appendix h analytical data - united states environmental ...environmental resources management, inc....

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Appendix HAnalytical Data

Analytical Quality AssuranceReport Tyler Refrigeration PitSurficial Soil Sampling EventCollected 21 July 1992Smyrna., Delaware

Prepared for Clark Equipment Company

28 October 1992

Environmental Resources Management Inc.855 Springdale DriveExton, Pennsylvania 19341

Hie No.: C2702.02.01

AR30I906

Analytical Quality AssuranceReport Tyler Refrigeration PitSurficial Soil Sampling EventCollected 21 July 1992Smyrna, Delaware


28 October 1992

iwne M. RoddersQuality Assurance Manager

Puishotam L. BatraQuality Assurance Chemist

Environmental Resources Management, Inc.855 Springdale DriveExton, Pennsylvania 19341

File No.: C2702.02.01

&R3QI907

TABLE OF CONTENTS

1.0 INTRODUCTION 1

2.0 ORGANIC DATA 22.1 GENERAL ORGANIC DATA QUALIFIERS 32.2 ORGANIC DATA QUALIFIERS 3

3.0 INORGANIC DATA 63.1 GENERAL INORGANIC DATA QUALIFIERS 73.2 INORGANIC DATA QUALIFIERS 7

4.0 SUMMARY 10

AR30I908

ATTACHMENTS

1 METHODOLOGY SUMMARY/METHOD REFERENCES

2 DATA SUMMARY TABLES

nAR30I909

LIST OF TABLES

1-1 Summary of Data Received

ARflOISIO I

1.0 INTRODUCTION

This analytical quality assurance report is based upon a review of allanalytical data generated for surficial soil samples and associated travel,equipment, and field blanks collected on 21 July 1992 at the TylerRefrigeration Pit Superfund Site, located in Smyrna, Delaware. Theanalytical methods which were used in these analyses are summarizedand referenced in Attachment 1. The sample locations, ERM andlaboratory sample identification numbers, dates of collection, and analysesperformed are presented on Table 1-1. Data summary tables presentingthe validated and/or qualified analytical results are provided inAttachment 2.

All data for the analyses were reviewed for adherence to the specifiedanalytical protocols. All results have been validated or qualifiedaccording to general guidance provided in "Region HI Modification toNational Functional Guidelines For Organic Data Review, Multi-Media,Multi-Concentration (OLM01.0-OLM01.8,6 June, 1992)" and "Region mModifications to the Inorganic Functional Guidelines, December 1990."

Table 1-1 Summary of Data Reviewed

SampleLocations

SS-1SS-2SS-3SS-4SS-5SS-6SS-7SS-8SS-9

SS-ll-rtTrip Blank

EB-1FB-1

ERMT.R.Number4640546407464084640946410

4641246413464144641546406464164641146404

Laboratory IDNumber

H92-07.187-003H92-07.187-005H92-07.187-006H92-07.187-007H92-07.187-010

H92-07.187-012H92-07.187-013H92-07.187-014 -H92-Q7.187-015H92-07.187-004

H92-07.187-016H92-07.187-011H92-07.187-002

Matrix

SoilSoilSoilSoilSoil

SoilSoilSoilSoilSoilSoilSoilSoil

DateCollected

7/21/927/21/927/21/927/21/927/21/92

7/21/927/21/927/21/927/21/927/21/927/21/927/21/927/21/92

AnalysesPerformed

[1], [3]

[1], [21, & [3][1], [3]

[III2I, *I3]

[11 [3][11 Bit [31

[11131[1], [2], & [3]

[1113][11 [3][11

[11 Bit [31[11 Bit [31

[11-Moisture, Target Compound List (TCL) Volatile Organic Compounds.[21 - Target Compound List (TCL) Semivolatile Organic Compounds and Pesticide/PCBs.[3] - Target Analyte List (TAL) Metals and Cyanideft-This sample is the blind field duplicate of sample SS-1.

1HEE8M GROUP 1 CLARK/TYLER-C2702.02.01 -10/28/92

RR30I9H

2.0 ORGANIC DATA

The organic analyses of surficial soil samples and associated travel,equipment and field blanks were performed by CHESTER LabNet'sHouston, Texas facility. The samples were analyzed for US EPA ContractLaboratory Program (CLP) Target Compound List (TCL) volatile organiccompounds, semivolatile organic compounds and pestiride/PCBs, asspecified in Table 1-1. All sample analyses were performed according tothe protocols specified in the OLM01.6 Statement of Work (SOW) forOrganic Analyses.

For the organic fractions analyzed by GC/MS, mass spectral librarysearches were performed to match sample spectra whose characteristicsdid not resemble those of the targeted compounds. This was performedfor up to ten volatile and twenty semivolatile extraneous peaks. Validatedresults for these library searches are found in the data summary tablesunder the heading "Tentatively Identified Compounds" (TICs).

The findings offered in this report are based on a detailed review of thefollowing deliverables the CLP format: chain of custody documentation,holding times, laboratory method and field blank analysis results,surrogate compound recoveries, matrix spike compound recoveries andreproducibility, duplicate analyses, bromofluorobenzene (BFB) anddecafluorotriphenylphosphine (DFTPP) mass tuning results, initial andcontinuing calibration data, internal standard area performance,pesticide/PCB resolution check sample results, DDD/Endrin breakdown,pesticide compound retention time shifts, summary for single andmulticomponent analytes, pesticide analysis sequence check, pesticidecleanup efficiency verification, pesticide identification, pesticide/PCB dualcolumn analysis precision, quantitation of results, and qualitative massspectral interpretation.

The quality assurance review of the data has been performed according tothe "Region HI Modification To National Functional Guidelines ForOrganic Data Review, Multi-Media, Multi-Concentration (OLM01.0-OLM01.8,6 June, 1992)" with the following exceptions:• ERM-established criteria was used to evaluate sample results based

on field duplicate analysis results. Precision was evaluated in termsof a relative percent difference between detected results in theduplicate samples. A relative percent difference criteria of 30 percentfor volatile parameters and 40 percent for semivolatile andpesticide/PCBs parameters.

THEERMCHOUP /I PZO f) I f\ I f\ OARK/mER-027010101-10/2J/92«030 I9|2

* For organic analyses where high surrogate recoveries were obtained,ERM has not qualified the quantitation limits as estimated.

The organic analyses were performed acceptably, but require a fewqualifying statements. It is recommended that the reported analyticalresults be used only with the qualifying statements provided below. Anyaspects of the data which are not qualified in this report should beconsidered qualitatively and quantitatively valid as reported based on thecriteria evaluated. Validated and/or qualified results for the samples areprovided on the attached sample data summary tables.

2.1 GENERAL ORGANIC DATA QUALIFIERS• As required by US EPA protocol, all tentatively identified compounds

(TICs) have been marked with a "JN" qualifier on the data summarytables to indicate that they are quantitative estimates, and the resultsare quantitated assuming 1:1 response with the associated internalstandards. ERM has regrouped the TICs according to chemicalclassification and has reported on the data summary tables only thoseTICs which have been demonstrated not to be the result of laboratorycontamination or an instrument artifact.

• As required by US EPA protocol, all compounds which werequalitatively identified at concentrations below their respectiveContract Required Quantitation Limits (CRQLs) have been qualifiedwith "J" qualifiers on the data summary tables to indicate that they arequantitative estimates.

22 ORGANIC DATA QUALIFIERS• Area counts for the volatile internal standards bromochloromethane,

1,4-difluorobenzene, and/or chlorobenzene-ds were substantiallybelow the quality control (QC) limits during the initial volatileorganic compound analysis of the surficial soil sample listed below.This indicates a substantial drop in instrument sensitivity or systemperformance for the compounds quantitated with these internalstandards probably due to the matrix of the samples. These sampleswere reanalyzed and again yielded internal standard area countsbelow the QC limits. Sample results have been reported from theinitial analysis. The positive results and/or quantitation limitsreported for volatile organic compounds that are quantitated usingthese internal standards should be considered quantitative estimates.This has been indicated by placing "J" qualifiers next to the positiveresult and/or quantitation limits reported for the affected volatileorganic compounds on the data summary table for these samples.

THEERMGROUP A D3<j Q I Q I Q CLARK/TYLER-C2702.0101-10/28/92

Sample Internal Standards with Low Area Counts

SS-2 Chlorobenzene-dsSS-6 Chlorobenzene-ds

SS-8 Bromochloromethane, 1,4-Difluorobenzene,Chlorobenzene-ds

SS-2 RE BromochloromethaneSS-6 RE Bromochloromethane, 1,4-Difluorobenzene,

Chlorobenzene-ds

SS-8 RE Bromochloromethane, 1,4-Difluorobenzene,Chlorobenzene-ds

• Low recoveries were obtained for two base-neutral extractablesurrogate compounds 2-fiuorobiphenyl and terphenyl-di4 for thesemivolatile analyses of water sample EB-1. These low recoveriesmay be the result of matrix interferences present in the samples. Thesample was not reextracted to confirm the matrix interferences. Thequantitation limits reported for base-neutral extractable fraction in theanalysis of sample EB-1 should be considered biased low quantitativeestimates. This has been indicated by placing "L" qualifiers next to thequantitation limits reported for base neutral extractable fraction onthe data summary table for this sample. There were no base-neutralextractable semivolatile compounds detected in any of the fieldsamples. 4-Nitrophenol was not detected in any of the field samples.

• The quantitation limits for the semivolatile organic compound 4-nitrophenol in field blank samples EB-1 and FB-1 should beconsidered biased low quantitative estimates. The continuingcalibration response factor (RF) for the specified compound in thesesamples was less than 0.05. Also, the percent difference (%D)between the initial calibration average relative response factor (RRF)and associated continuing calibration relative response factor (RRF)exceeded the quality control limit of 25 percent. This indicates a lackof instrument sensitivity for the analysis of this compound. Nopositive results was reported for the this compound in these fieldblanks. This has been indicated by placing "J" qualifiers next to thequantitation limits reported for 4-nitrophenol on the data summarytable for these samples. 4-Nitrophenol was not detected in any of theassociated field samples.

• Initial dilutions were performed for the analyses of semivolatileorganic compounds in the surfkial soil samples SS-2 and SS-4 becauseof the presence of the matrix interference and/or suspected highconcentrations of semivolatile organic compounds TICs in thesesamples. These dilutions were required to prevent saturation of theinstrument and to allow quantitation of the compounds within thelinear range of the calibration curve. However, the dilutions have

THE ERM GROUP AR3ft/Qlll CLARK/TYLER-CaratOZOl -10/28/92

resulted in elevated quantitation limits for non-detected compoundsin these semivolatile organic compounds. The possibility of elevatedquantitation limits should be noted when assessing the data for thequalitative absence of specific fractions in these samples.The positive results reported for pesticides gamma-BHC (lindane),dieldrin, 4,4'-DDE, endrin, and 4,4'-DDT in the surficial soil sampleSS-6 should be considered quantitative estimates. The percentdifference (%D) calculated for the positive results reported for thesespecified pesticides on the two GC columns exceeded dual columnprecision criteria of 25 percent. This has been indicated by placing "J"qualifiers next to the positive results reported for gamma-BHC(lindane), dieldrin, 4,4'-DDE, endrin, and 4,4'-DDT on the datasummary table for this sample.Surficial soil duplicate field samples SS-1 and SS-11 were submitted tothe laboratory and analyzed for volatile organic compounds toevaluate overall laboratory and sampling precision. Sampling andlaboratory precision was determined by comparison of the relativepercent difference (RPD) of the positive results reported for thecompounds which were confidently detected in the original sampleand its blind field duplicate.ERM's blind field duplicate precision criteria of 30% used to evaluatethe blind duplicate volatile organic compound results was met forsample SS-1 and its blind field duplicate sample SS-11.

THEERMGROUP . 5 n rs /> rt I <*tfBK/CrLER-C27Q2.02fll-10/28/92

3.0 INORGANIC DATA

The inorganic analyses of surficial soil samples and associated travel,equipment and field blanks were performed by CHESTER LabNet'sHouston, Texas facility. The samples were analyzed for USEPA CLPTarget Analyte List (TAL) metals and cyanide, as specified in Table 1-1.All sample analyses were performed according to protocols specified inthe ILM01.0 Statement of Work (SOW) for Inorganic Analyses.

The findings in this report are based on a review of the followingdeliverables reported according to the CLP format: chain of custodydocumentation, holding times, laboratory method and field blank analysisresults, matrix spike recoveries, laboratory and field duplicate analysisresults, detection limits/sensitivity, initial and continuing calibrations,CRDL standard analysis, laboratory control sample results, ICPinterference check sample results, ICP serial dilution results, graphitefurnace atomic absorption (GFAA) spectroscopy post-digestion spikerecoveries and duplicate burn results, standard addition results,qualitative identification, and quantitation of results.

The quality assurance review of the data has been performed according tothe requirements of the document entitled "Region HI Modifications to theInorganic Functional Guidelines, December 1990." with followingexceptions:• ERM-established criteria was used to evaluate sample results based

on the negative blank readings. Sample results which were less thanfive times the absolute negative blank value were qualified as biasedlow quantitative estimates due to the possibility of negative drift, asevidenced by the negative blank value.

• ERM-established criteria was used to evaluate sample results basedon field duplicate analysis results. Precision was evaluated in termsof a relative percent difference between detected results in theduplicate samples. A relative percent difference criteria of 30 percentfor inorganic parameters.

The inorganic analyses were performed acceptably, but requiredqualifying statements. It is recommended that the analytical results beused only with the qualifying statements presented below. Any aspects ofthe data that are not qualified in this report should be consideredqualitatively and quantitatively valid as reported. Validated and qualifiedanalytical results for these samples are provided in Attachment 2.

THEERMGHDUP 6 CUkRK/TYLER-CZHBJBdl-10/28/92

HR30I9I6

3.1 GENERAL INORGANIC DATA QUALIFIERS

• It should be noted that field blank and equipment blank samples arethe aqueous samples consisting of deionized distilled water and theresults for these blanks are used to evaluate the sample data forsampling and/or laboratory contamination. The aqueous results inthese blanks are reported in M-g/L and are converted into solid unitsof Mg/Kg before using them to qualify solid results. .

INORGANIC DATA QUALIFIERS• The positive results reported for sodium in the surficial soil samples

listed below are qualitatively invalid due to the level at which thisanalyte was detected in associated laboratory method and/or fieldblanks. Therefore, the results reported by the laboratory are notindicative of the sampling location. USEPA protocol requires positivesample results for sodium that are less than five times the leveldetected in associated laboratory method and /or field blanks to bequalified as qualitatively invalid, his has been indicated by placing"B" qualifiers next to the positive results for these samples on the datasummary tables. ____________________________

Analyte Samples Affected

Sodium SS-1, SS-2, SS-3, SS4,_______________ ________________ SS-6, SS-7, SS-8, SS-9, SS-11 ______

• The detection limits reported for cadmium in the surficial soil sampleslisted below should be considered biased low quantitative estimatesdue to negative results reported in laboratory and/or method blanks.The negative blanks indicate the probability of underestimation of theanalyte concentrations by the instrument. These detection limits havebeen marked with "L" qualifiers to indicate that they are biased lowquantitative estimates. _________________________


Cadmium SS-1, SS-2, SS-3, SS-4, SS-5,__ ___ SS-6, SS-7, SS-8, SS-9, SS-11

• The positive results and/or detection limits reported for selenium andsilver in the surficial soil samples listed below should be consideredquantitative estimates and may be biased low. The associated matrixspike recoveries were below the established quality control (QC) limit.This has been indicated by placing "L" qualifiers next to the positiveresults and/or detection limits for these samples on the datasummary tables.

THE ERM GROUP

Analyte

Selenium

Silver

Samples Affected

SS-1, SS-2, SS-3, SS-4, SS-5, SS-6,SS-7, SS-8, SS-9, SS-11, FB-1, EB-1

SS-1, SS-2, SS-3, SS-4, SS-5, SS-6,SS-7, SS-8, SS-9, SS-11, FB-1, EB-1

The positive results and/or detection limits reported for arsenic in thesurficial soil samples should be considered quantitative estimates andmay be biased extremely low. The associated matrix spike analysisyielded no recovery for arsenic for these samples. The low recoverieswere also obtained for the GFAA post-digestion spike analyses,further indicating severe matrix interference. This has been indicatedby placing "L" qualifier next to the positive results and the detectionlimits, respectively, on the data summary tables for these samples.ERM has not qualified the detection limits for arsenic in these samplesas unusable "R" to allow for the maximum possible use of the data.The positive results reported for antimony, cadmium, thallium, andzinc in surficial soil samples listed below should be considered biasedhigh quantitative estimates. The CRDL Standard recoveries weregreater than the acceptance criteria. High recoveries indicate lack oflinearity near the CRDL and laboratory problem to measure theanalyte concentrations in the range of the CRDL. This has beenindicated by placing "K" qualifiers next to the quantitative results toindicate that they are quantitative estimates.

Analyte

Antimony

ThalliumZinc

Samples Affected

SS-4, SS-11

SS-2, SS-3, SS-11

SS-1, SS SS-3, SS-4, SS-5, SS-6,SS-7, SS-8, SS-9, SS-11, FB-1, EB-1

The positive results for calcium and zinc in surficial soil samples SS-1,SS-2, SS-3, SS-4, SS-5, SS-6, SS-7, SS-8, SS-9, SS-11, FB-1, and EB-1should be considered quantitative estimates. The associated ICPserial dilution analysis results for these analytes were outside theestablished precision criterion of 10% of the original undilutedanalyses results. This indicates the presence of a chemical or physicalinterference in these samples. The positive results obtained forcalcium and zinc in a five-fold dilution analysis of sample SS-4 werehigher than the original undiluted results. This indicates that positiveresults for calcium and zinc may be biased low for samples of thesame matrix. This has been indicated by placing a "L" qualifier nextto the reported quantitative results for these analytes.

AR3gQI9l8THEERMGROUP n . I wjj ^ | \j CLARK/TYLER-C2702dl01-10/28/92

Soil sample SS-9 was quantitated for arsenic by method of standardaddition (MS A). The MS A correlation coefficient was greater than0.995, therefore, this result for arsenic is acceptable as reported.Surficial soil duplicate field samples SS-1 and SS-11 were submitted tothe laboratory and analyzed for metals and cyanide to evaluateoverall laboratory and sampling precision. Sampling and laboratoryprecision was determined by comparison of the relative percentdifference (RPD) of the positive results reported for the analyteswhich were confidently detected in the original sample and its blindfield duplicate.ERM's blind field duplicate precision criteria of 40%, used to evaluatethe blind duplicate metals and cyanide results, was met for sampleSS-1 and its blind field duplicate sample SS-11.

THEERMGROUP "' 9 •' CLARK/TVLER-C2702.0101-10/28/92

4.0 SUMMARY

The organic analyses were performed acceptably, but required a fewqualifying statements. This analytical quality assurance report hasidentified the aspects of the data which required qualification. Thesequalifiers are noted on the attached analytical data tables. A supportdocumentation package has been prepared for this quality assurancereview and is filed with the Tyler Refrigeration Pit Superfund site projectfile.

THBERUGBOUP * Am n I fl O rt CLARK/mER-C2702.02fll-10/28/92A#$01920

Attachment 1Methodology Summary/Method References

AR30I92!

ATTACHMENT 1 METHODOLOGY SUMMARY AND METHOD REFERENCES

METHODOLOGY SUMMARY

Analysis for Moisture

A well-mixed sample is placed in a weighed beaker and dried to constantweight in an oven at 103-105° C. The decrease in weight of the sample isproportional to the moisture content.

Analysis for Volatile Organic Compounds by GC/MS

The surficial soil samples were analyzed for TCL volatile organiccompounds by adding a five-gram (wet weight) sample aliquot or 5 mL ofwater sample to reagent water containing surrogate compounds andinternal standards and purging the mixture with helium at ambienttemperature. The volatile compounds were transferred from the aqueousphase to the vapor phase and trapped onto a sorbent column. Afterpurging, the column was heated and backflushed to desorb thecompounds onto a gas chromatographic column. The gas chromatographwas temperature programmed to separate the sample components, whichwere then detected by a mass spectrometer. The target compounds werequalitatively identified and quantitated through calibration withstandards.

Analysis for Semivolatile Organic Compounds by GC/MS

Thirty grams (wet weight) of the soil are extracted with 1:1 methylenechloride and acetone by sonic disruption. The extract is decanted andfiltered. The extraction is repeated two or more times, decanting aftereach sonication. The extract is then concentrated and analyzed by firstseparating the extract components using a gas chromatographic columnand then detecting them with a mass spectrometer for qualitative andquantitative evaluation.

Analysis for Pesticides/PCBs

Thirty grams (wet weight) of the soil are extracted with 1:1 methylenechloride and acetone by sonic disruption. The extract is decanted andfiltered. The extraction is repeated two or more times, decanting aftereach sonication. The extract is then concentrated and analyzed by firstseparating the extract components using a gas chromatographic columnand then detecting them with an electron capture detector (BCD).

THE ERM GROUP fi'P'L' '"' ' c3*«-WLER REFRIGERATION 027010101 -10/27/92

Florisil cleanup is performed on the chromatographic column prior to thesample analysis.

Gel-Permeation Cleanup

Gel-Permeation Chromatography (GPC) is a size-exclusion procedureusing organic solvents and hydrophobic gels in the separation of highmolecular-weight material from the sample constituents. The column ispacked with the required amount of preswelled absorbent and flushedwith the solvent for extended period. The column is calibrated and thenloaded with the sample to be analyzed. Elusion is effected with a suitablesolvent(s) and the product is concentrated.

Florisil Column Cleanup

Florisil is a magnesium silicate with acidic properties, which is used forgeneral column chromatography as a cleanup procedure prior to sampleanalysis by gas chromatography. The column is packed with the requiredadsorbent, topped with a water adsorbent, and then loaded with thesample to be analyzed. Elusion is effected with a suitable solvents)leaving the interfering compounds on the column. The eluate is thenconcentrated.

Analysis for TAL ICP Metals

Prior to analysis, 100- milliliter sample aliquots were digested with nitricand hydrochloric acids for aqueous analysis. One-gram sample aliquotswere digested with nitric and hydrochloric acids and hydrogen peroxidefor soil analyses. The solution resulting from the metals digestion wasanalyzed by Inductively Coupled Plasma (ICP) Emission Spectroscopy.

Analysis for TAL Arsenic, Selenium, Thallium, and Lead

One hundred- milliliter sample aliquots were digested with nitric andhydrogen peroxide for aqueous analysis. One-gram sample aliquots weredigested for soil analyses. The resulting solutions were analyzed bygraphite furnace atomic absorption (GFAA).

Analysis for Mercury

Aqueous and soil samples analyzed for mercury were oxidized withpotassium permanganate. Mercury was reduced to its elemental form andaerated from solution in a closed system. Mercury was then determinedwith an atomic absorption spectrophotometer.

THEERMCROUP ' Al-2 CLARK-TyLERREFRIGERA'nONC2702.02.(n-10/27/92

A D O n i r\ A -.

METHOD REFERENCESAnalysis ReferenceMoisture USEPA Contract Laboratory

Program, OLM01.6Volatile Organic Compounds USEPA Contract Laboratory

Program, OLM01.6Semivolatile Organic Compounds USEPA Contract Laboratory

Program, OLM01.6Pesticides/PCBs USEPA Contract Laboratory

Program, OLM01.6Gel-Permeation Cleanup USEPA Contract Laboratory

Program, OLM01.6Florisil Column Cleanup USEPA Contract Laboratory

Program, OLM01.6

TAL Metals US EPA Contract LaboratoryProgram ILM01.0

TAL Cyanide US EPA Contract LaboratoryProgram ILM01.0

THEERMGROUP n RMJU I 3CaMK-TYI REFRIGERATIONC27<tt02:m-10/27/92

Attachment 2Data Summary Tables

Surfioial Soil Analytical RaaultaTyl.r Ralrlgaration Pit

Supwfund Site, Smyrna, OilmanRamadM InvaatlgatlortfFaaalblltty Study

(All raauKa in raportad on a dry walgnt batla)

Sampla LocationEMIT*) Nun earSam ft* DataParoant Malatura

TCL Votatlla Organic ComMunaa tua/Kgl

ChloromathanaBromomathanaVinyl ChloridaChloroathanaMa<hylana ChtorkJaAcatonaCuban DlauHkfa1 .1 -Olchloroathana1,1 -Olchlorothana1,2-Dlchlroroathana (total)Chloroform1,2-Olchloroathana2-3utanona1.1,1-TrlchlorathanaCarbon TatrachlorMaBromodicflloroniahana1 ,2-OlchlorooroDanaCli-1 ,3-Dlchloroprop«naTrlehloroathanaDlbromochloromahana1T1 ,2-TrichloroathanaBanzanaTrana-1 ,3-DlchloropropanaBromoform4-Mathyl-2-Pantanona2-HaxanonaTatrachloroathana1 .1 ,2,2-TatrachloroathanaToluanaChlorobanzanaEthyltonzanaStyranaTotaJ Xytanaa

Tantatlvaly IdantltlaalVolatile Organic Compound* (no/Kg)

Total Unknown

SS-14*4067/21/925

11 U11 U11 U11 U9 J11 U11 U11 U11 U11 U11 U11 U11 U11 U11 U11 U11 U11 U11 U11 U11 U11 U11 U11 U11 U11 U11 U11 U11 U11 U11 U11 U11 U

NO

SS.11tt4S4M7/21/925


NO

SS-2484077/21/92

S

11 U11 U11 U11 U1111 U11 U11 U11 U11 U11 U11 U11 U11 U11 U11 U11 U11 U11 U11 U11 U11 U11 U11 U11 UJ11 UJ11 UJ11 U.11 UJ11 U.11 U,11 UJ11 U,

NO

SS-34*40*7/21/92S

11 U11 U11 U11 US J11 U11 U11 U11 U11 U11 U11 U11 U11 U11 U11 U11 U11 U11 U11 U11 U11 U11 U11 U11 U11 U11 U11 U11 U11 U11 U11 U11 U

NO

SS-44*40*7/21/924


NO

SS-f4*4107/21/921


NO

SS-*4*4127/21/924

10' U10 U10 U10 U7 J10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 UJ10 U.10 UJ10 UJ10 U.10 UJ10 UJ10 UJ10 UJ

NO

OuaaflaraCoda:B: Thla raault la quattatlvaly invalid bacauaa tha compound/analyta waa DM datactad In a blank at a aimlar concantratlon.J: Thla raault ahould ba oonskland a quantKatJva aatimata.JN: ThiaTCraauttanouldbacornUdaradaquantHatlvaaatlmala. TharaauKwaa

quanUatad aaaumlng 1:1 raaponu with tha aaaoctatad mtarnal atandard.NO: NotoaMdad.NA: NotAnalyzadU - TMa oompound/analyla waa analyzad but not datactad, Tha numarleal valua

raportad rapnaanta tha quantHatlon/datactlon limit of tha eompounoVanalyta.ft - Thia aampla la tha Wind flaid dupllcata ot sampla SS-1.

APPROVED FORRELEASE BY

QUALITY ASSURANCE

Paga 1 of 6

Surficial Soil Analytical Raaulta: Tylar Rafrigaratlon PitSuparfund Slta, Smyrna, DaiawaraRamadlal InvaatlgatloiVFaaalolllty Study

(All mulls ira raportad on « dry waiont baala)

3amu4» LocationEMITRNumtaarSafflDl* DataPareant Molatura

TCL Samivolatlla Organic Comaounda (ua/Ko)

P HanoiBla (2-Chloroathyt) Ethar2-Chlorophanol1 .3-Olchlorobanzana1 ,4-Olchlorobanzana1 ,2-Olchlorobanzana2-Mathvlphanol2,2'-Oxybl*(1 -Chloropropana)4-MathylphanolN-Nltro»o-di-n-oropylamlnaHaxachloroathanaNltrobanzanaIsophorona2-NHrophanol2,4-OlmathylphanolBla (2-Chk>roathoxy)mathana2.4-0 IchloroDhanol1 ,2.4-TrlchlorobanzanaNaohthalana4-Chloroanilinahiaxachlorobutadlana4-Chloro-3-mathvlphanol2-MathylnaphthalanaHaxachktrocvclopantadiana2.4,6-Trichlorophanol2,4,5-Trichlorophanol2-Chloronaohthalana2-Nltro«nilinaDimathylphthalataAcanaohthylana2,6-Olnltrotoluana3-NltroanlllnaAcanaohthana2.4-Olnitroohanol4-Nltrophanol3lbanzofuran2.4-Oinitrotoluana3lathylphthalata4-Chlorophanyl-phanylathar:luorana4-Nltroanilina4,8-Dlnitro-2-m»thvoh«nolN-Nitroaodiphanylamlna4-Bromophanyl-phanylatharHaxachlorobanzanaPantachktrophanolPhananthranaAnthracanaCarbazola31-n-SutylphthalataRuoranthanaPyranaJutylbanzylphthalata3,3'-DlohlorobanzidinaBanzo(a)anthraoanaChryaana31s (2-athylhaxyl)phthalata31-n-octvlPhthalata3anzo(b)Fluoranthana3anzo(k)FluoranthanaBanzc(a)Pyranandanod ,2,3-cd)pyrana3lbanz(a,h)anthracanaBanzo(g,h.i)parylana

SS-14*4057/21/«2

f

NA

SS-11tt4(4087/21/92S

NA

SS-2464077/21/928

NO

700 U700 U700 U700 U700 U700 U700 U700 U700 U700 U700 U700 U700 U700 U700 U700 U700 U700 U700 U700 U700 U700 U700 U700 U700 U1700 U700 U1700 U700 U700 U700 U1700 U700 U1700 U1700 U700 U700 U700 U700 U700 U1700 U1700 U700 U700 U700 U1700 U700 U700 U700 U700 U700 U700 U700 U700 U700 U700 U700 U700 U700 U700 U700 U700 U700 U700 U

SS-34840*7/21/92S

NA

SS-4484097/21/924

NO


ss-s4*4107/21/92S

NA

SS-44*4127/21/924

NO


Paga 2 of 8

Qua Nflani Coda:B: Thla ram* la quattatlvaly Invalid bacauaa tha compound/analyta was alao datactad In a blank at a aimilar eoneantnUon.J: Thla raauK shouW baconsioarad a quantKatlva aatimata.JN: Thla TIC raw* should baconaidarad a.quantitatlva aatlmaM. Tharaaul*

quantttatad aaauming 1:1 rasponsa with tha associated intamal standard.NO: Notoattctad.NA: Not AnalyzedU - Thla oompound/anaiyta was anatyzad but not dataetsd. Tha numaricat valiw

raportad raprasants tha quanttation/detectlon Sm* of tha oompound/anaiyta.ft • Thia sampla is tha blind fiald dupllcata of sampla SS-1.

AR301927


QUALITY ASSURANCE

XQA/QC lv1ANX(~ER

Surficial Soil Analytical RaaultaTylar Rafrlgaratlon Pit

SuiMrfund Slta, Smyrna, DalawarammaaUl irwaatlgaHoiVFaaalMltty Study

(AD results ara raportad on a dry waight baaia)

lama!* Laeatlan

lampll flatsPafoant MoMura

Fantatlvary Idantlfladtamtvolatlla Organto Compounda (tig/Kg)

Total UnknownTotal Unknown Aliphatic CompoundaTotal Unknown Aflehatio Mvdrooafbona•laxaoaoanolo Add

ret. PaalteMa/PCSa (uaVKoJ

Upn«-3HC*»ta-8HCJaka-BHCJamm«-BHC (Undam)•laotaohtorAldrln•laotaohlor EpoxMaindoauKan 1JUIdrln4.4--OOEin or In•ndoaultan II4.4--OOOEndoaulfan SuHata4.4'-OOTOathoxvonlorEndrin KalonaEndrin AMahvdaAloha-Chkxdana3amma-ChlordanaToxaonanaArchlor-101*Archlor-1221Arohlor-1232Arohlor-1242Archlor-124*Arohlor-1254Arehlor-1260

TAL Matala (mgyKg)

AluminumAntimonyArsanlo3ariumiarvlllumCadmiumCalciumChromiumCobaltCoccarIronLaadMagnaakxnManoanaaaUarcurvNtek.lPotassiumSaknlumSllvarSodiumThalliumVanadiumZlno

CyanM* (mfl/Kf)

SS-14*40*7/21/92I

NA

NA

77704.0 U6.3 U571O.«10.42 U528 L8.74.54.21030023.77171910.11 L5.S4320.«3 UO.S3 U30.1 t0.21 I17.i20.0 L

0.53 I

SS-IItt4*40*7/21/92S

NA

NA

72504.2 K8.3 U!ss.s0.5*0.42 ULS44 L9.44.33.51070021.9803its0.11 I5.33880.83 U0.83 U30.1 E0.25 K18.217.S L

NA

SS-2484077/21/928

290 JN

NO

1.8 U1.8 U1.6 U1.8 U1.* U1.8 U1.8 U1.1 U3.5 U3.5 U3.5 U3.5 U3.5 U3.5 U3.5 U18 U3.5 U3.5 U1.8 U1.6 U1*0 U35 U71 U35 U35 U35 U35 U35 U

89304.1 U6.4 Ul62.10.510.43 UL3740 L10.45.33.11080025.27802090.11 I9.95790.64 U0.64 U85.4 E0.24 H19.221.7 L

NA

SS-34*40*7/21/92S

NA

NA

123004.0 U6.4 U!640.500.43 Ul541 L15.45.94.11170028.79292200.11 U10.74910.64 U0.84 U45.7 B0.2* K21.331.1 L

NA

S»-44*40*7/21/924

540 JN

990 JN

NO

1.8 U1.8 U1.8 U1.8 U1.1 U1.1 U1.1 U1.1 U3.5 U3.5 U3.5 U3.5 U3.5 U3.5 U3.5 U11 U3.5 U>3.5 U1.8 U1.8 U180 U35 U71 U35 U35 U35 U35 U35 U

92504.7 K8.3 Ul81.80.500.42 Ul6*1 L17.14.93.11120027.18751610.11 U10.74070.13 U0.83 U34.1 80.21 L20.730.9 L

0.53 (.

S*44*4107/21/92I

NA

NA

122004.1 U1.4 Ui85.90.810.43 U835 L12.95.03.71210034.410101950.11 U7.S7210.84 U0.84 U4*.i a0.21 L22.1273 L

NA

SS-44*4127/21/924

3930 JN570 JN

1.1 U1.1 U1* U0.49 J0.57 J1.8 U1.8 U1.1 U093 J031 J091 J3.4 U3.4 U3.4 U1.4 J11 U3.4 U3.4 U1.1 U1.1 U110 U34 U70 U34 U34 U34 U34 U34 U

82904.0 U3.1 L55.50450.42 Ui737 L10.34.92.9947Q2939011740.11 U4.53*90.13 U0.«3 U27.1 S0,21 U17.924.7 L

0.53 U

Qualnancoda:B: This raau* la quattaUvaly Invalid baoauaatnacompound/analyta waa also datactad m a blank at a similar concentration.J: TtanautaftouMoaoonaJdaradaqiarallaswariniata.K: Thla raaul la a biaaad high quansaava aattmata.L: Tha raaut ia a blaaad low quankaliva aathnsta.JN: TNaTICfasu*shouldbaconsidaradaquamHatlva aatlmata. TharssuKwss

quanttatadassuming in raaponaawitti thaasaociatad kitamal standard.NO: NotdaaKtad.NA: NotAnalyzadU: This oompound/analyla waa analyzad but not dataaad. Tha numarical valua

rapoflad rapraaams tha quamtation/datactlon Km* of tha compound/anatyla.UljThiaquaMlUaon/datacaonllniKlsbiasadlow. •tt • Tna) sampla Is tha blind I Wd duplicate of sampla SS-1.

Paga 3 of •

APPROVED FORRELEACr

QUALITY AS:

QA/QC MAN/&EH VD/TE

. Surficial Soil Analytical ResultsTylar Rafrigaration Pit

Suparfund Sita, Smyrna, DalawaraRamadlal Investigation/Feasibility Study

(All rasults ara rgportad on a dry waight basis)

Sample LocationEFM Tit NumberSamel* DataParcantMalatura

TCL Volatile Organic Comsounda (ug/Kg)

ChloromathanaBromomathanaVlnvl ChlorideChloroathanaMathvlcna ChlorideAcetoneCarbon DisurtWe1 .1 -Olchloroethene1,1-Dlchlorothan*1 ,2-Olchlroroethene (total)Chloroform1 ,2-Olchloroathana2-Butanone1,1,1-TrichlorathanaCarbon Tetrachlorlde3romodlchk>romehane1 ,2-Oichloro propaneCIa-1 ,3-OichloropropeneTdohloroathenaDibromochloromahan*1 ,1 ,2-TrlchloroathanaBenzeneTrans-1 ,3-Olehloropropana9romoform4-Mathvi-2-Pentanone2-HaxanonaTetrachloroethene1 ,1 ,2,2-TatrachloroathaneTolueneChlorobanzaneithylbenzaneStyreneTotal Xvlanaa

Tentatively IdentifiedVolatile Organic Compounds (ug/Kg)

Total Unknown

SS-74*4137/21/924

NO

10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U

NO

S3-*484147/21/924

NO

10 UJ10 UJ10 UJ10 UJ10 UJ10 UJ10 UJ10 UJ10 UJ10 UJ10 UJ10 UJ10 UJ10 UJ10 UJ10 UJ10 UJ10 UJ10 UJ10 UJ10 UJ10 UJ10 UJ10 UJ10 UJ10 UJ10 UJ10 UJ10 UJ10 UJ10 UJ10 UJ10 UJ

NO

3*94*4157/21/924


NO

Trip Blankt484167/21/92NA

NO

10 UJ10 UJ10 UJ10 UJ10 UJ10 UJ10 UJ10 UJ10 UJ10 UJ10 UJ10 UJ10 UJ10 UJ10 UJ10 uj10 UJ10 UJ10 UJ10 UJ10 UJ10 UJ10 UJ10 UJ10 UJ10 UJ10 UJ10 UJ10 UJ10 UJ10 UJ10 UJ10 UJ

NO

Ell-It484117/31/92NA

NO

10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 u10 U10 U10 u10 U10 U10 U10 U10 U10 U10 U10 U

NO

ra-it4*4047/21/92NA

NO

10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U

NO

Qualifiers Coda:B: This result Is qualitatively invalid because the compound/analyta was also detected in a blank at a similar concentration.J: Thia result should be considered a quantitative estimate.JN: Thia TIC raault should be consldand a quantitative estimate. The result was

quantitated assuming 1:1 response with the associated Internal standard.NO: Not detected.NA: Not AnalyzedU - This compound/analvte was analyzed but not detected. The numerical value

reported represents the quantHatJon/dstectlon limit of tha compound/analyta.f - The results for these samples are reported in u£/L.


QUALITY ASSURANCE

Paga 4 of «

AR30I929-

Surficial Soil Analytical ResultsTylar Refrigeration Pit

Supertund Site, Smyrna, DelawareRemedial InveetlgatloiVFeaalblllty Study

(All results are reported on a dry weight bails)

Sam pie LocationEIMTR NumberSample DatePercent Mo leture

TCL Semivolatile Organic Compounda (uo/Ko)

PhenolBH (2-Chloroethvl) Ether2-Chlorophenol1 ,3-Olchlorobenzene1 ,4-Olchlorabenzana1 ,2-Olchlorobenzana2-Methvlphenol2.2'-Oxvbls(1 -Chloropropana)4-MethylphenolN-Nltroso-di-n-propylaminehiexachloroethaneMltrobenzeneIspphorone2-Nltrophenol2,4-OlmethvlphenolBis (2-Chloroethoxy)methane2,4-Oiehlorophenol1 .2.4-TrichlorobenzeneNaphthalene4-ChloroanillnaHexachlorobutadlene4-Chloro-3-methvlphenol2-MethylnaphthaleneHexachlorocvclopentadlene2,4,6-Trlchlorophenol2.4,5-Trlchlorophenol2-Chloronaphthalene2-NitroanllinaDimethylphthalateAcenaphthyiene2.6-Olnitrotoluene3-NHroanlllneAcenaphthene2.4-Olnltrophenol4-NltrophenolDlbenzoturan2.4-OinltrotoluanaOlethvlphthalate4-Chlorophenvl-phenyletherFluorene4-NHroaniline4,{-Olnltro-2-methyphenolN-Nltrosodlphenylamlna4-Bromophenyl-phenyletherHaxachlorobenzanaPentachlorophanolPhenamhraneAnthraceneCarbazoleOI-n-ButylphthalateFluoranthenePyreneButylbenzylphthalate3.3'-DlchlorobenzidlneBenzo(a)anthraosnaChryseneBis (2-ethvlhexvl)phthaJaleDi-n-octylphthalateBenzo(b)Fluoraurthena8anzo(k)FluoranthanaBenzo(a)PyreneIndenod ,2.3-cd)pyr*naDlbenz(a,h)anthracaneBenzofo.h.Dperylene

3S-74*4137/21/924

NA

SS-»4*4147/21/924

NO

340 U340 U340 U340 U340 U340 U340 U340 U340 U340 U340 U340 U340 U340 U340 U340 U340 U340 U340 U340 U340 U340 U340 U340 U340 U830 U340 U830 U340 U340 U340 U830 U340 U830 U830 U340 U340 U340 U340 U340 U830 U830 U340 U340 U340 U830 U340 U340 U340 U340 U340 U340 U340 U340 U340 U340 U340 U340 . U340 U340 U340 U340 U340 U340 U

33-94841 S7/21/924

NA

Trip llankf4*4167/21/92NA

NA

Il.1t4*4117/21/92NA

NO

10 U10 UL10 U10 UL10 UL10 UL10 U10 UL10 U10 UL10 UL10 UL10 UL10 U10 U10 UL10 U10 UL10 UL10 UL10 UL10 U10 UL10 UL10 U25 U10 UL25 UL10 UL10 UL10 UL25 UU10 UL25 U25 U,10 UL10 UL10 UL10 UL10 UL25 UL25 U10 UL10 UL10 UL25 U10 UL10 UL10 UL10 UL10 UL10 UL10 UL10 UL10 UL10 UL10 UL10 UL10 UL10 UL10 UL10 UL10 UL10 UL

«-1t4*4047/21/92NA

NO

10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U25 U10 U25 U.10 U10 U10 U25 U10 U25 U25 U.10 U10 U10 U10 U10 U25 U25 U10 U10 U10 U25 U10 L10 U10 U10 U10 U10 U10 L10 U10 U10 U10 U10 U10 L10 U10 U10 U10 U10 L

Quarters Code:8: This result is qualitatively invaH because tha compound/anatyla was also detected in a blank al a sMIw concentration,J: This nwuK should be considered a quantitative estimate.JN: TMs TIC resuisrtould be consictonKi a quaMitathn estimate. Tha result wes-

Quantitatea1 assuming 1 1 response with the associated Internal standard.NO: Not detected.NA: Not AnalyzedU - This compound/analyte was analyzed but not detected. The numerical vahM

reported represents the quantitttion/detection knit of tha compound/analyta.f - The results lor these samples are reported in pg/L.

Paga 5 of 6

flR30i930


QUALITY ASSUHAI

DATE

Surficial Soil Analytical RaaultaTyler Refrigeration Pit

Superfund Site, Smyrna, DelawareRemedial Investigation/Feasibility Study

(All raaulls are raportad on a dry weight basis)

Sample LocationERMTH NumberSample DataPercent UoMure

Tentatively IdentifiedSemivolatile Organic Comoaunda (ua/Kg)

Total UnknownTotal Unknown AHohatlo Compound*Total Unknown Aliphatic HydrocarbonsHexabecanolc Add

TCL PeetWde/PCSe (uo/Ko)

Atoha-BHC3*t«-8HCDelta-BHCGamma-BHC (Undane)HeptaehlorAldrlnHaptaohtor EooxktoEndoauKan 1Dieldrin4.4'-DDEEndrinEndosulfan II4.4--OODEndosuKan Sulfata4,4'-OOTMethoxvchlorEflOfm KMOfWEndrin AldehydeAlpha-ChlordaneQamma-ChlordanaToxaoheneArchlor-1016Arehlor-1221 'Arohlor-1232Arehler-1242Archlor-1248Archlor-1254Archlor-1280

TAL Uetala (mg/Kg)

AluminumAntimonyAraanieJariumBerylliumZadmlumCalciumShromiumCobaltDoccerIron.sadMaanaskimManganeeeMercuryNickel'otaaalumSelenium •SliverSodiumThalliumVanadiumZinc

Cyanide (mo/Ko)

SS-7484137/21/924

NA

NA

68004.0 U6.3 UL60.00.450.42 UL2550 L9.34.73.11010020.212902210.11 U4.19030.63 Ul0.13 Ul37.3 a.30 U11.120.2 L

NA

SS-*484147/21/924

3000 JN340 JN760 JN450 JN

NO

1.8 U1.8 U1.8 U1.8 U1.8 U1.8 U1.8 U1.8 U3.4 U3.4 U3.4 U3.4 U3.4 U3.4 U3.4 U11 U3.4 U3.4 U1.8 U1.8 U180 U34 U70 U34 U34 U34 U34 U34 U

102004.0 U6.3 UL41.40.550.42 UL835 L21.74.72.91070025.17871280.10 U11.754*0.83 UL0.83 UL38.7 B021 U18.728.2 L

0.52 U

SS-9484157/21/924

NA

NA

82104.0 U7.3 L92.00.780.42 Ul853 L11.85.19.61090050.99334010.11 U6.56530.63 Ul0.63 Ut49.2 B0.25 U1935.9 L

NA

Trip Blankt484117/21/92NA

NA

NA

NA

E«-1t484117/21/92NA

NO

NO

0.05 U0.05 U0.05 U0.05 U0.05 U0.05 U0.05 UO.OS U0.10 U0.10 U0.10 U0.10 U0.10 U0.10 U0.10 UO.SO U0.10 U0.10 u0.05 U0.05 U5.0 U1.0 U2.0 U1.0 U1.0 U1.0 U1.0 U1.0 U

20.0 U19.0 U3.0 U1.0 U1.0 U2.0 UL51.93.0 U4.0 U4.0 U21.15.327.0 U1.40.20 U16.0 U671 U3.0 U3,0 U1301.0 U3.0 U4.3

10.0 U

FB-1t484047/21/92NA

NO

NO

0.05 U0.05 U0.05 U0.05 U0.05 U0.05 U0.05 U0.05 U0.10 U0.10 U0.10 U0.10 U0.10 U0.10 U0.10 U0.50 U0.10 U0.10 UO.OS UO.OS U5.0 U1.0 U2.0 U1.0 U1.0 U1,0 U1.0 U1.0 U

20.0 U19.0 U3.0 U1.0 U1.0 U2.0 UL54.13.0 U4.0 U4.0 U10.21.627.0 U1.0 U0.20 U16.0 U671 U3.0 U3.0 U81.71.03.0 U5.1

10.0 L

Ou alners Code:8: Thia raaut Is qualitatively Invalid because the compound/analyta waa also detected in a blank at a similar concentration.J: TMsreautiftwId be coraMered a o tilaUve estimate.K: TO* raaut la a biased high quantauVe estimate.L: Tha reeuH la a biased tow qusniattve estimate.JN: Thla •ncreaut should be considered a quantitative estimate. The result wasquantsaM assuming 1 :1 response with the associated Internal standard.

NO: Not detected.NA: Not AnalyzedU: Thia oompound/inalvte was analyzed but not detected. The numerical value OIIAI I TV AQOI?1"*WUMLlllUL: This quanttatktn/detectlon llmtt Is biased tow.

Paga 6 of 6 flR30i93i

APPROVED FORRELEASE 3Y

Analytical Quality AssuranceReport Tyler Refrigeration PitSmyrna, DelawareSoil Boring SamplesCollected 3 August to 10 August1992


13 November 1992


File No.: C2702.02.01

Analytical Quality AssuranceReport Tyler Refrigeration PitSmyrna, DelawareSoil Boring SamplesCollected 3 August to 14 August1992


13 November 1992 1992

yt 'Shawne M. Rodgers/ 0Quality Assurance Manag*

L. BatraQuality Assurance Chemist


AR30I933

1.0 INTRODUCTION

This analytical quality assurance report is based upon a review of allanalytical data generated for soil boring samples and associated travel,equipment and field blanks collected from 3 August through 10 August1992 at Tyler Refrigeration Pit, located in Smyrna, Delaware. Theanalytical methods which were used in these analyses are summarizedand referenced in Attachment 1. The sample locations, ERM andlaboratory sample identification numbers, dates of collection, and analysesperformed are presented on Table 1-1. Data summary tables presentingthe validated and/or qualified analytical results are provided inAttachment 2.

All data for the analyses were reviewed for adherence to the specifiedanalytical protocols. All results have been validated or qualifiedaccording to general guidance provided in the document entitled "Regionin Modification To National Functional Guidelines For Organic DataReview, Multi-Media, Multi-Concentration (OLM01.0-OLM01,6 June1992)" and "Region III Modifications to the Inorganic FunctionalGuidelines, December 1990.".

THE ERM CROUP 1 CLARK- TYLER REFWCERATION 070102.01-11/13/92

J5R3QI931*


Sample ERMT.R. Laboratory ID Date AnalysesLocations Number Number Matrix Collected PerformedB-l (4'-6') 46596 920801229 Soil 8/7/92 UT12]

92812-029 [3]920812029 [4]

B-K20--221) 46597 920801230 Soil 8/7/92 m920812030 |4j

B-2(4'-6') 46589 920801222 Soil 8/6/92 [1],[2]92812-022 [31920812022 [4]

B-2(6'-8') 46590 920801223 Soil 8/6/92 m920812023 [4j

B-2(20'-22') 46591 920801224 Soil 8/6/92 [1], [2]92812-024 [3]

; 920812024 [4]B-3(4'-6') 46586 920801219 Soil 8/5/92 11

920812019 [4]

B-3d4'-16') 46587 920801220 Soil 8/5/92 Ul, [2]92812-020 [3]920812020 [4]

B-4(2'-4') 46592 920801225 Soil 8/6/92 m920812025 |4j

B-ll (2/-4')tt 46594 920801227 Soil 8/6/92 m920812027 (4j

B-4(20'-22') 46593 920801226 Soil 8/6/92 [11 [2192812-026 [3]920812026 [4]

B-5(2'-4') 46571 920801202 Soil 8/3/92 m920812002 [4]

B-Ste'-S1) 46572 920801203 Soil 8/3/92 [1], [2]92812-003 [3]920812003 [41

B-5(20'-22f) 46573 920801204 Soil 8/3/92 m920812004 [4J

B-6(0'-2') 46577 920801208 Soil 8/4/92 [11, [2J92812-008 [3]920812008 14]

B-6(S-W} 46578 920801211 Soil 8/4/92 [1], [2]92812-011 [3]920812011 [4]

B-6(14'-16') 46579 920801212 Soil 8/4/92 m920812012 (4j

B-7(2'-4') 46580 920801213 Soil 8/4/92 m920812013 (4]

B-7(4'-6') 46581 920801214 Soil 8/4/92 m920812014 [4]

B-7(10'-12') 46582 920801215 Soil 8/4/92 [1], [2]92812-015 [31920812015 [4]

THEERMGIOUP fl R 3 0 i CLARK- TYLER REFRIGERATION C2702.CCLOt-ll/13/92

Table 1-1 Summary of Data Reviezved (Continued)

Sample ERMT.R. Laboratory ID Date AnalysesLocations Number Number Matrix Collected PerformedB-8 (4'-6') 46584 920801217 Soil 8/5/92 [1L121

92812-017 [3J920812017 [4]

B-8(22'-24') 46585 920801218 Soil 8/5/92 m920812018 [4j

B-9(4'-6') 46598 920801231 Soil 8/7/92 [11, [2]92812-031 [3J920812031 [4]

B-10(2' ') 46418 920807202 Soil 8/10/92 [1], [2]92872-002 [3],920872002 [4]

B-10 (20'-22') 46419 920807205 Soil 8/10/92 [I],920872005 [4],

B-ll (20'-2Z) 46420 920807206 Soil 8/10/92 [11,920872006 [41,

Trip Blank 1 46576 920801207 Soil 8/3/92 (1]Trip Blank 2 46583 920801216 Soil 8/4/92 ft]Trip Blank 3 46588 920801221 Soil 8/5/92 (1jTrip Blank 4 46595 920801228 Soil 8/6/92 mTrip BlankS 46417 920801232 Soil 8/7/92 (1]Trip Blank 6 46833 920807209 Soil 8/10/92 j

EB-2 46575 920801206 Soil 8/3/92 m [2]92812-006 131920812006 [4)

FB-2 46574 920801205 Soil 8/3/92 m r2]92812-005 r'3]920812005 (4]

EB-3 46832 920807208 Soil 8/10/92 m [2i92872-008 r'3]920872008 (4]

FB-3 46831 920807207 Soil 8/10/92 m [2]92872-007 r'3j920872007 [4j

Ill-Moisture, Target Compound List (TCL) Volatile Organic Compounds.[21 -Target Compound List (TCL) Semivolatile Organic Compounds.

[3] -Target Compound List (TCL) Pesticide/PCBs.[4] - Target Analyte List (TAL) Metals and Cyanide.

tt - This sample is a blind field duplicate of sample B-4(2'-4').

THEERMGROUP M r\ <*v r% » X - CLARK-TYLERREFRIGERATION02702.02.01-11/13/92AR30i9§6

2.0 ORGANIC DATA

The organic analyses of the soil boring samples and associated travel,equipment and field blanks were performed by CHESTER LabNet'sHouston, Texas facility. Soil samples were analyzed for US EPA ContractLaboratory Program (CLP) Target Compound List (TCL) volatile organiccompounds, semivolatile organic compounds and Pesticide/PCBs, asspecified in Table 1-1. All sample analyses were performed according tothe protocols specified in the OLM01.6 Statement of Work (SOW) forOrganic Analyses.

For the organic fractions analyzed by GC/MS, mass spectral librarysearches were performed to match sample spectra whose characteristicsdid not resemble those of the targeted compounds. This was performedfor up to ten volatile and twenty semivolatile extraneous peaks. Validatedresults for these library searches are found in the data summary tablesunder the heading "Tentatively Identified Compounds" (TICs).

The findings offered in this report are based on a detailed review of thefollowing deliverables reported according the CLP format: chain ofcustody documentation, holding times, laboratory method and field blankanalysis results, surrogate compound recoveries, matrix spike compoundrecoveries and reproducibility, duplicate analyses, bromofluorobenzene(BFB) and decafluorotriphenylphosphine (DFTPP) mass tuning results,initial and continuing calibration data, internal standard areaperformance, pesticide/PCB resolution check sample results,DDD/Endrin breakdown, pesticide compound retention time shifts,summary for single and multicomponent analytes, pesticide analysissequence check, pesticide cleanup efficiency verification, pesticideidentification, pesticide/PCB dual column analysis precision, quantitationof results, and qualitative mass spectral interpretation.

The quality assurance review of the data has been performed according tothe "Region HI Modification To National Functional Guidelines ForOrganic Data Review, Multi-Media, Multi-Concentration (OLM01.0-OLM01.8,6 June, 1992)" with the following exceptions:• ERM-established criteria was used to evaluate sample results based


THEERMCROUP ' ' " *"' V ' J tj / 4 CLARK-TYLERREFRIGERATIONC2702.02jn-ll/13/92

• For organic analyses where high surrogate recoveries were obtained,ERM has not qualified the quantitation limits as estimated.


2.1 GENERAL ORGANIC DATA QUALIFIERS

• As required by US EPA protocols, all tentatively identifiedcompounds (TICs) have been marked with a "JN" qualifier in the datasummary tables to indicate that they are quantitative estimates, andthe results are quantitated assuming 1:1 response with the associatedinternal standards. ERM has regrouped the TICs according tochemical classification and has reported on the data summary tablesonly those TICs which have been demonstrated not to be the result oflaboratory contamination or an instrument artifact.

• As required by US EPA protocols, all compounds which werequalitatively identified at concentrations below their respectiveContract Required Quantitation Limits (CRQLs) have been qualifiedwith "J" qualifiers on the data summary tables to indicate that they arequantitative estimates.

2.2 ORGANIC DATA QUALIFIERS

• The positive results reported for methylene chloride and acetone insoil boring samples listed in the table below are consideredqualitatively invalid due to the levels at which these compounds werepresent in the associated laboratory method and/or field blanks. Theresults reported by the laboratory are not representative of the samplelocation. US EPA protocol requires that positive results for commonlaboratory contaminants, such as methylene chloride and acetone thatare less than or equal to ten times the method, and/or field blankcontamination levels to be qualified as qualitatively invalid This hasbeen indicated by placing "B" qualifiers next to the reportedquantitative results for methylene chloride and acetone in the datasummary tables for these soil boring samples.

THEERMGBOUP I Q ,5MlK-t tER REFRIGERATION C270102jn-ll/13/92

Compound Affected Samples

Methylene Chloride - B-2 (4'-6'), B-3 (4'-6'), B-3 (U'-16"), B-6 (8'-10'), B-7 (4'-6')

Acetone B-2 (6'-8')

• Area counts for volatile internal standards bromochloromethane, 1,4-difluorobenzene, and/or chlorobenzene-ds were substantially belowthe quality control (QC) limits during the initial volatile organiccompound analysis of the soil boring sample B-3 (14'-16'). Thisindicates a substantial drop in instrument sensitivity or systemperformance for the compounds quantitated with these internalstandards, probably due to the matrix of the samples. This samplewas reanalyzed and again yielded internal standard area countsbelow the QC limits. Sample results have been reported using theinitial analysis. The positive results and/or quantitation limitsreported for volatile organic compounds that are quantitated usingthese internal standards should be considered quantitative estimates.This has been indicated by placing "J" qualifiers next to the positiveresult and/or quantitation limits reported for volatile organiccompounds on the data summary table for this sample.

RE - Sample Reanalyzed.• A high recovery (124%) was obtained for the volatile surrogate

compound 1,2-dichloroethane-cU for the diluted reanalysis of soilboring sample B-6 (8'-10')- The dilution analysis was performed toallow for the quantitation of xylene within the linear range of theGC/MS instrument. The high recovery for this volatile surrogatecompound may be the result of matrix interferences present in thissample. Sample results for xylene (total) reported from the dilutedanalysis should be considered quantitative estimates. This has beenindicated by placing "J" qualifiers next to the positive results reportedfor xylene (total) on the data summary table for this sample.

• Low recoveries were obtained for two or more base neutral and/oracid extractable surrogate compounds for the semivolatile analyses ofthe sample B-10 (2'-4') listed below. These low recoveries may be theresult of matrix interferences present in the samples. The sample wasre-extracted and yielded recoveries within the established qualitycontrol limits. However, the re-extraction was performed outside the7-day extraction holding time. The results for semivolatile organiccompounds are reported from the initial analyses. The positiveresults and/or quantitation limits reported for semivolatile organic

1 compounds should be considered quantitative estimates. This hasbeen indicated by placing "J" qualifiers next to the positive resultand/or quantitation limits reported for semivolatile organiccompounds on the data summary table for this sample.

THE ERM GROUP OH </} j fPo/1 CI>RK-TYl REFRIGERATION C2702.02.0I-U/I3/92

Surrogate Recovery QC LimitsSample Compound (%) (%)__——— —— —— —— -- —————_______

B-10(2'-4') Nitrobcn/one-d5 11 23-120

2-Fluorobiphonyl 13 30-115Tcrphenyl-du 11 18-137

2,4,6-Tribromophenol 0 19-122

l,2-Dichlorobenzono-d4 3 20-130

• Area counts for semivolatile internal standard l,4-dichlorobenzene-d4were substantially below the quality control (QC) limits during theinitial semivolatile organic compound analysis of the soil boringsample B-2 (20'-22'). This sample was not reanalyzed to confirm thethe matrix interferences in this sample. The low area counts indicate asubstantial drop in instrument sensitivity or system performance forthe compounds quantitated with this internal standard. There wereno positive results for compounds quantitated using this internalstandard. The quantitation limits reported for semivolatile organiccompounds that are quantitated using this internal standard shouldbe considered quantitative estimates. This has been indicated byplacing "J" qualifiers next to the quantitation limits reported forsemivolatile organic compounds on the data summary table for thissample.

• The positive results reported for volatile organic compound acetone,in samples B-5 (6'-8*) and B-7 (10'-12') should be consideredquantitative estimates. The percent relative standard deviation(%RSD) between the relative response factors (RRFs) for thesecompounds exceeded the linear range of the calibration curve of 30%.This indicate lack of instrument stability for the analysis of thesecompounds. ERM has placed a "J" qualifier next to reported positiveresults for acetone in these samples on the data summary table toindicate that these are quantitative estimates.

• The quantitation limits for the semivolatile organic compound 4-chloroaniline in field blank samples B-l (4'-6'), B-2 (20--221), B-4 (201-22')/ and B-9 (4'6') should be considered biased low quantitativeestimates. The continuing calibration response factor (RF) for thespecified compound in these samples was less than 0.05. Also, thepercent difference (%D) between the initial calibration averagerelative response factor (RRF) and associated continuing calibrationrelative response factor (RRF) exceeded the quality control limit of 25percent. This indicates a lack of instrument sensitivity for the analysisof this compound. No positive result was reported for the thiscompound in these field blanks or their associated samples. This hasbeen indicated by placing "J" qualifiers next to the quantitation limits

i

THEERMGItHJP A R 3 0 I 9 0 CLARK-T\LERREFRIGERATIONC27(a.Oim-ll/13/92

reported for 4-chloroaniline on the data summary table for thesesamples. ;Soil boring sample B-4 (2'-4') and its blind field duplicate sample B-ll(2'-4') were analyzed for volatile organic compounds to evaluateoverall laboratory and sampling precision. Sampling and laboratoryprecision was determined by comparison of the relative percentdifference (RPD) of the positive results reported for the compoundswhich were confidently detected in the original sample and its blindfield duplicate. No positive results were reported for these specifiedsamples.ERM's blind field duplicate precision criteria of 25% used to evaluatethe blind duplicate volatile organic compound results was met forsamples B-4 (2'-4') and its blind field duplicate sample B-ll (2'-4').

THEERMGROUP __. rt ,CL*RK-TyLERREFRIGERATIONC2702.02 1-ll/13/92fl"R30lWF

3.0 INORGANIC DATA

The inorganic analyses of soil boring samples and associated field blankswere performed by Keystone Lab - Houston of Houston, Taxes. Soilsamples were analyzed for US EPA CLP Target Analyte List (TAL) metalsand cyanide specified in Table 1-1. All sample analyses were performedaccording to protocols specified in the ILM01.0 Statement of Work (SOW)for Inorganic Analyses.

The findings in this report are based on a review of the following criteriareported according to the CLP deliverable format: chain of custodydocumentation, holding times, field and laboratory method blank results,matrix spike recoveries, laboratory and field duplicate analysis results,detection limits/sensitivity, initial and continuing calibrations, CRDLstandard analysis, laboratory control sample results, ICP interferencecheck sample results, ICP serial dilution results, graphite furnace atomicabsorption (GFAA) spectroscopy, post-digestion spike and duplicate burnresults, standard addition results, qualitative identification, andquantitation of results.

The quality assurance review of the data has been performed according tothe requirements of the document entitled "Region HI Modifications to theInorganic Functional Guidelines, December 1990" with the followingexceptions:• ERM-established criteria was used to evaluate sample results based



The inorganic analyses were performed acceptably, but requiredqualifying statements. It is recommended that the analytical results beused only with the qualifying statements presented below. Any aspects ofthe data that are not qualified in this report should be consideredqualitatively and quantitatively valid as reported. Data summary tablespresenting the validated and qualified analytical results are presented inAttachment 2.

THEERMCROUP ^ n O l J / v J / i O " CLARK-TYLER REFRIGERATION C2702.02JM-11/13/92

3.2 GENERAL INORGANIC DATA QUALIFIERS

• It should be noted that field blank and equipment blank samples arethe aqueous samples consisting of deionized distilled water and theresults for these blanks are used to evaluate the sample data forsampling and/or laboratory contamination. The aqueous results inthese blanks are reported in (ig/L and are converted into solid unitsof ug/Kg before using them to qualify solid results.

33 INORGANIC DATA QLIALIFIERS

• The positive results reported for sodium in the soil boring sampleslisted below are qualitatively invalid due to the level at which thisanalyte was detected in associated laboratory method and/or fieldblanks. Therefore, the results reported by the laboratory are notindicative of the sampling location. US EPA protocol requirespositive sample results that are less than five times the level detectedin an associated laboratory method and/or field blanks to be qualifiedas qualitatively invalid. This has been indicated by placing "B"qualifiers next to the positive results for sodium in these samples onthe data summary tables.________________________


Sodium B-10 a1-*), B-10 (20'-22'), B-ll (20'-22')

• The positive results and/or detection limits reported for lead andthallium in the soil boring samples listed below should be consideredbiased low quantitative estimates due to negative results reported inlaboratory and/or method blanks. The negative blanks indicate theprobability of underestimation of the analyte concentrations by theinstrument. These positive results and/or detection limits have beenmarked with "L" qualifiers to indicate that they are biased lowquantitative estimates.__________________________


Lead B-l (4--61), B-l (20'-22'), B-2 (4'-6'), B-2 (6-81),B-2 (20'-221), B-3 (4--61), B-3 (K-161), B-4 (2'-4),B-4 (20'-22'), B-5 (2'-4'), B-5 (6'-8'), B-5 (20i-22<),B O'-Z), B-6 (8'-10"), B-6.(14'-16>), B-7 (2'-4'),B-7 (4'-6'), B-7 (10M21), B-8 (4'-6-), B-8 (20'-221)B-9 (4-61), B-10 (2'-4'), B-10 (20'-22'), B-l 1 (2'-4')

B-ll (20--221)

Thallium B-10 (7-4"), B-10 Qff-ZT), B-ll (20--221)

• The positive results reported for aluminum in the soil boring sampleslisted below should be considered biased low quantitative estimatesand may be biased low. The recovery for the analysis of the associatedlaboratory control sample (LCS) was below the established quality

THE ERM GROUP IU CLARK -TYLER REFRIGERATION C2702.02.Ol-U/13/92

control (QC) limit for this analyte. This has been indicated by placing"L" qualifiers next to the positive results for aluminum in thesesamples on the data summary tables. __________________


Aluminum B-10 (2'-4'), B-10 (20'-221), B-ll (20'-22')

The positive results and/or detection reported for arsenic, selenium,silver, and thallium in the soil boring samples listed below should beconsidered quantitative estimates and may be biased extremely low.The associated matrix spike analysis yielded extremely low recoveryfor arsenic, lead, selenium, silver, and thallium for these samples.The low recoveries were also obtained for the GFAA post-digestionspike analyses, further indicating severe matrix interference. This hasbeen indicated by placing "L" qualifier next to the positive resultsand /or the detection limits for these analytes on the data summarytables for these samples. ERM has not qualified the detection limitsfor any of these analytes in these samples as unusable "R" to allow forthe maximum use of the analytical data. _______________

Analyte Qualifier Samples Affected

Arsenic L B-l (4'-6'), B-l (20'-221), B-2 (4'-6'), B-2 (6-81),B-2 (20'-22'), B-3 (4'-6%), B-3 (14M61), B-4 (2'-4),B-4 (20--22), B-5 (2'-4'), B-5 (G-8). B-5 (20'-221).B-6(0'-2'), B-6 (8'-10"), B-6 (14--161), B-7 (2'-4'),

B-7 (4--61), B-7 (10--121), B-8 (4'-6'),B-8 (20'-22% B-9 (4--61), B-ll

Selenium L B-l (4--6r), B-l (2Q--221), B-2(4--6'), 8-2(6-8"),B-2 (20'-22'), B-3 (4'-6'), B-3 (14'-16'), B-4 (2'-4),B-4 (20--221), B-5 (Z'-4"), B-5 (&-S), B-5 (20'-22'),B O'-D, B-6 (8'-10"), B-6 (M'-ie1), B-7 (Z-41),B-7 (4--61), B-7 (lO'-lZ), B-8 (4'-6')( B-8 (20'-221),B-9 (4'-6'), B-10 (2-41), B-10 (20'-2Z),B-11 (2'-4'),

B-ll (20--221)

Silver L B-l 0(2' A'}, B-10 (20'-22<), B-ll (2Q--221)

Thallium L B-10(2M'), B-10 (20--221), B-ll (20--221)

The positive results reported for zinc in soil boring samples listedbelow should be considered biased high quantitative estimates. TheCRDL Standard recoveries were greater than the acceptance criteria.High recoveries indicate lack of linearity near the CRDL andlaboratory problem to measure the analyte concentrations in therange of the GRDL. This has been indicated by placing "K" qualifiersnext to the positive results for zinc to indicate that these arequantitative estimates.

THEERMCROLP " ft R 3 0 1^9 CLARK-TYLERREFRICERATlONC2702.mjn-ll/13/92


Zinc K B-K4--6'), B-l (2Q--221), B-2(4'-6'), B-2(6-8'),B-2 (20'-221), B-3 (4'-6'>, B-3 (14'-16'), B-4 (2'-4),B-4 (20--22'), B-5 Q'-O, B-5 (6'-8'), B-5 (20--221),B-6(0'-2'), B-6 (8'-10"), B-6 (14'-16'), B-7 (2'-4'),

B-7(4<-6'),B-7(10'-121), B-8(4'-6'),B-8 (20--221), B-9 (4'-6'), B-10 (2'-4'), B-

10 (20--221), B-ll (2'-4'), B-ll (20'-22')

The positive results reported for chromium, lead, and manganese insoil boring samples listed below should be considered quantitativeestimates. Laboratory duplicate analysis precision criteria wasexceeded tor these analytes. This indicates a lack of precision for theanalysis of chromium, lead, and manganese in these samples. Thishas been indicated by placing "J" qualifiers next to the positive resultsfor chromium, lead, and manganese to indicate that these arequantitative estimates. __________________________


Chromium j B-l (4-61), B-l (20'-22'), B-2 (4'-6')( B-2 (6-8'),B-2 (20'-22'), B-3 (4'-6'), B-3 (14'-16'), B-4 (2'-4),B-4 (20--221), B-5 (2M1), B-5 (6'-8% B-5 (20'-22'),

'), B-6 (8'-10"), B-6 (14M61), B-7 (2M1),B-7 (4'-6% B-7 (lOMZ), B-8 (4'-6'),B-8 (20'-2Z), B-9 (4-6">, B-ll

Manganese J B-l (4'-6'), B-l (20'-22'), B-2 (4'-6'), B-2 (6-81),B-2 (20--22'). B-3 (4-61), B-3 (14'-16'X B-4 (2'-4),B-4 (20--22-), B-5 (2--41), B-5 (6--81), B-5 (20--220,B-6(0'-2>), B-6 (8'-10"), B-6 (14'-16'), B-7 (2M1),

B-7 (4--61), B-7 (10'-12'), B-8 (4'-6'),B-8 (20>-22')/ B-9 (4'-6'), B-ll

The positive results for zinc in soil boring samples listed belowshould be considered quantitative estimates. The associated ICPserial dilution (a five fold dilution) analyses results for these analyteswere outside the established precision criterion of 10% of the originalundiluted analyses results. This indicates the presence of a chemicalor physical interference in these samples. The positive resultsobtained for zinc in a five-fold dilution analysis of samples B-6 (0'-2')and B-10 (2'-4') were higher than the original undiluted results. Thisindicates that positive results for zinc may be biased low for samplesof the same matrix. This has been indicated by placing an "L"qualifier next to the reported quantitative results for these analytes.

THEERMCROLP « n /-> « CLARK-TYLERREFRIGERATION0702.02.01-11/13/92

Analyte

Zinc

Qualifier Samples Affected

J B-l (4'-6')( B-l (20'-22'), B-2 (4'-6')( B-2 (6-81),B-2 (20--221), B-3 (4'-6'), B-3 <14M6'), B-4 (2'-4),B-4 (20'-22<), B-5 (2-4), B-5 (G-81, B-5 (20'-22'),B-6(0'-2'), B-6 (8'-10"), B-6 (14--161), B-7 (2'4'),B-7 (4--61), B-7 (lO'-lT), B-8 (<¥-6">, B-8 (20'-22'),

B-9 (4--61), B-ll (2'-4f)

However, the positive results reported for zinc have been found to bebiased very high in these samples and marked with "K" qualifiersbecause the CRDL standard recovery was greater than theacceptance criteria for this analyte.Soil boring sample results for the analysis of lead in samples B-l (41-6'), B-3 (14-16'), B-5 (2'-4% B-5 (6-8% B-6 (8'-10'), B-7 (4'-6% B-8 (4'-6'),B-10 (2'-4'), and B-ll (2'-4') were quantitated by method of standardaddition (MSA). The MSA correlation coefficient was less than 0.995for the first analysis of the samples B-l (4'-6'), B-3 (14-161), B-5 (2'-4'),B-7 (4'-6'), and B-10 (2'-4'). Therefore, these MSA results were notacceptable. However, second MSA determinations which yieldedcorrelation coefficient more than 0.995 were acceptable for theseanalyses. The lead result for soil boring sample B-5 (6-81), B-6 (8'-10'),B-8 (4'-6'), and B-ll (2'-4') have been reported from the first MSAdetermination.Calcium and copper were detected in soil boring sample B-4 (2'-4')and its blind field duplicate sample B-ll (2'-4') at significantlydifferent concentrations. The concentrations of these analytes in theoriginal sample and and its blind duplicate sample exceeded theContract Required Detection Limit (CRDL) by a factor of two or more.The relative percent difference (RPD) of these analytes in the originalsample and blind field duplicates were calculated and aresummarized below.___________________________

Analyte B-ll (2M1) Percent

___________ B4 (2'-4')________(Blind Pup.)______RPD_________

Calcium 1030mg/Kg 660mg/Kg 44Copper 14.1 mg/Kg 4.8 mg/Kg 98The calculated RPDs for the above analytes exceeded ERM's duplicateprecision criteria of 40% for soil boring metal analyses. Theseelevated RPDs indicate a lack of sample homogeneity or analyticalprecision for these analytes. This has been indicated by placing a "]"qualifier next to the reported quantitative results for these analytes.

THEERMGROUP . _ 13 CLARK -TYIiRREFRIGERATIONCZ702.aZ.m-n/13/92

4.0 SUMMARY

The organic analyses were performed acceptably, but required a fewqualifying statements. This analytical quality assurance report hasidentified the aspects of the data which required qualification. Thesequalifiers are noted on the attached analytical data tables. A supportdocumentation package has been prepared for this quality assurancereview and is filed with the Tyler Refrigeration Pit project file.

THE ERM CROUP jl4;% O H lcQjk.TJkERREFRIGERATIONC270Z02.m-ll/13/92

Attachment 1Methodology Summary [Method References

AR3Q19l*8


METHODOLOGY SUMMARY

Analysis for Moisture

A well-mixed sample is placed in a weighed beaker and dried to constantweight in an oven at 103-105° C. The decrease in weight of the sample isproportional to the moisture content.


The soil boring samples were analyzed for TGL volatile organiccompounds by adding a five-gram (wet weight) sample aliquot or 5 mL ofwater sample to reagent water containing surrogate compounds andinternal standards and purging the mixture with helium at ambienttemperature. The volatile compounds were transferred from the aqueousphase to the vapor phase and trapped onto a sorbent column. Afterpurging, the column was heated and backflushed to desorb thecompounds onto a gas chromatographic column. The gas chromatographwas temperature programmed to separate the sample components, whichwere then detected by a mass spectrometer. The target compounds werequalitatively identified and quantitated through calibration withstandards.


Thirty grams (wet weight) of the soil are extracted with 1:1 methylenechloride and acetone by sonic disruption. The extract is decanted andfiltered. The extraction is repeated two or more times, decanting aftereach sonication. The extract is then concentrated and analyzed by firstseparating the extract components using a gas chromatographic columnand then detecting them with a mass spectrometer for qualitative andquantitative evaluation.


Thirty grams (wet weight) of the soil are extracted with 1:1 methylenechloride and acetone by sonic disruption. The extract is decanted andfiltered. The extraction is repeated two or more times, decanting aftereach sonication. The extract is then concentrated and analyzed by firstseparating the extract components using a gas chromatographic columnand then detecting them with an electron capture detector (ECD).

i

THEERMCROUP „ _. _, Al-1 CLARK-TYLERREFRIGERATIONC270Z02J01-11/13/92





Florisil is a magnesium silicate with acidic properties, which is used forgeneral column chromatography as a cleanup procedure prior to sampleanalysis by gas chromatography. The column is packed with the requiredadsorbent, topped with a water adsorbent, and then loaded with thesample to be analyzed. Elusion is effected with a suitable solvent(s)leaving the interfering compounds on the column. The elevate is thenconcentrated.






Aqueous and soil samples analyzed for mercury were oxidized withpotassium permanganate. Mercury was reduced to its elemental form andaerated from solution in a closed system. Mercury was then determinedwith an atomic absorption spectrophotometer.

THEERMGROUP ft D 3 £T"P Q S 0:I-A

METHOD REFERENCESAnalysis ReferenceMoisture USEPA 600/4-79-020, Methods for

Chemical Analysis of Water andWastes, Office of R and D, USEPA •EMSL, Cincinnati, Ohio, March1983, Method 160.3

Volatile Organic Compounds USEPA Contract LaboratoryProgram, OLM01.0

Semivolatile Organic Compounds USEPA Contract LaboratoryProgram, OLM01.0

Pesticides/PCBs USEPA Contract LaboratoryProgram, OLM01.0

Gel-Permeation Cleanup USEPA Contract LaboratoryProgram, OLM01.0

Florisil Column Cleanup USEPA Contract LaboratoryProgram, OLM01.0

TAL Metals, US EPA Contract LaboratoryProgram ILMO1.0

TAL Cyanide ' US EPA Contract LaboratoryProgram ILMO1.0

THEERMCROUP • r> O fW-W C I CLARK-TYLERREFRICERATIONC2702.Q2.01-lin3/92AR30f¥$5l


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UntUUMt**IBM Tamilian

ftiL §amlvo*atlla organte conwouna't (uaVKa)

PbaftoiBia a-CNoRMthvO gthar2-CMoreohanoltiS-OfeMorobaruafltt.4-CXchlorooanza<MBanzvt Alcoholt ,2-Ofehfor obanzam2-MMhylphanol2,2--Orytonn -CNoroorooana)4-M*(nylph»nolN-Nitroao-41-n-omevlamfn*HlaxacNqroalhanartttobanzanaIsophoron*2-Nilroph«nol2,4-Oima<hYlp!iano<Bit (J MoraMhoxvlmathan*2,4-OicMorophanolt 2 4-TrieMorebanz*naNaphthalan*4-CMoroanilfnaHaiaeMorobutadlant4-CHIoro-3-fnathvlDhanot2-M*thvfnaohttial»n«HaiacNofocYdooantadiana2.4.*.TricMoroQhanol2,4, S-TricMorophtnol2-Chloronaphthalafw2-NHroanilin*Dim*thylDHthalat«Aoanaphthvfana3-NitroanclintAeanapMtiant2,4-O<nitr»phaM<4-NitroehanolOibanzofuraii2.4-OinitrotoluM*[XathylphthalM*4^MorophafliHH>h*Avlalh«rFHjortflt4-Nitroanillna4^f-Dinitro-2-ma!hvphanotN-nStroaodiphaniHamin*4-8fomoph«nvl-phanyl»th«<H«xachlarab*nzan« *PantacnlwopnanolPhananthrwiaAntliraean*CtramtaOi-n-ButylphthalattFluoranlhan*PrnxwButyRMnzylphtnalattJ.J -OichlorabanzkMn*B4)nzo<a)gMhrae*iwBia (2-«<hyma»y<lpnthalat*ChiyaantOi-n-octyiphthalat«Banzo(b)f1ueninm«n«BtAiofkinuanMhtn*B«nio(«)*\r«i>«lno>no<1 ,2.3-c4lpvr>MOib«ii(a.li)an<)irae*ntBanzoft.B.Optrytofl*

Taaiatlvrty IdantKlad

Teul UnknownTotal Unknown Aliphate CompoundaTotal Unknown AHphaM HvdroeaibonaHaiaoacanoK Ao>dTotal $ub»Muu« Naenthaltn*TotaJ AIM SubaMMiaf BanzanoTotal Aronwfee Compound*Octamatnyt Cydotatratiloiana

til*-

8TO*1

NO

300 U3M U3*0 U3*0 U3*0 U3*0 U3*0 U3*0 U300 U3*0 U3*0 U3M U3M U3*0 U3*0 U3*0 U3*0 U3*0 U3*0 U3*0 UMO gj3*0 U390 U3*0 U3*0 U3*0 U840 U300 U840 U3*0 U3*0 U»40 U3*0 U840 U940 U3*0 U380 U380 U380 U380 U940 U840 U3*0 U3*0 U3*0 U840 U380 U3*0 U380 03*0 U3*0 U3*0 U3M U3*0 U3*0 U3*0 U3*0 0380 U3*9 U3*0 U380 U3*0 U380 U3*0 U

M JN

•>i ««••»)K7/82

NA

NA

*• j tr-rt— 55*

I/M2

NO

370 U370 U370 U370 U370 U370 U370 U370 U370 U370 U370 U370 U370 U370 U370 U370 U370 U370 U370 U370 U370 U370 U370 U370 U370 U370 U8*0 U370 U8*0 U370 U370 U8(0 U370 U8*0 U8*0 U370 U370 U370 U370 U370 U8*0 U8*0 U370 U370 U370 U8*0 U370 U370 U370 U370 U370 U370 U370 U370 U370 U370 U370 U370 U370 U370 U370 U370 U370 U370 U

NO

••*<•••«MS*88/tV*2

NA

8nVttM

3(0 UJ3(0 UJ310 UJ3BO UJ3SO UJ310 UJ3SO UJ3(0 UJ360 UJ3(0 UJ3SO U.3SO UJ3(0 U3(0 U3(0 U3(0 U3(0 U3(0 UMO U3(0 U3(0 U.3(0 U3(0 UMO U3(0 U3(0 U880 U3(0 UMO U3(0 U3M UatO U3M U8(0 U8(0 Um u3(0 U3(0 U3(0 U3(0 U8(0 UMO U3(0 U3(0 U3(0 U8(0 U3(0 U3(0 U3(0 U3(0 U3(0 U3(0 U3(0 U3(0 U3(0 U130 J3(0 U3(0 U350 U3(0 U3(0 U360 U3(0 U3(0 U

NO

-a«8? —,_"H, .,,..

NO

i-inr-ir) —— 1— «ssF — ]„ «** . J

=M3(0 U3(0 U38* U3(0 Uw> u3(0 U3(0 U3t* U3(0 U3(0 U

,„„.„„, W, ,„,«3*0 g3(0 U3(0 U3(0 u3(0 g3(0 g3*0 g3(0 U3(0 U3*8 U3(0 USO U3M u3(9 U3(0 UKO U3M U*J* gxo gw gM* g*9 UM* UM* U3(8 U3(0 gj»»» i3(8 I3(0 U]aio gNO U3(9 U3(0 U3(9 U8(0 U3(0 U310 U310 U3(9 U3(0 U3(0 U3(0 U3M U3*9 g79 J31* U3*8 U3H U3d U3N g3(8 U3(9 U3(9 g

NO

OuaWanCota:i: Tmiw«laqua«a*v«l»iri»aMliacauia*»cortipoundftnal»1a»aaatodal«M^J: Trteraai«alvMMbaconixl*radaquanJti*va*iamala.JN: ThtaTCnMuN*ho<Mbacanii6w*daouantt»»nM*niaa>. TnaraaUtwaa

quMKilad muunJng 1 it ruponta *«h t» >uocuWd Infernal Manoard.NO: NoldilKiad.NA: NotAntfyna'U-Th)toirnomnlfanMyta»a<*nalyz*dbu(rtttM<aeMd, Tha nunancal valua

npoitad rtfnum th« quanntaloiVdaMOon to* ol tia oanpounyamlyia.


QUALITY ASSURANCE

r « TC

S*« larlnf AnalytKil HatutU*v - Tylar Raingaritlon PHSuaartuad SHa, Smyrna, Oalawar*

Study(AX coneantrttioM art itportad on a dry waight bam)

EFW TR NunbarSamptaOalapanMnt Uaiakjr*

TCL P*ttleM«PCi* (uo/Ka)

AJoha-BHCBala-8HC0*Ha-BHCOamma-BHC Ojnoana)HaptachlorAldrinHaptaehlor EoondaindauHtn 1Dialdrin4.4'-ODEEndrinEndeauKan 114,4'-ODOEndoiulfan Sulfata4.4--OOTMalhoxyehlorEndrin KttpntEnditn AMahvdaAlpha<hlordanaSamma-CNoraanaToxaohanaArehlor-101*Arehlor-1221Arehlor-1232Arehlor-1242Arehlor-124*Arehlor-1234Arehlor-12«0

i ——— .-t(4- _. 1—— u5t ———

isMO

2.0 g2.0 g2.0 g2.0 U2.0 g2.0 g2.0 g2.0 u39 U.3.9 U3.9 U19 U3.9 g3.9 g3.9 g20 U3.* U3.9 U2.0 g2.0 g200 g3* g7* U38 U39 U39 U39 U3* U

NA

NA

10

18 U19 U19 U1.8 U1.9 U1.8 U1.9 U

F 19 U3.7 g08* JP3.7 U3.7 U035 JP3.7 g0.74 JP19 U3.7 U3.7 U1.9 U1 9 U190 U37 U74 U37 g37 U37 U37 U37 U

•-2<8'*1

NA

NA

••aw-m44581

5.8

t.l U.8 U.» U.8 U.« U.8 U.8 Ui.i g3.t g3.S U3.S uIS U3.( U3.S U3.S U4.1 JP3.S U3.5 UI.* U11 UIM u3$ U71 U3( U35 U3S U35 U38 U

— dip*! —— 1— am ——NA

NA

«flNO

M gi.* g18 U1.8 Ut.* U1.8 U1.8 U1.» U3.S U3.S U35 Uis g3.S g3,5 g3.5 U11 g3.s g3.$ gu gt.a g1*0 g3( g71 g3K U3S U35 U3S g

..» g

QuaHtanCoOa:

B: ThH) nm/K Kl nu*ml'"'> <nnaa bacauta Ha compomVanalyta w«» alio dattcud In a Hank at a *n*tf unimHallen.J: Thla rax* ttaud ba conaidarad i quanturvt arimala.JN: THaTKraauittoddba conaidarad a ouattKatvaaaainiM. TharatuKwaa

quantUMd aaunng t:! ratpoma w«h *<a auodalad intamal standard.NO: NotdattcMdNA: NMAnalyzMU - TNa compouiBanalyla wu anilyzad but not d>uciiij. Tha nunartcal vakja

rapoflad r«pna»« tha quantiUliaiVoalaOon Imjt ol tia cnmpouid/anilyla.S - Tnata raauK an unuaabta.P • ThU paatdda-inidorwai oMacMd on turn OC cokmna but p«reaot ditlanine* (%O) balwatn tiaaa rtponad poaKva raaummotadad tia OC Jmil of 25%. Tha tewaroltia two ratultt it raportad on tia laboratory anayiiarapoR.

Pajt 3 ol 20

fiR30!955


QUALITY ASSURANCE

Soil lorlnf Analytical RaaultaTylar Rattlflantltn Pit

Suparfunf Sha, Smyrna, Oalawar*Rim.au tw«a<ga8-an»aaa»illlty Study

(AH concantmiona ara raportad on a dry waieht batia)

«»n»U La»aa«nERM TO NumkarSametaOataP*r**nt UaOajra

TAL Hataia (ma>K9)Aluminum

Art anteBanumSarylliumCadmwmCalciumChromiumCobaltCopparIronLaadMagnaatumManoanaaaMareuryNickalPotaitiumS«ianMjmSilvarSodiumThalliumVanadiumZincCvanida

*-1<4".4->4«8M8W*t*.7

73SO

5.3 L26.80.320.44 U21453.0 J3.42.09*709.1 L29*987 J0.11 U29.3ISO UO.M ULO.C8 U38.(0.22 U18.2134 KO.S5 U

*-t (2**-22*)4(9879/JM«•*

0.42 gi13.10.31042 U40.43.7 J2.70.14 U5*700.2S L11.1

o.to u14 U142 U0.83 Ul0.83 U838021 U127.4 KNA

1-1 (4M144 U*8/8/*27.1

4610

1.9 L

—— it ———0.310.43 U2787.9 J4.21.58130S.I L305S2.2 Jo.tt g3.4 gi4« g08* UV0.8* g»»•».0.22 Utf.O19.1 KO.M U

t-irt'-r)

•HIM11.2

3.2 L4V, 90.330.4* U87438S J34519320*.* L37274.0 JO.It U44.11S2 U3.4 IX0.88 U2*80.23 U18.5<2I KNA

•-KW-2T)441*18WAM«

2330

0,42 UL

— M ——042 U72.58.2 J380.84 U80701.0 L13281.5 J0.11 g3.4 U143 U0(3 IX083 U70.10.21 U(.871 K053 U

*XJ(4--4148SM8WM9*

3750

OM L

———— $K —————— •0.32044 UIT*11.7 J3.03.8(3407.1 L21858.0 J011 U5.9149 UO.M Ul0.8* U80.80.22 U11.931.1 KNA

• tr-ir)4(5*78f5AM I

" m———— ••2730

042 ULto021 U042 g10870 •!3.0084 g38*02.7 L134272 J0,11 g33.1143 g083 Ul083 U2430.21 U8.020.1 K0.53 g

OuaManCoda:

B: TNara*uKia<ij*IUtvalyimaMbacwMtwcornpaund/analJ: TNa raault ihauMaaconaidaraa' a quanttatnaallmata.JN: TNa TICraauHadeuMbaecnUdaradapuanttaiv* aaamala, Tharaauftwa*

fmiHtli:! iminina ft nifiiiiui niiatitu imnHMil murnal imiiXilNO: NatdattcMd.NA: NotAnalyzadU-Trciooinpouna/analylawaaanalyzadbulnotdaiaciad. Thanumancalvakia

rtaortad rapraaanli »a quamUtorVdaaidlen to* of tia compounoyanayia.R • Tnaaa raauX ara unuaaMa.K: TNa raaoHatwuWba conaidarad a blaaad No* quantMva arfrnata.L:


QUALITY ASSURANCE

Pa«a4ol20

^30/956

... Soil Boring Analytical RaaultsTylar RafrlgaratKa PH

Supartund SKt, Smyrna, Dalawtr*Rmtdal awaadgatlonyrnatillHy *ki«y

(AH concantrationt art raoonad on a dry waigM baai<)

JERH TR NumbarISanvlaOalatPartant Iftahriufa1TCL VtLttrta Orgtirio Cpmoeunda (jifi/Kfl)

CMoronttthtntBramomathanaVinyl CMoridaCMoroalhanaMathvlana CMoridaAcatonaCarbon OiauMd*1.l-Oichloro«hana1.1-0ichlorothana1 ,2-Oichlroroalhant (total)Chloroform1 .Z-Oichlorotthin*2-Butanona1,1.1 -Triehiorathantlarbon TalraehlorioaVinyl Acatatt9romodichloromahana1 ,2-DieMorooropanaIia-1 ,3-OicMoroprooan*ThehloroathanaDihramoehloremahana1 1 2-Tnehloroathana9tnztntTrans-1 ,3-OicWoropropan*2-ChloroathylvinylathtrSromoform4-Mathyl-2-Pantanona2-Haunon.ratrachloroathana1 , t ,2,2-Tatrachloroath anaTohitntChforobanzanazthvfcaAzanaitvranaTotal Xylanaa

rantatlvaly lOntHlaa1rota-ill* Organic Compounds (no/Kg)

Total UnknownTotal Cvdic Aliphatic CompoundaTotal Aliphatic HydrocarbonTotal AIM Subatnutad BantanaTrimathyl SilanolOctamathyl Cyciotatraailaxana

4(1*1anVW9.1

NO

11 Uit gtt g11 u_11 uIt UIt U11 U11 UIt U11 U11 U11 U11 U11 Utt utt u11 U11 U11 U11 U11 U11 U11 UIt U11 Utt u" , . ... uIt Utt g11 g11 git uti u11 U

NO

Ml (T-W4*5*4•am8.8

NO

it g11 g11 g11 g11 g11 g11 g11 g11 g11 gu g11 g11 g11 Un git g11 u11 U11 U11 g11 U11 g11 g11 U11 Utt uit u11 Uu u11 U11 UIt U11 Uu g11 U

NO

wao-.masajMitt8.0

NO

11 U11 U11 U11 U11 UIt UIt U11 U11 git git u11 g11 g11 un git g11 g11 U11 g11 g11 gtt gn git g11 utt g11 Utt u11 U11 Un utt uit u1t Uit u

9 JK

•46V414(171•am9.0

NO

11 UUuuuuuuu

11 Utt uIt UIt U11 UIt U11 U11 U11 U11 U11 U11 Utt git gn uit u11 U11 Utt un uit u11 U11 Utt un gIt U

NO

M <!••»)4U7Z8/3/tf"

12 U12 U12 u12 g12 U10 J8 J12 U12 U12 U12 U

,„„_ '* u12 u12 U12 U12 U12 U12 U12 U12 U12 U12 U12 U12 U12 U12 U12 U

.._.. 12 • g12 U12 U12 U12 U

_. « "12 u8 J

17 JN

..Mown4*171tarn•»NO

11 U11 U11 U11 g11 un gtt u11 U11 git un uit u11 U11 U11 U11 U11 U11 U11 U11 U11 U11 U11 gtt g11 Utt g11 U1t U11 Utt uit uIt UIt Uit g11 g

NO

nor-n ——48*77•inn8.8

NO

11 I11 LIt L11 I.11 L11 L11 L11 U11 Uit g11 U11 Utt git uIt Uit utt u11 U11 U11 U11 U11 U11 U11 UIt U11 Uit git git git uit uit u11 U11 g11 U

NO

QuaWanCada:

B: Thia itauMI* qmlrtiavaly mvmd bacauta t» eompouncVannyn wit mo dataciad m i blar* it a anJaf eoiKtunlon.J: TNaraaictinouMbaconaiaaradaauanttilvaatilmita.JN: T)*TKiwuNirtouMbaconai6aradaquar!«atVamlimik>. Tharaiuttwaa

ouanatatad attuning 1 : t retoonaa with *w attoaatad ntamn standard.NO: NatdatacM.NA: NotAnHyitdU-1Nacampouna7anilyia<iattnalyzadbutnotdtMclad. Ihtnumancalvalua

R - Dwaa raault ara unuaada.t • Thia tamp* 1*4 bind 4jp*ca» of itmpta B-4 (V4r>

Paga 4


QUALITY ASSURANCE

DATE

Sou taring Analytical Raault*Tylaf Ralrtgaratlon PK

Suparfun* SKa, Smyrna, Dalaw«n>Ramatltt twaaagatlon/FtaalbWty SUoy

(AH eoneantratona an) raportad on a dry waight baaia)

ERUTRNumMrMm»taua»»F«ra«ot Uttatun

PhanotBit (2-Chloroathy!) gthar2-CMorephana41 ,3-Otchlorobanzan*1 ,4*0ichlorobanzanaBantvl Alcoholt ,2-Qtcnlorobanzana2-MatRylphanol2.2*-Oiybii<t -CMoropropana)4-MathylphanalN-Ntitrof o-oi-n -oroovlamin*htaiachtonMthanaHrtrooanzanaItophorona2-Nitrophanol2.4-DimathvlphanotSit (2*Chlon>athOkv)m4»tftana2.4.QlcMorophanelt ,2,4-TriehlorobanzanaNaoMhalana4-ChtoroamlinaHaiacMorobutadian*4-Chlora-3-mathylphanol2-MathvlnaphmalanaHaxacMorocydopantadiana2.4,8-TrieMorophanolZ,4,S.TricMorophano<2-C Moron aphtha! ana2-NitroanilinaDimwhylphlhalattAcanaphtflvlana3-NitroamlinaAeanaphthana2,4-Oinitrophane44-NitraphanolL>b*nzoHiran2.4-OinittotoluanaNathylphthalata4-CMoropnanvl-chanylathafr jorana4-Nitroamlina4l*-Dinitro-2-mathvphanolN-Nitrotodiohanviamfna4-8romophanyl-phanylath*rHaiacMorobanzanal>*machlaraphano!fhananttiranaAnthracanaCarbazol*Di-n-BuiylphlhalataRuoranthantPywnaButybanzylphthalata3.3'-OicMorobanzidinaB*nzo(a)aMhracan*Bla (2-«ihvlha>vl)phthalat*ChrytanaDt-n-octylohlhalalaB*nzo(b)Pkjoramhan*BanzodofluonmhtntBanzofalPyranalndano<1 ,2,3-cd)pyrantDibwiiIa.hJaMhnicanaBanza<a.h.i)p*rylana

T««till»»ly laamHIafS*mlv«latna OreinK ComMund* (uaVKO

Total UnknownTotal Unknown Aliphatic CompoundlTotal Unknown Aliphatic Hydrocarbon*HaEadaeanoie Aaa1Total Subattutae' Naehthtlan*Total AIM SubtMutad BanzanaTotal AromalK Compound*Oetamathyl Cydotatratilouna

•*«•-*48MI8nVttNA

NA

»-ii <r-«TtIMlNA

•

NA

4(5*3Wll7J

3so g350 g350 g350 g3SO U350 g350 g350 g

„ ,.»»_ ,.„. ..."n 350 g

350 U3SO U3SO U3(0 U350 U3(0 U350 U3(0 U350 U350 U3(0 U3(0 g310 U350 U350 U3(0 U**o g3(0 U8*0 U3(0 U350 U8*0 g3(0 g8(0 U8*0 U350 U350 U330 J350 U3(0 U880 U8*0 U350 U350 U360 U8*0 L3(0 U350 U350 L350 U350 1.350 L350 g350 1,350 (.3(0 U350 L3(0 U3(0 U3(0 t.350 I.350 I3(0 I310 U

NO

MO-T)4*1718(341NA

NA

«-§<*•.*)4*1728T3/MK

390 U3*0 U380 U380 U390 U390 g3*0 g3*0 g3*0 g3*0 U3*0 g390 g3*0 U3*0 g3*0 g390 U3*0 g3*0 g3*0 U3*0 U3*0 g390 g3*0 g„ „»•» ,,.„ ,v3*0 g3*0 g(40 g3*0 U940 g3*0 U3*0 g940 g3*0 g840 U940 g3*9 U3*0 g3*0 g390 U3*0 U•40 U»40 U3*0 U3*0 g3*0 g840 g380 g3*0 g399 u3*0 g3*0 g3*0 U380 g380 g380 g3*0 g3*0 U3*0 U380 g3*0 g3*0 U3*0 g3*0 g3*0 U

100 JNI

1*0 JN

Moe-m4(8738/3*tNA

NA

«4«r*544(77

-.?«*, ,.„., I

=£d3*0 U3*0 U3*0 U380 Um g380 g380 g380 U380 U3*0 g3*0 g380 g380 g3*0 g310 0MO g380 g380 U3*0 U3to g380 U3*0 U340 g

_3*o g3*0 U3*0 g1*0 U3*0 UMO u3*0 g3M Ua*o g3*0 U8(0 U8*0 U3*0 U3*9 Ul3*0 J*> I3(0 18*0 Ui8*0 g3*0 g3*0 U3*0 g8*0 U380 g3*0 g3*0 g3(0 U3(0 U3(0 g3(0 U3*0 g3*0 U3*0 g3(0 U380 U3(0 U3(0 g3*0 U380 U3*0 g3*0 g

,— NO . . . . . .

i

OuaWtanCoda:B: Thia raauK la <ijalu»¥«ly irv M bacauta fia canpounayanalyla ««i tlao dtHdtd n t biarifc at a ilmHf Laiuama8en.J: 1N*raai«iriouMbae!intidaradat|uaniltatvaa«ama<a.JN: Tnj*TK7raauktnouldbaainaid*radaquanua*v*Maniala. IHaraaultwai

quantrUUd muring 1:1 ratpoma with tia tuodatad InMmal uandard.NO: Not datactad.NA: NotAnalyzadU- Thla con aundranilyiaiMtwiityztd but not dataclad, Tha numatical yama

rtpanad raer»tanei ma quanttaton/dataclon fcrit ol tia compound/analyta.

Paga S ...

APPROVED FORELEASE BY

QUALITY ASSURANCEflR30i958

Soil Boring Analytical RaaultaTylar IMrlgaratlon Pit

Suptrfund SHa, Smyrna, Oalawir*Rtmadal kwaaagatlon/FaaalbMty Study

(AM concantratont ara raponad on a dry waight batit)

Sampla LataaanERMTRNumbarSMBtoOM.PtnMnt kMakn

TCL PattfcidavPCii (uaVKa)

Alpha -8 HCSata-8HCDada-BHCGamma-BHC (Lindana)HaptaehlofAldrinHaataehlor Eporid*Endotulfan 1Dialdrin4.4--OOEEndrinEndotuHan II4.4M30DEndotuKan Sulfala4.4--OOTMathonehlorEndrin Katon*Endrin Aldahvd*Alpht-ChlordtnaGamma-ChlordanaToiaphanalrehlor-1O1*Archlor.1221Arehfor-1232lrchlor-1242Arclllor-124*Arehlor-1254Archlor.1210

«-4<r-41445*38/*/MNA

NA

*-tt <r-ot4*5*4I/4A2NA

NA

B-4 (20*-2D4(5938AVM7.0

NO

1.1 Ui * gi.* g1.8 gt.( g1.8 g1.8 g1.8 U35 U3.5 U3.S U3.S U3.5 U3.5 U3.S g18 g3.s g3.S U18 U1.8 UISO U35 U72 U35 u3S U35 g35 g35 g

•-1(3-04*S71t/*MNA

NA

••s <«•-••>4*572aftvnIS

NO

2.0 U2.0 g2.0 U2.0 U2.0 U2.0 U2.0 U2.0 U39 g3.9 U3.9 g3,9 g3.9 g3,9 g3,9 Uso u39 g3.9 U2.0 U2.0 U200 U39 U79 U39 U39 g39 g3* g

—— 39 g

*-s<w-tn4*579t»»tMA

NA

1-4 (o'-n445771/4/13(.9

NO

i,a g1.9 g19 g1.9 g1.9 g1.9 Ut,9 U19 U3.* U3.8 g3.* g3.8 g3.8 g3.* g38 U19 g3,8 U3.* U1,9 U1,9 g180 g38 g74 g3*3* g3* U383* U

OuaHnanCoda:

B: TterttuMisqualttilHfalyirNalidbacauiatoconiPOtJ: IbMtnauttltouMbacoraidwtdaquanWttVaaatntata.JN: ThMTWratullahouldbacanaidaradae^arillUfvaaalirntla. Tharaauttwa*

quanaailad uauming 1 :t mponta w»n t» attodalad nwmat standard.NO: Notdattaad.NA: Not AnalyztdU- TMa compound/analyta watanalyzad but not dm clad. Tha numancal vakia

raponad rteraaam lha quantiUton/dataclcn ImK ot tia canpound/arMh/ta.R - Thaia rtauK ai* unutabfa.P • TnH pattdda/arodorwat dawctad on Mo QC cokmnt but ptrcant dflaranea (%O) bakmntwta raportad poaitVaraauNtaicaadadtwOC limit of 2S% Tha lowar ot *» t*o ratuttt It raponad on tia labortkay analytii report.

t • Tr* Sampla it a blind dupfcatt at ttmpla B-4 (4'*)

.,-, APPROVED FORRELEASE BY

QUALITY^ ASSURANCE

Ptga ( 4 £: 0R30I959

S«M String Analytical Raault*Tylar Rairigaratloii Pit

Su*M<4unf SHa, Smyrna, Oalawtra

(AD concammona ara raponad on a dry waight bawi)

lam*** LMaMnEMITANumaMr

TAt, MMais (mg/Kg)

AluminumAntimonyArtvjnieBariumBvrylliumCad mumCalciumChromiumCobaltCopp»fIronLM**M»gnaaJumMgAoan*M«M«fCUfVNick a*PotassiumS«t*ntumSilverSodiumThalliumVanadhjmZincCyamd*

.w<r-4r•MM14J

94905.*3.0 L51,90.4*0.47 U1030 J15.4 J5.414.1 J94*013.4 L.11002M J0.12 U7.1M*3.S UL0.70 U3*70.23 gl«.725.5 KNA

§-11 <r.r>tSAVMta

72704,2 g15 U7* 50.430.44 g8(0 J11.1 J5.14.* J

1120012.0 L87718* Jo.tt g5.73040.8* LN0.84 U27.80.22 g19.517.3 KNA

•(2**'2t

*AV*21.7

2*1040 g0.42 i.12.70.21 g0.42 g30.73.0 J2.2O.*i U83701.0 L77.1t».» J0.11 U3.4 U141 UO.M UtO.M U30.*0.21 U5.9«2 K0.53 U

WOMI48*71tnm8.1

494O

4,1 U13 L

——— Pn ————0370.44 Um

_ *,* J3.812«MO4.* L47271.8 J0.11 g3.s g147 U3.3 ut086 ga*s0.22 g12.2tt.t KNA

B.«r-n4*8728WWMM

813047 U2.7 L

$A0.480,4* U44*to.s j5.*2.S12*00U L8*7tt* J0.12 u«.t1** g3.7 UL0.74 U58.80.25 g17128.1 K0.81 U

t-star-trtt»tn•rutt*j

34104.1 U0.43 Ut.

_I020.3 10.43 g

.__7»448 J2.008* U7440O.M L77*20.1 Jo.tt g3.4 g144 g3.2 ULO.M U24.*0.21 U84(.3 KNA

t-tvr-rt \4*877 j**w J

(2*04 1 U2.7 LKt34J044 gMl108 J423.0932015.4 t(0*tM J0.11 g«i1603.3 Ul0.14 U402022 g18323.3 K054 U

OuaWanCoda:

8: ThteraaulltoquttajtValyirNaMbaeautatMcompoun^analyltwatalaaaalactadlnibltr*J: ThferaaittatouMbacenaklwadatiunttatvaattTnaia.JN: Thta TIC raauK ahouldbac»nak)aradtquan*la«yata*mila. TnaraauKwaaquvWtud attuning 1 :1 naeonaa wth (w ataodalad Wtmal ttandard.

NO: NetJaltnad.NA: NotAnatyzadU Tlia uttitKHJiyanalymMi analyiaillmiiillihittLtail Tha numarical valua

rapartad rapraaaott *» quanoaitovaiHrton ImM of tia eampeuno/analyla,R - Thata raault ara unutaUa.K: Th»raau>ahouldb*comioaradabteaadhio^ouaiiMMvaat<im<t*,L. TKtrMuUOuanatat • Thit Smpto it a Mnd dupacata ot umpla 8 (4'-«1


QUALITY ASSUNCE

Paga*ot20 fiR30i960

Soil Soring Analytical RaaultaTylar flalrtgariilon PH

Supartund Slta, Smyrna, OalawaraRamadlal lnvt**ga**n/«aMlbillty Study

(AH concantratfont am raponad on a dry «aight batit)

USSTGSCn ———————————————————— 1§IMumb*r

Oata

TCL Volatlla Organle Compound* (utVKfl)

ChloromathanaBramomtthan*Vinyl CNondaChloroathanaMatnylana CMondaAeatonaCarbon Ditulfidat . 1 -Oichloroathana1.1-Oiehlerothantt .2-Oichlraro*th«na (total)Chloroform1 .2-DieMoroathana2-Butanona1 1 . 1-TrichlorathanaCarbon Tatrachlorid*Vinyl AcatataBromodiehforomahan*1 ,2-Dichloropropan*Cit*1,3-0ichloropropanaTrichloroathtn*DibremocNoromahana1 , 1 ,2-TnchloroathanaBanzan*Trant-1,3-0ichloropropant2-ChloroathylvinylatharBromolorm4-Mathyl-2-Pantanona2-HaianonaTatrachloroathana1 . 1 .2.2-TatraehloroalhanaToluanaChlorobanzanaEthvfcantantSty rantTotal Xvtana*

Ttntttlyaly IdantHladVolatlla Organle Compound* (ufl/Kg)

Total UnknownTotal Cyclic Aliphatic Compound!Total Aliphatic HydrocarbonTotal AIM Sobatitutad BanzanaTrimaihyl SilanolC«tamathyl Cvctotatratilaiana

4*87*8/4/n

12 U12 U12 U12 g8 a4*12 U12 g12 g12 g12 g12 U2212 U12 U12 U12 U12 U12 U12 U12 U8 J12 U12 g12 g12 g12 g12 g12 g12 g12 g12 U14012 U960 J

21 JN2* JN12 J*760 JK

1 a-4(i4--m —— I4*57*8/4/82

NO

11 Uit g11 U11 UIt U11 U11 u11 Uit u11 Uit git gtt uit git g11 Utt u11 U11 U11 U11 U11 U11 U11 U11 UIt U11 UIt UIt UIt UIt U11 U11 U11 U11 U

NO

485*98/4ntt8d

11 U11 U11 U11 U11 U11 U11 U11 U11 UIt U11 U11 U11 UIt Uit g11 Uit u11 U11 U11 Utt uit u11 U11 U11 U11 U11 U11 U11 U11 U11 U11 U11 U11 U7 J

NO

4*5*18/4V2

12 U12 g12 U12 U2 B12 U12 U12 U12 g12 g12 g12 g12 g12 g12 g12 g12 g12 g12 g12 g12 g12 g12 g12 u12 U12 g12 g12 g12 g12 g12 g12 g12 g12 g12 g

NO

8/4*2

it gIt U11 UIt UIt Ut* JIt U11 Un git g11 g11 g9 J11 g11 git g11 gtt git g11 g11 u11 git gn git git git gtt gtt gtt gtt gn git git gn g

17 JK

44SM•ISM

NO

12 g12 g12 g12 U12 g12 U12 U12 U12 U12 U12 U12 g12 g12 g12 g12 g12 U12 g12 g12 g12 g12 U12 g12 g12 g12 g12 g12 g12 g12 U12 g12 g12 g12 g12 g

NO

44USusm8J

NO

it g11 g11 Utt git git g11 git u11 U

, » "11 Uit u11 U11 U11 U11 U11 U11 U11 UIt UIt U11 U11 Un g11 U11 U11 Uit u11 U11 U11 U11 U11 U11 U11 U

NO

Ouamin Coot:

B:J: TOaraauXihaUdbacontidaradiquanttatlvaaitinata.JN: Thia11Craii*iriouUbtc9naidaradaou4rtitatv*4«»mMa. TharaauKwaa

qutntttatad attuning 1 :1 rtaponta w*h t» uiooitvd intamal ttandard.NO: Notdataaa*.NA: NMAnalyiadg- TMa compound/analyta wat tralyiad but not am clad. Tha numancal vakia

raportadrtuiaiamitiaquanUlallen/ottaelion fcnrtol tia compeund/analyla.R • Thata raauX art unutaWa


QUALITY^ASSUBANCE

Paga 7

flR30i96l

Sail String Analytical Raault*Tylar Ratrlgaritlon Pit

Supartund Stta, Smyrna, OalawartHamadW »waa*ga*an/Ftain>Uty Study

(AN concantrafcont ara rapoitad on a diy wa*ghl baait)

tainalt LatatanSMTftNumbar*am*4aO*M

TCL samtvtiataa Organle CaHnpouna1* (u*yKa)

!>hanoiBit (2-CNonathyl) Ethtr2-CMorophanol1 ,3>Dichlorob«nzantt ,4-DieMorobanzantBanzvl Alcoholt ,2-Otchlorobanzan*2-Matnvlphanol2,2'-Orybi»(1-Chl<xooroo*na)4-M*thvlph*nolN-Nitroto-di-n-propylamin*HaxachlofotthantNHrobanzantItophoront2-Nilroohanol2,4-Oim*thylphtnolBit (2-Chloroathoivimathant2.4-Oichloraohanol1 ,2.4-TncMorobanzantNaphthalana4-CMoroanilintHaiacMorobuladiana4>Chlora-3-mathy!ohano!2-MalhylnaphthalanaHaiaeMoroeydopantadian*2.4.4-Trichlorophanol2,4,5-TncNofoph«no(2-CMtronaphthatan*2-NitroanilinaMmathylphthalataAoan aphmyla no3-NilroanillnaAcanachthant2.4-Oinilrophtnol4*Nitroph*ne4p%*nto<Mrin1,4-OlnitrotoluatiaOia<hylphthalata4-CMaraohanyl-phanylatharPfciontn*4-Nitroantlina4, *-Q«nitro-2-m«thYphanolN-Nitroaodiphanylamina4-Sromophanyl-phanylatharHaxaehtorebanzanaPaMachJoroananolPhanamftranaAnthractntCarbtzotaDi.n-ButylphthalataFluoctMhafltPyrnn*ButylbanzYlphthalat*3,r >«nl«rob*nzidln«B«nzo(alaMhrae«naBit (2-*thyl1taMtohtha(at*ChrytantQi-n ctylphthalat*B*nio(b)Fhior*nthant$a«zo<k)nuomntnantBanipttlPyrtn*lndano(1,2,3.cd)pyranaD*anl (a.htanmnctntBanzo(i,h,i)eafylant

Tamatlvaiy IdantNlad5«mlv»mna Onianlt CtniBaundt (uaVKf)

Total UnknownTotal Unknown Afipnttk: ComooundaTatal Unknown Aliphatic HydrocamonaHaiadacaooc AadTotal SubaMutM NapMhalantTotal AIM SubaMut**' Banian*Total Aromaac Compound*Octamathyl Cydotatratiloiana

M(r-iar)

•HM

NO

3*0 g3*0 U3*0 U3(0 U3*0 g3*0 U3*0 U3*0 g3*0 g3*0 g3*0 U380 U3*0 U3io g3*0 g3*0 g3*0 U3*0 U3*0 g3*0 g3*0 g3*0 g3*0 g3*0 g3*0 g3*0 g930 g3*0 g930 g3*0 U3*0 g930 U3*0 g930 U930 U3*0 U380 U380 g380 U3*0 U930 U930 U3*0 u3*0 g3*0 U930 U3*0 U3*0 <J3*0 L3*0 U3*0 U3*0 U3*0 U3*0 U3*0 U3*0 U3*0 L3*0 U3*0 U3*0 I3*0 L3*0 I3*0 g3*0 1.

5(0 Jl

a* J

8*0 Jl

•-td -t**)

*/«•?

NA

NA

«-7(r-4144SW8/4/tz

NA

NA

•-7(4-*)4tS*18/4*1

NA

NA

*-7(ir-i«4*Mt*«•*

NO

370 g370 g370 g370 g370 g370 g370 U379 U370 g370 U370 U370 U370 g370 g370 g370 U370 U370 U370 g370 g370 g370 U370 U370 U370 U370 g(10 U370 U(10 U370 U370 Uno g370 g(to g*to g370 U370 g370 U370 g370 g810 g810 U370 g370 g370 g910 g370 U370 U370 U370 U370 g370 U370 U370 U370 U370 U370 11370 U370 U370 U370 U370 U370 g370 U

1143 Jt

87* J»7(0 Jf

*-4(4-*14*f*4*/Mf'«

NO

3*0 U3*0 g380 g380 g3*0 g3*0 g3*9 g3*0 U3*0 U3M g3*0 g3*0 g3*0 U380 U3*0 U3*0 U3*0 u3(0 U3io g3*0 U3*0 U3*0 g3*0 g3*0 g3*0 g3*0 g8(0 U3*0 gMO g3*0 g3*0 gMO g3*0 g9(0 gNO g3*0 g3*0 U3(0 u3*0 u3*0 U940 g««o g3*0 g3*0 g3*0 U840 U380 U3*0 U3*0 U3*0 U390 U3*0 U3*0 U3*0 U3M 113*4 (j31* V3*0 U3*0 g3d U3*4 U3*0 U3(0 U3*8 11

NO

t-t (tr-trl 144MS ]

, ,,.,....*'Mt _J— £ ——— as ———

^

NA

QuaMiari coaia:B: TNaraau»laouaau*»tl>lriyaMbacaijta»aeany)una/aritlyltwJ: TNaraaiAihouldbaoanaklaradaquanitilvttctnMa,JN; TNaTICraauRihauUbacanixtetdavianKMIvaMWnata. flia raauK waa

ouanttatad auumjng 1 1 ratoonta w*> tia utooaltd Inttmtl tUndtnlNO: Not datactad.NA: NotAnalyzadU-Trtocanvound/analyiawatanilyzadbuinMdMacMd. Tnanumaiicilviiua

rtpoftad rtpratants ttia QuanMaton/dttacton frnt ol Via compound/anjlyta.

PtttS

AR30I962


QUALITY, ASSURANCE

Soil Boring Analytical Raault*Tylar Refrlgtrttlon PM

Suparfund SHa, Smyrna, OalawaraRamadlal Im<t«gt8«n/P*tilbillty Study

(AH concantraaont ara raportad on a dry waight batit)

Sampla LaaaaanERM TR NumbarSamvlaOataPwvant Ualalurt

TCL PttttoMa/PCB* (utVK*)

Atoha -8 HCBalt-BHCOalta-BHCGamma-SHC (Lindana)HaptaeMorAldrinHapuchkw Epond*Endotulfan 1Dialdrin4.4'-OOEEndrinEndoauHan II4.4'-000EndotuHan Sulfata4.4'-OOTMathoxvcMorEndrin Kalon*Endrin Akfahyd*Alpha-ChlordanaQamma-ChlordanaToxaphanaArchlor-1016Archlor-1221Archlo -1232Archto .1242Archlo -124*Archlo -1254Archie -12(0

Mir-tlT)4*5788/4/V214

2.0 g2.0 g2.0 g2.0 g2.0 g2.0 U2.0 U2.0 U021 JP0.2* J3.1 g3.* U3.* g3.* g031 JP20 g3.* U3.* U2.0 U2.0 g200 g3* g7* U31 U3* U38 U31 U31 U

•4<14'-1(')4*57*8/4/92NA

NA

*-7(T-41485*08/4/V2NA

NA

•-7(4'*)4*5818/4/V3NA

NA

*-7(1*'-12144 Mtnun«NO

20 U2.0 g2.0 g2.0 g2.0 g2.0 g2.0 g2.0 U31 g3.8 U3.1 g3.8 U3.8 U38 U3.8 U20 U3.8 g3.8 U2.0 g2.0 g200 U38 U77 g38 g38 g3* g38 g38 g

w(4- r48U48/S*21*

NO

2.0 U2.0 U2.0 U2.0 U2.0 U2.0 U2.0 g10 g39 g3.9 g3.9 , U3.* g3.9 U3.9 U3.9 U20 U3.* U3.1 g2.0 g2.0 g200 g3* g*o g3* U3* U3* U3* U3* U

•-* (2T-S4T4858S1/5*1NA

NA

OuatMan Coda:

B: Thit rttuH it qualitalivtly mv»td bicauia t» eempouno/arafrta wat ilto dtttdad « t blank at a «VnH»r ujmamaHm.J: Thit ratutt should ba eomidtrtd t quantiutwa tttmtla.JN: ThiatlC/MuNthouMbtnntidaradaquanliUlivaMlknilt. TnanxuHwat

quanaUMO auurnng t :1 rttponta with fia tttocwtad iilamal standard.NO: NMdatacwd.NA: NotAnriyzadg-mteainpounavanalytawalinalyztdbulmtdtlaclad. Tha numancal vakia

raponad rapratarM tha guarMaiion/daMcton Irrtt ol tia eompound/tnalyta.R • lhata raault ara unutabla.P - ThJt pMtcida/aredor wtt dMKlad on two QC column! but parcant dfltranoa (%0) bawatn tiaaa raportad poaMlva raatMaucaadad tw OC Unit o)25%. lhalowaroltia two rttuM it raportad on naiabornoryanalyiitnipon

Pag* «

4R30I963


QUALIT^SSURANCE

SaN Baring Analytical RaauHiTylar RalrlgaraiMn PM

SupaffciBf SNa, Smyrna, Dalawar*

(AH concantraliona ara raponad on a dry waight batit)

iaiiailt LttadtnEMITKNumtarSamMDaH•araant attlatura

TAL HataH (mg/Kg)

AluminumAntimonyArtameBariumBarylliumCadmiumCalciumChromiumCobaHCceearIron

MaonatiumManojnaaaMarcunrNickalPotattiumSaianiumSilvarSodiumThalliumVanadkimZincCyanida

§-*<r-t»)4*87*nun13.1

(9304.4 UO.M L

0.340.44 g«1714* J4.410.310*00

S3*90.1 J0.12 g34.4158 go.** giO.M g5*50.23 g19.29*2 Ko.s* g

M (i4-.tr)4*S7*nun7.7

3MO4.1 g0.43 gi

0.370.43 g104«3 J2.7087 U(280

134244 Jo.ti g3,5 g14* g3* UtO.M g7220.22 UI0.(17.5 KNA

1-7O--O48SM1/4/M1*.4

73304.2 u10 L

0,4*0.4$ U»412.1 J5.11310(00

(18100 Jo.ti g4.8tsi g0*7 Mo.*7 g5420.22 g17.824.7 KNA

••7 (4-*)4*5*1•MM11.*

591043 g1.8 L3540 330.44 g344478 J423.19440

Ml97.2 J0.11 g11.4153 g0(4 LH0.88 g43(0.23 U1S.7180 KNA

*.7(1*M*V4*8*28/4/W11.4

1020043 U1.4 L33 90 330,44 U4*J15* J3*(79*40

342M8 J0.1729.8154 U3.4 Ut0.** U4410.23 U14.*792 K0.57 U

Ml*-*!44 U4***t14J

9*7045 g1.4 L

——— xi* ————0,920.47 g71488 J8312

11100

81*78* J0.12 g71is* gO.TO gt|OTO g28*0.23 g11.722.0 K05* U

Mar-M-i44 U(tarn

=1IMO "14.1 g6.43 gi

——— TO ————0.41 U92.31* J140.8* USMO

72.812.$ J0.11 U3.4 U144 UOM IXOM g1(80.21 g4.88.7 KNA

OuaMartCoda:

S: TNt mutt it tguattatvtn; inva8d btcauat tw eompounoranilyta w» alto dattcitd in t Mar* it I amlv concanntonJ: Tr»»raauRinauMbacariiid«*daouar*fta«vaatftnala,JN: TMa TIC raauK ahauld ba eontidtrta' a ouanntrtva aatmala ThanMUtwaa

auanHalad munng t .1 rtaeonaawan tm moomd mtarnal itandara.NO: NotoMKSn).NA: NotAnriyzadg-INt compound/analyta watanalyztdbul not dawcwd. THa numtncH vakia

rtporttd rtprtttna t» qmnHUtorvoMactcn ImH o< *ia eompoundyanalyla.R - Thata raauH ara unuttbla.K: Thitraau«ttoiMbacBnariiradabla!a4Non,quaraKatvaaiiiTujta,t:


QUALnf

Pag* 12 ol 20

961,

Soil Boring Analytical RtaulttTylar B«frlg»«tlon PK

Supartund Stta, Smyrna, Oalawiran.m.«H kiy*t«gtton/F>aalliWty Shwy

(All coneamntxsnt ara raportad on t dry wtight baail)

Sampla LaaaaanERHTRNumbar

P*ra*nt Uelatura

TCL Volatlla Organle Compound* (uoVKo)

ChloromathantBromomathanaVinyl ChloridtChloroathan*Mtlhylana Chlorid*Acaton*Carbon OituMdtt 1 -Oichloroathana1,1-Oichlorothana1 2-Oichlroroathan* (total)Chloroform1,2-Oichloroathana2-Butanona1 1 1-Triehlortthan*Carbon TatraeNoridaVinyl AcatattBromodichloremahana1 2-Oichloroorop*n*Cia-1 ,3-Oichlorooropan*TrichloroathanaDibromocNoromahana1 1 2-TriehloroathanaSanzantTrant-1 .3-Oiehloropropana2-Chloroathvlvinyl*th*rBromoform4-Mathyl-2-Pantanon*2-HaxanonaTatraehloroathan*1,1,2,2-TatrachlaroafhanaToluanaChlorobanzanaEthyfcanzanaSty rantTotal Xvlanaa

Tantatlvalv IdantHladVttatHt Organic Compound* (uoVKa)

Total UnknownTotal Cydic Aliphatic CompoundtTotal Aliphatic HydrocarbonTotal Alkyl Subttitutad BanzanaTrimathyl SUanolOctamathvl Cvdotatratilaiana

B-*(4--*14*$**•rr/n• sNO

11 git git gtt git git g11 git git uit git g11 U11 U11 U11 U11 Un u11 U11 U11 U11 U11 U11 g11 g11 gn u11 gn git g11 git g11 git gtt u11 U

NO

8-10 (JMT4*418B/tOV*2

1S

NO

12 U12 U12 U12 UJ12 U12 u12 U12 U12 u12 U12 g12 g12 g12 g12 g12 g12 g12 g12 g12 g12 g12 g12 g12 g12 g12 U12 g12 g12 g12 g12 U12 U12 g12 g12 g

NO

B-10 (20*-27)4*41*B/1QA127.0

NO

11 gtt git g11 U*tt git git u11 g11 Uit un utt git uit u1 U1 Ut ut g1 g1 gi git g11 git gti g11 U11 git g11 gtt git gtt g11 gn u11 U

NO

B-11 (20*27)

t/IOAtt*.*

NO

11 U11 U11 U11 IXtt g11 gti git gn gtt gtt gn gtt gtt gtt gtt g11 U11 g11 Uti UIt Uit uIt U11 u11 . UIt U11 Uti u11 Uit gtt git g11 Uit utt u

NO

Tit* dank t44S7*•amNA

NO

10 L10 I10 L10 I10 I10 1.10 I10 LtO L10 L10 I10 ItO L10 L10 Lto i10 Lto i10 ttO L10 I.10 Lto L10 L10 L10 L10 tto _yto U10' Uto u10 gto uto gto u

NO

TrtaUar*]4*5*3•HMNA

NO

to g10 g10 gto gto g10 g10 g10 gto g10 gto gto g10 g10 g10 g10 g10 g10 g10 g10 g10 g10 gto uto g10 g10 Uto u10 g10 gto g10 g10 gto g10 g10 g

12 JN

Trip Wank 344S8*8/S»2NA

NO

to gto gto g10 g10 g10 gto g10 Uto uto u10 U10 U10 U10 gto uto gto gto gto gto gto gto gto gto uto gto uto g10 Uto uto uto u10 Uto uto gto g

« JN

Pag* 10 •'

OuaffltraCoda:

S: TnferaauRiioualitalivatyimaMbtcauaatM03mpouvyaralytawttal»da«a^J: ThMraautihouMtaaaintidaradaouamtatvatftmaia.JN: THtTKra*u»thmJdbaccntio«adaauarilitatvaat<mala. TntratuKwaa

outnttalad attuning t t ratpontawantlatKoatttd humtl ttandard.NO: Notdataelad.NA: NetAnalyzadg- Thit eempaund/analyta wat anatyztd but not datactad. ThanumtncHvHua

raponad raptttanU tht ouamiuiion/daiaelon ImH ol *>t compaunoyanalyla.R - Intta rtauM ara unutacJa.


QUALITY^ASSU RANGE

Sell Boring Analytical RaauHsTytar Rairlgarttloii PH

Suparfund SHa, Smyrna, OaiawaraRtmadM itvartgalanvFtatlbllHy Sbdy

(AH concantraMnt tra raponad on a dry waight bttit)

tamaJi LurtinEW TM NumiMr•amatoQaiaP*r»*M* U*4*j*jf*

TCL .«mtv«iatM organic G&mpauiXt (uflSKfl)

PhaflOlSis (2-Ch(aroa<hvO Eth*r2-CMoro0h*>nol1 ,3*0ichfofo6anzana1 4>Qichforooanzana3anzv4 Alcohol1 .2-OteMoroto*nzan«2-MalhviDhanof2.2*-Oxytxsi!l -Chloropropana)4-Uathvtohaftoi1N-Nitro«o-*-n-oroovlarmnaKaiachloroathanaNrtrobaflXaftaIftoohorona2-Nitroohanol2,4-OimathylphanolBra (2*CNore*4hoxy) math ana2.4*DicMofOphanoi1,2.4*TneMo/obanzanaNaphthalana4-CMoroamIinahtaxachlof otoutadian a4-CMora>9*mathytDhanol2'M*4hv4n«ohttt«J«naHa xacM oroeydooantadiana2.41f-TneMorophanol2,4,5-TricMorophanoi2-C hlofon apht h alafl a2*NitroamlinaDJmathyjphthalalaAcanaphthylana3-NitroanilinaAcanacMhan*2.4-Dimtroph.jnoJ•t-NitreohanoJDiban.fo4ur.in2,4-DinitroioJuanaDitXhylphlhaJtta4<CMofOOhafiyt>ohaAylathafRtjorana4>Nitroanilina4. t-Dimtro-S-mathvohanofW • ftStrof odioha nyi ami na4-Sromoqhanvl-phanylatharhtaKaehtorebanzanaFantacMoropharvo.PhananthranaAnthracanaC«r azoJaDi*n*8utylphthalataFtuofaMhanaPvranaBu tylba n zy t phlhal ata3.3*-DicMofoban?idln«lan zo<a)«n<hr»caflaBta (2- hylhaxyl.oMhalataChrysaMW-n»oetylpMhafaiaLUrt7O<b}FrxjOftMhaflaBan rofr) Fluora nth anaBanzofolPvranatndano<1 ,2,3<d)pvr«naDtbatu (a.hja ntft rattanaBa*wo<9,h .Opafylana

Tamaitvaly IfamHIa*SamtvvMIla Onanfa Camaauiida (u*/Ka>

Totaf UnknownTotal Lk*fwwrn AMenave ComoeufldtTotal Unknown Aliphafee Hydrocarbon*Haxadacanotc Aoa*Total SwUMutaa1 NaoMhaJanaTotal AIM Subatitutad SanzanaTotal Arematc CompoundaOeumathvl Cydotatratiloxana

B-*<4--r)4*SMvim•*

380 g380 g3*0 g3*0 g380 g380 g3*0 g380 g380 g3*0 g3*0 g3*0 U380 U3*0 U3*0 U3*0 U380 U380 U380 U3*0 U3*0 Ul3*0 U380 U380 U3*0 U3*0 U870 U380 U(70 U380 g380 U870 U3*0 U170 U870 U3*0 U3*0 U3*0 U3*0 U3*0 U870 U(70 U380 U380 U380 U870 U380 U380 U380 U380 U380 U380 U380 U380 U380 U58 J3M g380 U3*0 U380 U3(0 U380 U3*0 U380 U

NO

1-1 9 {T414*4181/1042

11

NO

380 UJ3*0 g3*0 U390 U390 U390 U390 U390 U390 g3*0 g390 g3*0 g3*0 g3*0 g390 g3*0 g3*0 g390 U3*0 g3*0 g390 g390 g390 g390 g390 g3*0 gMO g3*0 g940 g3*0 g390 g940 g3*0 g940 g940 g3*0 g390 g390 g3*0 g390 gMO g940 g3*0 g390 g3*0 gMO g3*0 g390 g3*0 g390 g3*0 g3*0 g3*0 g390 g390 g3*0 g3*0 g3*0 g340 g3*0 g390 U390 g3*0 , u3*0 g

340 JN

7*0 JN

••K (Vt-tt4*41*8/1M2KA

NA

••11 (20-1214*42*8/10/92NA

NA

Tit* Stank 14*57*8/3/tt

NA

Trta Hank!44S83(/**»NA

MA

Trip Wank 344U*WJNA

HA

OuaMartCoda:B:J: ThMraautttruuktbaconudtradiouanttatvaattknalt.JN: Tlw TK ratuK imuM bt comK)ar»d t ouantKatv* tiimita, ThartauRwaa A nn D/*\\/C P\ C/"%D

ojantlattd«iumig1:1r*iponta»i*htiaauoattidfittm itan<HRl. AHHrivJVtL/ PvJHNO: Notdatactad.NA: NotAnalyzadg.Tr**compoxjnoyinih wwtnalyz*dbulrn<d*l*cl*d. Tht numtncal vaki* QUALITY: ASSURANCEraponad rtprtatnti lha ouinliuv»vd»lac«en fcrit o( tia compound/analyla.

Pagan

flR30J966

RELEASE BY

Soil Boring Analytical Raault*Tylar Rairlgaratlon PH

SuparfuiMj Sha, Smyrna, DatawareRimidlal awaa*ga*an/F»aalb«Ky SkMy

(All concantraliona art raporttd on a dry waight batit)

4-.4.L.C———ERUTRNumbtr

Ptraant Ualtluoi

TCL Paatlelda Ci* (pf/Kf )

Atoha-aHCBaia-BHCOatta-BHC0*mmt-8MC (lindin*)HaotachlorAldnnHaotachlor EpondaEndotuHwi 1Dialdrin4.4--OOEEndnnEndoauKan II4.4--000Endntulfan SuMata4.4--OOTUMhonchlorEndrin Kattn*Endnn AldanydaAlpha-C MordantGamma-ChlordanaToxaphanaArchlor-101*Arehlor-1221Archlor-1232Archlor-1242Arehlor-124*Archlor-12S4Archlor-tZSO

an*

•»

NO

i* g18 U18 U1.1 U1.8 U1.8 U1.8 U18 U3.S U3.4 U3.* U3.* g3.* g3.* g3.* gt* g3.* git u1.8 U11 U180 U38 U73 U38 U38 U38 U34 g3* g

4M1*

IS

NO

2.0 g2.0 U2.0 U2.0 U2.0 U2.0 U2.0 U2.0 U39 U3.9 U3.9 U3.* g3.* g3.9 g3.9 g20 g3.9 g3.9 g2.0 g2.0 g200 g39 g79 g39 g39 g39 g39 g39 g

4*41*

NA

NA

4*420

NA

NA

4*57*

N*

NA

4*5*1

NA

NA

445J88/S/afNA

NA

OualinareCoda:

B: Trferaauft it ojuaMitVtly invalid btcautaftaoimpour iraJ: TMa ratuRahouM bt coraidirad a ouamttativa aatimata.JN: TNaTICraattilwjMbacomid*adaopanMlhw4**rnatt. ThtrttUtwat

auanttatad attuning 1:1 ratponta *an t<a attoaatad Mama! ttancard.NO: Notdtttctta.NA: NotAnatyzafg-TNacomaound/anilylawat«nalyzadbolnotdatacltd. Tha numaricH vakja

rtponad raprttaiiU the auant*ttan<dalaclon fcnt o( tw compound/analyta.R • Thaaa ratuK wa unutaota.P - ThJa pattoda/andor wat oatactad on iwo OC columnt but parcant omartnoa (%0) bakwtn Iwta raponad poaMvanMuMncaadad t» CCknrt of 25%, Tha kwnar ol ma «•» rxuHl it raporttd en tia Itbcrtlory tnHyvt npon.

AR30I967


QUALITY ASSURANCE

San Boring Analytical RaaultaTylar Rafrlgaratlon PH

luptrtuad SHa, Smyrna, Oaltwar*RmiidM kwaadgtalan/Ftaaiawty s*jdy

(AN oancantrationt ara raponad on a dry waight batit)

tampM LaataanUtUTRNumMrlamaltOalaPtnant HaMurt

TAL Matait (moVKt)

AluminumAntimonyArtanicBariumBarvlliumCadmiuniCalciumChromiumCobaltCopparIronL*adMaonaawmManojnat*MareunjMckalPotattiumSataniumSilvarSodiumThalliumVanadkjmZincCyan! da

M<4T*)

•T7W1*

71604.1 g0.43 gL•£?0.3Z0.43 U27*59 J3.4t.S7**03.4 L1(0470 J0.11 U3.5 U14* U0.8S Ulo.«* g53.00.22 _..._U12.57.1 KO.M g

S-IOtzM*)4*41**/10/*213.7

13*00 L45 U3.41*40*2048 g7M18.889801780021.0 J14901970.12 g8.44440.71 gL0.71 gLM* B0.71 UL31828.1 K0.5* U

t-\0 (XT-IT)4*41*8/1 am7.7

5040 L4 1 u0.722506.2*043 U78.13.21.80.87 U74 to24 J11*13.90.11 U35 U14* U0.8S Ut0.84 Ul332 BOK UL8.19.4 KNA

»-iin«-zn4*42*art«/*til*

4*00 L44 g0.4* U27.70.4*0.4* g8S2405.70.92 U10*00Z2 J12S4*30.11 g3.7 g154 UO.M IX04* (A312 B088 gt.114104 KNA

OuaMart Coda:

B: TrnratuftitOAuMair«tfyimaMb*caute»MaxnpourKyvu^J: 114araaullllmMt»coniidartdaquanlKnvat«»mita.JN: TmTKraauHihouMbaconfidtradiquanlKatwaaamMa, TharaauRwat

tuanlHatad attuming 1 : 1 manna with tia attoaatad intamal ttandard.NO: Notdttactad.NA: NotAnalyztdg - INa campound/analyla wat tmlyztd but not datactad. Tha numarteal valua

rttortadr»cr«atnui quintlatorvotiac»onliTi<olt)a compeundnintlyia.R - Tnata raauK ara unutabla,K:L: TMa n>aJmutiial«*un fcnlt a culd ba contidanid t btttad low ouantUUva aaUmata.

APPROVEDR'Hl.lIAGE BY

QUALITY AG:u

/zfafe'GER DATE

AR30I968

Soil Boring Analytical SttulttTylar Ralrlgaratloa PH

Supartund Slta, Smyma, D*l*wartRamadlal kwta*ga«on*Malblllty Study

(AH concantrauoni ara raportad on a dry waight batia)

ISampW LamtanIWITRNumMTSampla DataPtraant Uataaxa

TCL Valatlia Organle Compound* uiaVKa)

ChioromathanaBromomtthantVinyl CntondaChleroathanaMalhvlana CMorida

Carbon DituHlda1 1-Oichloroathant1.1-Oichlorothanat 2-Diehlroroathana (total)Chloroform1 2-Oichloroathana2-Bulanona1.1.1-TrichlorathanaCarbon TatrachtoridtVinyl AcatataBromodichloromahant1 ,2-OichloroorooanaCit-1 3-OichloropropantTrichloroathan*Dibromochloromahana1 1 2-TrichloroathanaBanzanaTr*nt-1 ,3-Oichloropropana2-ChloroathvlvinvlatharBromoform4-Mathvl-2-Pantanona2-HaxanontTatraehloroathana1 1.2.2-TalrachloroalhtnaToluanaChlorobanzantEthvlbanzan*StvrantTotal Xylanaa

Tanlttlvtly IdantHIa*Vaiallla Organle Compound* (uoyKa)

Total UnknownTotal Cyclic Aliphatic Compound*Total Aliphatic HydrccaibonTotal Alkvl Subatitutad BanzanaTrimathvl SilanolOctamalhvl Cvclotatratilaiana

Trt»oUnk4

— w5a ——NA

NO

10 g10 g10 g10 g10 gto g10 Uto uto u10 U10 Uto gto g10 U10 U10 Uto gto gto gto gto g10 Uto g10 g10 U10 uto g10 g10 gto g10 g10 g10 gto g10 g

NO

8/7*1NA

10 g10 U10 g10 g10 Uto u10 Uto u10 g10 gto g10 gto uto uto g10 g10 gto gto g10 g10 Uto u10 g10 U10 U10 U10 U10 g10 g10 gto uto gto uto gto g

7 JN

•flamNA

NO

10 g10 gto u10 g10 gto g10 g10 g10 U10 g10 g10 U10 U10 g10 g10 gto gto uto uto g10 g10 U10 Uto g10 u10 g10 g10 U10 uto gto g10 gto gto u

8 JN8 JN

t/3/tlNA

10 U10 U10 U10 g10 Uto g10 U10 U10 g10 gto gto g10 U10 U

10 gto uto uto u10 U10 gto g10 g10 U10 u10 Uto uto g10 gto uto u10 U10 Uto u10 U

9 JNS JN

FM -

8/3/S2NA

NO

10 Uto u10 g10 Uto u10 U10 Uto u10 g10 u10 g10 g10 gto u

10 uto g10 g10 gto gto u10 g10 g10 g10 g10 U10 g10 gto g10 g10 g10 gto g10 gto g

8 JN

"5TJ —4*8328/10/92NA

NO

10 g10 Uto u10 U10 U10 U10 U10 U10 U10 U10 Uto g10 U10 U

10 g10 U10 gto gto gto gto gto gto uto g10 Uto g10 gto u10 Uto u10 U10 Uto gto g

NO

8/10AWNA

to u10 g10 Uto u10 gto g10 U10 g10 Uto g10 Uto uto gto g10 g10 gto uto uto gto g10 gto gto u10 gto u10 U10 gto uto u10 Uto gto g10 gto g

NO

QuaMitntCoea

B:J. IhjtratuXaheuMbacontidariidiauamiafvatMmita,JN: ThmTICrttuKinouttbacoritioKMaovMtalmMMnMa IharatUtwat

ouanttalad attunng I 1 rttponta wan tit tuoattad ntamu standard.NO: Notdaataad.NA: Not Anah/zadU-TT»»eem>uund/analylawttanalyza8butnotaaltelad. Tht numaneal vakja

rtponad rapratantt the ouantitttowdalacaon fcnrt ol tia eompcunoVanHyl*.R • That* rtau» an unutabM.


QUALITY ASSURANCE

HR301969 ~————— °ATE

Soil Boring Analytical Raault*Tylar Rafrlgaratfen PM

Suparfund SKa, Smyrna, Dalawar*RamadM kwtttlga8*n/F«a»lblllty Study

(AH concantraaont ara raponad on t dry wa<ght bant)

Samt4t L*«a*anERUTRMunbarTaiiMli rv rPwaant tfalatura

TCl. 3amhrolat*a Organla Campoun** (uo/Kg)

PhonalBia (2-CNoroathyl) Ethar2-Chlorephanol1 ,3-OicMorobanzana1 ,4-DtchJorobanzanaBanzvl Alcohol1 .2-0*cMorobanzan*2-Mathylphanal2,2I-OiYbii(1-CMon>propan*)4.Mathylph*noiN-Nitroto-dt-n-proevlaminaHaxacNaroathanaNStrobanzanaItophorona2-Nitrophanol2.4-OifflathylphanolBit (2-Chloro»thoiy)mathan*2.4-Otchlorophanol1.2.4.Tnchlorob*nz*naNaphmalana4-CMoroanilintHaxicnlorobutadiana4-CMore-3-mathvlphanol2-MathvlnaohmllanaHaxacNorocydopantadiana2,4,(-Tnchlorophanol2.4.5-TncMoroohanol2-Chtomnaphthalana2-NitroanilinaDimathvlphthalataAcanaphmylana3-NitroanilinaAcanaphthana2.4-Oinftrophanol4-NitraohanolDibanzofuran2,4-DinitrotoluanaDiathvlphlhalata4-CMorephanyf-phanvlatharFktorana4-Nitroanilin*414-Oinitro-2-mathyohanolN-Mtrotodtahanvlamina4-Bromophanyl-phanylalharHaxachloroeanzanaPantaehloroohanolPhanantnran*AnthraeanaCarbazoUDi-n-ButvlphthalalaFkjoranthaflaPyranaButylbanzvlphthalataJ.y-OiehlorobanzidlntBanzofalanthracanaBit n-athylhaxyllphlhalataCtuytantOi- n-aetytpht halaltBanzo(b)nuoninthanaBanzoOOFtuoranthanaBanze(a)Pvranalndano(1 ,2.3-cd)pyranaDibanz(a,h)anthnicanaBanzoU.h.Ooarvlana

Taatatlvaly IdantMlatSamlyalatlla Orgaale Compound! (tm/Ka)

Total UnknownTotal Unknown Aliphaac CampoundtTotal Unknown Altphaac HvdrocatbontMaxadacanotc AodTotal Subttilulad NaphthalanaTotal Alkvl Subttnutad BanzanaTout Aromatic CompoundaOctamathyl Cydotatratiloxana

Trip Wank 44(IM•ItMNA

NA

NA

Trip Hank 54*417tnrnNA

NA

NA

Trtp Hank 848*338/t a/nNA

NA

NA

EB-24(S7S•ana.NA

10 Uto u10 U10 U10 U10 U10 g.10 g10 g10 g10 Uto uto u10 U10 U10 g10 g10 g10 gto uto uto uto u10 gto g10 g25 g10 g25 Uto uto ga g10 U25 U25 g10 g10 Uto uto gto g25 g2S gto gto gto u25 u10 g10 g10 U10 U10 Uto uto gto uto u7 Jto g10 g10 U10 U10 Uto uto uto u

5 JN

F8VJ4*574i/l*JNA

to gto gto gto g10 g10 g10 gto gto u10 U10 Uto uto uto g10 gto gto g10 Uto u10 u10 g10 g10 g10 Uto uto u25 gto g25 gto g10 ga gto ua u25 Uto gto gto gto gto g25 g2* gto g10 U10 U2S U10 U10 U10 g10 gto gto gto gto g10 g2 J10 g10 U10 U10 U10 Uto gto gto g

3 JN

EJB-34*8328/t onNA

10 L10 Li10 L10 U10 L10 U10 U10 U10 LI10 U10 LI10 U10 LI10 Ito ui10 LI10 LJ10 LI10 V10 Lto i.10 LtO L10 l»10 L10 L25 L10 LI24 LI10 U10 U25 U10 L25 U24 1110 U10 LJto uto u10 L2S U2S gito gito uto ui2i U10 LJ10 g10 LI10 Uto uto gito uto i>to L8 JtO LI10 LI10 LI10 U10 U10 LI10 U10 U

NO

F*-J4U31*nt*iHA

10 L10 L10 L10 L10 L10 U10 t10 U10 L10 U10 Li10 Li10 LI10 L10 Lto u10 LJ10 LI10 L10 L10 I10 L10 L10 L10 L10 L25 U10 LJ25 U10 LIto ua u1* Ll2* L>28 Ll10 Ul10 m10 Ll10 U10 Ua u25 Ul10 Ul10 U10 U25 U10 Ll10 LJ10 U10 g10 LJto g10 U10 L10 LJ08 J10 Ui10 Ut* uto u10 Ll10 Llto u1* U

NO

( JOuaMartCada:

l**ml«c_»pp.pOVEDJ: Trtartai«ihouttbtcanaxfcradtouantta*ra*t»mttt. MrrriWVfc.«wJN: TNaTICraai«>tauMbacontic«rtdlouanMallvaattimata. TharaauKwat

euanktttad auumwig 1:1 ratpontawahtwatsooattdinlamtl standard.NO: NetdiMciad.NA: NotAnalyzadU-TMt oompaund/anatyta watinHyztd but not datacMd. Tha numaneal vakia

rtporMd raprafami ma euintiuiorvoatacMn krM ol tia cempounoyanalyta.

Pata 14

AR30I970

RELEASE BYQUALITY ASSURA

~

Soil Boring Analytical RatultaTylar Ralrlgaratlon Pit

Suparlund Slta, Smyrna, OalawaraRamtdM lnv««»9««0(VF««albtHty SUdy

(All concantratwnt ara raportad on a dry waight batit)

mISampla LaaaJanlERUTRNumbarSampiaoaiajPwwnt Kalctura

TCL PattteMa/PCSJ* (ua/Kal

Alpha-8HCB»tt-8HCDalta-eHCGamma-BHC (IJndana)HaptachlorAldrinHaptachlor EpocidtEndeaulfan 1Dialdrin4.4--OOEEndrinEndotuKan II4.4--OOOEndotuKan SuHata4.4--OOTMathoxvchlorEndrin KatonaEndrin AkfahvdaAlpha-ChlordanaGamma-ChlordanaToxaphanaArehlor-101*Arehlor-1221Arehlor-1232Arehlor-1242Archlor-124*Archlor-1254Arehlor-1240

Trip dank 44*59*t/t/*lNA

NA

Trip Blank S4*4178/7/*2NA

NA

Trip Wank (4(8338/10/92NA

NA

EB-248575w/*2NA

NO

o.os go.os goos goos go.os go.os g0.05 goos go.to go.to go.to g0.10 go.to g010 Uo.to u0.50 uo.to go.to go.os go.os u5.0 U10 gt.a gt.o gto gt.o u1.0 Ui.o g

F4-24(574t/3/*3NA

NO

0.05 goos go.os goos goos uo.os uo.os g0.05 goto go.to go.to go.to u0.10 Uo.io go.io goso go.io go.io go.os goos g50 gto u2.0 U1.0 U1.0 Ut.o g10 U10 U

ca-34*832t/10/92NA

NO

O.OS UO.OS LlOOS Uo.os go.os go.os uo.os go.os uo.io g0.10 Uo.io go.io g0.10 Uo.io go.io go.so go.to go.io go.os uo.os u5.0 gi.o g2.0 Uto ut.o u1.0 U10 gi.o g

FI-3448311/10/11NA

NO

OOS UO.OS LJ0.05 Uo.os goos go.os uo.os goos u0.10 go.to go.to uo.to g0.10 go.to uo.to go.so g0.10 g0.10 Uo.os go.os gs.o gt.o g2.0 U1.0 gt.o ut.o gto gt.o g

auaWani Coda:

B: TNt ratuH it ouuutvaly invalid bacauia tia compound/anHyta wat alto datactad in t Mink it t arnjiv ooricannton.J: TNt raault ahoukl ba contidarad a ouarKRttva Mlimttt.JN: Thit TIC ratu* thoukt ba contidarad a ouanatttva atimtta. TharatuKwat

quanattlad tttunng 1:1 ratponta with tia attoottad Inlamal ttandtrd.NO: Notdatactad.NA: NotAnHyzadg • Thit eempound/antlyta wat inalyzad but not dtltcttd. Tha numarical valua

raportad rapratantt tha qutntitalian/dattofon Imt ol tw oompounoYanatyta.R - Thata raault ara unuublaP - Thit patikioWaredor wat dauctad on two OC cdumnt but parcant oniaranoa (%0) batwaan tiata raportad poaitva raauMMcaadad tia OC Smrt of 25%, Tha lowarottwtMrttuia it raoonad on tw laboratory aruly»! report

Pag* IS

AR30J97I


QUALITY ASS'IRANCE

DATE

Flald Blank Analytical RaauK*Tylar Rafrfgaratlon Ptt

Suptrfund Slta, Smyrna, DaliwirtRamaalal ktvtatgaaen/Ftaalblllty Study

Sampla LotafanERMTRNumbtrSampla DataPwtint IMttura

TAL Hatala (ua/L)

AluminumAntimonyArtanicBtnumBarvlliumCadmiumCalciumChromiumCobaltCopoarronLaadMagnatiumManama*MarcuiyNickalPotattiumSalanhjmSilvarSodiumThalliumVanadkjmZincCvaraoa

Trip Wank 14*87*MMNA

NA

Trip Mmk 24SS838/4*2NA

NA

Trip Wank 3445*8•ISMNA

NA

.

Trip Blank 4445*58/8/82NA

NA

Trip Wankf4(417trrtnNA

NA

TriaWank*4*8338/10/82NA

NA

IB-248S7S•I3MNA

20 g19.22.0 gi.o g10 g2,0 g41.23.0 g4.0 g4.0 g319t.o g36*i.o g0.20 gt* g878 g3.0 U3.0 g27 gt.o g3.0 g4,7to g

F*-l44174tarnNA

20 g1* g2.0 g1.1to g2.0 g54.13.0 g4.0 g4,0 g37,91.0 U33.7t.o u0.20 g14 g47* Li30 L3.0 g27 Li.o g3.0 Ls.s10 L

El-34*131•HUMNA

2*t* g2.0 g1.8to g20 U72.13.0 U4.0 g4.0 g4491.0 LJ(4,27,»0.20 g1* U87* L3.0 L3.0 U1113.0 U3.0 U7310 L

n-t I48(31 1•neM LNA,„„._[

20 Ui* uto uiti.o _y2.0 g17.110 U4.0 U40 gt*.31.387 U1.0 U0,20 gK g87* g3.0 LJ3.0 U38.83.0 U3.0 U8.410 Ll

OuaHartCada:

B: Thit raault la Qjuaaia8»alylnya»dbKauta tha eon ouneyanalytt wat alaa dill clad In aJ: ThWrtau»inoJdbaojnaloaradao)uanlltatyaa»amat«.JN: ThfeTWraauRihouttbaconaidaradicijantMKiatttlmala, Tharaauttwaa

autmmtd ataunUng 1:1 raapenta wHh tia attocinid Intamtl tandtntNO: Notdtnetad.NA: NotAnah/zadU-Tr»»eampcund/inaly»wttanatyzadBulnold«ltclad. Tnanumtncatvalua

rapartid raprttanli t>a autntlatlon/datacllon fcnH ol tia eompounoyantlyta.R • Thaaa rttuK ant unuutt*.K: ThltraauMahouldbao»itle»»<ablatadhtghojitri*B*»at«niitt.L

APPROVED FOR

SR30I972

Analytical Quality AssuranceReport Tyler Refrigeration PitSmyrna, DelawareGround Water Sampling EventCollected 9 September through 11September 1992


9 December 1992


File No.: C2702.04.01

5R30I973

Analytical Quality AssuranceReport Tyler Refrigeration PitSmyrna, DelawareGround Water Sampling EventCollected 9 September through 11September 1992


9 December 1992

iwne M.Quality Assurance Manager

Furshotam L. BatraQuality Assurance Chemist


File No.: C2702.04.01

AR30l9.7lt

TABLE OF CONTENTS

1.0 INTRODUCTION 1

2.0 ORGANIC DATA 32.1 GENERAL ORGANIC DATA QUALIFIERS 42.2 ORGANIC DATA QUALIFIERS 4

3.0 INORGANIC DATA 83.2 INORGANIC DATA QUALIFIERS 9

4.0 SUMMARY 11

ATTACHMENTS

1 METHODOLOGY SUMMARY/METHOD REFERENCES

2 DATA SUMMARY TABLES

LIST OF TABLES

1-1 Summary of Data Received

flR30!976

1.0 INTRODUCTION

This analytical quality assurance report is based upon a review of allanalytical data generated for ground water samples and associated fieldblanks collected from 9 September through 11 September 1992 at the TylerRefrigeration Pit, Superfund Site, located in Smyrna, Delaware. Theanalytical methods which were used in these analyses are summarizedand referenced in Attachment 1. The sample locations, ERM andlaboratory sample identification numbers, dates of collection, and analysesperformed are presented on Table 1-1. Data summary tables presentingthe validated and/or qualified analytical results are provided inAttachment 2.

All data for the analyses were reviewed for adherence to the specifiedanalytical protocols. All results have been validated or qualifiedaccording to general guidance provided in "Region HI Modification ToNational Functional Guidelines For Organic Data Review, Multi-Media,Multi-Concentration (OLM01.0-OLM01,6 June, 1992)" and "Region mModifications to the Inorganic Functional Guidelines, December 1990."


SampleLocation

• : s-i

S-2

S-3

'. S-4

S-5

S-6

ERM T.R. LaboratoryNumber ID Number

47626 920907114929711492097014

47618 920907108929710892097008

47613 920907102929710292097002

47620 920907110929711092097010

47616 920907105929710592097005

47624 920907118929711892097018

Date AnalysesMatrix Collected Performed

Water 9/11/92 [1], [2][3][41

Water 9/10/92 [1], [2][31141

Water 9/9/92 [11, [2][3][41

Water 9/10/92 [1], [2][3][41

Water 9/9/92 [11, [21[31[41

Water 9/11/92 [1], [21[31[41

/IR30I97TTHEERMGSOUP fl R X fi I A -flGViRK EQUIPMENT COMPANY- TYLER REFRIGERATION 71102702.04.01-12/9/92

Table 1-1 Summary of Data Reviewed (Continued)

SampleLocationD-l

D-7t

D-2

D-3

D-4

D-5

D-6

EB-1

FB-1

TB-1

TB-2

TB-3

ERMT.R.Number47627

47628

47619

47614

47621

47617

47625

47622

47623

47631

47632

47630

LaboratoryID Number920907117929711792097017920907120929712092097020920907109929710992097009920907103929710392097003920907111929711192097011920907106929710692097006920907119929711992097019920907112929711292097012920907104929710492097004920907107

920907113

920907121

MatrixWater

Water

Water

Water

Water

Water

Water

Water

Water

Water

Water

Water

DateCollected9/11/92

9/11/92

9/10/92

9/9/92

9/10/92

9/9/92

9/11/92

9/10/92

9/9/92

9/9/92

9/10/92

9/11/92

AnalysesPerformed

[11, [2][3][41

[11 [2][3][4]

[11, [21[31[4]

[11, [2][3][41

[11 [2][31[4]

[11, [2][31[41

[11, [21[3][4]

[11, [21[3][41

[11, [21[31[4][11*

[11*

[ir

[11 - Target Compound List (TCL) Volatile Organic Compounds plus vinyl chloride by US EPA

Method 8010.

[21 - Target Compound List (TCL) Semivolatile Organic Compounds.[31 - Target Compound List (TCL) Pesticide/PCBs.[4J - Target Analyte List (TAL) Metals and Cyanide (total and dissolved)t -This sample is the blind field duplicate of sample D-l.* - This sample was not separately analyzed for vinyl chloride by US EPA Method 8010.

THEERMGBODP S D BLJ lEt.,»«PMEOTCOMPA rlf-TYIiRREFRIGERATK)NP C (1 04 1--12/9/92

2.0 ORGANIC DATA

The organic analyses of ground water samples and associated field blankswere performed by CHESTER LabNet's Houston, Texas facility. Thesamples were analyzed for US EPA Contract Laboratory Program (CLP)Target Compound List (TCL) volatile organic compounds, semivolatileorganic compounds and pesticide/PCBs, as specified in Table 1-1. Allsample analyses were performed according to the protocols specified inthe OLM01.6 Statement of Work (SOW) for Organic Analyses. In addition,all samples were analyzed for vinyl chloride by US EPA method 8010.For the organic fractions analyzed by GC/MS, mass spectral librarysearches were performed to match sample spectra whose characteristicsdid not resemble those of the targeted compounds. This was performedfor up to ten volatile and twenty semivolatile extraneous peaks. Validatedresults for these library searches are found in the data summary tablesunder the heading "Tentatively Identified Compounds" (TICs).

The findings offered in this report are based on a detailed review of thefollowing deliverables the CLP format: chain of custody documentation,holding times, laboratory method and field blank analysis results,surrogate compound recoveries, matrix spike compound recoveries andreproducibility, duplicate analyses, bromofluorobenzene (BFB) anddecafluorotriphenylphosphine (DFTPP) mass tuning results, initial andcontinuing calibration data, internal standard area performance,pesticide/PCB resolution check sample results, DDD/Endrin breakdown,pesticide compound retention time shifts, summary for single andmulticomponent analytes, pesticide analysis sequence check, pesticidecleanup efficiency verification, pesticide identification, pesticide/PCBdual column analysis precision, quantitation of results, and qualitativemass spectral interpretation.

The quality assurance review of the data has been performed according tothe "Region HI Modification To National Functional Guidelines ForOrganic Data Review, Multi-Media, Multi-Concentration (OLM01.0-OLM01,6 June, 1992)" with the following exceptions:• ERM-established criteria was used to evaluate sample results based


• For the volatile organic analyses where high surrogate recoveries areobtained, ERM has not qualified the quantitation limits as estimated.

THE ERM GROUP H M 3 $l4X&jcQfr&Em COMPANY- TYLER REFRIGERATION PIT C2702.04.01-:•12/9/92


2.1 GENERAL ORGANIC DATA QUALIFIERS

• As required by US EPA protocol, all tentatively identified compounds(TICs) have been marked with a "JN" qualifier on the data summarytables to indicate that they are quantitative estimates, and the resultsare quantitated assuming 1:1 response with the associated internalstandards. ERM has regrouped the TICs according to chemicalclassification and has reported on the data summary tables only thoseTICs which have been demonstrated not to be the result of laboratorycontamination or an instrument artifact.

• As required by US EPA protocol, all compounds which werequalitatively identified at concentrations below their respectiveContract Required Quantitation Limits (CRQLs) have been qualifiedwith'T' qualifiers on the data summary tables to indicate that they arequantitative estimates.

2.2 ORGANIC DATA QUALIFIERS• Area counts for the semivolatile internal standard compound

perylene-di2 were substantially below the quality control (QC) limitsfor the initial semivolatile organic compound analysis of the groundwater sample S-4. This indicates a substantial drop in instrumentsensitivity or system performance for the compounds quantitatedwith this internal standard due to sample matrix. This sample wasreanalyzed and again yielded internal standard area counts belowthe QC limits for the specified internal standard. Sample results havebeen reported using the initial analysis in which the internal standardareas are closer to the associated continuing calibration standard. Thepositive results and/or quantitation limits reported for semivolatileorganic compounds that were quantitated using this internalstandard should be considered quantitative estimates. This has beenindicated by placing "J" qualifiers next to the positive result and/orquantitation limits reported for semivolatile organic compounds onthe data summary table for this sample.

• Poor recoveries were obtained for four acid-extractable surrogatecompounds phenol-ds, 2-fluorophenol, 2,4,6-tribromophenol, 2-

THEERMGaOUP <qijUK-1C WPMENT COMPANY-TYLER REFRIGERATION P!TC27Q2.04U)l-12/9/92HR30TW"

chlorophenol for the semivolatile analyses of ground water sample S-3. These low recoveries are summarized below and may be the resultof matrix interferences present in the samples. The sample was re-extracted and again yielded low recoveries for the specified surrogatecompounds and for base-neutral surrogate compound terphenyl-di4.The results have been reported from the initial analysis. The positiveresults and/or quantitation limits reported for acid-extractablefraction in the analysis of sample S-3 should be considered biased lowquantitative estimates. This has been indicated by placing "J"qualifiers next to the positive results and quantitation limits reportedfor acid-extractable fraction on the data summary table for thissample. ERM has not qualified the quantitation limits for acidfraction in this sample as unusable "R" to allow for the maximumpossible use of the data._________________•___________

Surrogate Recovery QC LimitsSample Compound (%) (%)

S-3 Phenol-ds 1 10-110

2-Fluorophenol 1 21-110


2-Chlorophenol-d4 3 33-110

S-3 RE Phenol-ds 5 10-110

2-Fluorophenol 4 21-110


2-Chlorophenol-d4 5 33-110

Terphenyl-dl4 31 33-141

• The quantitation limits reported for the semivolatile organiccompound 4-nitrophenol in the ground water samples S-l, S-6, D-l,D-6, and D-7 should be considered biased low quantitative estimates.The continuing calibration relative response factor (RRF) for thespecified compound in these samples was less than 0.05. Thisindicates a lack of instrument sensitivity for the analysis of thiscompound. No positive results were reported for the this compoundin these samples. The quantitation limits for 4-nitrophenol have beenmarked with "J" qualifiers to indicate that they are quantitativeestimates.

• Ground water sample S-l was analyzed for volatile organiccompounds at a five-fold initial dilution. This dilution wasperformed because of the presence of the matrix interference and/orsuspected high concentrations of the volatile organic compounds.

THEERMCBOUP H l\ A H / A^ SCLARK EQUIPMENT COMPANY- TYLER REFRIGERATION PIT C27Q2.04.01-12/9/9298;

This dilution was required to prevent saturation of the instrumentand to allow quantitation of the compounds within the linear range ofthe calibration curve. However, this dilution has resulted in elevatedquantitation limits for non-detected compounds in these volatileorganic compounds. The possibility of elevated quantitation limitsshould be noted when assessing the data for the qualitative absence ofnon-detected volatiles in this sample.Low recoveries were obtained for surrogate compoundsdecachlorobiphenyl and tetrachlorometaxylene for the pesticide/PCBanalyses of the samples presented in the following table. Theserecoveries may be the result of inadequate extraction efficienciesand/or matrix interferences in these samples. Laboratory alsoprovided analytical results for blank spike samples which wereextracted with each batch of samples extracted. The recoveries forthese blank spike samples were consistent with the recoveriesobtained for the actual samples. This indicates that the low surrogaterecoveries were probably due to poor extraction efficiencies. Thelaboratory was contacted concerning the low recoveries, andindicated that historically, low surrogate recoveries have beenobtained for the analysis of both aqueous and solid samples, and thatthey have been unable to pinpoint the source of the problem.Therefore the positive results and quantitation limits forpesticide/PCB compounds in these samples should be consideredbiased low quantitative estimates. This has been indicated by placing"J" qualifiers next to the positive results and quantitation limits toindicate that they are quantitative estimates.

THEHSMGROUP . SCLARK BQU:PME {tCO I»-TVT RREFR GERATlONP •C2702.04.01-12/9/92RR30T9S2

Sample ___Surrogate Compound Recovery (%)___QC Limits(%)S-l Tetrachloro-m-xylene (172) 60-150

Decachlorobiphenyl 43 (39) 60-150

S-2 Decachlorobiphenyl 27(24) 60-150





D-l Decachlorobiphenyl ' (46) 60-150

D-2 Decachlorobiphenyl 43(44) 60-150




EB-1 Decachlorobiphenyl 52(53) 60-150

• The positive results reported for pesticide compounds gamma-BHC(lindane), dieldrin, and/or endrin in the ground water samples S-2and S-3 should be considered quantitative estimates. Dual columnprecision criteria were exceeded for these samples. This has beenindicated by placing "J" qualifiers next to the positive results reportedfor gamma-BHC (lindane), dieldrin, and endrin on the data summarytable for these samples.

• Ground water sample D-l and its blind field duplicate sample D-7were analyzed for volatile organic compounds to evaluate overalllaboratory and sampling precision. Sampling and laboratoryprecision was determined by comparison of the relative percentdifference (RPD) of the positive results reported for the compoundswhich were confidently detected in the original sample and its blindfield duplicate. No positive volatile results were reported for thesespecified samples.ERM's blind field duplicate precision criteria of 20% used to evaluatethe blind duplicate volatile organic compound results and 25 percentfor semivolatile and pesticide/PCBs results was met for samples D-land its blind field duplicate sample D-7.

THEERMGBOUP 7CLARK EQl FM!jhr O A -TYLmREFRIGERATiONPITC27Q2.M.01-12/9/92

flR3C

3.0 INORGANIC DATA

The inorganic analyses of surficial soil samples and associated field blankswere performed by CHESTER LabNet's Houston, Texas facility. Thesamples were analyzed for USEPA CLP Target Analyte List (TAL) metalsand cyanide, as specified in Table 1-1. All sample analyses wereperformed according to protocols specified in the ILM01.0 Statement ofWork (SOW) for Inorganic Analyses.

The findings in this report are based on a review of the followingdeliverables reported according to the CLP format: chain of custodydocumentation, holding times, laboratory method and field blank analysisresults, matrix spike recoveries, laboratory and field duplicate analysisresults, detection limits/sensitivity, initial and continuing calibrations,CRDL standard analysis, laboratory control sample results, ICPinterference check sample results, ICP serial dilution results, graphitefurnace atomic absorption (GFAA) spectroscopy, post-digestion spikerecoveries and duplicate burn results, standard addition results,qualitative identification, and quantitation of results.

The quality assurance review of the data has been performed according tothe requirements of the document entitled, "Region HI Modifications to theInorganic Functional Guidelines, December 1990", with followingexceptions:• ERM-established criteria was used to evaluate sample results based



The inorganic analyses were performed acceptably, but requiredqualifying statements. It is recommended that the analytical results beused only with the qualifying statements presented below. Any aspects ofthe data that are not qualified in this report should be consideredqualitatively and quantitatively valid as reported. Validated and qualifiedanalytical results for these samples are provided in Attachment 2.

THEERMCROUP ICLARK EQWI EOTCOMPAW-mERREFRKERA7KINPlTC27a2 4.0l-12/9/92

RR3Q1981*

3.2 INORGANIC DATA QUALIFIERS

The positive results reported for aluminum (total and dissolved),copper (total and dissolved), iron (total and dissolved), lead (total anddissolved), and zinc (total) in the ground water samples listed beloware qualitatively invalid due to the level at which this analyte weredetected in associated laboratory method and/or field blanks.Therefore, the results reported by the laboratory are not indicative ofthe sampling location. USEPA protocol requires positive sampleresults for sodium that are less than five times the level detected inassociated laboratory method and/or field blanks to be qualified asqualitatively invalid. This has been indicated by placing "B" qualifiersnext to the positive results for aluminum (total and dissolved), copper(total and dissolved), iron (total and dissolved), lead (total anddissolved), and zinc (total) in these samples on the data summarytables.___________________________________


Aluminum (total) D-2, D-4,D-5

Aluminum (dissolved) S-4, D-l, D-2, D-3, D-4, D-6, D-7Copper (total) S-l, S-2, S-3, S-5, S-6, D-l, D-2, D-3, D4, D-5, D-6

Copper (dissolved) S-4, D-2, D-3

Iron (total) D-2, D-3, D-6Iron (dissolved) S-4, S-5, D-2, D-3, D-5Lead (total) S-l, S-4, S-5, S-6, D-l, D-2, D-3, D-l, D-5, D-6, D-7

Lead (dissolved) S-l, S-2, S-3, S-5, S-6, D-l, D-2, D-3, D-4, D-5, D-6, D-7Zinc (total) S-4, S-5

The positive results and/or detection limits reported for cadmium,potassium, and thallium in all ground water samples (total anddissolved) should be considered biased low quantitative estimatesdue to negative results reported in laboratory and/or method blanks.The negative blanks indicate the probability of underestimation of theanalyte concentrations by the instrument. These positive resultsand/or detection limits have been marked with "L" qualifiers toindicate that this is a biased low quantitative estimate.The positive results and/or detection limits reported for thallium(total) in all ground water samples should be considered quantitativeestimates and may be biased low. The associated matrix spikerecoveries were below the established quality control (QC) limit. Thishas been indicated by placing "L" qualifiers next to the positiveresults and/or detection limits for these samples on the datasummary tables.

THEERMGBOUP _ ^ 9CLARK B3UIPMENTCON«PANY-TYLERREFRICERAT!ONPItC27a2.04.01-12/9/92

5R30I985

• The positive results and/or detection limits reported for selenium inthe ground water samples listed below should be consideredquantitative estimates and may be biased low. Low recoveries wereobtained for the GFAA post-digestion spike analyses for thesesamples. This has been indicated by placing "L" qualifiers next to thepositive results and/or detection limits for these samples on the datasummary tables.__________________________________________


Selenium S-2 (total), S-2 (dissolved), S-6 (total), D-6(dissolved), D-7 (dissolved)

• The positive results reported for copper and zinc in ground watersamples listed below should be considered biased high quantitativeestimates. The CRDL Standard recoveries were greater than theacceptance criteria. High recoveries indicate lack of linearity near theCRDL and laboratory problem to measure the analyte concentrationsin the range of the CRDL. This has been indicated by placing "K"qualifiers next to the quantitative results to indicate that they arequantitative estimates.

Analyte

Copper

Zinc

Samples Affected

All positive ground water sample resultsAll positive ground water sample results

The ground water samples S-2 and S-3 were quantitated for lead bymethod of standard addition (MSA). The MSA correlation coefficientwere greater than 0.995, therefore, these results for lead are acceptableas reported.The ground water sample D-l and its blind field duplicate sample D-7were analyzed for TAL metals to evaluate overall laboratory andsampling precision. Sampling and laboratory precision wasdetermined by comparison of the relative percent difference (RPD) ofthe positive results reported for the metals which were confidentlydetected in the original sample and its blind field duplicate. Theconcentrations of these analytes in the original sample and and itsblind duplicate sample exceeded the Contract Required DetectionLimit (CRDL) by a factor of two or more. The relative percentdifference (RPD) of these analytes in the original sample and blindfield duplicates were calculated.ERM's blind field duplicate precision criteria of 25% used to evaluatethe blind duplicate metal results was met for samples D-l and itsblind field duplicate sample D-7.

THE ERM GROUP 1JCV4R& ECajn MEJOTCOMPANY- TYLER REFRIGERATION PIT C2702.W.01-12/9/92

4.0 SUMMARY

The organic analyses were performed acceptably, but required a fewqualifying statements. This analytical quality assurance report hasidentified the aspects of the data which required qualification. Thesequalifiers are noted on the attached analytical data tables. A supportdocumentation package has been prepared for this quality assurancereview and is filed with the Tyler Refrigeration Pit Superfund site projectfile.

THEERMGROUP fl D O O llcQRfiBXJlTMENTCOMPANY-TYLERREFRIGERA-nONPrrC2702.04J31-12/9/92

Attachment 1Methodology Summary/Method References

flR30i988


METHODOLOGY SUMMARY


The ground water samples were analyzed for TCL volatile organiccompounds by adding a 5 mL of water sample to reagent water containingsurrogate compounds and internal standards and purging the mixturewith helium at ambient temperature. The volatile compounds weretransferred from the aqueous phase to the vapor phase and trapped onto asorbent column. After purging, the column was heated and backflushedto desorb the compounds onto a gas chromatographic column. The gaschromatograph was temperature programmed to separate the samplecomponents, which were then detected by a mass spectrometer. Thetarget compounds were qualitatively identified and quantitated throughcalibration with standards.

Analysis for Vinyl Chloride by GC

Analyses for vinyl chloride (purgeable halocarbon) in ground water wereperformed according to Test Methods for the Evaluation of Solid Waste,SW-846, Third Edition. Method 8010. Sample aliquots at ambienttemperature were purged with helium transferring the purgeablecompounds onto a sorbent column. Sample components were thermallydesorbed onto a gas chromatographic column for separation and detectionusing a halogen-specific Hall Electrolyte Conductivity Detector.


One liter of the ground water sample was serially are extracted withseparatory funnel using methylene chloride at both acidic and basic pH.The extract is decanted and filtered. The extraction is repeated two ormore times, decanting after each operation. The extract is thenconcentrated and analyzed by first separating the extract componentsusing a gas chromatographic column and then detecting them with a massspectrometer for qualitative and quantitative evaluation.


One liter of the ground water sample was serially are extracted withseparatory funnel using methylene chloride. The extract is decanted andfiltered. The extraction is repeated two or more times, decanting after

THEERMGROUP ^r, O nCtAM-,m BREHUGERATIONC2702.02.01-12/9/92

each operation. The extract is then concentrated and analyzed by firstseparating the extract components using a gas chromatographic columnand then detecting them with an electron capture detector (ECD).





Florisil is a magnesium silicate with acidic properties, which is used forgeneral column chromatography as a cleanup procedure prior to sampleanalysis by gas chromatography. The column is packed with the requiredadsorbent, topped with a water adsorbent, and then loaded with thesample to be analyzed. Elusion is effected with a suitable solvent(s)leaving the interfering compounds on the column. The eluate is thenconcentrated.





THEERMGROUP Al-2 ,_CLARK--M,«M5RlGERA-nONC27a2.02.01-12/9/92


Aqueous and soil samples analyzed for mercury were oxidized withpotassium permanganate. Mercury was reduced to its elemental form andaerated from solution in a dosed system. Mercury was then determinedwith an atomic absorption spectrophotometer.

METHOD REFERENCESAnalysis ReferenceVolatile Organic Compounds USEPA Contract Laboratory

Program, OLM01.6Semivolatile Organic Compounds USEPA Contract Laboratory

Program, OLM01.6Pesticides /PCBs USEPA Contract Laboratory

Program, OLM01.6Gel-Permeation Cleanup USEPA Contract Laboratory

Program, OLM01.6Florisil Column Cleanup USEPA Contract Laboratory

Program, OLM01.6

TAL Metals, US EPA Contract LaboratoryProgram ILM01.0

TAL Cyanide . US EPA Contract LaboratoryProgram ILM01.0

THEERMGROUP AuFBO U I CSkgJt-TYLER REFRIGERATION C27Q2.02.01-12/9/92


flR30!992

around Water Analytical fleauttaTyfrr Refrigeration Pit

Superfund SKe, Smyrna, DelawareRemedial InvMtfgMon/FHMHHy Study

Semite |J<miKi<wEflM TH NumberSample Date

TCL Volatile Oroanto Canioaund* (uo/U

ChloromothanoBromomethaneVinvl ChlorideChtoroolhaneMethylene ChlorideAcetoneCarbon ObuHide1.1-Diohloroethene1 1 1 -Olohlorothane1 ,2-Oichlroroethene (total)Chloroform1 .2-Oichloroethane2-Butanone1 , 1 j 1 -TrichlorethtneCarbon TetraehlorideVinvl AcetateBromodiohloromehano1 .2-OlchlorooroDanaCit-1 ,3-DichloroorooeneTriehloroetheneDibromochloromohana1, 1 ,2-TriehloroetheneBenzeneTrana-1 ,3-Dichloropropeno2-Chloroethvlvinvlether9romoform4-Methvl-2-Pentanone2-HaxtnonaTetrachloraethene1,1 ,2,2-TetraehloroethaneTolueneChlorobonzeneEthylbenzeneStvreneTotal Xvlene*

Tentatively IdentifiedVoletlle Oraanio Compounda fuo/L)

Total Unknown

S-147t»9/11/02

SO USO U0.00 USO Uso uso uso u33 Jso uso uso uso uso u720SO Uso uso uso uso uso uso uso uso uso uso uso uso uso uso uso uso uso uso uso uso u

NO

S-2476119HO/92

10 U10 U0.80 U10 U10 u10 U10 U10 U10 U10 U10 U10 U10 U10 U10 u10 U10 U10 U10 U10 U10 U10 u10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U4 J10 U25

NO

S-347813a/an

NO

10 U10 UO.flO U10 U10 u10 U10 ' U10 U10 U10 u10 U10 u10 U10 u10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U

NO

S-4476209/10/92

10 U10 U0.90 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U9 j10 U10 U10 U10 u10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U

NO

S-54761S9/9/92

NO

10 U10 U0.90 U10 U10 U10 U10 U10 U10 U10 u10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U

NO

34476249/11/92

10 U10 U0.90 U10 U10 U1410 US J10 U10 U10 U10 U10 U2110 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U

NO

0-147827wn/92

10 U10 U0.80 U10 U10 U10 U10 U10 U10 U10 U10 U10 U"10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U1.0 J

NO

QueMenCode:

3: Thie rent it quallallwV invejd becaue* the eompound/analyle wa* alio Detected in a blank at i a'milar concentration.J: TtereautaheuM be conadered a qualitative eetntte.JN: TNeTereartirxuUbeconoideredao antftaiveeatirriew. Thereeultvwa

quanWaled aaaunng 1 r) reepenee mirth the aieociated internal standard.NO: Not detected.NA: NotAneJyxedU-Thie OMnpound/anaVtt wee analyzed but not detected. The numerical vetM

retorted lecreeenta the quanHtatpn/detecllcn lirtt of the cempound/anelyle.

APPROVED FORpc; n^cs nv< n w <*».*..i* L•*,.;• -in L...* %

QUAUIV /-.CGU-n

Page 1 of 13

Qroune! Water Analytical BttuHtTyter Refrigeration Pit

Superfund Site, Smyrna, DelawareRemedial mveedgatkwffeeeaiMty Study

iumlil nillinERM TR NumberimiaiiDiii

ret, Semhwlatile Organte CaejMwt* (ua/U

>henollie (2-ChkxoethvO Ether2-Chiorophenol1 ,3-Oiohlorobenzene1 ,4-Oioh(orobenzene1 ,2-Oiohlorobenzene2-Methvlphenol2.2>-Qxvbit(1-Chtoroprooano)l-MethvfchanolJ-Nrtroio-di-n-oroDVlamine•lexachloroethaneNitrobenzenetophorone2-NltroDhenol2,4-Oimethvtohenollie (Z-CMoroethoxvlmethane2.4-Oiehloroohenol1 ,2,4-TrlehlorobenzeneNaphthalene4-ChloroanilineHexaohlorobuladlene4-Chloro-3-rnethvlohenol2-Methylnaphthalene•texaohlorocyciopontadiene2.4.1-Triehloroohenol2.4.5-Triohloroohenol2-Chloronaohthalone2-Nltroanillne3imethvtohthalataAoenaohthvlene2,6-OinHrotoluene3-NitroanillntAoenapnthene2.4-Dlmtroohenol4-Nitrophenol3fcenzofuran2,4-Dinttrotoluene3lethyjphthalate4-Chtorophonyl-phenylother-kwrene4-Nltroaniline4,6-Olnitro-2-methyphenoiN-Nitroeodiohenvlaniine4-aromophenvl-phenylelherHexachlorobenzenePenfaehlorophenolPhenanthrenaAnthraceneCarbazoleDI-n-ButvlphthalatenuoranlhenePyreneButylbenzylphthalatea.y-OtflhtorobenzldineBenzofalanthraceneCNyjuneSi* (Z-etnylhenvDghthalat*Oi-n-ootvlphthalateBenzofbtRuoramhenaBenzoOOFluorantheneBenzo(a)Pvrenelndeno<1,2,3-o<J>pyreneDinenz(a,h)anthraeeneBenzo(a.h,i)e»rylene

S-1476366/11/62

NO

10 U10 U10 u10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U29 U10 U25 g10 U10 U10 U29 U10 U25 U25 U10 U10 u10 U10 U10 U25 U25 U10 U10 u10 U25 U10 U10 U10 U10 L10 U10 U10 L10 i.10 u10 L10 I10 L10 I10 L10 L10 I10 L10 t.

S-2476166/10/62

NO

10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U29 U10 U

10 U10 U10 U25 U10 U25 U25 U10 U10 U10 U10 U10 U25 U25 I10 U10 L10 U25 U10 U10 I10 U10 L10 L10 U10 t10 L1O U10 L10 t10 L10 I10 I10 I10 I.10 I10 I

S-3476139/9/62

NO

10 UJ10 U10 UJ10 U10 U10 U10 UJ10 Uto u10 U10 U10 U10 U10 a10 U.10 u10 a10 U10 U10 U10 U10 u.10 U10 U10 U.29 U10 u10 U10 U10 U25 U10 U

25 UJ10 U10 U10 U.10 U10 U25 t25 U.10 U10 I10 U25 U10 U10 L10 U10 L10 L10 U10 I10 I10 U10 110 L10 L10 I10 1.10 I10 I10 L1O I

S-4476209/10/62

NO

10 U10 U10 U10 U10 U10 U10 U10 U10 u10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U29 U10 U25 U10 U10 U10 U25 U10 U25 U25 U10 U10 U10 U10 U10 U25 U25 U10 U10 U10 U25 U'10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U.10 U10 U10 a10 U,10 U10 U

S4476169/9/82

NO

10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U29 U10 U25 U10 U10 t10 L25 U10 L25 L25 U10 I10 I10 L10 I10 L25 I.25 L10 U10 I10 L25 I10 I10 I10 U10 I10 I10 U10 110 tto i10 I10 I10 t10 I10 I10 I10 I10 I10 I

34476249/11/92

NO ,.....,—

10 U10 U10 U10 U10 U10 U10 U10 U10 U10 u10 u10 U10 U10 U10 u10 U10 U10 U10 U10 U10 U10 U10 u10 U10 U25 U10 U25 U10 U10 U10 t25 U10 U29 C29 U.10 L10 L10 L10 I10 L25 L29 L10 U10 I10 I.25 L10 L10 L10 U10 L10 I10 L10 I10 I10 1.10 I10 I10 L10 I10 I10 U10 I10 I10 I

0-1476276/11/92

NO

10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 Uto u10 U10 U10 U10 U10 Ll10 U10 Uto u10 U10 U10 U10 I.29 LI10 1.25 t.10 L10 L10 I25 U10 I2S L25 U10 I10 U10 U10 L10 U25 I25 U10 I10 U10 I25 I10 L10 U10 U10 I10 U10 U10 I10 U10 I10 I10 U10 I10 I10 U10 U10 t10 U10 I

QueMenCode:

B: TNeraeufclea eltatVelyinvaldbecaueetoeanipcuiKl/arialytewaaatoJ: TMa reeua thcuM be coneMered a <fwaUttiM eel melt.JN: ThtoT1Cieeu»acieuldbecone»<ei»da8iuan<rta<vei>imett. Thereto*wat

auammuJiaaiininain leeponea wfti fte iitcciaurt internal nandaid.NO: Net APPROVED FORNA: Not Analyzed ^ (_U- TMaeompound/tnelrle wet analyzed but nctdewcted. The numerical value | RS* fF t" . - E <

reported repreeenla the ouenlitalien/deleclion imk ol the eempounoVanalyte. I *" '"" •- - -

iCUALITV /.:.:'JT.

Page 2 of 13

flR30!

Qraund Water Analytical ReauHaTyler Refrigeration Pit

Supertund Site, Smyrna, DelawareRemedial lnveetlgaUonff=eaaamity Study

Sample LocationERM TR Numberjamala Dale

Tentatively IdentifiedSemivolatile Oroanlo Compound* (uo/L)

Total UnknownTotal Unknown Aliohatie ComooundaTotal Unknown Aliohatie Hydrocarbon*Hexadeeanoie AcidTotal Unknown Carboxvlio AcidSlloon ComooondAlkvl Subatituted Cvclot*tra*ik»an*Total Unknown Aromatic Compound*

TCL P**tk)W«PC8* (uo/U

Alpha-BHCaeta-BHCDerti-BHCQamrna-aHC (Undane)NeptaohlorAldrinHeotachtor EpoxideEndotutftn 1Oieldrin4.4'-ODEEndrinSndotuXan II4,4'-ODOEndotulfan SuHate4.4'-OOTMethoxyohlorEndrin Keton*Endrin AldehydeAtoha-Chlordano3amma-ChlordaneToxaoheneArehlor-1018Arohlor-1221Arohlor-1232Archlor-1242Arehlor-1246Archlor-1254Arehlor-1280

S-1478260/11/92

7 JN

NO

0.060 UJ0.090 UJ0.050 UJ0.050 UJ0.080 UJ0.030 UJO.OSO UJ0.090 UU0.10 uj0.10 UJ0.10 UJ0.10 UJ0.10 UJ0.10 UU0.10 uuO.SO UJ0.10 UU0.10 UJ0.050 UJ0.090 UU5.0 UJ1.0 UU20 UJ1.0 UU1.0 UU1.0 LL1.0 UJ1.0 UJ

S-347618W10/92

11 JN42 JN

0.050 UJO.OSO UJO.OSO UJ0.050 UJ0.050 LL0.050 LL0.090 U0.050 U0.051 J0.10 U.0.10 LU0.10 U.o.io a0.10 a0.10 U.0.50 U.0.0081 Jf"0.10 LU0.050 U,0.050 a5.0 LL1.0 LL.2.0 LL1.0 U.1.0 UJi.o LL1.0 UJ1.0 LL

S-J476139rW92

24 JN19 JN

S JN9 JN

0.050 UJ0.050 UJO.OSO UJ0.022 JPO.OSO UJ0.050 LUO.OSO UJo.oso a.0.078 JP0.10 UJ0.0058 JP0.10 LU010 LL0.10 LL0.10 LLaw LL0.010 J0.10 LLO.OSO LL0.050 LL9.0 LL1.0 LL2.0 LL1.0 LL1.0 a1.0 LL1.0 LL1.0 LL

S-4478209/10/92

3 JN18 JN

11 JN52 JN

NO

0.050 LU0.050 LU0.090 LU0.050 LU0.050 LU0.050 LU0.050 LU0.050 UJ0.10 LU0.10 LU0.10 LU0.10 LU0.10 LU0.10 LU0.10 LUO.SO UJ0.10 LU0.10 UJ0.050 LU0.050 LUS.O UJ1.0 LU2.0 LU1.0 LU1.0 LU1.0 LU1.0 LU1.0 UJ

s-s478169/V92

2 M

0.050 LL0.050 LL0.090 LLO.OSO UJ0.050 LL0.050 LL0.050 LL0.050 LL0.0080 J0.10 LL0.10 LL0.10 LU0.10 a0.10 a0.10 U.0.50 LL0.10 LL0.10 LL0.050 LUO.OSO UJs.o u1.0 LL2.0 UJ1.0 LL1.0 LU1.0 U1.0 LL1.0 U

S-e470249/11/92

4 JN

15 JN

NO

O.OSO LL0.090 LL0.030 LL0.050 LL0030 LLO.OSO LL0.050 LLO.OSO LL0.10 LL0.10 LL0.10 LL0.10 LL0.10 LL0.10 LL0.10 U.0.50 U0.10 LL0.10 LU0.050 LLO.OSO LLS.O LL1.0 LL2.0 LU1.0 LL1.0 LU1.0 U1.0 UJ1.0 LL

0-1478279/11/92

25 JN

NO

0.050 LLo.oso aO.OSO LLO.OSO LLO.OSO LLO.OSO LLO.OSO U.O.OSO LL0.10 LL0.10 U0.10 LL0.10 LL0.10 LL0.10 LL0.10 LLO.SO LL0.10 a0.10 LL0.050 LLO.OSO LL5.0 U1.0 LL2.0 LL1.0 LL1.0 LL1.0 U1.0 LL1.0 LL

OuaMertCode:

8: Thle remit i* quaftatvely iimtfd becauee the compcund/analyte wat alto detected in a blank at a eimilar concentration.J: ThkitttukihouldbecanekleradequanMetiveeeliniete.JN: ThiaTK:reeu«ariouldbece4ieidefeda«ianiitaiveetlirnete. Theretultwat

qutimieltJ eetuming 1:1 reepontewith the ateociated internal ttandard.NO: Not detected.NA: Not AnalyzedU-TNaeompound/analytt wet analyzed but not detected. The numerical value

reported reprtetnn the i|uanlilai'un/deteOon in* of the compound/analyie.R - Thee* reeuk am unuaable.P- Thia peellada/aiockir waa detected on two QC column but pereeM dlllerenee (%0) betwttn theee repcited pceHi>» retulu.

d the QC lent 0*29%. Thebwerof tto two reeuta it recalled on the laboratory anal?** "Port.

APPROVED.—• ,-• n <•>••r.LcMO

Pag* 3 of 13

flR30!995

Qreund Water Analytical ReauKaTyler Refrigeration Pit

Sueerfund Site, Smyrna, DelawareRemedial InveetJgtHon/FteetoWy Study

laiiyle LaeatjoaERM TR NumberUma4aOate

TCL Volatile Organ)* C*at«wind» biaVU

ChloromethaneBrorno methaneVinyl ChlorideChloroethaneMethvtene ChlorideAcetone2«rbon DituWde1.1-Olchloroethene1 .1 -Oiehlorothane1 ,2-Qichlroroethene (total)Chloroform1,2-Dtchlorotthane2-Sutanone1.1.1-TriohlorethaneDarboo TetrachlorideVinvi AcetateSromodichloromehane1 ,2-OtohkireorooaneCl«-1 ,3-OlchlorooropeneTriohforoetheneDilxo mochtoromehane1,1.2-Trlohloroethaneienzen*Tran«-1 ,3-Oiohlorooropene2-ChloroethvlvinvletherIromotorm4-Methvl-2-Pantanone2-HexanoneTetraohtoroetheno1.1 ,2,2-Tatrachloroethan*TokteneChloropenzeneEthyfcenzeneSty re n*Total Xvtenea

Tentatively IdentifiedVelatUe Oaanit Com»*und* (uaVU

Total Unknown

0-7t476269/11/61

10 U10 U0.90 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 u10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 Uto u10 U10 U10 U10 U1.0 J

NO

0-J476169/10/92

NO

10 U10 U0.00 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 u10 U10 U10 U10 U10 U10 U10 U10 U10 Uto u10 U10 U10 U10 U10 U10 U10 U

NO

D-3478149/6/92

NO

10 U10 U0.60 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 u10 U10 U10 Ll10 U10 U10 U10 Uto u10 U10 L10 L10 L10 L10 L10 L10 L10 L

NO

O-4476219/10/92

NO

10 U10 U0.90 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 u10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 Uto u10 U10 U10 U10 U10 U10 U10 U10 L

NO

D-6476179/0/92

10 U10 U0.00 U10 U10 U10 U10 U10 Uto uto u10 U10 Uto u10 u10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U3 J10 U22

NO

o-t476269/11/92

NO

10 U10 U0.90 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 u10 U10 U10 u10 U10 U10 u10 U10 Uto u10 u10 u10 u10 u10 U10 U

NO

OueHemCode:

B: Thie reeutleijutlta<»el»lmialdbecauee the eotipound/arMlyte wea aleo dtteeltd in a Mar* at a imiik« eer«er»alieii.J: Thla retua ihould be coneidtred a guanXetivt eetmate.JN: ThtaTCreouathouldbaconekleivdaajUanMaiiveaeimale. TheieeuKwat

auaMNatedaeeurringin raaponae with the atenriattd internal atandard.NO: Not detteltd.NA: NotAnelyzedU- Thie compound/anelyle waa analyzed but not detected. The numerical value

reported lepreeenlt the nuenliltlinn/ilHeaiDn In* e« the compound/tneyte.t - Thia tampt* i* th* Wind field duplicate of umpl* 0-1.

APPROVED FORR^LLAS^ BY

QUALITY A2.'ja

MANAGER

Page 4 of 13

^30/996

Oraund Water Analytical ReeuKaTyler Refrigeration Pit

Superlund SKo, Smyrna, DelawareRemedial Inveatigaflon/FtaetiKKy study

SamMoUeettaiIRMTR NumberSample Data

TCL Semivelattle Oroanie Comaaunoai (ua/U

PhenolBla (2-ChloroethvO Ether2-Chloroohenol1 3-Oiohlorobenzene1,4-Oiohlorobenzen*1 ,2-Dtehforobenzeno2-M*thy(phenolg,2*-Oxvbit(1 -Chlorapropane)4-MothvlohenolN-Nttroao-di-n-propylamin*HexaehloroethaneNitrobenzeneItoohorone2-Nitrooh*nol2.4-Oim*thvlphenolBle /2-CMoroethoxvlmethane2.4-Dichlorophenol1 .2.4-TriehlorobenzeneNaphthalene4-ChloroanitineHexachlorobutadiene4-Chk>ro-3-methvlohenol2-MethylnaphthaieneHexachloroevclopentadiene2,4,8-Trichlorophenol2,4,5-Trichtorophenol2-Chloronaohthalene2-NitroanilineDimethylohthalateAcenaphthviene2.8-Oinitrotoluene3-NitroaniiineAcenaphthen*2.4-Olnitroohenol4-Nitrooh*nolDibenzofuran2,4-DinitrotoluaneDiethvlphthalate4-Chloroohenyl-DhenvletherFluorene4-Nitroaniline4.6-Oinitro-2-methyphenolN-Nttrotodiphenylamine4-3romophenvl-ph*nyl*th*rHoxachlorobenzonePemaehloroohenolPhenanthreneAnthraceneCarbazoleDi-n-ButylphthalateFkjoranthenePyreneSutylbenzylphthalat*3.3'-Oiehlorobonzidfne9enzo(a)anihrae*n*Shrvaene9ia (2-ethvlhexvllohthalat*3i-n-oetvlohthalata3enzo(b)Fluoranthene3enzo(k)Ruorar)then*3enzo<*)Pyren*lnd*no<1 ,2.3-cd)pyr*n*3ibenz(a,h)anthracene3enzo(o.h,i)pervlene

0-7t476266/11/92

NO

10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U25 U10 U25 U10 U10 U10 U29 U10 U29 U25 LL10 U10 U10 U10 U10 U25 U25 U10 U10 U10 U25 U10 U10 U10 U10 U10 u10 u10 U10 Uto u10 U10 u10 U10 U10 u10 Uto uto uto u

0-2476168/10/82

10 U10 U10 U10 U10 U10 U10 U10 U10 Uto u10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 Uto u10 U10 u25 U10 U25 U10 Uto u10 U25 U10 U29 U25 U10 U10 U10 U10 U10 U25 U25 U10 U10 U10 U25 U10 U10 U10 U10 U10 U10 U10 U10 U10 Uto u0.9 J2 J10 U10 U10 U10 U10 U10 U

476146/9/62

10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 u10 U10 Uto u10 U10 U10 U25 U10 U25 U10 U10 U10 U29 U10 U25 U25 U10 U10 U10 U10 U10 U2S U2S U10 U10 U10 U25 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U1 J10 U10 U10 Uto u10 U10 U10 U

478219/10/92

10 U10 U10 U10 U10 Uto u10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U25 U10 U25 U10 U10 U10 U25 U10 U29 U29 U10 U10 U10 U10 U10 U25 U25 U10 U10 uto u25 Uto u10 U10 Uto u10 U10 U10 U10 U10 U10 U1 J10 U10 U10 U10 U10 Uto u10 U

04478179/6/93

10 U10 U10 U10 U10 U10 U10 U10 U10 Uto u10 U10 . U10 U10 U10 U10 U10 U10 U10 U10 Uto u10 U10 U10 Uto u25 U10 U29 U10 U10 U10 U29 U10 U29 U29 U10 U10 U10 U10 U10 U29 U25 U10 U10 U10 U25 U10 U10 U10 U10 U10 U10 U10 U10 Uto u10 U2 J10 U10 Uto u10 U10 U10 U10 U

04478269/11/92

10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U25 U10 U25 U10 U10 Uto u29 U10 U29 U25 LU10 Uto u10 U10 U10 U29 U25 U10 U10 U10 U25 U10 U10 U10 U10 U10 U10 U10 U10 Uto u10 U2 J10 U10 U10 U10 U10 U10 U10 U

OuaMereCode:

3: Thla MeuaieoualtaHveVinvaidbecauee the eempeund/analyie wat alto detected in a blank aienknilef concentration.J: Tr*r*eu*tr»uHI» chartered a ojantrWrveeelimaie.JN: TMaTICratiittAouldbecoflekleredequaniitatvetetimeie. Theraeultwai

quanlHaled attuning 1 .1 leepente with the aaeociated Internal ttandard.

U • Thie compound/analyle wee analyzed but not detected. The numerical value . PPI P /< Q Creported repretemi the qutmimion/axtaion imH ot the compeund/anelyie. ; ** *— *- >— •**• <•-•••—

t - Thia temple i* the blind field duplicate of sample 0-1. • »~\ ] j (» ! '• r' •' A •?"•


QUALITY ASSURANCE

Ground Water Amlytleai Betutt*Tyler Refrigeration Pit

Suaeriund SHe, Smyrna, DelawareRemedm Inveedgetton/lteea.ltty Study

UmMeUoetto*•RMTR Numberiama4eOale

Tentatively IdentifiedSemivelatHe Oroente Cetnaeund* (uo/L)

Total UnknownTotal Unknown Altohatk) Compound*Total Unknown Aliphatic HvdroearbonaHexadecanoio AcidTotal Unknown CarboxyBo AcidSMoon CompoundAfcyl Substituted CvolatetraailaxaneTotal Unknown Aromatic Compound*

TCL PtatlcldafPCK (uaVU

Ateha-BHCSeta-SHCDeKa-BHCQamma-SHC OJndane)HtottchlorAldrinHeptachlor EpoxideEndoeuKan 1Dieldrin4.4--OOEEndrinEndoeuKmn II4.4--OODEndotuKan SuMate4.4'-ODTMethoxvcMorEndrin KetooeEndrin AldehydeAlpha-ChlordaneQamma.ChlordaneToxaphan*Archlor-1016Arohlor-1221Arohlor-1232Archlor-1242Archlor-1248Archlor-1254Archlor-1280

0-7t476269/11/62

57 JN26 JN

NO

O.OSO U0.090 U0.040 UO.OSO U0.050 U0.050 U0.050 U0.050 U0.10 U0.10 U0.10 U0,10 U0.10 U0.10 U0.10 Uo.so u0.10 U0.10 U0.050 Ll0.090 L5.0 U1.0 U2.0 U1.0 L1.0 L1.0 L1.0 L1.0 L

D-2476168/10/92

9 JN17 JN

S JN

7 JN4 JN

0.030 UJ0.050 Ul0.050 UU0.050 UJ0.050 UJ0.050 UJ0.050 UJO.OSO UJOM J0.10 UJ0.10 UJ0.10 LL0.10 UU0.10 LL0.10 UU0.50 UU0.031 J0.10 LL0.050 LL0.090 LL5.0 LL1.0 LL2.0 LL1.0 LL1,0 U1.0 a1.0 LL1.0 LL

D-3476149/6/92

3 JN75 JN84 JN20 JN20 JN

NO

0.050 LL0.050 LLO.OSO UO.OSO U.O.OSO UO.OSO LLo.oso a0.090 U0.10 LL0.10 U0.10 a0.10 a0.10 U0.10 U0.10 LLO.SO LL0.10 U0.10 LLO.OSO UO.OSO LL9.0 U1.0 U.2.0 U.1.0 U.1.0 LUt.o a1.0 UJ1.0 LU

D-»476219/10/62

2 JN

2 JN3 JNS JN

NO

0.050 UO.OSO UO.OSO U0.050 U0.050 UO.OSO U0.050 U0.090 U0.013 J0.10 U0.10 U0.10 t0.10 u0.10 lj0.10 Uo.so u0.10 L0.10 L0.090 L0.050 L9.0 L1.0 L2.0 L1.0 L1.0 L1.0 L1.0 L1.0 L

D-6476179/6/62

29 JN

NO

0.090 LU0.050 UJO.OSO UJ0.030 UJ0050 UJO.OSO UJ0.050 UJ0.050 UJ0.10 UJ0.10 UJ0.10 IL0.10 LL0.10 LL0.10 LL0.10 LL0.90 UJ0.10 LL0.10 LL0.090 LL0.090 LL5.0 LL1.0 LL20 LL1.0 U.1.0 LL1.0 LL1.0 UJ1.0 LL

04476269/11/92

NO

NO

0.050 LLO.OSO UJO.OSO LL0.050 LUaoso LL0.050 LLaoso LLaoso LL.0.10 LU0.10 LU0.10 LL0.10 LU0.10 U,0.10 LU0.10 LLO.SO LU0.10 U.0.10 LU0.050 a0.090 LUS.O LL1.0 UJ2.0 U1.0 LL1.0 LU10 LL1.0 UJ1.0 UJ

Quail era Code:

B: Thltrieutianuelle<»tly iiweidbeceueelhecomcoufioVentVle wee alee detected in e blank at a «ifnilar concentration,J: Tr»ir**u«*houUteoonetteradaqu*nilM*M*e«niale.JN: Tr*TICra*rtahauMboaon*kj*redaquaMtfatvoeeimieIe. Theieeultwee

mandated tammini) irt napeneewith *»eiteodatidinterne!elandaid.NO: Not detected.NA: NotAiMk/zedU-Thktcompou«**»*Vle we* analyzed but net detected. The numerical value

remaned npnnnmhe nuialilaton/dtleca'cn Irntef thecompound/analyte,H • The** raaut am uweataia.P-TM«a*»lfclda/aiBekir»i»a deal etidoa two OC column but percent di*erenee (%0) between met* reported poeilive reeulla.. eao*ededtheOCImitof23%. The kmer of the two retult* it icpontdon the laoorakxy aneVek teport• - The** temple were reanalyzed tor voMU* oiganic compound*t - Thit temple ia the blind field duplicate of tample 0-1.

i APPROVED FORi RELEASE BYQUALITY ASSURANCE

/QA/QC K.1AN4GER

Page 6o< 13

ReM Blank Analytical ReeuHtTyler Refrigeration Pit

Suaerfund SKe, Smyrna, DelawareRem*dW Inveattgetlon/FtattXItty Study

8au*ila LocatloaERM TR NumberSample Data

ChtoromothaneBromomethan*Vinyl ChlorideChloroethaneMethvlene ChlorideAcetoneCarbon Ditutfide1.1-Dichloroetheno1.1-Olehlorothan*1 ,2-Oichlroroethene (total)Chloroform1 ,2-Oichloroethane2-Butanone1,1,1-TrichlorethaneCarbon TetrachlorideVinvl Aoettte9romodichloroniehan*1 .2-OichloroorooaneCia-1 . 3-OiehloroprooanaTrichloroetheneDibromochloromahan*1.1, 2-TrichloroethaneBanzan*Trant-1 .3-Oiohloropropene2-ChloroathvlvinvletherUromoform4-Methyl-2-Pentanone2-HexanoneTetraehloroethene1 , 1 ,2,2-Tetrachloroethan*Toluene2hlorob*nz*n*EthvfoenzeneStvren*Total Xvienet

Tentatively IdentifiedVolatile Orotnlo Compound* (uoVL)

Total Unknown

ta>1478229/10/62

NO

10 U10 U0.60 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 Uto u10 U10 U10 U10 U10 Uto u10 U10 U10 U10 U10 U10 U

NO

F6V1476239W62

NO

10 U10 UO.M U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 Uto u10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U

NO

TB-1476319/9/92

NO

10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 Uto u10 U10 U10 U10 U10 U10 U10 U10 U10 U10 Uto u10 U10 U

NO

TB-2476329/10/62

NO

10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 Uto u10 U10 U

NO

TB-3478309/11/92

NO

10 U10 U10 U10 U10 U10 U10 U10 U10 U10 Uto u10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 u10 U10 U10 U10 U10 U10 U10 U

NO

QuaMertCode:

B: Thie reaua ie queltaliveiy Invtld becauee ft* eempeund/analyie wee alto detected in a blank tt a «milef concentration.J: Trifcr**uaitiauldb*cor«idai*da«MnlMivette'male.JN: TTiie TIC MeuathcuM be ecaeidered a quantitative teirnaie. Theneukwaa

gutnillenj aatummg 1:1 reaponee with the tieoeieled internal ttandaid.NO: Nat detected.NA: NotAnalyMdU-Thktcompound/anaJyla waa analyzed but not detected. The numerical value

reported lepreeentathequenlllafcjii/oeteclien ImHoftheeonpound/antlyle.• Tntjwv •*w*pw VMM PMnMyzto for volMw opywvc compounds.

APPROVED FORRELEASS SY

QUALITY ACSUHANCE

MANAGER DATE

/1R30I999

Field Blank Analytical ReeuritTyler Refrigeration Pit

Suaerfund Me, Smyrna, DelawareRemedial lav**Ugatl**ye*aa*HHy Study

tainrte LocationERM TN Numberlaiiialt Dau

TCL Semivolatile Ooanie Cemeeunde (uo/U

PhenolRia (2-CMoraethyQ Ether2-Chlorophenol1 3-Okthlorobenzene,4-Oichiorobenzene

1 ,2-OioMorobenzene2-Methvlphenol2.2*Oxvbl«<1-CNorooroo»ne)l-Methvlohenol4-NHroao-di-n-oropylaminetaxaohloroe thaneNitrobenzeneaophorone2-Nltrophenol2,4-OimethylphenolUt (2-Chloroathoxy)mathane2.4-Olohlorophenol1 .2.4-TrichlorobenzenaNaphthalene4'Chloroaniiine•lexachlorobutadiene4-Chloro-3-methylphenol2-Methylnaphthalene•iexaehlorocvclopenWdien*2,4,6-Trichiorophenoi2, 4,5-Trichlorophenol2-ChlaranapMhalene2-NltroanilinaJimethvlohthalateAcenaphthylene2,6-Oinitrotoluene3-NitroanilineAcenaphthene2,4-Oinitroohenal4-Nitroohenol3benzofuran2,4-Oinrtrotoluene3iothylphthalate4-Chtoroohenvl-phenvletherFiuoreno4-Nitroaniline4,8-Oinitro-2-methyphenolN-NHroaodiphenyiamine4-Bromophenyl-phenvletherNexaohterobenzenePentaehtoroohenolPhenantnrenoAnthraceneCarbazol*Oi-n-ButvlphthalateRuoranfhenePyreneButvjbenzylphthalate3,3'-OlchlorobenzidlneBenzo(a)anthraceneChryteneBia <2-ethvlhexvl)phthalateOi-n-octylphthalataBenzo(b)F1uoranlheneBenzpWFluoranthen*BenzortlPvren*lndeno<1 .2.3-edtpvreneDfb*nz<a.h)anthrao*n*Benzo(g.h,i)perylene

EB-1478229/10/62

NO

10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 Uto u10 U10 U10 Uto u10 U10 U10 U10 U10 U10 U10 U29 U10 U25 U10 I10 U10 U29 U10 U29 L29 L10 L10 L10 U10 L10 L25 U25 L10 L10 L10 L25 L10 U10 L10 L10 U10 L10 U10 I10 U10 I10 t10 I10 I10 I10 I10 I10 L10 Ito i

™-1478239/6/92

NO

10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 u10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U10 U25 U10 U25 U10 U10 U10 U25 Ll10 U25 U25 t10 U10 Uto u10 L10 U25 U25 L10 U10 L10 L25 L10 U10 L10 U10 U10 L10 U10 L10 U10 L10 I10 U10 I10 L10 L10 I10 I10 U10 I

TB-1476319W92

NA

TM476326/10/92

NA

TB-3476309/11/92

NA

QuaM era Code:

B: Thktraauliae aitBlrvelymvaldbecauMtrwcofnpami/aitaJ: Thl* reeua eheuM be eontldertd e quaiiillaii« animate.JN: Tr»iTCr«au««heuldb»eoriaio redaquarH)tatveetlirnita. The retu« wet __«_«_______________________

HuanftaUd ateiiming 1:1 retponee with the aaeocieted internal ttandard.SIS-— ; APPROVED FORU-Thia eompeund/analyte wet analyzed but not detected. The numerical vekw !

reported nproeantt the quantitaeon/deteelion irrit of the compounoVanelyte.*-Theae temple wen raenalyzed tor veMleoiyanic compound*. —,,,,., ,-- -

; UUALt i i

Page 8 of 13

flR3Q

n*M Stank Analytical RewittaTyter Refrigeration Pit

Sueertund Site, Smyrna, DelawareRemedial Inveattgallon/FeataHHty Study

Sample LocationCRN TR NumberSample Otto

Tentatively Identified

Total UnknownTotal Unknown Aliphatic Compound*Total Unknown Aliohatto HvdrocarboneHexadecanoic AcidTotal Unknown Carboxvlk) AcidSffioon CompoundAlkyt Suottrtutad Cvckjtetrt«iioxaneTotal Unknown Aromatic Compound*

TCL Poatfeido/PCg* (uo/L)

Atoha-BHCJeu-BHCDeHa-BHCQamma-aHC (Lindane)HeotachlorAldrinHeotachlor EpoxideEndoaulfan 1Dieldrin4.4'-DDEEndrinEndoaulfan II4.4<-OOOindotuifan Sulfate414'-ODTtfelhoxvehlorEndrin Ketonerndrin AldehydeAloha-CWordaneQamma-ChlordaneToxic heneArchlor-1016Archlor-1221Archlor-1232Arehlor-1242Archlor-1248Archlor-1254Archlor-1260

EB-147822a/10/62

NO

NO

aoso LL0.050 LL0.050 LLaoso LL0.050 LLaoso LLO.OSO LL0.050 LL0.10 LL0.10 LL0.10 LL0.10 LL0.10 LL0.10 LL0.10 aO.SO LL0.10 LL0.10 LLaoso LLaoso a5.0 LL1.0 LL2.0 a1.0 u,1.0 LL1.0 LL1.0 LL1.0 LL

FB-147*231WK

NO

NO

aoso uaoso uaoso uaoso u0.050 U0.050 UO.OSO U0.050 U0.10 U0.10 U0.10 U0.10 U0.10 U0.10 U0.10 U0.90 U0.10 U0.10 Uaoso uaoso u9.0 U1.0 U2.0 U1.0 U1.0 U1.0 U1.0 U1.0 U

TH476319/0/92

NA

NA

Tf>2478329/10/92

NA

NA

TB-3476309/11/92

NA

NA

QuaMoreCode:

B: Tritareeii«ioqiiaiaMlv»Vinv*Jdbeciuwth*ccrnp ^J: Thiareaua*heuldbaconekl*i*daouanMalive*elimele.JN: ThteTKSr*tu«itiouldb*ceri*id*redaquan1itatVeeetimate. Thereaullwaa

quandlalad aaniming 1 n naponee wnh the aaeaciated internal ttandaid.NO: Not detected.NA: NotAnolyaedU • TO* compound/analyta waa analyzed but net detected. Th* numerical v*lu*

reported repreeenn the o emttetoiVoetecBon init of the eompound/analrie.H - Theae raauK ara unuaabtoiP • TNa peaHdde/ancbr waa detected on two GC column but percent difference (%0) between tht*o reported poenive retullt.

taeita'ed th* QC ImH of 25%. The tower of the two rente ia reported on trw laboratory analy tit report.• • Thee* temple went reanalyzed for volatile oganic compounda.

APPROVED FORRELEASE 3Y

QUALITY ACSURANCE

'DA'TE

Page 9 of 13

5R30200!

around Water Analytical Remit*Tyl*r Refrigeration Pit

Superfund Site, Smyrna, DelawareRemedial InveellgiileA/Aaiiblllty Study

smew LeeiifenEM T.R NumberSenate DM*

TAL Uetala <uoVU

AluminumAntimonyArsenicBariumBerylliumCadmiumCalciumChromiumCobaltCoeeerIronleadUigotxumManoeneteMercuryNickelfotituumSeleniumSilverSodiumThalliumVtniokxnZincCvaniot

3.1 (MM471*11T1 142

110019 U2.0 U2*3t.S2.0 UL170003.014.09.9 a419S.S B17700USa 32K U2140 L2.0 U3.0 U9110t.O UL4.219 Kto u

3-1 (dlteotved)47«s*•mm

20 U19 U2.0 U79.S1.0 UZO UL1890010 U4.0 U4.0 U5.0 U2.2 917*007».S0.20 U1« U2740 L2.0 U3.0 U10600t.O UL10 U14.1 KNA

S-2IIOUO47<18art an

268019 U2.0 U1070s.« u2.0 UL3410019.* U8.4(.9 853937.12*3005470.20 UIt U7710 L3.0 UL3.0 U24900t.O UL(.011.1 KNA

3-S IdlMOMei47118*rio/*2

20 U19 U2.0 Uas1.0 U2.0 UL2710015.14.0 U4.0 U5.0 U3.1 B24200US0.20 Utf U7400 L10 UL10 U2MOO1.0 UL10 U95.3 KNA

soiiotu)47813VM2

362019 U2.0 U8792.52.0 UL132004022.910.1 8197022.1933012500.20 Ut* U5100 L2.0 U3.0 U1590019.9 L3.0 U27.4 K10 U

j.3(d(i««v««47*13M/*2

20 Ut9 U2,0 U552t.O U20 UL103003.0 U4.0 U40 U5.0 Ut.9 B4*401270.20 U11 U5710 L3.0 U3.0 U177001.0 IX3.0 U11.7 KNA

1-4 (lot*)47120mom

31*19 U2.0 U1431.0 U2.0 UL2020044.14.0 U4.0 U2712.1 B71107N0.20 U1* U3330 L3.0 U3.0 U105001.0 UL3,0 U7,1 8to u

QudilertCodK

B: Thit remit it quattalrvefr ioveid beceiiee Hie oompound/milyle WM tiea otlerted in • blank «t t licniUr oancenimion.J: Th»r««uklhouidb«oanid«d«qu«l«(«t« «•!««».JN: TN«TCf««*tl»oMb«con«<i««i«qu«l—»/«««lim«». Theratuttww

quenHMed euumin? t :1 tMperae w* he <Mo<Mt«d hMnul UmdtidNO: KMdeMtdNA: NotAntlyudU- Thit oompoundftnalyte w«* aniiyzed but net oetecMd. The nunMrical vikie

r«port«d r reMnk tie qutntufcxVdMclnn limit of t* eompouid/mlyle.R * Theee rceuk ve unucable.K: Th» rewK diould be ooMidHed • iMMd high qu«nm«v» «Mm«H.L' TNe rewltlquanflilicn in* iwJd be oomic«red a blend low quenCtatve eMkiuM.

APPROVED FOR

! QUALi; /' AC3 .'

Page 10 of 13

around W.Mr Analytical BeaulteTyler Refrigeration Pit

Superfund Site, Smyrna, DelawareRemedltl kivaaUoaawUFasalbilltY Study

Sample LocationERM T.R. NumberSample Oaai

TAL Met*!* (uo/L)

AluminumAntimonyArsenicBariumBerylliumCadmiumCaldumChromiumCobaltCooperIronLeadMaonasiumManganeseMercuryNickelPotaaaiumSeleniumSilverSodiumThalliumVanadiumZincCytnidt

S-4 (dtoeaniedl47128BY1WH

20.8 319 U2.0 U168t.O U2.0 UL20(0041.94.0 U1.4 B8.S Bt.O U7S106010.20 UIS U3730 L3.0 U3.0 U120001.0 UL3.0 U63.9 KNA

S>S(IMaD47*119/ej*2

42419 U20 U370t.O U2.0 UL314003.0 U11«.4 34323.1 B152002830.20 U16 U53*0 L3.0 U3.0 U56000t.O UL1120 B10 U

S*S (daeolved}47(11avM9

20 U19 U2.0 U4121.0 U2.0 UL317003,97.14.0 U6.3 33.4 3170002430.20 U16 U5780 U3.0 U3.0 U802001.0 UL3.0 U46.4 KNA

M (total)476249/11/82

151019 U2.0 U4831.0 U2.0 UL237004.116.75.5 B87«5.2 a8680S530.20 U11 U4420 L3.0 UL3.0 U138001.0 UL4.1 U19 K10 U

34 (dtaeotved)47124*/11/*2

20 U19 U2.0 U2581.0 U2.0 UL238003.74.0 U4.0 U5.0 U2.8 887603060.20 U18 U4*10 L3.0 U3.0 U155001.0 UL3.0 U55.1 KNA

0-1(100047127*Y11/*2

11519 U2.0 U80.21.0 U&o m028010 U4.0 U4.4 B1004.4 3282057.30.20 U18 U2970 L20 U3.0 U73101.0 Ul3.0 U42.1 Kto u

0-1 (aMeolved)47127evil/ax

102 B19 U2.0 U8111.0 U2.0 U882010 U4.0 U4.0 U5.0 U1.7 8324085.50.20 U16 U4*00 L3.0 U3.0 U83SO1.0 Ul10 U4*.5 KNA

0-7 (went47826*rl1/*2

tit19 U2.0 U601.0 U2.0 UL83903.0 U4.0 U4.0 U91.72.5 B2(40S*0.20 U16 U3270 L3.0 U3.0 U74701.0 UL3.0 U43 Kto u

Qutlifeit Code:

8: Tlwuaeall la cjueitaliveryinvafd because irwoxnpound/an ^J: This feeull should be <»naiderad a (fjanlKaliveesliniale.JN: TrtsTCreeukthouUbeooneteedao lilttoeaimale. Thereeullwat

<»janaMed aaauming 1:1 reeponeewiet rte aaaociated internal atandardNO: NotdMtoMdNA: NMAnelyzedU- Thie coaipaund/aneytewte andyzed but not detected The numerical value

raponad repraaanls lha laianlilaton/daleclian lim*< of Hw compound/anaiyta.R - Theee raedt are unutebte.1C Thitmeukaheuldbeoonaidaredebiaciedhighquenlitalive estimate.L ThteraeuiUquenlilalknffliilahoUd be oonaiderad a biaaed tow quanl'taive aaamala.t • Thie sample it blind field duplicate of sample 0-1 (total).


'QUALITY ACSLHANCE

QA/QCÂNAÊR DAÊ

Page It of 13

Oround Water Analytical HaeultiTylar Refrigeration Pit

Superfund Site, Smyrna. DalawereRemedial laveedgideivFsaslbWty Study

f sm*la LaiaynI!"* T.R. NumberSample Date

TAL Uetalt (ua/U

AluminumAntimonyArtenlcBariumBerylliumCadmiumCalciumChromiumCo* altCopperIronLeadMtonaemmUanoenateUercuryNickelPotassiumSeleniumSilverSodiumThalliumVinadlumZincCyanida

0-7 (tlaanvaOt47126t/11/92

102 81* U2.0 U64.8t.O U2.0 UL16003.0 U4.0 U4.0 U5.0 U2.8 631 SOK.I0.20 UIt U4170 L3.0 UL3.0 U13301.0 UL3.0 U43.7 KNA

O.a(to*»47(1*W1V62

83.1 B11 U10 U1231.0 U2.0 UtI4M17.240 U4.4 B»,22.1 B342037.20.20 U1* U8230 L10 U10 U1*300t.O Ut10 U18.4 K10 U

n.2<«ecelved>4711*in om

21.5 a19 U2.0 U121t.O U2.0 UL71SO73.14.0 U1.4 112.1 61.4 6310039.40.20 Ut* U8430 L2.0 U3.0 U11400t.O UL3.0 U54 KNA

0-3 (man47114InVK

14*19 U2.0 U47.31.0 U2.0 Ut72803.0 U4.0 U4.4 8lit19 62100S4.S0.20 U11 U3470 L3.0 U3.0 U7110t.O Ul3.0 U41.7 K10 U

0-3 (deceived)47(14aYM2

80 B19 Uzo u41.31.0 U2.0 Ul720010 U4.0 U19 65.9 81.7 123704490.20 U11 U4430 L10 U10 UMM1.0 M10 U52.5 KNA

tM(WM47*21•rtevaa

U.1 i19 U2.0 U41.31.0 U10 Ut15*0017.54.95.4 61*91.0 11*101300.20 U1* U1310 L10 U3.0 U153001.0 Ul10 U21.1 K10 U

CMtetaeaMO47*21•rant

213 81* U2.0 U41.3t.O U2.0 UL170001124.0 U4.0 U5.0 U2.7 617101320.20 U11 U99M L3.0 U3.0 U1SK»1.0 IX10 U18.2 KNA

(Moat*) 147*17 j|awti fl

W9 81* U2.0 U95.11,0 UZO I*1210034 U13.99.4 62911.0 638104960.20 U1* UMM L10 U10 U

110001,0 Ut10 U41.7 K10 U

Outlier* Code:

•k Thie reauit should be considered a quantitative eJN: Thie TO leauk should baoonaioa a quentteMaeaMle. ThereeuUwa*

quenMeladaseuiiiing 1:1 response wiei tie ateocieMd ntemal standardNO: NetdMtcMdNA: NMAnalyzadU • Thia eomcovnoYenalyle waa analyzed bu< not dslsctae*. The nwaerioal value

reported rearsaenli tie quenltaiion/daaKlion j»at of tie cceipamd/enalyle.R • Theee reatat ere unuaatia.K: This raerft should be ooxeiawia'aniaaedhigh quanlitatve aeama».L Tt«t»au(»«panli«i»cnfan*ahoJ<ibaoonaKJar«Jab»aa<)towquanitalv.»«»r • TNt sample it blind field duplicate of sample 0-1 (dissolved).


QUALITY ASSURANCE

Peoe 12 of 13

appendix h analytical data - united states environmental ...environmental resources management, inc....

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