ardrox 666 - sil-mid · ardrox 666 version: 4.0 revision date 17.11.2011 print date 17.11.2011 1 /...

SAFETY DATA SHEETaccording to Regulation (EC) No. 1907/2006

Ardrox 666

Version: 4.0 Revision Date 17.11.2011 Print Date 17.11.2011

1 / 21- EN

1. Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier

Trade name : Ardrox 666

1.2 Relevant identified uses of the substance or mixture and uses advised against

Use of the Sub-stance/Mixture

: Paint stripper

Recommended restrictionson use

: Contains dichloromethane; Restricted to industrial use and toprofessionals approved in certain EU Member States – verifywhere use is allowed.

1.3 Details of the supplier of the safety data sheet

Company : Chemetall LtdDenbigh RoadBletchley Milton Keynes MK1 1PB

Telephone : 01908 649333Telefax : 01908 373939

Contact person product safetyTelephone : +49(0)6971652832E-mail address : [email protected]

1.4 Emergency telephone number

Emergency telephonenumber

: 01908 649333

2. Hazards identification

2.1 Classification of the substance or mixture

Classification (REGULATION (EC) No 1272/2008)

Acute toxicity, Category 4 H302: Harmful if swallowed.Acute toxicity, Category 3 H311: Toxic in contact with skin.Skin corrosion, Category 1B H314: Causes severe skin burns and eye damage.Germ cell mutagenicity, Category 1B H340: May cause genetic defects.Carcinogenicity, Category 1A H350: May cause cancer.Specific target organ toxicity - single ex-posure, Category 3

H335: May cause respiratory irritation.

H336: May cause drowsiness or dizziness.Specific target organ toxicity - repeatedexposure, Category 2

H373: May cause damage to organs through pro-longed or repeated exposure if swallowed.

Chronic aquatic toxicity, Category 3 H412: Harmful to aquatic life with long lasting ef-fects.


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Classification (67/548/EEC, 1999/45/EC)

Carcinogenic Category 1 R45: May cause cancer.toxic R24/25: Toxic in contact with skin and if swallowed.Mutagenic Category 2 R46: May cause heritable genetic damage.Corrosive R34: Causes burns.Harmful R48/22: Harmful: danger of serious damage to

health by prolonged exposure if swallowed.R20: Harmful by inhalation.

Irritant R37: Irritating to respiratory system.Dangerous for the environment R51/53: Toxic to aquatic organisms, may cause

long-term adverse effects in the aquatic environ-ment.

2.2 Label elements

Labelling (REGULATION (EC) No 1272/2008)

Hazard pictograms :

Signal word : Danger

Hazard statements : H302 Harmful if swallowed.H311 Toxic in contact with skin.H314 Causes severe skin burns and eye damage.H335 + H336 May cause respiratory irritation, and

drowsiness or dizziness.H340 May cause genetic defects.H350 May cause cancer.H373 May cause damage to organs through pro-

longed or repeated exposure if swallowed.H412 Harmful to aquatic life with long lasting ef-

fects.

Precautionary statements : Prevention:P201 Obtain special instructions before use.P260 Do not breathe dust/ fume/ gas/ mist/ va-

pours/ spray.P262 Do not get in eyes, on skin, or on clothing.P280 Wear protective gloves/ protective clothing/

eye protection/ face protection.P273 Avoid release to the environment.Response:P303 + P361 + P353 IF ON SKIN (or hair): Remove/ Take

off immediately all contaminated clothing.Rinse skin with water/ shower.

P305 + P351 + P338 IF IN EYES: Rinse cautiously with wa-ter for several minutes. Remove contact


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lenses, if present and easy to do. Continuerinsing.

P308 IF exposed or concerned:P310 Immediately call a POISON CENTER or

doctor/ physician.Disposal:P501 Dispose of contents/ container to an ap-

proved waste disposal plant.

Hazardous components which must be listed on the label: 75-09-2 Dichloromethane; Methylene Chloride

1319-77-3 Cresol

1333-82-0 Chromium trioxide

Additional Labelling:

EUH208 Contains: Chromium trioxide May produce an allergic reaction.

Restricted to professional users.

Labelling according to EC Directives (1999/45/EC)

Hazard pictograms :

Toxic Dangerousfor the envi-ronment

R-phrase(s) : R45 May cause cancer.R46 May cause heritable genetic damage.R20 Also harmful by inhalation.R24/25 Also toxic in contact with skin and if swal-

lowed.R48/22 Also harmful: danger of serious damage to

health by prolonged exposure if swallowed.R34 Causes burns.R37 Irritating to respiratory system.R51/53 Toxic to aquatic organisms, may cause

long-term adverse effects in the aquaticenvironment.

S-phrase(s) : S53 Avoid exposure - obtain special instruc-tions before use.

S23 Do not breathe gas/fumes/vapour/spray.S24/25 Avoid contact with skin and eyes.S26 In case of contact with eyes, rinse immedi-

ately with plenty of water and seek medical


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advice.S36/37/39 Wear suitable protective clothing, gloves

and eye/face protection.S45 In case of accident or if you feel unwell,

seek medical advice immediately (showthe label where possible).

S60 This material and its container must bedisposed of as hazardous waste.

S61 Avoid release to the environment. Refer tospecial instructions/ Safety data sheets.

Hazardous components which must be listed on the label: 75-09-2 Dichloromethane; Methylene Chloride

1319-77-3 Cresol

1310-58-3 Potassium Hydroxide

1333-82-0 Chromium trioxide

Special labelling of certainmixtures

: Restricted to professional users.

Sensitising components : Chromium trioxideMay produce an allergic reaction.

2.3 Other hazards

The information required is contained in this Material Safety Data Sheet.

3. Composition/information on ingredients

3.1 Substances

Identification: Ardrox 6663.2 Mixtures

Chemical nature : Mixture of organic solvents.

Hazardous components

Chemical Name CAS-No.EC-No.

Registration num-ber

Classification(67/548/EEC)

Classification(REGULATION

(EC) No1272/2008)

Concentration[%]

Dichloromethane; Me-thylene Chloride

75-09-2200-838-901-2119480404-41

Carc.Cat.3; R40

Xn; R48/22

Xi; R36/37/38

R67

Carc. 2; H351

STOT RE 2;H373

Eye Irrit. 2;H319

STOT SE 3;

>= 50 - < 65


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H335, H336

Skin Irrit. 2;H315

Cresol 1319-77-3215-293-2

T; R24/25

C; R34

T; R24/25

C; R34

Nota CNota C

Acute Tox. 3;H311

Acute Tox. 3;H301

Skin Corr. 1B;H314

>= 10 - < 25

Solvent naphtha (petro-leum), light arom.; Lowboiling point naphtha -unspecified

64742-95-6265-199-0

R10

Xi; R37

Xn; R65

N; R51/53

R66

R67

Aquatic Chronic2; H411

STOT SE 3;H335

Flam. Liq. 3;H226

Asp. Tox. 1;H304

STOT SE 3;H336

>= 2.5 - < 10

Xylenol 1300-71-6215-089-3

T; R24/25

C; R34

N; R51-R53

Nota C

Acute Tox. 3;H311

Acute Tox. 3;H301

Skin Corr. 1B;H314


>= 1 - < 2.5

Potassium Hydroxide 1310-58-3215-181-31-2119487136-33

C; R35

Xn; R22

Acute Tox. 4;H302

>= 0.5 - < 1


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Skin Corr. 1A;H314

Phenol 108-95-2203-632-7

Mut.Cat.3; R68

T; R23/24/25

C; R34

Xn; R48/20/21/22

Muta. 2; H341

Acute Tox. 3;H331

Acute Tox. 3;H311

Acute Tox. 3;H301

STOT RE 2;H373

Skin Corr. 1B;H314

>= 0.1 - < 1

Chromium trioxide 1333-82-0215-607-801-2119458868-17

O; R 9

Carc.Cat.1; R45

Repr.Cat.3; R62

Mut.Cat.2; R46

T+; R26

T; R24/25-R48/23

C; R35

R42/43

N; R50-R53

Nota E

Ox. Sol. 1;H271

Carc. 1A; H350

Muta. 1B; H340

Repr. 2; H361f

Acute Tox. 2;H330

Acute Tox. 3;H311

Acute Tox. 3;H301

STOT RE 1;H372

Skin Corr. 1A;H314

Resp. Sens. 1;H334

Skin Sens. 1;H317

>= 0.3 - < 1


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Aquatic Acute1; H400


For the full text of the R-phrases mentioned in this Section, see Section 16.For the full text of the H-Statements mentioned in this Section, see Section 16.For the full text of the Notas mentioned in this Section, see Section 16.

4. First aid measures

4.1 Description of first aid measures

General advice : First-aid crew: Ensure self-protection.Move out of dangerous area.Take off contaminated clothing and shoes immediately.

If inhaled : Move to fresh air.Consult a physician.

In case of skin contact : Wash off with soap and plenty of water.Consult a physician.

In case of eye contact : Rinse immediately with plenty of water, also under the eyelids.Consult a physician.

If swallowed : Rinse mouth with water.Do not induce vomiting without medical advice.Call a physician immediately.

4.2 Most important symptoms and effects, both acute and delayed

Symptoms : No information available.

Risks : corrosive effects

4.3 Indication of any immediate medical attention and special treatment needed

Treatment : Treat symptomatically.For specialist advice physicians should contact the PoisonsInformation Service.

5. Firefighting measures

5.1 Extinguishing media

Suitable extinguishing media : Carbon dioxide (CO2)


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Dry powderAlcohol-resistant foamWater spray

Unsuitable extinguishingmedia

: High volume water jet

5.2 Special hazards arising from the substance or mixture

Specific hazards during fire-fighting

: May form toxic gases on heating or in case of fire.Hydrogen chloride gasCarbon monoxidePhosgene

5.3 Advice for firefighters

Special protective equipmentfor firefighters

: In the event of fire, wear self-contained breathing apparatus.

Further information : Risk of bursting.Use water spray to cool unopened containers.

6. Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures

Personal precautions : Wear personal protective equipment.Evacuate personnel to safe areas.Ensure adequate ventilation.

6.2 Environmental precautions

Environmental precautions : Do not flush into surface water or sanitary sewer system.Avoid subsoil penetration.

6.3 Methods and materials for containment and cleaning up

Methods for cleaning up : Ensure adequate ventilation.Contenga el derrame. Absorba con material absorbente nocombustible (p.ej., arena, tierra, diatomita, vermiculita) y tra-sládelo a un contendedor adecuado para su eliminaciónsegún las normativas locales / nacionales (ver sección 13).Contain spillage, soak up with non-combustible absorbentmaterial, (e.g. sand, earth, diatomaceous earth, vermiculite)and transfer to a container for disposal according to local /national regulations (see section 13).

6.4 Reference to other sections

See chapter 8 and 13


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7. Handling and storage

7.1 Precautions for safe handling

Advice on safe handling : Provide sufficient air exchange and/or exhaust in work rooms.Have eye wash bottle or eye rinse ready at the work place.

Advice on protection againstfire and explosion

: Normal measures for preventive fire protection.

7.2 Conditions for safe storage, including any incompatibilities

Requirements for storageareas and containers

: Keep containers tightly closed in a dry, cool and well-ventilated place.

Storage temperature : 0 - 30 °C

7.3 Specific end uses

Specific use(s) : Paint stripper

8. Exposure controls/personal protection

8.1 Control parameters

Components CAS-No. ValueControl pa-rameters

Update Basis

Dichloro-methane;MethyleneChloride

75-09-2 TWA 100 ppm350 mg/m3

2007-08-01 GB EH40

Further informa-tion

: Sk: Can be absorbed through skin. The assigned substances are those for which there areconcerns that dermal absorption will lead to systemic toxicity.HSC/E plans to review the limit values for this substance.

75-09-2 STEL 300 ppm1,060 mg/m3

2007-08-01 GB EH40


: Sk: Can be absorbed through skin. The assigned substances are those for which there areconcerns that dermal absorption will lead to systemic toxicity.HSC/E plans to review the limit values for this substance.

Cresol 1319-77-3 TWA 5 ppm22 mg/m3

1991-07-05 91/322/EEC


: 6: Existing scientific data on health effects appear to be particularly limitedIndicative


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PotassiumHydroxide

1310-58-3 STEL 2 mg/m3 2005-04-06 GB EH40

Phenol 108-95-2 TWA 2 ppm 2005-04-06 GB EH40


: Sk: Can be absorbed through skin. The assigned substances are those for which there areconcerns that dermal absorption will lead to systemic toxicity.Where no specific short-term exposure limit is listed, a figure three times the long-term expo-sure should be used

108-95-2 TWA 2 ppm8 mg/m3

2009-12-19 2009/161/EU


: skin: Identifies the possibility of significant uptake through the skinIndicative

108-95-2 STEL 4 ppm16 mg/m3

2009-12-19 2009/161/EU


: skin: Identifies the possibility of significant uptake through the skinIndicative

Chromiumtrioxide

1333-82-0 TWA 0.05 mg/m3chromium

2007-08-01 GB EH40


: 68: Substances that can cause occupational asthma (also known as asthmagens and respira-tory sensitisers) can induce a state of specific airway hyper-responsiveness via an immunologi-cal, irritant or other mechanisms. Once the airways have become hyper-responsive, furtherexposure to the substance, sometimes even to tiny quantities, may cause respiratory symp-toms. These symptoms can range in severity from a runny nose to asthma. Not all workers whoare exposed to a sensitiser will become hyper-responsive and it is impossible to identify inadvance those who are likely to become hyper-responsive. . Substances that can cause occu-pational asthma are classified under the 'Chemicals (Hazard information and Packaging forsupply) Regulations (CHIP) ' and assigned the risk phrase 'R42 May cause sensitisation byinhalation' or 'R42/43 May cause sensitisation by inhalation and skin contact' in the 'Approvedsupply list'.Wherever it is reasonably practicable, exposure to substances that can cause occupational;asthma should be prevented. Where this is not possible, the primary aim is to apply adequatestandards of control to prevent workers from becoming hyper-responsive. For substances thatcan cause occupational asthma, COSHH requires that exposure be reduced to as low as isreasonably practicable. Activities giving rise to short-term peak concentrations should receiveparticular attention when risk management is being considered. Health surveillance is appropri-ate fro all employee's exposed or liable to be exposed to a substance which may cause occu-pational asthma and there should be appropriate consultation with an occupational healthprofessional over the degree of risk and level of surveillance.Capable of causing occupational asthma. The identified substances are those which: - areassigned the risk phrase 'R42: May cause sensitisation by inhalation'; or 'R42/43: May causesensitisation by inhalation and skin contact' or - are listed in section C of HSE publication'Asthmagen? Critical assessments of the evidence for agents implicated in occupationalasthma' as updated from time to time, or any other substance which the risk assessment hasshown to be a potential cause of occupational asthma.Capable of causing cancer and/or heritable genetic damage. The identified substances includethose which: - are assigned the risk phrases 'R45: May cause cancer'; 'R46: may cause herita-


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ble genetic damage'; 'R49: May cause cancer by inhalation' or - a substance or process listedin Schedule 1 of COSHH.Where no specific short-term exposure limit is listed, a figure three times the long-term expo-sure should be usedThe 'Sen' notation in the list of WELs has been assigned only to those substances which maycause occupational asthma in the listed categories.

chromium

8.2 Exposure controls

Engineering measures

Ensure adequate ventilation, especially in confined areas.

Personal protective equipment

Respiratory protection : In case of insufficient ventilation wear suitable respiratoryequipment.Recommended Filter type:AX-P3

Hand protection : Neoprene glovesbutyl-rubberProtective gloves complying with EN 374.Please observe the instructions regarding permeability andbreakthrough time which are provided by the supplier of thegloves. Also take into consideration the specific local condi-tions under which the product is used, such as the danger ofcuts, abrasion, and the contact time.

Eye protection : Eye protection (EN 166)Tightly fitting safety goggles

Skin and body protection : Chemical resistant protective clothing according to DIN EN13034 (Type 6)

Hygiene measures : Take off contaminated clothing and shoes immediately.Keep away from food, drink and animal feedingstuffs.Wash hands before breaks and immediately after handling theproduct.Avoid contact with skin and eyes.Do not breathe vapour.Do not breathe spray.

Environmental exposure controls

General advice : Do not flush into surface water or sanitary sewer system.Avoid subsoil penetration.


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9. Physical and chemical properties

9.1 Information on basic physical and chemical properties

Appearance : liquid 2 layers

Colour : yellowUpper layer

: brownLower layer

Odour : characteristic

Flash point : not applicable

Melting point/range : -2 °CUpper layer

< -10 °CLower layer

Boiling point/boiling range : 44 °C

Density : 1.11 g/cm3Upper layer

1.2 g/cm3Lower layer

Water solubility : completely miscibleUpper layer

immiscibleLower layer

Viscosity, dynamic : ca.15 mPa*s

9.2 Other information

Explosivity : Vapour/air-mixtures are explosive at intense warming.

10. Stability and reactivity

10.1 Reactivity

No dangerous reaction known under conditions of normal use.

10.2 Chemical stability


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Stable under normal conditions.10.3 Possibility of hazardous reactions

Hazardous reactions : With oxidizing agents possible.

10.4 Conditions to avoid

Conditions to avoid : Keep away from open flames, hot surfaces and sources ofignition.

10.5 Incompatible materials

Materials to avoid : Strong oxidizing agentsStrong acidsPowdered metals

10.6 Hazardous decomposition products

Risk of decomposition. : No decomposition if stored and applied as directed.

11. Toxicological information

11.1 Information on toxicological effects

Acute toxicity

Acute oral toxicity : Acute toxicity estimate: 613.5 mg/kgMethod: Calculation method

Acute oral toxicityCresol : Acute toxicity estimate: 100 mg/kg

Method: Converted acute toxicity point estimate

Solvent naphtha (petroleum),light arom.; Low boiling pointnaphtha - unspecified

: LD50: > 3,000 mg/kg

Xylenol : Acute toxicity estimate: 100 mg/kgMethod: Converted acute toxicity point estimate

Potassium Hydroxide : LD50: 365 mg/kgSpecies: rat

Phenol : Acute toxicity estimate: 100 mg/kgMethod: Converted acute toxicity point estimate

Chromium trioxide : LD50: 25 mg/kgSpecies: rat

LD50: 80 mg/kgSpecies: mouse


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Acute inhalation toxicity : Acute toxicity estimate: 55.78 mg/lMethod: Calculation method

Acute inhalation toxicityDichloromethane; MethyleneChloride

: LC50: 49 mg/lSpecies: rat

Phenol : LC50/inhalation/4h/rat.: 316.0 mg/l

Chromium trioxide : LC50: 0.217 mg/lExposure time: 4 hSpecies: rat

Acute dermal toxicity : Acute toxicity estimate: 914.25 mg/kgMethod: Calculation method

Acute dermal toxicityDichloromethane; MethyleneChloride

: LD50 Dermal: 2,000 mg/kgSpecies: rat

Cresol : Acute toxicity estimate: 300 mg/kgMethod: Converted acute toxicity point estimate

Solvent naphtha (petroleum),light arom.; Low boiling pointnaphtha - unspecified

: LD50: > 3,160 mg/kg

Xylenol : Acute toxicity estimate: 300 mg/kgMethod: Converted acute toxicity point estimate

Phenol : Acute toxicity estimate: 300 mg/kgMethod: Converted acute toxicity point estimate

Chromium trioxide : LD50: 57 mg/kgSpecies: rabbit

Skin corrosion/irritation

Skin irritation : Causes severe burns.

Serious eye damage/eye irritation

Eye irritation : Causes serious eye damage.

Respiratory or skin sensitization

Sensitisation : Contains one or more substance(s) classified as sensitising.


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Germ cell mutagenicity

Remarks : May cause genetic defects.

Carcinogenicity

Remarks : May cause cancer.

Toxicology Assessment

Acute effects : Toxic in contact with skin., Harmful if swallowed.

Repeated dose toxicity : May cause damage to organs through prolonged or repeatedexposure if swallowed.

Further information : May cause respiratory irritation.May cause drowsiness or dizziness.Inhalation of high vapour concentrations can cause CNS-depression and narcosis.If swallowed, severe burns in the oral cavity and throat as wellas danger of perforation of the digestive tract and stomach.

12. Ecological information

12.1 Toxicity

Ecotoxicology studies for the product are not available.

Toxicity to fishPotassium Hydroxide : LC50: 80 mg/l

Exposure time: 96 hSpecies: Gambusia affinis (Mosquito fish)

Chromium trioxide : LC50: 30 mg/lExposure time: 96 hSpecies: Carassius auratus (goldfish)

LC50: 37 mg/lExposure time: 96 hSpecies: Pimephales promelas (Fathead minnow)

NOEC: 0.105 mg/lExposure time: 60 dSpecies: Fish

Toxicity to daphnia and other aquatic invertebrates.Dichloromethane; Methylene : EC50: 480 mg/l


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Chloride Exposure time: 48 hSpecies: Daphnia magna (Water flea)

LC50: 244 mg/lExposure time: 96 hSpecies: Daphnia magna (Water flea)

Chromium trioxide : EC50: 0.035 mg/lExposure time: 48 hSpecies: Daphnia magna (Water flea)

NOEC: 60 mg/lExposure time: 21 dSpecies: Daphnia magna (Water flea)

Toxicity to algaeDichloromethane; MethyleneChloride

: EC50: > 662 mg/lSpecies: Selenastrum capricornutum (fresh water algae)

Chromium trioxide : NOEC: 0.5 mg/lExposure time: 10 d

Toxicity to bacteriaChromium trioxide : IC50: 30 mg/l

Exposure time: 3 hSpecies: activated sludge

Species: Photobacterium phosphoreum

12.2 Persistence and degradability

Biodegradability : no data available

12.3 Bioaccumulative potential

Bioaccumulation : no data available

12.4 Mobility in soil

Distribution among environ-mental compartments

: no data available

12.5 Results of PBT and vPvB assessment

no data available

12.6 Other adverse effects


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Chemical Oxygen Demand(COD)

: 1,000,000 mg/l

Additional ecological informa-tion

: highly water endangeringHarmful to aquatic life with long lasting effects.Do not flush into surface water or sanitary sewer system.Avoid subsoil penetration.Even leakage of small amounts in the subsoil can contaminatedrinking water.

13. Disposal considerations

13.1 Waste treatment methods

Product : Dispose of in accordance with local regulations.

Contaminated packaging : Dispose of as unused product.

Waste Code : Waste codes should be assigned by the user, preferably indiscussion with the waste disposal authorities.

14. Transport information

ADRUN number : 2927UN proper shipping name : TOXIC LIQUID, CORROSIVE, ORGANIC, N.O.S., Dichloro-

methane/ Methylene Chloride, CresolTransport hazard class(es) : 6.1Packing group : IIClassification Code : TC1Hazard identification No : 68Packing instruction (LQ) : LQ17Labels : 6.1 (8)Tunnel restriction code : (D/E),Environmentally hazardous : no

IATAUN number : 2927Description of the goods : TOXIC LIQUID, CORROSIVE, ORGANIC, N.O.S., Dichloro-

methane/ Methylene Chloride, CresolClass : 6.1Packing group : IILabels : 6.1 (8)

Packing instruction (cargoaircraft)

: 660

IATA_CEnvironmentally hazardous : no


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Packing instruction (passen-ger aircraft)

: 653

IATA_PEnvironmentally hazardous : no

IMDGUN number : 2927Description of the goods : TOXIC LIQUID, CORROSIVE, ORGANIC, N.O.S., Dichloro-

methane/ Methylene Chloride, CresolClass : 6.1Packing group : IILabels : 6.1 (8)EmS Number 1 : F-AEmS Number 2 : S-BMarine pollutant : no

RIDUN number : 2927Description of the goods : TOXIC LIQUID, CORROSIVE, ORGANIC, N.O.S., Dichloro-

methane/ Methylene Chloride , CresolTransport hazard class(es) : 6.1Packing group : IIClassification Code : TC1Hazard identification No : 68Labels : 6.1 (8)Packing instruction (LQ) : LQ17Environmentally hazardous : no

15. Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

Water contaminating class(Germany)

: WGK 3 highly water endangeringVWVWS A4

Other regulations : The product is classified and labelled in accordance with ECdirectives or respective national laws.Regional or national implementations of GHS may not imple-ment all hazard classes and categories.

15.2 Chemical Safety AssessmentA Chemical Safety Assessment is not required for this substance.


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16. Other information

Full text of R-phrases referred to under sections 2 and 3

R 9 Explosive when mixed with combustible material.R10 Flammable.R20 Harmful by inhalation.R22 Harmful if swallowed.R23/24/25 Toxic by inhalation, in contact with skin and if swallowed.R24/25 Toxic in contact with skin and if swallowed.R26 Very toxic by inhalation.R34 Causes burns.R35 Causes severe burns.R36/37/38 Irritating to eyes, respiratory system and skin.R37 Irritating to respiratory system.R40 Limited evidence of a carcinogenic effect.R42/43 May cause sensitization by inhalation and skin contact.R45 May cause cancer.R46 May cause heritable genetic damage.R48/20/21/22 Harmful: danger of serious damage to health by prolonged exposure

through inhalation, in contact with skin and if swallowed.R48/22 Harmful: danger of serious damage to health by prolonged exposure if

swallowed.R48/23 Toxic: danger of serious damage to health by prolonged exposure

through inhalation.R50 Very toxic to aquatic organisms.R51 Toxic to aquatic organisms.R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the

aquatic environment.R53 May cause long-term adverse effects in the aquatic environment.R62 Possible risk of impaired fertility.R65 Harmful: may cause lung damage if swallowed.R66 Repeated exposure may cause skin dryness or cracking.R67 Vapours may cause drowsiness and dizziness.R68 Possible risk of irreversible effects.

Full text of H-Statements referred to under sections 2 and 3.


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H226 Flammable liquid and vapour.H271 May cause fire or explosion; strong oxidiser.H301 Toxic if swallowed.H302 Harmful if swallowed.H304 May be fatal if swallowed and enters airways.H311 Toxic in contact with skin.H314 Causes severe skin burns and eye damage.H315 Causes skin irritation.H317 May cause an allergic skin reaction.H319 Causes serious eye irritation.H330 Fatal if inhaled.H331 Toxic if inhaled.H334 May cause allergy or asthma symptoms or breathing difficulties if in-

haled.H335 May cause respiratory irritation.H335 + H336 May cause respiratory irritation, and drowsiness or dizziness.H336 May cause drowsiness or dizziness.H340 May cause genetic defects.H341 Suspected of causing genetic defects.H350 May cause cancer.H351 Suspected of causing cancer.H361f Suspected of damaging fertility.H372 Causes damage to organs through prolonged or repeated exposure if

inhaled.H373 May cause damage to organs through prolonged or repeated exposure

if swallowed.H400 Very toxic to aquatic life.H410 Very toxic to aquatic life with long lasting effects.H411 Toxic to aquatic life with long lasting effects.H412 Harmful to aquatic life with long lasting effects.

Full text of Notas referred to under section 3

Nota C Some organic substances may be marketed either in a specific isomericform or as a mixture of several isomers. In Annex I, a general designa-tion of the following type is sometimes used: "xylenol". In this case themanufacturer or any other person who markets such a substance muststate on the label whether the substance is a specific isomer (a) or amixture of isomers (b). Example: (a) 2,4-dimethylphenol (b) xylenol(mixture of isomers).

Nota E Substances with specific effects on human health (see Chapter 4 ofAnnex VI) that are classified as carcinogenic, mutagenic and/or toxic forreproduction in categories 1 or 2 are ascribed Note E if they are alsoclassified as very toxic (T+), toxic (T) or harmful (Xn). For these sub-stances, the risk phrases R 20, R 21, R 22, R 23, R 24, R 25, R 26, R27, R 28, R 39, R68 (harmful), R 48 and R 65 and all combinations ofthese risk phrases shall be preceded by the word "Also". Examples: R45-23 "May cause cancer. Also toxic by inhalation". R 46-27/28 "Maycause heritable genetic damage. Also very toxic in contact with skin andif swallowed".


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Further information

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ardrox 666 - sil-mid · ardrox 666 version: 4.0 revision date 17.11.2011 print date 17.11.2011 1 /...

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