applications of nanotechnology for safe and sustainable ...the applications of nanotechnology for...

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Acknowledgments Organizing and Planning Committee for Nano-4-Rem ANssERs initiative Board of Regent for Partial Support All Sponsors for the Workshop: NANOIRON Future Technology; Norco Manufacturing Complex; Louisiana Chemical Association; REPSS Incorporated; Environmental Measurements Corporation Applications of Nanotechnology for Safe and Sustainable Environmental Remediations (Nano-4-Rem ANSSERS): A framework regulation and oversight of engineering nanoparticles at the local level Ephraim Massawe, ScD, Assistant Professor Computer Science & Industrial Technology Southeastern Louisiana University The Nano-4-Rem ANSSERS Initiative The findings and conclusions in this report are those of the author and do not necessarily represent the views of the Nano-4-Rem organizing committee or Southeastern Louisiana University. Areas of numerous applications of ENPs ENPs in remediation processes Nano-4-Rem Background A framework for oversight and regulation at the local level There is need for a Road Map for Nano-4-Rem AnnseRs Guidelines for best practices in handling ENPs throughout their life cycle Guidelines needed for estimating human health risks based on mathematical models or use of instrumentation Provide education and training to communities, academia and professionals by using existing case studies Continuous improvement in advancing knowledge, Technology and information for regulatory oversight Understanding key players in the synthesis, characterization, and applications of ENPs in the U.S. and across the world Traditional steps to evaluate occupational and environmental exposures to ENPs Understanding and meeting information and technology needs to prevent exposures to engineered nanoparticles Additional information on the Nano-4-Rem Initiative can be found at:www.selu.edu/acad_research/programs/ nano_4_rem_anssers/ Bibliography EPA (Sept 2006). Technology Update #1: Nanotechnology. Nease Chemical Site, Columbiana County, Ohio. EPA (2009). Fate, Transport, and Toxicity of Nanoscale Zero-Valent Iron (nZVI) used during Superfund Remediation. Prepared by E. Keane, National Network for Environmental Management Studies Fellow, Duke University Khan FI, T Husain, and R Hejazi (June 2004). An Overview and Analysis of Site Remediation Technologies. J Env Mngt 71(2): 95122. Available: http://linkinghub.elsevier.com/retrieve/pii/S030147 9704000313 Kuempel ED, V Castranova, CL Geraci, and PA Schulte (2012). Development of Risk-based Nanomaterial Groups for Occupational Exposure Control. J Nanopart Res 14:1029 Available: DOI 10.1007/s11051-012-0878-5 Liu S-H et al. (2012). Epidemiological Study of Health Hazards among Workers Handling Engineered Nanomaterials. J Nanopart Res 14:878 Available: DOI 10.1007/s11051-012-0878-5 Muller NC and B Nowack (2010). Nanoparticles for Remediation: Solving Big Problems with Little Particles. J Elements, 6: 395400 Rajendran P and P Gunasekaran (2007). Nanotechnology for Bioremediation of Heavy Metals. In: Environmental Bioremediation Technologies. (Eds. Singh, S.N., Tripathi, R.D) Springer, NY, pp 211- 221. Elements of a framework for sustainable regulation and oversight of ENPs The Applications of Nanotechnology for Safe and Sustainable Environmental Remediation (Nano-4-Rem ANSSERS) informatics initiative is an initiative designed to understand and meet information and technology needs of emerging Engineered Nanoparticles (ENPs) The Nano-4-Rem is one step closer to prevent exposure and human health risks from ENPs in nano-enhanced remediation and by extension, in other areas where ENPs are used. This work can be accomplished by professionals, industry, academia, and government who will collaborate to: Organize information available, to share perspectives and pose relevant and specific questions related to Nano-4-Rem Discuss best practices and guidelines, and the selection of ENPs or best available technology (BAT) for specific applications. Prevention of ecological catastrophic ecological impacts is one of the expectations from these discussions leading to empowering local agencies regulatory and oversight of ENPs Creating a network of opportunities for inter and intra institution research and teaching, and promote sharing of knowledge Laws governing the remediation of contaminated soils or water include: the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA), and the Resource Conservation and Recovery Act (RCRA) Current traditional remediation technologies: pump-and- treat and permeable reactive barriers (PRBs) etc. Newer , emerging and innovative remediation methods now include use of engineered nanoparticles (ENPs). ENPs used for Rem include nano zero-valent iron, bimetallic nZVI/Pd/carbon nanosystems, and titanium dioxide. ENPs advantages may be time-savings and cost- effectiveness for remediation of bioaccumulative toxic and persistence substances. Advances in nanotechnology-enabled assessment and monitoring methods such as nano-sensors may improve remediation activities. Recent studies show association between exposure to ENPs and significant health risks and ecological impacts Recalling the impacts of DDT and PCBs decades ago, compels to do something now about ENPs Many more areas where ENPs are used are emerging!

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Page 1: Applications of Nanotechnology for Safe and Sustainable ...The Applications of Nanotechnology for Safe and Sustainable Environmental Remediation (Nano-4-Rem ANSSERS) informatics initiative

Acknowledgments Organizing and Planning Committee for Nano-4-Rem ANssERs initiative

Board of Regent for Partial Support All Sponsors for the Workshop: NANOIRON Future Technology; Norco Manufacturing Complex; Louisiana Chemical Association; REPSS Incorporated; Environmental Measurements Corporation

Applications of Nanotechnology for Safe and Sustainable Environmental Remediations (Nano-4-Rem ANSSERS): A framework regulation and oversight of engineering nanoparticles at the local level

Ephraim Massawe, ScD, Assistant Professor Computer Science & Industrial Technology

Southeastern Louisiana University

The Nano-4-Rem ANSSERS Initiative

The findings and conclusions in this report are those of the author and do not necessarily represent the views of the Nano-4-Rem organizing committee or Southeastern Louisiana University.

Areas of numerous applications of ENPs ENPs in remediation processes

Nano-4-Rem Background

A framework for oversight and regulation at the local level

There is need for a Road Map for Nano-4-Rem AnnseRs

Guidelines for best practices in handling ENPs throughout their life cycle

Guidelines needed for estimating human health risks based on mathematical models or use of instrumentation

Provide education and training to communities, academia and professionals by using existing case studies

Continuous improvement in advancing knowledge, Technology and information for regulatory oversight

Understanding key players in the synthesis, characterization, and applications of ENPs in the U.S. and across the world

Traditional steps to evaluate occupational and environmental exposures to ENPs

Understanding and meeting information and technology needs to prevent exposures to engineered nanoparticles

Additional information on the Nano-4-Rem Initiative can be found at:www.selu.edu/acad_research/programs/ nano_4_rem_anssers/

Bibliography EPA (Sept 2006). Technology Update #1: Nanotechnology. Nease Chemical Site, Columbiana County,

Ohio.

EPA (2009). Fate, Transport, and Toxicity of Nanoscale Zero-Valent Iron (nZVI) used during Superfund Remediation. Prepared by E. Keane, National Network for Environmental Management Studies Fellow, Duke University

Khan FI, T Husain, and R Hejazi (June 2004). An Overview and Analysis of Site Remediation Technologies. J Env Mngt 71(2): 95–122. Available: http://linkinghub.elsevier.com/retrieve/pii/S030147 9704000313

Kuempel ED, V Castranova, CL Geraci, and PA Schulte (2012). Development of Risk-based Nanomaterial Groups for Occupational Exposure Control. J Nanopart Res 14:1029 Available: DOI 10.1007/s11051-012-0878-5

Liu S-H et al. (2012). Epidemiological Study of Health Hazards among Workers Handling Engineered Nanomaterials. J Nanopart Res 14:878 Available: DOI 10.1007/s11051-012-0878-5

Muller NC and B Nowack (2010). Nanoparticles for Remediation: Solving Big Problems with Little Particles. J Elements, 6: 395–400

Rajendran P and P Gunasekaran (2007). Nanotechnology for Bioremediation of Heavy Metals. In: Environmental Bioremediation Technologies. (Eds. Singh, S.N., Tripathi, R.D) Springer, NY, pp 211-221.

Elements of a framework for

sustainable regulation and oversight of ENPs

The Applications of Nanotechnology for Safe and Sustainable Environmental Remediation (Nano-4-Rem ANSSERS) informatics initiative is an initiative designed to understand and meet information and technology needs of emerging Engineered Nanoparticles (ENPs)

The Nano-4-Rem is one step closer to prevent exposure and human health risks from ENPs in nano-enhanced remediation and by extension, in other areas where ENPs are used. This work can be accomplished by professionals, industry, academia, and government who will collaborate to:

• Organize information available, to share perspectives and pose relevant and specific questions related to Nano-4-Rem

• Discuss best practices and guidelines, and the selection of ENPs or best available technology (BAT) for specific applications. Prevention of ecological catastrophic ecological impacts is one of the expectations from these discussions leading to empowering local agencies regulatory and oversight of ENPs

• Creating a network of opportunities for inter and intra institution research and teaching, and promote sharing of knowledge

Laws governing the remediation of contaminated soils or water include: the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA), and the Resource Conservation and Recovery Act (RCRA)

Current traditional remediation technologies: pump-and-treat and permeable reactive barriers (PRBs) etc.

Newer , emerging and innovative remediation methods now include use of engineered nanoparticles (ENPs). ENPs used for Rem include nano zero-valent iron, bimetallic nZVI/Pd/carbon nanosystems, and titanium dioxide.

ENPs advantages may be time-savings and cost-effectiveness for remediation of bioaccumulative toxic and persistence substances.

Advances in nanotechnology-enabled assessment and monitoring methods such as nano-sensors may improve remediation activities.

Recent studies show association between exposure to ENPs and significant health risks and ecological impacts

Recalling the impacts of DDT and PCBs decades ago, compels to do something now about ENPs

Many more areas where ENPs are used are emerging!