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BASF - The Chemical CompanyMaterialSafetyDataSheet

MSDS code: HLG130F

Revision date: 11/01/06

Other Information:NOTE:The percentage byweightvalues reportedforthis productrepresent approximateformulationvalues.

Emergency Overview:Color:Form:Odor:Flash Point, °C:

RedLiquidTerpene Odor.48

Most Important Hazards: Prolonged or repeated exposure effects: May cause liver and kidney damage. Maycause lung damage. May affect the blood and blood system. May cause central nervous system depression.Symptoms include: nausea, drowsiness, dizziness, headache, weakness, tremors and loss of consciousness.Harmful if swallowed. May cause pain, nausea, vomiting and diarrhea. May cause loss of consciousness. Aspiration(breathing) of vomitus into lungs may result in pneumonitis. Irritatingto eyes, respiratory system and skin. Maycause an allergic skin reaction. May cause allergic respiratory reactions. Water willcause an exothermic reactionand the release of butanol.

Potential Health Effects:Inhalation:

Ingestion:

Causes respiratory tract irritation.Exposure to high concentrations may result incentral nervous system depression. Symptoms include: nausea, drowsiness,dizziness, headache, weakness, tremors and loss of consciousness.

May cause pain, nausea, vomiting and diarrhea. May cause central nervous systemdepression. Symptoms include: nausea, drowsiness, dizziness, headache,weakness, tremors and loss of consciousness.

Causes skin irritation. Prolonged contact may cause dermatitis. Prolonged orrepeated contact may cause skin absorption. May cause an allergic skin reaction.

Causes eye irritation.May cause corneal injury.

Skin Contact:

Eye Contact:

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Ingredient Weight in Percent (%) NotesCASNumber

Turpentine 20-30 None.8006-64-2

EssentialOils 20-30 None.

Terpineol 5-15 None.8000-41-7

Cyclohexanone 1-5 None.108-94-1

Tetra ButylTitanate 1-5 None.5593-70-4

EthylAcetate 1-5 None.141-78-6

MineralSpirits 1-5 None.8052-41-3

Rosin 5-10 None.

Metallo-OrganicBismuth 5-10 None.Compounds

BASF -The Chemical CompanyMaterialSafetyDataSheet

MSDS code: HLG130F


Other Effects: NOTE: Ingestion of the product may result in vomiting. Aspiration (breathing) of thevomitus into the lungs must be avoided as even small quantities may result inaspiration pneumonitis.

Carcinogenicity:

Notes:IARC: Y1=Carcinogenic to humans; Y2A=Probably carcinogenic to humans; Y2B=Possibly carcinogenic to humans; N3=Not classifiable as to itscarcinogenicity; N=Not studied or probably not carcinogenic.ACGIH: A1=Confirmed human carcinogen; A2=Suspected human carcinogen; A3=Confirmed animal carcinogen; A4=Not classifiable as a humancarcinogen; A5=Not suspected as a human carcinogen; N=Not studied.

May cause liver and kidney damage. Prolonged or repeated exposure may causelung damage. May affect the blood and blood system. May cause sensitization byinhalation and skin contact.

Aggravated Medical Conditions: Eye ailments. Dermal ailments. Respiratory. Blood disorders. Kidney disorders. Liverdisorders.

Chronic Health Hazards:

Inhalation: Move person to fresh air. Aid in breathing, if necessary, and get immediate medicalattention.

Ingestion: Get medical attention! If vomiting occurs, keep head lower than hips to preventaspiration.

Flush area with water while removing contaminated clothing and shoes. Wash withsoap and water. Clean contaminated clothing and shoes before reuse. Get medicalattention if irritation persists.

In case of contact, or suspected contact, immediately flush eyes with plenty of waterfor at least 15 minutes and get medical attention immediately after flushing.

Skin Contact:

Eye Contact:

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Ingredient Weight in NTP IARC OSHA ACGIHCAS Number Percent (Y/N) (See Notes) (Y/N) (See Notes)

(%)Turpentine 20-30 N N N A48006-64-2

Essential Oils 20-30 N N N N

Terpineol 5-15 N N N N8000-41-7

Cyclohexanone 1-5 N N3 N A3108-94-1

Tetra ButylTitanate 1-5 N N N N5593-70-4

EthylAcetate 1-5 N N N A4141-78-6

MineralSpirits 1-5 N N N N8052-41-3

Rosin 5-10 N N N N

Metallo-OrganicBismuth 5-10 N N N N

Compounds


MSDS code: HLG130F


Flash Point, °c:Autoignition Temperature, °c:Lower Explosive Limit,%:Upper Explosive Limit,%:

48Not DeterminedNot DeterminedNot Determined

Extinguishing Media:

Fire Fighting Procedures:

Unusual Fire and ExplosionHazards:

Water mist. Carbon dioxide. Drychemical. Foam.

Positive pressure, self-contained breathing apparatus. Wear fullprotective clothing.

Combustible liquid.Toxic vapors are emitted in a fire condition.

Spill Procedures: Contain spillage. Soak up spillusing an absorbent. Scoop into a suitable container.

Avoid contact with heat, sparks, open flame and static discharge.Keep container closed.Store in a cool, dry location away from incompatible materials.Do not eat, drink or smoke when using.Use only with adequate ventilation.Do not inhale vapors.Do not breathe mist.Wash thoroughly after handling.

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MSDS code: HLG130F


Unless otherwise noted, all values are reported as 8-hour Time-Weighted Averages (TWAs) and total dust (particulatesonly). All ACGIH TLVs refer to the 2006 standards. Unless otherwise noted, all OSHA PELs refer to 29CFR Part 1910 AirContaminants: Final Rule, June 30, 1993.

Personal Protective Equipment: Safety glasses with side shields. Wear suitable gloves. Wear clean, body-coveringclothing.

Respiratory Protection: Use approved respiratory protection if exposure limits are exceeded, oroverexposure is likely.

General ventilation. Local exhaust ventilation is recommended to control exposuresto within applicable limits.

Ventilation:

Form:Color:Odor:

LiquidRedTerpeneOdor.

Specific Gravity:Solubility (in water):pH:

0.98InsolubleNot Determined

Stability Data:

Conditions/Hazards to Avoid:

Stable

Incompatibility (Materialsto Avoid):

Avoid contact with heat, sparks, open flame, and staticdischarge.

Strong acids or alkalies. Strong oxidizing agents. Reactswith water to form n-butanol.

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Ingredient Weight in OSHA PEL ACGIH TLVCAS Number Percent

(%)Turpentine 20-30 100ppm 20 ppm Sensitizer8006-64-2

EssentialOils 20-30 NoneEstablished NoneEstablished

Terpineol 5-15 NoneEstablished NoneEstablished8000-41-7

Cyclohexanone 1-5 50 ppm 20 ppm108-94-1 50 ppm STELSKIN

T.etraButylTitanate 1-5 NoneEstablished None Established5593-70-4

EthylAcetate 1-5 400 ppm 400 ppm141-78-6

MineralSpirits 1-5 100 ppm 100 ppm8052-41-3

Rosin 5-10 NoneEstablished NoneEstablished

Metallo-OrganicBismuth 5-10 NoneEstablished NoneEstablished

Compounds

BASF .-The Chemical CompanyMaterialSafety Data Sheet

MSDS code: HLG130F


Hazardous Decomposition Products:

Polymerization:

Polymerization -Avoid:

Oxides of carbon. Metal oxide fumes.

None anticipated.

None anticipated.

<.

Information on Product:Nodata available.

Information on Components:

Information on Product:Environmental Fate:

Ecotoxicologicallnforination:

No data available.

No data available.

US EPAWaste Number: 0001

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Ingredient Weight in Acute Toxicity . Acute Toxicity- Acute Toxicity - Acute Toxicity-CAS Number Percent Oral Inhalation Dermal Other

t%)Turpentine 20-30 5,760 mg/kg (rat) 12,000 mg/m3/6 < NotAvailable Not Available8006-64-2 hr (rat)

Essential Oils 20-30 NotAvailable Not Available Not Available Not Available

Terpineol 5-15 NotAvailable Not Available Not Available 2,000 mg/kg8000-41-7 intraperitoneal

< (mouse)

Cyclohexanone 1-5 NotAvailable 8,000 ppm 14hr 948 mg/kg Not Available108-94-1 (rat) (rabbit)

Tetra ButylTitanate 1-5 3,122 mg/kg (rat) Not Available Not Available Not Available5593-70-4

Ethyl Acetate 1-5 5,600 mg/kg(rat) 1,600 ppm 18hr Not Available Not Available141-78-6 (rat)

Mineral Spirits 1-5 > 5,000 mg/kg Not Available Not Available Not Available8052-41-3 (rat)

Rosin 5-10 NotAvailable Not Available Not Available Not Available

Metallo-Organic Bismuth 5-10 Not Available Not Available Not Available Not AvailableCompounds


MSDS code: HLG130F


Disposal of Waste Method: Local disposal laws and regulations willdetermine the proper wastedisposal/recycling/reclamation procedure. Disposal requirements are dependent on the hazard classification and willvaryby location and the type of disposal selected. Allwaste materials should be reviewed to determine the applicable hazards(testing may be necessary).

- ...

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International Transport Regulations:ICAOClass: NotRegulated

IMOClass:

US Transportation Regulations:UN/NA/PINNumber:DOTClassification:Proper Shipping Name:Packing Group:

Not Regulated

UN19933 Flammable liquidFlammable liquids, n.o.s. (Contains Turpentine)III

Canadian Transportation of Dangerous Goods (TDG):TDGClassification: 3 Flammableliquid

International Inventories:United States:Canada:Europe:Japan:Australia:Korea:Philippines:China:

US Federal Regulations:

This product or its ingredients are listed on or compliant with the TSCA Inventory.This product or one or more of its ingredients are NOT REGISTERED in Canada.Not DeterminedNot DeterminedNot DeterminedNot DeterminedNot DeterminedNot Determined

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BASF - The Chemical CompanyMaterialSafety Data Sheet

MSDScode: HLG130F


SARA311/312 Hazard Categories:AcuteHealthHazard ChronicHealthHazard Fire Hazard

CAA602 Ozone Depleting Substances (ODS):This productneithercontainsnor is manufacturedwith an ozonedepletingsubstancesubjectto the labelingrequirementsof the CleanAir Act Amendments1990 and40 CFR Part 82.

VOC Content: Not Determined

US State Regulations:California Proposition 65 -Carcinogen:WARNING: This product contains chemicals known to the State of California to cause cancer.

VOC Content (CARB): Not Determined

Canadian Regulations:WHMISClassification:Class B Division 3Class D Division 2 Subdivision AClass D Division 2 Subdivision B

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Ingredient Weight in Percent (%) Subject to SARA 313 ReportingCAS Number

Turpentine 20-30 No8006-64-2

EssentialOils 20-30 No

Terpineol 5-15 No8000-41-7

Cyclohexanone 1-5 No108-94-1

Tetra ButylTitanate 1-5 No5593-70-4

EthylAcetate 1-5 No141-78-6

MineralSpirits 1-5 No8052-41-3

Rosin 5-10 No

Metallo-OrganicBismuth 5-10 No

Compounds


MSDS code: HLG130F


1!i. OTHERINFORMATION!

Revision number: 14

Section(s) Revised in thisVersion:

Prepared By:

Section 1: Chemical Product and Company IdentificationSection 16: . Other Information

Corporate Environmental Health &Safety Group

IMPORTANT: WHILE THE DESCRIPTIONS, DESIGNS, DATA AND INFORMATION CONTAINED HEREIN AREPRESENTED IN GOOD FAITH AND BELIEVED TO BE ACCURATE, IT IS PROVIDED FOR YOUR GUIDANCE ONLY.BECAUSE MANY FACTORS MAY AFFECT PROCESSING OR APPLICATION/USE, WE RECOMMEND THAT YOUMAKE TESTS TO DETERMINE THE SUITABILITY OF A PRODUCT FOR YOUR PARTICULAR PURPOSE PRIOR TOUSE. NO WARRANTIES OF ANY KIND, EITHER EXPRESSED OR IMPLIED, INCLUDING WARRANTIES OFMERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE, ARE MADE REGARDING PRODUCTSDESCRIBED OR DESIGNS, DATA OR INFORMATION SET FORTH, OR THAT THE PRODUCTS, DESIGNS, DATA ORINFORMATION MAY BE USED WITHOUT INFRINGING THE INTELLECTUAL PROPERTY RIGHTS OF OTHERS. INNO CASE SHALL THE DESCRIPTIONS, INFORMATION, DATA OR DESIGNS PROVIDED BE CONSIDERED A PARTOF OUR TERMS AND CONDITIONS OF SALE. FURTHER, YOU EXPRESSLY UNDERSTAND AND AGREE THATTHE DESCRIPTIONS, DESIGNS, DATA, AND INFORMATION FURNISHED BY BASF HEREUNDER ARE GIVENGRATIS AND BASF ASSUMES NO OBLIGATION OR LIABILITYFOR THE DESCRIPTION, DESIGNS, DATA ANDINFORMATION GIVEN OR RESULTS OBTAINED, ALL SUCH BEING GIVEN AND ACCEPTED AT YOUR RISK.END OF DATA SHEET

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