c -dynamical systems and nonequilibrium...
TRANSCRIPT
C∗-Dynamical Systems
andNonequilibrium Quantum Statistical Mechanics
Algebraic Approach to the Thermodynamicsof
Open Quantum Systems
C.-A. Pillet
Centre de Physique Theorique – UMR 6207
Universite du Sud – Toulon-Var
ESI–June 2008 – p. 1
Overview
ESI–June 2008 – p. 2
Overview
• Review of some recent results in the Nonequilibrium Quantum StatisticalMechanics of open systems:Joint program (1997-2008) with Vojkan Jakšic, McGill University – Montreal.
ESI–June 2008 – p. 2
Overview
• Review of some recent results in the Nonequilibrium Quantum StatisticalMechanics of open systems:Joint program (1997-2008) with Vojkan Jakšic, McGill University – Montreal.
• Nonequilibrium Steady States (NESS).
ESI–June 2008 – p. 2
Overview
• Review of some recent results in the Nonequilibrium Quantum StatisticalMechanics of open systems:Joint program (1997-2008) with Vojkan Jakšic, McGill University – Montreal.
• Nonequilibrium Steady States (NESS).
• Entropy Production in NESS.
ESI–June 2008 – p. 2
Overview
• Review of some recent results in the Nonequilibrium Quantum StatisticalMechanics of open systems:Joint program (1997-2008) with Vojkan Jakšic, McGill University – Montreal.
• Nonequilibrium Steady States (NESS).
• Entropy Production in NESS.
• [Structural Properties of NESS.]
ESI–June 2008 – p. 2
Overview
• Review of some recent results in the Nonequilibrium Quantum StatisticalMechanics of open systems:Joint program (1997-2008) with Vojkan Jakšic, McGill University – Montreal.
• Nonequilibrium Steady States (NESS).
• Entropy Production in NESS.
• [Structural Properties of NESS.]
• Linear Response Theory (with Yoshiko Ogata, Fukuoka University).
ESI–June 2008 – p. 2
Overview
• Review of some recent results in the Nonequilibrium Quantum StatisticalMechanics of open systems:Joint program (1997-2008) with Vojkan Jakšic, McGill University – Montreal.
• Nonequilibrium Steady States (NESS).
• Entropy Production in NESS.
• [Structural Properties of NESS.]
• Linear Response Theory (with Yoshiko Ogata, Fukuoka University).
• Central Limit Theorem (with Yan Pautrat, Orsay).
ESI–June 2008 – p. 2
Overview
• Review of some recent results in the Nonequilibrium Quantum StatisticalMechanics of open systems:Joint program (1997-2008) with Vojkan Jakšic, McGill University – Montreal.
• Nonequilibrium Steady States (NESS).
• Entropy Production in NESS.
• [Structural Properties of NESS.]
• Linear Response Theory (with Yoshiko Ogata, Fukuoka University).
• Central Limit Theorem (with Yan Pautrat, Orsay).
• [Landauer-Büttiker approach (with Walter Aschbacher, TU-München and YanPautrat).]
ESI–June 2008 – p. 2
Overview
• Review of some recent results in the Nonequilibrium Quantum StatisticalMechanics of open systems:Joint program (1997-2008) with Vojkan Jakšic, McGill University – Montreal.
• Nonequilibrium Steady States (NESS).
• Entropy Production in NESS.
• [Structural Properties of NESS.]
• Linear Response Theory (with Yoshiko Ogata, Fukuoka University).
• Central Limit Theorem (with Yan Pautrat, Orsay).
• [Landauer-Büttiker approach (with Walter Aschbacher, TU-München and YanPautrat).]
• Models: Quasifree and locally interacting fermions. N -levels system coupled tofree Fermi reservoirs.
ESI–June 2008 – p. 2
Overview
• Review of some recent results in the Nonequilibrium Quantum StatisticalMechanics of open systems:Joint program (1997-2008) with Vojkan Jakšic, McGill University – Montreal.
• Nonequilibrium Steady States (NESS).
• Entropy Production in NESS.
• [Structural Properties of NESS.]
• Linear Response Theory (with Yoshiko Ogata, Fukuoka University).
• Central Limit Theorem (with Yan Pautrat, Orsay).
• [Landauer-Büttiker approach (with Walter Aschbacher, TU-München and YanPautrat).]
• Models: Quasifree and locally interacting fermions. N -levels system coupled tofree Fermi reservoirs.
• [Repeated Interactions (with Laurent Bruneau, Cergy).]
ESI–June 2008 – p. 2
Overview
• Review of some recent results in the Nonequilibrium Quantum StatisticalMechanics of open systems:Joint program (1997-2008) with Vojkan Jakšic, McGill University – Montreal.
• Nonequilibrium Steady States (NESS).
• Entropy Production in NESS.
• [Structural Properties of NESS.]
• Linear Response Theory (with Yoshiko Ogata, Fukuoka University).
• Central Limit Theorem (with Yan Pautrat, Orsay).
• [Landauer-Büttiker approach (with Walter Aschbacher, TU-München and YanPautrat).]
• Models: Quasifree and locally interacting fermions. N -levels system coupled tofree Fermi reservoirs.
• [Repeated Interactions (with Laurent Bruneau, Cergy).]
ESI–June 2008 – p. 2
0. Mathematical Framework
Algebraic Quantum Statistical Mechanics as described in "the Bible":O. Bratteli D. Robinson: Operator Algebras in Quantum Statistical Mechanics vol. 1 & 2
ESI–June 2008 – p. 3
0. Mathematical Framework
Algebraic Quantum Statistical Mechanics as described in "the Bible":O. Bratteli D. Robinson: Operator Algebras in Quantum Statistical Mechanics vol. 1 & 2
Dynamical system (M,φ, µ) C∗-dynamical system (O, τ, ω)
ESI–June 2008 – p. 3
0. Mathematical Framework
Algebraic Quantum Statistical Mechanics as described in "the Bible":O. Bratteli D. Robinson: Operator Algebras in Quantum Statistical Mechanics vol. 1 & 2
Dynamical system (M,φ, µ) C∗-dynamical system (O, τ, ω)
Group G ∋ t 7→ φt : M →M
ESI–June 2008 – p. 3
0. Mathematical Framework
Algebraic Quantum Statistical Mechanics as described in "the Bible":O. Bratteli D. Robinson: Operator Algebras in Quantum Statistical Mechanics vol. 1 & 2
Dynamical system (M,φ, µ) C∗-dynamical system (O, τ, ω)
Group G ∋ t 7→ φt : M →M
Observables f ∈ C(M) Observables A ∈ O, a C∗-algebra
ESI–June 2008 – p. 3
0. Mathematical Framework
Algebraic Quantum Statistical Mechanics as described in "the Bible":O. Bratteli D. Robinson: Operator Algebras in Quantum Statistical Mechanics vol. 1 & 2
Dynamical system (M,φ, µ) C∗-dynamical system (O, τ, ω)
Group G ∋ t 7→ φt : M →M
Observables f ∈ C(M) Observables A ∈ O, a C∗-algebraτ t(f) = f φt Group of ∗-automorphisms τ t(A)
ESI–June 2008 – p. 3
0. Mathematical Framework
Algebraic Quantum Statistical Mechanics as described in "the Bible":O. Bratteli D. Robinson: Operator Algebras in Quantum Statistical Mechanics vol. 1 & 2
Dynamical system (M,φ, µ) C∗-dynamical system (O, τ, ω)
Group G ∋ t 7→ φt : M →M
Observables f ∈ C(M) Observables A ∈ O, a C∗-algebraτ t(f) = f φt Group of ∗-automorphisms τ t(A)
Measure µ⇒ expectation µ(f) State ω ⇒ expectation ω(A)
ESI–June 2008 – p. 3
0. Mathematical Framework
Algebraic Quantum Statistical Mechanics as described in "the Bible":O. Bratteli D. Robinson: Operator Algebras in Quantum Statistical Mechanics vol. 1 & 2
Dynamical system (M,φ, µ) C∗-dynamical system (O, τ, ω)
Group G ∋ t 7→ φt : M →M
Observables f ∈ C(M) Observables A ∈ O, a C∗-algebraτ t(f) = f φt Group of ∗-automorphisms τ t(A)
Measure µ⇒ expectation µ(f) State ω ⇒ expectation ω(A)
Invariant measure µ(τ t(f)) = µ(f) Invariant state ω τ t = ω
ESI–June 2008 – p. 3
0. Mathematical Framework
Algebraic Quantum Statistical Mechanics as described in "the Bible":O. Bratteli D. Robinson: Operator Algebras in Quantum Statistical Mechanics vol. 1 & 2
Dynamical system (M,φ, µ) C∗-dynamical system (O, τ, ω)
Group G ∋ t 7→ φt : M →M
Observables f ∈ C(M) Observables A ∈ O, a C∗-algebraτ t(f) = f φt Group of ∗-automorphisms τ t(A)
Measure µ⇒ expectation µ(f) State ω ⇒ expectation ω(A)
Invariant measure µ(τ t(f)) = µ(f) Invariant state ω τ t = ω
Koopman space Hµ = L2(M,µ) GNS representation (Hω , πω ,Ωω)
ESI–June 2008 – p. 3
0. Mathematical Framework
Algebraic Quantum Statistical Mechanics as described in "the Bible":O. Bratteli D. Robinson: Operator Algebras in Quantum Statistical Mechanics vol. 1 & 2
Dynamical system (M,φ, µ) C∗-dynamical system (O, τ, ω)
Group G ∋ t 7→ φt : M →M
Observables f ∈ C(M) Observables A ∈ O, a C∗-algebraτ t(f) = f φt Group of ∗-automorphisms τ t(A)
Measure µ⇒ expectation µ(f) State ω ⇒ expectation ω(A)
Invariant measure µ(τ t(f)) = µ(f) Invariant state ω τ t = ω
Koopman space Hµ = L2(M,µ) GNS representation (Hω , πω ,Ωω)
eitLψ = ψ φt, L1 = 0 eitLπω(A)Ωω = πω τ t(A)Ωω
eitLfe−itL = τ t(f) eitLπω(A)e−itL = πω(τ t(A))
ESI–June 2008 – p. 3
0. Mathematical Framework
Algebraic Quantum Statistical Mechanics as described in "the Bible":O. Bratteli D. Robinson: Operator Algebras in Quantum Statistical Mechanics vol. 1 & 2
Dynamical system (M,φ, µ) C∗-dynamical system (O, τ, ω)
Group G ∋ t 7→ φt : M →M
Observables f ∈ C(M) Observables A ∈ O, a C∗-algebraτ t(f) = f φt Group of ∗-automorphisms τ t(A)
Measure µ⇒ expectation µ(f) State ω ⇒ expectation ω(A)
Invariant measure µ(τ t(f)) = µ(f) Invariant state ω τ t = ω
Koopman space Hµ = L2(M,µ) GNS representation (Hω , πω ,Ωω)
eitLψ = ψ φt, L1 = 0 eitLπω(A)Ωω = πω τ t(A)Ωω
eitLfe−itL = τ t(f) eitLπω(A)e−itL = πω(τ t(A))
ν ≪ µ ω-normal states: η(A) = trρπω(A)
ESI–June 2008 – p. 3
0. Mathematical Framework
Algebraic Quantum Statistical Mechanics as described in "the Bible":O. Bratteli D. Robinson: Operator Algebras in Quantum Statistical Mechanics vol. 1 & 2
Dynamical system (M,φ, µ) C∗-dynamical system (O, τ, ω)
Group G ∋ t 7→ φt : M →M
Observables f ∈ C(M) Observables A ∈ O, a C∗-algebraτ t(f) = f φt Group of ∗-automorphisms τ t(A)
Measure µ⇒ expectation µ(f) State ω ⇒ expectation ω(A)
Invariant measure µ(τ t(f)) = µ(f) Invariant state ω τ t = ω
Koopman space Hµ = L2(M,µ) GNS representation (Hω , πω ,Ωω)
eitLψ = ψ φt, L1 = 0 eitLπω(A)Ωω = πω τ t(A)Ωω
eitLfe−itL = τ t(f) eitLπω(A)e−itL = πω(τ t(A))
ν ≪ µ ω-normal states: η(A) = trρπω(A)
Lebesgue decomposition ν = νac + νsing η = ηnormal + ηsing
ESI–June 2008 – p. 3
0. Mathematical Framework
Algebraic Quantum Statistical Mechanics as described in "the Bible":O. Bratteli D. Robinson: Operator Algebras in Quantum Statistical Mechanics vol. 1 & 2
Dynamical system (M,φ, µ) C∗-dynamical system (O, τ, ω)
Group G ∋ t 7→ φt : M →M
Observables f ∈ C(M) Observables A ∈ O, a C∗-algebraτ t(f) = f φt Group of ∗-automorphisms τ t(A)
Measure µ⇒ expectation µ(f) State ω ⇒ expectation ω(A)
Invariant measure µ(τ t(f)) = µ(f) Invariant state ω τ t = ω
Koopman space Hµ = L2(M,µ) GNS representation (Hω , πω ,Ωω)
eitLψ = ψ φt, L1 = 0 eitLπω(A)Ωω = πω τ t(A)Ωω
eitLfe−itL = τ t(f) eitLπω(A)e−itL = πω(τ t(A))
ν ≪ µ ω-normal states: η(A) = trρπω(A)
Lebesgue decomposition ν = νac + νsing η = ηnormal + ηsing
Koopmanism: ergodic prop. ⇔ sp(L) Quantum-Koopmanism
ESI–June 2008 – p. 3
0. Mathematical Framework
Algebraic Quantum Statistical Mechanics as described in "the Bible":O. Bratteli D. Robinson: Operator Algebras in Quantum Statistical Mechanics vol. 1 & 2
Dynamical system (M,φ, µ) C∗-dynamical system (O, τ, ω)
Group G ∋ t 7→ φt : M →M
Observables f ∈ C(M) Observables A ∈ O, a C∗-algebraτ t(f) = f φt Group of ∗-automorphisms τ t(A)
Measure µ⇒ expectation µ(f) State ω ⇒ expectation ω(A)
Invariant measure µ(τ t(f)) = µ(f) Invariant state ω τ t = ω
Koopman space Hµ = L2(M,µ) GNS representation (Hω , πω ,Ωω)
eitLψ = ψ φt, L1 = 0 eitLπω(A)Ωω = πω τ t(A)Ωω
eitLfe−itL = τ t(f) eitLπω(A)e−itL = πω(τ t(A))
ν ≪ µ ω-normal states: η(A) = trρπω(A)
Lebesgue decomposition ν = νac + νsing η = ηnormal + ηsing
Koopmanism: ergodic prop. ⇔ sp(L) Quantum-Koopmanismµ(fτ t(g)) = µ(τ t(g)f) (τ, β)-KMS states ω(Aτ t+iβ(B)) = ω(τ t(B)A)
ESI–June 2008 – p. 3
1. Example: The Ideal Fermi Gas
ESI–June 2008 – p. 4
1. Example: The Ideal Fermi Gas
• Simplest model for electrons in a (semi-)conductor.
ESI–June 2008 – p. 4
1. Example: The Ideal Fermi Gas
• Simplest model for electrons in a (semi-)conductor.
• 1-particle Hilbert space h (e.g L2(M),M ⊂ Rd or ℓ2(M),M ⊂ Zd).
ESI–June 2008 – p. 4
1. Example: The Ideal Fermi Gas
• Simplest model for electrons in a (semi-)conductor.
• 1-particle Hilbert space h (e.g L2(M),M ⊂ Rd or ℓ2(M),M ⊂ Zd).
• 1-particle Hamiltonian H (e.g. H = −∆ + V ).
ESI–June 2008 – p. 4
1. Example: The Ideal Fermi Gas
• Simplest model for electrons in a (semi-)conductor.
• 1-particle Hilbert space h (e.g L2(M),M ⊂ Rd or ℓ2(M),M ⊂ Zd).
• 1-particle Hamiltonian H (e.g. H = −∆ + V ).
• 1-particle propagator U(t) = e−itH solves the Schrödinger equation i∂tψ = Hψ.
ESI–June 2008 – p. 4
1. Example: The Ideal Fermi Gas
• Simplest model for electrons in a (semi-)conductor.
• 1-particle Hilbert space h (e.g L2(M),M ⊂ Rd or ℓ2(M),M ⊂ Zd).
• 1-particle Hamiltonian H (e.g. H = −∆ + V ).
• 1-particle propagator U(t) = e−itH solves the Schrödinger equation i∂tψ = Hψ.
• n-particles Hilbert space and propagator, taking Pauli into account
Γ−n (h) = h∧ · · · ∧ h, Γn(U(t)) = U(t) ⊗ · · · ⊗ U(t).
ESI–June 2008 – p. 4
1. Example: The Ideal Fermi Gas
• Simplest model for electrons in a (semi-)conductor.
• 1-particle Hilbert space h (e.g L2(M),M ⊂ Rd or ℓ2(M),M ⊂ Zd).
• 1-particle Hamiltonian H (e.g. H = −∆ + V ).
• 1-particle propagator U(t) = e−itH solves the Schrödinger equation i∂tψ = Hψ.
• n-particles Hilbert space and propagator, taking Pauli into account
Γ−n (h) = h∧ · · · ∧ h, Γn(U(t)) = U(t) ⊗ · · · ⊗ U(t).
• Second quantization: With Γ−0 (h) = C, Γ0(U(t)) = I,
Γ−(h) =
∞M
n=0
Γ−n (h), Γ(U(t)) =
∞M
n=0
Γn(U(t)).
ESI–June 2008 – p. 4
1. Example: The Ideal Fermi Gas
• Simplest model for electrons in a (semi-)conductor.
• 1-particle Hilbert space h (e.g L2(M),M ⊂ Rd or ℓ2(M),M ⊂ Zd).
• 1-particle Hamiltonian H (e.g. H = −∆ + V ).
• 1-particle propagator U(t) = e−itH solves the Schrödinger equation i∂tψ = Hψ.
• n-particles Hilbert space and propagator, taking Pauli into account
Γ−n (h) = h∧ · · · ∧ h, Γn(U(t)) = U(t) ⊗ · · · ⊗ U(t).
• Second quantization: With Γ−0 (h) = C, Γ0(U(t)) = I,
Γ−(h) =
∞M
n=0
Γ−n (h), Γ(U(t)) =
∞M
n=0
Γn(U(t)).
• Creation/annihilation operators
a∗(f)f1 ∧ · · · ∧ fn =√n+ 1f1 ∧ · · · ∧ fn ∧ f,
a(f)f1 ∧ · · · ∧ fn =1√n
nX
j=1
(−1)n−j(f, fj)f1 ∧ · · ·fj · · · ∧ fn.
ESI–June 2008 – p. 4
1. Example: The Ideal Fermi Gas
• Canonical Anticommutation Relations (CAR):
a(f), a(g) = a(f)a(g) + a(g)a(f) = 0,
a(f), a∗(g) = a(f)a∗(g) + a∗(g)a(f) = (f, g)I.
ESI–June 2008 – p. 5
1. Example: The Ideal Fermi Gas
• Canonical Anticommutation Relations (CAR):
a(f), a(g) = a(f)a(g) + a(g)a(f) = 0,
a(f), a∗(g) = a(f)a∗(g) + a∗(g)a(f) = (f, g)I.
• CAR(h) = C∗-algebra generated by a(f)|f ∈ h.
ESI–June 2008 – p. 5
1. Example: The Ideal Fermi Gas
• Canonical Anticommutation Relations (CAR):
a(f), a(g) = a(f)a(g) + a(g)a(f) = 0,
a(f), a∗(g) = a(f)a∗(g) + a∗(g)a(f) = (f, g)I.
• CAR(h) = C∗-algebra generated by a(f)|f ∈ h.
• C∗-dynamical system (CAR(h), τ) with
τ t(a(f)) ≡ Γ(U(t))∗a(f)Γ(U(t)) = a(eitHf),
ESI–June 2008 – p. 5
1. Example: The Ideal Fermi Gas
• Canonical Anticommutation Relations (CAR):
a(f), a(g) = a(f)a(g) + a(g)a(f) = 0,
a(f), a∗(g) = a(f)a∗(g) + a∗(g)a(f) = (f, g)I.
• CAR(h) = C∗-algebra generated by a(f)|f ∈ h.
• C∗-dynamical system (CAR(h), τ) with
τ t(a(f)) ≡ Γ(U(t))∗a(f)Γ(U(t)) = a(eitHf),
• Unique (τ, β)-KMS state
ωβ(a∗(g1) · · · a∗(gn)a(fm) · · · a(f1)) = δnm det(fi, T gj),
with T = (I + eβH)−1 (Gauge-invariant quasi-free state ⇒ Araki-Wyss).
ESI–June 2008 – p. 5
1. Example: The Ideal Fermi Gas
• Canonical Anticommutation Relations (CAR):
a(f), a(g) = a(f)a(g) + a(g)a(f) = 0,
a(f), a∗(g) = a(f)a∗(g) + a∗(g)a(f) = (f, g)I.
• CAR(h) = C∗-algebra generated by a(f)|f ∈ h.
• C∗-dynamical system (CAR(h), τ) with
τ t(a(f)) ≡ Γ(U(t))∗a(f)Γ(U(t)) = a(eitHf),
• Unique (τ, β)-KMS state
ωβ(a∗(g1) · · · a∗(gn)a(fm) · · · a(f1)) = δnm det(fi, T gj),
with T = (I + eβH)−1 (Gauge-invariant quasi-free state ⇒ Araki-Wyss).
• Local perturbation
V =K
X
k=1
nkY
j=1
a∗(gkj)a(fkj),
leads to locally interacting Fermi gas.
ESI–June 2008 – p. 5
2. Open Quantum Systems
S
R1
R2
V2
V1
ESI–June 2008 – p. 6
2. Open Quantum Systems
S
R1
R2
V2
V1
Reservoir Rj : Extended ideal quantum gas (Oj , τtj = etδj ).
ESI–June 2008 – p. 6
2. Open Quantum Systems
S
R1
R2
V2
V1
Reservoir Rj : Extended ideal quantum gas (Oj , τtj = etδj ).
Small system S: Finite quantum system (O0, τt0 = etδ0 ) (may be absent!).
ESI–June 2008 – p. 6
2. Open Quantum Systems
S
R1
R2
V2
V1
Reservoir Rj : Extended ideal quantum gas (Oj , τtj = etδj ).
Small system S: Finite quantum system (O0, τt0 = etδ0 ) (may be absent!).
(O, τ) = ⊗j(Oj , τj) with multi-KMS reference state ω−→β
= ⊗jωβj.
ESI–June 2008 – p. 6
2. Open Quantum Systems
S
R1
R2
V2
V1
Reservoir Rj : Extended ideal quantum gas (Oj , τtj = etδj ).
Small system S: Finite quantum system (O0, τt0 = etδ0 ) (may be absent!).
(O, τ) = ⊗j(Oj , τj) with multi-KMS reference state ω−→β
= ⊗jωβj.
Coupling V =P
j>0 Vj : Local perturbation Vj ∈ O0 ⊗Oj .
ESI–June 2008 – p. 6
2. Open Quantum Systems
S
R1
R2
V2
V1
Reservoir Rj : Extended ideal quantum gas (Oj , τtj = etδj ).
Small system S: Finite quantum system (O0, τt0 = etδ0 ) (may be absent!).
(O, τ) = ⊗j(Oj , τj) with multi-KMS reference state ω−→β
= ⊗jωβj.
Coupling V =P
j>0 Vj : Local perturbation Vj ∈ O0 ⊗Oj .
Coupled system (O, τ tV = et(
P
j δj+i[V, · ])).
ESI–June 2008 – p. 6
2.1 NESS of Open Quantum Systems
[Ruelle ’00]For all A ∈ O and all ω−→
β–normal state η
limt→∞
η τ tV (A) = ω−→
β+(A).
ESI–June 2008 – p. 7
2.1 NESS of Open Quantum Systems
[Ruelle ’00]For all A ∈ O and all ω−→
β–normal state η
limt→∞
η τ tV (A) = ω−→
β+(A).
Return to equilibrium: β1 = β2 = · · · = β =⇒ ω−→β
+ is (τV , β)-KMS;
[Jakšic-P ’96], [Bach-Fröhlich-Sigal ’00], [Derezinski-Jakšic ’03], [Fröhlich-Merkli ’04].
ESI–June 2008 – p. 7
2.1 NESS of Open Quantum Systems
[Ruelle ’00]For all A ∈ O and all ω−→
β–normal state η
limt→∞
η τ tV (A) = ω−→
β+(A).
Return to equilibrium: β1 = β2 = · · · = β =⇒ ω−→β
+ is (τV , β)-KMS;
[Jakšic-P ’96], [Bach-Fröhlich-Sigal ’00], [Derezinski-Jakšic ’03], [Fröhlich-Merkli ’04].
Out of equilibrium: βi 6= βj =⇒ ω−→β
+ is ω−→β
-singular.
⇓No density matrix in GNS space Hω−→
β:
Hilbert space approach ?
ESI–June 2008 – p. 7
2.1 NESS of Open Quantum Systems
[Ruelle ’00]For all A ∈ O and all ω−→
β–normal state η
limt→∞
η τ tV (A) = ω−→
β+(A).
Return to equilibrium: β1 = β2 = · · · = β =⇒ ω−→β
+ is (τV , β)-KMS;
[Jakšic-P ’96], [Bach-Fröhlich-Sigal ’00], [Derezinski-Jakšic ’03], [Fröhlich-Merkli ’04].
Out of equilibrium: βi 6= βj =⇒ ω−→β
+ is ω−→β
-singular.
⇓No density matrix in GNS space Hω−→
β:
Hilbert space approach ?
Basic Problem 1. Existence of NESS.
ESI–June 2008 – p. 7
2.2 NESS: The Scattering Approach
C∗-scattering theory: [Hepp ’70], [Robinson ’73], [Botvich-Malyshev ’78].
ESI–June 2008 – p. 8
2.2 NESS: The Scattering Approach
C∗-scattering theory: [Hepp ’70], [Robinson ’73], [Botvich-Malyshev ’78].
NESS construction: [Dirren-Fröhlich-Graf ’98], [Ruelle ’00], [Fröhlich-Merkli-Ueltschi ’03].
ESI–June 2008 – p. 8
2.2 NESS: The Scattering Approach
C∗-scattering theory: [Hepp ’70], [Robinson ’73], [Botvich-Malyshev ’78].
NESS construction: [Dirren-Fröhlich-Graf ’98], [Ruelle ’00], [Fröhlich-Merkli-Ueltschi ’03].
τ -invariant reference state ω: ω τ tV = ω τ−t τ t
V ,
ESI–June 2008 – p. 8
2.2 NESS: The Scattering Approach
C∗-scattering theory: [Hepp ’70], [Robinson ’73], [Botvich-Malyshev ’78].
NESS construction: [Dirren-Fröhlich-Graf ’98], [Ruelle ’00], [Fröhlich-Merkli-Ueltschi ’03].
τ -invariant reference state ω: ω τ tV = ω τ−t τ t
V ,
Møller morphism: γ+(A) = limt→∞
τ−t τ tV (A),
ESI–June 2008 – p. 8
2.2 NESS: The Scattering Approach
C∗-scattering theory: [Hepp ’70], [Robinson ’73], [Botvich-Malyshev ’78].
NESS construction: [Dirren-Fröhlich-Graf ’98], [Ruelle ’00], [Fröhlich-Merkli-Ueltschi ’03].
τ -invariant reference state ω: ω τ tV = ω τ−t τ t
V ,
Møller morphism: γ+(A) = limt→∞
τ−t τ tV (A),
limt→∞
ω τ tV = ω γ+ = ω+
ESI–June 2008 – p. 8
2.2 NESS: The Scattering Approach
C∗-scattering theory: [Hepp ’70], [Robinson ’73], [Botvich-Malyshev ’78].
NESS construction: [Dirren-Fröhlich-Graf ’98], [Ruelle ’00], [Fröhlich-Merkli-Ueltschi ’03].
τ -invariant reference state ω: ω τ tV = ω τ−t τ t
V ,
Møller morphism: γ+(A) = limt→∞
τ−t τ tV (A),
limt→∞
ω τ tV = ω γ+ = ω+
O+ ≡ Ranγ+ ⇒ (O+, τ |O+ , ω|O+ ) ∼ (O, τV , ω+)
ESI–June 2008 – p. 8
2.2 NESS: The Scattering Approach
C∗-scattering theory: [Hepp ’70], [Robinson ’73], [Botvich-Malyshev ’78].
NESS construction: [Dirren-Fröhlich-Graf ’98], [Ruelle ’00], [Fröhlich-Merkli-Ueltschi ’03].
τ -invariant reference state ω: ω τ tV = ω τ−t τ t
V ,
Møller morphism: γ+(A) = limt→∞
τ−t τ tV (A),
limt→∞
ω τ tV = ω γ+ = ω+
O+ ≡ Ranγ+ ⇒ (O+, τ |O+ , ω|O+ ) ∼ (O, τV , ω+)
Theorem. [Aschbacher-Jakšic-Pautrat-P ’06] If the C∗-dynamical system(O+, τ |O+ , ω|O+ ) is mixing then
limt→∞
η τ tV (A) = ω+(A), (∗)
for all A ∈ O and all ω-normal states η. Moreover (O, τV , ω+) is mixing.
Remark. The scattering approach does not directly provide information on the rate ofconvergence in (∗).
ESI–June 2008 – p. 8
2.2 NESS: The Scattering Approach
C∗-scattering theory: [Hepp ’70], [Robinson ’73], [Botvich-Malyshev ’78].
NESS construction: [Dirren-Fröhlich-Graf ’98], [Ruelle ’00], [Fröhlich-Merkli-Ueltschi ’03].
τ -invariant reference state ω: ω τ tV = ω τ−t τ t
V ,
Møller morphism: γ+(A) = limt→∞
τ−t τ tV (A),
limt→∞
ω τ tV = ω γ+ = ω+
O+ ≡ Ranγ+ ⇒ (O+, τ |O+ , ω|O+ ) ∼ (O, τV , ω+)
Application to open systems. Show that:
1. (OR, τR, ωR) ≡ ⊗j>0(Oj , τj , ωβj) is mixing (the easy part).
2. γ+ exists.
3. O+ = OR (⇒ ω+ independent of ω|O0).
ESI–June 2008 – p. 8
2.2 NESS: The Scattering Approach
Strategy. Ideas from Hilbert space scattering theory.
ESI–June 2008 – p. 9
2.2 NESS: The Scattering Approach
Strategy. Ideas from Hilbert space scattering theory.
1. If α+(A) = limt→∞ τ−tV τ t(A) exists for all A ∈ OR ⇒ γ+ α+(A) = A
↓OR ⊂ O+.
ESI–June 2008 – p. 9
2.2 NESS: The Scattering Approach
Strategy. Ideas from Hilbert space scattering theory.
1. If α+(A) = limt→∞ τ−tV τ t(A) exists for all A ∈ OR ⇒ γ+ α+(A) = A
↓OR ⊂ O+.
2. Cook’s method:
τ−tV τ t(A) = A+
Z t
0
d
dsτ−sV τs(A) ds = A+
Z t
0τ−sV (i[V, τs(A)]) ds.
ESI–June 2008 – p. 9
2.2 NESS: The Scattering Approach
Strategy. Ideas from Hilbert space scattering theory.
1. If α+(A) = limt→∞ τ−tV τ t(A) exists for all A ∈ OR ⇒ γ+ α+(A) = A
↓OR ⊂ O+.
2. Cook’s method:
τ−tV τ t(A) = A+
Z t
0
d
dsτ−sV τs(A) ds = A+
Z t
0τ−sV (i[V, τs(A)]) ds.
3. If δ0 has only pure point spectrum and limt→∞ ‖[X, τ tV (A)]‖ = 0 for all X ∈ O0
↓O+ ⊂ OR.
ESI–June 2008 – p. 9
2.2 NESS: The Scattering Approach
Strategy. Ideas from Hilbert space scattering theory.
1. If α+(A) = limt→∞ τ−tV τ t(A) exists for all A ∈ OR ⇒ γ+ α+(A) = A
↓OR ⊂ O+.
2. Cook’s method:
τ−tV τ t(A) = A+
Z t
0
d
dsτ−sV τs(A) ds = A+
Z t
0τ−sV (i[V, τs(A)]) ds.
3. If δ0 has only pure point spectrum and limt→∞ ‖[X, τ tV (A)]‖ = 0 for all X ∈ O0
↓O+ ⊂ OR.
4. Schwinger-Dyson expansion
τ−t τ tV (A) = A+
X
n>0
Z
−t<tn<···<t1<0i[τ tn (V ), i[· · · , i[τ t1 (V ), A] · · · ]] dt1 · · · dtn.
ESI–June 2008 – p. 9
2.2 NESS: The Scattering Approach
Strategy. Ideas from Hilbert space scattering theory.
1. If α+(A) = limt→∞ τ−tV τ t(A) exists for all A ∈ OR ⇒ γ+ α+(A) = A
↓OR ⊂ O+.
2. Cook’s method:
τ−tV τ t(A) = A+
Z t
0
d
dsτ−sV τs(A) ds = A+
Z t
0τ−sV (i[V, τs(A)]) ds.
3. If δ0 has only pure point spectrum and limt→∞ ‖[X, τ tV (A)]‖ = 0 for all X ∈ O0
↓O+ ⊂ OR.
4. Schwinger-Dyson expansion
τ−t τ tV (A) = A+
X
n>0
Z
−t<tn<···<t1<0i[τ tn (V ), i[· · · , i[τ t1 (V ), A] · · · ]] dt1 · · · dtn.
5. CAR ⇒ diagrammatic expansion, rooted trees combinatorics.
ESI–June 2008 – p. 9
2.3 NESS: The Liouvillean Approach
[Jakšic-P ’02], [Merkli-Mueck-Sigal ’06].Work in GNS representation (Hω , πω ,Ωω) of reference state.
ESI–June 2008 – p. 10
2.3 NESS: The Liouvillean Approach
[Jakšic-P ’02], [Merkli-Mueck-Sigal ’06].Work in GNS representation (Hω , πω ,Ωω) of reference state.
Assume that the reference state ω is τ -invariant and modular (e.g. ω = ω−→β
):
πω(O)′Ωωcl
= Hω .
ESI–June 2008 – p. 10
2.3 NESS: The Liouvillean Approach
[Jakšic-P ’02], [Merkli-Mueck-Sigal ’06].Work in GNS representation (Hω , πω ,Ωω) of reference state.
Assume that the reference state ω is τ -invariant and modular (e.g. ω = ω−→β
):
πω(O)′Ωωcl
= Hω .
↓S : πω(A)Ωω 7→ πω(A∗)Ωω ,
densely defines a closable anti-linear operator on Hω .
ESI–June 2008 – p. 10
2.3 NESS: The Liouvillean Approach
[Jakšic-P ’02], [Merkli-Mueck-Sigal ’06].Work in GNS representation (Hω , πω ,Ωω) of reference state.
Assume that the reference state ω is τ -invariant and modular (e.g. ω = ω−→β
):
πω(O)′Ωωcl
= Hω .
↓S : πω(A)Ωω 7→ πω(A∗)Ωω ,
densely defines a closable anti-linear operator on Hω .
Tomita-Takesaki modular theory↓
Polar decomposition S = J∆1/2ω with ∆ω ≡ S∗S > 0.
ESI–June 2008 – p. 10
2.3 NESS: The Liouvillean Approach
[Jakšic-P ’02], [Merkli-Mueck-Sigal ’06].Work in GNS representation (Hω , πω ,Ωω) of reference state.
Assume that the reference state ω is τ -invariant and modular (e.g. ω = ω−→β
):
πω(O)′Ωωcl
= Hω .
↓S : πω(A)Ωω 7→ πω(A∗)Ωω ,
densely defines a closable anti-linear operator on Hω .
Tomita-Takesaki modular theory↓
Polar decomposition S = J∆1/2ω with ∆ω ≡ S∗S > 0.
J = J∗ = J−1: modular conjugation: J∆ωJ = ∆−1ω , Jπω(O)′′J = πω(O)′,
σtω(A) ≡ ∆it
ωA∆−itω : modular group on πω(O)′′.
ESI–June 2008 – p. 10
2.3 NESS: The Liouvillean Approach
πω(τ tV (A)) = eiLV tπω(A)e−iLV t with L∗
V Ωω = 0,
uniquely defines the C-Liouvillean LV (non-selfadjoint !).
ESI–June 2008 – p. 11
2.3 NESS: The Liouvillean Approach
πω(τ tV (A)) = eiLV tπω(A)e−iLV t with L∗
V Ωω = 0,
uniquely defines the C-Liouvillean LV (non-selfadjoint !).
LV = L+ πω(V ) − Jσi/2ω (πω(V ))J.
ESI–June 2008 – p. 11
2.3 NESS: The Liouvillean Approach
πω(τ tV (A)) = eiLV tπω(A)e−iLV t with L∗
V Ωω = 0,
uniquely defines the C-Liouvillean LV (non-selfadjoint !).
LV = L+ πω(V ) − Jσi/2ω (πω(V ))J.
Strategy: Gelfand triplet K ⊂ Hω ⊂ K′, dense subalgebra O ⊂ O s.t. πω(O)Ωω ⊂ K.
if ∃Ψ ∈ K′ s.t. w∗ − limt→∞
e−iL∗tφ = (Ψ, φ)Ωω for all φ ∈ K, (∗)⇓
limt→∞
η τ tV (A) = ω+(A) for all A ∈ O and all ω-normal state η,
ω+(A) = (Ωω , πω(A)Ψ) for A ∈ O.
ESI–June 2008 – p. 11
2.3 NESS: The Liouvillean Approach
πω(τ tV (A)) = eiLV tπω(A)e−iLV t with L∗
V Ωω = 0,
uniquely defines the C-Liouvillean LV (non-selfadjoint !).
LV = L+ πω(V ) − Jσi/2ω (πω(V ))J.
Strategy: Gelfand triplet K ⊂ Hω ⊂ K′, dense subalgebra O ⊂ O s.t. πω(O)Ωω ⊂ K.
if ∃Ψ ∈ K′ s.t. w∗ − limt→∞
e−iL∗tφ = (Ψ, φ)Ωω for all φ ∈ K, (∗)⇓
limt→∞
η τ tV (A) = ω+(A) for all A ∈ O and all ω-normal state η,
ω+(A) = (Ωω , πω(A)Ψ) for A ∈ O.
Under sufficient regularity assumptions on V spectral deformation techniques allow tocontrol resonances of L and prove (∗).
ESI–June 2008 – p. 11
2.3 NESS: The Liouvillean Approach
sp(L∗|K) sp(e−itL∗
|K)
0
1
ESI–June 2008 – p. 12
2.3 NESS: The Liouvillean Approach
sp(L∗|K) sp(e−itL∗
|K)
0
1
Imaginary part of resonances control rate of convergence
|η τ tV (A) − ω+(A)| ≃ e−γt
ESI–June 2008 – p. 12
3. Entropy Production
Φj = energy flux out of Rj = −rate of change of energy in Rj .
ESI–June 2008 – p. 13
3. Entropy Production
Φj = energy flux out of Rj = −rate of change of energy in Rj .Total energy is conserved:
X
j>0
Φj =d
dtτ tV (H0 + V )
˛
˛
˛
˛
t=0
=X
j>0
δj(H0 + V ) + i[H0, H0 + V ] + i[V,H0 + V ].
ESI–June 2008 – p. 13
3. Entropy Production
Φj = energy flux out of Rj = −rate of change of energy in Rj .
X
j>0
Φj =d
dtτ tV (H0 + V )
˛
˛
˛
˛
t=0
=X
j>0
δj(V ).
ESI–June 2008 – p. 13
3. Entropy Production
Φj = energy flux out of Rj = −rate of change of energy in Rj .
X
j>0
Φj =d
dtτ tV (H0 + V )
˛
˛
˛
˛
t=0
=X
j>0
δj(V ).
Φj = δj(V ) = δj(Vj).
ESI–June 2008 – p. 13
3. Entropy Production
Φj = energy flux out of Rj = −rate of change of energy in Rj .
X
j>0
Φj =d
dtτ tV (H0 + V )
˛
˛
˛
˛
t=0
=X
j>0
δj(V ).
Φj = δj(V ) = δj(Vj).
Steady state entropy production rate = − total entropy flux
Ep(ω−→β
+) ≡ ω−→β
+(σ), σ ≡ −X
j>0
βjΦj .
The observable σ plays in this context a similar role as the phase-space contraction ratein dissipative classical dynamical systems.
ESI–June 2008 – p. 13
3. Entropy Production
Φj = energy flux out of Rj = −rate of change of energy in Rj .
X
j>0
Φj =d
dtτ tV (H0 + V )
˛
˛
˛
˛
t=0
=X
j>0
δj(V ).
Φj = δj(V ) = δj(Vj).
Steady state entropy production rate = − total entropy flux
Ep(ω−→β
+) ≡ ω−→β
+(σ), σ ≡ −X
j>0
βjΦj .
Theorem. [Ruelle ’01], [Jakšic-P ’01] If η is ω−→β
-normal then
Ep(ω−→β
+) = − limt→∞
Ent(η τ tV |ω−→
β)
t≥ 0.
ESI–June 2008 – p. 13
3. Entropy Production
Φj = energy flux out of Rj = −rate of change of energy in Rj .
X
j>0
Φj =d
dtτ tV (H0 + V )
˛
˛
˛
˛
t=0
=X
j>0
δj(V ).
Φj = δj(V ) = δj(Vj).
Steady state entropy production rate = − total entropy flux
Ep(ω−→β
+) ≡ ω−→β
+(σ), σ ≡ −X
j>0
βjΦj .
Basic Problem 2. Strict positivity of entropy production
Ep(ω−→β
+) > 0.
ESI–June 2008 – p. 13
3. Entropy Production
Φj = energy flux out of Rj = −rate of change of energy in Rj .
X
j>0
Φj =d
dtτ tV (H0 + V )
˛
˛
˛
˛
t=0
=X
j>0
δj(V ).
Φj = δj(V ) = δj(Vj).
Steady state entropy production rate = − total entropy flux
Ep(ω−→β
+) ≡ ω−→β
+(σ), σ ≡ −X
j>0
βjΦj .
Theorem. [Jakšic-P ’02] If Ep(ω−→β
+) > 0 then ω−→β
+ is not ω−→β
-normal. Reciproquely, if
ω−→β
+ is not ω−→β
-normal and
lim supt→∞
˛
˛
˛
˛
Z t
0
“
ω−→β
τsV (σ) − ω−→
β+(σ)
”
ds
˛
˛
˛
˛
<∞,
then Ep(ω−→β
+) > 0.
ESI–June 2008 – p. 13
4. Linear Response
−→β equ = (β, β, . . . , β).
ω−→β
+ = limt→∞
ω−→β
τ tV , (|−→β −−→
β equ| < ǫ ).
Transport coefficients (Onsager matrix):Lkj = −∂βj
ω−→β
+(Φk)|−→β =
−→β equ
.
ESI–June 2008 – p. 14
4. Linear Response
−→β equ = (β, β, . . . , β).
ω−→β
+ = limt→∞
ω−→β
τ tV , (|−→β −−→
β equ| < ǫ ).
Transport coefficients (Onsager matrix):Lkj = −∂βj
ω−→β
+(Φk)|−→β =
−→β equ
.
Basic Problems 3.
ESI–June 2008 – p. 14
4. Linear Response
−→β equ = (β, β, . . . , β).
ω−→β
+ = limt→∞
ω−→β
τ tV , (|−→β −−→
β equ| < ǫ ).
Transport coefficients (Onsager matrix):Lkj = −∂βj
ω−→β
+(Φk)|−→β =
−→β equ
.
Basic Problems 3.
• Existence: ω−→β
depends singularly on−→β .
ESI–June 2008 – p. 14
4. Linear Response
−→β equ = (β, β, . . . , β).
ω−→β
+ = limt→∞
ω−→β
τ tV , (|−→β −−→
β equ| < ǫ ).
Transport coefficients (Onsager matrix):Lkj = −∂βj
ω−→β
+(Φk)|−→β =
−→β equ
.
Basic Problems 3.
• Existence: ω−→β
depends singularly on−→β .
• Green-Einstein-Kubo Formula (1):
Lkj = β−1
Z β
0dθ
Z ∞
0dt ω−→
β equ
(τ t(Φk)τ iθ(Φj)).
ESI–June 2008 – p. 14
4. Linear Response
−→β equ = (β, β, . . . , β).
ω−→β
+ = limt→∞
ω−→β
τ tV , (|−→β −−→
β equ| < ǫ ).
Transport coefficients (Onsager matrix):Lkj = −∂βj
ω−→β
+(Φk)|−→β =
−→β equ
.
Basic Problems 3.
• Existence: ω−→β
depends singularly on−→β .
• Green-Einstein-Kubo Formula (1):
Lkj = β−1
Z β
0dθ
Z ∞
0dt ω−→
β equ
(τ t(Φk)τ iθ(Φj)).
• Green-Einstein-Kubo Formula (2): Lkj =1
2
Z ∞
−∞
dt ω−→β equ
(Φkτt(Φj)).
ESI–June 2008 – p. 14
4. Linear Response
−→β equ = (β, β, . . . , β).
ω−→β
+ = limt→∞
ω−→β
τ tV , (|−→β −−→
β equ| < ǫ ).
Transport coefficients (Onsager matrix):Lkj = −∂βj
ω−→β
+(Φk)|−→β =
−→β equ
.
Basic Problems 3.
• Existence: ω−→β
depends singularly on−→β .
• Green-Einstein-Kubo Formula (1):
Lkj = β−1
Z β
0dθ
Z ∞
0dt ω−→
β equ
(τ t(Φk)τ iθ(Φj)).
• Green-Einstein-Kubo Formula (2): Lkj =1
2
Z ∞
−∞
dt ω−→β equ
(Φkτt(Φj)).
• Onsager reciprocity relations: Lkj = Ljk.
ESI–June 2008 – p. 14
4. Linear Response
−→β equ = (β, β, . . . , β).
ω−→β
+ = limt→∞
ω−→β
τ tV , (|−→β −−→
β equ| < ǫ ).
Transport coefficients (Onsager matrix):Lkj = −∂βj
ω−→β
+(Φk)|−→β =
−→β equ
.
Basic Problems 3.
• Existence: ω−→β
depends singularly on−→β .
• Green-Einstein-Kubo Formula (1):
Lkj = β−1
Z β
0dθ
Z ∞
0dt ω−→
β equ
(τ t(Φk)τ iθ(Φj)).
• Green-Einstein-Kubo Formula (2): Lkj =1
2
Z ∞
−∞
dt ω−→β equ
(Φkτt(Φj)).
• Onsager reciprocity relations: Lkj = Ljk.
Remark. Order of limits: 1st thermodynamic limit, 2nd long time limit, 3rd weak forcinglimit.
ESI–June 2008 – p. 14
5. Quantum Dynamical Central Limit Theorem
[Hepp-Lieb ’73], [Derezinski ’ 85], [Goderis-Verbeure-Vets ’88], [Matsui ’02]
ESI–June 2008 – p. 15
5. Quantum Dynamical Central Limit Theorem
[Hepp-Lieb ’73], [Derezinski ’ 85], [Goderis-Verbeure-Vets ’88], [Matsui ’02]
C ⊂ O real subspace of self-adjoint elements is CLT-admissible ifZ ∞
−∞
|ω−→β
+(Aτ tV (B)) − ω−→
β+(A)ω−→
β+(B)| dt <∞ for A,B ∈ C.
ESI–June 2008 – p. 15
5. Quantum Dynamical Central Limit Theorem
[Hepp-Lieb ’73], [Derezinski ’ 85], [Goderis-Verbeure-Vets ’88], [Matsui ’02]
C ⊂ O real subspace of self-adjoint elements is CLT-admissible ifZ ∞
−∞
|ω−→β
+(Aτ tV (B)) − ω−→
β+(A)ω−→
β+(B)| dt <∞ for A,B ∈ C.
At ≡ 1√t
Z t
0(τs
V (A) − ω−→β
+(A)) ds,
L(A,B) ≡Z ∞
−∞
“
ω−→β
+(Aτ tV (B)) − ω−→
β+(A)ω−→
β+(B)
”
dt.
ESI–June 2008 – p. 15
5. Quantum Dynamical Central Limit Theorem
[Hepp-Lieb ’73], [Derezinski ’ 85], [Goderis-Verbeure-Vets ’88], [Matsui ’02]
C ⊂ O real subspace of self-adjoint elements is CLT-admissible ifZ ∞
−∞
|ω−→β
+(Aτ tV (B)) − ω−→
β+(A)ω−→
β+(B)| dt <∞ for A,B ∈ C.
At ≡ 1√t
Z t
0(τs
V (A) − ω−→β
+(A)) ds,
L(A,B) ≡Z ∞
−∞
“
ω−→β
+(Aτ tV (B)) − ω−→
β+(A)ω−→
β+(B)
”
dt.
Symplectic form on C: ς(A,B) ≡ 1
2i
Z ∞
−∞
ω−→β
+([τ tV (A), B]) dt.
ESI–June 2008 – p. 15
5. Quantum Dynamical Central Limit Theorem
[Hepp-Lieb ’73], [Derezinski ’ 85], [Goderis-Verbeure-Vets ’88], [Matsui ’02]
C ⊂ O real subspace of self-adjoint elements is CLT-admissible ifZ ∞
−∞
|ω−→β
+(Aτ tV (B)) − ω−→
β+(A)ω−→
β+(B)| dt <∞ for A,B ∈ C.
At ≡ 1√t
Z t
0(τs
V (A) − ω−→β
+(A)) ds,
L(A,B) ≡Z ∞
−∞
“
ω−→β
+(Aτ tV (B)) − ω−→
β+(A)ω−→
β+(B)
”
dt.
Symplectic form on C: ς(A,B) ≡ 1
2i
Z ∞
−∞
ω−→β
+([τ tV (A), B]) dt.
Fluctuation Algebra W: C ∋ A 7→W (A) s.t.:
W (−A) = W (A)∗ and W (A)W (B) = e−iς(A,B)/2W (A+B).
W = CCR-algebra over (C, ς).
ESI–June 2008 – p. 15
5. Quantum Dynamical Central Limit Theorem
[Hepp-Lieb ’73], [Derezinski ’ 85], [Goderis-Verbeure-Vets ’88], [Matsui ’02]
C ⊂ O real subspace of self-adjoint elements is CLT-admissible ifZ ∞
−∞
|ω−→β
+(Aτ tV (B)) − ω−→
β+(A)ω−→
β+(B)| dt <∞ for A,B ∈ C.
At ≡ 1√t
Z t
0(τs
V (A) − ω−→β
+(A)) ds,
L(A,B) ≡Z ∞
−∞
“
ω−→β
+(Aτ tV (B)) − ω−→
β+(A)ω−→
β+(B)
”
dt.
Symplectic form on C: ς(A,B) ≡ 1
2i
Z ∞
−∞
ω−→β
+([τ tV (A), B]) dt.
Fluctuation Algebra W: C ∋ A 7→W (A) s.t.:
W (−A) = W (A)∗ and W (A)W (B) = e−iς(A,B)/2W (A+B).
W = CCR-algebra over (C, ς).
Quasi-free state µL(W (A)) = e−L(A,A)/2
⇓regular GNS representation (HL, πL,ΩL) with πL(W (A)) = eiφL(A).
ESI–June 2008 – p. 15
5. Quantum Dynamical Central Limit Theorem
Basic Problem 4. Simple Quantum Dynamical CLT:
limt→∞
ω−→β
+“
eiAt
”
= e−L(A,A)/2, for any A ∈ C.
ESI–June 2008 – p. 16
5. Quantum Dynamical Central Limit Theorem
Basic Problem 4. Simple Quantum Dynamical CLT:
limt→∞
ω−→β
+“
eiAt
”
= e−L(A,A)/2, for any A ∈ C.
Theorem. [Jakšic-Pautrat-P ’07] If SQD-CLT holds for C andZ ∞
−∞
‖[A, τ tV (B)]‖ dt <∞
for A,B ∈ C then the Quantum Dynamical CLT
limt→∞
ω−→β
+“
eiA1t · · · eiAnt
”
=
exp
0
@−1
2L
0
@
nX
j=1
Aj ,
nX
j=1
Aj
1
A − iX
1≤j<k≤n
ς(Aj , Ak)
1
A ,
holds too.
ESI–June 2008 – p. 16
5. Quantum Dynamical Central Limit Theorem
Basic Problem 4. Simple Quantum Dynamical CLT:
limt→∞
ω−→β
+“
eiAt
”
= e−L(A,A)/2, for any A ∈ C.
Theorem. [Jakšic-Pautrat-P ’07] If SQD-CLT holds for C andZ ∞
−∞
‖[A, τ tV (B)]‖ dt <∞
for A,B ∈ C then the Quantum Dynamical CLT
limt→∞
ω−→β
+“
eiA1t · · · eiAnt
”
=
exp
0
@−1
2L
0
@
nX
j=1
Aj ,
nX
j=1
Aj
1
A − iX
1≤j<k≤n
ς(Aj , Ak)
1
A ,
holds too.
Theorem. [Jakšic-Pautrat-P ’07] If QD-CLT holds for C then
limt→∞
ω−→β
+“
f1(A1t) · · · fn(Ant)”
= µL(f1(φL(A1)) · · · fn(φL(An))),
holds for all bounded Borel functions f1, . . . , fn.
ESI–June 2008 – p. 16
7. Models
Classified by techniques:
ESI–June 2008 – p. 17
7. Models
Classified by techniques:
• Quasifree fermions/bosons and XY spin chains (→ independent particlesmodels): C∗- scattering reduces to Hilbert space scattering leading toLandauer-Büttiker formalism,[Araki-Ho ’00], [Aschbacher-P ’02], [Avron-Elgart-Graf-Sadun-Schnee ’02],[Cornean-Jensen-Moldoveanu ’04], [Barbaroux-Aschbacher ’06],[Aschbacher-Jakšic-Pautrat-P ’07], [Nenciu ’07], [Avron-Bachmann-Graf-Klich ’07].
ESI–June 2008 – p. 17
7. Models
Classified by techniques:
• Quasifree fermions/bosons and XY spin chains (→ independent particlesmodels): C∗- scattering reduces to Hilbert space scattering leading toLandauer-Büttiker formalism,[Araki-Ho ’00], [Aschbacher-P ’02], [Avron-Elgart-Graf-Sadun-Schnee ’02],[Cornean-Jensen-Moldoveanu ’04], [Barbaroux-Aschbacher ’06],[Aschbacher-Jakšic-Pautrat-P ’07], [Nenciu ’07], [Avron-Bachmann-Graf-Klich ’07].
• N -level system coupled to ideal quantum gases: Liouvillean approach,[Jakšic-P ’02], [Abou Salem-Fröhlich ’05], [Merkli-Mueck-Sigal ’06].
ESI–June 2008 – p. 17
7. Models
Classified by techniques:
• Quasifree fermions/bosons and XY spin chains (→ independent particlesmodels): C∗- scattering reduces to Hilbert space scattering leading toLandauer-Büttiker formalism,[Araki-Ho ’00], [Aschbacher-P ’02], [Avron-Elgart-Graf-Sadun-Schnee ’02],[Cornean-Jensen-Moldoveanu ’04], [Barbaroux-Aschbacher ’06],[Aschbacher-Jakšic-Pautrat-P ’07], [Nenciu ’07], [Avron-Bachmann-Graf-Klich ’07].
• N -level system coupled to ideal quantum gases: Liouvillean approach,[Jakšic-P ’02], [Abou Salem-Fröhlich ’05], [Merkli-Mueck-Sigal ’06].
• Quantum spin systems: C∗ scattering approach,[Ruelle ’00].
ESI–June 2008 – p. 17
7. Models
Classified by techniques:
• Quasifree fermions/bosons and XY spin chains (→ independent particlesmodels): C∗- scattering reduces to Hilbert space scattering leading toLandauer-Büttiker formalism,[Araki-Ho ’00], [Aschbacher-P ’02], [Avron-Elgart-Graf-Sadun-Schnee ’02],[Cornean-Jensen-Moldoveanu ’04], [Barbaroux-Aschbacher ’06],[Aschbacher-Jakšic-Pautrat-P ’07], [Nenciu ’07], [Avron-Bachmann-Graf-Klich ’07].
• N -level system coupled to ideal quantum gases: Liouvillean approach,[Jakšic-P ’02], [Abou Salem-Fröhlich ’05], [Merkli-Mueck-Sigal ’06].
• Quantum spin systems: C∗ scattering approach,[Ruelle ’00].
• Locally interacting Fermi gases: C∗ scattering approach,[Dirren-Fröhlich-Graf ’89], [Fröhlich-Merkli-Ueltschi ’03], [Jakšic-Ogata-Pautrat-P’06].
ESI–June 2008 – p. 17
7. Models
Classified by techniques:
• Quasifree fermions/bosons and XY spin chains (→ independent particlesmodels): C∗- scattering reduces to Hilbert space scattering leading toLandauer-Büttiker formalism,[Araki-Ho ’00], [Aschbacher-P ’02], [Avron-Elgart-Graf-Sadun-Schnee ’02],[Cornean-Jensen-Moldoveanu ’04], [Barbaroux-Aschbacher ’06],[Aschbacher-Jakšic-Pautrat-P ’07], [Nenciu ’07], [Avron-Bachmann-Graf-Klich ’07].
• N -level system coupled to ideal quantum gases: Liouvillean approach,[Jakšic-P ’02], [Abou Salem-Fröhlich ’05], [Merkli-Mueck-Sigal ’06].
• Quantum spin systems: C∗ scattering approach,[Ruelle ’00].
• Locally interacting Fermi gases: C∗ scattering approach,[Dirren-Fröhlich-Graf ’89], [Fröhlich-Merkli-Ueltschi ’03], [Jakšic-Ogata-Pautrat-P’06].
• Repeated interactions: Liouvillean approach [Attal-Pautrat ’06],[Bruneau-Joye-Merkli ’06], [Attal-Joye ’07].
ESI–June 2008 – p. 17
Example 1: The Spin-Fermion Model
Simplest example of N -level system coupled to ideal quantum gases.
ESI–June 2008 – p. 18
Example 1: The Spin-Fermion Model
Simplest example of N -level system coupled to ideal quantum gases.
S is a 2-level system: O0 = Mat(2,C), τ t0(A) = eitH0Ae−itH0 , H0 = σz .
ESI–June 2008 – p. 18
Example 1: The Spin-Fermion Model
Simplest example of N -level system coupled to ideal quantum gases.
S is a 2-level system: O0 = Mat(2,C), τ t0(A) = eitH0Ae−itH0 , H0 = σz .
Rj is a free Fermi gas: One particle Hilbert space hj and Hamiltonian hj .Oj = CAR(hj), C∗ algebra generated by creation/annihilation operators aj(f), a∗j (f),
f ∈ hj .
τ tj (aj(f)) = aj(e
ithj f) Bogoliubov automorphism.
ESI–June 2008 – p. 18
Example 1: The Spin-Fermion Model
Simplest example of N -level system coupled to ideal quantum gases.
S is a 2-level system: O0 = Mat(2,C), τ t0(A) = eitH0Ae−itH0 , H0 = σz .
Rj is a free Fermi gas: One particle Hilbert space hj and Hamiltonian hj .Oj = CAR(hj), C∗ algebra generated by creation/annihilation operators aj(f), a∗j (f),
f ∈ hj .
τ tj (aj(f)) = aj(e
ithj f) Bogoliubov automorphism.
Coupling Vj = λσx ⊗ (a(αj) + a∗(αj)), αj ∈ hj .
ESI–June 2008 – p. 18
Example 1: The Spin-Fermion Model
Simplest example of N -level system coupled to ideal quantum gases.
S is a 2-level system: O0 = Mat(2,C), τ t0(A) = eitH0Ae−itH0 , H0 = σz .
Rj is a free Fermi gas: One particle Hilbert space hj and Hamiltonian hj .Oj = CAR(hj), C∗ algebra generated by creation/annihilation operators aj(f), a∗j (f),
f ∈ hj .
τ tj (aj(f)) = aj(e
ithj f) Bogoliubov automorphism.
Coupling Vj = λσx ⊗ (a(αj) + a∗(αj)), αj ∈ hj .
Assumptions. For all j’s:
(A1) hj = L2(R+, ds) ⊗ Kj and hj = s (spectral representation).
(A2) For some δ > 0 and all a: e−asαj(|s|) ∈ H2(|Ims| < δ) ⊗ Kj (analyticity).
(A3) ‖αj(2)‖Kj6= 0 (effective coupling).
ESI–June 2008 – p. 18
Example 1: The Spin-Fermion Model
Assumptions. For all j’s:
(A1) hj = L2(R+, ds) ⊗ Kj and hj = s (spectral representation).
(A2) For some δ > 0 and all a: e−asαj(|s|) ∈ H2(|Ims| < δ) ⊗ Kj (analyticity).
(A3) ‖αj(2)‖Kj6= 0 (effective coupling).
ESI–June 2008 – p. 19
Example 1: The Spin-Fermion Model
Assumptions. For all j’s:
(A1) hj = L2(R+, ds) ⊗ Kj and hj = s (spectral representation).
(A2) For some δ > 0 and all a: e−asαj(|s|) ∈ H2(|Ims| < δ) ⊗ Kj (analyticity).
(A3) ‖αj(2)‖Kj6= 0 (effective coupling).
Theorem. [Jakšic-P ’02], [Jakšic-Ogata-P, ’06] Assume (A1)-(A3) and let 0 < γ1 < γ2 begiven. Then there exists Λ > 0 such that, for all 0 < |λ| < Λ and γ1 < βj < γ2:
1. There exists a NESS ω−→β
+.
2. If the βj ’s are not all equal then ω−→β
+ is not ω−→β
-normal and Ep(ω−→β
+) > 0.
3. The Green-Einstein-Kubo formulas (1) and (2) hold as well as the Onsagerreciprocity relations.
ESI–June 2008 – p. 19
Example 2: Locally Interacting Fermi Gases
R1 R3
R2
Intera tion regionESI–June 2008 – p. 20
Example 2: Locally Interacting Fermi Gases
No small system S (included in reservoirs).
ESI–June 2008 – p. 20
Example 2: Locally Interacting Fermi Gases
No small system S (included in reservoirs).Rj is a free Fermi gas: One particle Hilbert space hj and Hamiltonian hj .
Oj = CAR(hj), C∗ algebra generated by creation/annihilation operators aj(f), a∗j (f),
f ∈ hj .
τ tj (aj(f)) = aj(e
ithj f) Bogoliubov automorphism.
ESI–June 2008 – p. 20
Example 2: Locally Interacting Fermi Gases
No small system S (included in reservoirs).Rj is a free Fermi gas: One particle Hilbert space hj and Hamiltonian hj .
Oj = CAR(hj), C∗ algebra generated by creation/annihilation operators aj(f), a∗j (f),
f ∈ hj .
τ tj (aj(f)) = aj(e
ithj f) Bogoliubov automorphism.
Gauge-invariant coupling/interaction
V = λ
KX
k=1
nkY
j=1
a∗(ujk)a(vjk).
ESI–June 2008 – p. 20
Example 2: Locally Interacting Fermi Gases
No small system S (included in reservoirs).Rj is a free Fermi gas: One particle Hilbert space hj and Hamiltonian hj .
Oj = CAR(hj), C∗ algebra generated by creation/annihilation operators aj(f), a∗j (f),
f ∈ hj .
τ tj (aj(f)) = aj(e
ithj f) Bogoliubov automorphism.
Gauge-invariant coupling/interaction
V = λ
KX
k=1
nkY
j=1
a∗(ujk)a(vjk).
Assumptions. Set h ≡ ⊕jhj , h ≡ ⊕jhj and D0 ≡ ujk, vjk:
(B1) There is a dense subspace D ⊂ h containing D0 and such thatZ ∞
−∞
|(f, eithg)| dt <∞,
for all f, g ∈ D.
(B2) hD0 ⊂ D.
(B3) There is a complex conjugation on h which commute with h and such that ujk, vjk
are real (Time reversal invariance).
ESI–June 2008 – p. 20
Example 2: Locally Interacting Fermi Gases
Assumptions. Set h ≡ ⊕jhj , h ≡ ⊕jhj and D0 ≡ ujk, vjk:
(B1) There is a dense subspace D ⊂ h containing D0 and such thatZ ∞
−∞
|(f, eithg)| dt <∞,
for all f, g ∈ D.
(B2) hD0 ⊂ D.
(B3) There is a complex conjugation on h which commute with h and such that ujk, vjk
are real (Time reversal invariance).
ESI–June 2008 – p. 21
Example 2: Locally Interacting Fermi Gases
Assumptions. Set h ≡ ⊕jhj , h ≡ ⊕jhj and D0 ≡ ujk, vjk:
(B1) There is a dense subspace D ⊂ h containing D0 and such thatZ ∞
−∞
|(f, eithg)| dt <∞,
for all f, g ∈ D.
(B2) hD0 ⊂ D.
(B3) There is a complex conjugation on h which commute with h and such that ujk, vjk
are real (Time reversal invariance).
Theorem. [Jakšic-Ogata-P ’06], [Jakšic-Pautrat-P ’07] If (B1) holds then there exists Λ > 0
such that, for 0 < |λ| < Λ:
1. There exists a NESS ω−→β
+.
2. If (B2) also holds then the Green-Einstein-Kubo formula (1) holds.
3. If, in addition, (B3) holds then the Green-Einstein-Kubo formula (2) and theOnsager reciprocity relations hold. Moreover QDCLT holds for C = Φ1,Φ2, . . ..
ESI–June 2008 – p. 21