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    Applications of nuclear technology

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    CONTENTS

    1 INTRODUCTION 5 1.1. Introduction ....................................................................................................... 51.2. History And Scientific Background ................................................................... 5

    2. APPLICATIONS IN DIFFERENT FIELDS 7 2.1. Scientific Analysis Techniques .. . .7

    2.1.1. Nuclear Magnetic Resonance (NMR) ................................................... ....72.1.2. Tracers .................................................................................................... 10

    2.2. Electric Power Generation ................................................................................. 112.2.1. Fission Reactor ....................................................................................... 112.2.2. Fusion Reactor ... ...........12

    2.3. Medicical .............................................................................................................. 132.3.1. Diagnosis ................................................................................................ 132.3.2. Therapy ................................................................................................... 142.3.3. Sterilisation ............................................................................................ 15

    2.4. Food and Agriculture........................................................................................... 152.4.1. Fertilisers ............................................................................................... 152.4.2. Increasing Genetic Variability ............................................................... 162.4.3. Insect Control ......................................................................................... 162.4.4. Food Preservation ................................................................................... 172.4.5. Water Resources ..................................................................................... 19

    2.5. Industry ............................................................................................................... 192.5.1. Gamma Radiography.............................................................................. 202.5.2. Measurement and Industrial Analysis .................................................. 212.5.3. Sample Power Sources ........................................................................... 212.5.4. Environmental Monitoring .................................................................... 222.5.5. Other Industrial Uses ............................................................................ 22

    2.6. Household Uses of Radiation .............................................................................. 232.6.1. Smoke Detector ...................................................................................... 232.6.2. Other Uses of Radionuclides in Houses ................................................. 24

    2.7. Archaology and Geology ...................................................................................... 242.7.1. Radioactive Dating ................................................................................. 252.7.2. Geology and Element Identification ...................................................... 27

    2.8. Space Mission ...................................................................................................... 28

    3 CONCLUSION 29

    4 REFERENCES 30

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    1 INTRODUCTION

    1.1 INTRODUCTION

    Nuclear Technology is the technology that involves the reactions of atomic nuclei. In our

    daily life we need food, water and good health. This Technology can be used in diversified fields

    for peaceful purposes such as electricity generation, medicinal purposes, reducing pollution, etc .

    Radioisotopes play an important part in technologies that provide us with these basic needs. The

    International Atomic Energy Agency (IAEA) is a base for international cooperation in hundreds

    of development projects.

    Nuclear Technology is all around us. We'll find aspects of nuclear Technology

    everywhere we go. Everywhere from power generation to medicine to daily life, most people

    will encounter some form of nuclear Technology in action, making their lives easier.

    1.2 HISTORY AND SCIENTIFIC BACKGROUND

    The vast majority of common, natural phenomena on Earth only involve gravity and

    electromagnetism, and not nuclear reactions. This is because atomic nuclei are generally kept

    apart because they contain positive electrical charges and therefore repel each other.

    In 1896, Henri Becquerel was investigating phosphorescence in uranium salts when he

    discovered a new phenomenon which came to be called radioactivity. He, Pierre Curie and Marie

    Curie began investigating the phenomenon. In the process, they isolated the element radium,

    which is highly radioactive. They discovered that radioactive materials produce intense,

    penetrating rays of three distinct sorts, which they labeled alpha, beta, and gamma after the

    Greek letters. Some of these kinds of radiation could pass through ordinary matter, and all of

    them could be harmful in large amounts. All of the early researchers received various radiation

    burns, much like sunburn, and thought little of it.

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    The new phenomenon of radioactivity was seized upon by the manufacturers of a number

    of patent medicines and treatments involving radioactivity were put forward. Gradually it was

    realized that the radiation produced by radioactive decay was ionizing radiation, and that even

    quantities too small to burn could pose a severe long-term hazard. Many of the scientists working

    on radioactivity died of cancer as a result of their exposure.

    As the atom came to be better understood, the nature of radioactivity became clearer.

    Some larger atomic nuclei are unstable, and so decay (release matter or energy) after a random

    interval. The three forms of radiation that Becquerel and the Curies discovered are also more

    fully understood. Alpha decay is when a nucleus releases an alpha particle, which is two protons

    and two neutrons, equivalent to a helium nucleus. Beta decay is the release of a beta particle, a

    high-energy electron. Gamma decay releases gamma rays, which unlike alpha and beta radiationare not matter but electromagnetic radiation of very high frequency, and therefore energy. This

    type of radiation is the most dangerous and most difficult to block. All three types of radiation

    occur naturally in certain elements.

    It has also become clear that the ultimate source of most terrestrial energy is nuclear,

    either through radiation from the Sun caused by stellar thermonuclear reactions or by radioactive

    decay of uranium within the Earth, the principal source of geothermal energy.

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    2 APPLICATIONS IN DIFFERENT FIELDS

    2 1 SCIENTIFIC ANALYSIS TECHNIQUES

    2 1 1 Nuclear Magnetic Resonance (NMR)

    Nuclear magnetic resonance (NMR) was a phenomenon first discovered in 1946, and was

    refined in the 1950s by the Swiss-born United States physicist Felix Bloch. Since then, it has

    been applied in sciences ranging from physics to biochemistry, as well as applications such as

    medicine and forensic science. It is a technique used for analysis of various substances.

    Nuclear magnetic resonance is the vibration or resonance of a nucleus, when it is placedin a magnetic field - hence the name nuclear magnetic resonance. Particularly in medicine, it is

    also known as magnetic resonance imaging . The word 'nuclear' in a medical procedure

    frightens some people, hence the alternative name! However, nuclear magnetic resonance has

    nothing to do with radiation or radioactivity.

    Nuclei begin to resonate when placed in strong magnetic fields and targeted with specific

    radio waves. (Energy of the radio waves is absorbed by the nuclei, making it resonate.) This

    resonance occurs because at certain radio frequencies nuclei will absorb the wave energy,

    becoming excited from a low energy state to a higher energy state. These different energy states

    are called magnetic moments . Without the magnetic field, nuclei do not have the magnetic

    moments: they cannot exist in different energy states, and will therefore not be able to absorb

    any energy from the radio waves. This is why a magnetic field is used.

    The energy the hydrogen nucleus can be split into two different levels in the presence of a

    magnetic field. The change between the levels (moments) requires a certain amount of energy.

    The energy of radio waves (E) is equal to a constant h (Planck's constant, 6.626 10 -34)

    multiplied by the frequency of the wave f ,

    E = hf

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    Thus, for the frequencies at which a nucleus will resonate, the corresponding energy can

    be calculated to give relative values for the magnetic moments.

    The specific frequencies at which nuclei resonate can be used to identify them - as a type

    of "fingerprint". Measurements have been taken by scientists for the frequencies and magnetic

    moments of many atoms - forming a database that can be used to identify unknown samples.

    Fig.2.1: MRI Scanner

    NMR SPECTOSCOPY

    Spectroscopy is the analysis of different compounds. Scientists use NMR spectroscopy to

    study the bonds and structures of molecules.

    Hydrogen atoms not bonded to other atoms are called free hydrogen atoms . These

    absorb energy at the radio wave frequency 42.58 MHz (in the presence of a magnetic field).

    However, this frequency varies slightly if the hydrogen atom is bonded to other atoms. This

    variance can be used to determine the structure of an unknown compound.

    The atoms surrounding the hydrogen atom in a molecule are collectively called the

    neighbourhood of atoms . Different neighbourhoods affect the absorbed frequency of the

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    hydrogen atom in different ways, giving rise to a fingerprint for each neighbourhood. Variations

    in the frequency absorbed due to different neighbourhoods are called chemical shifts . Because

    of this variation, shifts can be used to identify a given neighbourhood.

    The specific hydrogen atom analysed with this technique is 1H, because it is the most

    abundant (over 99% of all hydrogen atoms in existence are of the 1H isotope) and it can take on

    different magnetic moments. However, 13C can also be analysed although this is not common

    since the abundance of it is very small, and equipment sensitivity to it is about 10,000 weaker

    than for 1H.

    NMR spectroscopy produces a graph which is then analysed to identify the compound

    tested. The technique is used to identify unknown compounds, analysing samples obtained from

    oil exploration, and forensic science. It is a widely used technique in organic chemistry, and has

    also been used to help establish the chemical structure of benzene - a structure that had eluded

    scientists for many years.

    Fig.2.2: NMR Spectroscopy

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    As the radioisotope passes through the body, the trail of radiation that is emitted can be

    recorded using networks of detectors to show how the radioisotope is consumed.

    Alternatively, in a process called autoradiography used often in studying plants, the plant is

    exposed to a radioactive isotope (for example, placed in an atmosphere filled with carbon

    dioxide containing the carbon-14 radioisotope). After absorbing the radioactive carbon dioxide,

    the plant has some of the radioisotope within it. It is then placed on a photographic film. The

    regions of the plant where the radioisotope has mostly concentrated darkens the film; the regions

    where the radioisotope does not exist does not affect the film. Overall a map of the location of

    the radioisotopes is generated. This technique is useful in the study of how plants absorb

    nutrients, and also has been used by scientists to study DNA replication.

    2 2 ELECTRIC POWER GENERATION

    2 2 1 Fission Reactor

    In a fission reaction, an atom such as 235 U is bombarded with a neutron. The 235 U atom

    then absorbs the neutron to form 236U. However, this is unstable, and it breaks up into two

    roughly equal sized atoms, releasing some neutrons and a lot of energy.

    Fig.2.4: Fission reaction of U-235

    Regardless of what the products may be, the neutrons released can continue on to break

    up more 235 U atoms. Thus, if a chain reaction can be created and sustained, there will be a lot of

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    energy released. In 1942, scientists at the University of Chicago in USA achieved such a self-

    sustaining chain reaction. They did this in the operation of the world's first ever nuclear reactor.

    235U atoms will only absorb slow moving neutrons. The neutrons produced from the

    breaking up of a 235U atom move at very high speed. Thus it is difficult to achieve a sustained

    chain reaction unless the produced neutrons can be slowed down. The slowing down is done by a

    moderator .

    Nuclear Reactors produce electricity by boiling water into steam.

    This steam then turns turbines to produce electricity.

    The difference is that nuclear Reactors do not burn anything.

    Instead, they use uranium fuel, consisting of solid ceramic pellets, to produceelectricity through a process called fission.

    Fig.2.5: General working of Nuclear Power Plant

    2 2 2 Fusion Reactor

    It is called 'fusion' because it is based on fusing light nuclei such as hydrogen isotopes to

    release energy, similar to that which powers the sun and other stars.

    Nuclei of two isotopes of hydrogen, deuterium(D) and tritium(T) react to produce a

    helium(He) nucleus and a neutron(n). In each reaction, 17.6 MeVof energy is liberated:

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    D + T 4He (3.5 MeV) + n (14.1 MeV)

    Fig.2.6: Fusion Process

    2 3 MEDICAL

    Radiation and radioisotopes are used in medicine particularly for diagnosis and

    therapy of various medical conditions. In developed countries the frequency of diagnostic

    nuclear medicine is 1.9% of the population per year, and the frequency of therapy with

    radioisotopes is about one tenth of this.

    Over 10,000 hospitals worldwide use radioisotopes in medicine. The use of

    radiopharmaceuticals in diagnosis is growing at over 10% per year.

    2 3 1 Diagnosis

    Radioisotopes are an essential part of diagnostic treatment. In combination with imaging

    devices which register the gamma rays emitted from within, they can study the dynamic

    processes taking place in various parts of the body. An advantage of nuclear over x-ray

    techniques is that both bone and soft tissue can be imaged very successfully.

    In using radiopharmaceuticals for diagnosis, a radioactive dose is given to the patient

    and the activity in the organ can then be studied either as a two dimensional picture or, with a

    special technique called tomography, as a three dimensional picture.

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    The most widely used diagnostic radioisotope is technetium-99m*, with a half-life of six

    hours, and which gives the patient a very low radiation dose. Such isotopes are ideal for tracing

    many bodily processes with the minimum of discomfort for the patient. They are widely used to

    indicate tumors and to study the heart, lungs, liver, kidneys, blood circulation and volume, and

    bone structure.

    Technetium generators, a lead pot enclosing a glass tube containing the radioisotope, are

    supplied to hospitals from the nuclear reactor where the isotopes are made. They contain 99Mo,

    with a half-life of 66 hours, which progressively decays to 99Tc. The 99Tc is washed out of the

    lead pot by saline solution when it is required. After two weeks or less the generator is returned

    for recharging. Tc-99 is employed in some 30 million diagnostic procedures per year

    Another major use of radioisotopes for diagnosis is in radio-immuno-assays for

    biochemical analysis in a laboratory. They can be used to measure very low concentrations of

    hormones, enzymes, hepatitis virus, some drugs and a range of other substances in a sample of

    the patient's blood. The patient never comes in contact with the radioisotopes used in the

    diagnostic tests.

    2 3 2 Therapy

    The uses of radioisotopes in therapy are comparatively few, but important. Cancerous

    growths are sensitive to damage by radiation, which may be external - using a gamma beam from

    a 60Co source, or internal - using a small gamma or beta radiation source.

    131I is commonly used to treat thyroid cancer, probably the most successful kind of cancer

    treatment, and also for non-malignant thyroid disorders. 192 Ir wire implants are used especially in

    the head and breast to give precise doses of beta rays to limited areas, then removed. A new

    treatment uses153

    Sm complexed with organic phosphate to relieve the pain of secondary cancerslodged in bone.

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    2 3 3 Sterilisation

    Many medical products today are sterilised by gamma rays from a 60Co source, a

    technique which generally is much cheaper and more effective than steam heat sterilisation. The

    disposable syringe is an example of a product sterilised by gamma rays. Because it is a 'cold'

    process radiation can be used to sterilise a range of heat-sensitive items such as powders,

    ointments and solutions and biological preparations such as bone, nerve, skin, etc, used in tissue

    grafts.

    The benefit to humanity of sterilisation by radiation is tremendous. It is safer and cheaper

    because it can be done after the item is packaged. The sterile shelf life of the item is then

    practically indefinite provided the package is not broken open. Apart from syringes, medical

    products sterilised by radiation include cotton wool, burn dressings, surgical gloves, heart valves,

    bandages, plastic and rubber sheets and surgical instruments.

    2 4 FOOD AND AGRICULTURE

    At least 800 million of the world's seven billion inhabitants are chronically malnourished,

    and tens of thousands die daily from hunger and hunger-related causes. Radioisotopes and

    radiation used in food and agriculture are helping to reduce these tragic figures.

    As well as directly improving food production, agriculture needs to be sustainable over

    the longer term. The UN's Food and Agriculture Organization (FAO) works with the IAEA on

    programs to improve food sustainability assisted by nuclear and related biotechnologies.

    2 4 1 Fertilisers

    Fertilisers are expensive and if not properly used can damage the environment. It is

    important that as much of the fertiliser as possible finds its way into plants and that a minimum is

    lost to the environment.

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    The IAEA and FAO are assessing the potential of using SIT against Sugarcane Borers on

    sugarcane, as well as consolidating Codling Moth management to support the apple and pear

    export industries.

    Three UN organizations - the IAEA, the FAO, the World Health Organisation (WHO),

    with the governments concerned, are promoting new SIT programs in many countries.

    2 4 4 Food Preservation

    Some 25-30% of the food harvested in many countries is lost as a result of spoilage by

    microbes and pests. In a hungry world we cannot afford this. The reduction of spoilage due to

    infestation and contamination is of the utmost importance. This is especially so in countries

    which have hot and humid climates and where an extension of the storage life of certain foods,

    even by a few days, is often enough to save them from spoiling before they can be consumed.

    Some countries lose a high proportion of harvested grain due to moulds and insects.

    In all parts of the world there is growing use of irradiation technology to preserve food.

    In over 40 countries health and safety authorities have approved irradiation of more than 60

    kinds of food, ranging from spices, grains and grain products to fruit, vegetables and meat. It can

    replace potentially harmful chemical fumigants to eliminate insects from dried fruit and grain,

    legumes, and spices.

    Radiation is also used to sterilise food packaging. In the Netherlands, for example, milk

    cartons are freed from bacteria by irradiation.

    As well as reducing spoilage after harvesting, increased use of food irradiation is driven

    by concerns about food-borne diseases as well as growing international trade in foodstuffs which

    must meet stringent standards of quality. On their trips into space, astronauts eat foods preserved

    by irradiation.

    Food irradiation means that raw foods are exposed to high levels of gamma radiation

    which kills bacteria and other harmful organisms without affecting the nutritional value of food

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    Fig.2.7: Irradiating process

    itself or leaving any residue. It is the only means of killing bacterial pathogens in raw and frozen

    food. Of course, irradiation of food does not make it radioactive!

    Table 2.1: Food Irradiation Applications

    Radiati on dose (ki lograys,

    kGy)

    Purpose

    "low" up to 1 kGy inhibits fruit and vegetable ripening

    controls some bacteria in meats

    controls insects in grains

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    2 4 5 Water Resources

    Adequate potable water is essential for life. Yet for any new development, whether

    agricultural, industrial or human settlement, a sustainable supply of good water is vital.

    Isotope hydrology techniques enable accurate tracing and measurement of the extent of

    underground water resources. Such techniques provide important analytical tools in the

    management and conservation of existing supplies of water and in the identification of new,

    renewable sources of water. They provide answers to questions about origin, age and distribution

    of groundwater, as well as the interconnections between ground and surface water and aquifer

    recharge systems. The results permit planning and sustainable management of these water

    resources.

    For surface waters they can give information about leakages through dams and irrigation

    channels, the dynamics of lakes and reservoirs, flow rates, river discharges and sedimentation

    rates. From Afghanistan to Zaire there some 60 countries, developed and developing, that have

    used isotope techniques to investigate their water resources in collaboration with IAEA.

    Neutron probes can measure soil moisture very accurately, enabling better management

    of land affected by salinity, particularly in respect to irrigation.

    2 5 INDUSTRY

    Radiation is used widely throughout industry for various tasks including quality control,

    maintenance work and assessment of the environment.

    "medium" 1-10 kGy destroys bacteria in meat including salmonella, shigella,

    campylobacter and yersinia

    inhibits mold growth on fruit

    "high" more than 10 kGy destroys insects and bacteria in spices

    sterilises food to the same extent achieved by high heat

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    happens, the radiation passes through any cracks that may exist, onto the photographic film taped

    on the outside. This film is then developed and checked for cracks or welding deterioration.

    Some industrial machinery contains parts that have small amounts of radioactive

    materials. This allows easy observation and detection of wear and tear.

    2 5 2 Measurement and Industrial Analysis

    Radioisotopes are commonly used for measuring viscosity, density and thickness in

    conditions where other methods would be difficult or impossible to apply. Since radiation does

    not require direct contact it is used where high heat or corrosive chemicals may exist.

    Radiation is reduced in intensity when it passes through many materials. Therefore the

    amount of stuff between a radiation detector and emitter can be determined by calculating the

    difference between the intensity of emitted radiation and the intensity of the received radiation.

    This concept is applied in the manufacture of thin plastic films. The produced film is passed

    through a radioisotope gauge - the thicker the film, the lower the detected radiation. Changes in

    the detected level of radiation correspond to a change in thickness of the plastic, so this is a form

    of quality control.

    Radioisotopes can also be used to calculate the efficiency of large mixers, or the flow of

    materials through blast furnaces. Leaks and other defects can also be detected in building cooling

    towers and power station heat exchangers.

    2 5 3 Sample Power Sources

    Radioisotopes are used as power sources for applications requiring small amounts of portable energy, such as for remote weather stations and weather balloons, and navigation

    beacons and buoys. They are more environmentally friendly than batteries because once all the

    energy from radioactivity is used, there are few left-over wastes except for the stable atoms

    formed, whereas used batteries will always contain toxic heavy metals that are hazardous to the

    environment.

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    Table 2.2: List of Some Common Radioisotopes used in Industry

    Radioisotope Industrial Uses

    Hydrogen-3 Water age measurement, study of sewage

    carbon-14 Water age measurement

    Chlorine-36 Water age measurement

    Scandium-40 Study of blast furnace efficiency

    Manganese-54 Study of environmental impact of mining

    Chromium-57 Study of coastal erosion

    Cobalt-60 Sterilisation

    Zinc-65 Study of environmental impact of mining

    Cesium-137 soil erosion monitoring

    Iridium-192 Study of coastal erosion, checking of aircraft welding faults

    Gold-198 Study of sewage and sources of water pollution, monitoring of sand movements

    in ocean floors and river beds, coastal erosion, study of blast furnace efficiency

    Lead-210 soil and sand age measurement

    2 6 HOUSEHOLD USES OF RADIATION

    2 6 1 Smoke Detector

    One of the commonest uses of radioisotopes today is in household smoke detectors.

    These contain a small amount of 241 Am which is a decay product of 241 Pu originating in nuclear

    reactors. The 241 Am emits alpha particles which ionise the air and allow a current between two

    electrodes. If smoke enters the detector it absorbs the alpha particles and interrupts the current,

    setting off the alarm.

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    Fig.2.9: Smoke Detector

    2 6 2 Other Uses of Radionuclides in Houses

    Other items that contain radiation are collectors and those who acquire antiques are

    watches and clocks; glassware (canary or Vaseline glass), tile, and ceramics; gas lantern mantles;

    and camera lenses. Some old watches and clocks have dials that were painted with a radiation-

    emitting compound to make them visible in the dark. Old glassware, tile, and ceramics that

    contain radioactivity generally have enhanced naturally occurring radionuclides (such asuranium, thorium, or potassium) incorporated right into the glass or into the glaze. An older-style

    gas lantern mantle with thorium in its silk threads is often used by radiation safety offices as a

    source to check the operation of their radiation-detection instruments. Old camera lenses also

    might contain some thorium, which was believed to create a better image on the film.

    2 7 ARCHEOLOGY AND GEOLOGY

    The principals of radioactive decay are employed widely in many fields of archeology

    and geology to determine the nature and age of materials, artifacts and rocks.

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    2 7 1 Radioactive Dating

    The principals of radioactive decay are applied in the technique of radioactive dating , a

    process widely used by geologists and archaeologists to determine the age of materials and

    artifacts.

    Radioactive 14C atoms exist naturally. They are everywhere around us: in our clothes, in

    the food we eat, even in the air we breathe. However, there are not many of these 1.310 -12

    percent of all carbon atoms are the 14C isotope. This is why they do not pose danger to us - there

    are so few of them.

    The ratio of radioactive 14C atoms to stable 12C atoms in the atmosphere has remained

    constant over thousands of years. 14C atoms are formed when neutrons from the sun's cosmic

    radiation collide with 14 N atoms in the atmosphere

    Thus the decay of 14 C is reasonably balanced with its production, resulting in a constant

    ratio of 14 C to 12 C .

    Fig.2.10: Production of Carbon - 14

    Carbon dioxide (CO 2) molecules in the air can contain either isotope of carbon. This CO 2

    is continually used by plants to grow. Because the ratio of 14C to 14C in atmospheric CO 2 is

    constant, the intake of CO 2 by a plant results in a constant ratio of the two isotopes in the plant's

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    body while it is alive. However, when the plant dies it will no longer take in CO 2. As a result, the14C decaying in the dead plant will not be replenished by a "fresh supply" of more CO 2, resulting

    in the ratio of 14C to 12C decreasing over time.

    Because animals eat plants, the ratio of 14C to 12C in them also decreases once they die,

    since the 14C cannot be replenished.

    This process of dating using 14C is used by paleontologists. Paleontologists burn a small

    sample of a fossil to react the carbon in it with oxygen, to form CO 2. The CO 2 that contains 14C

    will be radioactive, and the amount can be easily measured using a radiation counter. Burning is

    done to facilitate measuring the level of 14C.

    14C has a half life of about 5730 years. This means that in a given sample of a carbon-

    containing substance, the ratio of 14C to 12C will decrease by half every 5730 years. Suppose for

    example, some archaeologists uncovered ancient manuscripts and found that the ratio of 14C to12C in the paper was half of that found in living trees. This would mean that the manuscripts

    would be about 5730 years old.

    The use of radioactive 14C for dating was first done by William Libby, an academic at the

    University of Chigaco, USA, in 1947.

    The relatively short half-life of 14C (5730 years) means that the amount of 14C remaining

    in materials and objects older than about 80,000 years is too small to be measured with today's

    equipment. Thus carbon dating is limited to objects which are not older than this. However, the

    abundance of other atoms with longer half-lives, such as 238U (half-life 4.5 10 9 years) can be

    measured in place of 14C. Geologists measure the amounts of other radioactive metal isotopes

    such as 238 U, 84Rb and 40P found in rocks to determine their age. Measurements show that the

    oldest rocks on Earth are about 4.6 billion years old - which is a reasonably accurate estimate of

    the Earth's age. Similarly, analysis of fossilised plants shows that they first occurred on Earth

    about 3 billion years ago.

    The major problem using radiocarbon dating is the chance of getting carbon from the

    samples mixed up with "fresh" carbon.

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    As well as using 14C to 12C decay, geologists also measure the decay of 40P to argon in

    dating rocks. This method is not accurate for rocks that have been heated above 120c (250f)

    because the argon diffuses out from the rock at these temperatures. The decay of 87Rb to 87Sr is

    used to check potassium-argon dates, and is much more accurate because neither isotope is

    diffused by heat. This rubidium technique was used by scientists to determine the age of the

    moon. Measurements using 238 U were used to determine the age of the Earth.

    2 7 2 Geology and Element Identification

    Radioactivity is also used to identify the location of deposits of uranium and other

    radioactive minerals. This is useful in mining exploration. The intensity of detected radiation

    also is an indication of the amount of uranium that may be located there.

    The mining industry employs radioactivity in its routines. One example is identification

    of rocks and minerals. X-rays from a radioactive material can induce other materials to emit

    fluorescent X-rays. These subsequent X-rays can have their energies measured, and then this

    gives an indication of the elements present in the original material. The intensity of these X-rays

    also is an indicator of the amount of the element present.

    This technique is done by placing probes into the slurry - water that contains sediments of

    minerals, etc. The probes contain a radioisotope and a detector. The radiation from the isotope

    causes metals in the slurry to emit fluorescent X-rays - these are identified by the detector also

    located on the probe. The probe's input is then analysed to give an indication of the types and

    amount of metals present in the slurry. Metals that are detected this way include lead, copper, tin,

    zinc, nickel and iron.

    Elements that can absorb neutrons will release gamma rays. These gamma rays can be

    analysed for their energies. Specific energies correspond to specific elements - thus this isanother way of identifying the metals and minerals that may be present.

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    2 8 SPACE MISSIONS

    Radioisotope thermal generators are used in space missions. The heat generated by the

    decay of a radioactive source, often 238Pu, is used to generate electricity. The Voyager space

    probes, the Cassini mission to Saturn, the Galileo mission to Jupiter and the New Horizons

    mission to Pluto all are powered by RTGs. A typical RTG produces about 300 watts of

    electricity and will operate unattended for many years. The Spirit and Opportunity Mars rovers

    have used a mix of solar panels for electricity and RTGs for heat. The latest Mars rover,

    Curiosity, is much bigger and uses RTGs for heat and electricity as solar panels would not be

    able to supply enough electricity.

    In the future electricity or heat from nuclear power plants could be used to make hydrogen.

    Hydrogen can be used in fuel cells to power cars, or can be burnt to provide heat in place of gas,

    without producing emissions that would cause climate change.

    Fig.2.11: Space crafts

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