products in

closed systems [CS101] With sample collection [CS56].

Filling / preparation of equipment from

drums or containers. [CS45].


changes per hour) [E11]. or: Wear a respirator conforming to EN140 with Type A/P2 filter or better

[PPE29]


[CS30].



[PPE29]





[PPE29]


[CS501]. Dedicated facility [CS81].



[PPE29].

Pouring from small containers [CS9]. Transport [CS58].



[PPE29].


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Rolling, Brushing [CS51]. Provide a good standard of general ventilation (not less than 3 to 5 air


[PPE29]


Wear a respirator conforming to EN140 with Type A/P2 filter or better [PPE29].


[CS30]. Manual [CS34].



[PPE29]

Manual spot cleaning (e.g. textiles etc) [CS52].



Heat and pressure transfer fluids

(closed systems) in dispersive use.


Equipment cleaning and maintenance [CS39].




[PPE29].

Laboratory activities [CS36]. Provide a good standard of general ventilation (not less than 3 to 5 air

changes per hour) [E11]. or:

Wear a respirator conforming to EN140 with Type A/P2 filter or better [PPE29].


[CS15].



[CS15].



9.7. Professional outdoor use of calcium chloride 9.7.1. Exposure scenario – Professional outdoor use (ES7)


Title Professional outdoor use of Calcium Chloride; CAS: 10043-52-4

Use Descriptor Sector of Use: Professional SU22 (SU1, SU5, SU10, SU13, SU19, SU20,

SU0- C23.5/ C23.6)

Process Categories: PROC1, PROC2, PROC5, PROC8a, PROC8b, PROC9, PROC10, PROC11, PROC13, PROC19, PROC20

Environmental Release Categories: ERC 8d

Processes, tasks, activities covered Professional outdoor use of CaCl2. Covers the end use of Calcium

chloride either pure or in formulation including pouring/unloading from drums or containers; and exposures during mixing/diluting in the

preparatory phase and by spraying, brushing, dipping, spreading

automated and by hand. Including storage, equipment clean-downs and disposal. E.g. the use of agrochemicals, dust suppression- and de-icing-

mixtures and the use of cement.



FFUUDDIIXX TT MM

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Concentration of substance in product Covers percentage substance in the product up to 100 % (unless stated differently) [G13].




management

Not applicable

Other Operational Conditions affecting worker exposure

Assumes use at not more than 20°C above ambient temperature, unless stated differently [G15].

Assumes a good basic standard of occupational hygiene is implemented

[G1]. Outdoor [OC9].

Contributing Scenarios Risk Management Measures Note: list RMM standard phrases according to the control hierarchy indicated in the ECHA template: 1. Technical measures to prevent release, 2. Technical measures to prevent dispersion, 3. Organisational measure, 4. Personal protection.

General measures (irritants) [G19]. Avoid all skin contact with product, clean up contamination/spills as soon

as they occur. Wear gloves (tested to EN374) if hand contamination likely, wash off any skin contamination immediately. Provide basic

employee training to prevent / minimise exposures and to report any skin problems that may develop [E3].



[CS30].


Bulk open loading and unloading

[CS503].



Filling / preparation of equipment from

drums or containers. [CS45]. Non-dedicated facility [CS82].



[CS501]. Dedicated facility [CS81].



Transport [CS58].


Pouring from small containers [CS9]. No specific measures identified [EI18].

Rolling, Brushing [CS51]. No specific measures identified [EI18].



Spraying [CS10]. Avoid carrying out operation for more than 1 hour [OC11], or:


Dipping, immersion and pouring No specific measures identified [EI18].


FFUUDDIIXX TT MM

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[CS4].

Spreading Large surfaces [CS46]. No specific measures identified [EI18].

Mixing operations (open systems) [CS30]. Manual [CS34].


Spreading Manual [CS34]. No specific measures identified [EI18].


[CS39]. Non-dedicated facility [CS82]


Heat and pressure transfer fluids

(closed systems) in dispersive use



[CS15].


Storage [CS67].General exposures (closed systems) [CS15].



Section 2.2 Control of environmental exposure

Product characteristics Substance is a unique structure [PrC1].

Inorganic substance.

Operational conditions Outdoor use [OOC1].

Contributing scenario De-icing agent, application as a mixture of 70% NaCl and 30% of a 20% solution of CaCl2

Amounts used











exposure




0



0



1







Contributing scenario De-icing agent, application as liquid CaCl2 brine (max. 35%

solution)

Amounts used




FFUUDDIIXX TT MM

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exposure




0


applied):

0


1


plant




Contributing scenario De-icing agent, application as solid CaCl2 (up to 100%)

Amounts used


Fraction of CaCl2 in road salt 1









exposure



0


process (release after RMMs are

applied):

0



1







Contributing scenario Dust suppressor, application as solid CaCl2 (up to 80%)

Amounts used




FFUUDDIIXX TT MM

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exposure




0


applied):

0


1


plant




Contributing scenario Dust suppressor, application as CaCl2 solution (up to 37%)

Amounts used










exposure



0


applied):

0


1


plant





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9.9. Handling of calcium chloride with low dustiness

9.9.1. Exposure scenario – Handling of calcium chloride with low dustiness (ES9)


Title Handling of Calcium Chloride with low dustiness ; CAS: 10043-

52-4

Use Descriptor Sector of Use: SU3,SU22 (SU1, SU2a,SU4,SU5,SU6b,SU8,SU9, SU10, SU11,SU12,SU13, SU14,SU15 SU19, SU20, SU0- C23.5/ C23.6)

Process Categories: PROC1, PROC2, PROC3, PROC4, PROC5, PROC6, PROC7, PROC8a, PROC8b, PROC9, PROC10, PROC11, PROC13,

PROC14, PROC15, PROC22a, PROC22b, PROC22c, PROC23a, PROC23b,

PROC23c

Environmental Release Categories: ERC1, ERC6a, ERC2, ERC4, ERC8a,

ERC8d

Processes, tasks, activities covered Handling of Calcium Chloride pellets, flakes or other Calcium Chloride with low dustiness or preparations of these.





Physical form of product Solid, low dustiness [OC1].

Concentration of substance in product Covers percentage substance in the product up to 100 % (unless stated

differently) [G13].



Human factors not influenced by risk management

Not applicable



unless stated differently [G15]. Assumes a good basic standard of occupational hygiene is implemented

[G1].


General measures (irritants) [G19]. Avoid all skin contact with product, clean up contamination/spills as soon as they occur. Wear gloves (tested to EN374) if hand

contamination likely, wash off any skin contamination immediately. Provide basic employee training to prevent / minimise exposure.


General measures applicable to all activities [CS135].



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9.10. Use of calcium chloride by consumers

9.10.1. Exposure scenario – Consumers (ES10)


Title Consumer use of Calcium Chloride and Calcium Chloride

containing products

Sector of Use SU21

Product Category PC2, PC4, PC 5, PC12, PC16, PC 27, PC35, PC37, PC0- UCN code K35100

Environmental Release

Category

ERC8a, ERC8d

Processes, tasks, activities

covered

Section 2 Operational conditions (OC) and risk management measures (RMM)

Field for additional statements to explain scenario if required

Section 2.1 Control of consumer exposure

Physical form of product

Concentration of

substance in product

Covers concentrations up to 100%. [ConsOC1]

Additional sub-headers to Product characteristic as required.

Standard phrases linked to each sub-header

Amounts used For each use event, covers use amounts up to 50 kg unless

stated differently. [ConsOC2]

Frequency and duration of

use

Covers use up to 365 days/year, unless stated differently

[ConsOC3]; Covers exposure up to 24 hours/event, unless stated differently [ConsOC14]


management

Inhalation rate up to 32,9 m3/day (Justification; Default ConsExpo light exercise- 60 kg. Average bw women, is

reasonable worst case);


worker exposure

Covers use at ambient temperatures. [ConsOC15]; Room volume of 1 m3 ‘Room volume’ is interpreted here as personal

space: a small area of 1 m3 around the use. Minimum 0,6 Air

Exchange Rate (1/hr) Justification; equals to indoor typical (ConsExpo General Factsheet (RIVM report 320104002/2006)-

unspecified room). Covers use with a release area up to 125 m2, unless stated differently. “Do not touch eyes when using

this product”.

Chemical Product Categories

Justification

PC2 (adsorbents) CaCl2

used as domestic dehumidifier.

OC No specific operation conditions identified Reasonable

worst-case estimate non-

spraying activities

RMM No specific measures identified

PC4 (antifreeze + de-

icing) CaCl2 used for de-icing and antifreeze


worst case estimate non-

spraying

activities


PC9b (Fillers, putties, OC No specific operation conditions identified Reasonable


FFUUDDIIXX TT MM

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plasters modelling clay) Calcium Chloride used in

modelling clay

RMM No specific measures identified worst case estimate non-

spraying activities

PC12 (fertilizers) Calcium

Chloride in domestic fertilizers


worst case estimate non-

spraying

activities


PC16 (Heat transfer

fluids) Calcium Chloride as

energy source in self-heating-cup.


worst case

estimate non-spraying

activities


PC27 (plant protection) Calcium Chloride in plant

protection formulations

OC Non-spraying activities - No specific operation conditions identified

Reasonable worst case


activities


OC Spraying- Covers concentration up to saturation (45%) [ConsOC1]; Covers spray duration up too

10 minutes/event. Covers use in room of 58m3

with room height of 2,5m. Justification; default Consexpo-Pestcontrol>>surface spraying


estimate

spraying.

RMM Spray away from person

PC35 (washing and

cleaning products)

Calcium Chloride containing washing and

cleaning products

OC Non-spraying activities - No specific operation

conditions identified

Reasonable

worst case


activities


OC Spraying- Covers concentration up to saturation (45%) [ConsOC1]; Covers spray duration up too

10 minutes/event. Covers use in room of 58m3 with room height of 2,5m. Justification; default

Consexpo-Pestcontrol>>surface spraying


estimate spraying

RMM Spray away from person

PC37 (water treatment

chemicals) Calcium

Chloride used as water treatment chemical e.g. in

aquaria


worst case


activities


PC0- UCN code K35100 (Cement/concrete/mortar)

Calcium Chloride in Cement/concrete/mortar

OC No specific operation conditions identified Reasonable worst case


activities


calcium chloride pellets/powder 95-98% fudix - · pdf filesafety data sheet calcium chloride...

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