annexure – a details of products sr. list of organic...

Annexures to Form – 1 & PFR for Proposed Expansion Project for manufacturing of Speciality Chemicals by M/s Industrial Solvents and Chemicals Pvt. Ltd., Plot No. 7906-

7909, GIDC Estate,Ankleshwar, Dist. Bharuch-393 002, Gujarat

ANNEXURE – A

DETAILS OF PRODUCTS

Sr.NO.

List of Organic Product Code Production [ MT/month ] Consented Pro posed Total

1. Dimethyl Sulphate DMS 3000 2000 5000

2. Diethyl Sulphate DES 500 500 1000

3. N-Ethyl Aniline (NEA) NEA 100 0 100

4. Diethyl Aniline DEA 100 0 100

5. Ethyl Benzyl Aniline EBA 120 0 120

6. N,N-Dimethyl Aniline DMA 530 0 530

7. N-Methyl Aniline NMA 20 0 20

8. Dimethyl Para Toluidine DMPT 100 0 100

9. Mono Ethyl Meta Toluidine& Diethyl Meta Toluidine

MEMT &DEMT

25 0 25

10. Absolute Alcohol Alc 100 0 100

11. Mono Methyl Meta Toluidine& Di Methyl Meta Toluidine

MMMT& DMMT

10 0 10

12. Methyl Benzyl Aniline MBA 10 0 10

13. Mono Ethyl Ortho Toluidine MEOT 10 0 10

14. Ether Solvents I.P./B.P ES 500 0 500

15. Ether Anaesthetic I.P/B.P EA 15 0 15

16. Ethyl Chloride I.P/B.P 2 0 2

TOTAL 5142 2500 7642



ANNEXURE – B

DETAILS OF RAW MATERIALS

Sr. no.

Name of Products Raw materials Consumption

T/T Consented [T/month]

Proposed [T/month]

Total [T/month]

1. Di Methyl Sulphate 1.00 3000 2000 5000 Methanol 0.53 1590 1060 2650 Sulphur Trioxide 0.68 2040 1360 3400 Sodium Sulphate 0.005 15 10 25

2. Di Ethyl Sulphate 1.00 500 500 1000 Ethanol 0.70 350 350 700 Sulphur Trioxide 1.20 600 600 1200 Ammonia 0.05 25 25 50 Sodium Sulphate 0.05 25 25 50

3. N-Ethyl Aniline 1.00 100 - 100 Aniline 0.79 79 - 79 Alcohol 0.40 40 - 40

4. Di Ethyl Aniline 1.00 100 - 100 Aniline 0.64 64 - 64 Alcohol 0.65 65 - 65

5. Ethyl Benzyl Aniline 1.00 120 - 120 N-Ethyl Aniline 0.51 61.2 - 61.2 Caustic lye 0.20 24.0 - 24.0 Benzyl Chloride 0.61 73.2 - 73.2

6. N,N-DiMethyl Aniline

1.00 530 - 530

Aniline 0.78 414 - 414 Methanol 0.54 287 - 287 Acetic Anhydride 0.015 8 - 8

7. N-Methyl Aniline 1.00 20 - 20 Aniline 0.90 18 - 18 Methanol 0.32 6.4 - 6.4

8. Di Methyl Para Toluidine

1.00 100 - 100

Methanol 0.445 44.5 - 44.5 Acetic Anhydride 0.05 5 - 5 Para Toluidine 0.80 80.0 - 80.0

9. Mono Ethyl Meta Toluidine& Diethyl Meta Toluidine

2.00 1.00

25 - 25



Meta Toluidine 2.31 57.75 - 57.75

Alcohol 1.48 37 - 37

10. Absolute Alcohol 1.00 100.0 - 100.0 Alcohol 1.06 106 - 106

11. Mono Methyl Meta Toluidine& Dimethyl Meta Toluidine

1.00 2.00

10 - 10

Meta Toluidine 2.55 25.5 - 25.5 Methanol 1.29 12.9 - 12.9

12. Methyl Benzyl Aniline

1.00 10.0 - 10.0

Mono Methyl Aniline 0.55 5.5 - 5.5 Benzyl Chloride 0.68 6.8 - 6.8 Caustic soda lye 0.05 0.5 - 0.5

13. Mono Ethyl Ortho Toluidine

1.00 10 - 10

Ortho Toluidine 0.83 8.3 - 8.3 Alcohol 0.40 4.0 - 4.0

14. Ether solvents I.P./B.P.

1.00 500 - 500

Alcohol 1.31 655 - 655 Sodium Bisulphite 0.04 20 - 20 Caustic soda flakes 0.03 15 - 15

15. Ether Anaesthetic I.P./B.P.

1.00 15 - 15

Ether solvents 1.20 18 - 18 Caustic soda flakes 0.03 0.45 - 0.45 Sodium Bi sulphite 0.05 0.75 - 0.75

16. Ethyl Chloride I.P./B.P.

1.00 2 - 2

Crude Ethyl Chloride

0.995 1.99 - 1.99

Eau-De-Cologne 0.005 0.01 - 0.01 17. ChloroSulphonic

acid &Sulphuric acid-70%

1.00 1.72

6000 - 6000

SO3 0.69 4140 - 4140 HCl 0.31 1860 - 1860 Sulphuric acid

[98%] 0.84 5040 - 5040

18. SO3, Sulphuric acid &Oleum [65% & 24%]

1.00,1.00, 1.00

15750 - 15750



Sulfur 1.08 17010 - 17010 O2 1.64 25830 - 25830

19. Sulphamic acid 1.00 900 - 900 Urea 0.30 270 - 270 Oleum [23%] 2.926 2633.5 - 2633.5

20. Non-Ferric Alum 1.00 3000 - 3000 Aluminium Hydrate 0.298 894 - 894 Sulphuric acid 0.859 2577 - 2577



DETAILS OF PRODUCTS

Sr.NO.

List of In Organic Product Code Production [ MT/month ] Consented Proposed Total

17. Spent Sulphuric Acid [ 65% Min ] 800 630 1430

18. Sulphuric Acid 70% 8000 0 8000

19. ChloroSulphonic Acid CSA 6000 0 6000

20. Sulphur Trioxide SO3 15750

0

15750

21. Sulphuric Acid

22. Oleum (65% &24%)

23. Sulphamic Acid 900 0 900

24. Non Ferric Alum 3000 0 3000

Total 34450 0 34450

Other

25. Captive Power Plant 2 MW [1MW X 2nos.]

0 2 MW [1MW X 2nos.]

26. Plastic Carboys [ Capacity 20-60 lit]

50000 0 50000

27. Plastic Barrels [Capacity 210-230 Lit]

30000 0 30000

28. M. S. Barrels/G I Barrels [Capacity 200-220 Lit ]

20000 0 20000

29. M.S. Drums [Capacity 20-100 Lit]

60000 0 60000

Note: While manufacturing DMS and DES Sulphuric acid 65% generated as per the reaction stoichiometric calculation.



DETAILS OF RAW MATERIALS

Sr. no.

Name of Products Raw materials Consumption

T/T Consented [T/month]

Proposed [T/month]

Total [T/month]

1. Di Methyl Sulphate 1.00 3000 2000 5000 Methanol 0.53 1590 1060 2650 Sulphur Trioxide 0.68 2040 1360 3400 Sodium Sulphate 0.005 15 10 25

2. Di Ethyl Sulphate 1.00 500 500 1000 Ethanol 0.70 350 350 700 Sulphur Trioxide 1.20 600 600 1200 Ammonia 0.05 25 25 50 Sodium Sulphate 0.05 25 25 50

3. N-Ethyl Aniline 1.00 100 - 100 Aniline 0.79 79 - 79 Alcohol 0.40 40 - 40

4. Di Ethyl Aniline 1.00 100 - 100 Aniline 0.64 64 - 64 Alcohol 0.65 65 - 65

5. Ethyl Benzyl Aniline 1.00 120 - 120 N-Ethyl Aniline 0.51 61.2 - 61.2 Caustic lye 0.20 24.0 - 24.0 Benzyl Chloride 0.61 73.2 - 73.2

6. N,N-DiMethyl Aniline 1.00 530 - 530 Aniline 0.78 414 - 414 Methanol 0.54 287 - 287 Acetic Anhydride 0.015 8 - 8

7. N-Methyl Aniline 1.00 20 - 20 Aniline 0.90 18 - 18 Methanol 0.32 6.4 - 6.4

8. Di Methyl Para Toluidine 1.00 100 - 100 Methanol 0.445 44.5 - 44.5 Acetic Anhydride 0.05 5 - 5 Para Toluidine 0.80 80.0 - 80.0

9. Mono Ethyl Meta Toluidine & Diethyl Meta Toluidine

2.00 1.00

25 - 25

Meta Toluidine 2.31 57.75 - 57.75

Alcohol 1.48 37 - 37

10. Absolute Alcohol 1.00 100.0 - 100.0 Alcohol 1.06 106 - 106



11. Mono Methyl Meta Toluidine& Dimethyl Meta Toluidine

1.00 2.00

10 - 10

Meta Toluidine 2.55 25.5 - 25.5 Methanol 1.29 12.9 - 12.9

12. Methyl Benzyl Aniline 1.00 10.0 - 10.0 Mono Methyl Aniline 0.55 5.5 - 5.5 Benzyl Chloride 0.68 6.8 - 6.8 Caustic soda lye 0.05 0.5 - 0.5

13. Mono Ethyl Ortho Toluidine

1.00 10 - 10

Ortho Toluidine 0.83 8.3 - 8.3 Alcohol 0.40 4.0 - 4.0

14. Ether solvents I.P./B.P. 1.00 500 - 500 Alcohol 1.31 655 - 655 Sodium Bisulphite 0.04 20 - 20 Caustic soda flakes 0.03 15 - 15

15. Ether Anaesthetic I.P./B.P.

1.00 15 - 15

Ether solvents 1.20 18 - 18 Caustic soda flakes 0.03 0.45 - 0.45 Sodium Bi sulphite 0.05 0.75 - 0.75

16. Ethyl Chloride I.P./B.P. 1.00 2 - 2 Crude Ethyl Chloride 0.995 1.99 - 1.99 Eau-De-Cologne 0.005 0.01 - 0.01

17. ChloroSulphonic acid &Sulphuric acid-70%

1.00 1.72

6000 - 6000

SO3 0.69 4140 - 4140 HCl 0.31 1860 - 1860 Sulphuric acid [98%] 0.84 5040 - 5040

18. SO3, Sulphuric acid &Oleum [65% & 24%]

1.00,1.00, 1.00

15750 - 15750

Sulfur 1.08 17010 - 17010 O2 1.64 25830 - 25830

19. Sulphamic acid 1.00 900 - 900 Urea 0.30 270 - 270 Oleum [23%] 2.926 2633.5 - 2633.5

20. Non-Ferric Alum 1.00 3000 - 3000 Aluminium Hydrate 0.298 894 - 894 Sulphuric acid 0.859 2577 - 2577

Annexures to Form – 1 & PFR for Proposed Expansion Project for manufacturing of Speciality Chemicals by M/s Industrial Solvents and Chemicals Pvt. Ltd., Plot No. 7906-7909, GIDC

Estate, Ankleshwar, Dist. Bharuch-393 002, Gujarat

1

ANNEXURE – C BRIEF PROCESS DESCRIPTION, MATERIAL BALANCE & FLOW DIAGRAM

1. DIMTHYL SULPHATE (DMS) AND SPENT SULPHURIC ACID 65% MIN Process Description: Methanol is evaporated in a vaporizer then it is passed through a tubular reactor

containing Alumina catalyst at 230°C to form Dimethyl Ether (DME), and water.

DME and water separated in a column.

DME Reacted with Sulphur Trioxide (SO3) in a tower to form crude Dimethyl

Sulphate having Sulphuric Acid content around 5 - 6%.

Water from the column drained to ETP.

Crude Dimethyl Sulphate is distilled in a column under vacuum, in presence of

sodium sulphate catalyst to get pure DMS. Distillation column bottom product is

Sulphuric Acid having strength 65% Min.

All the above operations are carried out in a closed loop by continuous process.

Chemical Reaction: I. 2 CH3OH (CH3) + H2O

0

(CH3)

Methanol DME Water

64 46 18

II. (CH3) + SO3 (CH3)2SO4

0

(CH3)

DME Sulphur trioxide Dimethyl Sulphate

46 80 126

III. H2O + SO3 H2SO4

Water Sulphur Trioxide Sulphuric Acid

18 80 98



2

5 – 6% Sulphuric Acid

Crude DMS

Material Balance

Process flow sheet with Material Balance

Summary

Raw Material Product Effluent water

Methanol 0.53 Pure DMS 1.000 Eff. Water 0.15

Sulphur trioxide 0.68 Sp.Sulphuric Acid [65%] Min

0.065

Sodium Sulphate 0.005

1.065 0.15

Total 1.215 Total Product + Water = 1.215

Tower

Pure Dimethyl Sulphate 1.0

Spent Sulphuric Acid 65% Min 0.065

1.06 MT

Distillation

Column

Vaporizer

Distillation

Column

Methanol

0.53

0.53

Reactor

SO3 0.68

Water to ETP 0.15


DME



3

2. DIETHYL SULPHATE (DES) AND SPENT SULPHURIC ACID 65% MIN Process Description: Sulphur Trioxide (SO3) is reacted with Ethyl Alcohol (Special Denatured Spirit) in

a reactor to get Diethyl Sulphate and Sulphuric Acid.

This mix is distilled under vacuum in presence of sodium Sulphate catalyst to get

pure DES and Sulphuric Acid 65% Min.

Ethyl Alcohol (Special Denatured Spirit) Contains about 6 – 7% water, this water

also reacting with Sulphur trioxide to form Sulphuric Acid.

Chemical Reaction :

I. 2 C2H5OH + 2 SO3 (C2H5)2 SO4 + H2SO4

Ethyl Alcohol (SDS) Sulphur trioxide Diethyl Sulphate Spent Sulphuric Acid

92 160 154 98

II. H2O + SO3 H2SO4

Water Sulphur trioxide Spent Sulphuric Acid

18 80 98

Summary

Raw Material Product Effluent water

Ethanol 0.70 Pure DES 1.00 Water 0.0

SulphurTrioxide 1.20 Sulphuric Acid [65%]Min 1.00


Catalyst – NH3 0.05

2.00 0.0




4

Pure Di Ethyl Sulphate

1.0 MT

Material Balance: Process flow sheet with Material Balance:

3. N-ETHYL ANILINE (NEA) Process Description: Aniline and Ethyl alcohol (Specially Denatured Spirit) (SDS) are fed to a vapouriser.

Vapours are passed through reactor containing alumina catalyst at high temperature.

Reactor product is N-Ethyl Aniline (MEA), with water is condensed. Water separated

crude NEA distilled to get Pure NEA.

Chemical Reaction: C6H5 NH2 + C2H5OH C6H5 NH (C2H5) + H2O

Aniline Ethyl Alcohol N-Ethylaniline Water

93 46 121 18

Reactor

Spent Sulphuric Acid 65% Min 1.0for sale

Ethyl Alcohol (SDS) 0.70

Distillation

Liq. SO3 1.20 MT

Sodium Sulphate

0.05 MT

1.95 MT

Reactor

Catalyst- NH3 0.05

MT



5

Crude NEA

Material Balance:

Summary

Raw Material Product Effluent Water+waste

Aniline 0.79 Pure NEA 1.00 From reaction 0.19

Alcohol 0.40 Process Washing 0.20

Water 0.20 1.00 Total Effluent 0.39

Distillation Residue 10 Kg/Month


Process Flow Diagram:

0.14Alcohol

Vaporiz

er

Reactor

SEPERATOR

1.00PURE NEA

0.79 ANILINE

DISTILLATION

COLUMN

Reaction Water 0.39

Mixed

Tank

Condenser



6

4. DIETHYL ANILINE (DEA) Process Description: Aniline and Ethyl alcohol (Specially Denatured Spirit) (SDS) are fed to a

vapouriser. Vapours are passed through reactor containing alumina catalyst at

high temperature. Reactor product which is Diethyl Aniline (DEA) with water is

condensed. Water separated.

Crude DEA distilled under vacuum to get pure DEA.

Chemical Reaction: C6H5 NH2 + 2C2H5OH C6H5N (C2H5)2 + 2H2O

Aniline Ethyl Alcohol Diethyl aniline Water

93 92 149 36

Material Balance:

Summary

Raw Material Product Effluent Water

Aniline 0.64 Pure DEA 1.00 Process Water 0.29

Alcohol 0.65 Washing 0.15

Water 0.15 1.00 Total Effluent 0.44

Distillation Residue 15 Kg/Month




7

Process Flow Diagram : 5. ETHYL BENZYL ANILINE (EBA) Process Description: Aniline and Ethyl alcohol (Specially Denatured Spirit) (SDS) are fed to a

vapouriser. Vapours are passed through reactor containing alumina catalyst at

high temperature. Reactor product which is N-Ethyl Aniline (MEA) with water is

condensed. Water separated.

N-Ethyl Aniline is either sold directly or reacted with Benzyl Chloride to get Ethyl

Benzyl Aniline, which is distilled further to get pure Ethyl Benzyl Aniline. Products

are sold in drums.

Chemical Reaction: 1). C6H5 NH (C2H5) + C6H5 CH2Cl C6H5-N-C2H5.CH2-C6 H5 + HCl

N-Ethyl Aniline Benzyl Chloride Ethyl Benzyl Aniline Hydrochloric Acid

121 126.5 211 36.5

2). HCl + NaOH NaCl +H2O

Hydrochloric Acid Caustic Soda Sod. Chloride Water

36.5 40 58.5 18

0.65 Ethyl Alcohol

Reactor

SEPERATOR 1.00PURE

DEA

0.64 ANILINE

DISTILLATION

COLUMN

Water 0.44

Mixed

Tank Condenser



8

NEA 0.51

Water + NaoH

1.82

5.3 Material Balance

Summary

Raw Material Product Effluent Water

MEA0.51 EBA 1.00 From Reaction 0.32

Caustic lye 0.20 Process Washing 1.50

Benzyl Chloride 0.61

Water 1.50 1.00 Total Effluent. 1.82

Distillation Residue. 12 Kg/Month



Neutralizer Reactor

Distillation

Column

EBA 1.0

0.2 NaoH +

Water

Benzyl Chloride

0.61



9

6. N,N- DIMETHYL ANILINE (DMA) Process Description: Aniline and Methanol vaporized in a vaporizer. Vapours passed through a Tubular

Reactor containing Alumina catalyst at 240°C. Reactor product is Dimethyl Aniline and

water condensed. Water separated. Then crude Dimethyl Aniline is reacted with Acetic

Anhydride, then washed with water and distilled under vacuum to get pure Dimethyl

Aniline.

Chemical Reaction: 2 CH3OH + C6H5NH2 C6H5N (CH3)2 + 2 H2O

64 93 121 36

Methanol Aniline Dimethyl AnilineWater

Material Balance:

Summary

Raw Material Product Effluent Water + Waste

Aniline 0.78 DMA 1.000

Methanol 0.54 From reaction 0.315

Acetic Anhydride 0.015 Process washing 0.58

Water for washing 0.56 1.000 Total effluent 0.895 Distillation Residue 75 Kg/month




10

1.32

Water 0.56

Acetic Anhydride 0.015

Effluent Water 0.58

Process flow Diagram:

0.54 METHANOL

Vapouriser

REACTOR

CONDENSOR

SEPERATOR

N,N - DMA 1.0

0.78 ANILINE

DISTILLATION

Reaction Water 0.315

REACTOR



11

7. N-METHYL ANILINE (NMA) Process Description : Aniline and Methanol passed through heat exchangers and then to a reactor, which

contains Catalyst there produce mainly MMA and water formed during reaction, water

separated product washed with water to remove traces impurities, then above technical

product taken to fractionating distillation column, water separated. Product MMA

distilled and collected in tank.

Chemical Reaction : CH3OH + C6H5NH2 C6H5NHCH3 + H2O

Methanol Aniline N- Methyl AnilineWater

32 93 107 18

Material Balance:

Summary

Raw Material Finished Goods Effluent Wate+waste

Aniline 0.90 NMA 1.000 From Reaction 0.215

Methanol 0.32 Process washing 0.585

Water wash 0.58 Total Eff. 0.800

Distillation Residue 10 KG/Month

1.000




12

Mix Tank

Process flow Diagram :

0.32 MT METHANOL

0.9 MT ANILINE

Dist. Column NMA 1.0

Effluent Water 0.8

Water 0.58

VAPORISER

Reactor

Condenser

Separator



13

8.DIMETHYL PARA TOLUIDINE (DMPT) Process Description : Melten Para Toluidine (PT) and Methanol mixed, vaporized. Then it is passed

through a tubular Reactor containing Alumina catalyst at 250°C.

Reactor product is mix of DMPT and water, water separated washed with water

to remove traces of methanol impurity. Distilled to get pure DMPT .

Reaction water is sent to ETP. All the above operations are carried out in a

closed loop, by continuous process.

Chemical Reaction : 1). 2CH3OH + C6H4CH3NH2 C6H4CH3N(CH3)2 + 2H2O

Methanol Para Toluidine Dimethyl p-Toluidine Water

64 107 135 36

17.3 MATERIAL BALANCE

Summary

Raw Material Product Effluent Water+Waste Methanol 0.445 PDMPT = 1.0 From Reaction 0.275 Acetic Anhydride 0.05 Process Washing 0.325 Water 0.305 Total Effluent 0.6

Distillation Residue. 2.0KG/Month Para Toludine 0.80 1.0 Total 1.6

Total Product + Water = 1+0.6 = 1.6



14

Process flow Diagram :

250°C

Mixing

Tank

Reactor

Condenser

Methanol 0.445

Column

Water 0.305

Para Toludine

0.80

Pure Dimethyl-p-

Toluidine 1.0

Seperator Crude DMPT

Effl.Water 0.60KL

Acetic Anhydride 0.05



15

9 . MONO ETHYL META TOLUIDINE (MEMT) & DIETYL META TOLUIDINE (MEMT & DEMT) Manufacturing Process: Ethyl alcohol and Meta Toluidine are mixed in a tank in required proportion, vaporized

in a vaporizer. Thenpassed through a Reactor containing Alumina catalyst. Reactor

product is Di-Ethyl Meta Toluidine and (DEMT) Mono Ethyl Meta Toluidine (MEMT)

collected in a tank, then separated by fractional distillation.

Chemical Reaction : CH3

|

C2H5OH + C6H4 NH2 (CH3) C6H4-NH-C2H5 + H2O

Ethyl Alcohol Meta Toluidine Mono Ethyl Water

Meta Toluidine

46 107 135 18

CH3

|

2C2H5OH + C6H4 NH2 (CH3) C6H4- N – (C2H5)2 + 2H2O

Ethyl Alcohol Meta Toluidine DiEthyl meta Water

Toluidine

92 107 163 36



16

MATERIAL BALANCE

Summary

Raw Material Product Effluent Water+ Waste

Meta toluidine 2.31 Pure MEMT 2.00 From Reaction 0.78

Alcohol 1.48 Pure DEMT 1.00 Process Washing 0.42

Water 0.41 Total Effluent 1.2 Distillation Residue 15 KG/Month



Vaporizer

Mixing tank Reactor

Separator

Condenser

Meta

Toludine

2.31

Ethyl

Alcohol 1.47

Water to

ETP

0.78

Reactor

Effluent.

Water 0.42

0.78

Distillation

MEMT

1.0

DEMT

2.0

Water

0.41



17

10. ABSOLUTE ALCOHOL Manufacturing Process Specially denatured spirit (SDS) containing about 6 % moisture is dried by passing

through molecular sieve, in a dryer.

Dry alcohol is collected in a tank and sold. Water from dryer is stripped and water

drained to ETP.

MATERIAL BALANCE

Summary

Raw Material Product Water

Alcohol 1.06 Absolute Alc. 1.00 Eff. Water 0.06



Alcohol

Day TK

Alcohol Dryer

Absolute Alcohol

Main Storage

Column

Ethyl Alcohol

(SDS) 1.06 KL

1.00 KL

Absolute

Alcohol

0.06KL

Water to ETP



18

11. MONO METHYL META TOLUIDINE & DIMETHYL META TOLUIDINE (MMMT & DMMT) Manufacturing Process : Methanol and meta-toluidine are mixed in a tank in required proportion, then vaporized

and passed through a Tubular Reactor containing Alumina catalyst. Reactor product is

Dimethyl Meta Toluidine (DMMT) and Mono Methyl Meta Toluidine (MMMT) collected in

a tank, water separated, washed with water to remove impurities .Then distilled under

vacuum to get pure MMMT and DMMT.

Chemical Reaction : CH3OH + C6H4 – NH2 – CH3 C6H4 – NH- (CH3)2 + H2O

Methanol M-Toluidine MMMT Water

32 107 121 18

2CH3OH + C6H4 – NH2 – CH3 C6H4 – N- (CH3)3 + 2H2O

Methanol M-Toludine DMMT Water

64 107 135 36

MATERIAL BALANCE :

Summary

Raw Material Product Effluent Water+waste

Meta toluidine 2.55 MMMT 1.00 From reaction 0.83

Methanol 1.29 DMMT 2.00 Process washing 0.47

Water 0.46 Total 1.30 KL

Distillation. Residue 15kg/Month




19


Vaporisor

Mixing tank Reactor

Dist.

Column

Separator Condenser

DMMT 2.0

Methanol

1.28

Meta Toluidine

2.55

MMMT 1.0

Water

0.46

Water ETP

1.3 KL



20

12. METHYL BENZYL ANILINE (MBA) Manufacturing Process Mono Methyl Aniline (MMA), caustic lye, are mixed in proper proportion, reacted with

benzyl chloride to get pure Methyl Benzyl Aniline. The aqueous layer separated,

drained to ETP. Then crude MBA distilled to get pure MBA.

Chemical Reaction : CH3

|

I. C6H5 – NH – CH3 + C6H5 – CH2Cl C6H5 – N – CH2 (C6H5) + HCL

MMA Benzyl Chloride MBA

107 126.5 197 36.5

II. HCL + NaOH NaCL + H2O

36.5 40 58.5 18

MATERIAL BALANCE

Summary

Raw Material Product Effluent Water+Waste

MMA 0.55 PMBA 1.00 From Reaction 0.27

BCL 0.68 Process Washing 1.73

C. S. Lye 0.05 Total Effluent 2.00 Distillation Residue 10Kg/Month

Water 1.72




21


MMA

0.55

Benzyl

Chloride

0.67 Caustic Lye

0.05

Reactor Separator Dist.

Column MBA

1.0

Water to ETP

2.0KL

Water

1.72



22

13. MONO ETHYL ORTHO TOLUIDINE (MEOT) Manufacturing Process : Ethyl Alcohol and Ortho Toluidine mixed in a tank, vaporized and passed through a

reactor containing Alumina Catalyst to get Mono Ethyl Ortho Toluidine (MEOT).

Chemical Reaction : C2H5OH + C6H4NH2 (CH3) C6H4- NH(C2H5) – CH3 + H2O

Ethyl Alcohol O-Toluidine MEOT Water

46 107 135 18 MATERIAL BALANCE

SUMMARY


Ortho Toluidine 0.83 MT Pure MEOT 1.0 MT From Reaction 0.23 KL

Alcohol 0.40 MT Process Washing 0.97 KL

Water 0.97 MT Total Effluent 1.20 KL

Distillation Residue 15Kg/Month

Total 2.2 MT Total Product + Water = 2.2 MT



23

MATERIAL BALANCE

Evaporator

Mixing tank Reactor

Dist.

Column

Separator Condenser

Ethyl

Alcohol

0.4

O-Toluidine

0.83

MEOT 1.0

Reaction Water

0.23

Water 0.97

Washing

0.97



24

14. ETHER SOLVENTS (ES) I.P./B.P. Process Description: Ethyl Alcohol (Specially Denatured Spirit), is evaporated in vaporizer. Then

vapors are fed to tabular reactor congaing Alum catalyst at 210°C Reactor mass

which Ether solvents and reaction water is cooled, fed to a distillation column.

Ether Solvents and water separated. Column bottom product which is water

discharged to ETP.

Column top product which is Diethyl Ether/Ether solvent taken for chemicals

treatment to remove impurities. This is treated with sodium bisulphite, Caustic

Soda and then washed with water.

Then it is distilled to get Ether solvent/Diethyl Ether.

Chemical Reaction : 2C2H5OH (C2H5) -O- (C2H5) + H2O

Ethyl Alcohol Ether Solvents/DiEthyl Ether Water

92 74 18

Material Balance:

Summary


Alcohol 1.31 Pure DEE 1.00

Sodium bisulphite 0.04 From Reaction 0.31

Caustic Soda Flake 0.03 From Washing 0.57

Water 0.5

1.00 0.88

Total 1.88 TOTAL Product + Water = 1.88



25


Vaporizer

Reactor

Condenser

Ethyl Alcohol 1.31

Caustic Soda 0.03

Sodium

BiSulphite

0.04 Water

0.5

Water to ETP 0.31

1.00 DIETHYL ETHER

Distillation Column

Reactor

Distillation Column

DiEthyl

Ether

Washing

0.57



26

15. ETHER ANAESTHETIC (EA) I.P./B.P. Manufacturing Process Ether Solvent contains some impurities like peroxide, aldehyde etc. It is purified by

chemicals treatment i.e. by treating in aqueous medium with sodium bisulphite, sodium

hydroxide. Then it is dried by passing through a tower containing caustic soda flakes.

Then it is distilled in a S. S. distillation column to get Anesthetic Ether I. P. / B. P. on

passing, this product is filled in bottles and sold.

Purification Of Solvent Ether As Under 2C2H5OH C2H5 – O – C2H5 + H2O

Ethyl Alcohol DiEthyl Ether Water

MATERIAL BALANCE

Summary

Raw Material Product Effluent Water Waste

Ether Solvents 1.20 Ether Anesthetic 1.0 Eff. Water 0.58

C. S. Flakes 0.03

Sod. Bi Sul 0.05

Water wash 0.30 1.0 0.58




27


Reactor Dist

Column

Water

0.3

Caustic soda 0.03

Sod.

Bisulphate

0.05

Ether

Solvent 1.2

Eff. Water 0.58

Anesthetic Ether

I.P/B.P 1.0



28

16. ETHYL CHLORIDE I.P./B.P. Manufacturing Process Crude Ethyl Chloride purchased in cylinder is distilled in a SS 316 column cooled and

product collected in a Tank. It is tested as per I.P. specs and filled in bottles.

MATERIAL BALANCE

Summary


Crude Ethyl Chloride 0.995 Pure Ethyl Chloride 1.00 Effl. Water NIL

Eau-De-Cologne 0.005



Ethyl Chloride

from Cylinder

Purification Pure Ethyl

Chloride 1.0MT

Eau-De-Cologne

0.005 MT

0.995 MT



29

17. Sulphuric Acid 65% Min MANUFACTURING PROCESS Sulphuric Acid generated from the enhancement of Dimethyl sulphate and Diethyl

Sulphate is spent Sulphuric Acid 65% Min, which is sold to fertilizer industry (Single

super phosphate) as a raw material.

18 &19 CHLORO SULPHONIC ACID (CSA) AND SULPHURIC ACID 70% Manufacturing Process

Chlorosulphonic Acid is manufactured by reacting dry HCl gas and liquid SO3 in

reaction tower. Dry HCl gas is produced by drying liquid HCl with 98% sulphuric acid in

a HCl generator. 70% Sulphuric acid from HCl generator is dechlorinated and made

free from HCl in a dechlorinator by hot air. 70% Sulphuric acid from dechlorinator

collected in a tank and recycled to the main sulphuric acid plant or sold.

Chemical Reaction : 1. SO3 + HCL(30%) HSO3CL

Sulphur trioxide Hydro chloric Acid Chloro sulphonic Acid

80 36.5 116.5

2. H2O + H2SO4(98%) H2SO4(70%)

Water Sulphuric Acid (98%) Sulphuric Acid (70%)

103 240 343



30

MATERIAL BALANCE

Summary


SO3 0.690 CSA 1.00 Eff. Water NIL *

HCl 0.31

H2O 0.88 Sulphuric Acid 70% 2.95

H2SO4(98%) 2.07

Total 3.95 Total Product = 3.95

Annexures to Form – 1 & PFR for Proposed Expansion Project for manufacturing of Speciality Chemicals by M/s Industrial Solvents and Chemicals Pvt. Ltd., Plot No. 7906-7909, GIDC Estate, Ankleshwar, Dist. Bharuch-393 002, Gujarat

31

Process flow Sheet with Mass BalanceW SHEET CHLORO SULPHONIC ACID (CSA) AND SULPHURIC ACID 70%

Tower

HCl

Generator

Dechlorinator CSA Storage

Tank

Chloro

Pump Tank

70% Sulphuric

Acid

Water

Scrubber

Water Tank

HCL Liquid 1.19

Sulphuric Acid

2.07

Vent

HCl

Gas

0.31

HCl

Gas

70% H2SO4

70% Sulphuric

Acid 2.95

CSA to

Despatch

70% Sulphuric Acid

for Recycle or sale

CSA

Hot

Air

CSA CSA

1.0

Liq SO3

0.69



32

20,21&22 SULPHUR TRIOXIDE(SO3),SULPHURIC ACID, & OLEUM (65% AND 24%) Manufacturing Process Solid Sulfur as received in Plant is melted and then burnt with air to get

sulfurdioxide (SO2). Which is oxidized in presence of Vanadium Pentoxide

Catalyst to convert to Sulfur Trioxide (SO3) which is absorbed in circulating

Sulfuric Acid in Absorption Towers. Increase in concentration of acid due to

absorption of SO3 in Acid is brought down to 98.4 % by dilution with water. Plant

uses DCDA process to control SO2 escape to less than GPCB norms in stack

gas.

A start up scrubber is installed using Alkaline solution of Caustic Soda to control

escape of SO2 during Commissioning or during any such period when plant is

started after shut down to keep emission below GPCB norms at any time.

Gas after 3RD pass of converter is withdrawn to pass through on Oleum tower

where 24 % Oleum is produced. Part of this production shall be sold while the

other part shall be converted to Liquid SO3 by evaporation and condensation.

Part of liquid SO3 produced shall be sold while the other part shall be converted

to 65 % Oleum by mixing Liquid SO3 with 24 % Oleum. Part of the liquid SO3

shall be sold or making Chloro Sulphonic Acid. Different sections of these plants

have suitable scrubber for control emission of SO3.

Chemical Reaction : 1. S + 3/2O2 SO3

Sulphur Oxygen Sulphur trioxide

32 48 80

2. SO3 + H2O H2SO4

Sulphur trioxide Water Sulphuric Acid

80 18 98

3. H2SO4 + SO3 H2S2O7

Sulphuric Acid Sulphur trioxide Oleum

98 80 178



33

MATERIAL BALANCE

Summary


Sulfur 1.08 SO3 1.00 Nil

O2 1.64 65% & 24% Oleum 1.00

Water 0.28 Sulphuric Acid 1.00

Total 3.000 Total Product = 3.00

Annexures to Form – 1 & PFR for Proposed Expansion Project for manufacturing of Speciality Chemicals by M/s Industrial Solvents and Chemicals Pvt. Ltd., Plot No. 7906-7909, GIDC Estate, Ankleshwar, Dist. Bharuch-393 002, Gujarat

34


S.Burner

Sulfur

1.08

O2

1.64 Converter Converter

Acid Tower

Oleum Tower

H2O

0.1

H2O

0.184

Sulphuric

Acid 1.0

65% and

24% Oleum

1.0

Liq. SO3 1.0

SO3

1.9

SO3

0.82

SO3

2.72



35

23. SULPHAMIC ACID Manufacturing Process Urea and Oleum 23% is fed in reactor continuously in measured quantity. The overflow

of CO2 liberated from reactor is connected to Vent. The overflow of reactor goes to

Clarifier. The overflow from clarifier (top side) 70% H2SO4 goes to 70%. H2SO4 storage

tank. The Sulphamic acid slurry from bottom is pumped to piller centrifuge. The

Sulphamic acid cake from piller centrifuge is sent to static mixture & then goes to

crystallizer. crystallizer bottom is drained in pusher centrifuge where sulphamic acid

crystals are separated & by screw conveyer sent to drier for drying. The product

Sulphamic acid is then packed in HDPE bags for sale.

Chemical Reaction NH2CONH2 + H2S2O7 2NH2SO3H + CO2

Urea Ole. 23 Sulphamic Acid Carbon Dioxide


Summary


Urea 0.3 Sulphamic Acid : 1.000 NIL

23% Oleum 2.926 MT CO2 : 0.226

70% Sul Acid : 2.000




36


Reactor

0.3MT

Urea

2.926MT

H2S2O7

0.226 MT

CO2

Clarifier Piller

0.226 MT

CO2

2.0MT 70%

H2SO4 ST

Static

Mixture

Pusher

Drier

1MT Sulphamic

Acid



37

24. NON FERRIC ALUM Manufacturing Process The 70% sulphuric acid and aluminum hydrate are added in measured quantity in

reactor. The slurry is heated by steam coil to complete the reaction. After completion of

reaction the material is drained in tray for drying and then milled & packed in HDPE

bags for sale.

Chemical Reaction Al2O3 + 3H2SO4 Al2(SO4)3 + 3H2O

Aluminium Sulphuric Non Ferric Water

Hydrate Acid Alum


Summary


Aluminum Hydrate : 0.298 Non Ferric Alum : 1.0 Water vapor: 0.157

Sulphuric Acid : 0.859




38


Reactor Trays Mill

0.298 Al2CO3 0.859 H2SO4

0.157 Water Vapor

1 Al2(SO4)


7909, GIDC Estate, Ankleshwar, Dist. Bharuch-393 002, Gujarat

ANNEXURE –D DETAILS OF WATER CONSUMPTION

DETAILS OF WASTE WATER GENERATION

Note:- 20**KLD Domestic Effluent to septic tank/Soak pit 72 KLD Existing Discharge to FETP (i.e. NCT) 302 KLD [251 Existing +51 Proposed] Water recycle with in the plant premises.

Sr. No.

Water consumption Quantity (KL/Day)

Consented Prop osed After Proposed

1. Domestic 20 0 20

2. Industrial

a. Process 185 0 185 b. Washing 20 0 20 c. Cooling 474 118 592 d. Boiler 200 44 244 Total [ a+ b + c + d ] 879 162 1041

3. Gardening 55 0 55 4. Other Use 2 0 2 Total [ 1+2+3+4] 956 162 1118

Waste Water Generation

Quantity (KL/day) Quantity (KL/day) Quantity (KL/day)

Consented P roposed Total After Proposed

Recycle To ETP

Remarks R ecycle To ETP

Remarks Recycle To ETP

Remarks

DOMESTIC 0 0 20** 0 0 0 0 0 20**

INDUSTRIAL

Process 61 64 ---- 11.0 0.0 ---- 72 64 ----

Washing 20 0 ---- 0.0 0.0 ---- 20 0 ----

Cooling 120 08 ---- 30.0 0.0 ---- 150 08 ----

Boiler 50 0 ---- 10.0 0.0 ---- 60 0 ----

Total [ Industrial ]

251 72 ---- 51.0 0.0 ---- 302 72 ----

Total Wastewater KL/day

251 72 20** 0.0 0.0 ---- 302 72 20**

Annexures to Form – 1 & PFR for Proposed Expansion Project for manufacturing of Speciality Chemicals by M/s Industrial Solvents & Chemicals Pvt. Ltd., Plot Nos. 7906-7909,

GIDC Estate, Ankleshwar, Dist. Bharuch-393 002, Gujarat

ANNEXURE – E

DETAILS OF HAZARDOUS WASTE

SR NO

Name of Waste

Category No.

Existing Quantity/

Year

Proposed Quantity/

Year

Total Quantity/

Year

Disposal

1. Used Oil 5.1 1.26KL - 1.26KL Collection, Storage, Transportation & Sale to MoEF registered reprocessors.

2. Distillation Residue

20.3 2.4MT - 2.4 MT Collection, Storage, Transportation & Disposal at common Incinerator of BEIL Ankleshwar.

3. Gunny Bags, Plastic Liners

33.1

1.2MT - 1.2MT Collection, Storage, Decontamination, Transportation

MS Drums 360 nos. - 360 nos.

HDPE Drums 2400 nos. - 2400 nos. Glass Wool 12 MT - 12 MT Collection, Storage,

Transportation,& Disposal at TSDF of M/S. BEIL ,Ankleshwar

Cooling tower Plastic fills

0.6 MT - 0.6 MT

4. ETP Sludge /MEE Sludge

35.3 1200 MT 200.00 1400 MT Collection, Storage, Transportation,& Disposal at TSDF of M/S. BEIL ,Ankleshwar

5. Activated Carbon

36.2 0.6 MT - 0.6 MT Collection, Storage, Transportation,& Disposed at TSDF of M/s. BEIL ,Ankleshwar

6. Sulphur Sludge

17.1 300 MT - 300 MT Collection, Storage, Transportation,& Disposed at TSDF of M/s. BEIL ,Ankleshwar

Annexures to Form – 1 & PFR for Proposed Expansion Project for manufacturing of Speciality Chemicals by M/s Industrial Solvents & Chemicals Pvt. Ltd., Plot Nos. 7906-7909,

GIDC Estate,Ankleshwar, Dist. Bharuch-393 002, Gujarat

ANNEXURE – F

DETAILS OF FLUE GAS EMISSION

Sr. No.

Stack Attached to

Name of fuel & its consumption

Stack Height

(m)

Control Measures

Type of pollutant

Permissible Limit,

1. Steam boiler (2 nos.)

Natural Gas 960 m3/hr

& Furnace oil 200 Lit/hr.

30 - PM 150 mg/Nm3 SO2 100 ppm

NOX 50 ppm 2. Thermic Fluid

oil Heater (3 nos.)

19.3 - PM 150 mg/Nm3 SO2 100 ppm NOX 50 ppm

3. Gas.Gen Set. [Waste Heat Recovery Boiler I &II

30 - PM 150 mg/Nm3 SO2 100 ppm NOX 50 ppm

DETAILS OF PROCESS GAS EMISSION

Sr. No.

Stack Attached to

Stack Height (m)

Control Measures

Type of pollutant

Permissible Limit,

1. Pump Gland (DMS)

30 Alkali Scrubber

SO2 40mg/Nm3

2. Pump Gland (DES)

11 Alkali Scrubber

SO2 40mg/Nm3

3. Sulphuric Acid Plant

50 Mist Eliminator

& Alkali Scrubber

SO2 2 Kg/Ton of 100% Sulphuric Acid

Production

Acid Mist

25mg/Nm3

4. CSA Plant 19 Scrubber HCl ≤20mg/Nm3

Note:For the proposed expansion steam will be satisfied from the existing utilities.-no any extra process gas emission stack will be installed.

We are using existing SO3 pump for pumping SO3 from ground level to process stack. Hence there is no any additional process stack require in DMS /DES Plants

PLOT NO.:- 7906 TO 7909 G.I.D.C. ANKLESHWAR

Annexures to Form – 1 & PFR for Proposed Expansion Project for manufacturing of Speciality Chemicals by M/s Industrial Solvents and Chemicals Pvt. Ltd., Plot No.

7906-7909, GIDC Estate,Ankleshwar, Dist. Bharuch-393 002, Gujarat

ANNEXURE – H PROPOSED TERMS OF REFERENCE

The generic structure of Environment Impact Assessment Study Report will be as

under:

1. Introduction This will cover the location and justification of the proposed project and scoping

and methodology for the EIA study.

2. Project Description

It will include the below mention details.

• Location of the project

• Product profile

• Resources requirement

• Manufacturing process and raw material requirement

• Material handling and storage

• Details on proposed Environmental Management System and

Monitoring.

• Storage and handling of hazardous chemicals

3. Baseline Environmental Description

The data regarding baseline environmental conditions will be collected

/generated as per the guidelines of MoEF. The methodology for collection of

baseline data for each of the component/environmental attribute is as follows: 1. Air

a. The study area will be of 10 Km radius considering the project site as center

and study period will be of one season except monsoon.

b. For estimation of back ground concentration of PM10, PM2.5, Oxides of

Nitrogen (NOx), Sulphur Dioxide (SO2), HC, VOC within study area,and 6 monitoring stati ons will be established as per theguidelines of CPCB and

Ministry of Environment & Forest, Government of India. At each station

monitoring will be carried out on 24 hourly bases twice in a week for entire

study period except monsoon.

Annexures to Form – 1 & PFR for Proposed Expansion Project for manufacturing of Speciality Chemicals by M/s Industrial Solvents and Chemicals Pvt. Ltd., Plot No.

7906-7909, GIDC Estate,Ankleshwar, Dist. Bharuch-393 002, Gujarat

2. Meteorology

Meteorological data like wind speed, wind direction, humidity, temperature,

will be collected at the location under consideration / from authorized agency, so

as to prepare wind-rose diagram and to predict the concentration of pollutants

using dispersion models. These data will be collected for a period of 12 weeks.

3. Water

Water samples will be collected and analyzed of raw water supply of the

Notified area.

4. Noise

The noise level will be measured once in a study period in Leq. at least at 6

different location within study area using an integrated sound level meter.

5. Land use pattern

The details of Land use pattern will be obtained from Satellite imagery.

4. Identification and Assessment of the Impacts

The activities having the potential to cause environmental impact will be

identified and the degree of impact will be assessed using standard matrix

methods. The following environmental attributes will be considered to establish

the cause-effect relationship with the various activities of the proposed project.

5. Environmental Management and Monitoring Plan

Environmental Management and Monitoring Plan will be prepared based on

the anticipated environmental impact. It will also cover details on Occupational

Health programs and as well as for corporate social responsibilities.

6. Risk Assessment : The study will include risk assessment for storage, handling, transportation

etc. for the raw material(s) and products to be used in the plant. Occupational risk

involved during operational phase of the plant will be assessed and necessary

safety and protective measures will be recommended.

COLOR NOTE

1. PLOT BOUNDARY

2. APPROVED WORK

3. REVISED WORK (EXISTING)

4. PROPOSED WORK

5. DRAINAGE LINE

6. GIDC ROAD

7. OPEN PARKING AREA

8. COMMON PLOT

9. APPROACH ROAD

10.PERCOLATING WELL WITH

R.W.H. SYSTEM

OWNER SIGN.

ENGINEER SIGN.

13

15.60

12

.5

0

14

1211

10

9

35

34

33

10.00

44

.7

0

16

.8

0

7.3020.20

20.20

10.00 7.30

16

.8

0

20.20

44

.7

0

44

.7

0

44

.7

0

10.00 7.30

25

20.00

15

.0

0

23.40

12

.4

0

24

11.00

22

.0

0

302.00 MT

160.00 M

T

5.0

0

11.00

12

.0

0

3.70

23

15

LAYOUT PLAN

( SCALE: 1 CM = 5.00 MT )

AREA TABLE

SQ.MT.

1. TOTAL PLOT AREA 47440.00

2. PERMISSIBLE B.A. ON G.F. 50% 23720.00

3. PERMISSIBLE F.S.I. 1.6 75904.00

4. APPROVED BUILT UP AREA

ON G. F. 06001.835

ON F. F. 03325.320

ON S. F. 02223.000

ON T. F. 00428.495

TOTAL B. A. 11978.65 - A

5. REVISED BUILT UP AREA (EXISTING)

ON G. F. 20943.23

ON F. F. 07026.91

ON S. F. 03757.06

ON T. F. 00874.86

ON F. F. 00537.25

ON MEZ. FL. 00000.00

TOTAL B. A. 33139.31 - B

6. C.O.P. - 1 TO 8 = 14147.16 SQ. MT.

REVISED FACTORY BUILDING ON PLOT NO.

7906 TO 7909 AT ANKLESHWAR, G.I.D.C,

INDUSTRAIL ESTATE, TALUKA. ANKLESHWAR ,

DIST.BHARUCH,

FOR M/s. INDUSTRIAL SOLVENT & CHEMICALS

PVT. LTD.

9.00 M

T

. W

I D

E

R

O

A

D

10.00 M T. R O A D

8.50 M

T

. W

I D

E

R

O

A

D

8.00 M

T

. W

I D

E

R

O

A

D

8.00 M T. W I D E R O A D 8.00 M T. W I D E R O A D

6.00 M T. W I D E R O A D

AUTHORITY

160.00 M

T

296.50 MT

2 0 . 0 0 M T. W I D E R O A D 2 0 . 0 0 M T. W I D E R O A D

3 0 . 0 0 M

T

. W

I D

E

R

O

A

D

8.20 M

T

. W

I D

E

R

O

A

D

3

2

1

4

7

6

5

8.00

9.00

9.009.60

34

.0

0

14

.0

0

14

.0

0

14

.0

0

19.807.00

3.25 3.25

6.50

6.50

8.3

09

.0

0

8.3

0

ALUM PLANT

SULPHUR

MELTER

EXISTING

STEAM TURBINE

PCC ROOM BLOWER ROOM

S A PLANT

SO3 PLANT

BUILDING

ACID FILLING SHED

(OLEUM & SA)

TANK YARD

SULPHUR YARD

FABRICATION

WORK SHOP

GAS

STATION

16

17

18

19

F.O.

21

39.00

61

.5

0

26.00

61

.5

0

39.00 35.00

21.309.50

16

.1

0

4.2

0

29

.2

0

22.20

29

.2

0

12.9015.30 22.30

22.20

24

.8

0

4.0

0

4.50

12

.0

0

12

.0

0

4.0

0

5.3

0

6.2

0

2.5

CHIMNEY

13.00

4.4

0

28

27

AT6 AT5

9.60

25.70

AT3 AT4

DMS

TK

SDS

TK

DMS

TK

DMS

TK

23.00

25.70

25.00

22

.7

0

13

.1

0

12

.9

0

22

.7

0

12

.9

0

13

.1

0

25.00

4.50

23.00

62.00

11.40

10

.0

0

AT2 AT1

25.00

13

.1

0

25.00

13

.1

0

7.80

11.90

3.60

26

11

.8

0

5.0

0

11.00

10

.2

0

4.90

6.6

0

5.00

3.00

25.00

7.0

08

.0

06

.6

0

25.00

6.70

6.00

10

.0

0

7.90

RO4

U/G WATER TANK

4 CELL

PUMP

51.10

7.10

6.2

06

.2

06

.2

06

.2

0

OPEN AREA

OPEN AREA

5.5

0

8.4

0

18

.8

0

9.00

9.00

9.00

9.50

D E S MCC

21.30

12

.0

0

12

.0

0

8.60

OPEN

AREA

9.50

D E S

D M A / E B A

COLLING

TOWER

NEW COLLING

TOWER

9.804.509.804.50

18

.6

0

18

.6

0

PU

MP

S

PU

MP

S

D M A C / D M S

61

.5

0

15.10

10

.2

0

4.20

8.1

0

10.00

7.0

0

3.1

0

4.50

7.10

6.3

0

20.20

10

.2

0

10

.0

0

45.00

13

.0

0

TANK

5.20

12.005.20

10.00

2.9

0

18

.9

0

16

.0

0

5.00

5.00 10.00

4.8

0

MAINT

PUMPS

UTILITY

H

AZ

W

S

TO

RA

GE

16

.0

0

30.50

26

.3

0

11

.9

0

28

.1

0

11.80

19.00

9.1

0

6.50

6.2

0

6.50

6.2

0

19.00

9.1

0

PLASTIC CARBOYS

& PLASTIC BARRELS PLANT

AMMONIA

CYLINDER

STORAGE

31

.3

0

8

9.5011.80

21

.6

0

1.9

20.60

24.00

13.00 5.00 6.00

8.2

0

8.2

0

13

.4

0

14.3014.30

42.00

10

.7

0

10

.7

0

42.00

U/G METHANOL STORAGE TANKS

20

SECURITY

CANTEEN

&

4.8

0

6.6

0

4.5

0

4.5

0

4.8

0

11

.0

0

7.50

6.5

0

4.50

12.00

6.0011.00

32

.0

0

8.90

6.0

0

RO3 PLANT

BARRAL SHED

2.1

3.40

5.7

0

19.00

20

.5

0

STORAGE TANK

19.00

T-304

T-305

T-601

T-600

22

16

.8

0

16

.8

0

37.50

61

.5

0

36

27/A

27

27

7.9

0

11

.8

0

GATE-1

SDS(ES)

SDS(ES) ANILINE

SPARE

14.00

14

.0

08

.0

0

MCC ROOM

HAZ. W .

STORAGE

14.005.65

5.65

12

.3

0

C/T

STORAGE

SHED

M

EE

P

LA

NT

29

30

RAMP

MEE

PUMP

22.50

42

.5

5

9.1

0

5.15

5.85

4.8

0

10.50

19

.4

51

1.6

5

10.50

5.00

5.4

5

9.1

0

31

EATHER PLANT

STORE

ROOM

E

AT

HE

R P

LA

NT

POWER

HOUSE

32

15.20

15

.2

0

15

.0

0

1.6

4.6

5

5.10

4.3

0

5.05 5.05

C. O. P.-1

23.00

46

.3

0

23.00 X 46.30 =1064.90

31.20

31

.1

0

13.60

20.00

5.0

0

C. O. P.-3

b. =68.00

c. 20.00 X 20.20

20

.2

0

a. 31.20 X 31.10 = 970.32

b. 13.60 x 05.00 = 68.00

c. 20.00 X 20.20 = 404.00

TOTAL =1584.32

27.65

4.50

4.65

35

.9

0

12

2

13

9

6

1

7

3

8

10

4

11

6.00 M T. W I D E R O A D

NOTE :-

LAST APPROVED FACTORY BUILDING PLAN BY EXECUTIVE

ENGINEER-I, G. I. D. C. ANKLESHWAR VIDE LATTER NO. 1031

DATE 26-03-1999.

2

6

8

7

9

4

5

10

3

11

12

13

14

15

16

17

1

NAME OF BUILDING

18

19

20

21

10.00 X 07.00

04.50 X 03.10

22

23

SECURITY CABIN

24

25

26

27

28

29

30

31

32

33

34

35

36

AMMONIA CYLINDER STORAGE SHED

WORK SHOP

PLASTIC CARBOYS BARRELS PLANT

SULPHER YARD

ALUM PLANT

SULPHER MELTER SHED

SULPHURIC ACID PLANT

OLEUM & S. A. TANK

ACID FILLING SHED

S O 3 PLANT

M.C.C. CONTROL ROOM

GAS RUN GENERATOR BLDG.

4 CELL COLLING TOWER

BOILER HOUSE

HCL & D. M. TANK FARM



UTILITY BLDG.

F. O. TANK

U/G METHANOL STORAGE TANK

U/G WATER TANK

SECURITY OHC & CANTEEN BLDG.

BARREL SHED & RO3 PLANT

E. T. P. PLANT

SDS (ES) TANK FARM

SDS / DMS TANK FARM

DRY ETHER & MEE PLANT

ETHER PLANT

D. G. ROOM / POWER HOUSE

D M A C / D M S PLANT

DMA / EBA PLANT

D E S PLANT

WEIGH BRIDGE ( UNDER GROUND )

20.20 X 10.20

04.20 X 08.10

30.50 X 26.30

45.00 X 13.00

19.80 X 14.00

09.60 X 34.00

09.60 X 06.20

07.00 X 31.30

30.80 X 29.20

09.50 X 28.10

11.80 X 12.00

21.30 X 16.10

15.60 X 12.50

15.10 X 10.20

25.00 X 21.60

07.90 X 10.00

24.00 X 08.20

20.60 X 13.40

19.00 X 09.10

2NO 06.50 X 06.20

14.30 X 18.60

14.30 X 18.60

10.00 X 04.80

10.00 X 02.90

32.20 X 16.00

07.50 X 06.50

42.00 X 10.70

03.70 X 12.00

11.00 X 32.00

STORAGE TANK T-304,T-305,T-600,T-601

19.00 X 20.50

37.50 X 61.50

39.00 X 61.50

35.00 X 61.50

20.00 X 15.00

23.40 X 12.40


25.70 X 12.90

2 NO 25.00 X 13.10

23.00 X 22.70

14.00 X 14.00

5.65 X 12.30

10.50 X 35.90

5.00 X 5.45

15.20 X 15.20

5.10 X 4.30

GA

TE

-2

STAIRCASE 3.27 X 2.50

51.50 X 12.00

03.00 X 04.80

02.40 X 04.85

04.40 X 06.60

27.65 X 26.45

17.65 X 16.10

2.40

4.40

4.8

5

6.6

0

30.80

10

.5

0

11.00

6.00

27/AE. T. P. PLANT

PRIMARY

TANK

PRIMARY

TANK

SETTING

6.2 X 4.6

SEC.

4.5X3

S.F

C.T

SECONDARY

CLARIFIER

F.C.T.

TANK

Ø3.5X2.5 ht

2.0 ht

SECONDARY

C.T.

2.50 ht

EQ TANKEQ TANK

EQ TANKEQ TANK

NEUTRALIZATION

TANK

SDB

5.0 x 5.0

LAMELA

S.FC.T

F.C.TK.

C.TK.

New SDB

4.2 x 4.5

New SDB

4.2 x 4.5

RO

C

ollection

3.0 D

EE

P

SEC.

Tk

2 1

34

2.5Deep

COLLECTION

3.5 DEEP

4.6 ht

S.F

C.T

Ø2.0 x 5.0ht

5.0 ht

2.5 DEEP

1.5Deep

2.5DEEP 2.5DEEP

4.0 ht

1.7DEEP

SDB

5.0 x 5.0

1.7DEEP

SDB

5.0 x 5.0

1.7DEEP

SDB

5.0 x 5.0

1.7DEEP

3.5 DEEP

NEUTRALIZATION

TANK

3.5 DEEP

3.2 DEEP 3.2 DEEP

3.2 DEEP 3.2 DEEP

2.9 ht

1.6ht

2.1DEEP

5.0 ht

47.50 x 29.90 = 1420.25

02.80 x 04.00 = 0011.20

LESS:- 0382.07

NET :- 1431.45

12.8032.70

05

.4

0

15

.0

0

11.50

07.40

28.60

PW-8

PW-1

PW-2

PW-3PW-4

PW-5

PW-6

PW-7

PW-9

PW-10

PW-11

PW-12

2

6

8

7

9

4

5

10

3

11

12

13

14

15

16

17

1

NAME OF BUILDING

18

19

20

21

22

23

SECURITY CABIN

24

25

26

27

28

29

30

31

32

33

34

35

36

AMMONIA CYLINDER STORAGE SHED

WORK SHOP

PLASTIC CARBOYS BARRELS PLANT

SULPHER YARD

ALUM PLANT

SULPHER MELTER SHED

SULPHURIC ACID PLANT

OLEUM & S. A. TANK

ACID FILLING SHED

S O 3 PLANT

M.C.C. CONTROL ROOM

GAS RUN GENERATOR BLDG.


BOILER HOUSE

HCL & D. M. TANK FARM



UTILITY BLDG.

F. O. TANK

U/G METHANOL STORAGE TANK

U/G WATER TANK

SECURITY OHC & CANTEEN BLDG.

BARREL SHED & RO3 PLANT

E. T. P. PLANT

SDS (ES) TANK FARM

SDS / DMS TANK FARM

DRY ETHER & MEE PLANT

HALOTHENE PLANT / -

D. G. ROOM / POWER HOUSE

D M A C / D M S PLANT

DMA / EBA PLANT

D E S PLANT


STORAGE TANK T-304,T-305,T-600,T-601

1552.06


27/AE. T. P. PLANT

G.F.

0916.99F.F.

0700.08S.F.

0237.50T.F.

2306.25

1621.50

1018.49

0145.09

0000.004th.F. 0013.32

0754.19

0704.51

0318.41

0092.41

0013.32

0000.00

0000.00

0000.00

0000.00

0000.00

1400.66

G.F.

1080.00F.F.

1015.00S.F.

0123.00T.F.

2398.50

1405.44

1214.85

0205.84

0997.84

0325.44

0199.58

0082.85

0000.00

0000.00

0000.00

0000.00

0450.57

G.F.

F.F.

S.F.

0050.75

T.F.

2152.50

1421.19

1102.38

0213.55

1701.43

0970.62

0651.81

0162.80

0000.00

0000.00

0000.00

0000.00

0450.57

0450.57

0000.00 0213.55 0213.55 0000.004th.F.

0400.00 0592.20 0192.20 0080.52

0594.67 0391.86 0000.000986.53

0000.00 1049.38 0000.001049.38

0159.36 0265.98 0106.62 0060.06

0000.00 0265.98 0265.98 0060.06

0255.495 0000.00 0000.000252.97

0031.36 0048.75 0017.39 0021.00

ELECTRICAL ROOM

0012.75 0000.00 0000.00 0000.00

0600.00

G.F.

0600.00F.F.

0057.35S.F.

1015.50

1015.50

0110.96

0415.50

0415.50

0053.61

0000.00

0000.00

0000.00

ETHER PLANT

0017.42

STAIR CABIN

0000.00 0000.00 0000.00

0232.99 0472.84 0239.85 0049.44

DETAILS OF COMPOUND WALL

GROUND BEAM

PILES/ COL. UP TO

YELLOW SOIL

BRICK WALL

0.80 M

T

GROUND BEAM

COPING BEAM

0.23

BRICK WALL

1.80 M

T.

PILES/ COL. UP TO

YELLOW SOIL

RCC COPING

0.23

ROAD SIDE

OTHER SIDE

C. C. JALI

1.50 M

T

0.70 M

T

DETAILS OF ENTRY GATE

COL UP TO FOUNDATION

ENTRY GATE

0.23

GROUND BEAM

7909 7908 7907 7906

79247925

7926

791079117912

7923

7922

62336234

20.00 MT WIDE R O A D

7905/A

7905/B

7905/C

7905/D

7905/E

7905/G

7905/F

7905/H

9704/A

9704/B

9704/C

9704/D

9704/E

9704/F

6401 6414

64026415

6713

67126716

6715

6816

6817

6820

6819

7115

7116

7118

7117

7307

7308 M

30.00 M

T W

ID

E R

O

A

D

20.00 MT WIDE R O A D

LAYOUT PLAN

( SCALE: 1 CM = 40.00 MT )

REQ PERCOLATING WELL= 48320 / 4000 = 12.08 NOS

PROVIDE PERCOLATING WELL = 12 NOS

PROVISION FOR RAIN WATER HARVESTING

0.60 X 0.60 CHAMBER

4" THK R.C.C SLAB

BRICK MASONARY

GRAVEL

STORAGE WATER

PAVED FLOOR

100 MM DIA AIR VENT

PLAN

SECTION

RECHARGE BORE - 1

150MM DIA P.V.C

PERFORATES PIPE

200MM CASING

GRAVEL FILLING

BOTTOM CAP

RECHARGE BORE - 1

RECHARGE BORE - 2

230MM THK BRICK WALL

150MM DIA P.V.C

PERFORATES PIPE

30.00 M

T.

3.00 M

T.

C O P - 1 = 1064.90 SQ. MT.

PROVIDED C. O. P.

TOTAL = 14147.16 SQ. MT.

C O P - 2 = 0260.70 SQ. MT.

PARKING SHED

0084.00 0000.00 0000.00 0000.00

D. G. ROOM & OFFICE 0227.92 0000.00 0000.000000.00G.F.

F.F. 0277.76 0000.00 0000.000000.00

9.00

9.00

0000.00 0604.00 0604.00 0012.00

0000.000389.70 0389.70 0155.48

0000.000619.00 0619.00 0078.96

0000.00 0253.50 0253.50 0085.50

6.2

0

0117.600000.00 0449.40 0449.40

7.50

0048.000000.00 0352.00 0352.00

0000.00 0000.00 0000.00 0000.00

0000.00

0000.00

0000.00

0000.00

0000.00

0000.00

0000.00

0000.00

0000.00

0000.00

0000.00

0000.00

0000.00

0000.00

0000.00

0000.00

0000.00

0000.00

0000.00 0522.100522.10

0000.00 0265.500265.50

0000.00 0404.200404.20

0000.00 0590.16 0590.16

0000.00 0000.00 0000.00

0000.00 0389.50 0389.50

0000.00 0044.40 0044.40

0000.00 0342.93 0342.93

0000.00 0416.72 0416.72

0000.00 0899.36 0899.36

0000.00 0219.10 0219.10

0000.00 0385.92 0385.92

0000.00 0277.20 0277.20

0000.00 0585.00 0585.00

0000.00 0802.15 0802.15

0000.00 0206.04 0206.04

0000.00 0083.95 0083.95

0000.00 0034.02 0034.02

11978.65 19773.50 0777.6233139.31

DEMOLISHDEMOLISH

DEMOLISH

DEMOLISH

DEMOLISH

0000.000000.00 0802.15 0802.15

G.F.

F.F.

0000.000000.00 0225.00 0225.00

G.F.

F.F.

G.F.

F.F.

S.F.

T.F.

4th.F.

0000.000000.00 0310.38 0342.93

0000.000000.00 0310.38 0342.93

0000.000000.00 0310.38 0342.93

0000.000000.00 0310.38 0342.93

0000.000000.00 0404.200225.75

G.F.

F.F.

C. O. P.- 4

31.20

22

.0

0

30.20 X 22.00 = 664.40

C O P - 3 = 1584.32 SQ. MT.

45.80

35

.4

0

45.80 x 35.40 = 1621.32

C. O. P.- 6

18.80 X 14.40 = 270.72

C. O. P.- 5

C O P - 4 = 1621.32 SQ. MT.

C O P - 5 = 0664.40 SQ. MT.

C. O. P.- 7

13.5 x 13.8

C. O. P.- 2

17.15 x 15.20 = 260.70

= 186.30

d. 10.00 X 14.20 = 142.00

d. 142.00

10.00

14

.2

0

= 404.00

C O P - 6 = 0270.72 SQ. MT.

C O P - 7 = 0186.30 SQ. MT.

COLOUR CODE1. EXISTING AREA IS SHOWN2. PROPOSED AREA IS SHOWN3. DMS PLANT (F.G. & R.M.)4. DES PLANT (F.G. & R.M.)

296.5 x 9 x 2 = 5337.00 SQ. MT.

160 x 9 x 2 = 2880.00 SQ. MT.

(R.M.)

(R.M.)

(R.M.)

(F.G.)

(R.M.)

(F.G.)

(F.G.)

(F.G.)

(F.G.)

(F.G.)

(F.G.)

(F.G.)

C. O. P.- 8

18.50 x 15.00

= 277.50

18.50

C O P - 8 = 0277.50 SQ. MT.

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