attachment 6 january 8, 2014 soil sample data (ikon solutions) · ces environmental services...

CES Environmental Services Voluntary Cleanup Program Application

Project No. 4006 May 2015

Attachment 6 January 8, 2014 Soil Sample Data (IKON Solutions)

01/30/14

Technical Report for

IKON Environmental Solutions

CES Environmental / 4904 Griggs Houston TX

Accutest Job Number: TC42161

Sampling Date: 01/08/14

Report to:

IKON Environmental Solutions

[email protected]@ikonenviro.comATTN: Greg Blomquist

Total number of pages in report:

Certifications: TX (T104704220-13-12) AR (13-019-0) AZ (AZ0769) FL (E87628) KS (E-10366)

LA (85695/04004) OK (2013-142) VA (2085)

This report shall not be reproduced, except in its entirety, without the written approval of Accutest Laboratories.

Test results relate only to samples analyzed.

Gulf Coast • 10165 Harwin Drive • Suite 150 • Houston, TX 77036 • tel: 713-271-4700 • fax: 713-271-4770 • http://www.accutest.com

Test results contained within this data package meet the requirements

of the National Environmental Laboratory Accreditation Program

and/or state specific certification programs as applicable.

Client Service contact: Electa Brown 713-271-4700

Richard RodriguezLaboratory Director

Gulf Coast

01/30/14

e-Hardcopy 2.0Automated Report

76

Accutest Laboratories is the sole authority for authorizing edits or modifications to thisdocument. Unauthorized modification of this report is strictly prohibited.

1 of 76TC42161

Table of Contents-1-

Sections:

Section 1: Sample Summary ................................................................................................... 3Section 2: Case Narrative/Conformance Summary .............................................................. 4Section 3: Summary of Hits .................................................................................................... 6Section 4: Sample Results ........................................................................................................ 8

4.1: TC42161-1: N.TANKS #1 0-1' ..................................................................................... 94.2: TC42161-2: N.TANKS #2 0-1' ..................................................................................... 164.3: TC42161-3: S.TANKS #1 0-1' ...................................................................................... 234.4: TC42161-4: S.TANKS #2 0-1' ...................................................................................... 30

Section 5: Misc. Forms ............................................................................................................ 375.1: Chain of Custody ........................................................................................................... 385.2: LRC Form ...................................................................................................................... 41

Section 6: GC/MS Volatiles - QC Data Summaries .............................................................. 456.1: Method Blank Summary ................................................................................................ 466.2: Blank Spike Summary ................................................................................................... 496.3: Matrix Spike/Matrix Spike Duplicate Summary ........................................................... 52

Section 7: GC/MS Semi-volatiles - QC Data Summaries ..................................................... 557.1: Method Blank Summary ................................................................................................ 567.2: Blank Spike Summary ................................................................................................... 597.3: Matrix Spike/Matrix Spike Duplicate Summary ........................................................... 62

Section 8: Metals Analysis - QC Data Summaries ................................................................ 658.1: Prep QC MP22462: Hg .................................................................................................. 668.2: Prep QC MP22463: As,Ba,Cd,Cr,Pb,Se,Ag .................................................................. 708.3: Metals CCB MDL Check ............................................................................................... 76

12

34

56

78

2 of 76TC42161

Accutest Laboratories

Sample Summary

IKON Environmental SolutionsJob No: TC42161

CES Environmental / 4904 Griggs Houston TX

Sample Collected Matrix Client Number Date Time By Received Code Type Sample ID

TC42161-1 01/08/14 09:30 01/09/14 SO Soil N.TANKS #1 0-1'

TC42161-2 01/08/14 11:50 01/09/14 SO Soil N.TANKS #2 0-1'

TC42161-3 01/08/14 10:40 01/09/14 SO Soil S.TANKS #1 0-1'

TC42161-4 01/08/14 11:00 01/09/14 SO Soil S.TANKS #2 0-1'

TC42161-5 01/08/14 09:30 01/09/14 SO Soil N.TANKS #1 3-4'

TC42161-6 01/08/14 11:50 01/09/14 SO Soil N.TANKS #2 3-4'

TC42161-7 01/08/14 10:45 01/09/14 SO Soil S.TANKS #1 3-4'

TC42161-8 01/08/14 11:10 01/09/14 SO Soil S.TANKS #2 3-4'

Soil samples reported on a dry weight basis unless otherwise indicated on result page.

3 of 76TC42161

1

4 Samples were collected on 01/08/2014 and received intact at Accutest on 01/09/2014 and properly preserved in 1 cooler at 2.2 Deg C. These Samples received an Accutest job number of TC42161. A listing of the Laboratory Sample ID, Client Sample ID and dates of collection are presented in the Results Summary Section of this report.

Except as noted below, all method specified calibrations and quality control performance criteria were met for this job. For more information, please refer to QC summary pages.

Client: IKON Environmental Solutions

Site: CES Environmental / 4904 Griggs Houston TX

Job No TC42161

Report Date 1/20/2014 2:12:30 PM

SAMPLE DELIVERY GROUP CASE NARRATIVE

Volatiles by GCMS By Method SW846 8260CMatrix SO Batch ID: VY3521

All samples were analyzed within the recommended method holding time.

All method blanks for this batch meet method specific criteria.

Sample(s) TC42188-1MS, TC42188-1MSD were used as the QC samples indicated.

Matrix Spike Duplicate Recovery(s) for Methyl bromide are outside control limits. Probable cause due to matrix interference.

TC42161-1, TC42161-2, TC42161-3, TC42161-4 for Hexachlorobutadiene, Dichlorodifluoromethane: CCV recovery was above method acceptance criteria. This target analyte was not detected in the sample.

Extractables by GCMS By Method SW846 8270DMatrix SO Batch ID: OP31117

All samples were extracted within the recommended method holding time.


Sample(s) TC42188-1MS, TC42188-1MSD were used as the QC samples indicated.


Matrix Spike Recovery(s) for 2,4-Dinitrophenol, 4,6-Dinitro-o-cresol, Pentachlorophenol are outside control limits. Probable cause due to matrix interference.

Matrix Spike Duplicate Recovery(s) for 2,4-Dinitrophenol, 4,6-Dinitro-o-cresol, Pentachlorophenol are outside control limits. Probable cause due to matrix interference.

Metals By Method SW846 6010BMatrix SO Batch ID: MP22463

All samples were digested within the recommended method holding time.



Sample(s) TC42161-1MS, TC42161-1MSD, TC42161-1SDL were used as the QC samples for metals.

Matrix Spike Duplicate Recovery(s) for Lead are outside control limits. Probable cause due to matrix interference.

Matrix Spike/Matrix Spike Duplicate Recovery(s) for Barium are outside control limits. Spike amount low relative to the sample amount. Refer to lab control or spike blank for recovery information.

RPD(s) for Serial Dilution for Arsenic, Barium, Chromium are outside control limits for sample MP22463-SD1. Serial dilution indicates possible matrix interference.

TC42161-1 for Selenium: Elevated reporting limit due to dilution required for matrix interference.

TC42161-3 for Cadmium, Selenium: Elevated reporting limit due to dilution required for high interfering element.

Monday, January 20, 2014 Page 1 of 2

4 of 76TC42161

2

Metals By Method SW846 7471AMatrix SO Batch ID: MP22462

All samples were digested within the recommended method holding time.



Sample(s) TC42161-1MS, TC42161-1MSD were used as the QC samples for metals.

Wet Chemistry By Method SM 2540 GMatrix SO Batch ID: GN55774

Sample(s) TC42161-1DUP were used as the QC samples for Solids, Percent.

Accutest Laboratories Gulf Coast (ALGC) certifies that this report meets the project requirements for analytical data produced for the samples as received at ALGC and as stated on the COC. ALGC certifies that the data meets the Data QualityObjectives for precision, accuracy and completeness as specified in the ALGC Quality Manual except as noted above. This report is to be used in its entirety. ALGC is not responsible for any assumptions of data quality if partial data packages are used

Monday, January 20, 2014 Page 2 of 2

5 of 76TC42161

2

Summary of Hits Page 1 of 2 Job Number: TC42161Account: IKON Environmental SolutionsProject: CES Environmental / 4904 Griggs Houston TXCollected: 01/08/14

Lab Sample ID Client Sample ID Result/Analyte Qual MQL SDL Units Method

TC42161-1 N.TANKS #1 0-1'

Acetone 84.7 49 12 ug/kg SW846 8260CCarbon disulfide 0.83 J 4.9 0.72 ug/kg SW846 8260CMethyl ethyl ketone 13.6 J 49 6.2 ug/kg SW846 8260CArsenic 8.4 1.6 0.55 mg/kg SW846 6010BBarium 783 13 0.089 mg/kg SW846 6010BCadmium 0.14 J 0.26 0.018 mg/kg SW846 6010BChromium 24.5 0.65 0.030 mg/kg SW846 6010BLead 58.7 0.20 0.065 mg/kg SW846 6010BMercury 0.063 0.039 0.016 mg/kg SW846 7471A

TC42161-2 N.TANKS #2 0-1'

Acetone 13.6 J 51 13 ug/kg SW846 8260CArsenic 4.7 1.7 0.57 mg/kg SW846 6010BBarium 166 14 0.093 mg/kg SW846 6010BCadmium 0.039 J 0.27 0.019 mg/kg SW846 6010BChromium 27.7 0.68 0.031 mg/kg SW846 6010BLead 14.5 0.20 0.068 mg/kg SW846 6010B

TC42161-3 S.TANKS #1 0-1'

Acetone 68.4 44 11 ug/kg SW846 8260CCarbon disulfide 1.8 J 4.4 0.64 ug/kg SW846 8260CMethyl ethyl ketone 12.6 J 44 5.5 ug/kg SW846 8260C1,2,4-Trimethylbenzene 0.49 J 4.4 0.44 ug/kg SW846 8260Cbis(2-Ethylhexyl)phthalate 110 J 190 93 ug/kg SW846 8270DArsenic 4.9 1.4 0.48 mg/kg SW846 6010BBarium 5550 57 0.39 mg/kg SW846 6010BCadmium a 0.86 J 1.1 0.080 mg/kg SW846 6010BChromium 55.3 0.57 0.026 mg/kg SW846 6010BLead 124 0.85 0.28 mg/kg SW846 6010BMercury 0.61 0.037 0.015 mg/kg SW846 7471ASilver 0.068 J 0.57 0.066 mg/kg SW846 6010B

TC42161-4 S.TANKS #2 0-1'

Acetone 105 43 11 ug/kg SW846 8260CBenzene 16.1 4.3 0.72 ug/kg SW846 8260CCarbon disulfide 1.1 J 4.3 0.62 ug/kg SW846 8260CEthylbenzene 1.1 J 4.3 1.0 ug/kg SW846 8260CMethyl ethyl ketone 15.2 J 43 5.3 ug/kg SW846 8260CMethyl Tert Butyl Ether 21.5 4.3 0.54 ug/kg SW846 8260C1,2,4-Trimethylbenzene 0.82 J 4.3 0.43 ug/kg SW846 8260C

6 of 76TC42161

3

Summary of Hits Page 2 of 2 Job Number: TC42161Account: IKON Environmental SolutionsProject: CES Environmental / 4904 Griggs Houston TXCollected: 01/08/14

Lab Sample ID Client Sample ID Result/Analyte Qual MQL SDL Units Method

Arsenic 3.6 0.30 0.10 mg/kg SW846 6010BBarium 417 12 0.083 mg/kg SW846 6010BCadmium 0.42 0.24 0.017 mg/kg SW846 6010BChromium 27.5 0.61 0.028 mg/kg SW846 6010BLead 37.0 0.18 0.061 mg/kg SW846 6010BMercury 0.19 0.037 0.015 mg/kg SW846 7471A

(a) Elevated reporting limit due to dilution required for high interfering element.

7 of 76TC42161

3


Sample Results

Report of Analysis

Gulf Coast

Section 4

8 of 76TC42161

4


Report of Analysis Page 1 of 3

Client Sample ID: N.TANKS #1 0-1' Lab Sample ID: TC42161-1 Date Sampled: 01/08/14 Matrix: SO - Soil Date Received: 01/09/14 Method: SW846 8260C Percent Solids: 80.0 Project: CES Environmental / 4904 Griggs Houston TX

File ID DF Analyzed By Prep Date Prep Batch Analytical BatchRun #1 Y0065390.D 1 01/10/14 FI n/a n/a VY3521Run #2

Initial Weight Final VolumeRun #1 5.06 g 5.0 mlRun #2

VOA 8260 List

CAS No. Compound Result MQL SDL Units Q

67-64-1 Acetone 84.7 49 12 ug/kg71-43-2 Benzene 0.83 U 4.9 0.83 ug/kg108-86-1 Bromobenzene 0.50 U 4.9 0.50 ug/kg74-97-5 Bromochloromethane 1.3 U 4.9 1.3 ug/kg75-27-4 Bromodichloromethane 0.55 U 4.9 0.55 ug/kg75-25-2 Bromoform 0.93 U 4.9 0.93 ug/kg104-51-8 n-Butylbenzene 0.54 U 4.9 0.54 ug/kg135-98-8 sec-Butylbenzene 1.1 U 4.9 1.1 ug/kg98-06-6 tert-Butylbenzene 0.96 U 4.9 0.96 ug/kg108-90-7 Chlorobenzene 1.2 U 4.9 1.2 ug/kg75-00-3 Chloroethane 1.9 U 4.9 1.9 ug/kg67-66-3 Chloroform 0.53 U 4.9 0.53 ug/kg95-49-8 o-Chlorotoluene 0.59 U 4.9 0.59 ug/kg106-43-4 p-Chlorotoluene 0.51 U 4.9 0.51 ug/kg75-15-0 Carbon disulfide 0.83 4.9 0.72 ug/kg J56-23-5 Carbon tetrachloride 1.1 U 4.9 1.1 ug/kg75-34-3 1,1-Dichloroethane 0.51 U 4.9 0.51 ug/kg75-35-4 1,1-Dichloroethylene 0.52 U 4.9 0.52 ug/kg563-58-6 1,1-Dichloropropene 0.55 U 4.9 0.55 ug/kg96-12-8 1,2-Dibromo-3-chloropropane 3.9 U 4.9 3.9 ug/kg106-93-4 1,2-Dibromoethane 0.52 U 4.9 0.52 ug/kg107-06-2 1,2-Dichloroethane 0.59 U 4.9 0.59 ug/kg78-87-5 1,2-Dichloropropane 0.72 U 4.9 0.72 ug/kg142-28-9 1,3-Dichloropropane 1.3 U 4.9 1.3 ug/kg594-20-7 2,2-Dichloropropane 0.67 U 4.9 0.67 ug/kg124-48-1 Dibromochloromethane 1.1 U 4.9 1.1 ug/kg75-71-8 Dichlorodifluoromethane a 1.4 U 4.9 1.4 ug/kg156-59-2 cis-1,2-Dichloroethylene 0.56 U 4.9 0.56 ug/kg10061-01-5 cis-1,3-Dichloropropene 0.56 U 4.9 0.56 ug/kg541-73-1 m-Dichlorobenzene 0.77 U 4.9 0.77 ug/kg95-50-1 o-Dichlorobenzene 1.2 U 4.9 1.2 ug/kg106-46-7 p-Dichlorobenzene 1.1 U 4.9 1.1 ug/kg

U = Not detected SDL - Sample Detection Limit J = Indicates an estimated valueMQL = Method Quantitation Limit B = Indicates analyte found in associated method blankE = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound

9 of 76TC42161

44.1




VOA 8260 List


156-60-5 trans-1,2-Dichloroethylene 0.54 U 4.9 0.54 ug/kg10061-02-6 trans-1,3-Dichloropropene 0.63 U 4.9 0.63 ug/kg100-41-4 Ethylbenzene 1.2 U 4.9 1.2 ug/kg591-78-6 2-Hexanone 9.1 U 49 9.1 ug/kg87-68-3 Hexachlorobutadiene a 0.85 U 4.9 0.85 ug/kg98-82-8 Isopropylbenzene 1.4 U 4.9 1.4 ug/kg99-87-6 p-Isopropyltoluene 0.45 U 4.9 0.45 ug/kg108-10-1 4-Methyl-2-pentanone 7.8 U 49 7.8 ug/kg74-83-9 Methyl bromide 2.3 U 4.9 2.3 ug/kg74-87-3 Methyl chloride 0.95 U 4.9 0.95 ug/kg74-95-3 Methylene bromide 0.80 U 4.9 0.80 ug/kg75-09-2 Methylene chloride 3.1 U 12 3.1 ug/kg78-93-3 Methyl ethyl ketone 13.6 49 6.2 ug/kg J1634-04-4 Methyl Tert Butyl Ether 0.63 U 4.9 0.63 ug/kg91-20-3 Naphthalene 2.5 U 4.9 2.5 ug/kg103-65-1 n-Propylbenzene 1.3 U 4.9 1.3 ug/kg100-42-5 Styrene 1.1 U 4.9 1.1 ug/kg630-20-6 1,1,1,2-Tetrachloroethane 0.62 U 4.9 0.62 ug/kg71-55-6 1,1,1-Trichloroethane 0.78 U 4.9 0.78 ug/kg79-34-5 1,1,2,2-Tetrachloroethane 0.83 U 4.9 0.83 ug/kg79-00-5 1,1,2-Trichloroethane 0.83 U 4.9 0.83 ug/kg87-61-6 1,2,3-Trichlorobenzene 0.65 U 4.9 0.65 ug/kg96-18-4 1,2,3-Trichloropropane 1.1 U 4.9 1.1 ug/kg120-82-1 1,2,4-Trichlorobenzene 0.61 U 4.9 0.61 ug/kg95-63-6 1,2,4-Trimethylbenzene 0.50 U 4.9 0.50 ug/kg108-67-8 1,3,5-Trimethylbenzene 1.2 U 4.9 1.2 ug/kg127-18-4 Tetrachloroethylene 1.2 U 4.9 1.2 ug/kg108-88-3 Toluene 1.3 U 4.9 1.3 ug/kg79-01-6 Trichloroethylene 0.58 U 4.9 0.58 ug/kg75-69-4 Trichlorofluoromethane 0.77 U 4.9 0.77 ug/kg75-01-4 Vinyl chloride 0.72 U 4.9 0.72 ug/kg1330-20-7 Xylene (total) 3.5 U 15 3.5 ug/kg

m,p-Xylene 2.2 U 9.9 2.2 ug/kg95-47-6 o-Xylene 1.2 U 4.9 1.2 ug/kg

CAS No. Surrogate Recoveries Run# 1 Run# 2 Limits

1868-53-7 Dibromofluoromethane 88% 59-126%2037-26-5 Toluene-D8 106% 70-139%460-00-4 4-Bromofluorobenzene 110% 63-138%


10 of 76TC42161

44.1




VOA 8260 List


17060-07-0 1,2-Dichloroethane-D4 83% 54-123%

(a) CCV recovery was above method acceptance criteria. This target analyte was not detected in the sample.


11 of 76TC42161

44.1



Client Sample ID: N.TANKS #1 0-1' Lab Sample ID: TC42161-1 Date Sampled: 01/08/14 Matrix: SO - Soil Date Received: 01/09/14 Method: SW846 8270D SW846 3550B Percent Solids: 80.0 Project: CES Environmental / 4904 Griggs Houston TX

File ID DF Analyzed By Prep Date Prep Batch Analytical BatchRun #1 W18767.D 1 01/13/14 GJ 01/13/14 OP31117 EW982Run #2


ABN Full List


65-85-0 Benzoic acid 330 U 1000 330 ug/kg95-57-8 2-Chlorophenol 93 U 210 93 ug/kg59-50-7 4-Chloro-3-methyl phenol 180 U 210 180 ug/kg120-83-2 2,4-Dichlorophenol 110 U 210 110 ug/kg105-67-9 2,4-Dimethylphenol 89 U 210 89 ug/kg51-28-5 2,4-Dinitrophenol 330 U 1000 330 ug/kg534-52-1 4,6-Dinitro-o-cresol 44 U 420 44 ug/kg95-48-7 2-Methylphenol 81 U 210 81 ug/kg

3&4-Methylphenol 74 U 210 74 ug/kg88-75-5 2-Nitrophenol 100 U 210 100 ug/kg100-02-7 4-Nitrophenol 290 U 1000 290 ug/kg87-86-5 Pentachlorophenol 420 U 1000 420 ug/kg108-95-2 Phenol 110 U 210 110 ug/kg95-95-4 2,4,5-Trichlorophenol 100 U 210 100 ug/kg88-06-2 2,4,6-Trichlorophenol 100 U 210 100 ug/kg83-32-9 Acenaphthene 110 U 210 110 ug/kg208-96-8 Acenaphthylene 110 U 210 110 ug/kg62-53-3 Aniline 61 U 1000 61 ug/kg120-12-7 Anthracene 100 U 210 100 ug/kg92-87-5 Benzidine 4000 U 8300 4000 ug/kg56-55-3 Benzo(a)anthracene 100 U 210 100 ug/kg50-32-8 Benzo(a)pyrene 100 U 210 100 ug/kg205-99-2 Benzo(b)fluoranthene 110 U 210 110 ug/kg191-24-2 Benzo(g,h,i)perylene 94 U 210 94 ug/kg207-08-9 Benzo(k)fluoranthene 100 U 210 100 ug/kg101-55-3 4-Bromophenyl phenyl ether 87 U 210 87 ug/kg85-68-7 Butyl benzyl phthalate 42 U 210 42 ug/kg100-51-6 Benzyl Alcohol 84 U 210 84 ug/kg91-58-7 2-Chloronaphthalene 120 U 210 120 ug/kg106-47-8 4-Chloroaniline 96 U 210 96 ug/kg86-74-8 Carbazole 110 U 210 110 ug/kg218-01-9 Chrysene 110 U 210 110 ug/kg


12 of 76TC42161

44.1




ABN Full List


111-91-1 bis(2-Chloroethoxy)methane 87 U 210 87 ug/kg111-44-4 bis(2-Chloroethyl)ether 85 U 210 85 ug/kg108-60-1 bis(2-Chloroisopropyl)ether 85 U 210 85 ug/kg7005-72-3 4-Chlorophenyl phenyl ether 44 U 210 44 ug/kg95-50-1 1,2-Dichlorobenzene 84 U 210 84 ug/kg122-66-7 1,2-Diphenylhydrazine 92 U 210 92 ug/kg541-73-1 1,3-Dichlorobenzene 87 U 210 87 ug/kg106-46-7 1,4-Dichlorobenzene 85 U 210 85 ug/kg121-14-2 2,4-Dinitrotoluene 100 U 210 100 ug/kg606-20-2 2,6-Dinitrotoluene 110 U 210 110 ug/kg91-94-1 3,3'-Dichlorobenzidine 110 U 420 110 ug/kg53-70-3 Dibenzo(a,h)anthracene 97 U 210 97 ug/kg132-64-9 Dibenzofuran 100 U 210 100 ug/kg84-74-2 Di-n-butyl phthalate 110 U 210 110 ug/kg117-84-0 Di-n-octyl phthalate 42 U 210 42 ug/kg84-66-2 Diethyl phthalate 110 U 210 110 ug/kg131-11-3 Dimethyl phthalate 83 U 210 83 ug/kg117-81-7 bis(2-Ethylhexyl)phthalate 100 U 210 100 ug/kg206-44-0 Fluoranthene 100 U 210 100 ug/kg86-73-7 Fluorene 110 U 210 110 ug/kg118-74-1 Hexachlorobenzene 89 U 210 89 ug/kg87-68-3 Hexachlorobutadiene 81 U 210 81 ug/kg77-47-4 Hexachlorocyclopentadiene 97 U 1000 97 ug/kg67-72-1 Hexachloroethane 81 U 210 81 ug/kg193-39-5 Indeno(1,2,3-cd)pyrene 92 U 210 92 ug/kg78-59-1 Isophorone 89 U 210 89 ug/kg90-12-0 1-Methylnaphthalene 100 U 210 100 ug/kg91-57-6 2-Methylnaphthalene 99 U 210 99 ug/kg88-74-4 2-Nitroaniline 100 U 210 100 ug/kg99-09-2 3-Nitroaniline 100 U 210 100 ug/kg100-01-6 4-Nitroaniline 110 U 420 110 ug/kg91-20-3 Naphthalene 94 U 210 94 ug/kg98-95-3 Nitrobenzene 81 U 210 81 ug/kg62-75-9 n-Nitrosodimethylamine 76 U 210 76 ug/kg621-64-7 N-Nitroso-di-n-propylamine 74 U 210 74 ug/kg86-30-6 N-Nitrosodiphenylamine 42 U 210 42 ug/kg85-01-8 Phenanthrene 110 U 210 110 ug/kg129-00-0 Pyrene 110 U 210 110 ug/kg110-86-1 Pyridine 120 U 210 120 ug/kg120-82-1 1,2,4-Trichlorobenzene 92 U 210 92 ug/kg


13 of 76TC42161

44.1




ABN Full List


367-12-4 2-Fluorophenol 55% 26-124%4165-62-2 Phenol-d5 62% 19-106%118-79-6 2,4,6-Tribromophenol 62% 18-129%4165-60-0 Nitrobenzene-d5 52% 18-104%321-60-8 2-Fluorobiphenyl 58% 21-114%1718-51-0 Terphenyl-d14 74% 24-149%


14 of 76TC42161

44.1



Client Sample ID: N.TANKS #1 0-1' Lab Sample ID: TC42161-1 Date Sampled: 01/08/14 Matrix: SO - Soil Date Received: 01/09/14

Percent Solids: 80.0 Project: CES Environmental / 4904 Griggs Houston TX

Metals Analysis

Analyte Result MQL SDL Units DF Prep Analyzed By Method Prep Method

Arsenic 8.4 1.6 0.55 mg/kg 5 01/10/14 01/13/14 EG SW846 6010B 2 SW846 3050B 4

Barium 783 13 0.089 mg/kg 1 01/10/14 01/13/14 EG SW846 6010B 2 SW846 3050B 4

Cadmium 0.14 J 0.26 0.018 mg/kg 1 01/10/14 01/13/14 EG SW846 6010B 2 SW846 3050B 4

Chromium 24.5 0.65 0.030 mg/kg 1 01/10/14 01/13/14 EG SW846 6010B 2 SW846 3050B 4

Lead 58.7 0.20 0.065 mg/kg 1 01/10/14 01/13/14 EG SW846 6010B 2 SW846 3050B 4

Mercury 0.063 0.039 0.016 mg/kg 1 01/10/14 01/10/14 NS SW846 7471A 1 SW846 7471A 3

Selenium a 0.93 U 1.6 0.93 mg/kg 5 01/10/14 01/13/14 EG SW846 6010B 2 SW846 3050B 4

Silver 0.076 U 0.65 0.076 mg/kg 1 01/10/14 01/13/14 EG SW846 6010B 2 SW846 3050B 4

(1) Instrument QC Batch: MA9177(2) Instrument QC Batch: MA9187(3) Prep QC Batch: MP22462(4) Prep QC Batch: MP22463

(a) Elevated reporting limit due to dilution required for matrix interference.

MQL = Method Quantitation Limit U = Indicates a result < SDLSDL = Sample Detection Limit J = Indicates a result >= SDL but < MQL

15 of 76TC42161

44.1






VOA 8260 List


67-64-1 Acetone 13.6 51 13 ug/kg J71-43-2 Benzene 0.86 U 5.1 0.86 ug/kg108-86-1 Bromobenzene 0.51 U 5.1 0.51 ug/kg74-97-5 Bromochloromethane 1.4 U 5.1 1.4 ug/kg75-27-4 Bromodichloromethane 0.57 U 5.1 0.57 ug/kg75-25-2 Bromoform 0.96 U 5.1 0.96 ug/kg104-51-8 n-Butylbenzene 0.56 U 5.1 0.56 ug/kg135-98-8 sec-Butylbenzene 1.1 U 5.1 1.1 ug/kg98-06-6 tert-Butylbenzene 0.99 U 5.1 0.99 ug/kg108-90-7 Chlorobenzene 1.2 U 5.1 1.2 ug/kg75-00-3 Chloroethane 2.0 U 5.1 2.0 ug/kg67-66-3 Chloroform 0.55 U 5.1 0.55 ug/kg95-49-8 o-Chlorotoluene 0.60 U 5.1 0.60 ug/kg106-43-4 p-Chlorotoluene 0.52 U 5.1 0.52 ug/kg75-15-0 Carbon disulfide 0.74 U 5.1 0.74 ug/kg56-23-5 Carbon tetrachloride 1.1 U 5.1 1.1 ug/kg75-34-3 1,1-Dichloroethane 0.52 U 5.1 0.52 ug/kg75-35-4 1,1-Dichloroethylene 0.53 U 5.1 0.53 ug/kg563-58-6 1,1-Dichloropropene 0.57 U 5.1 0.57 ug/kg96-12-8 1,2-Dibromo-3-chloropropane 4.0 U 5.1 4.0 ug/kg106-93-4 1,2-Dibromoethane 0.54 U 5.1 0.54 ug/kg107-06-2 1,2-Dichloroethane 0.60 U 5.1 0.60 ug/kg78-87-5 1,2-Dichloropropane 0.74 U 5.1 0.74 ug/kg142-28-9 1,3-Dichloropropane 1.3 U 5.1 1.3 ug/kg594-20-7 2,2-Dichloropropane 0.68 U 5.1 0.68 ug/kg124-48-1 Dibromochloromethane 1.2 U 5.1 1.2 ug/kg75-71-8 Dichlorodifluoromethane a 1.4 U 5.1 1.4 ug/kg156-59-2 cis-1,2-Dichloroethylene 0.58 U 5.1 0.58 ug/kg10061-01-5 cis-1,3-Dichloropropene 0.57 U 5.1 0.57 ug/kg541-73-1 m-Dichlorobenzene 0.79 U 5.1 0.79 ug/kg95-50-1 o-Dichlorobenzene 1.2 U 5.1 1.2 ug/kg106-46-7 p-Dichlorobenzene 1.1 U 5.1 1.1 ug/kg


16 of 76TC42161

44.2




VOA 8260 List


156-60-5 trans-1,2-Dichloroethylene 0.55 U 5.1 0.55 ug/kg10061-02-6 trans-1,3-Dichloropropene 0.65 U 5.1 0.65 ug/kg100-41-4 Ethylbenzene 1.2 U 5.1 1.2 ug/kg591-78-6 2-Hexanone 9.4 U 51 9.4 ug/kg87-68-3 Hexachlorobutadiene a 0.88 U 5.1 0.88 ug/kg98-82-8 Isopropylbenzene 1.4 U 5.1 1.4 ug/kg99-87-6 p-Isopropyltoluene 0.46 U 5.1 0.46 ug/kg108-10-1 4-Methyl-2-pentanone 8.0 U 51 8.0 ug/kg74-83-9 Methyl bromide 2.4 U 5.1 2.4 ug/kg74-87-3 Methyl chloride 0.97 U 5.1 0.97 ug/kg74-95-3 Methylene bromide 0.82 U 5.1 0.82 ug/kg75-09-2 Methylene chloride 3.2 U 13 3.2 ug/kg78-93-3 Methyl ethyl ketone 6.3 U 51 6.3 ug/kg1634-04-4 Methyl Tert Butyl Ether 0.64 U 5.1 0.64 ug/kg91-20-3 Naphthalene 2.5 U 5.1 2.5 ug/kg103-65-1 n-Propylbenzene 1.3 U 5.1 1.3 ug/kg100-42-5 Styrene 1.2 U 5.1 1.2 ug/kg630-20-6 1,1,1,2-Tetrachloroethane 0.64 U 5.1 0.64 ug/kg71-55-6 1,1,1-Trichloroethane 0.80 U 5.1 0.80 ug/kg79-34-5 1,1,2,2-Tetrachloroethane 0.86 U 5.1 0.86 ug/kg79-00-5 1,1,2-Trichloroethane 0.85 U 5.1 0.85 ug/kg87-61-6 1,2,3-Trichlorobenzene 0.66 U 5.1 0.66 ug/kg96-18-4 1,2,3-Trichloropropane 1.2 U 5.1 1.2 ug/kg120-82-1 1,2,4-Trichlorobenzene 0.63 U 5.1 0.63 ug/kg95-63-6 1,2,4-Trimethylbenzene 0.51 U 5.1 0.51 ug/kg108-67-8 1,3,5-Trimethylbenzene 1.2 U 5.1 1.2 ug/kg127-18-4 Tetrachloroethylene 1.3 U 5.1 1.3 ug/kg108-88-3 Toluene 1.3 U 5.1 1.3 ug/kg79-01-6 Trichloroethylene 0.59 U 5.1 0.59 ug/kg75-69-4 Trichlorofluoromethane 0.80 U 5.1 0.80 ug/kg75-01-4 Vinyl chloride 0.74 U 5.1 0.74 ug/kg1330-20-7 Xylene (total) 3.6 U 15 3.6 ug/kg

m,p-Xylene 2.3 U 10 2.3 ug/kg95-47-6 o-Xylene 1.3 U 5.1 1.3 ug/kg




17 of 76TC42161

44.2




VOA 8260 List





18 of 76TC42161

44.2






ABN Full List





19 of 76TC42161

44.2




ABN Full List




20 of 76TC42161

44.2




ABN Full List




21 of 76TC42161

44.2



Client Sample ID: N.TANKS #2 0-1' Lab Sample ID: TC42161-2 Date Sampled: 01/08/14 Matrix: SO - Soil Date Received: 01/09/14


Metals Analysis




Cadmium 0.039 J 0.27 0.019 mg/kg 1 01/10/14 01/13/14 EG SW846 6010B 2 SW846 3050B 4



Mercury 0.017 U 0.042 0.017 mg/kg 1 01/10/14 01/10/14 NS SW846 7471A 1 SW846 7471A 3

Selenium 0.19 U 0.34 0.19 mg/kg 1 01/10/14 01/13/14 EG SW846 6010B 2 SW846 3050B 4




22 of 76TC42161

44.2



Client Sample ID: S.TANKS #1 0-1' Lab Sample ID: TC42161-3 Date Sampled: 01/08/14 Matrix: SO - Soil Date Received: 01/09/14 Method: SW846 8260C Percent Solids: 89.3 Project: CES Environmental / 4904 Griggs Houston TX



VOA 8260 List


67-64-1 Acetone 68.4 44 11 ug/kg71-43-2 Benzene 0.74 U 4.4 0.74 ug/kg108-86-1 Bromobenzene 0.44 U 4.4 0.44 ug/kg74-97-5 Bromochloromethane 1.2 U 4.4 1.2 ug/kg75-27-4 Bromodichloromethane 0.49 U 4.4 0.49 ug/kg75-25-2 Bromoform 0.82 U 4.4 0.82 ug/kg104-51-8 n-Butylbenzene 0.48 U 4.4 0.48 ug/kg135-98-8 sec-Butylbenzene 0.95 U 4.4 0.95 ug/kg98-06-6 tert-Butylbenzene 0.85 U 4.4 0.85 ug/kg108-90-7 Chlorobenzene 1.0 U 4.4 1.0 ug/kg75-00-3 Chloroethane 1.7 U 4.4 1.7 ug/kg67-66-3 Chloroform 0.47 U 4.4 0.47 ug/kg95-49-8 o-Chlorotoluene 0.52 U 4.4 0.52 ug/kg106-43-4 p-Chlorotoluene 0.45 U 4.4 0.45 ug/kg75-15-0 Carbon disulfide 1.8 4.4 0.64 ug/kg J56-23-5 Carbon tetrachloride 0.94 U 4.4 0.94 ug/kg75-34-3 1,1-Dichloroethane 0.45 U 4.4 0.45 ug/kg75-35-4 1,1-Dichloroethylene 0.46 U 4.4 0.46 ug/kg563-58-6 1,1-Dichloropropene 0.49 U 4.4 0.49 ug/kg96-12-8 1,2-Dibromo-3-chloropropane 3.5 U 4.4 3.5 ug/kg106-93-4 1,2-Dibromoethane 0.46 U 4.4 0.46 ug/kg107-06-2 1,2-Dichloroethane 0.52 U 4.4 0.52 ug/kg78-87-5 1,2-Dichloropropane 0.63 U 4.4 0.63 ug/kg142-28-9 1,3-Dichloropropane 1.1 U 4.4 1.1 ug/kg594-20-7 2,2-Dichloropropane 0.59 U 4.4 0.59 ug/kg124-48-1 Dibromochloromethane 0.99 U 4.4 0.99 ug/kg75-71-8 Dichlorodifluoromethane a 1.2 U 4.4 1.2 ug/kg156-59-2 cis-1,2-Dichloroethylene 0.50 U 4.4 0.50 ug/kg10061-01-5 cis-1,3-Dichloropropene 0.49 U 4.4 0.49 ug/kg541-73-1 m-Dichlorobenzene 0.68 U 4.4 0.68 ug/kg95-50-1 o-Dichlorobenzene 1.1 U 4.4 1.1 ug/kg106-46-7 p-Dichlorobenzene 0.94 U 4.4 0.94 ug/kg


23 of 76TC42161

44.3




VOA 8260 List


156-60-5 trans-1,2-Dichloroethylene 0.48 U 4.4 0.48 ug/kg10061-02-6 trans-1,3-Dichloropropene 0.56 U 4.4 0.56 ug/kg100-41-4 Ethylbenzene 1.1 U 4.4 1.1 ug/kg591-78-6 2-Hexanone 8.1 U 44 8.1 ug/kg87-68-3 Hexachlorobutadiene a 0.76 U 4.4 0.76 ug/kg98-82-8 Isopropylbenzene 1.2 U 4.4 1.2 ug/kg99-87-6 p-Isopropyltoluene 0.40 U 4.4 0.40 ug/kg108-10-1 4-Methyl-2-pentanone 6.9 U 44 6.9 ug/kg74-83-9 Methyl bromide 2.0 U 4.4 2.0 ug/kg74-87-3 Methyl chloride 0.84 U 4.4 0.84 ug/kg74-95-3 Methylene bromide 0.71 U 4.4 0.71 ug/kg75-09-2 Methylene chloride 2.7 U 11 2.7 ug/kg78-93-3 Methyl ethyl ketone 12.6 44 5.5 ug/kg J1634-04-4 Methyl Tert Butyl Ether 0.56 U 4.4 0.56 ug/kg91-20-3 Naphthalene 2.2 U 4.4 2.2 ug/kg103-65-1 n-Propylbenzene 1.1 U 4.4 1.1 ug/kg100-42-5 Styrene 1.0 U 4.4 1.0 ug/kg630-20-6 1,1,1,2-Tetrachloroethane 0.55 U 4.4 0.55 ug/kg71-55-6 1,1,1-Trichloroethane 0.69 U 4.4 0.69 ug/kg79-34-5 1,1,2,2-Tetrachloroethane 0.74 U 4.4 0.74 ug/kg79-00-5 1,1,2-Trichloroethane 0.73 U 4.4 0.73 ug/kg87-61-6 1,2,3-Trichlorobenzene 0.57 U 4.4 0.57 ug/kg96-18-4 1,2,3-Trichloropropane 0.99 U 4.4 0.99 ug/kg120-82-1 1,2,4-Trichlorobenzene 0.54 U 4.4 0.54 ug/kg95-63-6 1,2,4-Trimethylbenzene 0.49 4.4 0.44 ug/kg J108-67-8 1,3,5-Trimethylbenzene 1.0 U 4.4 1.0 ug/kg127-18-4 Tetrachloroethylene 1.1 U 4.4 1.1 ug/kg108-88-3 Toluene 1.1 U 4.4 1.1 ug/kg79-01-6 Trichloroethylene 0.51 U 4.4 0.51 ug/kg75-69-4 Trichlorofluoromethane 0.69 U 4.4 0.69 ug/kg75-01-4 Vinyl chloride 0.63 U 4.4 0.63 ug/kg1330-20-7 Xylene (total) 3.1 U 13 3.1 ug/kg





24 of 76TC42161

44.3




VOA 8260 List





25 of 76TC42161

44.3



Client Sample ID: S.TANKS #1 0-1' Lab Sample ID: TC42161-3 Date Sampled: 01/08/14 Matrix: SO - Soil Date Received: 01/09/14 Method: SW846 8270D SW846 3550B Percent Solids: 89.3 Project: CES Environmental / 4904 Griggs Houston TX



ABN Full List





26 of 76TC42161

44.3




ABN Full List


111-91-1 bis(2-Chloroethoxy)methane 78 U 190 78 ug/kg111-44-4 bis(2-Chloroethyl)ether 76 U 190 76 ug/kg108-60-1 bis(2-Chloroisopropyl)ether 75 U 190 75 ug/kg7005-72-3 4-Chlorophenyl phenyl ether 39 U 190 39 ug/kg95-50-1 1,2-Dichlorobenzene 75 U 190 75 ug/kg122-66-7 1,2-Diphenylhydrazine 82 U 190 82 ug/kg541-73-1 1,3-Dichlorobenzene 77 U 190 77 ug/kg106-46-7 1,4-Dichlorobenzene 75 U 190 75 ug/kg121-14-2 2,4-Dinitrotoluene 91 U 190 91 ug/kg606-20-2 2,6-Dinitrotoluene 100 U 190 100 ug/kg91-94-1 3,3'-Dichlorobenzidine 98 U 370 98 ug/kg53-70-3 Dibenzo(a,h)anthracene 87 U 190 87 ug/kg132-64-9 Dibenzofuran 92 U 190 92 ug/kg84-74-2 Di-n-butyl phthalate 99 U 190 99 ug/kg117-84-0 Di-n-octyl phthalate 37 U 190 37 ug/kg84-66-2 Diethyl phthalate 95 U 190 95 ug/kg131-11-3 Dimethyl phthalate 74 U 190 74 ug/kg117-81-7 bis(2-Ethylhexyl)phthalate 110 190 93 ug/kg J206-44-0 Fluoranthene 90 U 190 90 ug/kg86-73-7 Fluorene 97 U 190 97 ug/kg118-74-1 Hexachlorobenzene 79 U 190 79 ug/kg87-68-3 Hexachlorobutadiene 72 U 190 72 ug/kg77-47-4 Hexachlorocyclopentadiene 86 U 930 86 ug/kg67-72-1 Hexachloroethane 72 U 190 72 ug/kg193-39-5 Indeno(1,2,3-cd)pyrene 82 U 190 82 ug/kg78-59-1 Isophorone 79 U 190 79 ug/kg90-12-0 1-Methylnaphthalene 91 U 190 91 ug/kg91-57-6 2-Methylnaphthalene 88 U 190 88 ug/kg88-74-4 2-Nitroaniline 89 U 190 89 ug/kg99-09-2 3-Nitroaniline 90 U 190 90 ug/kg100-01-6 4-Nitroaniline 98 U 370 98 ug/kg91-20-3 Naphthalene 83 U 190 83 ug/kg98-95-3 Nitrobenzene 73 U 190 73 ug/kg62-75-9 n-Nitrosodimethylamine 68 U 190 68 ug/kg621-64-7 N-Nitroso-di-n-propylamine 66 U 190 66 ug/kg86-30-6 N-Nitrosodiphenylamine 37 U 190 37 ug/kg85-01-8 Phenanthrene 94 U 190 94 ug/kg129-00-0 Pyrene 97 U 190 97 ug/kg110-86-1 Pyridine 110 U 190 110 ug/kg120-82-1 1,2,4-Trichlorobenzene 82 U 190 82 ug/kg


27 of 76TC42161

44.3




ABN Full List




28 of 76TC42161

44.3



Client Sample ID: S.TANKS #1 0-1' Lab Sample ID: TC42161-3 Date Sampled: 01/08/14 Matrix: SO - Soil Date Received: 01/09/14


Metals Analysis




Cadmium a 0.86 J 1.1 0.080 mg/kg 5 01/10/14 01/13/14 EG SW846 6010B 2 SW846 3050B 4


Lead 124 0.85 0.28 mg/kg 5 01/10/14 01/13/14 EG SW846 6010B 2 SW846 3050B 4


Selenium a 0.81 U 1.4 0.81 mg/kg 5 01/10/14 01/13/14 EG SW846 6010B 2 SW846 3050B 4

Silver 0.068 J 0.57 0.066 mg/kg 1 01/10/14 01/13/14 EG SW846 6010B 2 SW846 3050B 4


(a) Elevated reporting limit due to dilution required for high interfering element.


29 of 76TC42161

44.3






VOA 8260 List


67-64-1 Acetone 105 43 11 ug/kg71-43-2 Benzene 16.1 4.3 0.72 ug/kg108-86-1 Bromobenzene 0.43 U 4.3 0.43 ug/kg74-97-5 Bromochloromethane 1.2 U 4.3 1.2 ug/kg75-27-4 Bromodichloromethane 0.48 U 4.3 0.48 ug/kg75-25-2 Bromoform 0.81 U 4.3 0.81 ug/kg104-51-8 n-Butylbenzene 0.47 U 4.3 0.47 ug/kg135-98-8 sec-Butylbenzene 0.93 U 4.3 0.93 ug/kg98-06-6 tert-Butylbenzene 0.84 U 4.3 0.84 ug/kg108-90-7 Chlorobenzene 1.0 U 4.3 1.0 ug/kg75-00-3 Chloroethane 1.7 U 4.3 1.7 ug/kg67-66-3 Chloroform 0.46 U 4.3 0.46 ug/kg95-49-8 o-Chlorotoluene 0.51 U 4.3 0.51 ug/kg106-43-4 p-Chlorotoluene 0.44 U 4.3 0.44 ug/kg75-15-0 Carbon disulfide 1.1 4.3 0.62 ug/kg J56-23-5 Carbon tetrachloride 0.92 U 4.3 0.92 ug/kg75-34-3 1,1-Dichloroethane 0.44 U 4.3 0.44 ug/kg75-35-4 1,1-Dichloroethylene 0.45 U 4.3 0.45 ug/kg563-58-6 1,1-Dichloropropene 0.48 U 4.3 0.48 ug/kg96-12-8 1,2-Dibromo-3-chloropropane 3.4 U 4.3 3.4 ug/kg106-93-4 1,2-Dibromoethane 0.45 U 4.3 0.45 ug/kg107-06-2 1,2-Dichloroethane 0.51 U 4.3 0.51 ug/kg78-87-5 1,2-Dichloropropane 0.62 U 4.3 0.62 ug/kg142-28-9 1,3-Dichloropropane 1.1 U 4.3 1.1 ug/kg594-20-7 2,2-Dichloropropane 0.58 U 4.3 0.58 ug/kg124-48-1 Dibromochloromethane 0.97 U 4.3 0.97 ug/kg75-71-8 Dichlorodifluoromethane a 1.2 U 4.3 1.2 ug/kg156-59-2 cis-1,2-Dichloroethylene 0.49 U 4.3 0.49 ug/kg10061-01-5 cis-1,3-Dichloropropene 0.48 U 4.3 0.48 ug/kg541-73-1 m-Dichlorobenzene 0.67 U 4.3 0.67 ug/kg95-50-1 o-Dichlorobenzene 1.0 U 4.3 1.0 ug/kg106-46-7 p-Dichlorobenzene 0.92 U 4.3 0.92 ug/kg


30 of 76TC42161

44.4




VOA 8260 List


156-60-5 trans-1,2-Dichloroethylene 0.47 U 4.3 0.47 ug/kg10061-02-6 trans-1,3-Dichloropropene 0.55 U 4.3 0.55 ug/kg100-41-4 Ethylbenzene 1.1 4.3 1.0 ug/kg J591-78-6 2-Hexanone 7.9 U 43 7.9 ug/kg87-68-3 Hexachlorobutadiene a 0.74 U 4.3 0.74 ug/kg98-82-8 Isopropylbenzene 1.2 U 4.3 1.2 ug/kg99-87-6 p-Isopropyltoluene 0.39 U 4.3 0.39 ug/kg108-10-1 4-Methyl-2-pentanone 6.7 U 43 6.7 ug/kg74-83-9 Methyl bromide 2.0 U 4.3 2.0 ug/kg74-87-3 Methyl chloride 0.82 U 4.3 0.82 ug/kg74-95-3 Methylene bromide 0.69 U 4.3 0.69 ug/kg75-09-2 Methylene chloride 2.7 U 11 2.7 ug/kg78-93-3 Methyl ethyl ketone 15.2 43 5.3 ug/kg J1634-04-4 Methyl Tert Butyl Ether 21.5 4.3 0.54 ug/kg91-20-3 Naphthalene 2.1 U 4.3 2.1 ug/kg103-65-1 n-Propylbenzene 1.1 U 4.3 1.1 ug/kg100-42-5 Styrene 0.98 U 4.3 0.98 ug/kg630-20-6 1,1,1,2-Tetrachloroethane 0.54 U 4.3 0.54 ug/kg71-55-6 1,1,1-Trichloroethane 0.67 U 4.3 0.67 ug/kg79-34-5 1,1,2,2-Tetrachloroethane 0.72 U 4.3 0.72 ug/kg79-00-5 1,1,2-Trichloroethane 0.72 U 4.3 0.72 ug/kg87-61-6 1,2,3-Trichlorobenzene 0.56 U 4.3 0.56 ug/kg96-18-4 1,2,3-Trichloropropane 0.97 U 4.3 0.97 ug/kg120-82-1 1,2,4-Trichlorobenzene 0.53 U 4.3 0.53 ug/kg95-63-6 1,2,4-Trimethylbenzene 0.82 4.3 0.43 ug/kg J108-67-8 1,3,5-Trimethylbenzene 1.0 U 4.3 1.0 ug/kg127-18-4 Tetrachloroethylene 1.1 U 4.3 1.1 ug/kg108-88-3 Toluene 1.1 U 4.3 1.1 ug/kg79-01-6 Trichloroethylene 0.50 U 4.3 0.50 ug/kg75-69-4 Trichlorofluoromethane 0.67 U 4.3 0.67 ug/kg75-01-4 Vinyl chloride 0.62 U 4.3 0.62 ug/kg1330-20-7 Xylene (total) 3.0 U 13 3.0 ug/kg





31 of 76TC42161

44.4




VOA 8260 List





32 of 76TC42161

44.4






ABN Full List





33 of 76TC42161

44.4




ABN Full List




34 of 76TC42161

44.4




ABN Full List




35 of 76TC42161

44.4



Client Sample ID: S.TANKS #2 0-1' Lab Sample ID: TC42161-4 Date Sampled: 01/08/14 Matrix: SO - Soil Date Received: 01/09/14


Metals Analysis




Cadmium 0.42 0.24 0.017 mg/kg 1 01/10/14 01/13/14 EG SW846 6010B 2 SW846 3050B 4




Selenium 0.17 U 0.30 0.17 mg/kg 1 01/10/14 01/13/14 EG SW846 6010B 2 SW846 3050B 4




36 of 76TC42161

44.4


Misc. Forms

Custody Documents and Other Forms

Includes the following where applicable:

• Chain of Custody• LRC Form

Gulf Coast

Section 5

37 of 76TC42161

5

TC42161: Chain of CustodyPage 1 of 3

38 of 76TC42161

55.1

of 2

Accutest Job Number: TC42161 Client: IKON ENVIRONMENTAL SOLUTIONS

Date / Time Received: 1/9/2014 Delivery Method:

Project: CES ENVIRONMENTAL

No. Coolers: 1

Airbill #'s:

Cooler Security

1. Custody Seals Present:

Y or N

2. Custody Seals Intact:

3. COC Present:

4. Smpl Dates/Time OK

2. Cooler temp verification:

Cooler Temperature Y or N

1. Temp criteria achieved:

3. Cooler media: Ice (Bag)

Quality Control Preservation Y or N N/A

1. Trip Blank present / cooler:

2. Trip Blank listed on COC:

3. Samples preserved properly:

4. VOCs headspace free:

Sample Integrity - Documentation Y or N

1. Sample labels present on bottles:

2. Container labeling complete:

3. Sample container label / COC agree:

Sample Integrity - Condition Y or N

1. Sample recvd within HT:

3. Condition of sample:

2. All containers accounted for:

Sample Integrity - Instructions

1. Analysis requested is clear:

2. Bottles received for unspecified tests

3. Sufficient volume recvd for analysis:

4. Compositing instructions clear:

5. Filtering instructions clear:

Intact

Y or N

Accutest LaboratoriesV:713.271.4700

10165 Harwin DriveF: 713.271.4770

Houston, TX 77036www/accutest.com

Comments

Y or N N/A

WTB STB

Cooler Temps (Initial/Adjusted): #1: (2.2/2.2);

Therm ID: IR-5; Temp Adjustment Factor: 0;

Accutest Laboratories Sample Receipt Summary


39 of 76TC42161

55.1

Sample Receipt Log

Job #: TC42161 Date / Time Received: 1/9/2014 9:30:00 AM Initials: EC

Client: IKON ENVIRONMENTAL SOLUTIONS

Sample ID: Bot #Cooler # Vol Location Pres pH Therm IDTherm

CFCorrected

TempInitialTemp

Page 2 of 2

8oz 2-96 N/P Note #2 - Preservative check not applicable. IR-5 0 2.21 TC42161-1 2.21

4oz VR N/P Note #2 - Preservative check not applicable. IR-5 0 2.21 TC42161-1 2.22
















40 of 76TC42161

55.1

R1 R2 R3

a)b)c)d)e)

R4a)b)

R5 R6

a)b)c)

R7a)b)c)d)e)

R8a)b)c)

R9 R10

Signature Official Title (printed)

Laboratory DirectorRichard Rodriguez 1/20/2014

This laboratory meets an exception under 30 TAC&25.6 and was last inspection by

[X ] TCEQ or [ ] ________ on April 2011. Any findings affecting the data in this laboratory data package are noted in the Exception Reports herein. The official signing the cover page of the report in which these data are used is responsible for releasing this data package and is by signature affirming the above release statement is true.

Check, if applicable: [ ]

List of method quantitation limits (MQLs) and detectability check sample results for each analyte for each Other problems or anomalies.

QA ManagerName (Printed) Date

The Exception Report for each “No” or “Not Reviewed (NR)” item in Laboratory Review Checklist and for each analyte, matrix, and method for which the laboratory does not hold NELAC accreditation under the Texas Laboratory Accreditation Program.

Release Statement: I am responsible for the release of this laboratory data package. This laboratory is NELAC accredited under the Texas Laboratory Accreditation Program for all the methods, analytes, and matrices reported in this data package except as noted in the Exception Report. This data package has been reviewed by the laboratory and is complete and technically compliant with the requirements of the methods used, except where noted by the laboratory in the attached exception reports. By my signature below, I affirm to the best of my knowledge, all problems/anomalies, observed by the laboratory as having the potential to affect the quality of the data, have been identified by the laboratory in the Laboratory Review Checklist, and no information or data have been knowingly withheld.

Laboratory analytical duplicate (if applicable) recovery and precision:The amount of analyte measured in the duplicate,The calculated RPD, andThe laboratory’s QC limits for analytical duplicates.

MS/MSD spiking amounts,Concentration of each MS/MSD analyte measured in the parent and Calculated %Rs and relative percent differences (RPDs), andThe laboratory’s MS/MSD QC limits

Calculated %R for each analyte, andThe laboratory’s LCS QC limits.

Test reports for project matrix spike/matrix spike duplicates (MS/MSDs) including:Samples associated with the MS/MSD clearly identified,

The laboratory’s surrogate QC limits.Test reports/summary forms for blank samples;Test reports/summary forms for laboratory control samples (LCSs) including:

LCS spiking amounts,

Appendix A Laboratory Data Package Cover Page

This signature page, the laboratory review checklist, and the following reportable data:

TC42161 This data package consists of

Field chain-of-custody documentation;Sample identification cross-reference;Test reports (analytical data sheets) for each environmental sample that includes:

Items consistent with NELAC 5.13 or ISO/IEC 17025 Section 5.10dilution factors,preparation methods,cleanup methods, andif required for the project, tentatively identified compounds (TICs).

Surrogate recovery data including:Calculated recovery (%R), and

41 of 76TC42161

55.2

Accutest Gulf Coast LRC Date:CES Environmental / 4904 Griggs Houston TX Laboratory Project Number:

Reviewer Name: Anita Patel Prep Batch Number(s):#1 A2 YES NO NA3 NR4 ER #5

R1 OI

X

XR2 OI

XX

R3 OIX

X

XXXXX

X

XR4 O

XX

R5 OIXX

X

XR6 OI

X

X

XX

X

XR7 OI

XX

X 4X

R8 OIXXX

R9 OIXX

X 2R10 OI

XX

X 3

DESCRIPTION

LABORATORY REVIEW CHECKLIST: REPORTABLE DATALaboratory Name: 1/20/2014

Project Name: TC42161

CHAIN-OF-CUSTODY (C-O-C):Did samples meet the laboratory's standard conditions of sample acceptability upon receipt?Were all departures from standard conditions described in an exception report?Sample and quality control (QC) identificationAre all field sample ID numbers cross-referenced to the laboratory ID numbers?Are all laboratory ID numbers cross-referenced to the corresponding QC data?Test reports

Surrogate recovery dataIf required for the project, are TIC's reported?

Laboratory control samples (LCS):

Were the project/method specified analytes included in the MS and MSD?

Analytical duplicate data

Were method blanks taken through the entire analytical process, including preparation and, if applicable, cleanup procedures?Were blank concentrations <MQL?

Were all COCs included in the LCS?Was each LCS taken through the entire analytical procedure, including prep and cleanup steps?Were LCSs analyzed at required frequency?Were LCS (and LCSD, if applicable) %Rs within the laboratory QC limits?Does the detectablility check sample data document the laboratory's capability to detect the COCs at the MDL used to calculate the SDLs?

Other problems/anomalies

Were samples prepared and analyzed within holding times?Other than those results <MQL, were all other raw values bracketed by calibration standards?Were calculations checked by a peer or supervisor?Were all analyte identifications checked by a peer or supervisor?Were sample detection limits reported for all analytes not detected?Were all results for soil and sediment samples reported on a dry weight basis?Were % moisture (or solids) reported for all soil and sediment samples?Were bulk soils/solids samples for volatile analysis extracted with methanol per SW846 Method 5035?

Test reports/summary forms for blank samples

Were surrogates added prior to extraction?Were surrogate percent recoveries in all samples within the laboratory QC limits?

Were appropriate type(s) of blanks analyzed?Were blanks analyzed at the appropriate frequency?

Was the LCSD RPD within QC limits?Matrix spike (MS) and matrix spike duplicate (MSD) data

Were MS/MSD analyzed at the appropriate frequency?Were MS (and MSD, if applicable) %Rs within the laboratory QC Limits?Were the MS/MSD RPDs within laboratory QC limits?

Were appropriate analytical duplicates analyzed for each matrix?Were analytical duplicates analyzed at the appropriate frequency?Were RPDs or relative standard deviations within the laboratory QC limits?

Are the MQLs for each method analyte included in the laboratory data package?Do the MQLs correspond to the concentration of the lowest non-zero calibration Are unadjusted MQLs and DCSs included in the laboratory data package?

Method quantitation limits (MQLs):

Are all known problems/anomalies/special conditions noted in this LRC and ER?Was applicable and available technology used to lower the SDL to minimize the Is the laboratory NELAC-accredited under the Texas Laboratory Accreditation Program for the analytes, matrices, and methods associated with this laboratory data package?

GN55774, MP22462, MP22463, OP31117, VY3521

42 of 76TC42161

55.2

Accutest Gulf Coast LRC Date:CES Environmental / 4904 Griggs Houston TXLaboratory Project Number:

Reviewer Name: Anita Patel Prep Batch Number(s):#1 A2 YES NO NA3 NR4 ER #5

S1 OI

X

XX

X

X

X

S2 OIX

X 4X

X 5S3 O

XX

S4 OX

S5 OI

X

XS6 O

XS7 O

X

S8 IX

S9 I

X 4

S10 OIXX

S11 OI

X

S12 OI

X

S13 OIX

S14 OIXX

S15 OI

X

S16 OIX

Laboratory Name: 1/20/2014Project Name: TC42161

DESCRIPTIONInitial calibration (ICAL)

Initial and continuing calibration verification (ICCV AND CCV) and continuing

Mass spectral tuningWas the absolute value of the analyte concentration in the inorganic CCB<MDL?Was the ICAL curve verified for each analyte?

Are ICAL data available for all instruments used?Has the initial calibration curve been verified using an appropriate second source standard?

Was the CCV analyzed at the method-required frequency?Were percent differences for each analyte within the method-required QC limits?

Were response factors and/or relative response factors for each analyte within QC limits?

Verification/validation documentation for methods (NELAC Chapter 5)Is documentation of the analyst's competency up-to-date and on file?

Interference Check Sample (ICS) results

Serial dilutions, post digestion spikes, and method of standard additions

Method detection limit (MDL) studies

Proficiency test reportsIs the MDL either adjusted or supported by the analysis of DCSs?

Standards documentation

Compound/analyte identification procedures

Demonstration of analyst competency (DOC)

Dual column confirmation

Tentatively identified compounds (TICs):

Were data associated with manual integrations flagged on the raw data?

Did dual column confirmation results meet the method-required QC?

Were percent RSDs or correlation coefficient criteria met?Was the number of standards recommended in the method used for all analytes?Were all points generated between the lowest and highest standard used to calculate the curve?

Was the appropriate compound for the method used for tuning?Were ion abundance data within the method-required QC limits?

Were IS area counts and retention times within the method-required QC limits?

Were the raw data (for example, chromatograms, spectral data) reviewed by an analyst?

Internal standards (IS)

Raw data (NELAC Section 5.5.10)

If TICs were requested, were the mass spectra and TIC data subject to appropriate checks?

Were percent recoveries within method QC limits?

Were percent differences, recoveries, and the linearity within the QC limits specified in the method?

Was a MDL study performed for each reported analyte?

Was the laboratory's performance acceptable on the applicable proficiency tests or evaluation studies?

Are all standards used in the analyses NIST-traceable or obtained from other appropriate source?

Are the procedures for compound/analyte identification documented?

Was DOC conducted consistent with NELAC Chapter 5?

Are all the methods used to generate the data documentated, verified, and validated, where applicable?

Are laboratory SOPs current and on file for each method performed?Laboratory standard operating procedures (SOPs)

GN55774, MP22462, MP22463, OP31117, VY3521

43 of 76TC42161

55.2

Accutest Gulf Coast LRC Date:CES Environmental / 4904 Griggs Houston TXLaboratory Project Number:

Reviewer Name: Anita Patel Prep Batch Number(s):ER#1

1

2

345

LABORATORY REVIEW CHECKLIST (continued): Exception ReportsLaboratory Name: 1/20/2014

All anomalies are discussed in the case narrative.See Metals CCB check section of report.

Project Name: TC42161

Description

For reporting purposes, the method blank represents the unadjusted MQL. The DCS is on file in the laboratory and is not included in the laboratory data package.

For reporting purposes, the MQL is defined in the report as the RL. The unadjusted MQL/RL is reported in the method blank. The SDL is defined in the report as the MDL.

1ER# = Exception Report identification number (an Exception Report should be completed for an item if "NR" or "No" is checked on

GN55774, MP22462, MP22463, OP31117, VY3521

The laboratory is NELAC-accredited under the Texas Laboratory Accreditation Program for the analytes, matrices, and methods associated with this laboratory data package for analytes that are listed in the Texas Fields of Accreditation.

44 of 76TC42161

55.2


GC/MS Volatiles

QC Data Summaries


• Method Blank Summaries• Blank Spike Summaries• Matrix Spike and Duplicate Summaries

Gulf Coast

Section 6

45 of 76TC42161

6

Method Blank Summary Page 1 of 3 Job Number: TC42161Account: IKONTXH IKON Environmental SolutionsProject: CES Environmental / 4904 Griggs Houston TX

Sample File ID DF Analyzed By Prep Date Prep Batch Analytical BatchVY3521-MB Y0065379.D 1 01/10/14 FI n/a n/a VY3521

The QC reported here applies to the following samples: Method: SW846 8260C

TC42161-1, TC42161-2, TC42161-3, TC42161-4

CAS No. Compound Result RL MDL Units Q

67-64-1 Acetone ND 39 9.7 ug/kg71-43-2 Benzene ND 3.9 0.66 ug/kg108-86-1 Bromobenzene ND 3.9 0.39 ug/kg74-97-5 Bromochloromethane ND 3.9 1.1 ug/kg75-27-4 Bromodichloromethane ND 3.9 0.44 ug/kg75-25-2 Bromoform ND 3.9 0.73 ug/kg104-51-8 n-Butylbenzene ND 3.9 0.43 ug/kg135-98-8 sec-Butylbenzene ND 3.9 0.85 ug/kg98-06-6 tert-Butylbenzene ND 3.9 0.76 ug/kg108-90-7 Chlorobenzene ND 3.9 0.91 ug/kg75-00-3 Chloroethane ND 3.9 1.5 ug/kg67-66-3 Chloroform ND 3.9 0.42 ug/kg95-49-8 o-Chlorotoluene ND 3.9 0.46 ug/kg106-43-4 p-Chlorotoluene ND 3.9 0.40 ug/kg75-15-0 Carbon disulfide ND 3.9 0.57 ug/kg56-23-5 Carbon tetrachloride ND 3.9 0.84 ug/kg75-34-3 1,1-Dichloroethane ND 3.9 0.40 ug/kg75-35-4 1,1-Dichloroethylene ND 3.9 0.41 ug/kg563-58-6 1,1-Dichloropropene ND 3.9 0.43 ug/kg96-12-8 1,2-Dibromo-3-chloropropane ND 3.9 3.1 ug/kg106-93-4 1,2-Dibromoethane ND 3.9 0.41 ug/kg107-06-2 1,2-Dichloroethane ND 3.9 0.46 ug/kg78-87-5 1,2-Dichloropropane ND 3.9 0.56 ug/kg142-28-9 1,3-Dichloropropane ND 3.9 0.99 ug/kg594-20-7 2,2-Dichloropropane ND 3.9 0.53 ug/kg124-48-1 Dibromochloromethane ND 3.9 0.88 ug/kg75-71-8 Dichlorodifluoromethane ND 3.9 1.1 ug/kg156-59-2 cis-1,2-Dichloroethylene ND 3.9 0.44 ug/kg10061-01-5 cis-1,3-Dichloropropene ND 3.9 0.44 ug/kg541-73-1 m-Dichlorobenzene ND 3.9 0.61 ug/kg95-50-1 o-Dichlorobenzene ND 3.9 0.94 ug/kg106-46-7 p-Dichlorobenzene ND 3.9 0.84 ug/kg156-60-5 trans-1,2-Dichloroethylene ND 3.9 0.43 ug/kg10061-02-6 trans-1,3-Dichloropropene ND 3.9 0.50 ug/kg100-41-4 Ethylbenzene ND 3.9 0.94 ug/kg591-78-6 2-Hexanone ND 39 7.2 ug/kg

46 of 76TC42161

66.1.1




TC42161-1, TC42161-2, TC42161-3, TC42161-4


87-68-3 Hexachlorobutadiene ND 3.9 0.67 ug/kg98-82-8 Isopropylbenzene ND 3.9 1.1 ug/kg99-87-6 p-Isopropyltoluene 0.44 3.9 0.35 ug/kg J108-10-1 4-Methyl-2-pentanone ND 39 6.1 ug/kg74-83-9 Methyl bromide ND 3.9 1.8 ug/kg74-87-3 Methyl chloride ND 3.9 0.75 ug/kg74-95-3 Methylene bromide ND 3.9 0.63 ug/kg75-09-2 Methylene chloride ND 9.7 2.4 ug/kg78-93-3 Methyl ethyl ketone ND 39 4.9 ug/kg1634-04-4 Methyl Tert Butyl Ether ND 3.9 0.49 ug/kg91-20-3 Naphthalene ND 3.9 1.9 ug/kg103-65-1 n-Propylbenzene ND 3.9 1.0 ug/kg100-42-5 Styrene ND 3.9 0.90 ug/kg630-20-6 1,1,1,2-Tetrachloroethane ND 3.9 0.49 ug/kg71-55-6 1,1,1-Trichloroethane ND 3.9 0.61 ug/kg79-34-5 1,1,2,2-Tetrachloroethane ND 3.9 0.66 ug/kg79-00-5 1,1,2-Trichloroethane ND 3.9 0.65 ug/kg87-61-6 1,2,3-Trichlorobenzene ND 3.9 0.51 ug/kg96-18-4 1,2,3-Trichloropropane ND 3.9 0.88 ug/kg120-82-1 1,2,4-Trichlorobenzene ND 3.9 0.48 ug/kg95-63-6 1,2,4-Trimethylbenzene ND 3.9 0.39 ug/kg108-67-8 1,3,5-Trimethylbenzene ND 3.9 0.91 ug/kg127-18-4 Tetrachloroethylene ND 3.9 0.98 ug/kg108-88-3 Toluene ND 3.9 0.99 ug/kg79-01-6 Trichloroethylene ND 3.9 0.45 ug/kg75-69-4 Trichlorofluoromethane ND 3.9 0.61 ug/kg75-01-4 Vinyl chloride ND 3.9 0.56 ug/kg1330-20-7 Xylene (total) ND 12 2.7 ug/kg

m,p-Xylene ND 7.8 1.7 ug/kg95-47-6 o-Xylene ND 3.9 0.98 ug/kg

CAS No. Surrogate Recoveries Limits

1868-53-7 Dibromofluoromethane 89% 59-126%2037-26-5 Toluene-D8 104% 70-139%

47 of 76TC42161

66.1.1




TC42161-1, TC42161-2, TC42161-3, TC42161-4


460-00-4 4-Bromofluorobenzene 97% 63-138%17060-07-0 1,2-Dichloroethane-D4 82% 54-123%

48 of 76TC42161

66.1.1

Blank Spike Summary Page 1 of 3 Job Number: TC42161Account: IKONTXH IKON Environmental SolutionsProject: CES Environmental / 4904 Griggs Houston TX

Sample File ID DF Analyzed By Prep Date Prep Batch Analytical BatchVY3521-BS Y0065377.D 1 01/10/14 FI n/a n/a VY3521


TC42161-1, TC42161-2, TC42161-3, TC42161-4

Spike BSP BSPCAS No. Compound ug/kg ug/kg % Limits

67-64-1 Acetone 234 201 86 43-14171-43-2 Benzene 46.7 47.5 102 58-124108-86-1 Bromobenzene 46.7 46.5 100 72-11074-97-5 Bromochloromethane 46.7 44.0 94 71-12275-27-4 Bromodichloromethane 46.7 45.4 97 72-11975-25-2 Bromoform 46.7 45.4 97 61-120104-51-8 n-Butylbenzene 46.7 53.2 114 58-118135-98-8 sec-Butylbenzene 46.7 51.5 110 63-11998-06-6 tert-Butylbenzene 46.7 49.6 106 67-121108-90-7 Chlorobenzene 46.7 46.6 100 74-11675-00-3 Chloroethane 46.7 53.0 113 48-13367-66-3 Chloroform 46.7 45.0 96 72-11995-49-8 o-Chlorotoluene 46.7 47.2 101 65-121106-43-4 p-Chlorotoluene 46.7 48.4 104 67-11875-15-0 Carbon disulfide 46.7 48.9 105 45-13356-23-5 Carbon tetrachloride 46.7 50.0 107 58-12875-34-3 1,1-Dichloroethane 46.7 46.6 100 69-12275-35-4 1,1-Dichloroethylene 46.7 49.0 105 60-131563-58-6 1,1-Dichloropropene 46.7 51.3 110 66-12396-12-8 1,2-Dibromo-3-chloropropane 46.7 50.7 108 55-125106-93-4 1,2-Dibromoethane 46.7 46.7 100 73-120107-06-2 1,2-Dichloroethane 46.7 45.8 98 69-12178-87-5 1,2-Dichloropropane 46.7 46.5 100 71-121142-28-9 1,3-Dichloropropane 46.7 46.7 100 72-117594-20-7 2,2-Dichloropropane 46.7 48.7 104 57-129124-48-1 Dibromochloromethane 46.7 45.5 97 71-12175-71-8 Dichlorodifluoromethane 46.7 51.0 109 22-158156-59-2 cis-1,2-Dichloroethylene 46.7 45.0 96 70-11910061-01-5 cis-1,3-Dichloropropene 46.7 44.9 96 75-117541-73-1 m-Dichlorobenzene 46.7 47.4 101 70-11995-50-1 o-Dichlorobenzene 46.7 47.5 102 73-116106-46-7 p-Dichlorobenzene 46.7 48.1 103 70-119156-60-5 trans-1,2-Dichloroethylene 46.7 48.1 103 62-11910061-02-6 trans-1,3-Dichloropropene 46.7 49.0 105 78-125100-41-4 Ethylbenzene 46.7 50.4 108 57-124591-78-6 2-Hexanone 234 217 93 58-124

* = Outside of Control Limits.

49 of 76TC42161

66.2.1




TC42161-1, TC42161-2, TC42161-3, TC42161-4


87-68-3 Hexachlorobutadiene 46.7 56.2 120 57-12798-82-8 Isopropylbenzene 46.7 50.4 108 77-13599-87-6 p-Isopropyltoluene 46.7 53.3 114 66-120108-10-1 4-Methyl-2-pentanone 234 218 93 60-12774-83-9 Methyl bromide 46.7 42.8 92 47-13774-87-3 Methyl chloride 46.7 50.0 107 46-13974-95-3 Methylene bromide 46.7 45.4 97 72-11875-09-2 Methylene chloride 46.7 44.9 96 50-13478-93-3 Methyl ethyl ketone 234 210 90 60-1311634-04-4 Methyl Tert Butyl Ether 46.7 45.3 97 65-11991-20-3 Naphthalene 46.7 52.0 111 56-122103-65-1 n-Propylbenzene 46.7 50.4 108 65-119100-42-5 Styrene 46.7 49.7 106 74-117630-20-6 1,1,1,2-Tetrachloroethane 46.7 46.5 100 74-11971-55-6 1,1,1-Trichloroethane 46.7 47.8 102 63-12679-34-5 1,1,2,2-Tetrachloroethane 46.7 48.5 104 65-12079-00-5 1,1,2-Trichloroethane 46.7 46.2 99 72-11987-61-6 1,2,3-Trichlorobenzene 46.7 51.0 109 62-11696-18-4 1,2,3-Trichloropropane 46.7 47.2 101 68-118120-82-1 1,2,4-Trichlorobenzene 46.7 50.8 109 58-12295-63-6 1,2,4-Trimethylbenzene 46.7 50.0 107 61-119108-67-8 1,3,5-Trimethylbenzene 46.7 49.9 107 53-123127-18-4 Tetrachloroethylene 46.7 52.3 112 64-130108-88-3 Toluene 46.7 49.7 106 67-11979-01-6 Trichloroethylene 46.7 46.8 100 70-12275-69-4 Trichlorofluoromethane 46.7 48.0 103 41-13775-01-4 Vinyl chloride 46.7 48.0 103 43-1201330-20-7 Xylene (total) 140 148 106 62-120

m,p-Xylene 93.5 99.6 107 62-12095-47-6 o-Xylene 46.7 48.3 103 62-121

CAS No. Surrogate Recoveries BSP Limits

1868-53-7 Dibromofluoromethane 84% 59-126%2037-26-5 Toluene-D8 102% 70-139%


50 of 76TC42161

66.2.1




TC42161-1, TC42161-2, TC42161-3, TC42161-4


460-00-4 4-Bromofluorobenzene 94% 63-138%17060-07-0 1,2-Dichloroethane-D4 82% 54-123%


51 of 76TC42161

66.2.1

Matrix Spike/Matrix Spike Duplicate Summary Page 1 of 3 Job Number: TC42161Account: IKONTXH IKON Environmental SolutionsProject: CES Environmental / 4904 Griggs Houston TX

Sample File ID DF Analyzed By Prep Date Prep Batch Analytical BatchTC42188-1MS Y0065384.D 1 01/10/14 FI n/a n/a VY3521TC42188-1MSD Y0065385.D 1 01/10/14 FI n/a n/a VY3521TC42188-1 a Y0065380.D 1 01/10/14 FI n/a n/a VY3521TC42188-1 Y0065394.D 1 01/10/14 FI n/a n/a VY3521


TC42161-1, TC42161-2, TC42161-3, TC42161-4

TC42188-1 Spike MS MS MSD MSD LimitsCAS No. Compound ug/kg Q ug/kg ug/kg % ug/kg % RPD Rec/RPD

67-64-1 Acetone 62 U b 28300 26000 92 26200 93 1 43-141/3371-43-2 Benzene 6.2 U b 5660 5750 102 5520 98 4 58-124/26108-86-1 Bromobenzene 6.2 U b 5660 5910 104 5680 100 4 72-110/2874-97-5 Bromochloromethane 6.2 U b 5660 5140 91 5150 91 0 71-122/2575-27-4 Bromodichloromethane 6.2 U b 5660 5410 96 5290 93 2 72-119/2575-25-2 Bromoform 6.2 U b 5660 5300 94 5280 93 0 61-120/27104-51-8 n-Butylbenzene 6.2 U b 5660 6670 118 5950 105 11 58-118/32135-98-8 sec-Butylbenzene 6.2 U b 5660 6210 110 5800 102 7 63-119/3198-06-6 tert-Butylbenzene 6.2 U b 5660 6010 106 5690 101 5 67-121/30108-90-7 Chlorobenzene 6.2 U b 5660 5570 98 5460 96 2 74-116/2675-00-3 Chloroethane 6.2 U b 5660 5110 90 4080 72 22 48-133/3867-66-3 Chloroform 6.2 U b 5660 5210 92 5090 90 2 72-119/2595-49-8 o-Chlorotoluene 6.2 U b 5660 5790 102 5500 97 5 65-121/30106-43-4 p-Chlorotoluene 6.2 U b 5660 6020 106 5720 101 5 67-118/2975-15-0 Carbon disulfide 2.4 b J 5660 5400 95 5130 91 5 45-133/3456-23-5 Carbon tetrachloride 6.2 U b 5660 5780 102 5440 96 6 58-128/2875-34-3 1,1-Dichloroethane 6.2 U b 5660 5430 96 5300 94 2 69-122/2575-35-4 1,1-Dichloroethylene 6.2 U b 5660 6140 108 5700 101 7 60-131/31563-58-6 1,1-Dichloropropene 6.2 U b 5660 5810 103 5630 99 3 66-123/2796-12-8 1,2-Dibromo-3-chloropropane 6.2 U b 5660 6090 108 6040 107 1 55-125/33106-93-4 1,2-Dibromoethane 6.2 U b 5660 5540 98 5570 98 1 73-120/26107-06-2 1,2-Dichloroethane 6.2 U b 5660 5500 97 5520 98 0 69-121/2478-87-5 1,2-Dichloropropane 6.2 U b 5660 5710 101 5520 98 3 71-121/26142-28-9 1,3-Dichloropropane 6.2 U b 5660 5580 99 5660 100 1 72-117/25594-20-7 2,2-Dichloropropane 6.2 U b 5660 5620 99 5290 93 6 57-129/29124-48-1 Dibromochloromethane 6.2 U b 5660 5340 94 5340 94 0 71-121/2675-71-8 Dichlorodifluoromethane 6.2 U b 5660 5670 100 5140 91 10 22-158/38156-59-2 cis-1,2-Dichloroethylene 6.2 U b 5660 5280 93 5160 91 2 70-119/2510061-01-5 cis-1,3-Dichloropropene 6.2 U b 5660 5440 96 5350 94 2 75-117/27541-73-1 m-Dichlorobenzene 6.2 U b 5660 5790 102 5640 100 3 70-119/3095-50-1 o-Dichlorobenzene 12.5 b 5660 5790 102 5600 99 3 73-116/30106-46-7 p-Dichlorobenzene 6.2 U b 5660 6010 106 5810 103 3 70-119/30156-60-5 trans-1,2-Dichloroethylene 6.2 U b 5660 5600 99 5390 95 4 62-119/2910061-02-6 trans-1,3-Dichloropropene 6.2 U b 5660 5850 103 5880 104 1 78-125/27100-41-4 Ethylbenzene 6.2 U b 5660 6000 106 5790 102 4 57-124/29591-78-6 2-Hexanone 4500 U 28300 25400 90 26100 92 3 58-124/32


52 of 76TC42161

66.3.1




TC42161-1, TC42161-2, TC42161-3, TC42161-4


87-68-3 Hexachlorobutadiene 450 U 5660 6760 119 6410 113 5 57-127/3398-82-8 Isopropylbenzene 6.2 U b 5660 6170 109 5720 101 8 77-135/2999-87-6 p-Isopropyltoluene 6.2 U b 5660 6470 114 6000 106 8 66-120/30108-10-1 4-Methyl-2-pentanone 62 U b 28300 25500 90 25900 91 2 60-127/3074-83-9 Methyl bromide 6.2 U b 5660 2740 48 2530 45* 8 47-137/3774-87-3 Methyl chloride 6.2 U b 5660 5410 96 4990 88 8 46-139/3674-95-3 Methylene bromide 6.2 U b 5660 5340 94 5330 94 0 72-118/2575-09-2 Methylene chloride 16 U b 5660 5590 99 5440 96 3 50-134/3578-93-3 Methyl ethyl ketone 62 U b 28300 24800 88 25700 91 4 60-131/311634-04-4 Methyl Tert Butyl Ether 450 U 5660 5380 95 5420 96 1 65-119/2991-20-3 Naphthalene 450 U 5660 6490 115 6370 113 2 56-122/36103-65-1 n-Propylbenzene 6.2 U b 5660 6110 108 5740 101 6 65-119/31100-42-5 Styrene 6.2 U b 5660 6070 107 5950 105 2 74-117/28630-20-6 1,1,1,2-Tetrachloroethane 6.2 U b 5660 5600 99 5500 97 2 74-119/2771-55-6 1,1,1-Trichloroethane 6.2 U b 5660 5340 94 5070 90 5 63-126/2779-34-5 1,1,2,2-Tetrachloroethane 6.2 U b 5660 5700 101 5670 100 1 65-120/3179-00-5 1,1,2-Trichloroethane 6.2 U b 5660 5480 97 5560 98 1 72-119/2787-61-6 1,2,3-Trichlorobenzene 6.2 U b 5660 6500 115 6330 112 3 62-116/3396-18-4 1,2,3-Trichloropropane 6.2 U b 5660 5700 101 5660 100 1 68-118/31120-82-1 1,2,4-Trichlorobenzene 450 U 5660 6460 114 6220 110 4 58-122/3495-63-6 1,2,4-Trimethylbenzene 6.2 U b 5660 6190 109 5920 105 4 61-119/30108-67-8 1,3,5-Trimethylbenzene 6.2 U b 5660 6190 109 5850 103 6 53-123/30127-18-4 Tetrachloroethylene 6.2 U b 5660 6270 111 6020 106 4 64-130/28108-88-3 Toluene 6.2 U b 5660 6000 106 5800 102 3 67-119/2879-01-6 Trichloroethylene 6.2 U b 5660 5670 100 5390 95 5 70-122/2775-69-4 Trichlorofluoromethane 6.2 U b 5660 4760 84 4330 76 9 41-137/3975-01-4 Vinyl chloride 6.2 U b 5660 5080 90 4680 83 8 43-120/381330-20-7 Xylene (total) 1400 U 17000 17800 105 17100 101 4 62-120/27

m,p-Xylene 12 U b 11300 11900 105 11400 101 4 62-120/2895-47-6 o-Xylene 6.2 U b 5660 5860 104 5660 100 3 62-121/28

CAS No. Surrogate Recoveries MS MSD TC42188-1 TC42188-1 Limits

1868-53-7 Dibromofluoromethane 84% 84% 79% 59-126%2037-26-5 Toluene-D8 105% 106% 102% 70-139%


53 of 76TC42161

66.3.1




TC42161-1, TC42161-2, TC42161-3, TC42161-4

CAS No. Surrogate Recoveries MS MSD TC42188-1 TC42188-1 Limits

460-00-4 4-Bromofluorobenzene 102% 100% 100% 63-138%17060-07-0 1,2-Dichloroethane-D4 85% 83% 77% 54-123%

(a) Sample used for QC purposes only.(b) Result is from Run #2.


54 of 76TC42161

66.3.1


GC/MS Semi-volatiles

QC Data Summaries


• Method Blank Summaries• Blank Spike Summaries• Matrix Spike and Duplicate Summaries

Gulf Coast

Section 7

55 of 76TC42161

7


Sample File ID DF Analyzed By Prep Date Prep Batch Analytical BatchOP31117-MB W18751.D 1 01/13/14 GJ 01/13/14 OP31117 EW982

The QC reported here applies to the following samples: Method: SW846 8270D

TC42161-1, TC42161-2, TC42161-3, TC42161-4


65-85-0 Benzoic acid ND 830 270 ug/kg95-57-8 2-Chlorophenol ND 170 74 ug/kg59-50-7 4-Chloro-3-methyl phenol ND 170 140 ug/kg120-83-2 2,4-Dichlorophenol ND 170 86 ug/kg105-67-9 2,4-Dimethylphenol ND 170 71 ug/kg51-28-5 2,4-Dinitrophenol ND 830 270 ug/kg534-52-1 4,6-Dinitro-o-cresol ND 330 35 ug/kg95-48-7 2-Methylphenol ND 170 65 ug/kg

3&4-Methylphenol ND 170 59 ug/kg88-75-5 2-Nitrophenol ND 170 81 ug/kg100-02-7 4-Nitrophenol ND 830 240 ug/kg87-86-5 Pentachlorophenol ND 830 330 ug/kg108-95-2 Phenol ND 170 88 ug/kg95-95-4 2,4,5-Trichlorophenol ND 170 81 ug/kg88-06-2 2,4,6-Trichlorophenol ND 170 81 ug/kg83-32-9 Acenaphthene ND 170 87 ug/kg208-96-8 Acenaphthylene ND 170 85 ug/kg62-53-3 Aniline ND 830 49 ug/kg120-12-7 Anthracene ND 170 81 ug/kg92-87-5 Benzidine ND 6700 3200 ug/kg56-55-3 Benzo(a)anthracene ND 170 83 ug/kg50-32-8 Benzo(a)pyrene ND 170 80 ug/kg205-99-2 Benzo(b)fluoranthene ND 170 87 ug/kg191-24-2 Benzo(g,h,i)perylene ND 170 76 ug/kg207-08-9 Benzo(k)fluoranthene ND 170 84 ug/kg101-55-3 4-Bromophenyl phenyl ether ND 170 70 ug/kg85-68-7 Butyl benzyl phthalate ND 170 33 ug/kg100-51-6 Benzyl Alcohol ND 170 67 ug/kg91-58-7 2-Chloronaphthalene ND 170 98 ug/kg106-47-8 4-Chloroaniline ND 170 77 ug/kg86-74-8 Carbazole ND 170 88 ug/kg218-01-9 Chrysene ND 170 87 ug/kg111-91-1 bis(2-Chloroethoxy)methane ND 170 70 ug/kg111-44-4 bis(2-Chloroethyl)ether ND 170 68 ug/kg108-60-1 bis(2-Chloroisopropyl)ether ND 170 68 ug/kg7005-72-3 4-Chlorophenyl phenyl ether ND 170 35 ug/kg

56 of 76TC42161

77.1.1




TC42161-1, TC42161-2, TC42161-3, TC42161-4


95-50-1 1,2-Dichlorobenzene ND 170 68 ug/kg122-66-7 1,2-Diphenylhydrazine ND 170 74 ug/kg541-73-1 1,3-Dichlorobenzene ND 170 70 ug/kg106-46-7 1,4-Dichlorobenzene ND 170 68 ug/kg121-14-2 2,4-Dinitrotoluene ND 170 82 ug/kg606-20-2 2,6-Dinitrotoluene ND 170 90 ug/kg91-94-1 3,3'-Dichlorobenzidine ND 330 88 ug/kg53-70-3 Dibenzo(a,h)anthracene ND 170 78 ug/kg132-64-9 Dibenzofuran ND 170 83 ug/kg84-74-2 Di-n-butyl phthalate ND 170 89 ug/kg117-84-0 Di-n-octyl phthalate ND 170 33 ug/kg84-66-2 Diethyl phthalate ND 170 85 ug/kg131-11-3 Dimethyl phthalate ND 170 67 ug/kg117-81-7 bis(2-Ethylhexyl)phthalate ND 170 83 ug/kg206-44-0 Fluoranthene ND 170 81 ug/kg86-73-7 Fluorene ND 170 88 ug/kg118-74-1 Hexachlorobenzene ND 170 71 ug/kg87-68-3 Hexachlorobutadiene ND 170 65 ug/kg77-47-4 Hexachlorocyclopentadiene ND 830 78 ug/kg67-72-1 Hexachloroethane ND 170 65 ug/kg193-39-5 Indeno(1,2,3-cd)pyrene ND 170 74 ug/kg78-59-1 Isophorone ND 170 71 ug/kg90-12-0 1-Methylnaphthalene ND 170 82 ug/kg91-57-6 2-Methylnaphthalene ND 170 79 ug/kg88-74-4 2-Nitroaniline ND 170 80 ug/kg99-09-2 3-Nitroaniline ND 170 81 ug/kg100-01-6 4-Nitroaniline ND 330 88 ug/kg91-20-3 Naphthalene ND 170 75 ug/kg98-95-3 Nitrobenzene ND 170 65 ug/kg62-75-9 n-Nitrosodimethylamine ND 170 61 ug/kg621-64-7 N-Nitroso-di-n-propylamine ND 170 59 ug/kg86-30-6 N-Nitrosodiphenylamine ND 170 33 ug/kg85-01-8 Phenanthrene ND 170 84 ug/kg129-00-0 Pyrene ND 170 87 ug/kg110-86-1 Pyridine ND 170 99 ug/kg120-82-1 1,2,4-Trichlorobenzene ND 170 74 ug/kg

57 of 76TC42161

77.1.1




TC42161-1, TC42161-2, TC42161-3, TC42161-4



CAS No. Tentatively Identified Compounds R.T. Est. Conc. Units Q

79-00-5 Ethane, 1,1,2-trichloro- 2.73 150 ug/kg JN79-34-5 Ethane, 1,1,2,2-tetrachloro- 3.92 310 ug/kg JN

Total TIC, Semi-Volatile 460 ug/kg J

58 of 76TC42161

77.1.1


Sample File ID DF Analyzed By Prep Date Prep Batch Analytical BatchOP31117-BS W18752.D 1 01/13/14 GJ 01/13/14 OP31117 EW982


TC42161-1, TC42161-2, TC42161-3, TC42161-4


65-85-0 Benzoic acid 1670 773 46 10-12295-57-8 2-Chlorophenol 1670 1080 65 49-10659-50-7 4-Chloro-3-methyl phenol 3330 2060 62 35-116120-83-2 2,4-Dichlorophenol 1670 1110 67 53-107105-67-9 2,4-Dimethylphenol 1670 1160 70 51-10951-28-5 2,4-Dinitrophenol 1670 1080 65 30-125534-52-1 4,6-Dinitro-o-cresol 1670 1100 66 41-12595-48-7 2-Methylphenol 1670 1100 66 46-105

3&4-Methylphenol 1670 1020 61 43-12088-75-5 2-Nitrophenol 1670 996 60 49-104100-02-7 4-Nitrophenol 1670 1540 92 29-12987-86-5 Pentachlorophenol 1670 1200 72 36-122108-95-2 Phenol 1670 1120 67 48-11795-95-4 2,4,5-Trichlorophenol 1670 1280 77 57-11688-06-2 2,4,6-Trichlorophenol 1670 1150 69 54-11283-32-9 Acenaphthene 1670 1110 67 52-109208-96-8 Acenaphthylene 1670 1190 71 54-11562-53-3 Aniline 3330 2040 61 28-116120-12-7 Anthracene 1670 1170 70 57-11492-87-5 Benzidine 16700 7340 44 15-15656-55-3 Benzo(a)anthracene 1670 1250 75 59-11450-32-8 Benzo(a)pyrene 1670 1380 83 53-106205-99-2 Benzo(b)fluoranthene 1670 1440 86 54-115191-24-2 Benzo(g,h,i)perylene 1670 1490 89 44-127207-08-9 Benzo(k)fluoranthene 1670 1390 83 52-124101-55-3 4-Bromophenyl phenyl ether 1670 1190 71 51-11685-68-7 Butyl benzyl phthalate 1670 1280 77 52-117100-51-6 Benzyl Alcohol 1670 1050 63 52-10491-58-7 2-Chloronaphthalene 1670 1260 76 47-125106-47-8 4-Chloroaniline 1670 1090 65 38-11386-74-8 Carbazole 1670 1190 71 53-113218-01-9 Chrysene 1670 1310 79 62-117111-91-1 bis(2-Chloroethoxy)methane 1670 1030 62 41-106111-44-4 bis(2-Chloroethyl)ether 1670 1070 64 36-108108-60-1 bis(2-Chloroisopropyl)ether 1670 1040 62 33-1117005-72-3 4-Chlorophenyl phenyl ether 1670 1110 67 52-113


59 of 76TC42161

77.2.1




TC42161-1, TC42161-2, TC42161-3, TC42161-4


95-50-1 1,2-Dichlorobenzene 1670 996 60 41-106122-66-7 1,2-Diphenylhydrazine 1670 1250 75 51-113541-73-1 1,3-Dichlorobenzene 1670 983 59 39-104106-46-7 1,4-Dichlorobenzene 1670 993 60 40-105121-14-2 2,4-Dinitrotoluene 1670 1160 70 55-117606-20-2 2,6-Dinitrotoluene 1670 1150 69 56-11291-94-1 3,3'-Dichlorobenzidine 1670 1200 72 33-12953-70-3 Dibenzo(a,h)anthracene 1670 1450 87 47-126132-64-9 Dibenzofuran 1670 1110 67 51-11284-74-2 Di-n-butyl phthalate 1670 1230 74 54-117117-84-0 Di-n-octyl phthalate 1670 1510 91 47-11984-66-2 Diethyl phthalate 1670 1160 70 53-114131-11-3 Dimethyl phthalate 1670 1160 70 55-111117-81-7 bis(2-Ethylhexyl)phthalate 1670 1310 79 51-123206-44-0 Fluoranthene 1670 1190 71 54-11886-73-7 Fluorene 1670 1150 69 55-114118-74-1 Hexachlorobenzene 1670 1160 70 51-11787-68-3 Hexachlorobutadiene 1670 936 56 37-11177-47-4 Hexachlorocyclopentadiene 1670 771 46 10-12167-72-1 Hexachloroethane 1670 1000 60 42-100193-39-5 Indeno(1,2,3-cd)pyrene 1670 1370 82 45-12978-59-1 Isophorone 1670 1130 68 47-10290-12-0 1-Methylnaphthalene 1670 1010 61 50-10691-57-6 2-Methylnaphthalene 1670 1030 62 45-10488-74-4 2-Nitroaniline 1670 1220 73 46-12199-09-2 3-Nitroaniline 1670 986 59 33-107100-01-6 4-Nitroaniline 1670 1000 60 52-11091-20-3 Naphthalene 1670 1010 61 47-10898-95-3 Nitrobenzene 1670 1020 61 45-10562-75-9 n-Nitrosodimethylamine 1670 1070 64 33-103621-64-7 N-Nitroso-di-n-propylamine 1670 1080 65 42-11086-30-6 N-Nitrosodiphenylamine 3330 2200 66 37-11485-01-8 Phenanthrene 1670 1210 73 57-116129-00-0 Pyrene 1670 1240 74 52-120110-86-1 Pyridine 3330 1800 54 17-105120-82-1 1,2,4-Trichlorobenzene 1670 978 59 40-101


60 of 76TC42161

77.2.1




TC42161-1, TC42161-2, TC42161-3, TC42161-4




61 of 76TC42161

77.2.1


Sample File ID DF Analyzed By Prep Date Prep Batch Analytical BatchOP31117-MS W18754.D 1 01/13/14 GJ 01/13/14 OP31117 EW982OP31117-MSD W18755.D 1 01/13/14 GJ 01/13/14 OP31117 EW982TC42188-1 W18753.D 1 01/13/14 GJ 01/13/14 OP31117 EW982


TC42161-1, TC42161-2, TC42161-3, TC42161-4


65-85-0 Benzoic acid 1400 U 2820 564 20 611 22 8 10-122/4095-57-8 2-Chlorophenol 280 U 2820 1950 69 1960 70 1 49-106/3659-50-7 4-Chloro-3-methyl phenol 280 U 5630 3440 61 3500 62 2 35-116/37120-83-2 2,4-Dichlorophenol 280 U 2820 1710 61 1740 62 2 53-107/37105-67-9 2,4-Dimethylphenol 280 U 2820 1990 71 2020 72 1 51-109/3551-28-5 2,4-Dinitrophenol 1400 U 2820 ND 0* ND 0* nc 30-125/43534-52-1 4,6-Dinitro-o-cresol 560 U 2820 472 17* 477 17* 1 41-125/3995-48-7 2-Methylphenol 280 U 2820 1970 70 1930 69 2 46-105/36

3&4-Methylphenol 280 U 2820 1780 63 1750 62 2 43-120/3488-75-5 2-Nitrophenol 280 U 2820 1780 63 1870 66 5 49-104/40100-02-7 4-Nitrophenol 1400 U 2820 1490 53 1690 60 13 29-129/4187-86-5 Pentachlorophenol 1400 U 2820 390 14* 320 11* 18 36-122/39108-95-2 Phenol 280 U 2820 1970 70 1940 69 2 48-117/3695-95-4 2,4,5-Trichlorophenol 280 U 2820 2040 72 2030 72 0 57-116/3788-06-2 2,4,6-Trichlorophenol 280 U 2820 1650 59 1600 57 3 54-112/3683-32-9 Acenaphthene 280 U 2820 1890 67 2030 72 7 52-109/35208-96-8 Acenaphthylene 280 U 2820 1990 71 2130 76 7 54-115/3362-53-3 Aniline 1400 U 5630 3730 66 3690 65 1 28-116/39120-12-7 Anthracene 280 U 2820 1910 68 2050 73 7 57-114/3592-87-5 Benzidine 11000 U 28200 13700 49 14000 50 2 15-156/4056-55-3 Benzo(a)anthracene 280 U 2820 1970 70 2130 76 8 59-114/3850-32-8 Benzo(a)pyrene 280 U 2820 2120 75 2320 82 9 53-106/37205-99-2 Benzo(b)fluoranthene 280 U 2820 2210 78 2370 84 7 54-115/40191-24-2 Benzo(g,h,i)perylene 280 U 2820 2260 80 2520 89 11 44-127/39207-08-9 Benzo(k)fluoranthene 280 U 2820 2120 75 2330 83 9 52-124/38101-55-3 4-Bromophenyl phenyl ether 280 U 2820 1910 68 2120 75 10 51-116/3585-68-7 Butyl benzyl phthalate 280 U 2820 2010 71 2160 77 7 52-117/36100-51-6 Benzyl Alcohol 280 U 2820 1880 67 1860 66 1 52-104/3791-58-7 2-Chloronaphthalene 280 U 2820 2200 78 2380 84 8 47-125/36106-47-8 4-Chloroaniline 280 U 2820 1910 68 1960 70 3 38-113/3686-74-8 Carbazole 280 U 2820 1970 70 2060 73 4 53-113/36218-01-9 Chrysene 280 U 2820 2060 73 2260 80 9 62-117/38111-91-1 bis(2-Chloroethoxy)methane 280 U 2820 1780 63 1830 65 3 41-106/35111-44-4 bis(2-Chloroethyl)ether 280 U 2820 1990 71 2010 71 1 36-108/37108-60-1 bis(2-Chloroisopropyl)ether 280 U 2820 1910 68 1930 69 1 33-111/397005-72-3 4-Chlorophenyl phenyl ether 280 U 2820 1840 65 1940 69 5 52-113/34


62 of 76TC42161

77.3.1




TC42161-1, TC42161-2, TC42161-3, TC42161-4


95-50-1 1,2-Dichlorobenzene 280 U 2820 1760 62 1860 66 6 41-106/38122-66-7 1,2-Diphenylhydrazine 280 U 2820 2050 73 2250 80 9 51-113/34541-73-1 1,3-Dichlorobenzene 280 U 2820 1710 61 1810 64 6 39-104/39106-46-7 1,4-Dichlorobenzene 280 U 2820 1720 61 1820 65 6 40-105/39121-14-2 2,4-Dinitrotoluene 280 U 2820 1940 69 2000 71 3 55-117/37606-20-2 2,6-Dinitrotoluene 280 U 2820 1930 69 2020 72 5 56-112/3691-94-1 3,3'-Dichlorobenzidine 560 U 2820 1840 65 2030 72 10 33-129/3953-70-3 Dibenzo(a,h)anthracene 280 U 2820 2230 79 2480 88 11 47-126/38132-64-9 Dibenzofuran 280 U 2820 1860 66 2010 71 8 51-112/3484-74-2 Di-n-butyl phthalate 280 U 2820 1990 71 2090 74 5 54-117/36117-84-0 Di-n-octyl phthalate 280 U 2820 2350 83 2590 92 10 47-119/4084-66-2 Diethyl phthalate 280 U 2820 1910 68 2000 71 5 53-114/36131-11-3 Dimethyl phthalate 280 U 2820 1940 69 2030 72 5 55-111/34117-81-7 bis(2-Ethylhexyl)phthalate 280 U 2820 2240 80 2490 88 11 51-123/40206-44-0 Fluoranthene 280 U 2820 1950 69 2010 71 3 54-118/3986-73-7 Fluorene 280 U 2820 1910 68 2030 72 6 55-114/37118-74-1 Hexachlorobenzene 280 U 2820 1920 68 2110 75 9 51-117/3787-68-3 Hexachlorobutadiene 280 U 2820 1620 58 1770 63 9 37-111/3877-47-4 Hexachlorocyclopentadiene 1400 U 2820 980 35 1220 43 22 10-121/4567-72-1 Hexachloroethane 280 U 2820 1720 61 1870 66 8 42-100/41193-39-5 Indeno(1,2,3-cd)pyrene 280 U 2820 2130 76 2390 85 12 45-129/3878-59-1 Isophorone 280 U 2820 1960 70 2000 71 2 47-102/3590-12-0 1-Methylnaphthalene 280 U 2820 1770 63 1950 69 10 50-106/3891-57-6 2-Methylnaphthalene 280 U 2820 1820 65 2030 72 11 45-104/3788-74-4 2-Nitroaniline 280 U 2820 2080 74 2180 77 5 46-121/4099-09-2 3-Nitroaniline 280 U 2820 1430 51 1380 49 4 33-107/37100-01-6 4-Nitroaniline 560 U 2820 1750 62 1690 60 3 52-110/3691-20-3 Naphthalene 280 U 2820 1830 65 2030 72 10 47-108/3498-95-3 Nitrobenzene 280 U 2820 1830 65 1910 68 4 45-105/3662-75-9 n-Nitrosodimethylamine 280 U 2820 1850 66 2040 72 10 33-103/39621-64-7 N-Nitroso-di-n-propylamine 280 U 2820 1940 69 1920 68 1 42-110/3686-30-6 N-Nitrosodiphenylamine 280 U 5630 3600 64 3940 70 9 37-114/3585-01-8 Phenanthrene 280 U 2820 1970 70 2140 76 8 57-116/42129-00-0 Pyrene 280 U 2820 1950 69 2160 77 10 52-120/40110-86-1 Pyridine 280 U 5630 3060 54 3350 59 9 17-105/43120-82-1 1,2,4-Trichlorobenzene 280 U 2820 1700 60 1830 65 7 40-101/36


63 of 76TC42161

77.3.1




TC42161-1, TC42161-2, TC42161-3, TC42161-4

CAS No. Surrogate Recoveries MS MSD TC42188-1 Limits

367-12-4 2-Fluorophenol 74% 74% 66% 26-124%4165-62-2 Phenol-d5 78% 77% 76% 19-106%118-79-6 2,4,6-Tribromophenol 61% 60% 59% 18-129%4165-60-0 Nitrobenzene-d5 66% 67% 62% 18-104%321-60-8 2-Fluorobiphenyl 68% 71% 61% 21-114%1718-51-0 Terphenyl-d14 73% 81% 74% 24-149%


64 of 76TC42161

77.3.1


Metals Analysis

QC Data Summaries


• Method Blank Summaries• Matrix Spike and Duplicate Summaries• Blank Spike and Lab Control Sample Summaries• Serial Dilution Summaries• Metals CCB MDL Check

Gulf Coast

Section 8

65 of 76TC42161

8

BLANK RESULTS SUMMARY Part 2 - Method Blanks

Login Number: TC42161 Account: IKONTXH - IKON Environmental Solutions

Project: CES Environmental / 4904 Griggs Houston TX

QC Batch ID: MP22462 Methods: SW846 7471A Matrix Type: SOLID Units: mg/kg

Prep Date: 01/10/14

MB Metal RL IDL MDL raw final

Mercury 0.033 .0082 .013 -0.0055 <0.033

Associated samples MP22462: TC42161-1, TC42161-2, TC42161-3, TC42161-4

Results < IDL are shown as zero for calculation purposes(*) Outside of QC limits(anr) Analyte not requested

_________________________________________________________________________________________________________

Page 1

66 of 76TC42161

88.1.1

MATRIX SPIKE AND DUPLICATE RESULTS SUMMARY




Prep Date: 01/10/14

TC42161-1 Spikelot QC Metal Original MS HGTXWS1 % Rec Limits

Mercury 0.063 0.69 0.614 102.2 75-125


Results < IDL are shown as zero for calculation purposes(*) Outside of QC limits(N) Matrix Spike Rec. outside of QC limits(anr) Analyte not requested

_________________________________________________________________________________________________________

Page 1

67 of 76TC42161

88.1.2





Prep Date: 01/10/14

TC42161-1 Spikelot MSD QC Metal Original MSD HGTXWS1 % Rec RPD Limit

Mercury 0.063 0.65 0.594 98.8 6.0 20


Results < IDL are shown as zero for calculation purposes(*) Outside of QC limits(N) Matrix Spike Rec. outside of QC limits(anr) Analyte not requested

_________________________________________________________________________________________________________

Page 2

68 of 76TC42161

88.1.2

SPIKE BLANK AND LAB CONTROL SAMPLE SUMMARY




Prep Date: 01/10/14

LCS Spikelot QC Metal Result HGLCD060 % Rec Limits

Mercury 16.8 19.9 84.4 69-130



_________________________________________________________________________________________________________

Page 1

69 of 76TC42161

88.1.3

BLANK RESULTS SUMMARY Part 2 - Method Blanks



QC Batch ID: MP22463 Methods: SW846 6010B Matrix Type: SOLID Units: mg/kg

Prep Date: 01/10/14

MB Metal RL IDL MDL raw final

Aluminum 10 .35 .73

Antimony 0.25 .028 .085

Arsenic 0.25 .05 .085 -0.20 <0.25

Barium 10 .008 .069 -0.0075 <10

Beryllium 0.20 .005 .0055

Boron 5.0 .02 .17

Cadmium 0.20 .0075 .014 0.0090 <0.20

Calcium 250 .2 1.3

Chromium 0.50 .011 .023 0.027 <0.50

Cobalt 2.5 .013 .03

Copper 1.0 .012 .056

Iron 5.0 .23 1.1

Lead 0.15 .033 .05 -0.015 <0.15

Lithium 15 .033 .045

Magnesium 250 .38 1.3

Manganese 0.75 .0045 .037

Molybdenum 0.50 .031 .025

Nickel 2.0 .011 .057

Potassium 250 .38 10

Selenium 0.25 .06 .14 0.17 <0.25

Silver 0.50 .01 .058 0.0035 <0.50

Sodium 250 .29 1.6

Sulfur 2.5 .41

Strontium 0.50 .0035 .059

Thallium 0.50 .042 .04

Tin 1.0 .034 .035

Titanium 1.0 .0095 .029

Vanadium 2.5 .009 .034

Zinc 1.0 .0065 .084



_________________________________________________________________________________________________________

Page 1

70 of 76TC42161

88.2.1





Prep Date: 01/10/14

TC42161-1 Spikelot QC Metal Original MS MPTW11 % Rec Limits

Aluminum anr

Antimony anr

Arsenic 8.4 29.8 25.9 92.0 75-125

Barium 783 561 25.9 -857.8(a 75-125

Beryllium anr

Boron

Cadmium 0.14 22.9 25.9 87.9 75-125

Calcium

Chromium 24.5 48.2 25.9 91.6 75-125

Cobalt anr

Copper anr

Iron anr

Lead 58.7 89.9 25.9 120.6 75-125

Lithium

Magnesium

Manganese anr

Molybdenum anr

Nickel anr

Potassium

Selenium 0.0 24.3 25.9 93.9 75-125

Silver 0.0 21.7 25.9 83.8 75-125

Sodium

Sulfur

Strontium

Thallium anr

Tin

Titanium anr

Vanadium anr

Zinc anr


Results < IDL are shown as zero for calculation purposes(*) Outside of QC limits(N) Matrix Spike Rec. outside of QC limits(anr) Analyte not requested(a) Spike amount low relative to the sample amount. Refer to lab control or spike blank for recovery

information._________________________________________________________________________________________________________

Page 1

71 of 76TC42161

88.2.2





Prep Date: 01/10/14

TC42161-1 Spikelot MSD QC Metal Original MSD MPTW11 % Rec RPD Limit

Aluminum anr

Antimony anr

Arsenic 8.4 29.3 25.8 90.3 11.2 20

Barium 783 476 25.8 -1189.9a 16.4 20

Beryllium anr

Boron

Cadmium 0.14 22.2 25.8 85.5 3.1 20

Calcium

Chromium 24.5 47.1 25.8 87.6 2.3 20

Cobalt anr

Copper anr

Iron anr

Lead 58.7 76.9 25.8 70.5N(b) 15.6 20

Lithium

Magnesium

Manganese anr

Molybdenum anr

Nickel anr

Potassium

Selenium 0.0 22.8 25.8 88.4 14.1 20

Silver 0.0 21.1 25.8 81.8 2.8 20

Sodium

Sulfur

Strontium

Thallium anr

Tin

Titanium anr

Vanadium anr

Zinc anr


Results < IDL are shown as zero for calculation purposes(*) Outside of QC limits(N) Matrix Spike Rec. outside of QC limits(anr) Analyte not requested(a) Spike amount low relative to the sample amount. Refer to lab control or spike blank for recovery

information._________________________________________________________________________________________________________

Page 2

72 of 76TC42161

88.2.2





Prep Date:

Metal

(b) Spike recovery indicates possible matrix interference or sample non-homogeneity.

_________________________________________________________________________________________________________

Page 3

73 of 76TC42161

88.2.2

SPIKE BLANK AND LAB CONTROL SAMPLE SUMMARY




Prep Date: 01/10/14

LCS Spikelot QC Metal Result MPLCD061 % Rec Limits

Aluminum anr

Antimony anr

Arsenic 97.5 99.6 97.9 81-119

Barium 300 310 96.8 83-117

Beryllium anr

Boron

Cadmium 172 182 94.5 82-118

Calcium

Chromium 124 136 91.2 80-121

Cobalt anr

Copper anr

Iron anr

Lead 113 115 98.3 82-119

Lithium

Magnesium

Manganese anr

Molybdenum anr

Nickel anr

Potassium

Selenium 149 150 99.3 77-123

Silver 36.8 40.4 91.1 75-125

Sodium

Sulfur

Strontium

Thallium anr

Tin

Titanium anr

Vanadium anr

Zinc anr



_________________________________________________________________________________________________________

Page 1

74 of 76TC42161

88.2.3

SERIAL DILUTION RESULTS SUMMARY



QC Batch ID: MP22463 Methods: SW846 6010B Matrix Type: SOLID Units: ug/l

Prep Date: 01/10/14

TC42161-1 QC Metal Original SDL 1:5 %DIF Limits

Aluminum anr

Antimony anr

Arsenic 129 70.6 24.0*(a) 0-10

Barium 12000 13400 11.0*(a) 0-10

Beryllium anr

Boron

Cadmium 2.11 2.25 6.6 0-10

Calcium

Chromium 377 458 21.6*(a) 0-10

Cobalt anr

Copper anr

Iron anr

Lead 902 859 4.8 0-10

Lithium

Magnesium

Manganese anr

Molybdenum anr

Nickel anr

Potassium

Selenium 0.00 73.7 NC 0-10

Silver 0.00 0.00 NC 0-10

Sodium

Sulfur

Strontium

Thallium anr

Tin

Titanium anr

Vanadium anr

Zinc anr


Results < IDL are shown as zero for calculation purposes(*) Outside of QC limits(anr) Analyte not requested(a) Serial dilution indicates possible matrix interference.

_________________________________________________________________________________________________________

Page 1

75 of 76TC42161

88.2.4

Metals CCB MDL Check Page 1 of 1 Job Number: TC42161Account: IKONTXH IKON Environmental SolutionsProject: CES Environmental / 4904 Griggs Houston TX

The following elements are braketed by CCB's at or above the MDL.

Sample Element Run ID Time MDL Units CCB Before CCB After

TC42161-1 Arsenic MA9187 16:26 1.7 ug/l CCB3 -3.0 CCB4 -1.1TC42161-2 Cadmium MA9187 17:25 .28 ug/l CCB4 0.15 CCB5 0.29TC42161-3 Cadmium MA9187 17:45 .28 ug/l CCB4 0.15 CCB5 0.29TC42161-4 Cadmium MA9187 17:52 .28 ug/l CCB4 0.15 CCB5 0.29TC42161-2 Selenium MA9187 17:25 2.9 ug/l CCB4 2.6 CCB5 3.0TC42161-3 Selenium MA9187 17:45 2.9 ug/l CCB4 2.6 CCB5 3.0TC42161-4 Selenium MA9187 17:52 2.9 ug/l CCB4 2.6 CCB5 3.0

Calibration blank validation to the MDL is not a method requirement, but is included for information purposes only.

76 of 76TC42161

88.3