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Analytical Standards

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Page 1: Analytical Standards - AppliChem · Panreac Química, with more than 70 years experience in the manufacture and control of analytical reagents, offers a wide range of standards with

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Analytical Standards

Page 2: Analytical Standards - AppliChem · Panreac Química, with more than 70 years experience in the manufacture and control of analytical reagents, offers a wide range of standards with

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Welcome to

Analytical reagentsand fine chemicals

Page 3: Analytical Standards - AppliChem · Panreac Química, with more than 70 years experience in the manufacture and control of analytical reagents, offers a wide range of standards with

Panreac Química, with more than 70 years experience in the manufacture and

control of analytical reagents, offers a wide range of standards with a quality

appropriate for multidisciplinary applications.

The aim of any analytical laboratory should be to obtain analytical results of the

highest possible accuracy and reliability, and to achieve this it needs reliable

reference standards for both analytical instrument calibration and verification and

for performing analytical assays.

Standards

AA x x x x x xICP x x x x x xpH x x x x x x xISE x x x xConductivity x x xIon Chromatography x UV-VIS x x x xVolumetry x x x x x x xKarl Fischer x xCOD x x x x x xColour (Ph. Eur., BP, USP, Food Chemicals Codex)

APHA colour x x x x x xRedox x xTurbidity x x x xOenology (saccharose solutions,

hydroalcoholic solutions) TOC/TIC x x x x

Use of standards by sector

Sector

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Food

and

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Page 4: Analytical Standards - AppliChem · Panreac Química, with more than 70 years experience in the manufacture and control of analytical reagents, offers a wide range of standards with

Each Panreac standard is carefully prepared and controlled under an ISO 9001:2008 quality

assurance system. Our Quality Control Department uses the most up-to-date equipment and

instrumental techniques, including fluorescence spectroscopy, AAS-GF, ICP-OES, UV-VIS and IR;

gas chromatography with FID, ECD, NPD, GC-MS and head space detectors; HPLC, automatic

titrators and other standard laboratory instruments.

All our standards come with their corresponding certificate of analysis, which contains, amongst

other data, information such as the code, batch number, date of manufacture, minimum expiry

date, the real value compared to the guaranteed value and its uncertainty.

The following pages contain detailed information for all our standards and some

auxiliary analytical reagents offered by Panreac Química. If you cannot find the

standard you need, do not hesitate to contact us.

Analytical Standards

ICP Standards

AAS Standards pH buffers Ion Selective Electrode Standards

Redox Standards Conductivity Standards Ion Chromatography Standards

UV/VIS Spectrophotometry Standards

Volumetric Standards Water Standards for Karl Fischer COD Standards TOC and TIC Standards Turbidity Standards Colour Standards Wine Standards

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Page 5: Analytical Standards - AppliChem · Panreac Química, with more than 70 years experience in the manufacture and control of analytical reagents, offers a wide range of standards with

The development and spectacular growth experienced by modern instrumental techniques such as ICP-OES and

ICP-MS, especially for environmental analysis, means that

high-performance calibration standards are required.

Panreac’s range of ICP element standards meets the very

highest purity and quality requirements demanded by these

highly sensitive techniques.

The range of ICP element standards consists of 72

elements in concentrations ranging from 1.000

to 10.000 g/L.

The concentration of each element is strictly controlled to

an accuracy of ±0.2% of the true value, with NIST traceability.

Traces of 69 elements are analysed by ICP and the result is specified

on the certificate of analysis.

Preparation is carried out using raw materials of the highest available purity: 99.999% for metals as well as

ultra-pure water and acids. ICP standards are available in pre-washed 100-mL PE bottles, all of which are supplied

with their corresponding detailed certificate of analysis. This certificate includes the composition of the standard, its

date of manufacture, minimum expiry date, the actual value with respect to guaranteed value, traceability and the

concentration of trace impurities.

ICP Standards

5

Page 6: Analytical Standards - AppliChem · Panreac Química, with more than 70 years experience in the manufacture and control of analytical reagents, offers a wide range of standards with

6

ICP Standards Single element standards

Aluminium Al Al in 2-5% HNO3 766034.1208 775943.1208

Antimony Sb Sb in 2-5% HNO3 766035.1208 775944.1208

Arsenic As As2O

3 in 2-5% HNO

3 766036.1208 775945.1208

Barium Ba BaCO3 in 2-5% HNO

3 766037.1208 775947.1208

Beryllium Be Be in 2-5% HNO3 763173.1208 775899.1208

Bismuth Bi Bi in 2-5% HNO3 766039.1208 775948.1208

Boron B H3BO

3 in H

2O 765900.1208 -

Boron B H3BO

3 in 1% NH

3 766878.1208 -

Cadmium Cd Cd in 2-5% HNO3 766038.1208 775949.1208

Calcium Ca CaCO3 in 2-5% HNO

3 766040.1208 775950.1208

Cerium Ce CeO2 in 2-5% HNO

3 765901.1208 775951.1208

Cesium Cs Cs2CO

3 in 2-5% HNO

3 765902.1208 775952.1208

Chloride Cl KCl in H2O 765903.1208 775953.1208

Chromium Cr Cr in 2-5% HNO3 766043.1208 775956.1208

Cobalt Co Co in 2-5% HNO3 766041.1208 775954.1208

Copper Cu Cu in 2-5% HNO3 766042.1208 775955.1208

Dysprosium Dy Dy2O

3 in 2-5% HNO

3 765904.1208 775957.1208

Erbium Er Er2O

3 in 2-5% HNO

3 765905.1208 775958.1208

Europium Eu Eu2O

3 in 2-5% HNO

3 765906.1208 775962.1208

Gadolinium Gd Gd2O

3 in 2-5% HNO

3 765908.1208 775963.1208

Gallium Ga Ga2O

3 in 2-5% HNO

3 + traces HCl 765909.1208 775964.1208

Germanium Ge Ge in 2-5% HNO3 + traces HF 765910.1208 775965.1208

Gold Au Au in 20% HCl 766061.1208 775984.1208Hafnium Hf Hf in 5% HF 765911.1208 775966.1208Holmium Ho Ho

2O

3 in 2-5% HNO

3 765912.1208 775968.1208

Indium In In2O

3 in 2-5% HNO

3 765913.1208 775969.1208

Iridium Ir IrCl3.3H

2O in 20% HCl 765941.1208 775970.1208

Iron Fe Fe in 2-5% HNO3 766049.1208 775967.1208

Lanthanum La La2O

3 in 2-5% HNO

3 765916.1208 775973.1208

Lead Pb Pb in 2-5% HNO3 766063.1208 775988.1208

Lithium Li Li2CO

3 in 2-5% HNO

3 766059.1208 775974.1208

Lutetium Lu Lu2O

3 in 2-5% HNO

3 765917.1208 775975.1208

Magnesium Mg Mg in 2-5% HNO3 766051.1208 775976.1208

Manganese Mn Mn in 2-5% HNO3 766052.1208 775977.1208

Mercury Hg Hg in 2-5% HNO3 766060.1208 775978.1208

Molybdenum Mo Mo in 2-5% HNO3 + traces HF 766053.1208 775979.1208

Neodymium Nd Nd2O

3 in 2-5% HNO

3 765918.1208 775980.1208

Nickel Ni Ni in 2-5% HNO3 766054.1208 775982.1208

Niobium Nb Nb in 5% HF 765919.1208 775981.1208Nitrogen N (NH

4)2SO

4 in H

2O / KNO

3 in H

2O 765920.1208 775983.1208

Osmium Os (NH4)2OsCl

6 in 2-5% HCl 765921.1208 -

Palladium Pd Pd in 20% HCl 765922.1208 775985.1208 Phosphorus P KH

2PO

4 in H

2O 766384.1208 775907.1208

Platinum Pt Pt in 20% HCl 765923.1208 775987.1208Potassium K KNO

3 in 2-5% HNO

3 766050.1208 775989.1208

Praseodymium Pr Pr6O

11 in 2-5% HNO

3 765924.1208 775990.1208

Rhenium Re NH4ReO

4 in H

2O 765925.1208 775991.1208

Rhodium Rh RhCl3.3H

2O in 20% HCl 765926.1208 775992.1208

Rubidium Rb Rb2CO

3 in 2-5% HNO

3 765927.1208 775993.1208

Ruthenium Ru RuCl3.3H

2O in 20% HCl 765928.1208 775994.1208

Samarium Sm Sm2O

3 in 2-5% HNO

3 765929.1208 775995.1208

Scandium Sc Sc2O

3 in 2-5% HNO

3 765930.1208 775959.1208

Selenium Se Se in 2-5% HNO3 766055.1208 775996.1208

Silicon Si (NH4)2SiF

6 in 5% HF 765997.1208 775998.1208

Silver Ag Ag in 2-5% HNO3 766062.1208 775986.1208

Sodium Na NaNO3 in 2-5% HNO

3 766056.1208 775999.1208

Strontium Sr SrCO3 in 2-5% HNO

3 766048.1208 775961.1208

Sulphur S H2SO

4 in H

2O 765898.1208 775946.1208

Tantalum Ta Ta in 5% HF 765932.1208 776001.1208Tellurium Te Te in 2-5% HNO

3 765933.1208 776002.1208

Terbium Tb Tb4O

7 in 2-5% HNO

3 765934.1208 776003.1208

Thallium Tl Tl in 2-5% HNO3 765931.1208 776000.1208

Thorium Th Th(NO3)4.5H

2O in 10% HNO

3 765935.1208 776005.1208

Thulium Tm Tm2O

3 in 2-5% HNO

3 765936.1208 776006.1208

Tin Sn Sn in 20% HCl 766047.1208 775960.1208Titanium Ti Ti in 5% HF 766057.1208 776004.1208Tungsten W W in 5% HF 765939.1208 776009.1208Uranium U U in 2-5% HNO

3 765937.1208 776007.1208

Vanadium V V in 2-5% HNO3 765938.1208 776008.1208

Ytterbium Yb Yb2O

3 in 2-5% HNO

3 765914.1208 775971.1208

Yttrium Y Y2O

3 in 2-5% HNO

3 765915.1208 775972.1208

Zinc Zn Zn in 2-5% HNO3 766058.1208 776010.1208

Zirconium Zr Zr in 5% HF 765940.1208 776011.1208

Product name eLement comPoSItIon code 1000mg/L 10 000mg/L

a >> Glass bottle.

b >> Polyethylene bottle.

i >> Polyethylene canister.

C >> Polyethylene container with

removable tap.

1 >> Carton box with inner

polyethylene bag .

l >> Polyethylene bottle with

dropper.

d >> Glass tube with stopper

and screw top.

k >> Glass ampoule.

x >> Crimp top vial with

septum.

PackagIng SymboLS

Page 7: Analytical Standards - AppliChem · Panreac Química, with more than 70 years experience in the manufacture and control of analytical reagents, offers a wide range of standards with

7

We supply ultra-pure water for trace metal analysis with guaranteed impurity levels at the ppt (ng/L) scale.

This reagent is packaged in specially washed 500- and 1000-mL HDPE bottles.

We also supply a wide range of HIPERPUR and

HIPERPUR-PLUS ultra-pure acids for

trace metal analysis.

Do not hesitate to contact us.

ICP StandardsMulti-element standards

Standard solution containing Hf, Ir, Sb, Sn, Ta, Ti, Zr (100 mg/L each) 15% HCl 766336.1208

7 elements

Standard solution containing As, Be, Cd, Cr, Pb, Hg, Ni, Se, Tl (100 mg/L each) 10% HNO3 766334.1208

9 elements

Standard solution containing As, Be, Ca, Cd, Co, Cr, Cu, Fe, Li, Mg, Mn, Mo, Ni, Pb, Sb,

21elements Se, Sr, Ti, Tl, V, Zn (100 mg/L each) 5% HNO3 766335.1208

Standard solution containing Al, B, Ba, Be, Bi, Ca, Cd, Co, Cr, Cu, Fe, Ga, K,Li, Mg, Mn,

24 elements Na, Ni, Pb, Se, Sr, Te, Tl, Zn (100 mg/L each) 2% HNO3 766333.1208

Standard solution containing Ag, Al, B, Ba, Bi, Ca, Cd, Co, Cr, Cu, Fe, Ga, In, K, Li, Mg,

23 elements Mn, Na, Ni, Pb, Sr, Tl, Zn (1000 mg/L each) 2% HNO3 766332.1208

Product name eLementS matrIx code

In 100-mL Pe bottles.

ICP Standards Auxiliary ICP reagents

Water 500 mL b 711074.0010

Water 1000 mL b 711074.0011

Product name contentS PackagIng code

Reactivos ultrapurospara análisis de trazas metálicas

Reactivos ultrapuros

para análisis de trazas

metálicas

Page 8: Analytical Standards - AppliChem · Panreac Química, with more than 70 years experience in the manufacture and control of analytical reagents, offers a wide range of standards with

8

We supply 28 atomic absorption spectroscopy

standards at a concentration of 1.000 g/L, with

a tolerance level, in the vast majority of cases, of

±0.002 g/L, in 250- and 500-mL PE containers.

Each standard is supplied with its corresponding

certificate of analysis, which indicates the NIST

standard against which it has been traced and the

assay method used.

Aluminium Al Al(NO3)3.9H

2O in 0.5N HNO

3 313170.1209 313170.1210

Antimony Sb SbCl3 in 5N HCl 314133.1209 314133.1210

Arsenic As As2O

5 in H

2O 313171.1209 -

Barium Ba Ba(NO3)2 in 0.5N HNO

3 313172.1209 313172.1210

Bismuth Bi Bi(NO3)3.5H

2O in 0.5N HNO

3 313174.1209 -

Cadmium Cd Cd(NO3)2.4H

2O in 0.5N HNO

3 313175.1209 313175.1210

Calcium Ca Ca(NO3)2.4H

2O in 0.5N HNO

3 313176.1209 313176.1210

Chromium Cr Cr(NO3)3.9H

2O in 0.5N HNO

3 313179.1209 313179.1210

Cobalt Co Co(NO3)2.6H

2O in 0.5N HNO

3 313177.1209 313177.1210

Copper Cu Cu(NO3)2.3H

2O in 0.5N HNO

3 313178.1209 313178.1210

Gold Au HAuCl4.4H

2O in 1.2% HCl 313672.1209 313672.1210

Iron Fe Fe(NO3)3.9H

2O in 0.5N HNO

3 313182.1209 313182.1210

Lead Pb Pb(NO3)2 in 0.5N HNO

3 313189.1209 313189.1210

Lithium Li LiCl in ~1% HCl 313183.1209 313183.1210Magnesium Mg Mg(NO

3)2.6H

2O in 0.5N HNO

3 313184.1209 313184.1210

Manganese Mn Mn(NO3)2 in 1N HNO

3 313185.1209 313185.1210

Mercury Hg Hg(NO3)2 in 1N HNO

3 313186.1209 313186.1210

Molybdenum Mo (NH4)6Mo

7O

24.4H

2O in 0.5N NH

4OH 314111.1209 314111.1210

Nickel Ni Ni(NO3)2.6H

2O in 0.5N HNO

3 313187.1209 313187.1210

Potassium K KCl in ~1% HCl 313190.1209 313190.1210Selenium Se H

2SeO

3 in 1N HNO

3 313191.1209 313191.1210

Silicon Si Na2SiO

3 in H

2O 312683.1209 312683.1210

Silver Ag AgNO3 in 0.5N HNO

3 313188.1209 313188.1210

Sodium Na NaCl in ~1% HCl 313192.1209 313192.1210Strontium Sr Sr(NO

3)2 in 0.5N HNO

3 313181.1209 -

Tin Sn SnCl4 in 5N HCl 313180.1209 313180.1210

Titanium Ti TiCl4 in 5N HCl 313960.1209 313960.1210

Zinc Zn Zn(NO3)2.6H

2O in 0.5N HNO

3 313193.1209 313193.1210

Product name eLement comPoSItIon code 250 mL 500 mL

AAS standards

AAS standards Single element standard solutions

Page 9: Analytical Standards - AppliChem · Panreac Química, with more than 70 years experience in the manufacture and control of analytical reagents, offers a wide range of standards with

9

We offer a full range of reagents to cover all atomic absorption spectroscopy needs.

PA products with a low Hg content are specifically recommended for assaying mercury by atomic absorption using the

cold vapour method. This range also includes the most common acids (Hg content < 0.05 ppm (mg/L)) and salts such as

sodium borohydride.

The ANALPUR range of acids, with low trace metal content, is suitable for the analysis of heavy metals such as Pb, Sn, Cr,

etc. or elements such as As, Zn, Cd, etc.

We also supply ionisation buffers for atomic absorption for use as ionisation suppressers and phosphate-, lanthanum-

and magnesium-based matrix modifiers to minimise chemical interference resulting from the presence of aluminium,

silicon or phosphorus.

We recommend that AAS standard solutions be prepared with our PA-ACS quality water, which guarantees trace metal

concentrations of less than 0.01 ppm in most cases.

Request further information regarding our PA

low-mercury range and the ANALPUR range of

low trace metal acids.

Product name comPoSItIon contentS PackagIng code

Buffer Solution Cesium CsCl + La2O

3 in HCl 1000 mL b 176168.1211

Chloride/Lanthanum Chloride

Hydroxylammonium Chloride --- 250 g b 471914.1209

Lanthanum Matrix Modifier La2O

3 in HCl 100 mL b 176166.1208

Magnesium Matrix Modifier Mg(NO3)2.6H

2O in 100 mL b 176170.1208

HNO3

Phosphate Matrix Modifier NH4H

2PO

4 in H

2O 100 mL b 176169.1208

Potassium Permanganate --- 500 g b 471527.1210

1000 g b 471527.1211

Sodium Borohydride (Reag. USP) --- 25 g a 123314.1606

100 g a 123314.1608

Tin(II) Chloride 2-hydrate --- 250 g a 471303.1609

Water --- 1000 mL b 131074.1211

2.5 L b 131074.1212

5L i 131074.1214

Low mercurycontent reagentsfor trace analysis

For Cold Vapour andHydride Generation methods

Low mercurycontent reagentsfor trace analysisFor Cold Vapour andHydride Generation methods

AAS standardsAuxiliary AAS reagents

Page 10: Analytical Standards - AppliChem · Panreac Química, with more than 70 years experience in the manufacture and control of analytical reagents, offers a wide range of standards with

10

pH measurement is critical to any analytical laboratory, therefore the equipment used for this

purpose must be checked and adjusted regularly.

Panreac offers a wide range of NIST SRM-traceable pH buffer

solutions for the calibration of pH meters. This range of buffers

includes both concentrated buffer solutions, which we refer to as STc

and ready-to-use solutions referred to as ST. All these solutions are

very stable and can be stored for long time periods (up to 6 years).

An accuracy of ±0.02 pH units, at a temperature of 20°C, is

guaranteed in most cases.

The label on each container indicates its composition, batch number,

expiry date and pH variation with temperature for better control of

quality management.

All sales units of these solutions

come with their corresponding

certificate of analysis.

If you cannot find the buffer solution

that you need, we can manufacture

it for you. Please do not

hesitate to contact us.

pH buffers Equipment verification and adjustment

Ready-to-use buffer solutions

ph vaLue (20ºc) comPonentS contentS PackagIng code

1.00 ± 0.02 Glycine 250 mL b 272580.1209

Sodium Chloride 1000 mL b 272580.1211

Hydrochloric acid

2.00 ± 0.02 Citric Acid 250 mL b 272581.1209

Sodium Hydroxide 1000 mL b 272581.1211

Hydrochloric acid

3.00 ± 0.02 Citric Acid 250 mL b 272537.1209

Sodium Hydroxide 1000 mL b 272537.1211

Hydrochloric acid

4.00 ± 0.02 Citric Acid 250 mL b 272168.1209

Sodium Hydroxide 1000 mL b 272168.1211

Hydrochloric acid 5 L i 272168.1214

10 L C 272168.1315

5.00 ± 0.02 Citric Acid 250 mL b 272582.1209

Sodium Hydroxide 1000 mL b 272582.1211

6.00 ± 0.02 Citric Acid 250 mL b 272549.1209

Sodium Hydroxide 1000 mL b 272549.1211

pH buffers

Page 11: Analytical Standards - AppliChem · Panreac Química, with more than 70 years experience in the manufacture and control of analytical reagents, offers a wide range of standards with

11

Ready-to-use buffer solutions

Coloured buffer solutions are easily identifiable in the laboratory.

They are also available in easy-to-handle single-dose packs, which means that a new solution is used each time,

thereby avoiding possible contamination problems.

ph vaLue (20ºc) comPonentS contentS PackagIng code

7.00 ± 0.02 Potassium di-Hydrogen Phosphate 250 mL b 272170.1209

di-Sodium Hydrogen Phosphate 1000 mL b 272170.1211

5 L i 272170.1214

10 L C 272170.1315

7.02 ± 0.02 Potassium di-Hydrogen Phosphate 250 mL b 273108.1209

di-Sodium Hydrogen Phosphate 1000 mL b 273108.1211

8.00 ± 0.02 Boric Acid 250 mL b 272583.1209

Sodium Hydroxide 1000 mL b 272583.1211

Hydrochloric acid

9.00 ± 0.02 Boric Acid 250 mL b 272172.1209

Potassium Chloride 1000 mL b 272172.1211

Sodium Hydroxide 10 L C 272172.1315

9.23 ± 0.02 Boric Acid 250 mL b 273107.1209

Sodium Hydroxide 1000 mL b 273107.1211

10.00 ± 0.05 Boric Acid 250 mL b 272584.1209

Potassium Chloride 1000 mL b 272584.1211

Sodium Hydroxide 5 L i 272584.1214

11.00 ± 0.05 Boric Acid 250 mL b 272585.1209

Sodium Hydroxide 1000 mL b 272585.1211

12.00 ± 0.05 di-Sodium Hydrogen Phosphate 250 mL b 272586.1209

Sodium Hydroxide 1000 mL b 272586.1211

13.00 ± 0.05 Potassium Chloride 250 mL b 272587.1209

Sodium Hydroxide 1000 mL b 272587.1211

ph vaLue (20ºc) comPonentS contentS PackagIng code

4,00 ± 0,02 (red) Cítric Acid 12 x 20 mL 1 273616.0922

Sodium Hydroxide 250 mL b 273616.1209

500 mL b 273616.1210

Hydrochloric acid 1000 mL b 273616.1211

10 L C 273616.1315

7,00 ± 0,02 (yellow) Potassium di-Hydrogen Phosphate 12 x 20 mL 1 273617.0922

di-Sodium Hydrogen Phosphate 250 mL b 273617.1209

500 mL b 273617.1210

1000 mL b 273617.1211

10 L C 273617.1315

10,00 ± 0,05 (blue) Boric Acid 250 mL b 273618.1209

Potassium Chloride 500 ml. b 273618.1210

Sodium Hydroxide 1000 mL b 273618.1211

10 L C 273618.1315

pH buffersColoured ready-to-use buffer solutions

Page 12: Analytical Standards - AppliChem · Panreac Química, with more than 70 years experience in the manufacture and control of analytical reagents, offers a wide range of standards with

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pH values depending on temperature

T(°C) DpH DpH DpH DpH DpH DpH DpH DpH

0 -0.04 0.01 0.05 0.05 0.06 0.04 0.13 0.13

5 -0.01 0.01 0.05 0.04 0.05 0.02 0.07 0.07

10 -0.01 0.01 0.03 0.02 0.02 0.01 0.05 0.05

15 -0.01 0 0.01 0.01 0.01 0 0.02 0.02

20 0 0 0 0 0 0 0 0

25 0.01 0 0 0.01 0 0.02 -0.02 -0.02

30 0.01 0 0 0.01 0 0.03 -0.02 -0.02

35 0.01 0 0 0.01 0 0.03 -0.04 -0.04

40 0.01 0 -0.02 0.01 0 0.04 -0.05 -0.05

50 0.01 0 -0.03 0 0.01 0.06 -0.05 -0.05

pH 8.00 9.00 9.23 10.00 11.00 12.00 13.00

T(°C) DpH DpH DpH DpH DpH DpH DpH

0 0.15 0.24 0.24 0.26 0.45 0.58 0.80

5 0.10 0.16 0.17 0.17 0.32 0.41 0.59

10 0.07 0.11 0.11 0.11 0.20 0.26 0.37

15 0.04 0.05 0.05 0.05 0.10 0.10 0.18

20 0 0 0 0 0 0 0

25 -0.04 -0.05 -0.05 -0.06 -0.10 -0.12 -0.17

30 -0.06 -0.09 -0.09 -0.11 -0.19 -0.28 -0.33

35 -0.08 -0.12 -0.12 -0.16 -0.28 -0.33 -0.41

40 -0.10 -0.15 -0.16 -0.18 -0.36 -0.46 -0.59

50 -0.15 -0.21 -0.21 -0.26 -0.52 -0.67 -0.85

a >> Glass bottle.

b >> Polyethylene bottle.

i >> Polyethylene canister.

C >> Polyethylene container with

removable tap.

1 >> Carton box with inner

polyethylene bag .

l >> Polyethylene bottle with

dropper.

d >> Glass tube with stopper

and screw top.

k >> Glass ampoule.

x >> Crimp top vial with

septum.

PackagIng SymboLS

pH 1.00 2.00 3.00 4.00 5.00 6.00 7.00 7.02

Page 13: Analytical Standards - AppliChem · Panreac Química, with more than 70 years experience in the manufacture and control of analytical reagents, offers a wide range of standards with

13

Concentrated buffer solutions save storage space. They are supplied in PE packs containing 25 capsules. Preparing

the solution is as simple as dissolving the contents of a capsule in 100 mL of distilled water.

ph vaLue (25ºc) code

4.01 ± 0.02 293164.1224

7.00 ± 0.02 293165.1224

9.00 ± 0.02 293166.1224

10.00 ± 0.02 293167.1224

pH 4.01 7.00 9.00 10.00

T (°C) pH pH pH pH

10 4.00 7.07 9.21 10.18

15 4.01 7.04 9.14 10.14

20 4.01 7.02 9.06 10.06

25 4.01 7.00 9.00 10.00

30 4.01 6.99 8.96 9.95

35 4.02 6.98 8.92 9.91

40 4.03 6.97 8.88 9.85

50 4.06 6.96 8.83 9.78

60 4.08 6.96 8.81 9.75

pH values depending on temperature

pH buffersConcentrated buffer solutions

Page 14: Analytical Standards - AppliChem · Panreac Química, with more than 70 years experience in the manufacture and control of analytical reagents, offers a wide range of standards with

14

We supply the different reagents needed to maintain the electrodes in optimum condition.

Electrode regenerating solutions, which allow certain anomalies, such as slow response, high asymmetry

potential or low sensitivity, to be resolved.

Protein Cleaning Solution: recommended for regenerating electrodes commonly used to measure

samples with a high protein content (milk, cheese, meat, blood, sera, etc.).

Electrolyte solutions for refilling the reference electrolyte when necessary. We supply three electrolyte solutions,

which we supply in both the standard 250-mL packaging and a special presentation consisting of a 100-mL bottle

with a spout to simplify the refilling of the electrode through the opening.

pH buffers Auxiliary reagents for pH determination

Protein Cleaning Solution 5% Pepsin in 0.1 mol/L HCl - 285252.1209

Potassium Chloride saturated solution 35 g KCl in 100 mL H2O 281495.1208 281495.1209

Potassium Chloride 3 mol/L 22.37 g KCl in 100 mL H2O 282775.1208 282775.1209

Potassium Chloride 3 mol/L + Silver Chloride 22.37 g KCl + 0.1 g AgCl in 100 mL H2O 282923.1208 282923.1209

Product name comPoSItIon code 100 mL * 250 mL

* bottle with a dropper nozzle

Page 15: Analytical Standards - AppliChem · Panreac Química, with more than 70 years experience in the manufacture and control of analytical reagents, offers a wide range of standards with

15

Ion-selective electrodes (ISE) are more sensitive to one type of

ion than to others with a similar electrochemical behaviour.

To control and verify the correct functioning of these electrodes,

we have a fluoride standard of 1.000 ± 0.005 g/L and an

ammonium standard of 1.000 ± 0.002 g/L.

Fluoride F- NaF in H2O 250 mL 312682.1209

500 mL 312682.1210

Ammonium NH4+ NH

4Cl in H

2O 500 mL 784241.1210

In Pe bottles

Product name Ion comPoSItIon contentS code

Ion Selective Electrode Standards

Page 16: Analytical Standards - AppliChem · Panreac Química, with more than 70 years experience in the manufacture and control of analytical reagents, offers a wide range of standards with

16

Iron and aluminium interfere with the detection of fluoride by ISEs. Depending on the pH at which the

measurement should be performed and the iron and/or aluminium concentration present in the sample, the use

of solutions that mask the interfering elements and buffer the pH to the required value may be needed.

Panreac Química supplies a wide range of Total Ionic Strength Adjustment Buffer (TISAB) solutions that help to

simplify these analyses.

In Pe bottles

TISAB I (ASTM D 1179) for samples containing 5.8 ± 0.1 Glacial acetic acid 1000 mL 275210.1211

<0.1 ppm in Fe Sodium Chloride

and/or Al Sodium Citrate

Sodium Hydroxide

TISAB II (STANDARD for samples containing 5.15 ± 0.1 1,2-Diaminocyclohexane 1000 mL 274765.1211

METHODS/AOAC) <3 ppm in Fe and/or Al N,N,N’,N’-tetraacetic acid

Sodium Hydroxide

Glacial acetic acid

Sodium Chloride

TISAB III for samples containing 5.25 ± 0.25 1,2-Diaminocyclohexane 500 mL 273526.1210

(concentrated solution) <3 ppm in Fe and/or Al N,N,N’,N’-tetraacetic acid

Ammonium Chloride

Ammonium Acetate

Cresol Red

TISAB IV for samples containing 8.5 ± 0.1 Hydrochloric acid 500 mL 273531.1210

(ASTM D 1179) <100 ppm in Fe and/or Al Tris (Hydroxymethyl)

Aminomethane

Sodium Tartrate

TISAB-ENOL for wine analysis 5.5 ± 0.1 1,2-Diaminocyclohexane 250 mL 625891.1209

(Dir. 2676/90) N,N,N’,N’-tetraacetic acid 1000 mL 625891.1211

Sodium Chloride

Sodium Citrate

Glacial acetic acid

Sodium Hydroxide

Product name tyPe of SamPLe ph comPoSItIon contentS code

Auxiliary reagents for ion-selective electrodes

Ion Selective Electrode Standards

Page 17: Analytical Standards - AppliChem · Panreac Química, with more than 70 years experience in the manufacture and control of analytical reagents, offers a wide range of standards with

17

Product name tyPe of SamPLe ph comPoSItIon contentS code

To verify the correct functioning of redox measuring systems,

Panreac offers two solutions that guarantee values of 220 and

468 mV at 25 °C.

Redox Standard 220 mV (25°C) Potassium Hexacyanoferrate(II) 395443.1209 Potassium Hexacyanoferrate(III) Buffer Solution pH 7.00 Redox Standard 468 mV (25°C) Iron(II) Sulphate 395442.1209 Iron(III) Sulphate Sulphuric Acid

Product name comPoSItIon code

In 250-mL Pe bottles

T(ºC) mV

Redox potential values (mV) depending on temperature

10 245 452

15 236 457

20 228 463

25 220 468

30 212 474

35 204 479

40 195 485

50 178 497

60 160 509

70 142 522

a >> Glass bottle.

b >> Polyethylene bottle.

i >> Polyethylene canister.

C >> Polyethylene container with

removable tap.

1 >> Carton box with inner

polyethylene bag .

l >> Polyethylene bottle with

dropper.

d >> Glass tube with stopper

and screw top.

k >> Glass ampoule.

x >> Crimp top vial with

septum.

PackagIng SymboLS:

Redox Standards

Page 18: Analytical Standards - AppliChem · Panreac Química, with more than 70 years experience in the manufacture and control of analytical reagents, offers a wide range of standards with

18

Conductivity is one of the fundamental parameters in chemical analysis,

especially in water quality control.

We supply different conductivity standards in 250-mL plastic bottles and

single-dose 20-mL bottles so that a new solution can be used each time,

thereby avoiding possible contamination problems.

All our conductivity standards are NIST traceable and are accompanied by their

corresponding certificate of analysis.

The product label indicates the composition, the variation of conductivity with

temperature and the expiry date for better quality assurance.

0.084 ± 0.002 0.00056 mol/L 12 x 20 mL 1 396882.0922

250 mL b 396882.1209

0.147 ± 0.005 0.001 mol/L 12 x 20 mL 1 396881.0922

250 mL b 396881.1209

1.413 ± 0.005 0.010 mol/L 12 x 20 mL 1 394659.0922

250 mL b 394659.1209

5.446 ± 0.025 0.040 mol/L 12 x 20 mL 1 394657.0922

250 mL b 394657.1209

12.88 ± 0.06 0.100 mol/L 12 x 20 mL 1 394658.0922

250 mL b 394658.1209

comPoSItIon (kcl) contentS PackagIng codeconductIvIty nomInaL vaLue (mS/cm) at 25ºc

T(ºC) (mS/cm)

Conductivity values depending on temperature

20.0 0.0758 0.133 1.278 4.915 11.67

21.0 0.0775 0.136 1.305 5.022 11.91

22.0 0.0791 0.139 1.332 5.128 12.15

23.0 0.0807 0.142 1.359 5.234 12.39

24.0 0.0824 0.145 1.386 5.340 12.64

25.0 0.0840 0.147 1.413 5.446 12.88

26.0 0.0856 0.150 1.440 5.552 13.13

27.0 0.0873 0.153 1.467 5.658 13.37

28.0 0.0889 0.156 1.494 5.764 13.62

29.0 0.0906 0.159 1.522 5.870 13.87

30.0 0.0922 0.162 1.549 5.976 14.12

Conductivity Standards

Ready-to-use conductivity standard solutions

Conductivity Standards

Page 19: Analytical Standards - AppliChem · Panreac Química, with more than 70 years experience in the manufacture and control of analytical reagents, offers a wide range of standards with

19

comPoSItIon (kcl) contentS PackagIng code

Ion chromatography is one of the most widely used trace-anion and

-cation analytical techniques in the fields of water and

environmental analysis.

Panreac Química supplies a very wide range of both mono- and

multi-element anion and cation standards in 500-mL polyethylene

bottles with a concentration of 1.000 g/L.

All our standard solutions are NIST traceable and come with their

corresponding certificate of analysis.

Product name Ion comPoSItIon (in h2o) code

Aluminium Al3+ 8.948 g/L AlCl3.6H

2O 786912.1210

Ammonium NH4

+ 2.97 g/L NH4Cl 784241.1210

Arsenic AsO2

- 1.734 g/L NaAsO2 786913.1210

Barium Ba2+ 1.779 g/L BaCl2.2H

2O 786347.1210

Boron BO2

- 6.086 g/L NaBO2 786914.1210

Bromide Br- 1.489 g/L KBr 784239.1210Cadmium Cd2+ 2.745 g/L Cd(NO

3)2.4H

2O 786915.1210

Calcium Ca2+ 3.668 g/L CaCl2.2H

2O 786345.1210

Cesium Cs+ 1.267 g/L CsCl 786916.1210Chloride Cl- 2.1 g/L KCl 784238.1210Chromate CrO

42- 1.674 g/L K

2CrO

4 786326.1210

Chromium (VI) Cr2O

72- 2.829 g/L K

2Cr

2O

7 786920.1210

Chromium (III) Cr3+ 7.696 g/L Cr(NO3)3.9H

2O 786921.1210

Cobalt Co2+ 4.938 g/L Co(NO3)2.6H

2O 786918.1210

Copper Cu2+ 3.802 g/L Cu(NO3)2.3H

2O 786919.1210

Cyanide CN- 2.503 g/L KCN 786917.1210Fluoride F- 2.21 g/L NaF 786328.1210Hidrazine NH

2NH

3+ 4.1 g/L N

2H

4.H

2SO

4 786923.1210

Hydrogen Carbonate HCO3

- 1.377 g/L NaHCO3 786924.1210

Iodide I- 1.308 g/L KI 786934.1210Iron Fe3+ 7.234 g/L Fe(NO

3)3.9H

2O 786925.1210

Lead Pb2+ 1.599 g/L Pb(NO3)2 786931.1210

Lithium Li+ 6.108 g/L LiCl 786348.1210Magnesium Mg2+ 8.363 g/L MgCl

2.6H

2O 786346.1210

Manganese Mn2+ 4.569 g/L Mn(NO3)2.4H

2O 786350.1210

Mercury Hg2+ 1.708 g/L Hg(NO3)2.1H

2O 786926.1210

Nickel Ni2+ 4.953 g/L Ni(NO3)2.6H

2O 786927.1210

Nitrate NO3

- 1.63 g/L KNO3 784237.1210

Nitrite NO2

- 1.50 g/L NaNO2 786327.1210

Nitrogen (N-NH4

+) NH4

+ 3.81 g/L NH4Cl 786325.1210

Nitrogen (N-NO2

-) NO2

- 4.9262 g/L NaNO2 786928.1210

Nitrogen (N-NO3

-) NO3

- 7.218 g/L KNO3 786929.1210

Ion Chromatography Standards

Single element standards Ion Chromatography Standards

Page 20: Analytical Standards - AppliChem · Panreac Química, with more than 70 years experience in the manufacture and control of analytical reagents, offers a wide range of standards with

20

Product name Ion comPoSItIon code

Phosphate HPO4

2- 2.2014 g/L NaNH4HPO

4.4H

2O 784236.1210

Phosphorus HPO4

2- 4.264 g/L (NH4)2HPO

4 786922.1210

Potassium K+ 1.907 g/L KCl 784242.1210Rubidium Rb+ 1.415 g/L RbCl 786932.1210Silver Ag+ 1.575 g/L AgNO

3 786930.1210

Sodium Na+ 2.542 g/L NaCl 784243.1210Strontium Sr2+ 2.416 g/L Sr(NO

3)2 786351.1210

Sulphate SO4

2- 1.479 g/L Na2SO

4 786329.1210

Sulphur SO4

2- 4.121 g/L (NH4)2SO

4 786933.1210

Zinc Zn2+ 3.998 g/L Zn(NO3)2.4H

2O 786349.1210

In Pe bottles

Product name contentS PackagIng code

Water 1000 mL b 131074.1211 2.5 L 131074.1212

Anion II Bromate 20 mg/L BrO3

- 100 mL 786936.1208

Chlorate: 20 mg/L ClO3

- 500 mL 786936.1210

Iodate: 20 mg/L IO3

-

Anion III Bromide: 100 mg/L Br- 100 mL 786937.1208

Chloride: 100 mg/L Cl- 500 mL 786937.1210

Fluoride: 100 mg/L F-

Phosphate: 100 mg/L PO4

3-

Nitrate: 100 mg/L NO3

-

Sulphate: 100 mg/L SO4

2-

Anion IV Bromide: 25 mg/L Br- 100 mL 786938.1208

Chloride: 10 mg/L Cl- 500 mL 786938.1210

Fluoride: 5 mg/L F-

Nitrate: 25 mg/L NO3

-

Nitrite: 15 mg/L NO2

-

Phosphate: 40 mg/L PO4

3-

Sulphate: 30 mg/L SO4

2-

Anion V Bromide: 1000 mg/L Br- 100 mL 786939.1208

Chloride: 1000 mg/L Cl- 500 mL 786939.1210

Fluoride: 1000 mg/L F-

Nitrate: 1000 mg/L NO3

-

Nitrite: 1000 mg/L NO2

-

Phosphate: 1000 mg/L PO4

3-

Sulphate: 1000 mg/L SO4

2-

Cation I Calcium: 1000 mg/L Ca2+ 100 mL 786940.1208

Magnesium: 1000 mg/L Mg2+ 500 mL 786940.1210

Potassium: 1000 mg/L K+

Sodium: 1000 mg/L Na+

Cation II Ammonium: 100 mg/L NH4

+ 100 mL 786941.1208

Calcium: 100 mg/L Ca2+ 500 mL 786941.1210

Magnesium: 100 mg/L Mg2+

Potassium: 100 mg/L K+

Sodium: 100 mg/L Na+

Cation III Ammonium: 2,5 mg/L NH4

+ 100 mL 786942.1208

Calcium: 5 mg/L Ca2+ 500 mL 786942.1210

Lithium: 0,5 mg/L Li+

Magnesium: 2,5 mg/L Mg2+

Potassium: 5 mg/L K+

Sodioum 2 mg/L Na+

Cation IV Ammonium: 40 mg/L NH4

+ 100 mL 786943.1208

Calcium: 40 mg/L Ca2+ 500 mL 786943.1210

Lithium: 10 mg/L Li+

Magnessium: 20 mg/L Mg2+

Potassium: 20 mg/L K+

Sodium: 20 mg/L Na+

Product name comPoSItIon (In h2o) contentS code Product name comPoSItIon (In h2o) contentS code

Ion Chromatography Standards

Auxiliary reagents for Ion Chromatography

Ion Chromatography Standards

Anion/Cation Multi-element Standards

Page 21: Analytical Standards - AppliChem · Panreac Química, with more than 70 years experience in the manufacture and control of analytical reagents, offers a wide range of standards with

21

Cation I Calcium: 1000 mg/L Ca2+ 100 mL 786940.1208

Magnesium: 1000 mg/L Mg2+ 500 mL 786940.1210

Potassium: 1000 mg/L K+

Sodium: 1000 mg/L Na+

Cation II Ammonium: 100 mg/L NH4

+ 100 mL 786941.1208

Calcium: 100 mg/L Ca2+ 500 mL 786941.1210

Magnesium: 100 mg/L Mg2+

Potassium: 100 mg/L K+

Sodium: 100 mg/L Na+

Cation III Ammonium: 2,5 mg/L NH4

+ 100 mL 786942.1208

Calcium: 5 mg/L Ca2+ 500 mL 786942.1210

Lithium: 0,5 mg/L Li+

Magnesium: 2,5 mg/L Mg2+

Potassium: 5 mg/L K+

Sodioum 2 mg/L Na+

Cation IV Ammonium: 40 mg/L NH4

+ 100 mL 786943.1208

Calcium: 40 mg/L Ca2+ 500 mL 786943.1210

Lithium: 10 mg/L Li+

Magnessium: 20 mg/L Mg2+

Potassium: 20 mg/L K+

Sodium: 20 mg/L Na+

UV/VIS spectrophotometers must be checked periodically to

ensure their correct functioning, thereby guaranteeing the

reliability of their results. The European Pharmacopoeia

recommends certain solutions for the control of UV/VIS

equipment that can be used to detect possible deviations arising

from electrical, mechanical or optical problems.

The parameters to be checked in UV/VIS spectroscopy according to the European Pharmacopoeia

are as follows:

Absorbance

Accuracy of the wavelength

Stray light limit

Spectral resolution

Panreac Química supplies four liquid standards that allow these parameters to be verified with

the following advantages:

Compliance with the European Pharmacopoeia.

Packaged in ready-to-use, disposable ampoules.

Certificate of analysis with each pack.

Three-year expiry date.

Absorbance Potassium Dichromate solution according to Ph. Eur. and RFE 395462.2590

4x10 mL Standard ampoules (60.06 mg/L K2Cr

2O

7 in H

2SO

4 0.01N)

4x10 mL Blank ampoules (H2SO

4 0.01N)

Wavelength Holmium Oxide solution according to Ph. Eur. 396070.2590

8x10 mL Standard ampoules (40.0 g/L Ho2O

3 in HClO

4 10% v/v)

Stray light Potassium Chloride solution according to Ph. Eur., BP and RFE 395460.2590

8x10 mL Standard ampoules (12 g/L KCl in H2O)

Spectral resolution Toluene solution in n-Hexane according to Ph.Eur. and RFE 395461.2590

4x10 mL Standard ampoules (0.02 mL toluene in 100 mL n-Hexane)

4x10 mL Blank ampoules (n-Hexane)

comPoSItIon codeSoLutIonS for the controL of:

8 x 10 mL ampoules

UV/VIS Spectrophotometry Standards

Auxiliary reagents for Ion Chromatography

Anion/Cation Multi-element Standards

Page 22: Analytical Standards - AppliChem · Panreac Química, with more than 70 years experience in the manufacture and control of analytical reagents, offers a wide range of standards with

22

Titration is one of the most common techniques used in analytical laboratories.

To check the factor of the solutions titrated, Panreac Química supplies Primary

Chemical Species (EQP) standards, highly chemically pure substances with a purity of 100 ±

0.05% after drying. We supply a total of 15 EQP standards, each available in boxes of 10

hermetically sealed glass tubes containing 1.5 g of the ready-to-use product as well as in

100-g glass bottles. As using the 100-g bottles exposes the product to air each time the bottle is

opened, we also provide suitable methods for drying the product. Each standard comes

with its corresponding certificate of analysis indicating its purity and tolerance, the method used

to determine this value, the NIST reference standard and the expiry date.

In the following table you will find information about the available EQP standards

and the suitable method for drying the product if necessary.

We supply a wide range of ready-to-use titrated solutions and a very wide range of

indicators. Do not hesitate to contact us.

acid

imet

ry

alka

limet

ry

arge

ntom

etry

com

plex

omet

ry

redo

x

Iodo

met

ry

SubStance tyPe of tItratIon dryIng temPerature (*) contentS PackagIng code

for sodium tartrate dihydrate, see water standards for karl fischer.

(*)dry in an oven at the indicated temperature for 2 hours and then allow to cool in a dessicator over P2o5

105ºC 10 x 1.5 g d 241151.1521 100 g a 241151.1608 80ºC 10 x 1.5 g d 241014.1521 100 g a 241014.1608 130ºC 10 x 1.5 g d 241487.1521 100 g a 241487.1608 110ºC 10 x 1.5 g d 241494.1521 100 g a 241494.1608 130ºC 10 x 1.5 g d 241500.1521 100 g a 241500.1608 105ºC 105ºC 10 x 1.5 g d 241481.1521 100 g a 241481.1608 130ºC 10 x 1.5 g d 241540.1521 100 g a 241540.1608 room temperature 10 x 1.5 g d 241459.1521 100 g a 241459.1608 120ºC 10 x 1.5 g d 241648.1521 100 g a 241648.1608 110ºC 10 x 1.5 g d 241659.1521 100 g a 241659.1608 130ºC 10 x 1.5 g d 241706.1521 100 g a 241706.1608 105ºC 10 x 1.5 g d 241940.1521 100 g a 241940.1608 130ºC 10 x 1.5 g d 241786.1521 100 g a 241786.1608

Arsenic(III) Oxide

Benzoic Acid

Potassium Bromate

Potassium Chloride

Potassium Dichromate

Potassium Hydrogen Diiodate

Potassium Hydrogen Phthalate

Potassium Iodate

Silver Nitrate

Sodium Carbonate anhydrous

Sodium Chloride

di-Sodium Oxalate

Tris (Hydroxymethyl)AminomethaneZinc Oxide

Volumetric Standards

100 g a 242697.1608

Page 23: Analytical Standards - AppliChem · Panreac Química, with more than 70 years experience in the manufacture and control of analytical reagents, offers a wide range of standards with

23

Water standards for calculating the titre (volumetric) and checking (coulometric)

Karl Fischer reagents. We supply both the solid standard sodium tartrate

dihydrate (EQP) and liquid standards.

A certificate of analysis is provided with each sales unit

Supplied in packs that prevent absorption of atmospheric moisture:

Liquid standards packaged in heat-sealed glass ampoules

Sodium tartrate dihydrate packaged in threaded glass tubes fitted

with a seal

We supply the AQUAMETRIC range of reagents for the

pyridine-free Karl Fischer determination of water. More

detailed information can be found in our AQUAMETRIC

leaflet. Do not hesitate to contact us.

Liquid 1.00 mg/g ± 0.005 mg/g 10 x 10 mL k 395459.2527

5.00 mg/g ± 0.02 mg/g 10 x 10 mL k 396883.2527

10.0 mg/g ± 0.1 mg/g 10 x 10 mL k 395458.2527

Solid 156.6 mg/g de Sodium ± 0.05 % 10 x 1.5 g d 241719.1521

Tartrate 2-hydrate(*) 100 g a 241719.1608

tyPe of Standard Water content of the Standard uncertaInty contentS PackagIng code

(*) the best method for conditioning the product is to store the standard in a desiccator over P2o5 for 24 hours.

Pyridine-free

Karl Fischer

reagents

For volumetric

and coulometric

water determination

Pyridine-free

Karl Fischer

reagents

For volumetric

and coulometric

water determination

Water standards for Karl Fischer

Page 24: Analytical Standards - AppliChem · Panreac Química, with more than 70 years experience in the manufacture and control of analytical reagents, offers a wide range of standards with

24

Chemical oxygen demand (COD) is a parameter used to measure the degree of water

pollution. It is the amount of oxygen (expressed in mg/L) consumed during the

oxidation of organic material present in the (natural or waste) water.

The procedure is based on oxidation of this material using potassium

dichromate as a strong oxidising agent in the presence of sulphuric acid

and silver and/or mercury ions as a catalyst.

Panreac Química supplies six potassium hydrogen phthalate standards

of different concentrations that allow the analyst to choose the most

appropriate depending on the COD concentration present in the samples.

All these standards are packaged in 25-mL glass bottles and come with their

corresponding certificate of analysis which indicates their NIST traceability.

In 25 mL-glass bottles

concentratIon comPoSItIon (PotaSSIum hydrogen PhthaLate In h2o) uncertaInty code

50 mg/L 0.0425 g/L ± 10 mg/L 394642.1606

150 mg/L 0.1275 g/L ± 25 mg/L 394547.1606

500 mg/L 0.4251 g/L ± 50 mg/L 394640.1606

1000 mg/L 0.8502 g/L ± 100 mg/L 394546.1606

3000 mg/L 2.5505 g/L ± 100 mg/L 394641.1606

7000 mg/L 5.9514 g/L ± 300 mg/L 394545.1606

COD Standards

Page 25: Analytical Standards - AppliChem · Panreac Química, with more than 70 years experience in the manufacture and control of analytical reagents, offers a wide range of standards with

25

Total Organic Carbon (TOC) is the amount of carbon linked to an organic

compound and is frequently used as a non-specific indicator of water

quality or the level of cleanliness of medical manufacturing equipment.

It is measured by the amount of carbon dioxide liberated on oxidising

the organic material under special conditions.

A distinction must be made between Total Inorganic Carbon (TIC), such

as carbonates, bicarbonates and dissolved carbon dioxide (CO2), and TOC,

which arises from the decomposition of plants, bacterial growth and

the metabolic activity of living organisms or chemical compounds.

Panreac Química supplies five TOC and five TIC standards for verifying analytical equipment. All these

standards are NIST traceable and come with their own certificate of analysis.

In 1000-mL Pe bottles

concentratIon comPoSItIon (PotaSSIum hydrogen PhthaLate In h2o) uncertaInty code

50 mg/L 0.1063 g/L ± 0.3 mg/L 396905.1211

100 mg/L 0.2126 g/L ± 0.5 mg/L 396906.1211

500 mg/L 1.063 g/L ± 3 mg/L 396907.1211

1000 mg/L 2.1255 g/L ± 5 mg/L 396908.1211

10 000 mg/L 21.255 g/L ± 50 mg/L 396909.1211

TOC Standards

In 1000-mL Pe bottles

concentratIon comPoSItIon uncertaInty code

50 mg/L 0.2206 g Na2CO

3 + 0.1749 g NaHCO

3 / L H

2O ± 0,3 mg/L 396900.1211

100 mg/L 0.4412 g Na2CO

3 + 0.3498 g NaHCO

3 / L H

2O ± 0,5 mg/L 396901.1211

500 mg/L 2.2061 g Na2CO

3 + 1.7486 g NaHCO

3 / L H

2O ± 3 mg/L 396902.1211

1000 mg/L 4.4122 g Na2CO

3 + 3.4972 g NaHCO

3 / L H

2O ± 5 mg/L 396903.1211

10 000 mg/L 44.122 g Na2CO

3 + 34.972 g NaHCO

3 / L H

2O ± 50 mg/L 396904.1211

TIC Standards

TOC and TIC standards

Page 26: Analytical Standards - AppliChem · Panreac Química, with more than 70 years experience in the manufacture and control of analytical reagents, offers a wide range of standards with

26

Turbidity is the lack of transparency of a liquid due to the presence

of suspended particles. Turbidity is considered a good measure of

water quality; the higher the turbidity the lower its quality.

A liquid can be considered transparent if its turbidity does not

exceed 3 NTU (Nephelometric Turbidity Units).

Panreac Química supplies a turbidity standard, Solution A and

Solution B. Its composition corresponds to that described in

Pharmacopeias (Ph.Eur., BP) and international regulations (Standard Methods for the Examination of Water and

Wastewater, ASTM for Water and Environmental Technology).

With these solutions can be prepared the 4000 NTU Primary Turbidity Suspension and from it by dilution achieved

diferent degrees of turbidity.

To obtain the 4000 NTU suspension, mix 5 ml of Turbidity Standard solution A with 5 ml of Turbidity Standard

solution B and allow to stand for 24 hours at 25°C. The required standard solutions can be prepared from this

standard by dillution with water. Shake the standard suspension before use. This suspension is stable for 2 months

when stored in a glass bottle.

Product name comPoSItIon code

Turbidity Standard Solution A 1.0 g Hidrazinium Sulphate in 100 mL water 395464.1209

Turbidity Standard Solution B 10.0 g Hexamethylenetetramine in 100 mL water 395465.1209

In 250-mL Pe bottles

Turbidity Standards

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We supply two types of colour standards:

Primary Solutions according to pharmacopoeia requirements for the

determination of the colour degree of liquids in the range of

brown-yellow-red colour.

Colour Standard Pt-Co according to APHA for the

determination of the colour intensity of liquids in the range from

pale yellow to reddish yellow.

Primary solutions established in Pharmacopoeias

Pharmacopoeias use these primary colour standards to provide the appropriate colour tone

for comparison with the substance described in the monograph upon mixing in the correct proportions.

Panreac Química offers three primary-colour solutions established by Pharmacopoeias (Ph. Eur, BP, USP

and Food Chemicals Codex).

We supply 10 g/L hydrochloric acid for the preparation of secondary solutions from the primary ones.

Panreac name Composition Ph. Eur. USP Code BP Food Chemicals Codex

Yellow Primary 45.00 ± 0.05 g FeCl3.6H

2O Yellow Primary Ferric Chloride - SC 125415.1208

Solution in 1L HCl 1% Solution

Blue Primary 62.40 ± 0.05 g CuSO4.5H

2O Blue Primary Cupric Sulphate - SC 125417.1208

Solution in 1L HCl 1% Solution

Red Primary 59.5 ± 0.1 g CoCl2.6H

2O Red Primary Cobalt Chloride - SC 125416.1208

Solution in 1L HCl 1% Solution

Primary solutions established in Pharmacopoeias

Product name contentS PackagIng code

Hydrochloric acid 10 g/L 1000 mL b 175567.1211

In 100 mL Pe bottles

Colour standards

Colour standards Auxiliary reagent

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APHA Pt-Co colour standard

The colour intensity of liquids can be estimated quickly using a platinum-cobalt standard according to ASTM D1209

(ASTM, 2000). Colour samples other than pale yellow or reddish yellow cannot be evaluated using this standard (in

these cases the colour standards according to Pharmacopoeia are recommended).

Panreac Química supplies the American Public Health Association (APHA) Pt-Co 500 colour standard, which contains

500 mg/L of platinum. Lower concentration colour standards can be prepared from this standard by

dilution with water.

The absorbance values of this APHA 500 standard are controlled and specified on the certificate.

Product name contentS PackagIng code

Colour Standard Pt-Co, 500 APHA 500 mL a 395508.1610

Wavelength (nm) Absorbance

430 0.110 - 0.120

455 0.130 - 0.145

480 0.105 - 0.120

510 0.055 - 0.065

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Must, or grape juice, contains variable amounts of

sugars. During alcoholic fermentation, these sugars

are converted into ethanol and carbon dioxide,

producing wine. The higher the sugar concentration

in the must, the higher the alcohol content in the

resulting wine.

The maturity index (sugar/total acidity) is used to choose the

correct moment for grape harvesting, therefore the maturity status of

the grape needs to be monitored regularly by refractometry.

Refractometry is an indirect method of determining the sugar concentration of the must by measuring its refractive

index. Panreac Química supplies sucrose standards for calibration and verification of refractometers used to

determine sugar content.

Each unit comes with its own certificate, which shows the actual value obtained from measuring 15 samples

thermostatted at 20.0 ± 0.1 °C with a refractometer. The tolerance limits are set to give a confidence interval of

95%. The specified value is guaranteed for two years from the date of issue of the certificate.

Wine StandardsRefractometer standard solutions

Product name contentS PackagIng code

Saccharose solutions pack (14.9% w/w, 3 x 3 x 10 mL l 625484.2122

19.4% w/w, 23.8% w/w)

Saccharose solution 14.9% w/w 1000 mL b 624867.1211

Saccharose solution 19.4% w/w 1000 mL b 624868.1211

Saccharose solution 23.8% w/w 1000 mL b 625241.1211

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Product name comPoSItIon concentratIon contentS PackagIng code

(mg/L In 10% ethanoL)

Methanol 100 20 x 1 mL x 345269.0922

1-Propanol 50

2-Butanol 20

Isobutanol 50

1- Butanol 30

2-Methyl-1-Butanol 100

3-Methyl-1-Butanol 100

Standard for Oenology

(Methanol and higher alcohols)

The acquired alcohol content (ABV) is a very important assay in wine

analysis as wines are valued in commercial transactions on the

basis of this value.

By definition, the acquired alcohol content is the number of

litres of ethanol and its homologues (methanol, higher alcohols,

2,3-butanediol, etc.) contained in 100 L of wine, both volumes

being measured at a temperature of 20 °C.

Panreac supplies two standards:

Oenology standard (Methanol and Higher Alcohols) for methanol and higher alcohol determinations by

gas chromatography.

Hydroalcoholic solutions with different concentrations for the calibration of alcohol meters and

densitometers used to determine alcohol content.

The Oenology standard is packaged in boxes of 20 single-use heat-sealed glass ampoules. Each box comes with its

corresponding certificate of analysis, indicating the chromatography conditions used and including the

corresponding chromatogram. The value specified on the certificate is guaranteed for two years from

its date of issue.

The hydroalcoholic solutions are packaged in 250-mL glass containers. Each bottle comes with its corresponding

certificate of analysis. The value specified on the certificate is guaranteed for five years from its date of issue.

Wine Standards Oenology Standard (Methanol and Higher Alcohols)

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Panreac supplies a wide range of reagents and products for the analysis of

wines and grape products.

The VINIKIT line includes over 50 specific reagents for use with standard

oenology analytical techniques. Do not hesitate to contact us.

Wine StandardsStandards for alcoholimeters and densimeters

Product name code

Hydroalcoholic Solution 13.5% v/v 625339.1609

Hydroalcoholic Solution 11% v/v 625338.1609

In 250 mL-glass bottles

a >> Glass bottle.

b >> Polyethylene bottle.

i >> Polyethylene canister.

C >> Polyethylene container with

removable tap.

1 >> Carton box with inner

polyethylene bag .

l >> Polyethylene bottle with

dropper.

d >> Glass tube with stopper

and screw top.

k >> Glass ampoule.

x >> Crimp top vial with

septum.

PackagIng SymboLS:

Kits and Reagents

for analysis of wines

Kits and Reagents for analysis of wines

Because of the continuous updating of our catalog of products and presentations, kindly confirm product availability, through our website.

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B

An ITW Company

Panreac Química S.L.U.C/ Garraf, 2 - Polígono Pla de la Bruguera E-08211 Castellar del Vallès (Barcelona) Spain Tel. (+34) 937 489 400 Fax (+34) 937 489 401 e-mail: [email protected]

Panreac Chimie S.A.R.L.129, rue ServientTour Credit Lyonnais69326 Lyon Cedex 03FranceTel. (+34) 902 438 439Fax (+34) 937 489 495 e-mail: [email protected]

Nova Chimica S.r.l.Via G. Galilei, 4720090 Cinisello Balsamo (MI)ItalyTel. +39 02 66045392Fax +39 02 66045394e-mail: [email protected]

www.panreac.comwww.yournewlifesciences.comwww.panreacpharma.com