attachment i.4 baseline report (part 1) · ingredients includes sodium bisulphite h302 harmful if...

ATTACHMENT I.4

BASELINE REPORT (PART 1)

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rpsgroup.com/ireland

1

Document Control Sheet

This report takes into account the particular instructions and requirements of the Client. It is provided for sole use of the Client and its professional advisors. Information disclosed should be treated as being strictly private and confidential. Any use which a third party makes of this document, or any reliance on or decisions to be made based on it, is the responsibility of such third parties. No responsibility is accepted by RPS for the use of this Document, in whole or in part, for any other purpose.

Client: Medite

Project Title: IED Licence Application

Document Title: Baseline Report

Document No: MCC0721Rp0001F01

Text Pages: 56 Appendices: 6

Rev. Status Date Author(s) Reviewed By Approved By

A01 Issue to Client 11th

February 2015 CD MS ML

F01 Final issue 2nd

April 2015

Medite

IED Licence Application

Baseline Report

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Medite - IED Licence Application - Baseline Report

MCC0721Rp0001F01 i

TABLE OF CONTENTS

1 INTRODUCTION ..................................................................................................................... 1

2 STAGE 1: IDENTIFYING THE HAZARDOUS SUBSTANCES ........................................................... 2

2.1 GUIDANCE REQUIREMENTS .................................................................................................... 2

2.2 APPLICANT DETAILS .............................................................................................................. 2

2.2.1 Substances Used .............................................................................................. 2

2.2.2 Substances Produced ....................................................................................... 5

2.2.3 Substances Released ........................................................................................ 5

3 STAGE 2: IDENTIFYING THE RELEVANT HAZARDOUS SUBSTANCES .......................................... 7

3.1 GUIDANCE REQUIREMENTS .................................................................................................... 7

3.2 APPLICANT DETAILS .............................................................................................................. 7

4 STAGE 3: ASSESSMENT OF THE SITE SPECIFIC POLLUTION POSSIBILITY ................................. 12

4.1 GUIDANCE REQUIREMENTS .................................................................................................. 12

4.2 APPLICANT DETAILS ............................................................................................................ 12

4.2.1 Corrshield MD4100 ........................................................................................ 12

4.2.2 Steamate NA0840 .......................................................................................... 13

4.2.3 Steamate FM1000 .......................................................................................... 14

4.2.4 Potassium Permanganate .............................................................................. 15

4.2.5 Optisperse PO5090 ........................................................................................ 16

4.2.6 Formic Acid .................................................................................................... 17

4.2.7 Hydrated Lime ................................................................................................ 18

4.2.8 Aluminium Chloride ....................................................................................... 19

4.2.9 Biofeed ........................................................................................................... 20

4.2.10 Toluene .......................................................................................................... 21

4.2.11 Urea Formaldehyde Resin .............................................................................. 22

4.2.12 Process Dyes .................................................................................................. 23

4.2.13 Mobiltherm 605 ............................................................................................. 24

4.2.14 Gas Oil Marked .............................................................................................. 25

4.2.15 Planned Emissions ......................................................................................... 25

4.2.16 Preventative Measures .................................................................................. 26

5 STAGE 4 – SITE HISTORY ...................................................................................................... 28


5.2 SITE HISTORY ..................................................................................................................... 28

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MCC0721Rp0001F01 ii

5.3 SITE PROCESSES ................................................................................................................. 29

5.4 INCIDENT HISTORY .............................................................................................................. 30

5.5 SITE INVESTIGATIONS .......................................................................................................... 31

5.6 PREVIOUS MONITORING ...................................................................................................... 31

6 STAGE 5 – ENVIRONMENTAL SETTING .................................................................................. 35



6.2.1 Background .................................................................................................... 35

6.2.2 Topography .................................................................................................... 35

6.2.3 Hydrology ....................................................................................................... 36

6.2.4 Geology and Hyrdrogeology .......................................................................... 37

6.2.5 Results of Previous Site Investigation ............................................................ 43

6.2.6 Groundwater Quality ..................................................................................... 47

6.2.7 Groundwater Flow ......................................................................................... 47

6.2.8 Other Potential Migration Pathways ............................................................. 47

6.2.9 Environmental Aspects .................................................................................. 48

6.2.10 Surrounding Landuse ..................................................................................... 48

6.2.11 Environmental Setting Conclusion ................................................................. 48

7 STAGE 6 – SITE CHARACTERISATION ..................................................................................... 50



7.2.1 Source Details ................................................................................................ 50

7.2.2 Pathway Details ............................................................................................. 53

7.2.3 Receptor Details ............................................................................................. 54

7.2.4 Conclusion ...................................................................................................... 54

8 STAGE 7 – SITE INVESTIGATIONS .......................................................................................... 55



9 STAGE 8 – BASELINE REPORT CONCLUSIONS ........................................................................ 56


9.2 APPLICANT DETAILS/CONCLUSION ......................................................................................... 56

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MCC0721Rp0001F01 iii

LIST OF APPENDICES

Appendix A Hazard Classes

Appendix B MSDS Sheets

Appendix C Site Investigation Report

Appendix D Borehole Logs

Appendix E Summary of Groundwater Monitoring Results - 2014

Appendix F Site Location Plan & Site Drawings

LIST OF FIGURES

Figure 5-1: Nitrate Concentration in Groundwater 2000 to 2014 ........................................................ 33 Figure 5-2: Ammonia Concentration in Groundwater 2000 to 2014 .................................................... 34 Figure 5-3: Chloride Concentration in Groundwater 2000 to 2014 ...................................................... 34 Figure 6-1: Location of Surface Water Features ................................................................................... 36 Figure 6-2: Location of Medite Facility ................................................................................................. 37 Figure 6-3: Teagasc Subsoil Map (Extract from GSI website) ............................................................... 38 Figure 6-4: Bedrock Geology Map (Extract from GSI website) ............................................................. 39 Figure 6-5: Aquifer Map (Extract from GSI website) ............................................................................. 40 Figure 6-6: Vulnerability Map (Extract from GSI website) .................................................................... 41 Figure 6-7: GSI Well Database (Extract from GSI website) ................................................................... 42

LIST OF TABLES

Table 2-1: List of “Hazardous Substances” used at the Medite Facility ................................................. 3 Table 3-1: Assessment of “Hazardous Substances” at the Medite Facility ............................................ 9 Table 4-1: Surface Water Emission Characteristics .............................................................................. 26 Table 5-1: Incident History at the Medite Facility ................................................................................ 30 Table 5-2: Summary of Groundwater Monitoring Locations. ............................................................... 31 Table 6-1: Summary of 2014 Site Investigation Drilling Phase ............................................................. 44 Table 6-2: Summary of Results of Installation of Monitoring Boreholes .............................................. 46 Table 7-1: Total bulk storage capacities of “relevant hazardous substances” ..................................... 50 Table 7-2: Historic Waste Quantities In Former Landfill Site ................................................................ 52

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MCC0721Rp0001F01 1

1 INTRODUCTION

Medite is submitting an IED Licence Application for the following classes of activities.

The relevant activity as set out in the First Schedule of the EPA Act 1992, as amended, is: -

Class 8.1 - The production of paper pulp, paper or board (including fibre-board, particle-board and plywood) with a production capacity exceeding 20 tonnes per day.

Class 8.7 - The production of one or more of the following wood-based panels: orient

strand board, particleboard or fibreboard with production capacity exceding 600 m3

per day.

This document presents the baseline report which has been prepared in accordance with the “European Commission Guidance concerning baseline reports under Article 22(2) of Directive 2010/75/EU on industrial emissions” (reference 2014/C 136/03). This guidance sets out a standard eight stage process that is required to complete the baseline report as outlined below:-

Stage 1: Identifying the Hazardous Substances that are Currently Used, Produced or Released at the Installation.

Stage 2: Identifying the Relevant Hazardous Substances.

Stage 3: Assessment of the Site-Specific Pollution Possibility.

Stage 4: Site History.

Stage 5: Environmental Setting.

Stage 6: Site Characterisation.

Stage 7: Site Investigations.

Stage 8: Production of the Baseline Report.

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MCC0721Rp0001F01 2

2 STAGE 1: IDENTIFYING THE HAZARDOUS SUBSTANCES

2.1 GUIDANCE REQUIREMENTS

The guidelines from the Commission require the following details for Stage 1:-

Identify which hazardous substances are used, produced or released at the installation and produce a list of these hazardous substances.

A “Hazardous substance” is defined in the Guidance as substances or mixtures as defined in Article 3 of Regulation (EC) No 1272/2008 of the European parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures.

Article 3 of Regulation (EC) No 1272/2008 defines hazardous substances and mixtures and specification of hazard classes as follows:-

A substance or a mixture fulfilling the criteria relating to physical hazards, health hazards or environmental hazards, laid down in Parts 2 to 5 of Annex l is hazardous and shall be classified in relation to the respective hazard classes provided for in that Annex.

Where, in Annex l, hazard classes are differentiated on the basis of the route of exposure or the nature of the effects, the substance or mixture shall be classified in accordance with such differentiation.

A full list of the relevant hazard classes applicable are presented in Appendix A for reference.

2.2 APPLICANT DETAILS

A full list of all substances and mixtures used, produced or released at the Medite facility has been compiled and is presented in the following sections along with details of the nature of the hazardous substances identified. The Commission Guidance states that substances must include raw materials, products, intermediaries, by-products, emissions or wastes at the facility. While fuels are not a requirement these are included for completeness.

2.2.1 Substances Used

The main substances used at the Medite facility include process materials and fuels. Table G.1(i) of the IED licence application provides details of process related raw materials used on the site.

The 2013 Annual Environmental Report lists the resources (fuels etc.) and quantities of same employed at the facility in 2013. The 2013 AER also lists the wastes generated during site operations in 2013. All of the above have been compiled to identify the “hazardous substances” at the facility which are listed in Table 2-1

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MCC0721Rp0001F01 3

The client provided the material safety data sheets (MSDS) for the hazardous substances used on site. Only the substances classed as hazardous have been included. Due to the variability of the information presented in the MSDS sheets the R phrase, S phrase and H phrase where available have been presented in Table 2-1 in accordance with S.I. No. 62 of 2004 European Communities (Classification, Packaging and Labelling of Dangerous Preparations) Regulations 2004. Schedule 10 of these regulations specifies the Risks Phrases and Schedule 11 specifies the Safety Phrases. Hazard statement codes are available for physical hazards, health hazards and environmental hazards. For the preparation of the baseline report the assessment has concentrated on the potential environmental hazards. A copy of the MSDS sheets for the hazardous substances used on site have been obtained from the client and are contained in Appendix B.

Table 2-1: List of “Hazardous Substances” used at the Medite Facility

Material/Substance Risk Phrases Safety Phrases Hazard Statement Codes

Hydrochloric Acid 28/36%

R34, R37 S2, S26 H314 Causes severe skin burns and eye damage.

H335 May cause respiratory irritation.

H290 May be corrosive to metals.

Sodium Hydroxide R34, R35 S26-28, S36/37/39-45 H314 Causes severe skin burns and eye damage.

Corrshield MD4100 R25-36/38 S26,27,28,36,37,39-45, S60

H301 Toxic if swallowed.

H315 causes skin irritation.

H319 causes serious eye irritation.

Irritating to eyes and skin.

Balanced Polymer 6473E

R36/37 S26-28-36/37/39 No MSDS sheet provided.

Steamate NA0840 R21/22.R34,

R43.

S24, S26, S28,

S36/37/39, S45

Information on ingredients H302 Harmful if swallowed.

H312 Harmful in contact with skin.

H314 Causes severe burns and eye damage.

H332 Harmful if inhaled - H226 Flammable liquid and vapour.

H317 May cause an allergic skin reaction.

Steamate FM1000 R36/38-43 S24-26-28-36/37/39 Information on ingredients –

R52 harmful to aquatic organisms.

R53 may cause long term effects in the aquatic environment.

H412 Harmful to aquatic life with long lasting effects.

Cortrol IS3000 R49-22-31 S23-26-28-36/37/39-45-53

Hazard statements – mixture does not meet the criteria for classification. But info on ingredients includes sodium bisulphite H302 Harmful if swallowed.

Depositrol PY5203 No R phrases No S phrases Not considered hazardous to health. The product is not classified as dangerous for the environment.

Potassium Permanganate

R8,22,50/53 S60, S61 There are no Hazard statements.

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MCC0721Rp0001F01 4


Napgel C2230 R22 S2,S20,S27,S46 There are no Hazard statements listed.

Optisperse P05090 R36/38 S26, S28, S36/37/39 Not classified for physical hazards. Irritating to eyes and skin. Not classified for hazards to the environment but ingredient referenced H314 causes severe skin burns and eye damage. Stated product is not classified as dangerous for the environment.

Hydrated Lime R37,38, 41 S2,25,26,37,39 H315 Causes skin irritation.

H318 Causes serious eye damage.


Aluminium Chloride R35, R41 S24,25,36 No hazard statements.

Biofeed

R35,41 S1,2,26,27/28,36/ 37/39,45

H315 contact with skin will cause irritation.

H314 contact with eyes may cause severe damage.

Formic Acid R35 S26,37/39,45 H314 causes severe skin burns and eye damage.

Toluene R11, 38, 48, 20, 63, 65, 67-20

S36/37, 62, 46 No H numbers given but following listed under hazard identification:

Highly flammable.

Irritating to the skin.

Possible risk of harm to the unborn child.

Harmful: may cause lung damage if swallowed.

Vapours may cause drowsiness and dizziness.

Harmful: danger of serious damage to health by prolonged exposure through inhalation.

COD Reagent R49-23/24/ 25-33-35-52/53

S26,28a, 45,60 No MSDS sheet provided.

Sulphuric Acid R35 S1,2,26,30,45 No MSDS sheet provided.

Hydrochloric Acid

R34-37 S1,2,26,45 H314 Causes severe skin burns and eye damage.


H290 May be corrosive

Glacial Acetic Acid R10,35 S23,26,45 No hazard statements

Formaldehyde Solution

R23,24, 25,34, 43,50

S26,36,37,44,51 No hazard statements

Urea Formaldehyde Resin

R23,24,25,34,

40, 43

S26, 36 37, 39,51 No hazard statement.

MDI Resin

Xn;R20

Xi;R36/37/38

R42/43

S23, 36/37/38,45 No Hazard statement but stated the following:

Harmful by inhalation.

Irritating to eyes, respiratory system and skin.

May cause sensitisation by inhalation and skin contact.

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MCC0721Rp0001F01 5


Green Process dye

R22,37,

38,41,

50,53

S24,26,37,39,61 No Hazard statements

Red Process dye

R34,51,

53

S36,37,39,45,57,61 Hazard statements are provided for components: H226 flammable liquid and vapour.

H314 Causes severe skin burns and eye damage.

H301 Toxic if swallowed.

H411 Toxic to aquatic life with long lasting effects.

LPG Propane

R12 S9,16,33 No H classes stated R and S phrases given. Stated

Liquefied gas.

Extremely flammable.

Natural Gas

R12 S9,16,33 No H classes but stated.

Extremely flammable.

In high concentrations may cause asphyxiation.

Compressed gas.

Mobiltherm 605 ** ** No Hazard statements but stated excessive exposure may result in eye, skin, or respiratory irritation.

Gas oil marked

R40,52, 53 S2,24,36, 37,43,61,62 No MSDS sheet provided.

2.2.2 Substances Produced

Medite produce a range of Medium Density Fibreboard (MDF) products for a range of industrial, commercial and domestic applications at the Clonmel Plant. The MDF sheets are manufactured from wood fibre bonded together with a synthetic resin adhesive. Various grades of MDF are produced using different adhesives and additives. Two production lines operate in parallel using the same chip processing facility and similar finishing facilities further downstream. Resins and other additives including dyes, urea, MDI and fire retardant chemicals are added to the wood chips in the MDF manufacturing process.

2.2.3 Substances Released

The releases from the Medite facility are as follows:

Discharges to air – these are not relevant to this baseline report which relates to soil and groundwater issues.

Discharges to surface water – there are two surface water discharges SW1 northern discharge and SW2 southern discharge (combined effluent and surface water discharge).

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MCC0721Rp0001F01 6

Discharges to sewer – there are no discharges to the local authority as there is an on-site wastewater treatment plant.

Discharges to ground or groundwater – there are no direct discharges to groundwater with the exception of 2 no. percolation areas associated with 2 no. on-site septic tanks (illustrated on Drawing EN/000-IPPC-011.

In terms of emissions to water the 2013 Annual Environmental Report (AER) provides information with respect to the annual emissions. The 2014 AER is not currently available but similar emissions would be expected on the basis that there were no significant changes to on site processes. The surface water discharges are direct to the River Anner. The River Anner and River Suir are considered to be located in the groundwater discharge zone and on this basis there is no potential for impact on the groundwater as a result of the direct discharges to the surface water.

In relation to this baseline report there are no routine discharges of hazardous substances to soil or groundwater at the Medite Facility.

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MCC0721Rp0001F01 7

3 STAGE 2: IDENTIFYING THE RELEVANT HAZARDOUS SUBSTANCES


The baseline report guidance requires the following to be addressed during Stage 2:

Identify which of the hazardous substances from Stage 1 are ‘relevant hazardous substances’ (see Section 4.2).

Discard those hazardous substances that are incapable of contaminating soil or groundwater. Justify and record the decisions taken to exclude certain hazardous substances.

The guidance document defines ‘Relevant hazardous substances’ as those substances or mixtures defined within Article 3 of Regulation (EC) No 1272/2008 (Identified in Stage 1) which, as a result of their hazardousness, mobility, persistence and biodegradability (as well as other characteristics), are capable of contaminating soil or groundwater and are used, produced and / or released by the installation.


Table 2-1 of Stage 1 presented the hazardous substances. These substances have been assessed in Table 3-1 in terms of which substances are capable of contaminating the soil or groundwater at the site. The hazardous substances can be broken down into the following categories:-

Boiler water treatment chemicals

Laboratory testing chemicals Quality Control (QC) analysis

Waste Water Treatment Plant (WWTP) chemicals

Raw materials

Fuel

There are 6 no. substances used for QC analysis in the laboratory (Table 3-1). All of these substances, with the exception of toluene, are used in very low volumes with less than 1 litre typically stored at a given time. All of these materials (except toluene) are stored internally in the facility. The transport and use of these substances is in very small volumes. There is no potential pathway to ground from a spill or incident involving these 5 no. substances as any incident would be contained on the facility floors and in the process water network. In the unlikely event of a spill or incident involving these substances, the environmental consequence would not be significant. Given the very low probability of an incident occurrence coupled with the absence of any environmental consequence, there is no pollution risk associated with these substances. As these 5 no. hazardous substances are incapable of contaminating soil or groundwater, they are discarded as “relevant hazardous substances” and are not considered further in this assessment.

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MCC0721Rp0001F01 8

For each of the remaining WWTP chemicals, raw material and fuel identified in Stage 1, a review of the following parameters derived from the MSDS has been completed to determine which, if any, of the substances are considered “relevant hazardous substances”:

Physical state

Solubility

Mobility

Environmental Hazard (Part 4 of Regulation (EC) No 1272/2008)

Each of the above is identified and used to determine what substances are included as “relevant hazardous substances” along with a rationale for the decision making. This element is presented in Table 3-1. Details of the chemical characteristics and environmental fate of these substances has been derived from the MSDS sheets provided by the client. In particular materials with the following risk phrases may represent a risk to soil or groundwater:

R50 – Very toxic to aquatic organisms.

R51 – Toxic to aquatic organisms.

R52 – Harmful to aquatic organisms.

R53 – May cause long-term adverse effects in the aquatic environment.

Based on the analysis the following are listed as “relevant hazardous substances” at the Medite Facility:

Corrshield MD4100

Steamate NA0840

Steamate FM1000


Optisperse P05090

Hydrated Lime

Aluminium Chloride

Biofeed

Formic Acid

Toluene

Urea Formaldehyde Resin

Green Process Dye

Red Process Dye

Mobiltherm

Gas Oil Marked

Each of these “relevant hazardous substances” is further assessed for risk of soil and groundwater contamination in Stage 3 of this report.

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MCC0721Rp0001F01 9

Table 3-1: Assessment of “Hazardous Substances” at the Medite Facility

Substance Nature of

Use Amount Stored

Annual Usage

Physical State

Soluble in Water

Mobility Environment

al Hazard

Relevant Hazardous Substance

Rationale / Assessment

Hydrochloric Acid 28/36%

Boiler water

20T 140T Liquid Yes Highly mobile

No No Short environmental lifetime. Readily degrades in environment in soil and

water to chloride and hydrogen ions.

Sodium Hydroxide

Boiler water

6 x 200L 20 x 200L Liquid Yes High mobility.

No No Short environmental lifetime that readily degrades in the environment.

Corrshield MD4100

Boiler water

200L 500L Liquid Yes Mobile in water

Yes Yes Not classified as dangerous for environment but some of ingredients

classed as H412 harmful to aquatic life with long lasting effects.

Balanced Polymer

Boiler water


No data No data No data.

Steamate NA0840

Boiler water


Yes Yes Not classified for environmental hazards but ingredients toxic to aquatic

life.

Steamate FM1000

Boiler water


Yes Yes Not classified for hazards to environment. Ingredient classed as

H412 harmful to aquatic life with long lasting effects

Cortrol IS3000 Boiler water


No No Not classified for hazards to environment.

Depositrol PY5203

Boiler water


Not hazardous

No Not classified as dangerous for the environment


Boiler water

50L 100L Powder Mobile in water

Hazardous Yes May cause long term adverse effects in environment.

Napgel C2230 Boiler water

2 x 230kg 2 x 230kg Liquid Yes Mobile in water

No No Non hazardous to aquatic species.

Optisperse P05090

Boiler water

2 x 220kg 2 x 220kg Liquid Yes Mobile in water

Yes Yes Harmful to aquatic life.

Hydrated Lime WWTP 15T 300T Powder Yes Mobile in water


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MCC0721Rp0001F01 10

Substance Nature of

Use Amount Stored

Annual Usage

Physical State

Soluble in Water


al Hazard



Aluminium Chloride

WWTP 20T 450T Powder Mobile in water


Biofeed

WWTP 6 x 1000L 60 T Liquid Highly mobile

Yes Yes Harmful to aquatic life

Formic Acid WWTP descaler

for air diffusers in MBBR tank

2 x 200L 4 x 200L Liquid Highly mobile

Yes Yes Harmful to environment

Toluene QC analysis 100L 600L Liquid Yes Yes Harmful to environment

COD Reagent QC analysis 1L 6L Liquid Yes Yes No Stored in lab small quantities.

Sulphuric Acid QC analysis 0.4L 0.5L Liquid Yes Yes No Stored in lab small quantities.

Hydrochloric Acid

QC analysis 0.4L 0.5L Liquid Yes Yes No Stored in lab small quantities.

Glacial Acetic Acid

QC analysis 1.0L 0.5L Liquid No Stored in lab small quantities.

Formaldehyde Solution

QC analysis 1.0L 0.5L Liquid No Stored in lab small quantities.

Urea Formaldehyde

Resin

Raw material

700 50,000 Liquid Partly Yes Yes Avoid dispersal of spilt material and runoff to soil, waterways, drains or

sewers.

MDI Resin

Raw material

20 550 Liquid Insoluble No No Environmental precautions – avoid dispersal of spilt material and runoff

and contact with soil, waterways, drains and sewers. Liquid insoluble in water and heavier than water reacts with water to produce inert and non-

biodegradable solids.

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MCC0721Rp0001F01 11

Substance Nature of

Use Amount Stored

Annual Usage

Physical State

Soluble in Water


al Hazard



Green Process Dye

Raw material

2 x 1000L 14 T Liquid Soluble Highly mobile

Yes Yes Classed as severe hazard to water causes long term adverse effects in

aquatic environment

Red Process Dye

Raw material

1 x 1000L 5 T Liquid No data Yes Yes Classed as toxic to aquatic life with long lasting effects

LPG Propane

Fuel 35,000L 200,000L Liquid Yes No No No known ecological damage.

Natural Gas

Fuel Gas No impact on soil / water

No Gas not issue in relation to soil or groundwater.

Mobiltherm 605

Production press heat

transfer medium

1,000L N/A Liquid Low solubility

Low potential

to migrate

Yes Yes High toxicity, low mobility may result in long term residual ground

contamination

Gas oil marked / Diesel

Mobile site vehicles

30,000L 300,000L Liquid Yes Yes Risk to soil & groundwater.

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MCC0721Rp0001F01 12

4 STAGE 3: ASSESSMENT OF THE SITE SPECIFIC POLLUTION POSSIBILITY


The Baseline Reports Guidance Document specifies the following details are required for Stage 3.

For each relevant hazardous substance brought forward from Stage 2, identify the actual possibility for soil or groundwater contamination at the site of the installation, including the probability of releases and their consequences, and taking particular account of:-

The quantities of each hazardous substance or groups of similar hazardous substances concerned.

How and where hazardous substances are stored, used and to be transported around the installation.

Where they pose a risk to be released.

In case of existing installations also the measures that have been adopted to ensure that it is impossible in practice that contamination of soil or groundwater takes place.


For each of the relevant hazardous substances identified in Stage 2, a risk assessment of the potential for ground contamination is provided in the following sections. The assessment includes a review of potential breaches caused by accidents / incidents, routine operations and planned emissions. The potential for breaches in relation to accidents and incidents during routine operations has been assessed in terms of each of the potentially hazardous substances (Section 4.2.1 to 4.2.14) while an assessment of the impact from planned emissions is provided in Section 4.2.15.

4.2.1 Corrshield MD4100

Criteria Description

Substance Corrshield MD4100

Annual Usage 500L

Storage Location 200L stored on site in the chemical drum store.

Description of Use Liquid used as additive for treatment of the boiler water in a closed loop boiler system.

Mode of Transport All drums are secured to pallets and a forklift is used to off load drums and transport then from the storage area to the point of use.

Potential Pathways to Ground

Potential pathways include the following:

Uncontrolled release during drum loading operation at the chemical store. In the event of the rupture of drums during loading / unloading operations the spilled material would flow across the hardstanding and would be contained by booms / spill kits. If the material entered the surface water / stormwater network the material would be contained in one of the interceptor settlement lagoons one of which is retained as an emergency holding lagoon. There is no direct pathway to ground.

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Rupture of drums in chemical store. The spill would be contained on the floor of the chemical store using bunds and spill kits. In the event of the loss of primary or secondary containment (bund) there is no direct pathway to ground as the chemical store is located in an area of hardstanding.

Uncontrolled release in the boiler room. Any spill would be to the boiler room floor and would be contained with the use of booms / spill kits. There is no direct pathway to ground.

Existing Mitigation The hauliers / drivers for the delivery of bulk materials have been trained in the procedures in relation to safe handling, safe unloading and emergency procedures. The hauliers for containers use IBCs or drums secured onto pallets. All deliveries are controlled and fully supervised. Spill kits and booms are maintained on site to ensure that any spill is quickly contained.

All IBCs and drums are stored in the bunded chemical storage area which provides secondary containment and spill containment. All tanks and bunds are regularly inspected and bund testing is carried out in accordance with the licence requirements with maintenance carried out as required.

Hardstanding areas are present throughout the site.

Probability of Release to Ground

Based on the existing controls, the probability of a breach of containment and an uncontrolled discharge to ground is considered very low. No such event has occurred in the past.

Consequence of Incident

Corrshield MD4100 is not classified as dangerous for the environment but as some of its ingredients are classed as harmful to aquatic life the main risk would be to surface water. Any spill to ground would have to percolate through the clay overburden to reach groundwater. Due to the thickness and permeability of the overburden this would be a slow process any ground impact would be localised.

Risk of Soil or Groundwater Contamination

The risk of soil or groundwater contamination from the uncontrolled release of this substance is considered to be low.

4.2.2 Steamate NA0840


Substance Steamate NA0840

Annual Usage 8,000L






Uncontrolled release during drum loading operation at the chemical store. In the event of the rupture of drums during loading / unloading operations the spilled material would flow across the hardstanding and would be contained with booms/ spill kits. If the material entered the surface water / stormwater network the material would be contained in one of the interceptor settlement lagoons one of which is retained as an emergency holding lagoon. There is no direct pathway to ground.

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Rupture of drums in chemical store. The spill would be contained on the chemical store floor using bunds and spill kits. In the event of the loss of primary or secondary containment (bunding) there is no direct pathway to ground as the chemical store is located in an area of hardstanding.

Uncontrolled release in the boiler room. Any spill would be to the boiler room floor and would be contained with booms / spill kits. There is no direct pathway to ground.

Existing Mitigation The hauliers / drivers for the delivery of bulk materials have been trained in the procedures in relation to safe handling, safe unloading and emergency procedures. The hauliers use IBCs or drums secured onto pallets. All deliveries are controlled and fully supervised. Spill kits and booms are available on site to ensure that any spill is quickly contained.






Steamate NA0840 is not classified as dangerous for the environment but as some of its ingredients are classed as harmful to aquatic life the main risk would be to surface water. Any spill to ground would have to percolate through the clay overburden to reach groundwater. Due to the thickness and permeability of the overburden this would be a slow process any ground impact would be localised.



4.2.3 Steamate FM1000


Substance Steamate FM1000

Annual Usage 2,000L






Uncontrolled release during drum loading operation at the chemical store. In the event of the rupture of drums during loading / unloading operations the spilled material would flow across the hardstanding and would be contained with booms/ spill kits. If the material entered the surface water / stormwater network the material would be contained in one of the interceptor settlement lagoons one of which is retained as an emergency holding lagoon. There is no direct pathway to ground.

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Rupture of drums in chemical store. The spill would be contained on the chemical store floor using bunds and spill kits. In the event of the loss of primary or secondary containment (bund) there is no direct pathway to ground as the chemical store is located in an area of hardstanding.

Uncontrolled release in the boiler room. Any spill would be to the boiler room floor and would be contained with booms / spill kits. There is no direct pathway to ground.







Steamate FM1000 is not classified as dangerous for the environment but as some of its ingredients are classed as harmful to aquatic life the main risk would be to surface water. Any spill to ground would have to percolate through the clay overburden to reach groundwater. Due to the thickness and permeability of the overburden this would be a slow process any ground impact would be localised.



4.2.4 Potassium Permanganate


Substance Potassium Permanganate

Annual Usage 100L






Uncontrolled release during drum loading operation at the chemical store. In the event of the rupture of drums during loading / unloading operations the spilled material would collect on the hardstanding and would be contained with spill kits. As the material is in power form it is unlikely the material would enter the surface water / stormwater network unless washed down or affected by rainfall. In the event of the material being washed into the stormwater collection system the runoff would be contained in one of the interceptor settlement lagoons one of which is retained as an emergency holding lagoon. There is no direct pathway to

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ground.

Rupture of drums in chemical store. The powder spill would be contained on the chemical store floor using spill kits. In the event of the loss of primary or secondary containment there is no direct pathway to ground as the chemical store is located in an area of hardstanding.

Uncontrolled release in the boiler room. Any spill would be to the boiler room floor and would be cleaned up using the appropriate spill kits. There is no direct pathway to ground.







Potassium Permanganate may cause long term adverse effects in the environment. Due to its power format it would need to be washed into the ground. Any spill of runoff to ground would have to percolate through the clay overburden to reach groundwater. Due to the thickness and permeability of the overburden this would be a slow process any ground impact would be localised.



4.2.5 Optisperse PO5090


Substance Optisperse P05090

Annual Usage 440 kg

Storage Location 440 kg stored on site in the chemical drum store.


Mode of Transport All drums and IBCs are secured to pallets and a forklift is used to off load drums and transport them from the storage area to the point of use.



Uncontrolled release during drum loading operation at the chemical store. In the event of the rupture of drums during loading / unloading operations the spilled material would collect on the hardstanding and would be contained with spill kits. In the event of the material being washed into the stormwater collection system the runoff would be contained in one of the interceptor settlement lagoons one of which is retained as an emergency holding lagoon. There is no direct pathway to ground.

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Rupture of drums in chemical store. The liquid spill would be contained on the chemical store floor using booms and spill kits. In the event of the loss of primary or secondary containment there is no direct pathway to ground as the chemical store is bunded and located in an area of hardstanding.

Uncontrolled release in the boiler room. Any spill would be to the boiler room floor and would be contained using a boom and cleaned up using the appropriate spill kits. There is no direct pathway to ground.

Existing Mitigation The hauliers / drivers for the delivery of bulk materials have been trained in the procedures in relation to safe handling, safe unloading and emergency procedures. The hauliers use IBCs or drums secured on pallets. All deliveries are controlled and fully supervised. Spill kits and booms are available on site to ensure that any spill is quickly contained.






Optisperse P05090 may cause long term adverse effects in the environment. Any spill to ground would have to percolate through the clay overburden to reach groundwater. Due to the thickness and permeability of the overburden this would be a slow process any ground impact would be localised.



4.2.6 Formic Acid


Substance Formic Acid

Annual Usage 800 L

Storage Location 400 L stored on site in the chemical drum store.

Description of Use Formic acid is used in the WWTP as a descaler for the air diffusers in the MBBR Tank.

Mode of Transport All drums and IBCs are secured to pallets and a forklift is used to off load drums and transport then from the storage area to the point of use.




Rupture of drums in chemical store. The liquid spill would be contained on the chemical store floor using booms and spill kits. In the event of the loss of primary or secondary containment there is no direct pathway to ground as the chemical

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store is located in an area of hardstanding.

Uncontrolled release in the boiler room. Any spill would be to the boiler room floor and would be contained using a boom and cleaned up using the appropriate spill kits. There is no direct pathway to ground.







Formic Acid is reported to be harmful to the environment. Any spill to ground would have to percolate through the clay overburden to reach groundwater. Due to the thickness and permeability of the overburden this would be a slow process any ground impact would be localised.



4.2.7 Hydrated Lime


Substance Hydrated Lime

Annual Usage 300 T

Storage Location 15 T stored on site. The hydrated lime is stored in a silo adjacent to the Wastewater Treatment plant.

Description of Use Powder used as additive in wastewater treatment.

Mode of Transport The lime is delivered by truck directly to the bulk storage tank / silo adjacent to the point of use.



Uncontrolled release during delivery at the WWTP. Any spilled material would collect on the hardstanding and would be contained with spill kits. In the event of the material being washed into the stormwater collection system the runoff would be contained in one of the interceptor settlement lagoons one of which is retained as an emergency holding lagoon. There is no direct pathway to ground.

Uncontrolled release in the WWTP would be contained within the treatment plant using a boom and cleaned up using the appropriate spill kits. There is no direct pathway to ground.

Existing Mitigation The hauliers / drivers for the delivery of bulk materials have been trained in the procedures in relation to safe handling, safe unloading and emergency procedures. All deliveries are controlled and fully supervised. Spill kits and booms are available on site to ensure that any spill is quickly contained.

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All tanks and bunds are regularly inspected and bund testing is carried out in accordance with the licence requirements with maintenance carried out as required.





Hydrated Lime is harmful to aquatic life and is more of a risk to surface water than groundwater. Any spill to ground would have to percolate through the clay overburden to reach groundwater. Due to the thickness and permeability of the overburden this would be a slow process any ground impact would be localised.


Harmful to aquatic life based on pH. The risk of soil or groundwater contamination from the uncontrolled release of this substance is considered to be low.

4.2.8 Aluminium Chloride


Substance Aluminium Chloride

Annual Usage 450 T

Storage Location 20 T stored on site. The aluminium chloride is stored in a bulk storage tank (integrated tank within a bund) adjacent to the Wastewater Treatment Plant.

Description of Use Powder used as additive in wastewater treatment.

Mode of Transport The aluminium chloride is delivered by truck directly to the bulk storage tank adjacent to the point of use.



Uncontrolled release during delivery at the WWTP. Any spilled material would collect on the hardstanding and would be contained with spill kits. In the event of the material being washed into the stormwater collection system the runoff would be contained in one of the interceptor settlement lagoons one of which is retained as an emergency holding lagoon. There is no direct pathway to ground.

Uncontrolled release in the WWTP would be contained within the treatment plant using a boom and cleaned up using the appropriate spill kits. There is no direct pathway to ground.







Aluminium chloride is harmful to aquatic life. May cause long term adverse effects in the environment. Any spill to ground would have to percolate through the clay overburden to reach groundwater. Due to the thickness and permeability of the

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overburden this would be a slow process any ground impact would be localised.



4.2.9 Biofeed


Substance Biofeed

Annual Usage 60 T

Storage Location 6,000 L stored on site in the WWTP chemical store.

Description of Use Liquid used as additive in wastewater treatment.

Mode of Transport All IBCs are secured to pallets and a forklift is used to off load and transport them from the delivery truck to the storage area and the point of use.



Uncontrolled release during IBC unloading operation at the WWTP chemical store. In the event of the rupture of IBC during loading / unloading operations the spilled material would collect on the hardstanding and would be contained with spill kits. In the event of the material being washed into the stormwater collection system the runoff would be contained in one of the interceptor settlement lagoons one of which is retained as an emergency holding lagoon. There is no direct pathway to ground.

Rupture of IBC in chemical store. The spill would be contained on the chemical store floor using spill kits. In the event of the loss of primary or secondary containment there is no direct pathway to ground as the WWTP chemical store is bunded and located in an area of hardstanding.

Uncontrolled release at the WWTP would be contained within the treatment plant using a boom and cleaned up using the appropriate spill kits. There is no direct pathway to ground.


All IBCs and drums are stored in the WWTP bunded chemical storage area which provides secondary containment and spill containment. All tanks and bunds are regularly inspected and bund testing is carried out in accordance with the licence requirements with maintenance carried out as required.





Biofeed is reported as harmful to aquatic life. Any spill would have to percolate through the clay overburden to reach groundwater. Due to the thickness and permeability of the overburden this would be a slow process any ground impact would be localised.

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4.2.10 Toluene


Substance Toluene

Annual Usage 600 L

Storage Location 100 L stored on site in the chemical drum store.

Description of Use Used in QC analysis.




Uncontrolled release during drum loading operation at the chemical store. In the event of the rupture of drums during loading / unloading operations the spilled material would collect on the hardstanding and would be contained using spill kits. In the event of the material being washed into the stormwater collection system the runoff would be contained in one of the interceptor settlement lagoons one of which is retained as an emergency holding lagoon. There is no direct pathway to ground.

Rupture of drums in chemical store. The powder spill would be contained on the chemical store floor using spill kits. In the event of the loss of primary or secondary containment there is no direct pathway to ground as the chemical store is bunded and located in an area of hardstanding.

Uncontrolled release within the laboratory / production area - spills would be small in nature and contained on production floors. Small volumes may enter the process water and be discharged to the WWTP. The spills would be contained within the laboratory / production area and would be cleaned up using the appropriate spill kits. There is no direct pathway to ground.







Toluene is harmful to the environment. Any spill would have to percolate through the clay overburden to reach groundwater. Due to the thickness and permeability of the overburden this would be a slow process any ground impact would be localised.

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The risk of soil or groundwater contamination from the uncontrolled release of this substance is considered to be low due to the area of the facility in which it is used and based on the low storage volume and the presence of bunding at the storage area.

4.2.11 Urea Formaldehyde Resin


Substance Urea Formaldehyde Resin

Annual Usage 50,000 T

Storage Location 700 T stored on site adjacent to the refiner and fibre handling buildings. Bund A (resin tanks 11, 12, 13); Bund G (resin tanks 15,16,17,19) and Bund D (resin tanks 21,22,23).

Description of Use One of the main raw materials (adhesive) used at the site for the manufacture of MDF.

Mode of Transport The resin is delivered by truck directly to the bulk storage tank adjacent to the point of use.



Uncontrolled release during unloading operations. In the event of spillage of the resin during loading / unloading operations the spilled material would collect on the hardstanding and would be contained with booms / spill kits. The material is partially soluble in water. If the material entered the surface water / stormwater network the material would be contained in one of the interceptor settlement lagoons one of which is retained as an emergency holding lagoon. There is no direct pathway to ground.

Rupture of the storage tanks. The spill would be contained within the tank bunds. In the event of the loss of primary or secondary containment there is no direct pathway as the tanks are located in an area of hardstanding in addition to being bunded.

Uncontrolled release in the production area. Any spill would be to the production area floor and would be contained with booms / spill kits. Small volumes may enter the process water and be discharged to the WWTP. There is no direct pathway to ground.







Urea Formaldehyde MSDS recommends avoid dispersal of spilt material and runoff to soil, waterways, drains or sewers. Any spill to ground would have to percolate through the clay overburden to reach groundwater. Due to the thickness and permeability of the overburden this would be a slow process any ground impact would be localised.

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The risk of soil or groundwater contamination from the uncontrolled release of this substance is considered to be low due to the storage and use of this substance in areas of hardstanding and presence of secondary containment (bunds) in the vicinity of the storage areas.

4.2.12 Process Dyes


Substance Green & Red Process Dye

Annual Usage 14 T green dye and 5 T red dye

Storage Location 2,000L green dye and 1,000 L red dye stored on site in the chemical store.

Description of Use Process dye used in the manufacture of MDF product.

Mode of Transport All drums and IBCs are secured to pallets and a forklift is used to off load drums and transport then from the storage area to the point of use.




Rupture of drums / IBCs in storage. The liquid spill would be contained on the hardstanding floor within the bunds. In the event of the loss of primary containment there is no direct pathway to ground as the storage area is bunded and located in an area of hardstanding.

Uncontrolled release in the process area. Any spill would be to the production area floor and would be contained using a boom and cleaned up using the appropriate spill kits. There is no direct pathway to ground.

Existing Mitigation The hauliers / drivers for the delivery of bulk materials have been trained in the procedures in relation to safe handling, safe unloading and emergency procedures. The hauliers for IBCs and drum containers use IBCs or drums secured on pallets. All deliveries are controlled and fully supervised. Spill kits and booms are available on site to ensure that any spill is quickly contained.






The process dyes are classed as a severe hazard to water and reported to cause long term adverse effects in the aquatic environment. Any spill to ground would have to percolate through the clay overburden to reach groundwater. Due to the thickness and permeability of the overburden this would be a slow process any ground impact would be localised.

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4.2.13 Mobiltherm 605


Substance Moblitherm 605

Annual Usage N/A

Storage Location 1,000 L stored in an IBC in the chemical store. Bund ref (I) Tank 38 Thermal Oil Production Line 2. Bund ref (J) Tank 41 Thermal Oil Production Line 1.

Description of Use Used as production press heat transfer medium.

Mode of Transport Delivered to site by truck to bulk storage tanks.



Uncontrolled release during delivery at the fuel storage area. Any spilled material would collect on the hardstanding and would be contained with spill kits. In the event of the material being washed into the stormwater collection system the runoff would be contained in one of the interceptor settlement lagoons one of which is retained as an emergency holding lagoon. There is no direct pathway to ground.

Uncontrolled release on the production line would be contained using a boom and cleaned up using the appropriate spill kits. There is no direct pathway to ground.







High toxicity and low mobility may cause long term residual contamination. However any spill to ground would have to migrate through the hardstanding surfacing and then percolate through the clay overburden to reach groundwater. Due to the thickness and permeability of the overburden this would be a slow process any ground impact would be localised.



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4.2.14 Gas Oil Marked


Substance Gas Oil

Annual Usage 300,000 L

Storage Location 30,000 L stored on site to south west of the chip yard.

Description of Use Used as on site as fuel for mobile site vehicles. Tank Bund 36 & 37

Mode of Transport Delivered by truck to bulk storage tanks.



Uncontrolled release during diesel delivery. Any spilled material would collect on the hardstanding and would be contained with spill kits. In the event of the material being washed into the stormwater collection system the runoff would be contained in one of the interceptor settlement lagoons one of which is retained as an emergency holding lagoon. There is no direct pathway to ground.

Uncontrolled release in the facility during operation of site vehicles on hardstanding areas would be of small volume and would be cleaned up using the appropriate spill kits. There is no direct pathway to ground.







Risk to soil and groundwater however any spill to ground would have to migrate through the hardstanding surfacing and then percolate through the clay overburden to reach groundwater. Due to the thickness and permeability of the overburden this would be a slow process any ground impact would be localised.



4.2.15 Planned Emissions

There are two discharges to surface water from the site. The surface water from the north end of the site (SW1), mainly from the log storage area, passes through a settling lagoon (settlement pond) before discharging to a drain leading to the River Anner. This drains internal roads in the northern half of the site, the log yard, the area around the debarker / chipper building and most of the warehouse building roof.

The surface water from the remainder of the site discharges via SW2. This includes the main process yard area and emissions from the process plant (including refiner packing water). This includes runoff from the internal roads in the southern part of the site, the car park, the fuel storage area, the chip storage area, paved areas to the west of the production building and the roofs of the

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boiler / refiner house, production building, the blender building and part of the warehouse building. This water discharges to a system of 3 no. interceptor settlement lagoons one of which is retained empty as an Emergency Holding Lagoon. The water is subject to both coarse and fine screening before discharge into two large interceptor settling lagoons. Surface water from the interceptor settling lagoons meets the clarified effluent from the process and sanitary effluent treatment plant. The flow is measured and monitored before discharge to the River Anner.

The surface water emission points are shown on drawing EN/000-IPPC-005 Surface Water Emission Point Locations. Table 4-1 details the characteristics of emissions to surface water.

Table 4-1: Surface Water Emission Characteristics

Parameter Units SW2-Combined SW1-North

Flow per Day m3 1,500m

3 0 to 200m

3

pH pH units 6 to 9 7 to 8

BOD kg/day 75 10

COD kg/day 600 250

Phenol kg/day 0.32 0.075

Ammonia kg/day 7.5 0.5

Suspended Solids kg/day 300 40

Orthophosphate kg/day 0.80 1

OFG kg/day 15 1

Nitrate kg/day 22.5 20

The process effluent from the facility is composed of effluent from the refiner plug feeder screws and wash water from the debarking process. Sanitary effluent from the plant is also discharged to the WWTP but it constitutes < 2% of total treated effluent. There are 3 no. septic tank systems within the facility discharging to the ground. These systems service small localised toilets and the locations are shown on Drawing EN/000-IPPC-011 Underground Tanks, Pipes Related to Effluent and Sewer and serve between 2 and 6 people.

The surface water is discharged to the River Anner therefore there is no discharge of the surface water to the ground or groundwater in the vicinity of the site.

4.2.16 Preventative Measures

As outlined in the assessment of each of the hazardous substances bulk chemical storage is provided with secondary containment for prevention of any sudden releases of chemicals to surface water. The locations of all of the bunds are shown on Drawing EN/000-IPPC-010 Bund & Tank Location.

There are 27 bunds on site including 11 mobile bunds on site. There are also 2 no. oil interceptors and 2 no. sumps on site. All sumps on the site are fitted with high level liquid alarms to prevent overflow. The high level liquid alarms are included in maintenance and testing programme. The fire water retention pond is included in the maintenance and testing programme. In accordance with the current licence bund testing is carried out every three years.

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The area where all bulk liquids and drums are stored drains to a settling system composed of 3 no. lagoons. One of the lagoons (each 425m3 volume) is kept empty to act as a holding area in the event of an emergency such as a rupture of a road tanker, process line or individual drums / IBCs. In the event of an emergency spillage there is a system for diversion of flow to the emergency holding lagoon via manual placement of sliding baffles to block off the route to normal discharge. The 2 no. lagoons that are in operation are used alternately so in the event of a sudden unnoticed spillage the lagoon in use will intercept the spillage. The emergency lagoon is approximately 4 times the volume of the largest storage tank.

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5 STAGE 4 – SITE HISTORY


The Baseline Report guidelines require the following details for Stage 4:

Provide a site history. Consider available data and information:

In relation to the present use of the site, and on emissions of hazardous substances which have occurred and which may give rise to pollution. In particular, consider accidents or incidents, drips or spills from routine operations, changes in operational practice, site surfacing, changes in the hazardous substances used.

Previous uses of the site that may have resulted in the release of hazardous substances, be they the same as those used, produced or released by the existing installation, or different ones.

Review of previous investigation reports may assist in compiling this data.

5.2 SITE HISTORY

Medite operate a production facility at Redmondstown, Clonmel where Medium Density Fibreboard (MDF) is produced for a range of industrial, commercial and domestic applications. Planning permission for the site was granted in 1982 prior to which the area was a greenfield site. Production operations commenced on site in September 1983. Ownership of the site has changed several times between 1983 and 2006.

The site has been in the ownership of Coillte Teoranta since 2006. The main upgrade works undertaken at the facility include the 1994 upgrade to increase capacity from 140,000m3/year to 260,000m3/year and in 2002 capacity was increased to 420,000m3/year.

An IPC Licence was granted for the facility on the 30th of November 2001 (Formerly IPC Licence 593 and P0027-02). It is now proposed to lodge an IED licence application. This baseline report forms part of the licence application process.

The development history of the site is summarised below:

1982 Medford Corporation USA built the mill.

1983 Production Line 1 was commissioned with a mill capacity of 140,000m3/year.

1984 Medford Corp was acquired by Valhi Corp, Dallas, Texas.

1994 Production Line 2 start up, 20m continuous production line. Production Line 1 was upgraded and the capacity increased to 190,000m3/year resulting in an overall mill capacity of 260,000m3/year.

1996 Mill was acquired by Willamette Industries Inc., Oregon, USA.

2002 Production Line 1 upgraded. Mill capacity increased to 420,000m3/year.

2002 Mill acquired by Weyerhaeuser Company, USA.

2006 Mill acquired by Coillte Teoranta.

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The area owned by Medite is approximately 180 acres in total. The main production site is surrounded by an embankment and occupies an area of approximately 31 acres.

The main elements of the production area are as follows:

Main production building and office.

Refiner and dryer building.

Fibre storage and blending.

Main Energy Plant.

Log storage.

Bark Storage.

Wood Chip storage.

Debarker building.

Surface water interceptor lagoons.

Effluent treatment plant.

Fire water reservoir.

External bulk chemical storage.

The production facility was established on a greenfield site and there are no other known historic land uses that could have potentially given rise to groundwater or soil contamination at the site.

5.3 SITE PROCESSES

A Plant Process Flow Diagram (Drawing EN/000-IPPC-003) outlines the sequencing of activities carried out at the manufacturing facility. Pulpwood logs arrive by truck and are unloaded and stored in the log yard prior to use. An operator driven grab machine loads the logs onto the debarker infeed conveyor. Bark is then removed and stored for use as boiler fuel or as a product for horticultural industry. The debarked logs are passed through a chipping machine for fibre production. The chips are then transported via conveyor to a chip storage yard.

Wood chips imported from sawmills are off loaded through an automatic truck tipper and conveyed directly to the storage area. A front loader is used to feed chips from the storage area into the chip-infeed hopper. The chips are then conveyed to a storage silo.

The chip refining process involves the chips being softened in pre steaming vessel and then through a Plug Feeder to a Steam Digester Column where chips subjected to high pressure steam. Excess water is squeezed out and the water is sent to the wastewater treatment plant. Softened chips are passed through refiner plates to create the wood fibre. The wet fibre is transported via a 100mm diameter blowline pipe to the dryer system. Resin and other additives (dyes, urea, MDI and fire retardant chemicals) are added after refining or drying.

The wood fibre is then dried by passing hot air through the tube dryers. The heat for drying is provided by steam from the boilers and the boiler flue gases. The dried fibre (3-14% moisture) passes over a continuous weigh belt and is conveyed to the Fibre Storage Bins.

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The next part of the process involves the forming of the wood products. The wood fibre mat is produced by the spreading of dried, resinated word fibre through Forming Heads. The wood fibre mat is then compressed. Excess wood fibre is re-cycled back into the wood fibre forming system. Cross cutting of the product occurs after pressing prior to cooling. The board is then cooled, stacked and removed for either storage or sanding.

The finishing process includes the sanding of the boards. Any dust generated is removed to boiler and used as a fuel source. Saw off-cuts are hogged and conveyed pneumatically to boilers and energy plant for use as a fuel. Packed units are loaded by forklift onto flat bed trailers for storage prior to transport.

5.4 INCIDENT HISTORY

A list of reported incidents has been obtained from a review of the historic data for the site has been undertaken. Information on non-compliances, accidents and incidents with potential for impact on soil and groundwater have been obtained from the Residuals Management Plan (prepared by Environet Consulting Ireland Ltd., February, 2014) and from the AER returns from 2008 to 2013 which are available to view on the EPA licensing website. There are no reported incidents from the Facility Manager that may have had an impact on soils or groundwater since the facility was established.

Table 5-1: Incident History at the Medite Facility

Year Incident Scale of Incident Potential for

Groundwater or Soil Contamination

2004 Emissions to water – ELVs for COD & BOD exceeded twice. ELV for flow exceeded twice.

Minor No potential

2005 Emissions to surface water – ELV for phenol exceeded twice.

Minor No potential

2006 Emissions to surface water – ELV for flow exceeded 13 times due to excessive rainfall.

Minor No potential

1996 - 2010

Operation of on-site landfill for disposal of settled solids from the surface water interceptors and lagoons; wood dust; culled MDF; soil from site levelling; dilute resin residue washes and clean soil. Resulted in elevated ammonia concentrations in groundwater. However it has been concluded that ammonia is naturally biodegrading and the groundwater quality moving off site is of satisfactory quality.

Moderate Potential for groundwater contamination.

2013 Breach of ELV at SW2 on 21/03/14 minor incident due to adverse weather.

Minor No potential

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5.5 SITE INVESTIGATIONS

The results of the site investigations undertaken at the site to date are discussed in further detail in Section 6.2.5. The investigation at part of the site formerly used as a landfill for waste generated on site included the excavation of 4 no. trial pits and the installation of up gradient and down gradient monitoring boreholes. Waste material was only encountered in TP3. Some of the material in the landfill contains additives containing ammonia and phosphate. The ammonia is considered to be related to degradation of resin wastes, contained in sawdust and sludges which were disposed of to landfill. The historic monitoring at the site indicated elevated ammonia concentrations in LF1 and LF2 however the monitoring at down gradient monitoring locations MW2, MW3 and MW4 indicates no contamination down gradient of the site. The results of the long term groundwater monitoring program are discussed below in Section 5.6.

5.6 PREVIOUS MONITORING

An IPC Licence was granted for the site in November 2001. There are 6 no. groundwater monitoring locations at the site as shown on Drawing EN/000-IPPC-008: Ground Water Well Location. 4 no. of the monitoring wells were installed in 1995 (MW1/AGW3, MW2 / AGW4, MW3/AGW5 and MW4/AGW6) the boreholes have subsequently been re labelled. Two further groundwater monitoring boreholes were installed in 1997 these being LF1/AGW1 and LF2/AGW2. A summary of the monitoring installations is provided in Table 5.2. A copy of the borehole logs are provided in Appendix D. The results of groundwater monitoring for the period 2000 to 2014 have been reviewed.

Table 5-2: Summary of Groundwater Monitoring Locations.

Borehole Code Location Monitoring Interval

MW1/AGW3 Up gradient of landfill 4m to 34mbgl in bedrock with dolomite bands.

LF1 / AGW1 Down gradient of landfill 30m to 36mbgl. Bedrock heavily weathered & dolomitised.

LF2 / AGW2 Down gradient of landfill 12m to 25mbgl in bedrock some fissures.

MW2 / AGW4 Down gradient of landfill 3m to 17m in sand & gravel and bedrock.

MW3 / AGW5 Down gradient of factory 12m to 16.5m in top of bedrock.

MW4 / AGW6 Down gradient of factory 1m to 20m in clay overburden and top of bedrock.

MW1/AGW3 is located up gradient of both the site and former landfill and represents the background groundwater quality up gradient of the site. Monitoring borehole MW3/AGW5 and MW4/AGW6 are located down gradient of the plant and are considered representative of the down gradient quality. Monitoring locations LF1/AGW1, LF2/AGW2 and MW2/AGW4 are located up gradient of the plant but are located down gradient of the former on site landfill. The data from 2014 is summarised in Table 5.3. The values in summary table are for Total Metals concentration rather than Dissolved Metals Concentrations.

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Higher sulphate concentrations seen at LF1 and LF2 than at the up gradient or down gradient monitoring locations. The concentration down gradient at MW2, MW3 and MW4 is higher than the up gradient or background monitoring location. The ammonia concentration at LF1 and LF2 are higher than the up gradient concentration and the IGV value for groundwater 0.15 mg/l and the drinking water limit 0.30 mg/l. However the concentrations have reduced at the facility boundary as seen in MW2, MW3 and MW4 which indicate no issue with the ammonia concentration down gradient of the site in 2014. The chloride concentrations at LF1 and LF2 are marginally higher than the up gradient and down gradient concentrations but the concentration at all locations is less than the IGV of 30 mg/l. The concentration of nitrate at LF2 is higher than the level seen up gradient or down gradient and is associated with the breakdown of the ammonia containing waste in the former landfill. The TOC at LF1 and LF2 is elevated in comparison to the up gradient and down gradient concentrations.

Formaldehyde was not detected in the groundwater samples during 2014. The heavy metals concentrations are generally low at the site. The concentration of arsenic, cadmium, chromium and mercury were below the IGV for groundwater and drinking water limit at all locations on all sampling dates in 2014. Minor exceedances were measured at MW1 in relation to copper, lead and nickel during the Quarter 3 round of analysis. The concentration of nickel in LF1 and LF2 are above the IGV and drinking water limit of 0.02 mg/l on all 2014 sampling dates but the concentration down gradient of the site is not elevated. The concentration of zinc at LF1 is also above the IGV of 0.1 mg/l but less than the drinking water limit of 5 mg/l. The zinc concentration is reduced down gradient of the site. The monitoring results indicate that the degradation of the landfilled material is taking place but is not causing groundwater contamination down gradient of the site.

Total Petroleum Hydrocarbon TPH concentrations above the limit of detection (LOD) were detected at MW1 in Quarter 1 and MW2 in Quarter 2 and Quarter 3. However the concentrations in the subsequent sampling rounds were once again less than the LOD. The concentration of Volatile Organic Compounds VOCs have been less than the limit of detection on all sampling dates. Toluene was has been detected on a number of occasions in the past but the levels have been less than the Interim Guideline Value for groundwater of 10 ug/l on all occasions. Toluene has been detected in MW1 in 2013 in Q1 at a concentration of 1.48 ug/l, MW2 at 1.54 ug/l Q1 and 1.44 ug/l in Q2, MW3 at 1.23 ug/l in Q1. MW4 1.57 ug/l in Q1 and 1.26 ug/l in Q2. LF1 1.4 ug/l Q1. All other samples were less than the LOD of 1 ug/l.

Groundwater monitoring indicates satisfactory groundwater quality with the exception of occasional elevated ammonia concentrations in the vicinity of the former landfill. The main contaminants of concern relate to the migration of contaminants from the former landfill site. Elevated concentrations of ammonia associated with the degradation of Urea Formaldehyde resin and MDI resin. Elevated levels of phosphate were expected as it had been reported that a phosphate compound would be present as a result of the presence of AMGARD. However, the concentration of ortho-phosphate is the same up gradient and down gradient of the site.

A detailed qualitative risk assessment and impact appraisal of the landfill site was undertaken by by GES Limited in 1998 (GES Report No. 98/29/01). The risk assessment indicated elevated concentrations of ammonia down gradient of the site but concluded that there was adequate attenuation and dilution down gradient of the landfill ensuring no significant movement of contaminants.

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Based on a review of the historical monitoring results and the most recent data for 2014 there is no evidence that contamination is migrating offsite. The results are tabulated in Appendix E.

Summary charts have been prepared (Figure 5.1 to 5.7) from the 2000 to 2014 groundwater monitoring data for ammonia, chloride, nitrate, iron, manganese, aluminium and orthophosphate as these were identified as varying with time.

It should be noted with respect to nitrate some of the analysis may have reported as N rather than N03. On the summary charts concentrations that were reported as being less than the LOD have been presented on the graphs as zero concentration. There also appears to be an issue with the reporting of ammonia concentration. The 2013 ammonia results are being reported as NH3-N while the 2012 results were reported as N and NH4. It is not clear what the pre 2012 results were reported as.

Figure 5-1: Nitrate Concentration in Groundwater 2000 to 2014

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Figure 5-2: Ammonia Concentration in Groundwater 2000 to 2014

Figure 5-3: Chloride Concentration in Groundwater 2000 to 2014

The elevated ammonia concentrations at monitoring location LF2/AGW2 is considered to be related to degradation of resin wastes, contained in sawdust and sludges disposed of to landfill. Some of the material in the landfill contains additives containing ammonia and phosphate. The changes in iron, manganese and nitrate concentrations are considered to be related to changes in redox state of groundwater as a result of oxygen consumption during the biodegradation process. The trends suggest migration of reduced (low oxygen) groundwater with inorganic contamination from the landfill towards the southeast. The rate of migration is slow and does not appear to be any impact on down gradient wells to date. There has been no evidence of elevated ammonia at the down gradient monitoring locations MW2/AGW4, MW3/AGW5 or MW4/AGW6.

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6 STAGE 5 – ENVIRONMENTAL SETTING


The Baseline Report Guidance specifies that the following details are required for Stage 5:

Identify the site’s environmental setting including:

Topography.

Geology.

Direction of Groundwater Flow.

Other potential migration pathways such as drains and service channels.

Environmental aspects (e.g. particular habitats, species, protected area etc.).

Surrounding land use.


6.2.1 Background

Medite operate a facility at Redmondstown, Clonmel where Medium Density Fibreboard (MDF) is manufactured for a range of industrial, commercial and domestic applications. The production facility has been in operation at this location since 1983. While the production capacity has increased there has been no expansion of the area occupied by the facility. Aerial photography for the area indicates no significant change in the layout of the site between 1995 and the present day.

6.2.2 Topography

The main production site is approximately 12.6 hectares (31 acres). The production facility was developed on a greenfield site. The land in the vicinity of the site slopes in a south easterly direction towards the River Suir. The 1:50,000 scale Ordnance Survey of Ireland map (OSI) indicates that the site is located at elevation of 20m to 35mOD. The original land surface sloped from 45mOD in the northwest of the site to 22mOD in the southeast. During the construction of the plant in 1982 the topography of the site was altered to form a level working area. This has resulted in the creation of steep embankments along the northwest boundary of the site.

The site is composed of the main production plant buildings and materials storage areas as shown on Drawing EN/000-IPPC-001: Site Location Plan (Appendix F). The surface is a mix of concrete and asphalt. All areas associated with the facility’s operations are hardstanding. A number of landscaped areas are located along the perimeter of the site. A former landfill site is located on the elevated ground north west of the plant, north of the Log Yard and Chip Store.

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6.2.3 Hydrology

The River Anner flows in a north to south direction approximately 100m east of the site. The River Anner discharges to the River Suir approximately 1km down gradient of the site at Anner Bridge. Information from the EPA Map Viewer indicates a Q rating of Q4 good status for surface water quality on the River Anner approximately 600m downstream of the site. The closest surface water quality monitoring stations up gradient of the site on the River Anner is located at Thorny Bridge, approximately 5km upstream, where a Q4 good status is also reported. The River Moyle, a tributary of the River Anner, has a Q2-Q3 Poor Status at bridge up stream of Anner River confluence also located approximately 5km upstream of the site.

The WFD Risk Score for both the River Anner and River Suir is Category 1a – at risk of not achieving good status. The River Anner is classed as “Good Status” for both the 2007 to 2009 and the 2010 to 2012 periods. While the River Suir is classed as moderate status.

Figure 6-1: Location of Surface Water Features

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There is an EPA hydrometric gauge flow recorder on the River Anner approximately 2km upstream of the Medite Plant (Station 16010). Information on the mean annual flows for the River Anner has been obtained from the hydro data website (Office of Public Works). The mean annual flow is reported as 6.3337 m3/s (1954 to 2005) while the 95%ile flow is 1.29m3/s.

6.2.4 Geology and Hyrdrogeology

Information on the regional geology and hydrogeology has been obtained from the following data sources:

The Geological Survey of Ireland (www.gsi.ie online mapping);

GSI 1:100,000 Bedrock Geology Map (online version)

GSI 1:10,560 Field Sheets

Ordnance Survey of Ireland online historic mapping and aerial photographs (www.osi.ie)

EPA Envision Map Viewer (www.epa.ie);

Site Investigation Reports (2014 Priority Geotechnical Ltd Report No. P13131 (27/03/2014); Geotechnical & Environmental Services Ltd. Risk Assessment Report (Report No. 98/29/01) and the 1981 Site Investigation Results.

Figure 6-2: Location of Medite Facility

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Overburden Geology Information on the overburden geology is available from the EPA website and GSI website. The subsoil data from the Teagasc Subsoil Map indicates the site is underlain by Made Ground (blue area). In the immediate vicinity of the site the subsoil is composed of low permeability till (TNSSs) which is described as shale and sandstone till with a clayey texture as shown in Figure 6-3 (green area). Alluvial deposits (yellow area) are mapped to the east of the facility in the vicinity of the River Anner and to the south in the vicinity of the River Suir. Figure 6-3: Teagasc Subsoil Map (Extract from GSI website)

Bedrock Geology The 1:100,000 series map (Figure 6-4) which is available to view online (www.gsi.ie) indicates the Waulsortian Formation (WA) underlies the site. This formation is composed of massive unbedded lime mudstone. This formation forms underlying bedrock in the area between Redmondstown and the River Suir. The Waulsortian formation typically has a weathered zone of 2m to 3m at the top of bedrock. The 1:10,560 field sheets describe the bedrock as grey clean compact limestone which is known to be dolomitied in places. The cleaner limestones is interbedded in places with more clayey limestone (argillaceous).

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Figure 6-4: Bedrock Geology Map (Extract from GSI website)

To the north of the site moving upwards in the rock sequence the Silversprings Formation (SS) forms the bedrock. This is described as a bedded cherty and dark grey limestone. This formation in turn is overlain by the Kilsheelan Formation (KS) which is described as a limestone which is occasionally cherty.

The structure of the area is characterised by east to west trending folds. The Carboniferous limestone bedrock forms the low lying ground in the vicinity of the River Suir. The higher ground to the north and south of Clonmel is composed of Devonian aged sandstone rocks. The Clonmel area is cross cut by a series of north to south trending faults. There are no faults identified on the 1:100,000 series bedrock geology map in the vicinity of the site.

Hydrogeology

The County Tipperary (South Riding) Groundwater Protection Scheme was completed by the GSI in 2001. Information on the aquifer classification for the study area has been obtained from the GSI online mapping (www.gsi.ie) and is presented in Figure 6-5.

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Figure 6-5: Aquifer Map (Extract from GSI website)

The Waulsortian Limestone is classed as a Regionally Important Aquifer Karst Aquifer (RKd) which is characterised by having diffuse flow due to the development of karst. Groundwater movement in this bedrock will be controlled by secondary permeability as a result of the development of structural features such as fault zones, karstification, dolomitisation and weathering. This leads to a wide variation in transmissivity in different areas.

A Regionally Important Aquifer would typically be capable of providing large abstractions for public water supply schemes (potentially well yields > 400m3/d) suitable to supply regional water supply schemes and large industries. In South Tipperary well and spring yields ranging from 196 to 21,600m3/d are reported by the GSI from this aquifer. The hydraulic gradients are typically low ranging from 0.003 to 0.007 which indicates well developed permeability.

To the south and north of the site the bedrock is classed as a Locally Important Aquifer (Ll) i.e. bedrock which is moderately productive only in local zones. There are no locally or regionally important sand and gravel aquifers in the area. There are springs to the north east of the site (north east of the former proposed extension area) which discharge to the River Anner. The springs are illustrated on the historic 25” to 1 mile series maps but not on the more recent OSI maps.

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There are no EPA or GSI Source Protection areas indicated on the GSI website in the vicinity of the proposed development.

The proposed development area is also located within the Clonmel B groundwater body. A description is available for the adjacent Clonmel Groundwater Body from the GSI website but not for the Clonmel B Groundwater body. The groundwater body description indicates “most of the groundwater moves rapidly along short flow paths and discharges into the streams which cross the aquifer”. There are reported to be considerable variations in the hydrogeological conditions in this aquifer due to its karstic nature. A review of the GSI online mapping indicated no karst features in the immediate vicinity of the proposed development area with the exception of boreholes indicating potential for karst.

The GSI Aquifer Vulnerability map indicates the vulnerability of the first groundwater encountered in either sand / gravel aquifers or in bedrock to contaminants released at depths of 1 – 2m below ground surface. The GSI have classed the vulnerability of the groundwater in the bedrock aquifer in the vicinity of the site as moderate (yellow) to high (orange area) (Figure 6-6).

Figure 6-6: Vulnerability Map (Extract from GSI website)

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Information from the GSI groundwater well database includes the monitoring boreholes MW1 to MW4 (green dots). The only additional borehole indicated down gradient of the site is 2311NWW051 which is reported to be an industrial well drilled to 3mbgl. There is potential for additional private wells within the study area which may not be indicated on the GSI well database. However the presence of the public water mains in the areas reduces the likelihood for a significant number of private wells in the area. There is no groundwater extracted for use on site. It is estimated that approximately 300m3/year of groundwater is abstracted during the purging of the groundwater monitoring boreholes prior to sampling. 344,246m3 / year surface water is abstracted from the River Anner to supply boiler feed water to the facility and to maintain the firewater reservoir. In the order of 13,063m3/ year of water is supplied by the public water supply.

Figure 6-7: GSI Well Database (Extract from GSI website)

Information from the EPA map viewer indicates the groundwater body status is classed as “good status” for 2007 to 2009 and 2010 to 2012.

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6.2.5 Results of Previous Site Investigation

2014 Site Investigation

A site investigation programme (Draft Report No. P13131 (27/03/2014)) was undertaken by Priority Geotechnical Ltd. in February 2014 to provide geotechnical and environmental information for use in the design of the proposed extension development immediately north of the existing facility. The field work was undertaken between 10th December 2013 and 7th February 2014. While this data is from the proposed extension area adjacent to the current site it provides information on the general geological and hydrogeological conditions in the area.

The 2014 site investigation report details the results of the geotechnical and chemical testing that was undertaken. A summary of the main findings of the site investigation is provided in Table 6.1 and summarised below while a full copy of the site investigation report is contained as Appendix C. The locations of the site investigation borings are illustrated on the Exploratory Hole Location Plan contained within Appendix C. The site investigation comprised of the following:

19 no. cable percussion boreholes (BH01 to BH17, BH08A & BH13A) to depths from 0.5m to 14.4m;

6 no. rotary boreholes (RC01 to RC06) to depths ranging from 15.0m to 20.2m;

22 no. trial pits (TP01 to TP16: 1.4m to 4.5m, SK01 – SK02: 1.6m to 2.1m, PBT01 to PT04: 1.5m);

Groundwater levels were recorded during drilling and the excavation of the trial pits;

Standard penetration tests;

1 no. in situ falling head permeability test k = 2.33 x 10-6m/s (BH17);

Infiltration test in SK01 and SK02;

Soil testing included natural moisture content, atterberg limits, particle size distribution, pH, sulphate, chloride, loss on ignition, moisture condition value, California bearing ratio;

Rock testing included point load index.

The 2014 site investigations confirm the presence of boulder clay across the site. The boulder clay is described as sandy gravelly clay with variable content of cobbles and boulders. The drilling phase confirms the boulder clay to depths of 3.0m below existing ground level (b.g.l) to 20.2 mbgl. Typically there was an increase in gravel and cobble content below depths of 2.0mbgl and the cable percussion boreholes were terminated frequently on cobbles. Gravel was identified below 1.8mbgl (BH12) and 4.0mbgl to depths of 7.0mbgl (BH04) and in BH07 from 8.0mbgl to 14.4mbgl. A number of the boreholes were terminated on cobbles. The site investigation data indicates the vulnerability ranges from high to low.

The rotary drilling phase indicates top of bedrock ranging from 4.50m bgl at RC04 to the north of the log yard > 20.20mbgl at RC01 to the north of the previously proposed extension are. The variation in the top of bedrock is related to the karstified nature of the bedrock.

The site investigations confirmed the presence of fossiliferous limestone with calcite veining which was cherty in places. The top of bedrock was weathered and fractured. Iron oxide staining was observed in RC06. The top of bedrock was only proven at 3 no. drilling locations. At 4.5mbgl at RC04, at 14.5mbgl in RC03 and in RC06 gravel was encountered between 14.60m and 20m which was interpreted as weathered rock. In RC04 the bedrock was described as medium strong to strong.

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RC03 and RC04 had only slight evidence of weathering. A summary of the results of the 2014 drilling phase is provided in Table 6.1.

Table 6-1: Summary of 2014 Site Investigation Drilling Phase

Code Elevation

(mAOD)

Total Depth

Water Strike

Overburden Description Depth Top

Bedrock (mbgl) Rock

Description

BH01 22.22m 0.60m N/A Slightly sandy slightly

gravelly CLAY N/A N/A

BH02 22.14m 3.10m N/A Slightly sandy slightly

gravelly CLAY N/A N/A

BH03 22.71m 7.10m 5.00m Sandy & gravelly CLAY to

3m, over clayey sandy GRAVEL.

N/A N/A

BH04 24.21m 6.10m N/A

Sandy gravelly CLAY to 4m over 1m of clayey gravelly SAND over 1.1om of clayey

and sandy GRAVEL.

N/A N/A

BH05 23.45 7.00m N/A

Gravelly sandy SILT to 1m, over 2m of clayey very

sandy GRAVEL over 2.5m of sandy gravelly CLAY over

1.50m of clayey very sandy GRAVEL.

N/A N/A

BH06 25.02m 9.20m N/A 0.30m SILT over 6.70m of sandy gravelly CLAY over 2.20m of sandy GRAVEL

N/A N/A

BH07 27.64m 14.40m 9.40m Sandy & gravelly CLAY to 8m

over 6.40m of clayey and sandy GRAVEL

N/A N/A

BH08 28.75m 0.90m N/A Sandy gravelly CLAY N/A N/A

BH08A 28.65m 1.20m N/A Sandy gravelly CLAY N/A N/A

BH09 28.46m 5.70m N/A Sandy gravelly CLAY to

5.60m N/A N/A

BH10 32.76m 2.70m N/A Sandy gravelly CLAY to

2.50m. N/A N/A

BH11 25.74m 2.10m N/A Sandy & gravelly CLAY N/A N/A

BH12 24.14m 4.20m N/A

Gravelly & sandy CLAY to 1.60m over boulder 0.20m over 2.30m of clayey and

sandy GRAVEL.

N/A N/A

BH13A 33.68m 0.50m N/A Sandy gravelly CLAY N/A N/A

BH13 33.68m 0.72m N/A Sandy gravelly CLAY N/A N/A

BH14 22.53m 9.20m N/A

Sandy CLAY to 1m over 6.50m of sandy & gravelly SILT over 1.70m of clayey

sandy GRAVEL.

N/A N/A

BH15 25.08m 1.20m N/A Sandy gravelly CLAY. N/A N/A

BH16 26.78m 7.90m N/A Sandy gravelly CLAY. N/A N/A

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Code Elevation

(mAOD)

Total Depth

Water Strike

Overburden Description Depth Top

Bedrock (mbgl) Rock

Description

BH17 22.47m 5.70m N/A Sandy & gravelly CLAY to

5.60m N/A

RC01 24.22m 20.20m

10.30m, 12.50m, 14.90m, 15.70m, 18.70m.

Boulder clay

RC02 22.26m 20.20m

3.00m, 10.10m, 14.90m, 17.60m.

3.10m to 4.50m GRAVEL rest of borehole boulder

clay. N/A N/A

RC03 27.77m 17.50m 14.00m, See BH03 14.40m

Fossiliferous Limestone with calcite

veining. Slightly

weathered & clay

smearing.

RC04 25.78m 16.50m 4.30m Gravel from 2.00m to

4.50m. 4.50m

4.50m to 6m weathered rock. At 6m fossiliferous

cherty limestone

with calcite veining and

oxide staining.

RC05 28.75m 15.00m 9.20m & 12.10m

Boulder clay. N/A N/A

RC06 22.31 20.00m 4.70m, 14.70m

Gravel 1.50m to 4.50m rest boulder clay.

14.60m

Weathered rock

recovered as gravel.

Groundwater was encountered in the trial pits are depth of 1.4mbgl to 3.9mbgl. During the drilling operations groundwater was encountered in the cable percussion boreholes at a depth of 5.0mbgl to 9.4mbgl. In BH03 groundwater was encountered at 5.00mbgl in gravel and in BH07 at 9.40mbgl in gravel. During the drilling of the rotary boreholes groundwater was encountered at depths ranging from 3mbgl to 18.7mbgl in the boulder clay.

The PGL interpretative report (Report No. P13131_INT) contains estimates of permeability based on the particle size distribution grading analysis. The following results were reported: slightly gravelly sandy clay with a permeability of 4 x 10-8m/s to 2.2 x 10-6m/s. Gravel strata gave results of order of 3.9 x 10-5m/s to 1.8 x 10-3 m/s.

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MCC0721Rp0001F01 46

Geotechnical & Environmental Services Ltd. – Risk Assessment Report (Report No. 98/29/01) date 16/07/1998.

This report involved a qualitative environmental risk assessment and impact appraisal of the on-site landfill. This report makes reference to geotechnical information for the site from June 1981. A copy of the site investigation report is not contained in the GES report but a summary of the site investigation is provided. The site investigation included the drilling of 21 no. borehole to depth of 2.0m to 6.0mbgl. The 1981 site investigation indicated 2m to 3m of medium gravel which in places may be completely weathered rock. The gravel was overlain by silty clay and topsoil. The depth to bedrock was reported as generally < 5m.

It has not been possible to review the borehole logs from this phase of investigation but based on the reported depths it is considered likely that they were cable percussion boreholes. It is possible that they were terminated on obstructions rather than true bedrock. Therefore there use in the development of the Conceptual Site Model is limited.

There was a subsequent report (E95-05-01 GES, 1995) which included information on installation of 4 no. monitoring points (MW1, MW2, MW3 and MW4) which were installed in 1995. In 1997 additional drilling was undertaken for the installation of LF1 and LF2 for monitoring of groundwater composition down gradient of the landfill. The excavation of 4 no. trial pits was also undertaken as part of the 1997 site investigation. The trial pits indicate made ground overlying a light brown stiff gravelly clay. Waste material was only encountered in TP3. The results of this phase of investigations are summarised in Table 6-2. These boreholes were drilled on the perimeter of the production facility. These boreholes indicate a variation in depth of bedrock ranging from 4mbgl at LF2 to 27mbgl at LF1. Over much of the site the depth to bedrock would appear to be > 10mbgl.

Table 6-2: Summary of Results of Installation of Monitoring Boreholes

Borehole NGR Overburden

Type & Thickness

Total Depth

Groundwater - Strikes & Static

Water Levels

Monitoring Interval

Bedrock Description

AGW1 / LF1

(Jan 1997)

223946E

124301N

27m clay, sand & gravel.

37m 27m to 33m. SWL 8.93m 07/07/98.

30m to 36m in bedrock.

Rock @27mbgl limestone bedrock completely dolomitised. 6m of heavily weathered dolomite 27m to 33m.

AGW2 / LF2

(Jan 1997)

224010E

124274N

4m. 25m SWL 7.52 07/07/98.


Rock @ 4m bgl pale dolomite. No weathering fissures @ 18m, 20m & 24m.

AGW3 / MW1

(27/05/95)

223798E

124380N

4m of gravelly clay

34m Strike @30m

SWL 24.23m 07/07/98. 24.8mbgl on 29/05/95.


Rock @ 4mbgl limestone bedrock. Bands of dolomite.

AGW4 / MW2

(29/05/95)

224193E

124297N

10m of sand & gravel

17m

3.3m SWL 07/07/98.

3.7mbgl 06/06/95.

3m to 17m. Limestone @10mbgl

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Borehole NGR Overburden

Type & Thickness

Total Depth

Groundwater - Strikes & Static

Water Levels

Monitoring Interval

Bedrock Description

AGW5 / MW3

(29/05/95)

224312E

124060N

12m sand

16.5m

1.75mbgl on 06/06/95

12m to 16.5m in bedrock.

Limestone @ 12mbgl.

AGW6 / MW4

(01/06/95)

224279E

123936N

17m clay

20m 1.75mbgl on 06/06/95

1m to 20m Limestone @ 17mbgl.

6.2.6 Groundwater Quality

The Medite Facility is located within the South Eastern River Basin District. Information on the background groundwater quality in the area is available from the EPA website. The Water Framework Directive (WFD) status 2007 to 2009 and 2010 to 2012 for groundwater are both classed as good status while the WFD Risk Score is classed as 1a – at risk of not achieving good status.

A detailed qualitative risk assessment and impact appraisal of the landfill was undertaken by GES Limited (GES Report No. 98/29/01). This report indicated elevated concentrations of ammonia down gradient of the site. The investigations indicated adequate attenuation and dilution down gradient of the landfill ensuring no significant off site movement of contaminants. The review of the monitoring data confirm that the operation of the facility is not having an impact on the down gradient groundwater quality.

6.2.7 Groundwater Flow

The regional groundwater flow direction is expected to be in a south easterly direction towards the River Anner and River Suir. On-site monitoring carried out by IE Consulting Engineers on the 05/12/2013, 25/06/2014 and 18/12/2014 indicates groundwater flow directions to the south-east, south/south-east and south. The results of groundwater level monitoring indicate an annual water table fluctuation of the up to 6m based on the 2006 to 2010 data (fluctuation of 1.5m to 5.8m).

6.2.8 Other Potential Migration Pathways

Information on the location of underground tanks and pipes is presented in Drawing EN/000-IPPC-011. This drawing shows the extent of the drainage system associated with the effluent collection and storm water drainage.

There is potential for the preferential migration of contaminants along the backfill material surrounding service ducts and pipeline. There is a programme in place for the testing and inspection of all underground effluent and foul sewer pipes at least once every three years. Remedial works are carried out as required and include works to the wood log storage area. This potential is discussed further in Section 7.2.2 Pathway details.

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MCC0721Rp0001F01 48

6.2.9 Environmental Aspects

A search of the NPWS website indicates the Lower River Suir Special Area of Conservation (SAC) includes the River Anner which is located immediately east of the site on opposite side of the road. There is no indication of springs in the area to suggest the presence of groundwater dependant ecosystems in proximity to the proposed development area. There is potential for the discharge of contaminants from the site to the SAC via the discharge of contaminated groundwater to the river or through the discharge of contaminated surface water runoff. An Appropriate Assessment has been completed with respect to the discharge of waste water from the facility by Aquafact International Services Ltd. in March 2011 which concluded that “it is unlikely that there will be any negative effects felt on the river environment due to the Medite facility effluents.

6.2.10 Surrounding Landuse

The landuse to the north-west and up gradient of the site is composed of agricultural land. There is industrial and commercial development to the south and down gradient of the site.

6.2.11 Environmental Setting Conclusion

The Conceptual Site Model has been developed based on the site investigation data and is summarised on Figure 6.8.

The various site investigations indicate top of bedrock ranged from 4.50mbgl to 27mbgl. The overburden deposits appear to be > 10m in thickness across much of the site with the exception of the area (RC04 / LF2) immediately up gradient of the site to north east of the log yard (south east of former landfill site). The overburden is composed mainly of sandy gravelly clay with cobbles and boulders. There are also gravel horizons within the boulder clay and on the top of bedrock. The main groundwater movement in the overburden is expected to be within the gravel deposits which had permeability values of 3.9 x 10-5m/s to 1.8 x 10-3 m/s. The thickness of overburden would provide good protection of the groundwater quality beneath the site.

The top of bedrock is weathered in places typically between 2m to 3m but up to 6m on occasion. The bedrock is classed as a Regionally Important Karst Aquifer and groundwater flow is controlled by the development of secondary permeability and expected to be concentrated in the weathered top of bedrock interval and at deeper levels within zones of dolomitised and fractured bedrock.

The groundwater flow direction is towards south east towards the River Anner and River Suir. There are no potential downgradient groundwater abstractions indicated. The main pathways for the movement of contaminants off site is via the discharge to groundwater and / or the discharge to surface water runoff. It is expected that groundwater will be discharging to the River Anner and River Suir downgradient of the site and contamination of the surface water could also occur via discharge to groundwater.

The identified potential receptors are the (i) Regionally Important Karst Aquifer and (ii) River Anner & River Suir.

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MCC0721Rp0001F01 49

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MCC0721Rp0001F01 50

7 STAGE 6 – SITE CHARACTERISATION


The Baseline Report Guidelines specify the following details are required for Stage 6.

Use the results of Stages 3 to 5 to describe the site, in particular demonstrating the location, type, extent and quantity of historic pollution and potential future emissions sources noting the strata and groundwater likely to be affected by those emissions – making links between sources of emissions, the pathways by which pollution may move and the receptors likely to be affected.


The results of Stages 2 to 5 have been collated to present a standard Source-Pathway-Receptor model to establish the potential pollutant linkages, if any, for the relevant hazardous substances identified to cause or having caused ground (soil) or groundwater contamination.

7.2.1 Source Details

The following potential sources of contamination of soils and groundwater by hazardous substances have been reviewed based on the “relevant hazardous substances” identified in Stage 2:

Above Ground Bulk storage tanks (loss of material from tanks or bunds).

Spills from site machinery or process works on areas of hardstanding resulting in contamination of runoff leading to contamination of soil / groundwater.

Wastewater Treatment System.

Fire on site leading to production of contaminated fire water / firewater retention ponds.

Leakage of drains / pipelines.

Chemical stores (loss of materials from drum, IBCs or bunds).

Contamination from former landfill site (ammonia & phosphate).

Table 7-1: Total bulk storage capacities of “relevant hazardous substances”

Substance Storage Capacity Storage Location

Corrshield MD4100 200 L Boiler chemical

Steamate NA0840 400 L Boiler chemical

Steamate FM1000 400 L Boiler Chemical

Potassium Permanganate 50 L Boiler Chemical

Optisperse P05090 440 kg Boiler Chemical

Formic Acid 400 L WWTP chemical store

Toluene 100 L Chemical Store

Hydrated Lime 15 T WWTP chemical store

Aluminium Chloride 20 T WWTP chemical store

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Substance Storage Capacity Storage Location

Biofeed 6,000 L WWTP chemical store

Urea Formaldehyde Resin 700 L Raw Material

Green Process Dye 2,000 L Raw Material

Red Process Dye 1,000 L Raw Material

Moblitherm Fuel 1,000 L Fuel

Gas Oil 30,000 L Fuel

The location of chemical and oil storage locations are illustrated on Drawing No. EN/000-IPPC-010 bund and tank location (Sheet 2 of 2). Boiler Chemical The chemicals required for use in the boiler system (Corrshield MD4100, Steamate NA0840, Steamate FM1000, Potassium Permanganate & Optisperse P05090) are stored in the Chemical Drum Store. These materials are stored in drums within the chemical store. All storage locations have double containment (double skinned and / or tanks and bunds) which are integrity tested in accordance with the existing licence. In addition all storage areas are located in hardstanding areas (concrete or tarmac) which provide an additional barrier to groundwater contamination. Toluene is also stored here. Based on the containment measures in place and the low volumes of materials stored these substances are considered to be a low risk.

WWTP Chemical Store The Biofeed used in the WWTP are stored in the WWTP chemical Store (bund E). The Biofeed is stored in IBCs within the chemical store. The chemical store has a bund (Bund E) which is integrity tested in accordance with the existing licence. In addition the chemical storage area is located on a hardstanding area which provides an additional barrier to groundwater contamination. The Hydrated Lime is stored in a silo while the Aluminium Chloride is stored in an integrated bunded storage tank adjacent to WWTP. These substances are considered a low risk source.

Raw Materials The raw materials are stored in the chemical store. The Urea Formaldehyde Resin is stored in the chemical store adjacent to the refiner and fibre handling buildings in Bund A (resin tanks 11, 12, 13), Bund G (resin tanks 15, 16, 17, 19) and Bund D (resin tanks 21,22 & 23). Green Process Dye & Red Process Dye are stored in the production additives storage area. All of the storage areas are bunded and regularly tested with further containment provided by the hardstanding surface present in the surrounding area. These substances are considered a moderate risk source.

Fuel 1,000 litres of Moblitherm 605 is stored in an IBC in the chemical store. The fuel for Thermal oil Production Line 1 is stored in Tank 41 (storage volume of 22,000 litres) and contained within Bund Ref. J. While Thermal Oil for Production Line 2 is stored in Tank 38 (storage volume of 20,000 litres) within Bund Ref (I).

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Diesel fuel is stored in two above ground mild steel storage tanks located in the south west corner of the site, south of the Chip Yard. Tank 36 has a storage volume of 22,000 litres while Tank 37 has a storage volume of 2,750 litres. The diesel is used to power the large site vehicles.

The fuel is considered a moderate risk source.

Former Landfill While the former landfill is not listed under “Table 3.1 List of Relevant Hazardous Substances” it does need to be considered in terms of a potential source of contamination. The former landfill is located 50m northwest of the boundary of current facility. The landfill occupies an area of approximately 10,000m2. It is reported that small quantities of non-hazardous wastes were deposited on site between 1983 and 1996. The materials placed in the landfill included: settled solids from the surface water interceptors and lagoons; wood dust; culled MDF; soil from site levelling; dilute resin residue washes. It is reported that in 1994 considerable quantities of clean soil were deposited when construction work was taking place at the site. Between 1996 and 2010 the landfill was occasionally used for the disposal of small quantities of inert materials including topsoil, rocks and stones with approximately 50 tonnes per annum reported as being landfilled. The landfill was unlined and was built on the natural ground. The GES report indicated the following waste quantities.

Table 7-2: Historic Waste Quantities in Former Landfill Site

Description Weight Volume Potential Contaminants

Settled solids from surface water lagoons

2,000 tonnes 5,000m3 Contains 1% flame retardant additive

AMGARD & wood adhesive Urea Formaldehyde Resin.

Sander dust (fire resistant)

3,600 tonnes 10,000m3 6-8% AMGARD

Culled board Unknown Contains Urea Formaldehyde

Soil excavation Unknown Inert

In relation to potential contaminants AMGARD is an aqueous solution of Ammonium Polyphosphate (NH4PO3). It is completely miscible with water and is acutely toxic to fish with ammonia being released during the decomposition process. Liquid Urea Formaldehyde Resin contains < 1% Formaldehyde and 60-70% Urea Formaldehyde Polymer. The resin is soluble in water and has a pH of 8 and produces nitrate during decomposition.

Monitoring from 2000 to 2014 indicates elevated ammonia concentration in the vicinity of LF1 and LF2 which are located down gradient of the former landfill. However, monitoring further down gradient of the site, within the facility boundary, indicates that the ammonia concentrations return to background concentrations.

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7.2.2 Pathway Details

The identified pathways associated with the “relevant hazardous substances” have been outlined previously in Stage 3 of this report. None of the potential pathways identified for any of the “relevant hazardous substances” allowed a pathway to ground or groundwater. The pathways which were identified can be summarised as follows:-

Uncontrolled release / spillage of substances to hardstanding area during loading and unloading operations or transport of materials around the site.

Runoff of spilled material on hardstanding area to the surface water / stormwater collection system.

Loss of primary or secondary containment bunds.

A number of mitigation measures are in place to ensure that no pathway to ground or groundwater is present at the facility. The measures that have been implemented are as follows:-

Construction of bund structures to comply with 110% rule for tanks/bunds.

Integrity testing of bund structures every 3 years. All tanks and bunds are regularly inspected and bund testing is carried out in accordance with the licence requirements with maintenance carried out as required.

Integrity testing of storm water discharge system every 3 years.

Regular visual inspection of hardstanding areas is undertaken to monitor the condition of hardstanding areas with maintenance and repairs being undertaken as necessary.

The procedure on site for the containment of spillages has two phases – (i) containment of liquid in the tank bund and where this fails (ii) manual placement of sliding baffles to block off the route to normal discharge and to divert the runoff to the emergency lagoon.

Procedures in place for the use, handling and storage of all chemicals on site to ensure that the risk of spills is minimised. Training is provided to staff in relation to the handling and storage of all chemicals on site to ensure the risk of spills is minimised.

Regular routine maintenance programmes are in place for the process equipment, environmental process equipment, continuous monitors, laboratory equipment and sampling equipment.

The emergency response teams are also trained in containment measures with respect to spillages including procedures for containment including diverting spillages to the emergency holding lagoon; use of spill kits and pig tails; cleaning up using sand or earth and safe disposal of clean up materials.

There is potential for contamination of firewater at the site. The procedure on site is for the emergency response team leader to divert firewater to the emergency holding lagoon.

Measures are also in place within the storm water discharge system to ensure that the River Anner is not impacted through receiving storm water discharges. These measures are listed in Section 4.2.15 of this baseline report and the diversion of flow to the emergency holding lagoon via manual placement of sliding baffles to block off the route to normal discharge. The 2 no. lagoons that are in operation are used alternately so in the event of a sudden unnoticed spillage the lagoon in use will intercept the spillage. The emergency lagoon approx 4 times the largest storage tank.

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7.2.3 Receptor Details

There are no groundwater abstractions located down gradient of the Medite Facility. The area is served by the public water mains and there are no private wells indicated on the GSI well database down gradient of the site.

The site is located on a Regionally Important Karst aquifer. The site investigation data indicates the vulnerability ranges from low to high due to the variation in the depth of overburden. The presence of hardstanding over the majority of the facility protects the groundwater beneath the site from the site processes. The groundwater quality confirms that the current site processes are not impacting on the groundwater quality at the site. The groundwater in the immediate vicinity of the former landfill site is being impacted upon by the former landfill site. The landfill is not impacting on the groundwater quality down gradient of the facility.

The River Anner is a potential receptor and is located approximately 100m down gradient of the site and joins the River Suir approximately 1km further down gradient. Both the River Anner and River Suir are located within the Lower Suir cSAC. The groundwater in the area is expected to be discharging to the rivers. Both the surface water quality up gradient and down gradient of the facility is classed as Q4 good status and there is no evidence that the surface water quality is being impacted by the facility.

7.2.4 Conclusion

The assessment of the potential Source-Pathway – Receptor linkages concludes that there is no pathway present to ground or groundwater at the facility from the current site operations. The risk from the current site activities on the groundwater is considered to be low.

There is however a pathway present from the historic landfill to contaminate the groundwater beneath the former landfill site as seen in the elevated concentrations of ammonia. The results of the monitoring for 2014 confirm that the landfill site is not impacting on the groundwater quality down gradient of the site. It is recommended the current monitoring programme continue to monitor the situation. In the event of the concentrations of ammonia or heavy metals increasing at the down gradient monitoring locations (MW2, MW3 or MW4) remedial measures would have to be examined. Based on the age of the waste and the downward trends the risk of groundwater pollution is considered to be low.

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8 STAGE 7 – SITE INVESTIGATIONS


The Baseline Report guidance specify the following details are required for Stage 7.

If there is sufficient information to quantity the state of soil and groundwater pollution by relevant hazardous substances on the basis of Stages (1) to (6) then go directly to Stage 8. If insufficient information exists then intrusive investigation of the site will be required in order to gather such information. The details of such investigation should be clarified with the competent authority.


There is considered to be adequate site investigation data and environmental monitoring data to characterise the potential for soil and groundwater pollution at the site. No further intrusive investigations are recommended. A summary of the findings of the intrusive investigations and the environmental monitoring programme have been discussed in Section 5.5 and 6.2.5.

The conclusions of the baseline report are presented in Section 7.

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9 STAGE 8 – BASELINE REPORT CONCLUSIONS


The Baseline Report Guidance specifies that the following is required for Stage 8:

Produce a baseline report for the installation that quantifies the state of soils and groundwater pollution by relevant hazardous substances.

9.2 APPLICANT DETAILS/CONCLUSION

This document presents the baseline report which has been prepared in accordance with the “European Commission Guidance concerning baseline report under Article 22 92) of Directive 2010/75/EU on industrial emissions” (Reference 2014/C 136/03).

The process identified the relevant hazardous substances associated with the operation of the facility. The storage, use and handling of these substances is heavily controlled and regulated. There are a series of containment and control measures in place to prevent any potential pathway to ground. There are no reported historic spills or incidents relating to these substances. The 2014 monitoring indicates no issues with respect to groundwater quality in the down gradient monitoring locations.

Assessment of the potential Source-Pathway-Receptor pollutant linkages concludes that as no pathway to ground or groundwater is present at the Medite facility there are no pollutant linkages to ground or groundwater associated with the current activities. The risk of activities at the facility having caused or causing pollution to ground or groundwater is low.

The former landfill is impacting on the groundwater quality in the immediate vicinity of the former landfill but there is no evidence of contamination in the down gradient monitoring boreholes. The impact of the landfill causing pollution to groundwater down gradient of the site is considered to be low.

It is recommended that the current groundwater monitoring programme be continued. There are also plans as part of the EMP to install 2 no. additional groundwater monitoring boreholes during 2015 once approval is obtained from the EPA. These will provide additional down gradient monitoring locations for the measurement of groundwater levels and groundwater quality. The additional groundwater monitoring locations were chosen based on the up gradient site activities, groundwater flow direction, access for a drilling rig and presence of underground services.

Monitoring borehole AGW7 has been located to monitor up gradient activities of fuel, chemical and raw material storage areas, the chip yard and boiler house. Monitoring borehole AGW8 has been located to monitor the energy plant, warehouse/shipping, septic tank/percolation area and raw material storage area.

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APPENDIX A

HAZARD CLASSES

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Article 3 of Regulation (EC) No 1272/2008 (Parts 2 to 5 of Annex I)

Part 2: Physical Hazards

2.1 Explosives H200: Unstable Explosive

H201: Explosive; mass explosion hazard

H202: Explosive; severe projection hazard

H203: Explosive; fire, blast or projection hazard

H204: Fire or projection hazard

H205: May mass explode in fire

2.2. Flammable gases H220: Extremely flammable gas

H221: Flammable gas

2.3. Flammable aerosols H222: Extremely flammable aerosol

H223: Flammable aerosol

2.4. Oxidising gases H270: May cause or intensify fire; oxidiser

2.5. Gases under pressure H280: Contains gas under pressure; may explode if heated

H280: Contains gas under pressure; may explode if heated

H281: Contains refrigerated gas; may cause cryogenic burns or injury

H280: Contains gas under pressure; may explode if heated

2.6. Flammable liquids H224: Extremely flammable liquid and vapour

H225: Highly flammable liquid and vapour

H226: Flammable liquid and vapour

2.7. Flammable solids H228: Flammable Solid

2.8. Self-reactive substances and mixtures

H240: Heating may cause an explosion

H241: Heating may cause a fire or explosion

H242: Heating may cause a fire

2.9. Pyrophoric liquids H250: Catches fire spontaneously if exposed to air

2.10. Pyrophoric solids H250: Catches fire spontaneously if exposed to air

2.11. Self-heating substances and mixtures

H251: Self-heating; may catch fire

H252: Self-heating in large quantities; may catch fire

2.12. Substances and mixtures which in contact with water emit flammable gases

H260: In contact with water releases flammable gases which may ignite spontaneously

H261: In contact with water releases flammable gases

2.13. Oxidising liquids H271:May cause fire or explosion; strong oxidiser

H272: May intensify fire; oxidiser

2.14. Oxidising solids H271: May cause fire or explosion; strong oxidiser

H272: May intensify fire; oxidiser

2.15. Organic peroxides H240: Heating may cause an explosion

H241: Heating may cause a fire or explosion

H242: Heating may cause a fire

2.16. Corrosive to metals H290: May be corrosive to metals

Part 3: Health Hazards

3.1. Acute toxicity H300: Fatal if swallowed

H301: Toxic if swallowed

H302: Harmful if swallowed

H310:Fatal in contact with skin

H311: Toxic in contact with skin

H312: Harmful in contact with skin

H330: Fatal if inhaled

H331: Toxic if inhaled

H332: Harmful if inhaled

3.2. Skin corrosion/irritation H314: Causes severe skin burns and eye damage

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H315: Causes skin irritation

3.3. Serious eye damage/eye irritation

H318: Causes serious eye damage

H319: Causes serious eye irritation

3.4. Respiratory or skin sensitisation

H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled

H317: May cause an allergic skin reaction

3.5. Germ cell mutagenicity H340: May cause genetic defects (state route of exposure if it is conclusively proven that No other routes of exposure cause the hazard)

H341: Suspected of causing genetic defects (state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard)

3.6. Carcinogenicity H350: May cause cancer (state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard)

H351: Suspected of causing cancer (state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard)

3.7. Reproductive toxicity H360: May damage fertility or the unborn child (state specific effect if known)(state route of exposure if it is

conclusively proven that no other routes of exposure cause the hazard)

H361: Suspected of damaging fertility or the unborn child (state specific effect if known) (state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard)

H362: May cause harm to breast-fed children.

3.8. Specific target organ toxicity — single exposure

H370: Causes damage to organs (or state all organs affected, if known) (state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard)

H371: May cause damage to organs (or state all organs affected, if known) (state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard)

H335: May cause respiratory irritation;

H336: May cause drowsiness or dizziness

3.9. Specific target organ toxicity — repeated exposure

H372: Causes damage to organs (state all organs affected, if known) through prolonged or repeated exposure (state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard)

H373: May cause damage to organs (state all organs affected, if known) through prolonged or repeated exposure (state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard)

3.10. Aspiration hazard H304: May be fatal if swallowed and enters airways

Part 4: Environmental Hazards

4.1. Hazardous to the aquatic environment

H400: Very toxic to aquatic life

H410: Very toxic to aquatic life with long lasting effects

H411: Toxic to aquatic life with long lasting effects

H412: Harmful to aquatic life with long lasting effects

H413: May cause long lasting harmful effects to aquatic life

Part 5: Additional EU Hazard Class

5.1. Hazardous to the ozone layer

EUH059: Hazardous to the Ozone Layer

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APPENDIX B

MSDS SHEETS

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Material Safety Data Sheet ENVA

Envirifloc CL1000

Rev No: 1 Date: 04.04.10________________________________________________________________________________1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND

COMPANY/UNDERTAKING

A: Product Name : Envirfloc CL1000

B: Company : Enva Ireland Ltd Raffeen Industrial Estate

Ringaskiddy Co. Cork Ireland

C: Telephone : (+353)21-4387200 Telefax : (+353)21-4387299 Emergency Phone No :Office hours (+353)21-4387200

After office hours 086-8200771

________________________________________________________________________________2. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical characterisation:

A: Description: Aqueous blend of proprietary inorganic coagulants

________________________________________________________________________________3. HAZARDS IDENTIFICATION

A: Description: Corrosive

B: Hazardous components1. Description: Corrosive.2. Symbol: Corrosive

3. R-Phrases R35 Causes Severe BurnsR41 Risk of serious damage to eyes

________________________________________________________________________________Page 1 of 4

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Envirifloc CL1000

Rev No: 1 Date: 04.04.10________________________________________________________________________________4. FIRST AID MEASURES

A Eye Contact (i) Rinse well with water for at least 15 minutes- if irritation persists seek medical advice.

B Skin Contact (i) Wash with water. Remove contaminated clothing. Ifirritation persists seek medical advice.

C Ingestion (i) Do not induce vomiting. Wash out mouth with water.Seek immediate medical advice.

D Inhalation (i) Remove to fresh air and rest. If irritation persists seekmedical advice.

_______________________________________________________________________________5. FIRE-FIGHTING MEASURES

A Special Hazards (i) Not flammable

B Extinguishing media - Suitable (i) Use extinguisher suitable to cause of fire. C Special protective equipment for fire fighter (i) Wear chemical resistant clothing.

_______________________________________________________________________________6. ACCIDENTAL RELEASE MEASURES

A Personal Precautions (i) Avoid contact with skin and eyes.(ii) Wear protective clothing.

B Environmental Precautions (i) Keep away from drains.(ii) Avoid contact with surface water or

groundwater.(iii) Inform local authority in case of large spills.

C Methods for cleaning up (i) Collect with absorbent material such as sand or earth.

(ii) Flush small spills to drain using large amounts water.

(iii) Dispose of by following all local authority laws.

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Envirifloc CL1000

Rev No: 1 Date: 04.04.10

7. HANDLING AND STORAGE

A Handling (i) Avoid contact with skin & eyes. Wear gloves and goggles.

B Storage (i) Store in a cool area.(ii) Store in a bunded area.

________________________________________________________________________________8. EXPOSURE CONTROLS/PERSONAL PROTECTION

A General Protection (i) Do not allow material to enter drains.(ii) Avoid spillages.

B Personal Protection (i) Wear rubber gloves.(ii) Wear PVC gloves.(iii) Wear safety goggles.(iv) Wear full protective suit.(v) Wear boots.

________________________________________________________________________________9. PHYSICAL AND CHEMICAL PROPERTIES

(i) Appearance: Clear Liquid(ii) Odour: Negligible.(iii) Specific Gravity: 1.1-1.2(iv) pH: 0-3(v) Particulate matter Negligible

_______________________________________________________________________________10. STABILITY AND REACTIVITY

A Conditions to avoid (i) Extreme temperature

B Materials to avoid (i) Alkalis(ii) Oxidising Agents

C Hazardous decomposition products:Decomposition may lead to the formation of hazardous gases

________________________________________________________________________________11. TOXICOLOGICAL INFORMATION

(i) No experimental toxicity values available

_____________________________________________________________________Page 3 of 4

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Envirifloc CL1000

Rev No: 1 Date: 04.04.10________________________________________________________________________________12. ECOLOGICAL INFORMATION

(i) No experimental toxicity values available.(ii) Care should be taken in water treatment not to overdose the system. Low pH of

material may injure aquatic life in sufficient concentrations.______________________________________________________________________________13. DISPOSAL CONSIDERATIONS

(i) Dispose of observing all local authority regulation to an authorised disposal facility.

_______________________________________________________________________________14. TRANSPORT INFORMATION

(i) Primary Hazard – Corrosive(ii) UN Number: 2581(iii) Class 8 C1 PG III

_______________________________________________________________________________15. REGULATORY INFORMATION

A Labelling (i) Symbols, Corrosive(ii) R-phrases R35 Causes severe burns

R41 Risk of serious eye damage

(iii) S-Phrases S24 Avoid contact with skinS25 Avoid contact with eyesS36 Wear suitable protective

clothing________________________________________________________________________________16. OTHER INFORMATION

A Recommended uses and restrictions. This product is used in the treatment of wastewater. For correct dosing and application always consult with your Enva representative.

B Training advice. N/AC Further information. N/AD The information given in this data sheet is based on our current knowledge and is given in good faith. However it should not be construed as a warranty for which Enva Ireland Ltd. assumes legal responsibility.

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Manual: Material Safety Data – Liquids Written By: D O Dubhgain Title: Biofeed 15T Revision: 0 Section No: MSDL B067 Date: 18/05/2011 Approved by: Page: 1 of 3

1. PRODUCT AND COMPANY IDENTIFICATION

Product name: Biofeed 15T Product Use: Effluent treatment Supplier: Biocel Ltd, Rockgrove Industrial Estate, Glounthaune, Cork Phone: 021- 4353516 Email for SDS: [email protected]

2. HAZARD IDENTIFICATION Contact with Skin will cause irritation – contact with eyes may cause severe damage. Hazardous components:

1. Description, corrosive liquid 2. Symbol, corrosive 3. R phrases

R35 causes severe burns R41 Risk of serious damage to eyes.

3. COMPOSITION / INFORMATION

Chemical Characterisation: Aqueous nutrient blend containing nitrogen, phosphorous.

4. FIRST AID MEASURES SEEK MEDICAL ATTENTION

Eye contact: Rinse well with water for 15 minutes. Do not stop rinsing until medical advice is available. Skin Contact: Wash with water. Remove contaminated clothing. If irritation persists seek medical advice. Ingestion: Wash out mouth with water. Do not induce vomiting. Seek immediate medical advice. Inhalation: Remove to fresh air and rest. If irritation persists seek medical advice.

5. FIRE FIGHTING MEASURES Special Hazards: May give off ammonia fumes and other hazardous materials when burned. Extinguishing Media – suitable: Foam, Carbon Dioxide, Water Spray/jet, Powder. Special Protective equipment for fire-fighter: Wear self contained breathing apparatus. 6. ACCIDENTAL RELEASE MEASURES

Personal Precautions: Wear protective clothing, Wear gloves/goggles. Environmental Precautions: Keep away from drains, avoid contact with surface water or ground water, inform local authority in case of large spills. Methods for cleaning up: Collect with absorbent material such as sand or earth, place in a skip.


Handling: Avoid contact with skin & eyes. Wear gloves and goggles. Emergency shower and eye wash facilities should be available. Storage: Store in a bunded area. Corrosive to steel.

8. EXPOSURE CONTROL/PERSONAL PROTECTION General Protection: Ensure Material is stored in a well ventilated area. Do not allow material to enter drains. Avoid spillages. Personal Protection: Wear PVC gloves. Wear safety goggles. Wear full protective suit.

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9. PHYSICAL & CHEMICAL PROPERTIES Appearance: Pale greenish/brown liquid Odour: Characteristic PH: 1.5 – 3.5 Specific Gravity: 1.1 – 1.2 Solubility: Complete Part. Matter: Negligible Shelf Life: 12 months

10. STABILITY & REACTIVITY Conditions to avoid: Stable under normal conditions. Materials to avoid: Alkalis

11. TOXICOLOGICAL INFORMATION No experimental toxicity values available. Skin irritation. Eye Irritation.

12. ECOLOGICAL INFORMATION As material has a low PH it will have a detrimental effect on aquatic life should it enter a waterway

No experimental toxicity values available. 13. DISPOSAL

Dispose of observing all local authority regulation to an authorised disposal facility.

14. TRANSPORT INFORMATION UN Number: 1850 Proper Shipping Name: Phosphoric acid solution. ADR/RID Class: 8 Packaging Group: III

15. REGULATORY INFORMATION

Labelling Information

EC Symbol: C Corrosive

R – Phrases: R35 Causes severe burns R41 Risk of serious damage to eyes. S – Phrases: S1/2 Keep locked up and out of reach of children. S26 In case of contact with eyes, rinse immediately with plenty of water

and seek medical advice. S27/28 After contact with skin, take off immediately all contaminated

clothing, and wash immediately with water. S36/37/39 Wear suitable protective clothing, gloves and eye/face protection. S45 In case of accident or if you feel unwell seek medical advice

immediately (show the label where possible)

16. OTHER INFORMATION Source of occupational exposure limits: EH40/2005 Workplace exposure limits (Table 1)

Notice Information contained in this publication, while accurate to the best knowledge and belief of Biocel Ltd. is not intended and should not be construed as a warranty or representation for which Biocel assumes any legal responsibility. Any information or advice obtained from Biocel otherwise than by means of this publication and whether relating to Biocel materials or other materials, is also given in good faith. However, it remains the responsibility of the customer to ensure that Biocel materials are suitable for the particular purpose intended. Biocel accepts no liability whatsoever (except as otherwise expressly provided by law) arising out of the use of the information supplied, the application, adaptation or processing of the products described herein, the use of other materials in lieu of Biocel materials or use of Biocel materials in conjunction with such other materials

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Signed on behalf of Biocel Ltd. Signed on behalf of Client company ____________________________________ ________________________________ Print: _______________________________ Print: ___________________________ Title: _______________________________ Title: ___________________________ Date: _______________________________ Date: ___________________________

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SAFETY DATA SHEET

DEPOSITROL PY5203A

Version:

Effective Date:

Previous Date: 19/06/2008

2

10/04/2009

.1

1 IDENTIFICATION OF PREPARATION AND OF COMPANY

GE Water & Process Technologies (UK) LLP

Foundry Lane

Widnes, Cheshire WA8 8UD U.K.

Tel.: 0151 424 5351, Fax : 0151 423 2722, Telex : 627341

e-mail : [email protected]

1.3 Company/undertaking identification

1.4 Emergency telephone

0151 424 5351

Official advisory body :

National Poisons Information Centre

Medical Toxicology Unit

Guy's and St. Thomas' NHS Trust

Avonley Road, London, SE14 5ER

Tel.: 0207 358 9167, Fax : 0207 771 5309

1.1 Identification of the substance or preparation

Product : DEPOSITROL PY5203A

1.2 Use of substance/preparation

Deposit control agent

Skin contact Wash with water.

4 FIRST AID MEASURES

Eye contact Flush immediately with plenty of running water.

Inhalation Remove to fresh air.

Ingestion Rinse mouth with water.

2 HAZARDS IDENTIFICATION

Important hazards

- Health/physical hazard Not considered hazardous to health.

- Environmental hazards The product is not classified as dangerous for the environment.

COMPOSITION / INFORMATION ON INGREDIENTS3

Hazardous component(s) EINECS/ELINCS # Conc.CAS #

None.

Product DEPOSITROL PY5203A: Page : 1 / 5

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SAFETY DATA SHEET

DEPOSITROL PY5203A

Version:

Effective Date:


2

10/04/2009

.1

5 FIRE-FIGHTING MEASURES

Extinguishing Media

- Suitable Carbon dioxide, dry chemicals, foam, water spray (fog).

Special protective equipment for

fire fighters

Self contained breathing apparatus. (CEN : EN 137)Protective clothing (CEN : EN 469)Protective gloves (CEN : EN 659)Helmet (CEN : EN 443)

Special exposure hazards None known.

ACCIDENTAL RELEASE MEASURES

Personal precautions Protective clothingPlease refer also to section no. 8 'Exposure controls' for further information.

6

Environmental precautions Prevent from entering sewers or the immediate environment.Accidental release of large quantities into the aquatic environment may harm aquaticorganisms.

Methods for Cleaning Up

- on soil Absorb onto inert material and dispose of according to Controlled Waste Regulations.Remove small spills with plenty of water.

7.1 Handling Normal chemical handling.

7 HANDLING AND STORAGE

7.2 Storage Store containers closed when not in use.Store between 3 - 30 °CKeep away from strong bases.

9 PHYSICAL AND CHEMICAL PROPERTIES

Exposure controls

- Recommended engineeringcontrols

Ensure good ventilation.

- Respiratory protection Not required.

- Hand protection Protective gloves (Plastic, impervious) (Protection against unintentional short-term contact)CEN : EN 420

- Eye protection Safety goggles.CEN : EN 166

- Skin protection Protective clothing if splashing or repeated contact with product is likely.CEN : EN 340

- Environmental exposure controls Prevent from entering in public sewers or the immediate environment.

8 EXPOSURE CONTROLS/PERSONAL PROTECTION

Maximum storage stability (days) 360

7.3 Specific use(s) Only for professional and industrial users


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SAFETY DATA SHEET

DEPOSITROL PY5203A

Version:

Effective Date:


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.1

Exposure hazard

- Inhalation Prolonged or repeated exposure may cause transient irritation.

- Skin contact Prolonged or repeated contact may cause transient irritation.

- Eye contact Prolonged or repeated contact may cause transient irritation.

- Ingestion May cause slight gastrointestinal irritation.

11 TOXICOLOGICAL INFORMATION

Mammalian Test Data

- Oral LD50, rat (mg/kg) > 5000 (estimated value)

- Dermal LD50, rabbit (mg/kg) > 5000 (estimated value)

10.3 Hazardous decomposition

products

None known.

10.2 Materials to avoid Avoid contact with strong oxidisers.

10.1 Conditions to avoid Keep away from heat.

10 STABILITY AND REACTIVITY

9.2 Important health, safety and environmental info

pH (concentrated product) 4

Flash point (Pensky/Martens) (°C) > 100

Density at 20°C (kg/m3) 1250

Solubility in water (% weight) Completely soluble

Viscosity at 20°C (mPas) 1000

Relative vapour density (air=1) < 1

Evaporation rate (ether=1) < 1

9.3 Other information

Melting point, (°C) 0

Pour point, (°C) 3

9.1 General information

Appearance Liquid

Colour Yellow


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SAFETY DATA SHEET

DEPOSITROL PY5203A

Version:

Effective Date:


2

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.1

Air transport

- ICAO/IATA classification Not classified under this legislation

Maritime transport

- IMO-IMDG class Not classified under this legislation

Land transport

- RID/ADR classification Not classified under this legislation.

Correct shipping name Not applicable.

Substance id.no. (SIN) (UN No.) Not applicable.

14 TRANSPORT INFORMATION

Disposal of packaging According to Controlled Waste Regulations.

EWC ( European Waste Code ) recommendation : 15 01 02, 15 01 0415 Waste packaging; absorbents, wiping cloths, filter materials and protective clothing nototherwise specified.15 01 Packaging (including separately collected municipal packaging waste).15 01 02 Plastic packaging.15 01 04 Metallic packaging.Depending on the origin and state of the waste, other EWC numbers may be applicable too.

Disposal of product

13 DISPOSAL CONSIDERATIONS

According to Controlled Waste Regulations.

EWC ( European Waste Code ) recommendation : 16 03 0616 Wastes not otherwise specified in the list.16 03 Off-specification batches and unused products.16 03 06 Organic wastesDepending on the origin and state of the waste, other EWC numbers may be applicable too.

Summary The product is not classified as dangerous for the environment.The evaluation of environmental hazards is based on the concentration limits as set out indirective 1999/45/EC.

Persistence and degradability No data available

12 ECOLOGICAL INFORMATION

Ecotoxicity

- Rainbow Trout (mg/l) LC50 : 700 96 hour static acute bioassay

- Fathead minnow (mg/l) LC50 : 5900NOEL : 2500 96 hour static renewal bioassay

- Daphnia Magna (mg/l) LC50 : 850NOEL : 310 48 hour static renewal bioassay

- Algae Inhibition (mg/l) EC50 : 180 96 hour, Growth Inhibition Test (OECD 201)


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SAFETY DATA SHEET

DEPOSITROL PY5203A

Version:

Effective Date:


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.1

15 REGULATORY INFORMATION

EEC labelling information

- Symbol(s) None.

- R Phrase(s) No Risk phrases assigned.

- S Phrase(s) No Safety phrases assigned.

- EINECS number All ingredients of this product are listed in EINECS or ELINCS, unless specifically exemptedunder the EEC Directive 67/548/EEC.

Based on EC Directive /

Regulations

1999/45/EC 2001/58/EC 2001/118/EC(EC) No 1907/2006 (REACH)

Nature of revision Correction in Section: 1

SDS issued on 01/02/2008

16 OTHER INFORMATION


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SAFETY DATA SHEET According to Regulation (EC)No. 453/2010

Page 1 of 8 Date issued: 05 April 2013 Revision: 1

1. Identification of the substance/preparation and of the company/undertaking

1.1. Product Identifiers

Trade name: Formic Acid 85-90%

REACH Registration number 02-2119752550-43-0000

CAS number 64-16-6

EC index number 200-579-1

EINECS number 607-001-00-0


Relevant identified uses of the substance or mixture and uses advised against

-Material for industrial applications

-Industrial and professional use

1.3. Supplier’s details

-Company: Biocel Ltd.

-Address: Rockgrove Industrial estate, Little Island, Co. Cork, Ireland

-Telephone: +353(021)4353516

-Fax: +353(021)4354358

-Contact Email [email protected]

1.4. Emergency telephone number

-Emergency telephone number (outside of office hours): +353(021)4353516

2. Hazards identification 2.1. Classification of the substance or mixture

Classification (1272/2008/CE):

Skin Corrosion, Category 1A (H314)

Classification (2006/121/EC, 1999/45/EC):

Causes severe burns.

2.2 Label elements

Hazardous components which must be listed on the label: Formic Acid

Labelling (1272/2008/CE):

Danger

Hazard statements:

H314 Causes severe skin burns and eye damage.

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Formic Acid Page 2 of 8

Precautionary statements:

P280 Wear protective gloves/protective clothing/eye protection/face protection.

P301+ P330+ p331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting.

P303+ P361 + P353IF ON SKIN (or hair): Remove/take off immediately all contaminated clothing.

Rinse skin with water/shower.

P305+ P351+ P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove

contact lenses, if present and easy to do. Continue rinsing.

P308 IF exposed or concerned:

P310 Immediately call a POISON CENTER or a doctor/physician.

Labelling (2006/121/EC, 1999/45/EC):

Labelling and classification in accordance with the EC Dangerous Preparations Directive

(1999/45/EC) and subsequent amendments

C Corrosive

Contains: Formic Acid

R-phrase(s): R35 Causes severe burns.

S-phrase(s): S26 In case of contact with eyes, rinse immediately with plenty of water

and seek medical advice.

S37/39 Wear suitable gloves and eye/face protection.

S45 In case of accident or if you feel unwell, seek medical advice

immediately (show the label where possible).

3. Composition/information on ingredients 3.1 Type of product: Aqueous Solution

Hazardous components

Sodium hydroxide (caustic soda)

Concentration (%): 85-90

CAS-No.: 64-18-6

EINECS-No.: 200=579-1

Index-No.: 607-001-00-0

Classification (1272/2008/CE): Skin Corr.1A H314 Flam. Liq. 3 H226

4. First-aid measures 4.1 Description of first aid measures

General advice: Remove victims from the danger zone without endangering your own safety.

Remove contaminated clothing (including underwear and shoes) immediately.

If inhaled: Bring accident victims out into the fresh air. If patient has difficulty in breathing,

administer oxygen, keep the patient calm and warm. Call a physician immediately.

In case of skin contact: After contact with skin, wash immediately with plenty of water. Apply

sterile protective bandage; consult GP.

In case of eye contact: Hold the eyes open and rinse with preferably lukewarm water for a

sufficiently long period of time (at least 10 minutes). Contact an ophthalmologist.

If swallowed: If swallowed, rinse mouth with water (only if the person is conscious). DO NOT

induce the patient to vomit, medical advice is required.

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4.2 Most important symptoms and effects, both acute and delayed

Notes to physician: Corrosive effects.

4.3 Indication of any immediate medical attention and special treatment needed

Therapeutic measures: Basic first aid, decontamination, symptomatic treatment.

5. Fire-fighting measures

5.1 Suitable extinguishing media: Carbon dioxide (CO2), foam, extinguishing powder, in cases

of larger fires, water spray should be used.

Unsuitable extinguishing media: High volume water jet.

5.2 Special hazards arising from the substance or mixture:

Burning releases carbon monoxide, carbon dioxide, oxides of nitrogen and traces of hydrogen

cyanide. In the event of fire and/or explosion do not breathe fumes.

5.3 Advice for fire-fighters:

During fire-fighting respirator with independent air-supply and airtight garment is required.

Fight fire in early stages if safe to do so. Containers at risk of fire should be cooled with water

and, if possible removed from the danger area. Do not allow contaminated extinguishing water

to enter the soil, ground-water or surface waters.

6. Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures:

Put on protective equipment (see Section 8). Ensure adequate ventilation/exhaust extraction. Keep

unauthorized persons away.

6.2.1 Environmental precautions: Do not flush into surface water or sanitary sewers system.

6.3 Methods and material for containment and cleaning up:

Take up with absorbent for chemicals or, if necessary with dry sand. Fill into labeled, sealable

containers. Also place used cleaning materials into closable receptacles.

6.4 Reference to other sections: For further disposal measures see Section 13.

7. Handling and storage 7.1 Precautions for safe handling:

Handle and open container with care. Provide sufficient air exchange and/or exhaust in work

rooms. Organize work procedures so that workers are not exposed to the effects of the products.

Vent waste air only via suitable separator or scrubbers.

Precautions should generally be taken against electrostatic charges according to the equipment

used and the way the product is handled and packaged.

The precautions required in the handling of irritant or corrosive substances must be taken.

Contact with skin and eyes and inhalation of vapors must be avoided under all circumstances.

Careful attention to industrial and personal hygiene is essential.

Keep away from foodstuffs, drinks and tobacco. Wash hands before breaks and at the end of work

day. Keep working clothes separately. Change contaminated or soaked clothing immediately. If the

suit becomes contaminated, first take a shower with the suit on.

Keep away from incompatible products and naked flames/heat.

Do not discharge the waste into drains.

The general conditions of use are further specified in the exposure scenarios which may be found in

the attached annex.

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7.2 Conditions for safe storage, including any incompatibilities:

Store in a dry, well-ventilated, bunded area.

Keep in properly labeled closed containers.

Keep away from incompatible products and naked flames/heat.

Storage temperature <30C

Keep away from: -combustible materials, - Corrosive to base metals, Alkalis, oxidizing agents & bases.

7.3 Specific end use(s):

For further information contact the supplier.

8. Exposure Controls/Personal Protection

8.1 Control parameters

Components with workplace control parameters

Substance CAS-No. Basis Type Value Ceiling Limit Value

Formic Acid 64-18-6 EH40 WEL TWA 9.6mg/m3

For technical protective measures to limit exposure see also Section 7 “Handling and storage".

The general RMMs are further specified in the exposure scenarios which may be found in the

attached annex.

8.2 Exposure controls

Respiratory protection:

Required if exposure limit is exceeded (eg OEL), recommended filter type F.

Hand protection:

Suitable materials for safety gloves; EN 374:

Polychloroprene- CR: thickness >=0,5mm; breakthrough time>=480min.

Butyl rubber llR: thickness>= 0,5mm; breakthrough time>=480min.

Fluorinated rubber- FKM: thickness>=0,4mm; breakthrough time>=480min.

Recommendation: contaminated gloves should be disposed of.

Eye protection:

Wear eye/face protection.

Skin and body protection:

Impervious protective clothing. On possible contact with the product (sampling, product leakage):

full protection or chemical protection clothing.

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9. Physical and Chemical Properties 9.1 Information on basic physical and chemical properties

Appearance: liquid

Colour: colourless

Odour: stinging

Odour Threshold: not established

pH: 2.2 at 10g/l at 20oC

Melting point/range: -13.5°C

Boiling point/range: 106°C

Flash point: 65°C Evaporation rate: not established

Flammability(solid, gas): not applicable

Upper explosion Limit: 47.6% V

Lower explosion Limit: 14.9% V

Vapour pressure: 28 hPa at 20oC

Vapour density: not established

Density: 1.19 at 20oC

Surface tension: not established

Partition coefficient not established

(n-octanol/water):

Autoignition temperature: not applicable

Ignition temperature: 500 oC

Decomposition temperature: not established

Viscosity, dynamic: 1.4 mPa.s at 20oC

Explosive properties: Formation of explosive air/vapour mixture is possible.

Dust explosion class: not applicable

Oxidising properties: not established


Miscibility with water: miscible

10. Stability and Reactivity 10.1 Reactivity:

No decomposition if stored and applied as directed.

10.2 Stability:

Stable under recommended storage conditions.

10.3. Possibility of hazardous reactions

Hydrogen peroxide explosive properties.

10.4 Conditions to avoid: -Over heating -Freezing -Direct sunlight -Moisture

10.5 Materials to avoid: Strong oxidising agents, aluminium, alkalis, alkalines, sulphuric acid, peroxides.

10.6 Hazardous Decomposition Products:

Carbon monoxide.

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11. Toxicological Information Toxicological studies on the product are not yet available. Please find below the data available to us:

11.1 Information on toxicological effects

Acute toxicity, dermal: Corrosive effects (rabbit)

If ingested, severe burning of the mouth and throat, as well as a danger of perforation of the esophagus and

the stomach.

12. Ecological Information

Do not allow to escape into waterways, wastewater or soil.

Ecotoxicological studies of the product are not available.

Please find below the data available to us:

12.1 Toxicity

Acute Fish toxicity:

LC50 46 - 100 mg/l

Species: Fish

Acute toxicity for daphnia:

EC50 120 mg/l

Exposure duration: 48 h

Acute toxicity for algae:

EC50 26.9 mg/l


Acute bacterial toxicity:

EC10 33.8 mg/l


12.2 Persistence and degradability

Persistence: No data available.

Biodegradability:

Readily biodegradable, 98% in 14 days.

12.3 Bioaccumulative potent: No data available.

12.4 Mobility: Mobile in water environment.

12.5 Results of PBT and vPvB assessment

This substance does not meet the criteria for classification as PBT or vPvB.

12.6 Other adverse effects:

BOD = 86 mg/g COD = 348mg/g

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Circul SHC Page 7 of 8

13. Disposal Considerations

Dispose in accordance with applicable international, national and local laws, ordinances and

statutes.

For disposal within the EC, the appropriate code according to the European Waste

Catalogue (EWC) should be used.

13.1 Waste treatment methods

After containers have been emptied as thoroughly as possible (e.g. by pouring, scraping or

draining until “drip-dry"), they can be sent to an appropriate collection point set up within the

framework of the existing take-back scheme of the chemical industry.

Containers must be recycled in compliance with national legislation and environmental regulations.

No disposal into surface or waste water.

14. Transport Information

ADR/RID

UN Number: 1779

Description of the goods: FORMIC ACID

Packaging group: II

Hazard identification No: 83

Hazard label: 8, 3

Environmentally Hazardous: No

Limited quantity regulations applicable in accordance with chapter 3.4 ADR/RID in compliance

with threshold value.

IMDG

UN Number: 1779

Description of the goods: FORMIC ACID

Class: 8

Packing Group: II

IMDG-Labels: 8,3

Marine Pollutant: No

Special precautions for user: Corrosive.

Keep away from foodstuffs, acids and alkalis.

15. Regulatory Information 15.1 Safety, health and environmental regulations/legislation specific for the substance or

mixture

Any existing national regulations on the handling of irritant or corrosive substances must be

observed.

National provisions:

Relevant Statutory Instruments

• Carriage of Dangerous Goods by Road Regulations 2007, S.I. 288 of 2007

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• Carriage of Dangerous Goods by Road (ADR miscellaneous provisions) Regulations 2007,

S.I.289 of 2007

• Carriage of Dangerous Goods by Road Act 1998 (Appointment of Competent Authorities)

Order 2007, S.I.290 of 2007

• Carriage of Dangerous Goods by Road Act 1998 (Fees) Regulations 2007, S.I. 291 of 2007

• Chemicals Act 2008, No. 13 of 2008

• ADR 2011

• Safety, Health and Welfare at Work (Chemical Agents) Regulation 2001, SI 619 of 2001

16. Other information

PBT-substances: Persistent, bioaccumulative and toxic substances

DSD: Dangerous Substance Directive

DPD: Dangerous Preparation Directive

CLP (EU-GHS): Classification, labelling and packaging

(Globally Harmonised System in Europe)

Met. Corr.: Substance or mixture corrosive to metals

Skin Corr.: Skin corrosion

Note:

The information contained in this data sheet is copied from the safety data sheet provided by the

manufacturer. The information is given in good faith and to the best of our knowledge but no

guarantee, implied or otherwise, is made.

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EPA Export 28-07-2015:23:40:10

Page : 1SAFETY DATA SHEETRevised edition no : 4

Date : 21/2/2008

Govinyl Green D SGS -IH Supersedes : 23/2/2005

97397www.lisam.com

êN êXN : Dangerous for Xn : Harmful

the environment

Producer Responsible for distributions.a. GOVI n.v. s.a. GOVI n.v.Landegemstraat 8 Landegemstraat 8B-9031 DRONGEN . Belgie-Belgique-Belgium B-9031 DRONGEN . Belgie-Belgique-BelgiumTEL + 32-(0)9-282.94.95 TEL + 32-(0)9-282.94.95FAX + 32-(0)9-282.94.79 FAX + 32-(0)[email protected] [email protected]://www.govi.com http://www.govi.comIn case of emergency : +32 (0)70 245 245 In case of emergency : +32 (0)70 245 245

1. Identification of the product

Chemical description : Dye stuff.

Trade name : Govinyl Green D SGS -IH

Use : Particle board industry, MDF & OSB.Industrial.

Company identification : See above.

2. Information on ingredients

This product is considered to be hazardous and contains hazardous components.*

Substance name Contents CAS No / EC No / Index No Symbol(s) R-Phrase(s)

[4-[a-[4-(dimethylamino)phenyl] : 20 to 30 % 41272-40-6 / 255-288-2 / ----- Xn Xi C 22-37/38-41-50/benzylidene]cyclohexa-2,5-dien-1- 53ylidene]dimethylammonium acetate

Acetic acid : 10 to 20 % 64-19-7 / 200-580-7 / 607-002-00-6 C 10-35

Diethylene glycol : < 5 % 111-46-6 / 203-872-2 / 603-140-00-6 Xn 22

Hydrochloric acid : 1 to 10 % 7647-01-0 / 231-595-7 / 017-002-01-X C 34-37

3. Hazards identification

Risk Phrases : R 34 Causes burns*Harmful if swallowed (R 22)R41 : Risk of serious damage to eyes.R 37 Irritating to respiratory system.R 50/53 Very toxic to aquatic organisms, may cause long-term adverse effects inthe aquatic environment.

Primary route of exposure : Skin and eyes contact. Inhalation.

- Inhalation : R 37 Irritating to respiratory system.*

- Skin contact : Causes burns.

- Eye contact : Risk of serious damage to eyes.

- Ingestion : Harmful if swallowed (R 22)

s.a. GOVI n.v. In case of emergency : +32 (0)70 245 245

Landegemstraat 8 B-9031 DRONGEN . Belgie-Belgique-Belgium

TEL + 32-(0)9-282.94.95

FAX + 32-(0)9-282.94.79

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97397www.lisam.com

4. First aid measures

- Prevention : Use good personal hygiene practices.

: Avoid all unnecessary exposure.

- Inhalation : Assure fresh air breathing. Obtain medical attention if breathing difficulty persists.

- Skin contact : Remove affected clothing and wash all exposed skin area with mild soap andwater, followed by warm water rinse. Seek medical attention if ill effect or irritationdevelops.

- Eye contact : In case of eye contact, immediately rinse with clean water for 20-30 minutes. Seekmedical attention immediately.

- Ingestion : DO NOT INDUCE VOMITING. Rinse mouth. Obtain emergency medical attention.

5. Fire - fighting measures

Flammable class : Not flammable.

Prevention : No naked lights. No smoking.

Extinguishing media : All extinguishing media can be used.

Surrounding fires : Apply water spray or fog to cool nearby equipment.

Protection against fire : Do not enter fire area without proper protective equipment, including respiratoryprotection.Wear self-contained breathing apparatus, rubber boots and thick rubber gloves.

Personal precautions : The driver shall not attempt to deal with any fire of the load.

6. Accidental release measures

Personal precautions : Avoid all unnecessary exposure.

: Avoid breathing vapours from hot material.

: Wear suitable protective clothing and gloves.Respiratory protection equipment may be necessary.

Environmental precautions : Prevent entry to sewers and public waters.

After spillage and/or leakage : Dike for recovery or absorb with appropriate material.Use non-corrodable disposal containers.

- on water : Soluble material/quickly disperses in water.

7. Handling and storage

General : Avoid all unnecessary exposure.

Storage : Keep container closed when not in use.Protect from low temperatures.

-Storage : Store between 5 & 35°C.

Handling : Handle in accordance with good industrial hygiene and safety procedures.For even minor contact, immediately remove contaminated clothing/wash skinthoroughly with mild soap / water.Where contact with eyes or skin is likely, wear suitable protection.Wash hands and other exposed areas with mild soap and water before eating,drinking, smoking and when leaving work.

±s.a. GOVI n.v. In case of emergency : +32 (0)70 245 245


TEL + 32-(0)9-282.94.95

FAX + 32-(0)9-282.94.79

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97397www.lisam.com

8. Exposure controls / personal protection

Personal protection

- Respiratory protection : Where exposure through inhalation may occur from use, approved respiratoryprotection equipment is recommended. filter grey B2P3

- Hand protection

=: Use rubber gloves.

- Skin protection : If skin contact or contamination of clothing is likely, protective clothing should beworn.

- Eye protection

8: Safety glasses with side guards should be worn to prevent injury from airborne

particles and/or other eye contact with this product.

Industrial hygiene : Either local exhaust or general room ventilation is usually required.

¡: Emergency eye wash fountains should be available in the immediate vicinity of any

potential exposure.

÷Occupational Exposure Limits : Acetic acid : TLV-TWA [mg/m3] : 25*

Acetic acid : TLV-TWA [ppm] : 10Hydrochloric acid : TLV-TWA [mg/m3] : 7.5Hydrochloric acid : TLV-TWA [ppm] : 5

9. Physical and chemical properties

Physical state : Liquid.

Colour : Green.

Odour : Acidic.

pH value : < 3

Viscosity at 20°C [mPa.s] : 30 - 80

Solubility in water : Complete.

10. Stability and reactivity

Hazardous decomposition products : None under normal conditions. On exposure to high temperature, may decompose,releasing toxic gases. Chlorine. Carbon monoxide. Carbon dioxide.

Hazardous properties : In aqueous solution it's a corrosive acid.Attacks metals

Materials to avoid : Strong oxidizers.Strong alkalis.Anionic products.

Conditions to avoid : Freezing.

-s.a. GOVI n.v. In case of emergency : +32 (0)70 245 245


TEL + 32-(0)9-282.94.95

FAX + 32-(0)9-282.94.79

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97397www.lisam.com

11. Toxicological information

Rat oral LD50 [mg/kg] : No data available.*

Rabbit dermal LD50 [mg/kg] : No data available.

Rat inhalation LC50 [mg/l/4h] : No data available.

12. Ecological information

ON PRODUCT : Soluble material/quickly disperses in water.

LC50-96 Hour - fish [mg/l] : No data available.*

48 Hour-EC50 - Daphnia magna [mg/l] : No data available.*

IC50 72h Algae [mg/l] : No data available.

WGK class (Germany) : 3 - Severe hazard to water*

13. Disposal considerations

Disposal : Dispose in a safe manner in accordance with local/national regulations.

14. Transport information

- Proper shipping name : UN3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (*contains 4-[alpha.-[4-(dimethylamino)phenyl]benzylidene]cyclohexa-2,5-dien-1-ylidene]dimethylammoniumacetate), 9, III

- UN No. : 3082*

- H.I. nr : : 90*

- ADR/RID : Group : III*Class : 9

15. Regulatory information

Symbol(s) : Harmful.Dangerous for the environment.

R Phrase(s) : R22 : Harmful if swallowed.*R37/38 : Irritating to respiratory system and skin.R41 : Risk of serious damage to eyes.R50/53 : Very toxic to aquatic organisms, may cause long-term adverse effects inthe aquatic environment.

S Phrase(s) : S24 : Avoid contact with skin.*S26 : In case of contact with eyes, rinse immediately with plenty of water and seekmedical advice.S37/39 : Wear suitable gloves and eye/face protection.S61 : Avoid release to the environment. Refer to special instructions/Safety datasheets.

16. Other information

Text of R-phrases in § 2 : R10 : Flammable.*R22 : Harmful if swallowed.R34 : Causes burns.R35 : Causes severe burns.R37 : Irritating to respiratory system.R37/38 : Irritating to respiratory system and skin.R41 : Risk of serious damage to eyes.R50/53 : Very toxic to aquatic organisms, may cause long-term adverse effects inthe aquatic environment.



TEL + 32-(0)9-282.94.95

FAX + 32-(0)9-282.94.79

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97397www.lisam.com

16. Other information (continued)

Training advice : Instruct personel about the product's risk, on precautions and measures to betaken in case of emergency.

Further information : Revision - See : *

DATE : : 28 / 2 / 2008

The contents and format of this SDS are in accordance with EEC Commission Directive 2001/58EC.

DISCLAIMER OF LIABILITY The information in this SDS was obtained from sources which we believe are reliable. However, theinformation is provided without any warranty, express or implied, regarding its correctness. The conditions or methods ofhandling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and otherreasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any wayconnected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for thisproduct. If the product is used as a component in another product, this MSDS information may not be applicable.

End of document



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FAX + 32-(0)9-282.94.79

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EPA Export 28-07-2015:23:40:10

PRODUCT SAFETY DATA SHEET for Ca(OH)2

prepared in accordance with Annex II of the REACH Regulation EC 1907/2006,

Regulation (EC) 1272/2008 and Regulation (EC) 453/2010

Version: 1.0

Revision date: December / 2010 Printing Date: June 27, 2012

Page 1 of 15

1 IDENTIFICATION OF THE SUBSTANCE/mixture AND OF THE COMPANY/UNDERTAKING

1.1 Product identifier

Substance name: Hydrated lime, Calcium dihydroxide

Synonyms: Slaked lime, Air slaked lime, Building lime, Fat lime, Chemical lime,

Finishing lime, Mason’s lime, Calcium dihydroxide, Calcium hydroxide,

Calcium hydrate, Lime, Lime water, Milk of Lime

Chemical name and formula: Calcium dihydroxide – Ca(OH)2

Trade name: White Rhino, White Rhino Hydrated Lime, Hydrapure, Agri Lime, Coarse Lime

CAS: 1305-62-0

EINECS: 215-137-3

Molecular Weight: 74.09 g/mol

REACH Registration number: 01-2119475151-45-0192

1.2 Relevant identified uses of the substance or mixture and uses advised against

Please check the identified uses in table 1 of the Appendix of this SDS.

Uses advised against: There are no uses advised against.

1.3 Details of the supplier of the safety data sheet

Name: Clogrennane Lime Ltd

Address: Clogrennane, Carlow, Ireland

Phone N°: 00353 599131811

Fax N°: 00353 599131607

E-mail of competent person responsible for SDS in the MS or in the EU:

[email protected]

1.4 Emergency telephone number

European Emergency N°: 112

National centre for Prevention and Treatment of Intoxications N°:

National Poison Information Center

Beaumont Hospital ( 00353 18092566)

Emergency telephone at the company 00353 879863618

Available outside office hours: Yes No

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Page 2 of 15


2.1 Classification of the substance

2.1.1 Classification according to Regulation (EC) 1272/2008

STOT Single Exp. 3, Route of exposure: Inhalation

Skin Irritation 2

Eye Damage 1

2.1.2 Classification according to Directive 67/548/EEC

Xi – irritant

2.2 Label elements

2.2.1 Labelling according to Regulation (EC) 1272/2008

Signal word: Danger

Hazard pictogram:

Hazard statements:



H335: May cause respiratory irritation

Precautionary statements:

P102: Keep out of reach of children

P280: Wear protective gloves/protective clothing/eye protection/face protection

P305+P351+P310: IF IN EYES: Rinse cautiously with water for several minutes. Immediately call a POISON CENTRE or doctor/physician

P302+P352: IF ON SKIN: Wash with plenty of water

P261: Avoid breathing dust/spray

P304+P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P501: Dispose of contents/container to hazardous waste collection point

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PRODUCT SAFETY DATA SHEET

prepared in accordance with Annex II of the REACH

Regulation (EC) 1272/2008 and

Version: 1.0

Revision date: December / 2010

2.2.2 Labelling according to Directive 67/548/EEC

Indication of danger:

Xi irritant

Risk phrases:

R37: Irritating to respiratory system

R38: Irritating to skin

R41: Risk of serious damage to eyes

Safety phrases:

S2: Keep out of the reach of children

S25: Avoid contact with eyes

S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice

S37: Wear suitable gloves

S39: Wear eye/face protection

2.3 Other hazards

The substance does not meet the cri

No other hazards identified.

3 COMPOSITION/INFORMATION ON INGREDIENTS

3.1 Substances

Main constituent

Name: Calcium dihydroxide

CAS: 1305

EINECS: 215

Impurities

No impurities relevant for classification and


4.1 Description of first aid measures

General advice

No known delayed effects. Consult a physician for all expos




Printing Date:

ing according to Directive 67/548/EEC

Irritating to respiratory system

serious damage to eyes

Keep out of the reach of children

In case of contact with eyes, rinse immediately with plenty of water and seek medical advice

The substance does not meet the criteria for PBT or vPvB substance.

COMPOSITION/INFORMATION ON INGREDIENTS

Calcium dihydroxide

1305-62-0

215-137-3

No impurities relevant for classification and labelling

Description of first aid measures

No known delayed effects. Consult a physician for all exposures except for minor instances.

for Ca(OH)2

egulation EC 1907/2006,

egulation (EC) 453/2010

Printing Date: June 27, 2012

In case of contact with eyes, rinse immediately with plenty of water and seek medical advice

ures except for minor instances.

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Following inhalation

Move source of dust or move person to fresh air. Obtain medical attention immediately.

Following skin contact

Carefully and gently brush the contaminated body surfaces in order to remove all traces of product. Wash affected area immediately with plenty of water. Remove contaminated clothing. If necessary seek medical advice.

Following eye contact

Rinse eyes immediately with plenty of water and seek medical advice.

After ingestion

Clean mouth with water and drink afterwards plenty of water. Do NOT induce vomiting. Obtain medical attention.

4.2 Most important symptoms and effects, both acute and delayed

Calcium dihydroxide is not acutely toxic via the oral, dermal, or inhalation route. The substance is classified as irritating to skin and the respiratory tract, and entails a risk of serious damage to the eye. There is no concern for adverse systemic effects because local effects (pH-effect) are the major health hazard.

4.3 Indication of any immediate medical attention and special treatment needed

Follow the advises given in section 4.1

5 FIRE FIGHTING MEASURES

5.1 Extinguishing media

5.1.1 Suitable extinguishing media

Suitable extinguishing media: The product is not combustible. Use a dry powder, foam or CO2 fire extinguisher to extinguish the surrounding fire.

Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.

5.1.2 Unsuitable extinguishing media

Do not use water.

5.2 Special hazards arising from the substance or mixture

None

5.3 Advice for fire fighters

Avoid generation of dust. Use breathing apparatus. Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.

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6 ACCIDENTAL RELEASE MEASURES

6.1 Personal precautions, protective equipment and emergency procedures

6.1.1 For non-emergency personnel

Ensure adequate ventilation.

Keep dust levels to a minimum.

Keep unprotected persons away.

Avoid contact with skin, eyes, and clothing – wear suitable protective equipment (see section 8).

Avoid inhalation of dust – ensure that sufficient ventilation or suitable respiratory protective equipment is used, wear suitable protective equipment (see section 8).

6.1.2 For emergency responders

Keep dust levels to a minimum.

Ensure adequate ventilation.

Keep unprotected persons away.

Avoid contact with skin, eyes, and clothing – wear suitable protective equipment (see section 8).

Avoid inhalation of dust – ensure that sufficient ventilation or suitable respiratory protective equipment is used, wear suitable protective equipment (see section 8).

6.2 Environmental precautions

Contain the spillage. Keep the material dry if possible. Cover area if possible to avoid unnecessary dust hazard. Avoid uncontrolled spills to watercourses and drains (pH increase). Any large spillage into watercourses must be alerted to the Environment Agency or other regulatory body.

6.3 Methods and material for containment and cleaning up

In all cases avoid dust formation.

Keep the material dry if possible.

Pick up the product mechanically in a dry way.

Use vacuum suction unit, or shovel into bags.

6.4 Reference to other sections

For more information on exposure controls/personal protection or disposal considerations, please check section 8 and 13 and the annex of this safety data sheet.


7.1 Precautions for safe handling

7.1.1 Protective measures

Avoid contact with skin and eyes. Wear protective equipment (refer to section 8 of this safety data sheet). Do not wear contact lenses when handling this product. It is also advisable to have individual pocket eyewash. Keep dust levels to a minimum. Minimize dust generation. Enclose dust sources, use

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exhaust ventilation (dust collector at handling points). Handling systems should preferably be enclosed. When handling bags usual precautions should be paid to the risks outlined in the Council Directive 90/269/EEC.

7.1.2 Advice on general occupational hygiene

Avoid inhalation or ingestion and contact with skin and eyes. General occupational hygiene measures are required to ensure safe handling of the substance. These measures involve good personal and housekeeping practices (i.e. regular cleaning with suitable cleaning devices), no drinking, eating and smoking at the workplace. Shower and change clothes at end of work shift. Do not wear contaminated clothing at home.

7.2 Conditions for safe storage, including any incompatibilities

The substance should be stored under dry conditions. Any contact with air and moisture should be avoided. Bulk storage should be in purpose – designed silos. Keep away from acids, significant quantities of paper, straw, and nitro compounds. Keep out of reach of children. Do not use aluminium for transport or storage if there is a risk of contact with water.

7.3 Specific end use(s)

Please check the identified uses in table 1 of the Appendix of this SDS.

For more information please see the relevant exposure scenario, available via your supplier/given in the Appendix, and check section 2.1: Control of worker exposure.


8.1 Control parameters

SCOEL recommendation (SCOEL/SUM/137 February 2008; see Section 16.6):

Occupational Exposure Limit (OEL), 8 h TWA: 1 mg/m³ respirable dust of calcium dihydroxide

Short-term exposure limit (STEL), 15 min: 4 mg/m³ respirable dust of calcium dihydroxide

PNEC aqua = 490 µg/l

PNEC soil/groundwater = 1080 mg/l

8.2 Exposure controls

To control potential exposures, generation of dust should be avoided. Further, appropriate protective equipment is recommended. Eye protection equipment (e.g. goggles or visors) must be worn, unless potential contact with the eye can be excluded by the nature and type of application (i.e. closed process). Additionally, face protection, protective clothing and safety shoes are required to be worn as appropriate.

Please check the relevant exposure scenario, given in the Appendix/available via your supplier.

8.2.1 Appropriate engineering controls

If user operations generate dust, use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne dust levels below recommended exposure limits.

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8.2.2 Individual protection measures, such as personal protective equipment

8.2.2.1 Eye/face protection

Do not wear contact lenses. For powders, tight fitting goggles with side shields, or wide vision full goggles. It is also advisable to have individual pocket eyewash.

8.2.2.2 Skin protection

Since calcium dihydroxide is classified as irritating to skin, dermal exposure has to be minimised as far as technically feasible. The use of protective gloves (nitrile), protective standard working clothes fully covering skin, full length trousers, long sleeved overalls, with close fittings at openings and shoes resistant to caustics and avoiding dust penetration are required to be worn.

8.2.2.3 Respiratory protection

Local ventilation to keep levels below established threshold values is recommended. A suitable particle filter mask is recommended, depending on the expected exposure levels - please check the relevant exposure scenario, given in the Appendix/available via your supplier.

8.2.2.4 Thermal hazards

The substance does not represent a thermal hazard, thus special consideration is not required.

8.2.3 Environmental exposure controls

All ventilation systems should be filtered before discharge to atmosphere.

Avoid releasing to the environment.

Contain the spillage. Any large spillage into watercourses must be alerted to the regulatory authority responsible for environmental protection or other regulatory body.

For detailed explanations of the risk management measures that adequately control exposure of the environment to the substance please check the relevant exposure scenario, available via your supplier.

For further detailed information, please check the Appendix of this SDS.


9.1 Information on basic physical and chemical properties

Appearance: White or off white (beige) fine powder

Odour: odourless

Odour threshold: not applicable

pH: 12.4 (saturated solution at 20 °C)

Melting point: > 450 °C (study result, EU A.1 method)

Boiling point: not applicable (solid with a melting point > 450 °C)

Flash point: not applicable (solid with a melting point > 450 °C)

Evaporation rate: not applicable (solid with a melting point > 450 °C)

Flammability: non flammable (study result, EU A.10 method)

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Explosive limits: non explosive (void of any chemical structures commonly associated with explosive properties)

Vapour pressure: not applicable (solid with a melting point > 450 °C)

Vapour density: not applicable

Relative density: 2.24 (study result, EU A.3 method)

Solubility in water: 1844.9 mg/L (study results, EU A.6 method)

Partition coefficient: not applicable (inorganic substance)

Auto ignition temperature: no relative self-ignition temperature below 400 °C (study result, EU A.16 method)

Decomposition temperature: When heated above 580 °C, calcium dihydroxide decomposes to produce calcium oxide (CaO) and water (H2O)

Viscosity: not applicable (solid with a melting point > 450 °C)

Oxidising properties: no oxidising properties (Based on the chemical structure, the substance does not contain a surplus of oxygen or any structural groups known to be correlated with a tendency to react exothermally with combustible material)


Not available


10.1 Reactivity

In aqueous media Ca(OH)2 dissociates resulting in the formation of calcium cations and hydroxyl anions (when below the limit of water solubility).

10.2 Chemical stability

Under normal conditions of use and storage, calcium dihydroxide is stable.

10.3 Possibility of hazardous reactions

Calcium dihydroxide reacts exothermically with acids. When heated above 580 °C, calcium dihydroxide decomposes to produce calcium oxide (CaO) and water (H2O): Ca(OH)2 � CaO + H2O. Calcium oxide reacts with water and generates heat. This may cause risk to flammable material.

10.4 Conditions to avoid

Minimise exposure to air and moisture to avoid degradation.

10.5 Incompatible materials

Calcium dihydroxide reacts exothermically with acids to form salts. Calcium dihydroxide reacts with aluminium and brass in the presence of moisture leading to the production of hydrogen.

Ca(OH)2 + 2 Al + 6 H2O � Ca[Al(OH)4]2 + 3 H2

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10.6 Hazardous decomposition products

None.

Further information: Calcium dihydroxide reacts with carbon dioxide to form calcium carbonate, which is a common material in nature.


11.1 Information on toxicological effects

a. Acute toxicity

Oral LD50 > 2000 mg/kg bw (OECD 425, rat)

Dermal LD50 > 2500 mg/kg bw (OECD 402, rabbit)

Inhalation no data available

Calcium dihydroxide is not acutely toxic.

Classification for acute toxicity is not warranted.

b. Skin corrosion/irritation

Calcium dihydroxide is irritating to skin (in vivo, rabbit).

Based on experimental results, calcium dihydroxide requires classification as irritating to skin [R38,

irritating to skin; Skin Irrit 2 (H315 – Causes skin irritation)].

c. Serious eye damage/irritation

Calcium dihydroxide entails a risk of serious damage to the eye (eye irritation studies (in vivo, rabbit).

Based on experimental results, calcium dihydroxide requires classification as severely irritating to the

eye [R41, Risk of serious damage to eye; Eye Damage 1 (H318 - Causes serious eye damage)].

d. Respiratory or skin sensitisation

No data available.

Calcium dihydroxide is considered not to be a skin sensitiser, based on the nature of the effect (pH

shift) and the essential requirement of calcium for human nutrition.

Classification for sensitisation is not warranted.

e. Germ cell mutagenicity

Bacterial reverse mutation assay (Ames test, OECD 471): Negative

Mammalian chromosome aberration test: Negative

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In view of the omnipresence and essentiality of Ca and of the physiological non-relevance of any pH

shift induced by lime in aqueous media, lime is obviously void of any genotoxic potential, including

germ cell mutagenicity.

Classification for genotoxicity is not warranted.

f. Carcinogenicity

Calcium (administered as Ca-lactate) is not carcinogenic (experimental result, rat).

The pH effect of calcium dihydroxide does not give rise to a carcinogenic risk.

Human epidemiological data support lack of any carcinogenic potential of calcium dihydroxide.

Classification for carcinogenicity is not warranted.

g. Reproductive toxicity

Calcium (administered as Ca-carbonate) is not toxic to reproduction (experimental result, mouse).

The pH effect does not give rise to a reproductive risk.

Human epidemiological data support lack of any potential for reproductive toxicity of calcium

dihydroxide.

Both in animal studies and human clinical studies on various calcium salts no reproductive or

developmental effects were detected. Also see the Scientific Committee on Food (Section 16.6). Thus,

calcium dihydroxide is not toxic for reproduction and/or development.

Classification for reproductive toxicity according to regulation (EC) 1272/2008 is not required.

h. STOT-single exposure

From human data it is concluded that Ca(OH)2 is irritating to the respiratory tract.

As summarised and evaluated in the SCOEL recommendation (Anonymous, 2008), based on human

data calcium dihydroxide is classified as irritating to the respiratory system [R37, Irritating to

respiratory system; STOT SE 3 (H335 – May cause respiratory irritation)].

i. STOT-repeated exposure

Toxicity of calcium via the oral route is addressed by upper intake levels (UL) for adults determined by

the Scientific Committee on Food (SCF), being

UL = 2500 mg/d, corresponding to 36 mg/kg bw/d (70 kg person) for calcium.

Toxicity of Ca(OH)2 via the dermal route is not considered as relevant in view of the anticipated

insignificant absorption through skin and due to local irritation as the primary health effect (pH shift).

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Toxicity of Ca(OH)2 via inhalation (local effect, irritation of mucous membranes) is addressed by an 8-

h TWA determined by the Scientific Committee on Occupational Exposure Limits (SCOEL) of 1 mg/m³

respirable dust (see Section 8.1).

Therefore, classification of Ca(OH)2 for toxicity upon prolonged exposure is not required.

j. Aspiration hazard

Calcium hydroxide is not known to present an aspiration hazard.


12.1 Toxicity

12.1.1 Acute/Prolonged toxicity to fish

LC50 (96h) for freshwater fish: 50.6 mg/l

LC50 (96h) for marine water fish: 457 mg/l

12.1.2 Acute/Prolonged toxicity to aquatic invertebrates

EC50 (48h) for freshwater invertebrates: 49.1 mg/l

LC50 (96h) for marine water invertebrates: 158 mg/l

12.1.3 Acute/Prolonged toxicity to aquatic plants

EC50 (72h) for freshwater algae: 184.57 mg/l

NOEC (72h) for freshwater algae: 48 mg/l

12.1.4 Toxicity to micro-organisms e.g. bacteria

At high concentration, through the rise of temperature and pH, calcium dihydroxide is used for

disinfection of sewage sludges.

12.1.5 Chronic toxicity to aquatic organisms

NOEC (14d) for marine water invertebrates: 32 mg/l

12.1.6 Toxicity to soil dwelling organisms

EC10/LC10 or NOEC for soil macroorganisms: 2000 mg/kg soil dw

EC10/LC10 or NOEC for soil microorganisms: 12000 mg/kg soil dw

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12.1.7 Toxicity to terrestrial plants

NOEC (21d) for terrestrial plants: 1080 mg/kg

12.1.8 General effect

Acute pH-effect. Although this product is useful to correct water acidity, an excess of more than 1 g/l

may be harmful to aquatic life. pH-value of > 12 will rapidly decrease as result of dilution and

carbonation.

12.2 Persistence and degradability

Not relevant for inorganic substances

12.3 Bioaccumulative potential


12.4 Mobility in soil

Calcium dihydroxide, which is sparingly soluble, presents a low mobility in most soils

12.5 Results of PBT and vPvB assessment


12.6 Other adverse effects

No other adverse effects are identified


13.1 Waste treatment methods

Disposal of calcium dihydroxide should be in accordance with local and national legislation.

Processing, use or contamination of this product may change the waste management options.

Dispose of container and unused contents in accordance with applicable member state and local

requirements.

The used packing is only meant for packing this product; it should not be reused for other purposes.

After usage, empty the packing completely.

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Calcium dihydroxide is not classified as hazardous for transport (ADR (Road), RID (Rail), IMDG /

GGVSea (Sea).

14.1 UN-Number

Not regulated

14.2 UN proper shipping name

Not regulated

14.3 Transport hazard class(es)

Not regulated

14.4 Packing group

Not regulated

14.5 Environmental hazards

None

14.6 Special precautions for user

Avoid any release of dust during transportation, by using air-tight tanks

14.7 Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code

Not regulated


15.1 Safety, health and environmental regulations/legislation specific for the substance

Authorisations: Not required

Restrictions on use: None

Other EU regulations: Calcium dihydroxide is not a SEVESO substance, not an ozone depleting substance and not a persistent organic pollutant.

National regulations: Water endangering class 1 (Germany)

15.2 Chemical safety assessment

A chemical safety assessment has been carried out for this substance.

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Data are based on our latest knowledge but do not constitute a guarantee for any specific product

features and do not establish a legally valid contractual relationship.

16.1 Hazard Statements



H335: May cause respiratory irritation

16.2 Precautionary Statements

P102: Keep out of reach of children

P280: Wear protective gloves/protective clothing/eye protection/face protection

P305+P351: IF IN EYES: Rinse cautiously with water for several minutes

P310: Immediately call a POISON CENTRE or doctor/physician

P302+P352: IF ON SKIN: Wash with plenty of soap and water

P261: Avoid breathing dust/fume/gas/mist/vapours/spray

P304+P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

P501: Dispose of contents/container to hazardous waste collection point

16.3 Risk Phrases

R37: Irritating to respiratory system

R38: Irritating to skin

R41: Risk of serious damage to eyes

16.4 Safety Phrases

S2: Keep out of the reach of children

S25: Avoid contact with eyes

S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice

S37: Wear suitable gloves

S39: Wear eye/face protection

16.5 Abbreviations

EC50: median effective concentration

LC50: median lethal concentration

LD50: median lethal dose

NOEC: no observable effect concentration

OEL: occupational exposure limit

PBT: persistent, bioaccumulative, toxic chemical

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PNEC: predicted no-effect concentration

STEL: short-term exposure limit

TWA: time weighted average

vPvB: very persistent, very bioaccumulative chemical

16.6 Key literature references

Anonymous, 2006: Tolerable upper intake levels for vitamins and minerals Scientific Committee on

Food, European Food Safety Authority, ISBN: 92-9199-014-0 [SCF document]

Anonymous, 2008: Recommendation from the Scientific Committee on Occupational Exposure Limits

(SCOEL) for calcium oxide (CaO) and calcium dihydroxide (Ca(OH)2), European Commission, DG

Employment, Social Affairs and Equal Opportunities, SCOEL/SUM/137 February 2008

16.7 Revision

Revision 1.0

Disclaimer

This safety data sheet (SDS) is based on the legal provisions of the REACH Regulation (EC

1907/2006; article 31 and Annex II), as amended. Its contents are intended as a guide to the

appropriate precautionary handling of the material. It is the responsibility of recipients of this SDS to

ensure that the information contained therein is properly read and understood by all people who may

use, handle, dispose or in any way come in contact with the product. Information and instructions

provided in this SDS are based on the current state of scientific and technical knowledge at the date of

issue indicated. It should not be construed as any guarantee of technical performance, suitability for

particular applications, and does not establish a legally valid contractual relationship. This version of

the SDS supersedes all previous versions.

ANNEX

See annex provided – also available on www.irishlime.ie

End of the Safety Data Sheet

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HYDROCHLORIC ACID (Concentration>= 25 %) - SAFETY DATA SHEET – according to Regulation (EC) No. 1907/2006

Page 1 of 8 Ireland / United Kingdom Micro-Bio (Ireland) Ltd

Reference:SDS1; Revision Date: 25/10/2012; Rev No: 04

HYDROCHLORIC ACID (Concentration >= 25 %)

1. PRODUCT AND COMPANY IDENTIFICATION


-Product Name : HYDROCHLORIC ACID (Concentration >= 25 %)

-Chemical Name : Hydrochloric acid

-Molecular Formula : HCl

-Reach Registration Number : 01-2119484862-27-0107

-Type of Product : Mixture

1.2. Identified uses / Uses advised against

-Identified uses : - Reagent

- pH-regulating agent

- Ion exchange resins regenerating agent

- Pickling agent

- Washing and Cleaning agent

- Laboratory chemical

-Uses advised against : - None

1.3. Manufacturer or supplier’s details

-Company : MICRO-BIO (IRELAND) LTD

-Address : Industrial Estate, Fermoy, Co. Cork, Ireland

-Telephone : +3532531388

-Fax : +3532532458

-E-mail address : [email protected]


-Emergency telephone number : +3532531388 (Available 24/7)

2. HAZARDS IDENTIFICATION

2.1. GHS Classification

2.1.1. European regulation (EC) 1272/2008, as amended

Classified as hazardous according to the European regulation (EC) 1272/2008, as amended

Hazard class Hazard category Route of exposure H Phrases

Skin corrosion Category 1B H314

Specific target organ toxicity - Single exposure

Category 3 Inhalation H335

Corrosive to metals Category 1 H290

2.1.2. European Directive 67/548/EEC or 1999/45/EC, as amended

Classified as hazardous according to the European Directive 67/548/EEC or 1999/45/EC, as amended

Hazard class / Hazard category R-phrase(s)

C R34

Xi R37

2.2. EC Label – According to Regulation (EC) 1272/2008, as amended

2.2.1. Name(s) on label

Hazardous components : Hydrochloric acid (>= 25 %)

2.2.2. Signal word

Danger

2.2.3. Hazard symbols

2.2.4. Hazard statements

H314 - Causes severe skin burns and eye damage.

H335 - May cause respiratory irritation.

H290 - May be corrosive to metals.

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mailto:[email protected]



2.2.5. Precautionary statements

Prevention P260 - Do not breathe dust or mist

P280 - Wear protective gloves/protective clothing/eye

protection/face protection.

Response P303 + P361 + P353 - IF ON SKIN (or hair): Remove/Take off immediately all

contaminated clothing. Rinse skin with water/shower.

P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact

lenses, if present and easy to do. Continue rinsing.

P304 + P340 - IF INHALED: Remove victim to fresh air and keep at rest in a position

comfortable for breathing.

P309 + P311 - IF exposed or if you feel unwell: Call a POISON CENTRE or doctor/physician.

Disposal P501 - Dispose of contents/container to an approved waste disposal plant.

3. COMPOSITION / INFORMATION ON INGREDIENTS

3.1. Concentration

Substance name: Concentration

Hydrochloric acid 25-38%

CAS-No.: 7647-01-0 / EC-No.: 231-595-7 / Index-No.: 017-002-01-X

3.2. Hazardous components – According to Regulation (EC) 1272/2008, as amended

Substance name Hazard class Hazard category Route of exposure H Phrases

Hydrochloric acid Skin corrosion Category 1B H314

Specific target organ toxicity

– singe exposure Category 3

H335

Corrosive to metals Category 1 H290

3.3. Hazardous components – European Directive 67/548/EEC or 1999/45/EC, as amended

Substance name Classification Hazard category R-phrase(s)

Sodium hypochlorite C Corrosive R34

Xi Irritant R37

4. FIRST AID MEASURES

4.1. Description of necessary first-aid measures

4.1.1. If inhaled

- Move to fresh air.

- Oxygen or artificial respiration if needed.

- Victim to lie down in the recovery position, cover and keep him warm.

- Call a physician immediately.

4.1.2. In case of eye contact

- SPEED IS ESSENTIAL.

- Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.

- In the case of difficulty of opening the lids, administer an analgesic eye wash (oxybuprocaine).

- Call a physician or poison control centre immediately.

- Take victim immediately to hospital.

4.1.3. In case of skin contact

- SPEED IS ESSENTIAL.

- Take off contaminated clothing and shoes immediately.

- Wash off immediately with plenty of water.

- Keep warm and in a quiet place.


- Wash contaminated clothing before re-use.

4.1.4. If swallowed


- Take victim immediately to hospital.

- If swallowed, rinse mouth with water (only if the person is conscious).

- Do NOT induce vomiting.

- Artificial respiration and/or oxygen may be necessary.

4.2. Most important symptoms/effects, acute and delayed

4.2.1. Inhalation

- Severe respiratory irritant

- Symptoms: Breathing difficulties, cough, chemical pneumonitis, pulmonary oedema

- Repeated or prolonged exposure: Nose bleeds, chronic bronchitis.

4.2.2. Skin contact

- Causes severe burns.

- Symptoms: Redness, Swelling of tissue, Burns.

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4.2.3. Eye contact

- Corrosive – causes irreversible eye damage

- May cause blindness.

- Symptoms: Redness, Lachrymation, Swelling of tissue, Burn

4.2.4. Ingestion

- If ingested, severe burns of the mouth and throat, as well as a danger of perforation of the oesophagus and the stomach.

- Symptoms: Nausea, Abdominal pain, Bloody vomiting, Diarrhoea, Suffocation, Cough, Severe shortness of breath.

5. FIRE-FIGHTING MEASURES

5.1. Extinguishing media

5.1.1. Suitable extinguishing media

- Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.

5.1.2. Unsuitable extinguishing media

- None.

5.2. Specific hazards arising from the chemical

- The product is not flammable.

- Not combustible

- Reacts violently with water.

- Hazardous decomposition products formed under fire conditions.

- Gives off hydrogen by reaction with metals.

5.3. Special protective actions for fire-fighters

- In the event of fire, wear self-contained breathing apparatus.

- Use personal protective equipment.

- Wear chemical resistant oversuit.

- Cool containers / tanks with water spray.

6. ACCIDENTAL RELEASE MEASURES

6.1. Personal precautions, protective equipment and emergency procedures

6.1.1. Advice for non-emergency personnel

- Prevent further leakage or spillage if safe to do so.

- Keep away from Incompatible products.

6.1.2. Advice for emergency responders

- Evacuate personnel to safe areas.

- Keep people away from and upwind of spill/leak.

- Ventilate the area.

- Wear suitable protective clothing.

6.2. Environmental precautions

- Should not be released into the environment.

- If the product contaminates rivers and lakes or drains inform respective authorities.

6.3. Methods and materials for containment and cleaning up

- Dam up.

- Soak up with inert absorbent material.

- Prevent product from entering drains.

- Keep in properly labelled containers.

- Keep in suitable, closed containers for disposal.

6.4. Reference to other sections

- Refer to protective measures listed in sections 7 and 8


7.1. Precautions for safe handling

- Used in closed system

- Use only in well-ventilated areas.

- When diluting, always add the product to water. Never add water to the product.

- Keep away from incompatible products.

- To avoid thermal decomposition, do not overheat.

7.2. Conditions for storage, including incompatibilities

7.2.1. Storage

- Store in original container.

- Keep in a well-ventilated place.

- Keep in properly labelled containers.

- Keep container closed.

- Keep away from incompatible products.

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7.2.2. Packaging material

7.2.2.1. Suitable material

- Steel coated.

- PVC

- Polyethylene

- Reinforced polyester

- Glass

7.2.2.2. Unsuitable material

- Metals

7.3. Specific use(s)

- For further information, please contact: Supplier

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1. Control parameters

8.1.1. Exposure Limit Values

Hydrochloric acid

- Ireland: Code of Practice for the Safety Health & Welfare at Work (Chemical Agents) Regulations 2011 (SI No. 619 of 2001)

Occupational Exposure Limit Value(8-hour reference period) = 5 ppm (= 8 mg/m3) - Remarks: Indicative

- Ireland: Code of Practice for the Safety Health & Welfare at Work (Chemical Agents) Regulations 2011 (SI No. 619 of 2001)

Occupational Exposure Limit Value(15 minute reference period) = 10 ppm (= 15 mg/m3) - Remarks: Indicative

- UK. EH40 Workplace Exposure Limits (WELs) 2007

Time weighted average = 1 ppm (=2 mg/m3) -Remarks: Gas and aerosol mists

- UK. EH40 Workplace Exposure Limits (WELs) 2007

Short term exposure limit = 5 ppm (= 8 mg/m3)- Remarks: Gas and aerosol mists

- US. ACGIH Threshold Limit Values 2009

Ceiling Limit Value = 2 ppm

- EU. Indicative Exposure and Directives relating to the protection of risks related to work exposure to chemical, physical, and biological

agents. 12 2009

Time weighted average = 5 ppm (= 8 mg/m3)- Remarks: Indicative

- EU. Indicative Exposure and Directives relating to the protection of risks related to work exposure to chemical, physical, and biological

agents. 12 2009

Short term exposure limit = 10 ppm (= 15 mg/m3)- Remarks: Indicative

8.1.2. Other information on limit values

8.1.2.1. Predicted No Effect Concentration

- Fresh water, 36 mg/l

- Marine water, 36 mg/l

- Sewage treatment plants, 36 mg/l

8.1.2.2. Derived No Effect Level / Derived minimal effect level

- Workers, Inhalation, Acute effects, 15 mg/m3, Local effects

- Workers, Inhalation, Chronic effects, 8 mg/m3, Local effects

8.2. Exposure controls

8.2.1. Appropriate engineering controls

- Provide adequate ventilation.

- Apply technical measures to comply with the occupational exposure limits.

8.2.2. Individual protection measures

8.2.2.1. Respiratory protection

- Use respirator when performing operations involving potential exposure to vapour of the product.

- Respirator with a vapour filter (EN 141)

- Recommended Filter type: AB

- Self-contained breathing apparatus in medium confinement/insufficient oxygen/in case of large uncontrolled emissions/in all circumstances

when the mask and cartridge do not give adequate protection.

8.2.2.2. Hand protection

- Impervious gloves in compliance with EN374:2003.

- Take note of the information given by the producer concerning permeability and break through times, and of special workplace conditions

(mechanical strain, duration of contact). The following list may be used for guidance but is not exhaustive:

- Nitrile rubber- NBR: thickness >= 0,35mm; breakthrough time>=480min.

- Polyvinyl chloride- PVC: thickness >=0,5mm; breakthrough time>=480min.

- Butyl rubber llR: thickness>= 0,5mm; breakthrough time>=480min.

- Dispose of contaminated gloves appropriately.

8.2.2.3. Eye protection

- Chemical resistant goggles or full-face shield must be worn.

- If splashes are likely to occur, wear: Tightly fitted safety goggles, Face shield.

8.2.2.4. Skin and body protection

- Chemical resistant apron

- If splashes are likely to occur, wear: Rubber or plastic boots, Rubber apron or full PVC overalls.

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8.2.2.5. Hygiene measures

- Eye wash bottles or eye wash stations in compliance with applicable standards.

- Take off contaminated clothing and shoes immediately.

- Wash contaminated clothing before re-use.

- When using, do not eat, drink or smoke.

- Wash hands before breaks and at the end of workday.

- Handle in accordance with good industrial hygiene and safety practice.

8.2.3. Environmental Exposure controls

- Dispose of rinse water in accordance with local and national regulations.

9. PHYSICAL AND CHEMICAL PROPERTIES

9.1. Physical and chemical properties

9.1.1. General Information

Appearance Fuming liquid when in contact with air

Colour colourless to pale yellow

Odour pungent

Molecular Weight 36.47 g/mol

9.1.2. Important health safety and environmental information

pH 0.1 (4 % solution)

pKa Not applicable

Melting point/freezing point -63oC (28%); -27

oC (36%)

Boiling point/boiling range 97.7oC (28%); 56.

oC (36%)108

oC

Flash point not applicable

Evaporation rate No data

Flammability (solid, gas) not applicable

Flammability The product is not flammable

Explosive properties Not explosive

Vapour pressure ca. 190 hPa, at 20oC

Vapour density No data

Relative density(20oC) 1.14 (28%); 1.18 (36%)

Bulk density No data

Solubility(ies) Completely soluble in water

Solubility/qualitative Completely miscible, Ether, Alcohol, Acetone, Acetic acid, Benzene, Chloroform

Partition coefficient: n-octanol/water not applicable

Autoignition temperature No data

Decomposition temperature No data

Viscosity No data

Oxidizing properties Non oxidizer

10. STABILITY AND REACTIVITY

10.1. Reactivity

- Potential for exothermic hazard

- Corrosive to metals

10.2. Chemical stability

- Stable under recommended storage conditions.


- Gives off hydrogen by reaction with metals.

- Keep away from strong bases

- Risk of violent reaction with oxidising agents liberating Chlorine.

- Risk of explosion.

10.4. Conditions to avoid

- Keep away from direct sunlight.

- To avoid thermal decomposition, do not overheat.

- Exposure to moisture.

- Generation of mists or aerosols

10.5. Materials to avoid

- Metals, Oxidizing agents, Acids, Fluorine, Strong bases, Vinylacetate, Hypochlorite

10.6. Hazardous decomposition products

- Hydrogen chloride gas, Hydrogen, Chlorine.

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11. TOXICOLOGICAL INFORMATION

11.1. Acute toxicity

11.1.1. Acute oral toxicity

- no data available. Will immediately cause corrosion of and damage to gastrointestinal tract.

11.1.2. Acute inhalation toxicity

- LC50, rat, 45.6 mg/m3 (Hydrogen Chloride)

11.1.3. Acute dermal toxicity

- no data available. Corrosive nature of the substance will predominate.

11.1.4. Irritation (other route)

- Inhalation, mouse, Irritating to respiratory system, 309 ppm, (Hydrogen chloride)

- Various species, Irritating to mucous membranes

11.2. Skin corrosion/irritation

- rabbit, Corrosive-causes severe burns.

11.3. Serious eye damage/eye irritation

- rabbit, Corrosive-causes severe eye damage.

11.4. Respiratory or skin sensitization

- Did not cause sensitization on laboratory animals.

11.5. Mutagenicity

- In vitro tests did not show mutagenic effects

11.6. Carcinogenicity

- Inhalation, Prolonged exposure, rat, Animal testing did not show any carcinogenic effects.

11.7. Toxicity for reproduction

- Animal testing did not show any effects on fertility.

11.8. Repeated dose toxicity

- Inhalation, rat, Respiratory system 15 mg/m3, NOAEC, (Hydrogen chloride)

12. ECOLOGICAL INFORMATION

12.1. Toxicity

Large discharges may contribute to the acidification of water and may be fatal to fish and other aquatic life. Can cause severe damage to aquatic

plants.

- Fishes, Lepomis macrochirus, LC50, 96 h, 20.5 mg/l, pH 3,25 – 3,5 (Hydrogen chloride)

- Crustaceans, Daphnia magna, EC50, 48 h, 0.45 mg/l, pH 4,9 (Hydrogen chloride)

- Algae, Chorella vulgaris, EC50, 72 h, 0.73 mg/l, pH 4,7 (Hydrogen Chloride)

12.2. Persistence and degradability

Freely dissociates to Hydrogen and Chloride ions.

12.2.1. Abiotic degradation

- Air, indirect photo-oxidation, t ½ 11 d

Conditions: sensitizer: OH radicals

- Water, Soil Result: Ionization/neutralization: Conditions: pH

12.2.2. Biodegradation

- The methods for determining biological degradability are not applicable to inorganic substances.

12.3. Bioaccumulative potential

- Not applicable

12.4. Mobility

- Air

Very volatile

- Water, Soil

Considerable solubility and mobility

12.5. Results of PBT and vPvB assessment

Not classified as PBT or vPvB

12.6. Other adverse effects

- No data available

13. DISPOSAL CONSIDERATIONS

13.1. Waste disposal methods

- Dilute with plenty of water.

- Solutions with low pH-value must be neutralized before discharge.

- Neutralize with chalk, alkali solution or ammonia.

- In accordance with local and national regulations.

13.2. Contaminated packaging

- Where possible recycling is preferred to disposal or incineration.

- Clean container with water.

- Dispose of as unused product.

- In accordance with local and national regulations.

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14. TRANSPORT INFORMATION

14.1. International transport regulations

- IATA-DGR

UN number UN 1789

Class 8

Packing group II

ICAO-Labels 8 - Corrosive

Proper shipping name HYDROCHLORIC ACID

- IMDG

UN number UN 1789

Class 8

Packing group II

IMDG-Labels 8 - Corrosive

HI/UN No. 1789

EmS F-A

S-B


- ADR

UN number UN 1789

Class 8

Packing group II

ADR/RID-Labels 8 – Corrosive

HI/UN No. 80 / 1789


- RID

UN number UN 1789

Class 8

Packing group II


HI/UN No. 80 / 1789


- ADN

UN number UN 1789

Class 8

Packing group II



15. REGULATORY INFORMATION

15.1. Applicable Laws or Regulations

- Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration,

Evaluation, Authorisation and Restriction of Chemicals (REACH), as amended.

- Directive 1999/45/EC of the European Parliament and of the Council of 31 May 1999 concerning the approximation of the laws, regulations

and administrative provisions of the Member States relating to the classification, packaging and labelling of dangerous preparations, as

amended.

- Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and

packaging of substances and mixtures, as amended.

- Council Directive 98/24/EC of 7 April 1998 on the protection of the health and safety of workers from the risks related to chemical agents at

work, as amended.

- Commission Directive 2000/39/EC of 8 June 2000 establishing a first list of indicative occupational exposure limit values in implementation

of Council Directive 98/24/EC on the protection of the health and safety of workers from the risks related to chemical agents at work, as

amended.

- Directive 2008/98/EC of the European Parliament and of the Council of 19 November 2008 on waste.

- Code of Practice for the Safety Health & Welfare at Work (Chemical Agents) Regulations 2011 (SI No. 619 of 2001)

- COUNCIL DIRECTIVE 96/82/EC on the control of major-accident hazards involving dangerous substances as amended.

- EH40/2005. Workplace Exposure Limits, as amended through 1,10,2007 (WELs). Published by the Health and Safety Executive (HSE).

Issued under the Control of Substances Hazardous to Health Regulations – as amended.

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15.2. Notification status

Inventory Information Status

Toxic Substance Control Act list (TSCA) - In compliance with inventory

Australian Inventory of Chemical Substances (AICS) - In compliance with inventory

Canadian Domestic Substances List (DSL) - In compliance with inventory

Korean Existing Chemicals List (ECL) - In compliance with inventory

EU list of existing chemical substances (EINECS) - In compliance with inventory

Japanese Existing and New Chemical Substances (MITI List) (ENCS) - In compliance with inventory

Inventory of Existing Chemical Substances (China) (IECS) - In compliance with inventory

Philippine Inventory of Chemicals and Chemical Substances (PICCS) - In compliance with inventory

New Zealand Inventory of Chemicals (NZIOC) - In compliance with inventory

16. OTHER INFORMATION

16.1. Full text of H-Statements referred to under section 3

H290 - May be corrosive to metals.

H314 - Causes severe skin burns and eye damage.

H335 - May cause respiratory irritation

16.2. Full text of R-phrases referred to under sections 2 and 3

16.2.1. Full text of R-phrases referred to under section 2

R34 - Causes burns.

R37 - Irritating to respiratory system.

16.2.2. Full text of R-phrases referred to under section 3

R34 - Causes burns.

R37 - Irritating to respiratory system.

16.3. Other information

- Revised SDS (Revision 4).

Section Revisions to Previous issue

8 Inclusion of OELV’s from Irish Code of Practice-Chemical Agents. Update of information on hand protection.

All General reformatting without content change.

- Distribute new edition to clients

This SDS is only intended for the indicated country to which it is applicable. The European SDS format compliant with the applicable European

legislation is not intended for use nor distribution in countries outside the European Union with the exception of Norway and Switzerland. Safety

datasheets applicable in other countries/regions are available upon request. The information given corresponds to the current state of our knowledge

and experience of the product, and is not exhaustive. This applies to product which conforms to the specification, unless otherwise stated. In this

case of combinations and mixtures one must make sure that no new dangers can arise. In any case, the user is not exempt from observing all legal,

administrative and regulatory procedures relating to the product, personal hygiene, and protection of human welfare and the environment.

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Safety Data Sheet

Version : 1.03

Product : Propane

MSDS Nr : 302-00-0045BOC(A)

Page :1/5

Date : 09/09/2003

Replaces version dated : 02/08/1994

BOC, Priestley Road, Worsley, Manchester M28 2UT Emergency tel: 0800 02 0800 - - UNITED KINGDOM

1 IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY

Product name Propane

Chemical formula C3H8

Company identification see heading and/or footer

Emergency phone numbers see heading and/or footer


Substance/Preparation Substance.

Components/Impurities Contains no other components or impurities which will influence the classification of the

product.

CAS Nr 74-98-6

EC Nr (from EINECS) 200-827-9


Hazards identification Liquefied gas

Extremely flammable


Inhalation In low concentrations may cause narcotic effects. Symptoms may include dizziness, headache,

nausea and loss of co-ordination.

In high concentrations may cause asphyxiation. Symptoms may include loss of

mobility/consciousness. Victim may not be aware of asphyxiation.

Remove victim to uncontaminated area wearing self contained breathing apparatus. Keep

victim warm and rested. Call a doctor. Apply artificial respiration if breathing stopped.

Skin/eye contact In case of frostbite spray with water for at least 15 minutes. Apply a sterile dressing.

Immediately flush eyes thoroughly with water for at least 15 minutes.

Obtain medical assistance

Ingestion Ingestion is not considered a potential route of exposure.


Specific hazards Exposure to fire may cause containers to rupture/explode.

Hazardous combustion products Incomplete combustion may form carbon monoxide.

Suitable extinguishing media All known extinguishants can be used.

Specific methods If possible, stop flow of product.

Move away from the container and cool with water from a protected position.

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Safety Data Sheet

Version : 1.03

Product : Propane

MSDS Nr : 302-00-0045BOC(A)

Page :2/5

Date : 09/09/2003



Do not extinguish a leaking gas flame unless absolutely necessary. Spontaneous/explosive

re-ignition may occur. Extinguish any other fire.

Special protective equipment for fire fighters Use self-contained breathing apparatus.


Personal precautions Evacuate area.

Wear self-contained breathing apparatus when entering area unless atmosphere is proved to be

safe.

Ensure adequate air ventilation.

Eliminate ignition sources.

Environmental precautions Try to stop release.

Prevent from entering sewers, basements and workpits, or any place where its accumulation

can be dangerous.

Clean up methods Ventilate area.


Handling and storage Ensure equipment is adequately earthed.

Suck back of water into the container must be prevented.

Purge air from system before introducing gas.

Do not allow backfeed into the container.

Use only properly specified equipment which is suitable for this product, its supply pressure

and temperature. Contact your gas supplier if in doubt.

Keep away from ignition sources (including static discharges).

Segregate from oxidant gases and other oxidants in store.

Refer to supplier's container handling instructions.

Keep container below 50°C in a well ventilated place.


Personal protection Ensure adequate ventilation.

Do not smoke while handling product.


Molecular weight 44

Melting point -188 °C

Boiling point -42.1 °C

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Safety Data Sheet

Version : 1.03

Product : Propane

MSDS Nr : 302-00-0045BOC(A)

Page :3/5

Date : 09/09/2003



Critical temperature 97 °C

Relative density, gas 1.5 (air=1)

Relative density, liquid 0.51 (water=1)

Vapour Pressure 20°C 8.3 bar

Solubility mg/l water 75 mg/l

Appearance/Colour Colourless gas

Odour Sweetish

Poor warning properties at low concentrations.

Stenchant often added

Flammability range 2.1 - 9.5 vol% in air.

Autoignition temperature 450 °C

Other data Gas/vapour heavier than air. May accumulate in confined spaces, particularly at or below

ground level.


Stability and reactivity Can form explosive mixture with air.

May react violently with oxidants.


General No known toxicological effects from this product.


General No known ecological damage caused by this product.


General Do not discharge into areas where there is a risk of forming an explosive mixture with air.

Waste gas should be flared through a suitable burner with flash back arrestor.

Do not discharge into any place where its accumulation could be dangerous.

Contact supplier if guidance is required.


Proper shipping name PROPANE

UN Nr 1978

Class 2

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Safety Data Sheet

Version : 1.03

Product : Propane

MSDS Nr : 302-00-0045BOC(A)

Page :4/5

Date : 09/09/2003



ADR/RID Classification code 2F

ADR/RID Hazard Nr 23

Labelling ADR Label 2.1: flammable gas

Other transport information Avoid transport on vehicles where the load space is not separated from the driver's

compartment.

Ensure vehicle driver is aware of the potential hazards of the load and knows what to do in the

event of an accident or an emergency.

Before transporting product containers ensure that they are firmly secured and:

- cylinder valve is closed and not leaking

- valve outlet cap nut or plug (where provided) is correctly fitted

- valve protection device (where provided) is correctly fitted

- there is adequate ventilation.

- compliance with applicable regulations.


Number in Annex I of Dir 67/548 601-003-00-5.

EC Classification F+;R12

-Symbols F+: Extremely flammable

Labelling of cylinders

-Symbols Label 2.1: flammable gas

-Risk phrases R12 Extremely flammable.

-Safety phrases S9 Keep container in well ventilated place.

S16 Keep away from ignition sources - No smoking.

S33 Take precautionary measures against static discharges.


Ensure all national/local regulations are observed.

Ensure operators understand the flammability hazard.

Contact with liquid may cause cold burns/frost bite.

The hazard of asphyxiation is often overlooked and must be stressed during operator training.

Users of breathing apparatus must be trained.

This Safety Data Sheet has been established in accordance with the applicable European Directives and applies to all countries that have translated the Directives in their

national laws.

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Safety Data Sheet

Version : 1.03

Product : Propane

MSDS Nr : 302-00-0045BOC(A)

Page :5/5

Date : 09/09/2003



Before using this product in any new process or experiment, a thorough material compatibility and safety study should be carried out.

Details given in this document are believed to be correct at the time of going to press. Whilst proper care has been taken in the preparation of this document, no liability

for injury or damage resulting from its use can be accepted.

End of document.Number of pages :5

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Safety Data Sheet

Version : 1.03

Product : Propane

MSDS Nr : 302-00-0045BOC(A)

Page :1/5

Date : 09/09/2003



1 IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY

Product name Propane

Chemical formula C3H8

Company identification see heading and/or footer

Emergency phone numbers see heading and/or footer


Substance/Preparation Substance.

Components/Impurities Contains no other components or impurities which will influence the classification of the

product.

CAS Nr 74-98-6

EC Nr (from EINECS) 200-827-9


Hazards identification Liquefied gas

Extremely flammable


Inhalation In low concentrations may cause narcotic effects. Symptoms may include dizziness, headache,

nausea and loss of co-ordination.

In high concentrations may cause asphyxiation. Symptoms may include loss of

mobility/consciousness. Victim may not be aware of asphyxiation.

Remove victim to uncontaminated area wearing self contained breathing apparatus. Keep

victim warm and rested. Call a doctor. Apply artificial respiration if breathing stopped.

Skin/eye contact In case of frostbite spray with water for at least 15 minutes. Apply a sterile dressing.

Immediately flush eyes thoroughly with water for at least 15 minutes.

Obtain medical assistance

Ingestion Ingestion is not considered a potential route of exposure.


Specific hazards Exposure to fire may cause containers to rupture/explode.

Hazardous combustion products Incomplete combustion may form carbon monoxide.

Suitable extinguishing media All known extinguishants can be used.

Specific methods If possible, stop flow of product.

Move away from the container and cool with water from a protected position.

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EPA Export 28-07-2015:23:40:11

Safety Data Sheet

Version : 1.03

Product : Propane

MSDS Nr : 302-00-0045BOC(A)

Page :2/5

Date : 09/09/2003



Do not extinguish a leaking gas flame unless absolutely necessary. Spontaneous/explosive

re-ignition may occur. Extinguish any other fire.

Special protective equipment for fire fighters Use self-contained breathing apparatus.


Personal precautions Evacuate area.

Wear self-contained breathing apparatus when entering area unless atmosphere is proved to be

safe.

Ensure adequate air ventilation.

Eliminate ignition sources.

Environmental precautions Try to stop release.

Prevent from entering sewers, basements and workpits, or any place where its accumulation

can be dangerous.

Clean up methods Ventilate area.


Handling and storage Ensure equipment is adequately earthed.

Suck back of water into the container must be prevented.

Purge air from system before introducing gas.

Do not allow backfeed into the container.

Use only properly specified equipment which is suitable for this product, its supply pressure

and temperature. Contact your gas supplier if in doubt.

Keep away from ignition sources (including static discharges).

Segregate from oxidant gases and other oxidants in store.

Refer to supplier's container handling instructions.

Keep container below 50°C in a well ventilated place.


Personal protection Ensure adequate ventilation.

Do not smoke while handling product.


Molecular weight 44

Melting point -188 °C

Boiling point -42.1 °C

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Safety Data Sheet

Version : 1.03

Product : Propane

MSDS Nr : 302-00-0045BOC(A)

Page :3/5

Date : 09/09/2003



Critical temperature 97 °C

Relative density, gas 1.5 (air=1)

Relative density, liquid 0.51 (water=1)

Vapour Pressure 20°C 8.3 bar

Solubility mg/l water 75 mg/l

Appearance/Colour Colourless gas

Odour Sweetish

Poor warning properties at low concentrations.

Stenchant often added

Flammability range 2.1 - 9.5 vol% in air.

Autoignition temperature 450 °C

Other data Gas/vapour heavier than air. May accumulate in confined spaces, particularly at or below

ground level.


Stability and reactivity Can form explosive mixture with air.

May react violently with oxidants.


General No known toxicological effects from this product.


General No known ecological damage caused by this product.


General Do not discharge into areas where there is a risk of forming an explosive mixture with air.

Waste gas should be flared through a suitable burner with flash back arrestor.

Do not discharge into any place where its accumulation could be dangerous.

Contact supplier if guidance is required.


Proper shipping name PROPANE

UN Nr 1978

Class 2

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Safety Data Sheet

Version : 1.03

Product : Propane

MSDS Nr : 302-00-0045BOC(A)

Page :4/5

Date : 09/09/2003



ADR/RID Classification code 2F

ADR/RID Hazard Nr 23

Labelling ADR Label 2.1: flammable gas

Other transport information Avoid transport on vehicles where the load space is not separated from the driver's

compartment.

Ensure vehicle driver is aware of the potential hazards of the load and knows what to do in the

event of an accident or an emergency.

Before transporting product containers ensure that they are firmly secured and:

- cylinder valve is closed and not leaking

- valve outlet cap nut or plug (where provided) is correctly fitted

- valve protection device (where provided) is correctly fitted

- there is adequate ventilation.

- compliance with applicable regulations.


Number in Annex I of Dir 67/548 601-003-00-5.

EC Classification F+;R12

-Symbols F+: Extremely flammable

Labelling of cylinders

-Symbols Label 2.1: flammable gas

-Risk phrases R12 Extremely flammable.

-Safety phrases S9 Keep container in well ventilated place.

S16 Keep away from ignition sources - No smoking.

S33 Take precautionary measures against static discharges.


Ensure all national/local regulations are observed.

Ensure operators understand the flammability hazard.

Contact with liquid may cause cold burns/frost bite.

The hazard of asphyxiation is often overlooked and must be stressed during operator training.

Users of breathing apparatus must be trained.

This Safety Data Sheet has been established in accordance with the applicable European Directives and applies to all countries that have translated the Directives in their

national laws.

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Safety Data Sheet

Version : 1.03

Product : Propane

MSDS Nr : 302-00-0045BOC(A)

Page :5/5

Date : 09/09/2003



Before using this product in any new process or experiment, a thorough material compatibility and safety study should be carried out.

Details given in this document are believed to be correct at the time of going to press. Whilst proper care has been taken in the preparation of this document, no liability

for injury or damage resulting from its use can be accepted.

End of document.Number of pages :5

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SUPRASEC® 1041

Identification of the substance/preparation and of thecompany/undertaking

SAFETY DATA SHEET

Product name

SUPRASEC® 1041

Conforms to EU Directive 91/155/EEC, as amended by 2001/58/EC - United Kingdom (UK)

1.

Emergency telephone number

:

Supplier

:

:

Use of thesubstance/preparation

:Component of a Polyurethane System

Identification of the substance or preparation

Company/undertaking identification

Huntsman Holland BVRozenburg WorksMerseyweg 10RotterdamThe NetherlandsTel +31 181 29 91 11

EUROPE: +32 35 75 1234ASIA: +65 6336-6011USA: +1/800/424.9300

Local contact address : if available, see section 16.

Composition/information on ingredients2.Substance/preparation Preparation:

Within the present knowledge of the supplier, this product does not contain any hazardous ingredients inquantities requiring reporting in this section, in accordance with EU or national regulations.

See section 16 for the full text of the R-phrasesdeclared above

Diphenylmethanediisocyanate, isomers andhomologues

9016-87-9 60 - 100 Xn; R20Xi; R36/37/38R42/43

Isocyanates, reaction product of polyol withmethylenediphenyl diisocyanate

3 - 7 Xn; R20Xi; R36/37/38R42/43

Hazards identification3.

Classification Xn; R20Xi; R36/37/38R42/43

:

The preparation is classified as dangerous according to Directive 1999/45/EC and its amendments.

Physical/chemical hazards : Reacts slowly with water to produce carbon dioxide which may rupture closedcontainers. This reaction accelerates at higher temperatures.

:Human health hazards Harmful by inhalation.Irritating to eyes, respiratory system and skin.May cause sensitisation by inhalation and skin contact.This product is a respiratory irritant and potential respiratory sensitiser: repeatedinhalation of vapour or aerosol at levels above the occupational exposure limit couldcause respiratory sensitisation. A hyper-reactive response to even minimalconcentrations of MDI may develop in sensitised persons. The onset of therespiratory symptoms may be delayed for several hours after exposure.

See section 11 for more detailed information on health effects and symptoms.

Date of issue : Page: 1/828 December 2005

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SUPRASEC 1041

Do NOT induce vomiting unless directed to do so by medical personnel. Never giveanything by mouth to an unconscious person. Provided the patient is conscious,wash out mouth with water. Get medical attention if symptoms appear.

Skin contact

In case of contact, immediately flush eyes with a copious amount of water for at least15 minutes. Obtain medical attention immediately.

After contact with skin, wash immediately with plenty of soap and water. Get medicalattention if irritation develops. Wash clothing before reuse. Clean shoes thoroughlybefore reuse. An MDI study has demonstrated that a polyglycol-based skin cleanseror corn oil may be more effective than soap and water.

4.First-aid measures

If inhaled, remove to fresh air. If not breathing, give artificial respiration. Obtainmedical attention immediately. Treatment is symptomatic for primary irritation orbronchospasm. If breathing is laboured, oxygen should be administered by qualifiedpersonnel.

Notes to physician Symptomatic treatment and supportive therapy as indicated. Following severeexposure the patient should be kept under medical review for at least 48 hours.

Ingestion

Inhalation

Eye contact

:

:

:

:

:

First-aid measures

See section 11 for more detailed information on health effects and symptoms.

Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training.

Fire-fighting measures5.

Hazardous thermaldecomposition products

Special exposure hazards

Combustion products may include: carbon oxides (CO, CO2) nitrogen oxides (NO,NO2...) hydrocarbons and HCN

No specific hazard.

Fire-fighters should wear appropriate protective equipment and self-containedbreathing apparatus (SCBA) with a full face-piece operated in positive pressuremode. PVC boots, gloves, safety helmet and protective clothing should be worn.

Special protectiveequipment for fire-fighters

:

:

:

Due to reaction with water producing CO2-gas, a hazardous build-up of pressurecould result if contaminated containers are re-sealed. Containers may burst ifoverheated.

Remark :

Use an extinguishing agent suitable for the surrounding fire.

Extinguishing media

None known.

Suitable :

Not suitable :

Environmental precautions

Personal precautions

If the product is in its solid form: Spilled MDI flakes should be picked up carefully.The area should be vacuum cleaned to remove remaining dust particles completely.If the product is in its liquid form: Absorb spillages onto sand, earth or any suitableadsorbent material. Leave to react for at least 30 minutes. Do not absorb ontosawdust or other combustible materials. Shovel into open-top drums for furtherdecontamination. Wash the spillage area with water. Test atmosphere for MDIvapour. Neutralise small spillages with decontaminant. Remove and dispose ofresidues. The compositions of liquid decontaminants are given in Section 16. Seealso brochure PU 193-1 (see section 16).

6. Accidental release measures

:

: Immediately contact emergency personnel. Evacuate the area. Keep upwind toavoid inhalation of vapours. Clean-up should only be performed by trained personnel.People dealing with major spillages should wear full protective clothing includingrespiratory protection. Use suitable protective equipment (section 8).

Avoid dispersal of spilt material and runoff and contact with soil, waterways, drainsand sewers.

Methods for cleaning up :


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SUPRASEC 1041

Handling

Handling and storage

Storage

7.Do not breathe vapour/spray. Avoid contact with skin and eyes. Atmosphericconcentrations should be minimised and kept as low as reasonably practicable belowthe occupational exposure limit. The efficiency of the ventilation system must bemonitored regularly because of the possibility of blockage. When the product issprayed or heated, suitable respiratory protection equipment with positive air supplyis required. Keep equipment clean.A basic essential in sampling, handling and storage is the prevention of contact withwater. Keep stocks of decontaminant readily available. The compositions of liquiddecontaminants are given in Section 16. See also brochure PU 193-1 (see section16).

Packaging materials

Suitable containers: Steel. Stainless steel.Unsuitable containers: Copper., copper alloy and galvanised surfaces

Keep container tightly closed. Keep container in a cool, well-ventilated area. Keepaway from moisture. If a container is contaminated, do not reseal it. Due to reactionwith water producing CO2-gas, a hazardous build-up of pressure could result ifcontaminated containers are re-sealed.Storage Life: See Product Data SheetStorage Temperature: See Product Data Sheet

:

:

:

Recommended

Ingredient name Occupational exposure limits

8. Exposure controls/personal protection

Hand protection

Exposure controls

Use a properly fitted, air-purifying or air-fed respirator complying with an approvedstandard if a risk assessment indicates this is necessary.Respirator selection mustbe based on known or anticipated exposure levels, the hazards of the product andthe safe working limits of the selected respirator.

Use chemical resistant gloves classified under Standard EN374: protective glovesagainst chemicals and microorganisms.Examples of glove materials that mightprovide suitable protection include :Butyl rubber, Chlorinated polyethylene,Polyethylene, Ethyl vinyl alcohol copolymers laminated (“EVAL”), Polychloroprene(Neoprene*), Nitrile/butadiene rubber (“nitrile”or “NBR”), Polyvinyl chloride (“PVC”or“vinyl”), Fluoroelastomer (Viton*).

When prolonged or frequently repeated contact may occur, a glove with protectionclass of 5 or higher (breakthrough time greater then 240 minutes according toEN374) is recommended.

When only brief contact is expected, a glove with protection class of 3 or higher

Respiratory protection :

:

Diphenylmethane 4,4' diisocyanate EH40-MEL (United Kingdom (UK), 1/2003).STEL: 0.07 mg/m3 15 minute/minutes. Form: All formsTWA: 0.02 mg/m3 8 hour/hours. Form: All forms

EH40-WEL (United Kingdom (UK), 1/2005).STEL: 0.07 mg/m3 15 minute/minutes. Form: All formsTWA: 0.02 mg/m3 8 hour/hours. Form: All forms

United Kingdom (UK)

Recommended monitoringprocedures

: Medical supervision of all employees who handle or come in contact with respiratorysensitisers is recommended. Personnel with a history of asthma-type conditions,bronchitis or skin sensitisation conditions should not work with MDI based products.The Occupational Exposure Limits listed do not apply to previously sensitisedindividuals. Sensitised individuals should be removed from any further exposure.

Occupational exposurecontrols

: Provide exhaust ventilation or other engineering controls to keep the airborneconcentrations of vapours below their respective occupational exposure limits. MDIcan only be smelled if the occupational exposure limit has been exceededconsiderably.

Environmental exposurecontrols

: Emissions from ventilation or work process equipment should be checked to ensurethey comply with the requirements of environmental protection legislation. In somecases, fume scrubbers, filters or engineering modifications to the process equipmentwill be necessary to reduce emissions to acceptable levels.


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SUPRASEC 1041

(breakthrough time greater than 60 minutes according to EN374) is recommended.Contaminated gloves should be decontaminated and disposed of.

Notice: The selection of a specific glove for a particular application and duration ofuse in a workplace should also take into account all requisite workplace factors suchas, but not limited to : other chemicals that may be handled, physical requirements(cut/puncture protection, dexterity, thermal protection), as well asinstructions/specifications provided by the glove supplier.

Protective gloves should be worn when handling freshly made polyurethane productsto avoid contact with trace residual materials which may be hazardous in contact withskin.

Safety eyewear complying with an approved standard should be used when a riskassessment indicates this is necessary to avoid exposure to liquid splashes, mists ordusts.

Eye protection :

Skin protection Personal protective equipment for the body should be selected based on the taskbeing performed and the risks involved and should be approved by a specialistbefore handling this product.Body: Recommended: Overall (preferably heavy cotton) or Tyvek-Pro Tech 'C' ,Tyvek-Pro 'F' disposable coverall.

:

Wash hands, forearms and face thoroughly after handling chemical products, beforeeating, smoking and using the lavatory and at the end of the working period.Appropriate techniques should be used to remove potentially contaminated clothing.Wash contaminated clothing before reusing. Ensure that eyewash stations andsafety showers are close to the workstation location.

>300 °C decomposes

Physical and chemical properties

Physical state

Melting point

Boiling point

Vapour pressure

Vapour density

Liquid.

Not available.

8.5

Not available.

slightly mustyOdour

Evaporation rate (butylacetate = 1)

Not available.

Auto-ignition temperature

Flash point

>600 Deg C

Closed cup: 222°C (431.6°F). Open cup: 222°C (431.6°F).

Not explosive

Not available.Flammability (solid, gas)

9.

Not applicable. Reacts with water and octanol.

Viscosity 1.80-3.70 poise(at 25C)

Not available.Odour threshold

Octanol/water partitioncoefficient

Explosive properties

:

:

:

:

:

:

:

:

:

:

:

:

:

:

Not available.Oxidising properties :

General information

Appearance

Important health, safety and environmental information

Other information

Saturated VapourConcentration

> 32 µg/m3 @ 20 Deg C:

Solubility : Insoluble in Water


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SUPRASEC 1041

Hazardous decompositionproducts

Conditions to Avoid Avoid high temperatures.

Stability and reactivity

Combustion products may include: carbon oxides (CO, CO2) nitrogen oxides (NO,NO2...) hydrocarbons and HCN

Stable at room temperature. Reaction with water (moisture) produces C02-gas.Exothermic reaction with materials containing active hydrogen groups. The reactionbecomes progressively more vigorous and can be violent at higher temperatures ifthe miscibility of the reaction partners is good or is supported by stirring or by thepresence of solvents. MDI is insoluble with, and heavier than water and sinks to thebottom but reacts slowly at the interface. A solid water-insoluble layer of polyurea isformed at the interface by liberating carbon dioxide gas.

Stability

10.

water, alcohols, amines, bases, and acids

:

:

:

Materials to avoid :

Potential chronic health effects

Toxicological information11.

Diphenylmethane 4,4'diisocyanate

LD50LD50LC50

>5000 mg/kg>5000 mg/kg0.49 mg/l (4 hour/hours)

OralDermalInhalation

RatRabbitRat

Product/ingredient name

Acute toxicity

Test Result Route Species

Other adverse effects Not available.:

Rats have been exposed for two years to a respirable aerosol of polymeric MDIwhich resulted in chronic pulmonary irritation at high concentrations. Only at the toplevel (6 mg/m3), there was a significant incidence of a benign tumour of the lung(adenoma) and one malignant tumour (adenocarcinoma). There were no lungtumours at 1 mg/m3 and no effects at 0.2 mg/m3. Overall, the tumour incidence,both benign and malignant, and the number of animals with the tumours were notdifferent from controls. The increased incidence of lung tumours is associated withprolonged respiratory irritation and the concurrent accumulation of yellow material inthe lung, which occurred throughout the study. In the absence of prolonged exposureto high concentrations leading to chronic irritation and lung damage, it is highlyunlikely that tumour formation will occur.

Carcinogenicity :

There is no substantial evidence of mutagenic potential.Mutagenicity :

No birth defects were seen in two independant animal (rat) studies. Fetotoxicity wasobserved at doses that were extremely toxic (including lethal) to the mother.Fetotoxicity was not observed at doses that were not maternally toxic. The dosesused in these studies were maximal, respirable concentrations, which are well inexcess of defined occupational exposure limits.

Reproductive toxicity :

Potential acute health effects

Inhalation : This product is a respiratory irritant and potential respiratory sensitiser: repeatedinhalation of vapour or aerosol at levels above the occupational exposure limit couldcause respiratory sensitisation. Symptoms may include irritation to the eyes, nose,throat and lungs, possibly combined with dryness of the throat, tightness of chestand difficulty in breathing. The onset of the respiratory symptoms may be delayed forseveral hours after exposure. A hyper-reactive response to even minimalconcentrations of MDI may develop in sensitised persons.

Low oral toxicity. Ingestion may cause irritation of the gastrointestinal tract.:Ingestion

Skin contact : Irritating to skin. May cause sensitisation by skin contact. Animal studies haveshown that respiratory sensitisation can be induced by skin contact with knownrespiratory sensitisers including diisocyanates. These results emphasize the need forprotective clothing including gloves to be worn at all times when handling thesechemicals or in maintenance work.

Irritating to eyes.:Eye contact


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SUPRASEC 1041

Ecological information

Mobility By considering the production and use of the substance, it is unlikely that significantenvironmental exposure in the air or water will arise. Immiscible with water, but willreact with water to produce inert and non-biodegradable solids. Conversion tosoluble products, including diamino- diphenylmethane (MDA), is very low under theoptimal laboratory conditions of good dispersion and low concentration. In air, thepredominant degradation process is predicted to be a relatively rapid OH radicalattack, by calculation and by analogy with related diisocyanates.

12.

:

Diphenylmethane 4,4' diisocyanate Zebra Fish (LC50)Daphnia magna (EC50)

96 hour/hours48 hour/hours

>1000 mg/l>1000 mg/l

Species Period Result

Ecotoxicity data

Ingredient name

Other adverse effects : By comparison with an analogous product, the following values are anticipated. Themeasured ecotoxicity is that of the hydrolised product, generally under conditionsmaximising production of soluble species. Even so, the observed ecotoxicity islow/very low. A pond study showed gross contamination caused no significant toxiceffects on a wide variety of flora in all trophic levels (including fish), no detectablediaminodiphenylmethane (MDA), and no evidence of bioaccumulation of MDI orMDA.

Disposal considerations13.

European waste catalogue(EWC)

:

The classification of the product may meet the criteria for a hazardous waste.Hazardous waste :

The generation of waste should be avoided or minimised wherever possible. Avoiddispersal of spilt material and runoff and contact with soil, waterways, drains andsewers. Disposal of this product, solutions and any by-products should at all timescomply with the requirements of environmental protection and waste disposallegislation and any regional local authority requirements.

:Methods of disposal

The relevant EU Directives and local, regional and national regulations must becomplied with. It is among the tasks of the end user to assign the waste to wastecodes specific to industrial sectors and processes according to the European Wastecatalogue. It is recommended that the details be agreed with the waste disposerresponsible.

ADR/RIDClassification

14.International transport regulations

-

IMO/IMDGClassification

-

ICAO/IATAClassification

Transport information

Regulatoryinformation

UN number

Proper shipping name

Packing group Label Additional information

-

-

-

-

ADR

IATA

IMDG

:

:

:

Not regulated.

Not regulated.

Not regulated.

Not regulated.

Not regulated.

Not regulated.


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SUPRASEC 1041

Regulatory information15.

Safety phrases S23- Do not breathe vapour spray.S36/37- Wear suitable protective clothing and gloves.S38- In case of insufficient ventilation, wear suitable respiratory equipment.S45- In case of accident or if you feel unwell, seek medical advice immediately(show the label where possible).

R20- Harmful by inhalation.R36/37/38- Irritating to eyes, respiratory system and skin.R42/43- May cause sensitisation by inhalation and skin contact.

Hazard symbol(s)

Risk phrases

EU Regulations

Contains

Other EU regulations

:

:

:

:

Additional warningphrases

: Contains isocyanates. See information supplied by the manufacturer. Thisinformation is provided by the current Safety Data Sheet.

Product use Classification and labelling have been performed according to EU Directives67/548/EEC and 1999/45/EC (including amendments) and the intended use.- Industrial applications.

:

Harmful

diphenylmethane-4,4'-diisocyanate

Xn

Other information

History

16.

Date of printing

Date of issue

Version

Notice to reader

1

Date of previous issue

:

:

:

:

R20- Harmful by inhalation.R36/37/38- Irritating to eyes, respiratory system and skin.R42/43- May cause sensitisation by inhalation and skin contact.

:Full text of R-phrasesreferred to in sections 2 and3 - United Kingdom (UK)

Xn - HarmfulXi - Irritant

:Full text of classificationsreferred to in sections 2 and3 - United Kingdom (UK)

While the information and recommendations in this publication are to the best of our knowledge, informationand belief accurate at the date of publication, NOTHING HEREIN IS TO BE CONSTRUED AS A WARRANTY,EXPRESS OR OTHERWISE.

IN ALL CASES, IT IS THE RESPONSIBILITY OF THE USER TO DETERMINE THE APPLICABILITY OF SUCHINFORMATION AND RECOMMENDATIONS AND THE SUITABILITY OF ANY PRODUCT FOR ITS OWNPARTICULAR PURPOSE.

THE PRODUCT MAY PRESENT HAZARDS AND SHOULD BE USED WITH CAUTION. WHILE CERTAIN HAZARDSARE DESCRIBED IN THIS PUBLICATION, NO GUARANTEE IS MADE THAT THESE ARE THE ONLY HAZARDSTHAT EXIST.

Hazards, toxicity and behaviour of the products may differ when used with other materials and are dependentupon the manufacturing circumstances or other processes. Such hazards, toxicity and behaviour should bedetermined by the user and made known to handlers, processors and end users.

28 Dec 2005

28 December 2005No previous validation

SUPRASEC® is a registered trademark of Huntsman LLC or an affiliate thereof in one ormore countries, but not all countries.

Copyright © 2005 Huntsman LLC or an affiliate thereof. All rights reserved.

Enquiries should be addressed to your nearest Huntsman sales office or to:


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SUPRASEC 1041

Huntsman Belgium (BVBA)Everslaan 45B-3078 EverbergBelgiumTel.:+32-(0)2-758-9211


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SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006

METHIC RED 3B LIQUID (C.I. BASIC VIOLET 16)

Version 5.0 Print Date 2013/08/20

Revision date / valid from 2013/08/20 MSDS code: GZC040

R61149 1/13 EN

Section 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Trade name : METHIC RED 3B LIQUID (C.I. BASIC VIOLET 16)

1.2. Relevant identified uses of the substance or mixture and uses advised against

Use of the Substance/Mixture

: paper industry

Uses advised against : At this moment we have not identified any uses advised

against

1.3. Details of the supplier of the safety data sheet

Company : Brenntag Colours Ltd. High level way GB HX1 4PN Halifax

Telephone : +44 (0) 1422 358 431 Telefax : +44 (0) 1422 330 867 E-mail address : [email protected]


Emergency telephone number

: EMERGENCY ONLY TELEPHONE NUMBER: +32 (0) 3 575 55 55 (SGS Emergency response services - 24 hours)

Section 2: Hazards identification

2.1. Classification of the substance or mixture

Classification according to EU Directives 67/548/EEC or 1999/45/EC

Directive 67/548/EEC or 1999/45/EC

Hazard symbol / Category of danger Risk phrases

Corrosive (C)Corrosive (C) R34

Harmful (Xn)Harmful (Xn) R22

Dangerous for the environment R52/53

For the full text of the R-phrases mentioned in this Section, see Section 16.

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R61149 / Version 5.0 2/13 EN

Most important adverse effects

Human Health : See section 11 for toxicological information.

Physical and chemical hazards

: See section 9 for physicochemical information.

Potential environmental effects

: See section 12 for environmental information.

2.2. Label elements

Labelling according to EC Directives 67/548/EEC or 1999/45/EC Hazard symbols:

Corrosive

R-phrase(s) : R22 Harmful if swallowed.

R34 Causes burns. R52/53 Harmful to aquatic organisms, may cause

long-term adverse effects in the aquatic environment.

S-phrase(s) : S26 In case of contact with eyes, rinse

immediately with plenty of water and seek medical advice.

S36/37/39 Wear suitable protective clothing, gloves and eye/face protection.

S45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

S60 This material and its container must be disposed of as hazardous waste.

Hazardous components which must be listed on the label:

• acetic acid • 2-[2-[4-(Diethylamino)phenyl]vinyl]-1,3,3-trimethyl-3H-indolium acetate

2.3. Other hazards

For Results of PBT and vPvB assessment see section 12.5.

Section 3: Composition/information on ingredients

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R61149 / Version 5.0 3/13 EN

3.2. Mixtures

Hazardous components Amount [%]

Classification (REGULATION (EC) No 1272/2008)

Classification (67/548/EEC) Hazard class /

Hazard category

Hazard

statements

acetic acid

Index-No. : 607-002-00-6 CAS-No. : 64-19-7

EC-No. : 200-580-7 C&L-No. : 02-2119752555-33-0000

>= 25 - < 50

Flam. Liq.3 Skin Corr.1A

H226 H314

R10 Corrosive; C; R35

2-[2-[4-(Diethylamino)phenyl]vinyl]-1,3,3-trimethyl-3H-indolium acetate

CAS-No. : 64346-30-1

EC-No. : 264-796-3

>= 10 - < 30

Acute Tox.3 Aquatic Chronic2

H301 H411

Toxic; T; R25 Dangerous for the environment; N; R51/53

For the full text of the R-phrases mentioned in this Section, see Section 16. For the full text of the H-Statements mentioned in this Section, see Section 16.

Section 4: First aid measures

4.1. Description of first aid measures

General advice : Take off all contaminated clothing immediately.

If inhaled : Remove to fresh air. If symptoms persist, call a physician.

In case of skin contact : Take off all contaminated clothing immediately. Wash off immediately with soap and plenty of water. Consult a physician.

In case of eye contact : Rinse immediately with plenty of water, also under the eyelids,

for at least 15 minutes. Consult an eye specialist immediately. Consult a physician.

If swallowed : Do NOT induce vomiting. Clean mouth with water and drink

afterwards plenty of water. Never give anything by mouth to an unconscious person. Call a physician immediately.

4.2. Most important symptoms and effects, both acute and delayed

Symptoms : See Section 11 for more detailed information on health effects and symptoms.

Effects : See Section 11 for more detailed information on health effects and symptoms.

4.3. Indication of any immediate medical attention and special treatment needed

Treatment : Treat symptomatically.

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R61149 / Version 5.0 4/13 EN

Section 5: Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media

: water mist, Foam

Unsuitable extinguishing media

: No information available.

5.2. Special hazards arising from the substance or mixture

Specific hazards during firefighting

: May decompose in a fire giving off toxic fumes

5.3. Advice for firefighters

Special protective equipment for firefighters

: In the event of fire, wear self-contained breathing apparatus.Wear personal protective equipment.

Further information : Collect contaminated fire extinguishing water separately. This must not be discharged into drains.

Section 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Personal precautions : Use personal protective equipment. Avoid contact with skin and eyes.

6.2. Environmental precautions

Environmental precautions

: Do not flush into surface water or sanitary sewer system. Should not be released into the environment.

6.3. Methods and materials for containment and cleaning up

Methods and materials for containment and cleaning up

: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders). Keep in suitable, closed containers for disposal.

Further information : Treat recovered material as described in the section "Disposal

considerations".

6.4. Reference to other sections

See Section 1 for emergency contact information. See Section 8 for information on personal protective equipment. See Section 13 for waste treatment information.

Section 7: Handling and storage

7.1. Precautions for safe handling

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Advice on safe handling : Keep container tightly closed. Avoid contact with skin, eyes and clothing. Emergency eye wash fountains and emergency showers should be available in the immediate vicinity.

Hygiene measures

: Keep away from food, drink and animal feedingstuffs. Smoking, eating and drinking should be prohibited in the application area. Wash hands before breaks and at the end of workday. Take off all contaminated clothing immediately. Provide adequate ventilation. Avoid contact with the skin and the eyes.

7.2. Conditions for safe storage, including any incompatibilities

Requirements for storage areas and containers

: Keep only in the original container. Keep from freezing

Advice on protection against fire and explosion

: Normal measures for preventive fire protection.

Further information on storage conditions

: Keep tightly closed in a dry and cool place. Keep away from heat. Protect from frost. Keep in a well-ventilated place.

Advice on common storage

: Keep away from food, drink and animal feedingstuffs.

7.3. Specific end use(s)

Specific use(s) : No information available.

Section 8: Exposure controls/personal protection

8.1. Control parameters

Component: acetic acid CAS-No.

64-19-7

Other Occupational Exposure Limit Values

EU ELV, Time Weighted Average (TWA): 10 ppm, 25 mg/m3 Indicative ELV (IE), Time Weighted Average (TWA): 10 ppm, 25 mg/m3 Indicative OELV

8.2. Exposure controls

Appropriate engineering controls Ensure adequate ventilation.

Personal protective equipment

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Respiratory protection

Advice : If ventilation is insufficient, suitable respiratory protection must be provided

Hand protection Advice : Wear impervious chemical resistant protective gloves.

Please observe the instructions regarding permeability and breakthrough time which are provided by the supplier of the gloves. Also take into consideration the specific local conditions under which the product is used, such as the danger of cuts, abrasion, and the contact time. Protective gloves should be replaced at first signs of wear.

Material : PVC

Material : Nitrile rubber

Eye protection

Advice : Tightly fitting safety goggles

Skin and body protection

Advice : Protective work clothing

Environmental exposure controls

General advice : Do not flush into surface water or sanitary sewer system. Should not be released into the environment.

Section 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Form : liquid

Colour : dark violet

Odour : no data available

Odour Threshold : no data available

pH : 2.5 - 4.5

Freezing point : no data available

Boiling point : no data available

Flash point : > 100 °C Evaporation rate : no data available

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Flammability (solid, gas) : no data available

Upper explosion limit : no data available

Lower explosion limit : no data available

Vapour pressure : no data available

Relative vapour density : no data available

Density : ca. 1.08 g/cm3

Solubility/qualitative : no data available

Partition coefficient: n-octanol/water : no data available

Auto-ignition temperature : no data available

Thermal decomposition : no data available

Viscosity, dynamic : < 100 mPa.s (25 °C)

Explosivity : no data available

Oxidizing properties : no data available

9.2. Other information

No further information available.

Section 10: Stability and reactivity

10.1. Reactivity

Advice : No information available.

10.2. Chemical stability

Advice : Stable under normal conditions.


Hazardous reactions : Note : no data available

10.4. Conditions to avoid

Conditions to avoid : no data available

10.5. Incompatible materials

Materials to avoid : Oxidizing agents

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10.6. Hazardous decomposition products

Hazardous decomposition products

: May decompose in a fire giving off toxic fumes

Section 11: Toxicological information

11.1. Information on toxicological effects

Acute toxicity

Oral

Harmful if swallowed., May cause burns to mouth, throat and

stomach.

Inhalation

There may be irritation of the throat with a feeling of tightness in

the chest.

Dermal

Causes skin burns.

Irritation

Skin

Result : Causes burns.

Eyes

Result : Causes burns.

Sensitisation

Result : no data available

CMR effects

CMR Properties

Carcinogenicity

: no data available

Mutagenicity

: no data available

Reproductive toxicity

: no data available

Specific Target Organ Toxicity

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Single exposure

no data available

Repeated exposure

no data available

Other toxic properties

Repeated dose toxicity

no data available

Aspiration hazard

no data available

Further information

Other relevant toxicity information

: Handle in accordance with good industrial hygiene and safety practice.


64-19-7

Acute toxicity

Oral

LD50 Oral : 3310 mg/kg (rat)

Inhalation

LC50 : > 40 mg/l (rat; 4 h)

Dermal

Study scientifically not justified.

Irritation

Skin

Result : corrosive effects (rabbit) (OECD Test Guideline 404)

Eyes

Result : corrosive effects (rabbit) (OECD Test Guideline 405)

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May cause corneal damage. Risk of serious damage to eyes.

Section 12: Ecological information

12.1. Toxicity

Acute toxicity

Fish

no data available


64-19-7

Acute toxicity

Fish

LC50

: > 300.82 mg/l (Oncorhynchus mykiss (rainbow trout); 96 h) (OECD 203)

Toxicity to daphnia and other aquatic invertebrates

EC50

: > 300.82 mg/l (Daphnia magna (Water flea); 48 h) (OECD Test Guideline 202)

algae

EC50

: > 300.82 mg/l (Skeletonema costatum; 72 h)

Bacteria

EC3

: 850 mg/l (Pseudomonas putida; 16 h)

12.2. Persistence and degradability

Persistence and degradability

Biodegradability

Result

: no data available

12.3. Bioaccumulative potential

Bioaccumulation

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Result

: no data available

12.4. Mobility in soil

Mobility

Result

: no data available

12.5. Results of PBT and vPvB assessment

Results of PBT and vPvB assessment

Result

: no data available

12.6. Other adverse effects

Additional ecological information

Result

: Do not flush into surface water or sanitary sewer system. Avoid subsoil penetration. Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

Section 13: Disposal considerations

13.1. Waste treatment methods

Product

: Disposal together with normal waste is not allowed. Special disposal required according to local regulations. Do not let product enter drains. Contact waste disposal services.

Contaminated packaging

: Empty contaminated packagings thoroughly. They can be recycled after thorough and proper cleaning. Packagings that cannot be cleaned are to be disposed of in the same manner as the product.

European Waste Catalogue Number

: No waste code according to the European Waste Catalogue can be assigned for this product, as the intended use dictates the assignment. The waste code is established in consultation with the regional waste disposer.

Section 14: Transport information

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14.1. UN number

2801

14.2. UN proper shipping name

ADR : DYE, LIQUID, CORROSIVE, N.O.S. (Acetic acid) RID : DYE, LIQUID, CORROSIVE, N.O.S. (Acetic acid) IMDG : DYE, LIQUID, CORROSIVE, N.O.S. (Acetic acid)

14.3. Transport hazard class(es)

ADR-Class (Labels; Classification Code; Hazard identification No; Tunnel restriction code)

: 8

8; C9; 80; (E)

RID-Class (Labels; Classification Code; Hazard identification No)

: 8

8; C9; 80

IMDG-Class (Labels; EmS)

: 8

8; F-A, S-B

14.4. Packaging group

ADR : III RID : III IMDG : III

14.5. Environmental hazards

Labeling according to 5.2.1.8 ADR : no Labeling according to 5.2.1.8 RID : no Labeling according to 5.2.1.6.3 IMDG : no Classification as environmentally hazardous according to 2.9.3 IMDG

: no

14.6. Special precautions for user

Not applicable.

14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code

IMDG : Not applicable.

Section 15: Regulatory information

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15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

15.2. Chemical Safety Assessment

The chemical safety assessment will be performed at a later time.

Section 16: Other information

Full text of R-phrases referred to under sections 2 and 3.

R10 Flammable. R22 Harmful if swallowed. R25 Toxic if swallowed. R34 Causes burns. R35 Causes severe burns.

R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

Full text of H-Statements referred to under sections 2 and 3.

H226 Flammable liquid and vapour. H301 Toxic if swallowed. H314 Causes severe skin burns and eye damage. H411 Toxic to aquatic life with long lasting effects.

Further information

Training advice : Provide adequate information, instruction and training for operators.

Other information : The information provided in this Safety Data Sheet is correct to

our knowledge at the date of its revision. The information given only describes the products with regard to safety arrangements and is not to be considered as a warranty or quality specification and does not constitute a legal relationship. The information contained in this Safety Data Sheet relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process, unless specified in the text

|| Indicates updated section.

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attachment i.4 baseline report (part 1) · ingredients includes sodium bisulphite h302 harmful if...

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